1.

1 Standarisasi
No Volume NaOH Volume Asam Oksalat Indikator PP Warna
1 0.7 mL 5 mL 3 tetes Merah muda
2 0.8 mL 5 mL 3 tetes Merah muda
1.2 Kelarutan
No Suhu NaOH Perubahan Warna
1 50oC V1 = 5.7 mL Bening Merah
V2 =5.8 mL muda
2 40 oC V1 = 6.9 mL Bening Merah
V2 5.9 mL muda
3 30 oC V1 = 4.8 mL Bening Merah
V2 = 5.1 mL muda
PERHITUNGAN

1. Pembuatan Larutan NaOH 0.2 M

𝑁 0.2 𝑁
𝑀= = = 0.2 𝑀
𝑒𝑘 1
𝑚 1000
𝑀= ×
𝑀𝑟 𝑉
𝑚 1000
0.2 𝑀 = 𝑔 × 100 𝑚𝐿
40
𝑚𝑜𝑙
𝑚 = 0.8 𝑔𝑟𝑎𝑚

2. Pembuatan Larutan H2C2O4 0.02N

𝑁 0.025 𝑁
𝑀= = = 0.0125 𝑀
𝑒𝑘 2
𝑚 1000
𝑀= ×
𝑀𝑟 𝑉
𝑚 1000
0.0125 𝑀 = 𝑔 × 100 𝑚𝑙
126
𝑚𝑜𝑙
𝑚 = 0.157 𝑔𝑟𝑎𝑚

3. Standarisasi NaOH
Dik : V H2C2O4 = 5 mL
M H2C2O4 = 0.0125 M
𝑉1 + 𝑉2 0.7+0.8
𝑉 𝑁𝑎𝑂𝐻 = 2
= 2
= 0.75 𝑚𝐿
Dit : M NaOH =........?
Jawab :
Rx : 2 NaOH + H2C2O4 Na2C2O4 + 2H2O
N NaOH = ½ n H2C2O4
(M x V) NaOH = ½ n H2C2O4
M x 0.75 mL = ½ (0.0125 M x 5 mL)
M x 0.75 mL = 0.03125
0.03125 𝑚𝑚𝑜𝑙
M =
0.75 𝑚𝐿
M = 0.0416 M

4. Kelarutan sebagai Fungsi Suhu

Dik : V H2C2O4 = 5 mL
M NaOH = 0.0416 M
Dit : mol H2C2O4 =........?
Jawab :
Rx : 2 NaOH + H2C2O4 Na2C2O4 + 2H2O
a) T= 50oC
𝑉1 + 𝑉𝑧 5.7 + 5.8
𝑉 𝑁𝑎𝑂𝐻 𝑡𝑖𝑡𝑟𝑎𝑠𝑖 = = = 5.75
2 2
Berdasarkan Rx, maka :
n H2C2O4 = 2 n NaOH
 n H2C2O4 = 2 ( M x V) NaOH
n H2C2O4 = 2 (0.0416 x 5.75) NaOH
n H2C2O4 = 0.4784 mmol
b) T = 40oC

𝑉1 + 𝑉𝑧 6.9 + 5.9
𝑉 𝑁𝑎𝑂𝐻 𝑡𝑖𝑡𝑟𝑎𝑠𝑖 = = = 6.4 𝑚𝐿
2 2
Berdasarkan Rx, maka :
n H2C2O4 = 2 n NaOH
n H2C2O4 = 2 ( M x V) NaOH
n H2C2O4 = 2 (0.0416 x 6.4) NaOH
n H2C2O4 = 0.53248 mmol
c) T =30 oC
𝑉1 + 𝑉𝑧 4.8 + 5.1
𝑉 𝑁𝑎𝑂𝐻 𝑡𝑖𝑡𝑟𝑎𝑠𝑖 = = = 4.95 𝑚𝐿
2 2
Berdasarkan Rx, maka :
n H2C2O4 = 2 n NaOH
n H2C2O4 = 2 ( M x V) NaOH
n H2C2O4 = 2 (0.0416 x 4.95) NaOH
n H2C2O4 = 0.41184 mmol

Tabel Berdasarkan Data :

T(K) 1/T (K) mmol Log mmol
323 0.0030 0.4784 -0.3202
313 0.0032 0.53248 -0.2737
303 0.0033 0.41184 -0.3853

Grafik 1/T Vs Log mmol :

1/T vs Log mmol

0
0.00295 0.003 0.00305 0.0031 0.00315 0.0032 0.00325 0.0033 0.00335
-0.05
-0.1
-0.15
Log mmol

-0.2 y = -152.79x + 0.1574

R² = 0.1733
-0.25
-0.3
-0.35
-0.4
-0.45
1/T
∆ 𝐻𝑝𝑠 = 𝑚 × 2.303 × 𝑅

= −152.79 × 2.303 × 8.314 𝐽𝑚𝑜𝑙 −1 𝐾 −1

= −2925.5 𝐽𝑚𝑜𝑙 −1 𝐾 −1

= −2.9255 𝐾𝐽𝑚𝑜𝑙 −1 𝐾 −1