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GEOSCIENCE FRONTIERS 3(6) (2012) 773e788

available at www.sciencedirect.com

China University of Geosciences (Beijing)

GEOSCIENCE FRONTIERS
journal homepage: www.elsevier.com/locate/gsf

RESEARCH PAPER

A geochemical perspective on charnockite magmatism


in Peninsular India
H.M. Rajesh

Department of Geology, University of Johannesburg, Johannesburg 2006, South Africa

Received 5 December 2011; received in revised form 20 March 2012; accepted 9 April 2012
Available online 17 May 2012

KEYWORDS Abstract Large charnockite massifs occur in the high-grade Southern Granulite Terrain (SGT) and
Charnockite massif; Eastern Ghats Belt (EGB) crustal provinces of Peninsular India. Available geochronological data indicate
Geochemistry; that the magmatism is episodic, associated with distinct orogenic cycles in the different crustal domains.
Peninsular India; The geochemical data also indicate a change in composition from trondhjemitic at w3.0e2.9 Ga to domi-
Southern granulite terrain; nantly tonalitic at w2.6e2.5 Ga to tonalitic-granodiorite-granitic at w2.0e1.9 Ga to dominantly tonalitic
Eastern Ghats belt at 1.7e1.6 Ga to quartz monzonitic or tonalitic at w1.0e0.9 Ga to granodiorite-granitic at w0.8e0.7 Ga.
The trondhjemitic and tonalitic end members are metaluminous, magnesian and calcic to calc-alkalic,
characteristic of magnesian group charnockites. The granodioritic to granitic end members are metalumi-
nous to slightly peraluminous, ferroan and calc-alkalic to alkali-calcic, characteristic of ferroan group
charnockites. The quartz monzonitic end members are metaluminous to peraluminous, magnesian to ferro-
an and calcic to calc-alkalic, neither characteristic of the magnesian group nor of the ferroan group of char-
nockites. Based on the occurrence and difference in composition of the charnockite massifs, it is suggested
that the charnockite magmatism registers the crustal growth of the Indian plate on its southern (SGT) and
eastern (EGB) sides, along active continental margins by accretion of arcs.
ª 2012, China University of Geosciences (Beijing) and Peking University. Production and hosting by
Elsevier B.V. All rights reserved.

1. Introduction

Charnockites characterized by orthopyroxene-bearing granitic


E-mail address: hmrajesh@uj.ac.za.
mineral assemblages are important components of the lower
1674-9871 ª 2012, China University of Geosciences (Beijing) and Peking
University. Production and hosting by Elsevier B.V. All rights reserved.
continental crust in many high-grade terrains (Bohlender et al.,
1992; Kilpatrick and Ellis, 1992; Sheraton et al., 1992; Berger
Peer-review under responsibility of China University of Geosciences et al., 1995; Zhou et al., 1995; Peucat et al., 1996; Duchesne
(Beijing). and Wilmart, 1997; Hughes et al., 1997; Prame, 1997; Frost
doi:10.1016/j.gsf.2012.04.003 et al., 2000; Janasi, 2002; Mendes et al., 2002; Percival and
Mortensen, 2002; Kar et al., 2003; Keppie et al., 2003;
Rajesh and Santosh, 2004; Shang et al., 2004; Janousek et al.,
2006; Mikhalsky et al., 2006; Tollo et al., 2006; Motuza et al.,
Production and hosting by Elsevier
2008; Skridlaite_ et al., 2008). The two high-grade crustal
provinces of Peninsular India, Southern granulite terrain and
774 H.M. Rajesh / Geoscience Frontiers 3(6) (2012) 773e788

Eastern Ghats belt, are characterized by large charnockite 2. Geologic setting


massifs (Fig. 1). They are the only known terrains in the world,
where charnockite massifs cover large tracts forming the 2.1. Southern Granulite Terrain
dominant rock type in the different blocks/provinces that make
up these terrains. Available geochronological and geochemical
The Southern Granulite Terrain (SGT), south of the Archean
data bearing on different charnockite massifs from the two
granite-greenstone terrane of the Dharwar Craton, consists of
high-grade provinces of Peninsular India are compiled here.
a series of Mesoarchean to Neoproterozoic polymetamorphic
Considering the occurrence of charnockite massifs as orthog-
blocks (the Salem, Madras, Nilgiri, Madurai and Trivandrum
neiss plutons and the pervasive nature of the regional meta-
blocks), separated from one another by regional shear zones
morphic events in the different blocks/provinces of the
(Drury et al., 1984; Harris et al., 1994; Braun and Kriegsman,
Southern granulite terrain and Eastern Ghats belt, which hosts
2003; Santosh et al., 2003, 2009; Fig. 1).
these charnockite massifs, an evaluation of the metamorphic
The region just to the south of Dharwar Craton, forming the
overprint on the chemistry of charnockites is carried out first.
northern part of SGT (the Salem, Nilgiri and Madras blocks)
This is followed by an evaluation of the geochemical charac-
preserves evidence for Neoproterozoic supra-subduction zone
teristics of charnockite massifs using samples that are least
magmatism followed by a prominent w2.5e2.4 Ga granulite-
likely to have been affected by the metamorphic overprint.
facies metamorphic event (Fig. 1; Peucat et al., 1993;
Based on the available tectonic models for Peninsular India, the
Mahabaleswar et al., 1995; Raith et al., 1999; Meissner et al.,
change in the geochemical characteristics of the charnockite
2002; Bhaskar Rao et al., 2003; Mojzsis et al., 2003; Santosh
massifs for different age brackets is used to place constraints
et al., 2003, 2011; Ghosh et al., 2004; Clark et al., 2009; Sato
on the nature of continental crust formation in Peninsular India
et al., 2011; Yellappa et al., 2011). The w2.5e2.4 Ga
with time.

Figure 1 Shaded relief image of Peninsular India showing the prominent geologic features, including the two high-grade crustal provinces of
Southern Granulite Terrain (SGT) and Eastern Ghats Belt (EGB) along the southern margin of Dharwar Craton and along the eastern margin of
eastern DharwareBastareSinghbhum cratons. The subdivisions of SGT and EGB, together with the approximate extent of the different meta-
morphic events in SGT are shown. Different charnockite massifs from SGT and EGB are indicated by white-filled abbreviations. See Table 1 for
details on the abbreviations. The Palghat Cauvery shear zone system (PCSS) includes a series of shear zones including the Moyar shear zone,
Bhavani shear zone, Palghat-Cauvery shear zone, Salem-Attue shear zone and Gangavalli shear zone.
H.M. Rajesh / Geoscience Frontiers 3(6) (2012) 773e788 775

metamorphic event extends south of the Palghat Cauvery shear preserves evidence for four metamorphic events (w1.2e1.1 Ga,
zone to the northern part of the Madurai block (Fig. 1; Bhaskar w1.0e0.9 Ga, w0.8e0.7 Ga and w0.6e0.5 Ga; Grew and Manton,
Rao et al., 2003; Ghosh et al., 2004; Brandt et al., 2011). The 1986; Shaw et al., 1997; Kovach et al., 1998; Mezger and Cosca,
region south of the Palghat Cauvery shear zone preserves evidence 1999; Bhattacharya et al., 2002; Dobmeier and Simmat, 2002;
for a prominent w0.6e0.5 Ga granulite-facies metamorphic event Biswal et al., 2007; Simmat and Raith, 2008; Upadhyay et al., 2009;
(Fig. 1; Bartlett et al., 1998; Braun et al., 1998; Meissner et al., Korhonen et al., 2011). Unlike SGT, the w1.0e0.9 Ga event corre-
2002; Santosh et al., 2003; Ghosh et al., 2004; Collins et al., sponds to the main fabric-defining granulite-facies metamorphism
2007; Brandt et al., 2011; Kr€oner et al., 2012). The eastern part and anatexis in EGB.
preserves a granulite-facies metamorphic event at w0.8e0.7 Ga
(Fig. 1; Santosh et al., 2003; Ghosh et al., 2004; Bhutani et al.,
2007; Catlos et al., 2008; Teale et al., 2011). The w0.8e0.7 Ga 3. Charnockite massifs from SGT and EGB
event has not been reported from the western part of SGT. The
southeastern part of Madurai block, in addition, preserves a local Available geochronological data, including igneous crystallization
granulite-facies metamorphic event at w0.9 Ga (Braun et al., and metamorphic overprint age, on the different charnockite
2007). The pervasive polyphase deformation and migmatization massifs from SGT and EGB is summarized in Table 1. Char-
that accompanied the latest granulite facies event (w0.6e0.5 Ga) nockite massifs in SGT occur along the southern margin of the
have largely erased structural imprints of early deformations in the Dharwar Craton. The northern part of SGT consists of Meso- to
SGT (Miller et al., 1996; Bartlett et al., 1998; Santosh et al., Neoarchean charnockite massifs. From west to east, these include
2003). Plate reconstructions suggest that the EdiacaraneCam- the Coorg hills massif, Biligirirangan hills massif, Shevroy hills
brian overprint of SGT is coincident with the amalgamation of massif, Madras massif, Nilgiri hills massif and Kollimalai massif
supercontinent Gondwana (Yoshida et al., 2003; Collins and (Fig. 1). At w3.0e2.9 Ga, the Biligirirangan hills massif forms
Pisarevsky, 2005; Santosh et al., 2009). the oldest charnockite massif in SGT (Mahabaleswar et al., 1995;
Mojzsis et al., 2003). Except the Coorg hills massif and the
2.2. Eastern Ghats Belt Kollimalai massif, available age data indicate that the remaining
charnockite massifs in the northern part of SGT were formed at
The Eastern Ghats Belt (EGB) is a high-grade terrain, extending in an w2.6e2.5 Ga (Table 1; Bernard-Griffiths et al., 1987; Peucat
arcuate pattern over 1000 km along the eastern fringe of Peninsular et al., 1993; Raith et al., 1999; Bhaskar Rao et al., 2003;
India (Fig. 1). The craton (eastern DharwareBastareSinghbhum)e Santosh et al., 2003; Ghosh et al., 2004; Clark et al., 2009; Sato
EGB contact in eastern India, where the granulite-facies rocks of the et al., 2011). No age data are available for the Coorg hills and
EGB are thrusted over the cratonic rocks, has been interpreted as Kollimalai massifs and these massifs are therefore not included in
a crustal suture related to Indo-Antarctic collisional events (Chetty this study.
and Murthy, 1994; Leelanandam et al., 2006; Biswal et al., 2007; Charnockite massifs from the northeastern part of the Madurai
Das et al., 2008; Upadhyay, 2008; Mohanty, 2012) which resulted in block (Kodaikanal hills massif) yield w2.6e2.5 Ga age (Brandt
the formation of the Proterozoic EGB orogen (Grew and Manton, et al., 2011; Plavsa et al., 2012), whereas those from the south-
1986; Dasgupta and Sengupta, 2003; Dobmeier and Raith, 2003). eastern part of the Madurai block (Cardamom hills massif) yield
Like the SGT, EGB also includes a series of multiply deformed and w1.0e0.9 Ga and w0.8e0.7 Ga ages (Santosh et al., 2003;
polymetamorphosed terrains, bounded and segmented by shear Ghosh et al., 2004; Plavsa et al., 2012). The northern part of the
zones and thrust faults (Ramakrishnan et al., 1998; Rickers et al., Trivandrum block exposes the w1.9 Ga Erinpura massif (Kr€ oner
2001; Dasgupta and Sengupta, 2003; Dobmeier and Raith, 2003). et al., 2012), while the southern part of Trivandrum block exposes
Not withstanding the arguments against it (e.g., Gupta, 2004), the the w2.0e1.9 Ga Nagercoil massif (Ghosh et al., 2004; Santosh
present study uses the classification scheme of Dobmeier and Raith et al., 2006).
(2003) which subdivided the EGB into four crustal provinces (the Charnockites are widely reported throughout the EGB (Halden
Jeypore, Rengali, Eastern Ghats and Krishna provinces; Fig. 1) based et al., 1982; Aftalion et al., 1988; Paul et al., 1990). Like SGT, the
on the isotopic data of Rickers et al. (2001) combined with available oldest charnockite massifs in EGB are w3.0e2.9 billion years old
petrological, structural and other geochronological data. and occur near the craton-mobile belt contact. This include the
Both the Jeypore province in the northwest, adjacent to the Bastar Jenapore massif near the contact of EGB and Singhbhum Craton,
Craton, and the Rengali Province in the north, adjacent to the close to the boundary of the Rengali Province (Bhattacharya et al.,
Singhbhum Craton (Fig. 1), preserve evidence for a granulite-facies 2001) and the Machkund massif within the Jeypore Province (Subba
metamorphic event at w2.8 Ga (Kovach et al., 2001). Although no Rao et al., 1998; Kovach et al., 2001; Rickers et al., 2001). No record
subsequent metamorphic imprints are identified from the Jeypore and of the dominant w2.6e2.5 Ga charnockite magmatism as in the
Rengali provinces, the shear zones and fault zones forming respective northern part of the SGT as well as the w2.0e1.9 Ga charnockite
boundaries with the Eastern Ghats province were reactivated during magmatism as in the southern part of the SGT is available from
w1.1e1.0 Ga and w0.6e0.5 Ga orognesis (Crowe et al., 2001; EGB. After the Mesoarchean, the next record of charnockite mag-
Upadhyay and Raith, 2006). The Ongole domain of the Krishna matism in EGB occurs at w1.7e1.6 Ga (Kovach et al., 2001;
province, which is closer to the eastern Dharwar Craton, preserves Dobmeier et al., 2006; Dharma Rao et al., 2012). The Kondapalle
evidence for a pervasive metamorphic event at w1.7e1.6 Ga massif belongs to this group (Dharma Rao et al., 2012). The
(Mezger and Cosca, 1999; Kovach et al., 2001; Simmat and Raith, dominant charnockite-forming event in EGB occurred at
2008; Upadhyay et al., 2009). No younger metamorphic events w1.0e0.9 Ga, as part of the Grenvillan orogeny (Grew and Manton,
have been reported from the Ongole domain, except its western 1986; Aftalion et al., 1988; Paul et al., 1990; Shaw et al., 1997;
margin which was reworked at amphibolite-facies conditions at Kovach et al., 1998; Krause et al., 2001). The charnockite massifs
w0.6e0.5 Ga (Dobmeier et al., 2006; Upadhyay et al., 2006). The near Eleswaram, Narsipatnam, Vizianagaram, Paderu, Visakha-
largest of the four provinces, the Eastern Ghats province (Fig. 1), patnam, Srikakulam and Bobili areas belong to this group.
776 H.M. Rajesh / Geoscience Frontiers 3(6) (2012) 773e788

Table 1 Summary of available geochronological data on the different charnockite massifs from SGT and EGB. See text for references on
geochronological data. Metamorphic overprint age refers to age of metamorphic overprint on the different charnockite massifs.
Charnockite massifa Abbreviation High-grade Block/Province Igneous crystallization Metamorphic overprint
used in Fig. 1 terrain age (Ga) age (Ga) from the massif
Biligirirangan hills massif BG SGT Salem block w3.0e2.9 w2.5e2.4
Nilgiri hills massif NG SGT Nilgiri block w2.6e2.5 w2.5e2.4
Shevroy hills massif SH SGT Salem block w2.5 w2.5e2.4
Madras massif MD SGT Madras block w2.6e2.5 w2.5e2.4
Kodaikanal hills massif KK SGT Madurai block w2.6e2.5 w0.6e0.5
Nagercoil massif NL SGT Trivandrum block w2.0e1.9 w0.6e0.5
Erinpura massif ER SGT Trivandrum block w1.9 w0.6e0.5
Cardamom hills massif CM SGT Madurai block w1.0e0.9 w0.6e0.5
Cardamom hills massif CM SGT Madurai block w0.8e0.7 w0.6e0.5
Jenapore massif JP EGB Rengali province w3.0e2.9 w2.8
Machukund massif MC EGB Jeypore province w3.0e2.9 w2.8
Kondapalle massif KP EGB Krishna province w1.7e1.6 w1.6
Visakhapatnam massif VK EGB Eastern Ghats province w1.0e0.9 w0.9
Vizianagram massif VN EGB Eastern Ghats province w1.0e0.9 w0.9
Bobili massif BB EGB Eastern Ghats province w1.0e0.9 w0.9
Srikakulam massif SK EGB Eastern Ghats province w1.0e0.9 w0.9
Eleswaram massif EL EGB Eastern Ghats province w1.0e0.9 w0.9
Narsipatnam massif NP EGB Eastern Ghats province w1.0e0.9 w0.9
Paderu massif PD EGB Eastern Ghats province w1.0e0.9 w0.9
a
highlands made of dark greenish charnockite rocks that underlie a prominent, high-standing topographic feature.

In general, the charnockite massifs from both SGT and EGB an invariable feature of granulite-facies rocks (e.g. Rollinson,
form highland areas of dark greenish to greenish-gray charnockite 1996). In spite of the metamorphic overprint, the K/Rb ratios of
interspersed with lowlands consisting of gneissic rocks (granitic different charnockites from SGT and EGB are similar to those
orthogneisses and/or paragneisses) that have experienced found in common igneous rocks, including unmetamorphosed
amphibolite to granulite-facies metamorphism. They are locally charnockites [e.g. charnockites from Louis Lake Batholith,
homogenous and massive in appearance in quarry exposures. Wyoming (Frost et al., 2000); Fig. 2a]. This raises the question of
Often the massive charnockite exposures are overprinted by foli- the effect of metamorphic overprint on the chemistry of these
ation, defined by mafic (biotite, pyroxene and/or garnet) and felsic charnockites. Despite the well-documented LILE depletion of
minerals. The xenoliths, occurring as either bands and/or lenses, in many granulites, an increasing number of studies indicate that this
the different charnockite massifs include aluminous metapelites, is not a universal character (e.g. Berger and Rollinson, 1997;
garnet-biotite gneisses, amphibole- and pyroxene-bearing mafic Rollinson and Tarney, 2005) and indeed some studies suggest that
granulites, calc-silicate rocks, and rare pyroxenites and kyanite- the LILE abundances in many granulites reflect the composition of
bearing metaquartzitic rocks (e.g. Raith et al., 1999; Rajesh et al., the pre-metamorphic protolith (e.g. Knudsen and Andersen,
2011). Cross-cutting charnockitic dykes have been reported from 1999).
the different charnockite massifs, with available geochronologic Rajesh et al. (2011) carried out a detailed geochemical study
studies indicating similar age with the main charnockite body (e.g. on the w2.0e1.9 Ga Nagercoil charnockite massif from SGT. In
w2 Ga charnockitic dyke within the Nagercoil massif; Ghosh spite of the Late NeoproterozoiceCambrian granulite-facies
et al., 2004). metamorphic overprint on the Nagercoil massif, the K/Rb ratios
Although all the charnockite massifs show overprints of of the charnockites are similar to those found in common igneous
subsequent granulite-facies metamorphism (see Table 1), the rocks, including unmetamorphosed charnockites (Fig. 2a). The Sr
igneous nature of their protoliths is evident from the homogeneity contents of the Nagercoil charnockite define a low Sr
at outcrop scale, presence of enclaves and xenoliths, cross-cutting (143e406 ppm) and high Sr (604e911 ppm) group (Fig. 2c). This
charnockitic dykes and preserved granitic textures (Rajesh and grouping can be extended to other major and trace elements
Santosh, 2004). (Fig. 3). The high Mg-number, high Ni, Cr and Sr, and low Y
assign TTG affinities to the high-Sr Nagercoil charnockite
samples (e.g. Fig. 2d). On the other hand, the low-Sr samples from
4. Geochemical characteristics of charnockite
the Nagercoil charnockite do not show any TTG affinity. The
massifs similar ranges of w(SiO2) contents for both low-Sr (w61%e72%)
and high-Sr (w61%e71%) group charnockites (e.g. Figs. 2c and 3),
4.1. Effect of metamorphic overprint indicate that the process that was responsible for lowering the Sr
contents was pervasive. Considering the probable effect of later
Considering the metamorphic overprint, it is important to under- metamorphic overprint, a comparison of the chemistry of low-Sr
stand the effect of granulite-facies metamorphism on the original Nagercoil charnockite samples was made with that of
igneous chemistry of the different charnockite massifs. Depletion orthopyroxene-bearing metamorphic dehydration zones (popularly
in Rb, as indicated by high K/Rb ratios, is a common, although not known as incipient charnockites) occurring in gneisses from
H.M. Rajesh / Geoscience Frontiers 3(6) (2012) 773e788 777

Figure 2 (a) K2O vs. K/Rb plot of the charnockite massifs considered here from SGT and EGB. Open and closed symbols for the Nagercoil and
Nilgiri hills massifs from SGT, and those for the Jenapore massif from EGB represent high-Sr and low-Sr samples, respectively. Unmetamor-
phosed charnockites from the Louis Lake Batholith, Wyoming (Frost et al., 2000) is shown for comparison; (b) Normative An-Ab-Or triplot
illustrating the similar chemical composition high-Sr and low-Sr charnockite samples from the Nagercoil and Nilgiri hills massifs from SGT; (c)
Sr vs. SiO2 plot illustrating the low-Sr and high-Sr group of charnockite samples from the Nagercoil and Nilgiri hills massifs from SGT and from
the Jenapore massif from EGB. See Rajesh et al. (2011) for references used to compile the compositional range of orthopyroxene-bearing
metamorphic dehydration zones; (d) Sr/Y vs. Y plot illustrating the similarity of high-Sr charnockite samples from the Nagercoil and Nilgiri
hills massifs from SGT to Archean TTGs. The fields are from Drummond and Defant (1990).

southern India and elsewhere (Figs. 2c and 3), which are carried out as the timing of formation of the orthopyroxene-
considered to represent in situ stages of granulite formation driven bearing metamorphic dehydration zones in gneisses surrounding
by the influx of low-aH2O fluids (e.g. Newton et al., 1980; the different charnockite massifs, including the Nagercoil massif,
Santosh, 1986; Hansen et al., 1987; Santosh and Omori, 2008; correspond to the metamorphic overprint reported in the different
Harlov, 2012; Touret and Huizenga, 2012). Such an exercise was charnockite massifs as well as the respective regional meta-
morphic event (e.g., Mojzsis et al., 2003; Ghosh et al., 2004;
Santosh et al., 2006; Clark et al., 2009; Brandt et al., 2011; Plavsa
et al., 2012; see also Table 1). At similar SiO2 contents, low-Sr
charnockite samples have higher TiO2, Fe2O3, K2O and Nb
contents and lower Na2O, and Al2O3 contents, similar to the
dehydration zones (e.g. Fig. 3). The high K2O and Nb contents of
the low-Sr charnockite samples correlate well with geochemical
studies that demonstrated the important role of potassium in the
formation of some dehydration zones (e.g. St€ahle et al., 1987;
Raith and Srikantappa, 1993). It follows that the chemistry of low-
Sr Nagercoil charnockite samples can be correlated with the late
metamorphic event, whereas the high-Sr Nagercoil charnockite
samples were most likely not affected by metamorphism.
The w2.6e2.5 Ga Nilgiri hills charnockite massif from SGT is
another example. In spite of the w2.5e2.4 Ga granulite-facies
metamorphic overprint on the Nilgiri hills massif, the K/Rb ratios
of the charnockites are similar to those found in common igneous
rocks, including unmetamorphosed charnockites (Fig. 2a). Like
the Nagercoil charnockite, the Sr contents of the Nilgiri hills
charnockite define a low Sr (125e471 ppm) and high Sr
(725e1087 ppm) groups (Fig. 2c). Both groups have similar
Figure 3 Representative major- and trace-element variation ranges of w(SiO2) contents (high-Sr group: 56%e66%; low-Sr
diagrams of the high-Sr and low-Sr charnockite samples from the group: 58%e70%). The Mg-number, high Ni, Cr and Sr, and
Nagercoil massif. See Rajesh et al. (2011) for references used to low Y assign TTG affinities to the high-Sr Nilgiri hills charnockite
compile the compositional range of orthopyroxene-bearing meta- samples (e.g. Fig. 2d). On the other hand, the low-Sr samples from
morphic dehydration zones. the Nilgiri hills charnockite do not show any TTG affinity. Like
778 H.M. Rajesh / Geoscience Frontiers 3(6) (2012) 773e788

Figure 4 Charnockites from SGT and EGB in terms of normative An-Ab-Or triplot (a), Fe*/(Fe*þMgO) vs. SiO2 plot (b) and Na2OþK2O-
CaO vs. SiO2 plot (c). w1.0e0.9 Ga charnockites from East Antarctica (Rayner complex) are shown for comparison. The fields in (b) and (c) are
from Frost et al. (2001). Source of geochemical data for Figs. 4e6: w3.0e2.9 Ga: Condie and Allen (1984), Janardhan et al. (1994), Subba Rao
et al. (1998), Raith et al. (1999), Bhattacharya et al. (2001), Kar et al. (2003), Mojzsis et al. (2003); w2.6e2.5 Ga: Howie (1955), Howie and
Subramaniam (1957), Subramaniam (1959), Weaver et al. (1978), Weaver (1980), Condie and Allen (1984), Bernard-Griffiths et al. (1987),
Janardhan et al. (1994), Srikantappa (1996), Raith et al. (1999), Tomson et al. (2006), Catlos et al. (2011); w2.0e1.9 Ga: Rajesh et al. (2011);
w1.7e1.6 Ga: Dharma Rao et al. (unpublished data); w1.0e0.9 Ga: Paul et al. (1990), Chacko et al. (1992), Munksgaard et al. (1992), Sheraton
et al. (1992), Young et al. (1997), Zhao et al. (1997), Saradhi et al. (2000), Mikhalsky et al. (2006), Rajesh (2007); w0.8e0.7 Ga: Chacko et al.
(1992), Rajesh (2007).
H.M. Rajesh / Geoscience Frontiers 3(6) (2012) 773e788 779

the w2.0e1.9 Ga Nagercoil massif, at similar SiO2 contents, the from both massifs define a low-Sr and high-Sr group [Jenapore
low-Sr Nilgiri hills charnockites have higher TiO2, Fe2O3, K2O massif: low Sr (94e472 ppm), high Sr (593e1075 ppm), Kar
and Nb contents and lower Na2O and Al2O3 contents, similar to et al., 2003; Kondapalle massif: low Sr (426e499 ppm), high Sr
that of orthopyroxene-bearing metamorphic dehydration zones (531e620 ppm), Dharma Rao et al., unpublished data; e.g.
(e.g. Fig. 2c). Fig. 2c]. Like the youngest massifs in SGT, the w1.0e0.9 Ga
Following the scenarios of the w2.0e1.9 Ga Nagercoil massif massifs from EGB do not show any low-Sr and high-Sr grouping
and the w2.6e2.5 Ga Nilgiri hills massif, available geochemical within individual massifs. Available geochemical data on these
data from the different charnockite massifs from SGT were evalu- massifs from EGB have uniformly low K/Rb values, lower than
ated in terms of their Sr content. Significantly, available geochem- those of the older episodes of charnockite magmatism (Fig. 2a).
ical data define low-Sr and high-Sr groups for the w3.0e2.9 Ga The Sr contents are also uniformly low for all the w1.0e0.9
Biligirirangan hills massif [low Sr (171e479 ppm), high Sr massifs from EGB (w40e280 ppm; Saradhi et al., 2000). The
(620e981 ppm); Condie and Allen, 1984; Janardhan et al., 1994; significance of the uniformly low-Sr contents for the different
Mojzsis et al., 2003], the w2.5 Ga Shevroy hills massif [low Sr w1.0e0.9 massifs from EGB is not clear at this stage.
(75e428 ppm), high Sr (591e879 ppm); Rameswar Rao et al.,
1991; Hansen et al., 1995; Hansen and Harlov, 2007], the 4.2. Geochemical characteristics of the charnockite massifs
w2.6e2.5 Ga Madras massif [low Sr (96e479 ppm), high Sr
(533e821 ppm); Weaver, 1980; Bernard-Griffiths et al., 1987], and This section evaluates the geochemical characteristics of the
the w2.6e2.5 Ga Kodaikanal massif [low Sr (100e461 ppm), high different charnockite massifs from SGT and EGB. For older
Sr (591e1576 ppm); Tomson et al., 2006; Catlos et al., 2011]. The episodes of charnockite magmatism, only the high-Sr samples
low-Sr samples of these charnockite massifs are similar in compo- were considered. Regarding the younger episodes of charnockite
sition to orthopyroxene-bearing metamorphic dehydration zones, magmatism (w1.0e0.9 Ga and w0.8e0.7 Ga massifs from SGT
while the composition of high-Sr samples are different and were and w1.0e0.9 Ga massifs from EGB), all the available
most likely not affected by later metamorphism.
An exception to the above exercise includes the w1.0e0.9 Ga
and w0.8e0.7 Ga charnockites within the Cardamom hills massif.
Here the older charnockites have high Sr (447e766 ppm)
contents, whereas the younger charncokites have low Sr
(223e455 ppm) contents (Chacko et al., 1992; Rajesh, 2007). This
raises the question of whether a low-Sr content can be used as an
indicator of metamorphic overprint in charnockite massifs of
a wide range of ages. Some studies (e.g. Martin and Moyen, 2002)
explain variations in Sr content in Archean TTG granitiods by the
presence or absence of residual plagioclase in the source. They
interpret the secular behavior of Sr in terms of melting depth, with
the depth of partial melting being relatively shallow at 4.0 Ga
(w550 ppm Sr) to greater depths of partial melting at 2.5 Ga
(w1200 ppm Sr). However, unlike the studies on TTG granitiods
compiled by Martin and Moyen (2002), where the Sr content of
TTG granitiods varies with time (w550 ppm at 4.0 Ga to
w1200 ppm at 2.5 Ga), available geochemical data define distinct
low Sr and high-Sr groups within individual charnockite massifs
from SGT (e.g. w2.0e1.9 Ga Nagercoil massif, w2.6e2.5 Ga
Nilgiri hills massif e see Fig. 2c). Considering that at similar
ranges of SiO2 contents (e.g. Figs. 2c and 3), both low-Sr and
high-Sr group charnockites within individual massifs have distinct
geochemical characteristics, with the former showing affinities to
Archean TTGs (e.g. Fig. 2d) and latter showing similarities to
orthopyroxene-bearing metamorphic dehydration zones
(e.g. Fig. 3) occurring in gneissic rocks surrounding the different
charnockite massifs, this study considers the high-Sr charnockites
to be not affected by later metamorphism and hence representative
of the original igneous protolith composition within individual
massifs. The significance of the Sr contents reported for the older
and younger charnockites within the Cardamom hills massif is not
clear at this stage.
The situation is no different for the charnockite massifs from
EGB. In spite of the later granulite-facies metamorphic overprint
on the w3.0e2.9 Ga Jenapore massif and the w1.7e1.6 Ga
Kondapalle massif, the K/Rb ratios of charnockites from these Figure 5 Plot of Rb-Sr-Ba concentrations for charnockites from the
massifs are similar to those found in common igneous rocks, SGT and EGB provinces. Data field for ca. 1.0e0.9 Ga charnockites
including unmetamorphosed charnockites (Fig. 2a). Available from East Antarctica (Rayner complex) shown for comparison. See
geochemical data indicate that the Sr contents of charnockites Rajesh and Santosh (2004) for details on the fields.
780 H.M. Rajesh / Geoscience Frontiers 3(6) (2012) 773e788

geochemical data from the literature were used for the the w2.6e2.5 Ga counterparts, the tonalitic samples from the
geochemical characterization. The geochemical data from the Madras massif have high Ba and Sr contents relative to Rb
different massifs are presented here using a series of diagrams (included in Fig. 5), and shows affinities to Archean TTGs
(Figs. 4e6; see the caption of Fig. 4 for the source of data). (included in Fig. 6).
The w3.0e2.9 Ga Bligirirangan hills massif from SGT and the The w2.0e1.9 Ga episode of charnockite magmatism, which
w3.0e2.9 Ga Jenapore and Machukund massifs from EGB are affected only the southern part of SGT, exhibits differentiated
dominantly trondhjemitic, metaluminous, magnesian and calcic to compositions from tonalite to granodiorite to granite, is metal-
calc-alkalic (Fig. 4aec). They have high contents of Ba and Sr uminous to slightly peraluminous, calcic to calc-alkalic to alkali-
relative to Rb (Fig. 5). These rocks show geochemical charac- calcic and magnesian to ferroan (Fig. 4aec). They have high Ba
teristics similar to those of Archean TTGs (Fig. 6). Their Mg# and Sr contents relative to Rb (Fig. 5). Like the w2.6e2.5 Ga
[Mg/(Mg þ Fetot): w30e55] values are similar to those of TTGs counterparts, the tonalitic samples from the w2.0e1.9 Ga episode
younger than 3.0 Ga and are slightly higher than those of TTGs of charnockite magmatism show TTG affinities (Fig. 6).
older than 3.0 Ga (see compilation in Smithies et al., 2003). The w1.7e1.6 Ga episode of charnockite magmatism, which
The w2.6e2.5 Ga episode of charnockite magmatism, which affected only the EGB, is dominantly tonalitic, metaluminous,
affected only the northern part of SGT, is dominantly tonalitic, magnesian and calcic to calc-alkalic (Fig. 4aec). Like the tonalitic
metaluminous, magnesian and calcic to calc-alkalic (Fig. 4aec). members of the older episodes of charnockite magmatism, the
Like the w3.0e2.9 Ga charnockites, the w2.6e2.5 Ga char- w1.7e1.6 Ga charnockite massifs also have high Ba and Sr
nockite massifs also have high Ba and Sr contents relative to Rb contents relative to Rb (Fig. 5), and show affinities to Archean
(Fig. 5), and show affinities to Archean TTGs (Fig. 6), with Mg# TTGs (Fig. 6).
values (w30e50) similar to those of TTGs younger than 3.0 Ga. The w1.0e0.9 Ga episode of charnockite magmatism affected
The w2.6e2.5 Ga Madras massif is an exception to the above both SGT and EGB. Like the w2.6e2.5 Ga episode forming the
group, and exhibits greater differentiation with compositions dominant episode of charnockite magmatism in SGT, the
extending from tonalite to granodiorite to granite. It is metal- w1.0e0.9 Ga episode forms the dominant episode of charnockite
uminous to slightly peraluminous, magnesian to ferroan, and magmatism in EGB. All the w1.0e0.9 Ga massifs from EGB are
calcic to calc-alkalic to alkali-calcic (not shown in Fig. 4). Like quartz monzonitic in composition and have slightly different

Figure 6 Plot of Y vs. Sr/Y concentrations for charnockites from the SGT and EGB provinces. Data field for ca. 1.0e0.9 Ga charnockites from
East Antarctica (Rayner complex) shown for comparison. The fields are from Drummond and Defant (1990).
H.M. Rajesh / Geoscience Frontiers 3(6) (2012) 773e788 781

trends (Fig. 4a) in comparison with the tonalitic-granodioritic- continental crust growth (preservation) with time presented by
granitic counterparts. They are metaluminous to peraluminous, Condie and Aster (2010) (Fig. 7). To evaluate the significance of
magnesian to ferroan and calcic to calc-alkalic (Fig. 4b, c). They this charnockite magmatism on the tectonic models for Peninsular
have low Ba and Sr contents relative to Rb (Fig. 5). Here the India, it is important to first evaluate the general geochemical
magnesian samples are calcic and peraluminous, whereas the characteristics of charnockites and their general tectonic
ferroan samples are calc-alkalic and metaluminous. connotation.
The youngest episode of charnockite magmatism in SGT is Recent compilations of geochemical data on charnockites from
represented by w1.0e0.9 Ga and w0.8e0.7 Ga charnockites of different parts of the world, including southern India, indicate that
the Cardamom hills massif in the southeastern part of the Madurai charnockites generally belong to three groups: (1) a magnesian,
block. They have distinct geochemical characteristics, with the calcic to calc-alkalic, metaluminous group, (2) a ferroan, alkali-
older charnockites tonalitic, predominantly metaluminous, calcic to alkalic, metaluminous group, and (3) a transitional group
magnesian and calc-alkalic (Fig. 4aec), whereas the younger that straddles from ferroan to magnesian group (Fig. 8; Rajesh and
charnockites are granodioritic to granitic, metaluminous to Santosh, 2004; Rajesh, 2007; Frost and Frost, 2008). In general,
slightly peraluminous, magnesian to ferroan and calc-alkalic to the magnesian charnockites are tonalitic (trondhjemitic counter-
alkali-calcic (Fig. 4aec). The older charnockites have high Ba and parts are also magnesian, but occurrences are few relative to
Sr contents relative to Rb (Fig. 6), whereas the younger char- tonalites), whereas the ferroan charnockites are granodioritic to
nockites have low Ba and Sr contents relative to Rb (Fig. 6). granitic (Rajesh, 2007). The transitional group charnockites are
quartz monzonitic. In general, the ferroan charnockites likely
occur in extensional tectonic settings whereas the magnesian
5. Discussion e Implications on the tectonic models group charnockites likely form in magmatic arcs (Frost and Frost,
for Peninsular India 2008). The transitional group charnockites likely occur in
continent-continent collision tectonic settings (Rajesh, 2007).
Available geochronologic data (Table 1) indicate that the char- Before addressing the significance of the geochemical char-
nockite magmatism affected the high-grade SGT and EGB prov- acteristics of the different charnockite massifs from SGT and EGB
inces at w3.0e2.9 Ga, w2.6e2.5 Ga, w2.0e1.9 Ga, with time, available tectonic models for Peninsular India are
w1.7e1.6 Ga, w1.0e0.9 Ga and w0.8e0.7 Ga. Interestingly, summarized. The Southern Granulite Terrain and Eastern Ghats
this distribution of the timing of charnockite magmatism from Belt form high-grade crustal provinces juxtaposed against low-
Peninsular India nearly corresponds with the beginning and grade granite-greenstone assemblages to the south (Dharwar
waning stages of peak clusters of frequency distribution of Craton) and to the east (eastern DharwareBastareSinghbhum

Figure 7 Frequency distribution of juvenile continental crust growth (preservation) with time in bins of 50 Ma (from Condie and Aster, 2010),
compared with time frames of episodic charnockite magmatism in Peninsular India. Bars labeled SGT and EGB indicate the timeframe of
charnockite formation in Southern granulite terrain and Eastern Ghats belt, respectively. See text for references on geochronological data used to
define the different episodes of charnockite magmatism in Peninsular India. V indicates the abundance in terms of aerial distributions of rocks of
known ages estimated from geologic maps.
782 H.M. Rajesh / Geoscience Frontiers 3(6) (2012) 773e788

(1989) to the concept of “synaccretion” granulite-facies meta-


morphism. Different studies supported this accretion event for
individual blocks of SGT using different parameters like structural
discontinuity, discontinuities in lithologic units, change in meta-
morphic conditions, age differences including Nd model ages,
variation in crustal thickness, bipolar magnetic-gravity signatures,
and other geophysical evidences (e.g. Drury et al., 1984; Peucat
et al., 1989; 1993; Harris et al., 1994; Hansen et al., 1997;
Meissner et al., 2002; Mojzsis et al., 2003; Rao et al., 2006; Clark
et al., 2009; Santosh et al., 2009; Naganjaneyulu and Santosh,
2010). The intervening shear zones that separate the different
blocks are proposed as suture zones (e.g. Drury et al., 1984;
Collins et al., 2007; Santosh et al., 2009), with recent studies
identifying ophiolitic components and high-pressure eclogitic
rocks within them (e.g. Sajeev et al., 2009; Yellappa et al., 2010;
Santosh et al., 2011). In the above scenario, the southern blocks
(Madurai and Trivandrum blocks) became part of the Indian
ensemble during the Neoproterozoic, with ocean closures along
the Palghat Cauvery shear zone and the Achankovil zone.
The craton (eastern DharwareBastareSinghbhum)eEGB
contact in eastern India, where the granulites of the EGB are
thrusted over the cratonic rocks, has been interpreted as a crustal
suture related to Indo-Antarctic collisional events (Chetty and
Murthy, 1994; Leelanandam et al., 2006; Biswal et al., 2007;
Das et al., 2008; Upadhyay, 2008) that resulted in the formation of
the Proterozoic EGB orogen (Grew and Manton, 1986; Dasgupta
and Sengupta, 2003; Dobmeier and Raith, 2003). Using a combi-
nation similar to that used in SGT, of Sm-Nd and Rb-Sr crustal
residence ages with Pb isotopes, which is very useful for the
discrimination of old reworked crust from juvenile crust (e.g.
DePaolo, 1988), an accretionary model similar to that for the
northern part of SGT has been proposed for the transition between
Figure 8 Fe*/(Fe*þMgO) vs. SiO2 and Na2OþK2O-CaO vs. SiO2 the Dharwar Craton and EGB (Rickers et al., 2001). Thus the
plots illustrating the general grouping of charnockites from different Rengali and Jeypore provinces were accreted to the cratonic India
parts of the world into magnesian, ferroan and transitional groups. In during w3.0e2.9 Ga. Based on similar aged events from the
addition to the references from SGT and EGB (see caption of Fig. 4), Krishna province of EGB and Napier complex of East Antarctica,
the following references were used to compile the geochemical data Dobmeier and Raith (2003) suggested that the collision between
used to define the different fields e Kilpatrick and Ellis (1992), the Napier complex and eastern Dharwar Craton occurred between
Bohlender et al. (1992), Sheraton et al. (1992), Whitney (1992), w1.7 and 1.6 Ga. Various continental reconstruction studies have
Berger et al. (1995), Zhou et al. (1995), Peucat et al. (1996), Duchesne pointed out the adjacent position of the largest province of EGB,
and Wilmart (1997), Hughes et al. (1997), Prame (1997), Young et al. the Eastern Ghats province and Rayner complex of East
(1997), Zhao et al. (1997), Volker and Drake (1999), Frost et al. Antarctica at w1 Ga as part of the Eastern GhatseRayner
(2000), Janasi (2002), Percival and Mortensen (2002), Mendes et al. complex terrane (Yoshida et al., 1992; Fitzsimons, 2000; Kelly
(2002), Elliott (2003), Keppie et al. (2003), Ownby et al. (2004), et al., 2002; Dasgupta and Sengupta, 2003; Dobmeier and Raith,
Slagstad et al. (2004), Shang et al. (2004), Tollo et al. (2004), Wilson 2003; Dobmeier et al., 2006; Kelsey et al., 2008). As the
and Overgaard (2005), D’Souza et al. (2006), Janousek et al. (2006), Archean cratonic forelands (the Jeypore and Rengali provinces)
Mikhalsky et al. (2006), Tollo et al. (2006), Motuza et al. (2008) and and the Krishna province of the EGB, lack any Grenvillian
Skridlait_e et al. (2008). (w1 Ga) tectono-metamorphic imprint, but have been affected by
late Neoproterozoic deformation and low-grade retrogression, the
Eastern GhatseRayner complex terrane was not welded to
cratons), respectively. Various geochronologic studies from the subcontinental India until the Late Neoproterozoic to Cambrian
northern part of SGT have shown that the different blocks south of aggregation of Gondwana (e.g. Fitzsimons, 2000; Dobmeier et al.,
the Dharwar Craton host quartzo feldspathic juvenile crust that 2006). According to isotope data presented by Rickers et al.
accreted to the south of the craton during two episodes e an older (2001), the continent-continent collision for the EGB at
one at w3.0e2.9 Ga and a younger one at w2.6e2.5 Ga (Peucat w1.7e1.6 and w1 Ga involved only minor addition of juvenile
et al., 1989, 1993; Hansen et al., 1997; Mojzsis et al., 2003). material.
Whole rock Sm/Nd and Rb/Sr initial isotope ratios correspond to The charnockites in Peninsular India occur to the south of the
direct mantle derivation with no record of prior crustal residence Dharwar Craton in SGT, and to the east of the eastern Dhar-
(e.g. Peucat et al., 1989), a finding that has been confirmed by wareBastareSinghbhum cratons in EGB (Fig. 1). The
single-crystal zircon U-Pb geochronology (e.g. Peucat et al., geochemical characteristics of the w3.0e2.9 Ga Biligirirangan
1993). The nearly synchronous crustal accretion and high-grade hills, Jenapore and Machukund massifs, typical of magnesian
metamorphism in the northern part of SGT led Peucat et al. group charnockites (Fig. 4), support formation in an active
H.M. Rajesh / Geoscience Frontiers 3(6) (2012) 773e788 783

continental margin setting (Fig. 9). It is suggested that these differentiated, showing tonalitic-granodioritic-granitic composi-
charnockite massifs form part of the initial crustal accretion event tions and belonging to both the magnesian and ferroan group of
to the Dharwar, Bastar and Singhbhum cratons, respectively. charnockites (Fig. 4). The geochemical characteristics of the least
The w2.6e2.5 Ga charnockites, occurring only in the SGT, differentiated samples from these charnockites are tonalitic and
represent abundant juvenile material added to the crust as indi- similar to magnesian group charnockites, supporting formation in
cated by their tonalitic composition (Fig. 4) and available Sm/Nd an active continental margin setting (Fig. 9).
and Rb/Sr isotope ratios in combination with Pb isotope results The w1.7e1.6 Ga episode of charnockite magmatism occurs
(Peucat et al., 1989, 1993; Hansen et al., 1997; Raith et al., 1999; only in EGB. Although the time frame of w1.7e1.6 Ga represents
Bhaskar Rao et al., 2003). Their geochemical characteristics, a pervasive tectono-metamorphic event in the Krishna province
typical of magnesian group of charnockites (Fig. 4), support near eastern Dharwar Craton, only one charnockite massif (Kon-
formation in an active continental margin setting (Fig. 9), forming dapalle massif) is reported from this province. The geochemical
part of the w2.6e2.5 Ga crustal accretion event to the south of the characteristics of the Kondapalle charnockites are tonalitic and
Dharwar Craton. similar to magnesian group charnockites (Fig. 4). It probably
The w2.0e1.9 Ga episode represented by the Nagercoil massif represents the minor juvenile material added to EGB during
in the southern tip of the Trivandrum block in SGT is more w1.7e1.6 Ga (Rickers et al., 2001).

Figure 9 Charnockites from SGT and EGB in terms of Nb/Zr vs. Zr plot. w1.0e0.9 Ga charnockites from East Antarctica (Rayner complex)
are shown for comparison. The fields are from Thieblemont and Tegyey (1994).
784 H.M. Rajesh / Geoscience Frontiers 3(6) (2012) 773e788

The w1.0e0.9 Ga charnockite massifs from the Eastern Ghats south of the shear zones represents an arc system (e.g. Chetty and
province, the largest of the provinces in EGB, are quartz mon- Murthy, 1994; Leelanandam et al., 2006; Biswal et al., 2007;
zonitic and have geochemical features that are neither character- Collins et al., 2007; Santosh et al., 2009, 2011). The w1.0e0.9 Ga
istic of the magnesian-group nor of the ferroan-group of charnockites from EGB are an exception to the above scenario,
charnockites (Fig. 4). Significantly, the w1.0e0.9 Ga charnockite with continent-continent collision being the likely tectonic setting
massifs from Rayner complex of East Antarctica are also quartz for their formation. Thus the charnockite magmatism registers the
monzonitic (Fig. 4). Their geochemical characteristics (Fig. 9) crustal growth of the Indian plate on its southern (SGT) and
support the possible collision between the Eastern Ghats province eastern (EGB) sides, respectively, along active continental
and Rayner complex, accounting for the widespread w1.0e0.9 Ga margins by the accretion of arcs.
charnockite massifs in the Eastern GhatseRayner complex
terrane.
The w1.0e0.9 Ga and w0.8e0.7 Ga episodes of charnockite
Acknowledgments
magmatism in SGT, form the older and younger components,
respectively, of the Cardamom hills massif in the southeastern Richard Tollo, Eugene Mikhalsky and Grazina Skridlait_e provided
Madurai block. The geochemical characteristics of the older detailed, encouraging and insightful comments on the manuscript.
charnockites are tonalitic and similar to magnesian group char- This is a contribution to the Paleoproterozoic Mineralization
nockites (Fig. 7), supporting formation in an active continental (PPM) Research Group and Gondwana Institute for Geology and
margin setting (Fig. 9). The younger charnockites on the other Environment (GIGE).
hand are granodioritic to granitic (Fig. 4). The details of the
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