Chemistry Screeni119 Test 2007: AIPMT

2
a. 1. The correct order of C- 0) bond length among CO, co:; , C02 is:

a. co < C02 <co;-

b.
C02 <co;- <co

c.
co <co;- < C02

d.
<cot < C02 <CO

Sol. The correct order ot C- 0 bond length will be CO < C02 <COt

b HS-

c NH;
d E-

a SrSO.,
b. Baso.
c. MgSO.,
d. ｒ｡ｳｯｾ＠

Sol. s.le out or the given alkaline ean11 metal sulphates. Correct choice: (3)

statements. about 111e advantage of roastin>J sulphide ore before reduction is

or I he sulphide to the oxide is thermodynamically feasible.

rbon and hydrogen are suitable reducing agents for metal sulphides.

c. The IJ. ,a• of t11e sulpllide is greater than those for cs, andH,S
d. The IJ. ,a• is negative lor roas1ing of sulphide ore to oxice

Sol. Carbon and hydrogen are not suitable tor reduction of sulphides directly. Correct choice: t2)
Q. 5. The correct order of increasing thermal stability of

K 2 C03 < MgC03 < CaC03 < BeC03

a.
BeC03 < MgC03 <K2 C03 <CaC03
b.
BeC03 < MgC03 <CaC03 < K 2 C03
c.
MgC03 < BeC0 3 < < ｃ｡ｾ＠ < K 2 C03
d.

b Argenllle
c Galena
d Copper pyrite

f Silver m 111e Me Arthur Forrest Cyamde

Q, 7. WhICh one Of the IOIIOWI

Sio'-
Si2o' 6 -
a.
1
b.
(Sio;-).
c.
d.
(Si 2 o52 -)•
•
, have the general formula (Sio;- )•Correct c11oice: (4)
of the loffowing orcers correctly represents I he increasing acid strengths of I he given

a. HOC10 3 < HOC10 2 < HOCJO < HOCJ

HOC10 3 < HOCJO < HOC10 2 < HOC10 3
b.
HOC103 < HOCJ < HOC103 < HOC10 2
c.
HOC10 2 < HOC10 3 < HOCJO < HOCJ
d.
Sol. The correct order is HOCJ03 < HOCJO < HOCl02 < HOCJ03
Correct choice: (2)

Q, 9. Wllich of the following oxidation states are tile most characteristic for lead and tin respectively?

+ 2. + 2
b + 4 + 2
c + 2. + 4

Q, 10. Identify the incorrect statement among the foBowing:

a. Shielding power of 4f electrons is quite weak

b.
c. s
d. f the transition elements have

Sol. The atomic radii of 4d and 5d elements come Q uHe ｳｩｭｴｾ｡ｲ＠ due to

a. Mn 3•
b. Cr3+
v3•
c.
7i3+
d.

= . V = 23. Cr = 24, Mn = 25)

stable ion in aqueous medium. Correct choice: (2)

electron configurations of Cr. Which one of the

｣ｯｭｰｾ･ｸｳ＠ will exhibit I he minhnum paramagoeHc behaviour?

a.
[cr(HA)t
b.
[Mn (HP6 )t
c. [F€(H 2 06 )t
 d.

(Atomic number. Cr + 24, Mn = 25, Fe= 26, Ni = 28)

least paramagnetic character. Correct choice: i4)

Q. 13. Wllich of the followin>J will give a pair of enanliomorplls'l

a. [Pt (NH 3 ),][Ptq]

b.
[co (NH 3 ) 4 c!J!V02
c.
[cr (NH 3\ ][co (CN)6 ]
[Co (en )2 CI2 ] Cl
d

6.02 X 10t4 mort

a.
6.02 X 10tS mort
b.
6.02 X 10t6 mort
c.
6.02 X 10t1 mort
d.

Sol. Number of ｭｯｬ･ｳｾ＠ jc

10""' ｾ＠
--=
2
10 mole
10

FCHpOOH >ClCH 2COOH > BrCH 2 COOH > CH 3COOH

CHpOOH > BrCH 2 COOH > CICH2 COOH > FCH2 COOH
FCHpOOH > CHpOOH > BrCH 2COOH > CICH2 COOH
c.
BrCH 2 COOH > CICHpOOH > FCH2 COOH > CH 3COOH
d.
Q, 16. Tile product formed in A!do! condensation is

a. an alpha. beta unsaturated ester

b. a beta·hydroxy acid
c. a beta·hydroxy aldehyde or a beta·hydroxy ketone
d.

Sot. Aldol condensation leads to formation of

a
b Ctemmensen Reducl!on
c. Cope Reduction
d. Dow Reduction

Sol. This is Ctemmensen's reduction. Correct ct1oice:

Q, 18. Consider the following compounds

a.

b.

c.

d.

o . of their reactivity towards hydrolysis is

(C)

attack of the nucteophite onto the carbonyl carbon is Ule rate·determining step. So. order must
(b)> (d)> ia) .>{c) Correct choice: i1)

Q, 19. Which one of the following on treatment with 50% aqueous sodium
 0
II
iCH 3 -C-CH 3
a.
b.
C6 H 5CH2 CHO
C6 H 5CHO

d
CHPH2CH2CHO

a. Methyl Cyanide
b. Nilroelllane
c. Methylisocyanide
d. Acetamide

Sol. Methyl isocyanide on reduction wilh LiAIH .1 will give

Q, 21. The order of decreasing reactivity towards

a. Benzene
b. Toluene
c. Chlorobenzene
d. Phenol would be

a. d-..,b>a >c
b. a ... b > c >d

c.
d.
•
d > b >a > c. Correct c11oice: (1 1

the product C obtained in the following reaction of

HI
CH3CH2- Ca CH CH + HCI --7B --7C
 I

CHPH2 - C- CH3

a. Cl

CH 3 - CH - CH2CH21

b. Cl
I

CH 3 -CH 2 -CH2 -C-H

c. Cl
I

CH 3 - CH2 - CH- CH 2CI

d.

I
HCI Hl

Sol.
Cl Cl
Correct choice:

with molecular formulaC5H 10 yields acetone on ozonolysis?

Methvl - 2 - butane
- 1 -butane

03

(CH 3 ) 2 C = CH- CH 3 -7(CH 3 ) 2 C = 0 + CHpHO

Sot. 2-methyl2-butene Zn1H2 0
 Correct choice: (2)

Q, 24. If there is no rotation of plane polarized light by a compound in a specific solvent thought to be
chiral. it may mean that

a. the compound may be a racemic mixture

tl. Ihe compound is certa;nly a ch;ral
c. the compound is certainly meso
d. there is no compound in the solvent

activity. it means the com pound must certainly be meso.

Q, 25. For tile following

a. l-
b. Cl-
c. Br-

the increasing order of nucleophilicity would be:

a.
s,.- <Cr <r
b.
r <Bt·- <Cr
c.
cr <Br- <r
d.
r <Cr <Br-

Sol. The orcer of nucleo(?s o ions in water idefault solvent) will be cr < Br- < r
Correct c11oice: (3 1
ｾ＠
Q, 26. CH 3 - CHCI- CH2 - CH3 has a chiral centre. Which one of the following represents its R
｣ｯｮｦｩｧｵ［Ｚｾ＠ •

3
' CH

ｾｈＭｃｊ＠
a. C2Hs
 C2 Hl

H 3C - C- C/
I
b.
Cl
C2 Hs

H - C -CH 3

c. C/
Cl Hs

H -C -CH 3

d.
C/

C:Jl ,
ct 0C i l,C\l

S ol. !!

heat ed
CH - CH - CH 2 0 - CH 2 - CH 3 +HI -l> .... ..
3

ｾｯｭｲ
- ＾ｯ ｵ Ｌｮ､ ｳ＠ will be forme d?

a.
 b.

CH 3 - CH- CH 3 +CH 3 CHpH

c.

d.

Correct choice: ( 1)

Q, 28. Which one of the following vitamins is

a. Vitam;n A
b. Vitamin B
c. Vitam;n E
d

are ｾｲ｡ｴ＠ molecules. llleir cllirality is due to

phosphate ester units

Deoxyribose and ribose sugars are D -chiral sugars in DNA and RNA. Correct choice: i1)

Q. 30. Wllich one of the followin>J polymers is prepared by condensation polymerization'!

a. Styrene l
 1>. Nylon - 66
C. Teflon
d. Rubber

Sol. Nylon-66 is a condensation polymer of 11examethylene diamine and adipic acid. ··.Correct choice: