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1 Introduction
The use of water mist for fire extinguishment has increased rapidly in recent years. The main
reason is the abandonment of halon-based extinguishing system in favour of environmentally
friendlier systems. With increased use of water mist, the evolution of existing techniques for
producing relevant droplets for a chosen enclosure and probable fire scenario has occurred.
This has called for a more detailed and thorough understanding of the interaction between
water and the fire environment. One tool to enhance the knowledge of water mist is to use
numerical models. However there is a big discrepancy between the results from current
available models for calculation of water mist as Fluent, FDS and Branzfire and results from
experiments1.
In this paper, physical and theoretical descriptions of water droplet dynamics in a fire
environment are gathered to form a basis for more accurate numerical models.
• Spray formation
• Droplet size distribution
• Spray throw-length
• Spray-gas momentum transfer
• Heat absorption
• Gas- and surface- cooling
Different types of nozzles will be discussed and spray droplet velocity maps based on PIV,
(Particle Induced Velocimetry) will be shown.
The most common type in water mist systems is by direct droplet formation from a turbulent
water jet. How the break-up of the jet takes place depends on the jet speed and diameter.
There are four different ways droplets can be formed from a water jet:
A “Rayleigh break-up” regime. The droplet is formed far away from the nozzle. The
diameter of the droplets is bigger than the hole in the nozzle.
i
Email: bph@dift.dk, Danish Institute of Fire and Security Technology, Jernholmen 12, 2650 Hvidovre,
Denmark, ph. +4536349000. Fax. +4536349001
1
Proc. IWMA conference 2004, 6-8 October 2004, Rome, Italy
D ”Atomization”. Droplet formation takes place at the exit from the nozzle. The
diameter of the droplets is much smaller than the diameter of the hole in the nozzle.
Figure 1 shows a picture of the four different ways droplets can be formed.
The dominating factors that control the droplet formation mechanism are the Reynolds
number and the Ohnesorge number. The Ohnesorge number, Oh, is the ratio between the
viscous forces and the surface tension.
µ
Oh = (1)
ρσd
where µ is the dynamic viscosity of the fluid (Ns/m2), σ is the surface tension (Ν/m), ρ is the
density and d is the diameter of the nozzle.
For a typical high pressure nozzle with a internal diameter of 0.8 mm the Ohnesorge number
is 0.004.
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Proc. IWMA conference 2004, 6-8 October 2004, Rome, Italy
The droplet size also depends on the pressure in the nozzle. The droplet size is reduced
considerately up to a pressure of 7 bars. At higher pressures, the situation becomes more
complex and droplet size is reduced at a much lower rate. Figure 3 shows the measured
droplet size distribution at different pressures.
35
30
25
% Droplets
20 15 bar
80 bar
15 100 bar
10
0
0 50 100 150 200 250 300
Diameter (10^-6 m)
3
Proc. IWMA conference 2004, 6-8 October 2004, Rome, Italy
Table 1 shows d32 (Sauter mean diameter) variation at the 3 different pressures in Figure 3. It
can be seen that the diameter is only reduced by 50%, when increasing the pressure from 15
to 100 bar.
The remaining forces that acts on the droplet can be derived from Newton's second law:
F=
d
dt
( )
m ⋅ v = m ⋅ g − CD ⋅
π ⋅ d 2 ⋅ ρl
8
( )
⋅ v − v l ⋅ v −v l (2)
In the equation:
π d3
F = The total force which acts on the droplet, m = mass of droplet = ρ w ⋅
6
ρw = density of water, d = droplet diameter, v = droplet velocity vector,
g = gravity, v l = velocity vector of the surrounding air,
v ⋅ d ⋅ ρl
CD = drag coefficient related to the Reynolds number of the droplet ( )
µ
Due to the frictional force, the droplet will slow down. Setting the force F = 0 in equation 2
gives the terminal velocity of the droplet. For droplet Reynolds number less than 1, the drag
coefficient (CD) can be calculated on the basis of Stokes law, CD = 24/Re. This means that
equation 2 can be solved analytically for droplets up to 80 µm. For droplets bigger than 80
µm (Re>1), the equation must be solved by numerical methods.
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Proc. IWMA conference 2004, 6-8 October 2004, Rome, Italy
100
0.005 mm
90 0.01 mm
0.05 mm
0.1 mm
80
0.5 mm
70
60
m/s
50
40
30
20
10
0
0 0.002 0.004 0.006 0.008 0.01
Time [s]
Figure 5 Vertical deceleration of different droplet sizes. Initial speed is 100 m/s.
0.8
0.005 mm
0.7 0.01 mm
0.05 mm
0.1 mm
0.6 0.5 mm
0.5
m0.4
0.3
0.2
0.1
0
0 0.002 0.004 0.006 0.008 0.01
Time [s]
Figure 6 Vertical distance vs. time for various droplet sizes. Initial speed 100 m/s.
As can been seen from the calculations in figure 5 and figure 6, small droplets decelerate very
fast. A droplet size of 100 µm, typical for water mist systems, deaccelerates in 0.01 second
from 100 till 10 m/s in a distance of 0.3 m. During deceleration, the droplet evaporates,
depending on the moisture content and temperature of the air. This influences the drag force
and the droplet size, but according to 3 it has only a minor influence on the drag force in
equation (2).
As can be seen from the calculation, the throw length for single water droplets with diameters
< 100-200 µm is very short, even if they have a initial speed created by a water pressure of
100-200 bar in the nozzle. The only way to increase throw length is to reduce the relative
velocity between the droplet and the surrounding air.
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Proc. IWMA conference 2004, 6-8 October 2004, Rome, Italy
How this will occur depends on how the nozzle distributes the droplets. The most common
spray patterns are full cone and hollow cone. In a full cone spray, the droplets are distributed
evenly across the entire spray angle, whereas in a hollow cone, the droplets are mostly in the
perimeter of the cone.
By analysing two pictures of droplets illuminated with a laser sheet and taken with a short
time interval, the velocity field can be defined experimentally. This type of measuring
equipment is called PIV, ”Particle Induced Velocimetry”, figure 7.
Figure 7 Velocity field in a spray (Hollow cone, 80 bar, nozzle diameter = 0.8 mm).
From figure 7, it can be seen that the droplets in the spray are decelerated from 90-100 m/s
to10-30 m/s in a distance of 0.3 m and that the velocity field inside the hollow cone is very
complex.
r
Nozzle ϑ
s
νl
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Proc. IWMA conference 2004, 6-8 October 2004, Rome, Italy
For nozzles that form a full cone spray the air velocity, νl, in the spray can be calculated
from4:
∗ 0.5
mw ⋅ p ∗
vl ≈ where m is mass flow rate of water, p is the nozzle pressure and r is the spray
r w
1
r ≈ s ⋅ tan (ϑ / 2 + φ ) ⋅ , ϑ ≤ 45 o
2
r = s ⋅ tan( ϑ /4), ϑ > 45 o
where ϑ is the cone angle, s is the distance from the nozzle and φ is defined in the entrainment
picture above.
60
50 1 l/min
40
2 l/min
m/s
30
5 l/min
20
10 10 l/min
0
0 0,2 0,4 0,6 0,8 1 1,2
Distance from nozzle, m
Figure 9 Calculated mean air flow speed in a full cone at various water mass flows
From figure 9, it can be seen that the air velocity is less than 5 m/s 1 m downstream of the full
cone nozzles, at flows up to 10 l/min. This means that the droplet will have lost most of the
initial momentum and also the additional momentum obtained from air entrainment close to
the nozzle.
dV 1 dd 3 1 dd Π 2 dd
= Π = Π ⋅ 3d 2 = d (3)
dt 6 dt 6 dt 2 dt
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Proc. IWMA conference 2004, 6-8 October 2004, Rome, Italy
The convective heat transfer to a droplet in hot air is proportional to the temperature
difference ∆T between the air and the droplet, heat transfer coefficient h and the square of the
droplet diameter, which gives
2
dQ d
= h ⋅ A ⋅ ∆ T = h ⋅ 4 ⋅ Π ⋅ ⋅ ∆T (4)
dt 2
If the heating of the droplet to 100° C is ignored, the received energy leads only to
evaporation of the droplet, which can be described as:
dQ dV Π dd
= −H v ⋅ ρ w ⋅ = −H v ⋅ ρ w ⋅ ⋅ d 2 ⋅ (5)
dt dt 2 dt
where Hv is the heat of evaporation for water. The change in droplet diameter over time can
then be written as
dd 2h
=− ⋅ ∆T (6)
dt Hv ⋅ ρ
For small water droplets the heat transfer coefficient h is given by the dimensionless Nusselt
number, Nu:
h⋅d
Nu = = 2 + 0.6 ⋅ Pr 0.33 ⋅ Re 0.5 (7)
k
This equation can be solved analytically for some simple cases.
For droplets smaller than 0.1 mm, the droplet is decelerated very rapidly and reaches terminal
velocity quickly. At that velocity, natural convection will dominate and the Nusselt number
will be equal to 2. Combining equations 6 and 7 gives:
dd 4 ⋅ k ⋅ ∆T
=− (8)
dt Hv ⋅ ρ ⋅d
If the temperature difference between the droplet and the air is constant over time, an
integration of (8) leads to
d 2 = d 02 − β ⋅ t (9)
where
8 ⋅ k ⋅ ∆T
β=
Hv ⋅ ρ
Table 2 shows the lifetime for droplets with different diameters and different gas
temperatures.
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Proc. IWMA conference 2004, 6-8 October 2004, Rome, Italy
However, during deceleration the convective heat transfer dominates, which will reduce
droplet lifetime even further.
Using equations (2), (6) and (7), a system of partial differential equations are obtained that
can be solved numerically
Table 3. Initial speed 100 m/s, temperature in fire room 150 °C.
Droplet diameter (10-6 m) Distance Life time, Initial sp. 100 m/s
5 0.239 mm 3.9 ms
10 7.87 mm 15.5 ms
50 111 mm 372.0 ms
100 387 mm 1400.0 ms
Table 3 shows how far a droplet is transported and the estimated droplet lifetime. In table 4,
the lifetime for droplets with and without initial speed is shown. It can be seen from table 4
that the lifetime of the droplet is not greatly influenced by the initial droplet speed.
Table 4. Comparison of lifetime for free falling droplets with droplets with an initial speed of
100 m/s, at a gas temperature of 150 °C.
Droplet diameter (10-6 m) Life time, free falling Life time, Initial sp. 100 m/s
5 3.9 ms 3.9 ms
10 15.6 ms 15.5 ms
50 391.2 ms 372.0 ms
100 1564.8 ms 1400.0 ms
The reason for the small difference in lifetimes is due to the fast deceleration of the droplet, as
seen in figure 10. Note that the droplet has a high speed for only a short period. The
conclusion is that a high initial speed (high nozzle pressure) does not substantially increase
the evaporation rate.
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Proc. IWMA conference 2004, 6-8 October 2004, Rome, Italy
-4
x 10
100 1
80 0.8
60 0.6
m/s
m
40 0.4
20 0.2
0 0
0 0.2 0.4 0.6 0.8 1 1.2 1.4
Time [s]
Figure 10. Evaporation of a droplet of 0.1 mm with an initial speed of 100 m/s against time. Left axis is
speed of droplet; right axis is diameter of droplet. Temperature of gas is 150 °C.
The thermal quenching concept is based on energy balance at stochiometry in the flame:
where Xw represent the mole fraction of water, Xf = mole fraction of fuel, Xp= mole fraction
of combustion products, XN2 = mole fraction of nitrogen, Xdi= mole fraction of dissociated
molecules. C represent the molar heat capacity of lw = liquid water, gw = water vapour, gp =
10
Proc. IWMA conference 2004, 6-8 October 2004, Rome, Italy
combustion products and gN2 = nitrogen. L is the latent heat of vaporisation of water, ∆H c =
heat of combustion, ∆H di = heat of dissociation.
Experimentally, it has been found that a hydrocarbon flame will extinguish at an adiabatic
flame of about 1550°K. It can be shown using equation (10) that for a premixed
stoichiometric propane-air flame a concentration of 280 g water per cubic metre can
extinguish the flame (assuming that all water will be evaporated).
For a diffusion flame, an extinguishing concentration of 140-190 g water mist per cubic meter
would be required, as a diffusion flame has higher heat loss than a premixed flame.
Experimental measurements on diffusion flames9 gives values which vary between 150 to 200
g water per cubic meter air. This is very close to the theoretical calculation.
If water vapour at 100°C is used instead of water droplets, about double the amount of water
is required.
When water is sprayed at a hot wall, it will absorb heat. Water has a high latent heat of
vaporisation, 2260 kJ/kg. By using water the right way, high cooling effects can be obtained.
After the water has hit the wall, it will be warmed up while running down the wall. Some of
the water will be evaporated. But the heat transfer from a hot wall to a water droplet is a very
complex process, which depends on the collision speed of the droplet at the wall, the diameter
of the droplet and the temperature of the wall. Here the dimensionless parameter, Weber
number (We), is used to describe what happens at the collision.
di(λ , S )
= − K a (λ , S )i (λ )
ds
where i is the radiation intensity, λ the radiation wave length and Ka the absorption
coefficient. The solution to this equation is the well-known expression:
i (λ , S ) = i (λ ,0)e [− K a ( λ ) S ]
If the gas is also emitting radiation due to high temperatures, the following differential
expression is used:
di(λ , S )
= − K a (λ , S )i (λ ) + K a (λ , S )ib (λ )
ds
11
Proc. IWMA conference 2004, 6-8 October 2004, Rome, Italy
where ib is the black-body radiation from the particle based on its temperature. The emission
and absorption coefficients are assumed equal, based on Kirchoff's law that states that the
emissivity and the absorbtivity of a gas are equal. If the volume S contains particulate material
(e.g. water droplets) that scatter radiation, the intensity attenuation obtained in S can be
described by similar simple expressions as long as the physics of in-scattering (i.e. the
radiation intensity increase due to scattering in surrounding particles) can be neglected. This
simplification leads to a Lambert-Beer type of attenuation description:
di(λ , S )
= − K s (λ , S )i (λ )
ds
i(S’)
ds
i(S) i(S+ds)
The differential equation describing radiation attenuation based on absorption, emission and
scattering is then obtained as:
di ( λ , S )
= −(K a ( λ , S ) + K s ( λ , S ) )i ( λ ) + K a ( λ , S )ib ( λ )
dS
(
i (λ , S ) = i (λ ,0)e [− K ( λ ) S ] + ib 1 − e [− K a ( λ ) S ] )
where K=Ka+Ks .
12
Proc. IWMA conference 2004, 6-8 October 2004, Rome, Italy
If in-scattering is included in the model and spherical coordinates (θ, φ) used, an integro-
differential equation, the Radiation Transfer Equation (RTE) is obtained:
2π π
diλ ( S , θ , φ ) K
= −(K a + K s ) iλ ( S , θ , φ ) + K a ibλ ( S ) + s ∫∫ iλ ( S , θ ' , φ ' ) P( S ' → S ) sin θ ' dθ ' dφ '
dS 4π 0 0
where index λ is used to indicate wave-length dependence and P is the phase function,
defined by
Energy scattered from the S ' to the S − direction
P( S ' → S ) = lim ds →0
Energy scattered to S in isotropic scattering
i.e. P=1 when the scattering is isotropic (direction-independent) . The phase function can be
derived from Maxwell’s fundamental equations on electricity and magnetism. When particle
size is much lessii than the electromagnetic wave length (λ), a more simple, Rayleigh
scattering model can be used, giving as phase functioniii
3
P ( Θ) = 1 + cos 2 ( Θ)
4
( )
where θ is the angle between the plane of the incident ray and the reflected ray.
For a ”large”iv opaque particle having a diffuse reflecting surface the phase function
8
P ( Θ) = (sin(Θ) − Θ cos(Θ) )
3π
is obtained. The phase functions given are depicted in figure 12.
Phase function P
3.00
2.50
Diffuse
2.00
Rayleigh
P(θ)
1.50
isotropic
1.00
0.50
0.00
0 20 40 60 80 100 120 140 160 180
Angle, θ
As can be seen from the figure, Rayleigh scattering has a minimum in a plane orthogonal to
the incident plane but diffusive scattering is dominated by backward scattering.
ii
Basically when ξ = π d <0.3
λ
iii
Since the phase function is general for all incident angles P=P(x) is written instead of P=P(x’->x).
iv
Basically when ξ > 5. For 0.3 < ξ < 5, Mie scattering theory is used.
13
Proc. IWMA conference 2004, 6-8 October 2004, Rome, Italy
In figure 13 is shown a comparison between a well-known simplified model for the full RTE,
the “Two-flux model” and a model without the scattering contribution, i.e. only based on the
Lambert-Beers law10. As can be seen, the estimated transmission is markedly different when
scattering is included.
Simulated attenuation comparison
100
90
80
70
Lambert-Beers law
Transmission (%)
60
50
40
30
"two-flux model"
20
10
0
0 50 100 150 200 250 300 350 400 450 500
Distance from radiation source (cm)
Figure 13 Simulation results for water mist attenuation of a black-body radiation source (1923ºC). The
amount of water is 5% by weight and the droplet diameter 15 µm.10
Figure 14 demonstrates simulated irradiation attenuation for different droplet sizes. Gas phase
absorption has been neglected. Values are obtained from Yang et. al10.
Simulated attenuation as a function of droplet size and amount of water
100
90
80
70
500 µm
Transmission (%)
60
50
100 µm
40
30
20
10 µm
10
0
0 1 2 3 4 5 6 7 8 9 10
Amount of water (weight%)
Figure 14 Simulated attenuation 3 meters away from a 1000°C black-body radiation source10
14
Proc. IWMA conference 2004, 6-8 October 2004, Rome, Italy
1.8 Conclusion
• Heat transfer during deceleration of high-speed droplets can be ignored.
• Modelling of water mist systems can be divided into two, deceleration can be treated
separately from evaporation of the droplet.
• Fast water droplets quickly loose their momentum to the surrounding air
• The water concentration to reduce radiation from a fire is about 30-40 g/m3, whereas
the concentration required to extinguish the fire is 5 times higher, about 180 g/m3. I.e.
it requires much less water to prevent flame spread than to extinguish a fire.
• Small droplets will evaporate very fast and the main radiation absorption will take
place in the gas phase of water rather than the liquid phase
1.9 Acknowledgement
Contribution from the Swedish Fire Research Board (BRANDFORSK) is gratefully
acknowledged.
1
Hertzberg T., Hahne A., Josefsson C., Holmstedt G., Husted B., Vattendimma: Teori, fysik och simulering.
BRANDFORSK projekt 514-021, SP Rapport 2004:15, Brandteknik, Borås 2004, Sweden.
2
Schneider B. M., Experimentelle Untersuchungen zur Spraystruktur in transienten, verdampfenden und nicht
verdampfenden Brennstoffstrahlen unter Hochdruck., Phd. thesis, Diss. ETH Nr. 15004, ETH, Zürich 2003
3
Gardiner, A.J. The mathematical modelling of the interaction between sprinkler sprays and the thermally
buoyant layers of gases in fires. England 1988.
4
Rasbash. Lecture notes, University of Edinburgh
5
Ewing, C.T., Hughes, JT and Carhart HW, The extinction of hydrocarbon flames based on the heat-absorption
process which occur in them, Fire and Materials, 8, pp. 148-156, 1984
6
Ewing, C.T., Faith, F.R, Hughes, JT and Carhart HW, Evidence for flame extinguishment by thermal
mechanism, Fire Technology, 25, pp 195-212, 1989
7
Beyler C, A unified model of fire suppression, Journal of Fire Protection Eng. vol 4, no 1 pp 5-16, 1992
8
S. Särdqvist and G. Holmstedt, Water for manual Fire Suppression, J. of Fire Protection Eng. 11, 209-231
(2001)
9
P. Andersson and G. Holmstedt, Limitations of Water Mist as a Total Flooding Agent, J. of Fire Protection
Eng., 9(4) 1999, pp 31-50
10
Yang W., Parker T., Ladouceur H.D., Kee J.K., The interaction of thermal radiation and water mist in fire
suppression, Fire Safety Journal, 39, 41-66, 2004
15