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Roll number
PP
Name

Instructions to candidate
 Read through the entire paper before you start writing
 Fill in your name, date and role number in appropriate Column
 Answer all questions on OMR seat
 Handle each question with managing time
 Use only black or blue ballpoint pen don’t use pencil
 Choose correct answer

Each Correct answer contains +4 marks

Each Incorrect answer contains -1 marks
More than one option marked -1 marks
Question left unanswered 0 marks
Ambition Academy Question paper composed by Dr. Ashok Choudhary

Questions Paper chemistry

1. If NaCl is doped with 10 - 4 mol of SrCl2, the number of cation vacancy will be
(NA = 6.02 X 1023)
(A) 6.02 X 1018
(B) 6.02 X 1019
(C) 6.02 X 1020
(D) 6.02 X 1021
2. The fraction of total volume occupied by the atom present in a simple cube is
𝜋 𝜋 𝜋 𝜋
(A) (B) (C) 4 (D) 6
3√2 4√2

3. Which of the following FCC structure contains cation in alternate tetrahedral voids
(A) NaCl (B) ZnS (C) Na2O (D) CaF2

4. The ratio of Fe+2 and Fe+3 ions in Fe0.9S1.0 is

(A) 0.28 (B) 2.5 (C) 2.0 (D) 3.5
5. Silicon doped with arsenic is an example of which type of semiconductor
(A) Intrinsic (B) p type (C) n type (D) p, n type
6. In a compound, atoms of element Y form CCP lattice and those of elements X occupy (2/3) rd of
tetrahedral voids. The formula of compound will be
(A) X3Y4 (B) X4Y3 (C) X2Y3 (D) X2Y
7. The closet packing sequence ABAB…represents
(A) SC (B) BCC (C) FCC (D) HCP
8. Which of the following statement is not true about NaCl structure
(A) Each unit cell contains 4 NaCl molecule
(B) CN of Cl ion is 6
(C) CN of Na ion is 4
(D) Cl ions are in FCC arrangement
Space for rough work…
9. Which of the following statement about amorphous solids is incorrect?
(A) They melt over a range of temperature
(B) They are anisotropic
(C) There is no orderly arrangement of particles
(D) They are rigid and incompressible
10. In a solid ‘AB’ having the NaCl structure, “A” atom occupy the corner of the cubic unit cell. If the
face centered atom along one of the axis are removed then the resultant Stoichiometry of the solid is
(A) A5B (B) AB5 (C) A4B3 (D) A3B4
11. Due to Frenkel defect, density of ionic solid
(A) Decreases (B) Increases (C) Does not change (D) None
12. Iron crystallizes in BCC system with a lattice parameter of 2.861A o. calculate the density of iron in
the BCC system (atomic weight of Fe is 56)
(A) 7.92 gm/cc (B) 8.96 gm/cc (C) 2.78 gm/cc (D) 6.72 gm/cc
13. In Stoichiometric defect, the type of compound exhibit Frenkel defect have/ has
(A) Low coordination
(B) High coordination
(C) Small difference in size of cation and anion
(D) None of these
14. On cooling oxygen freezes to dark blue crystalline solid. It is belongs to which of following type of
solid
(A) Covalent solid
(B) Ionic solid
(C) Molecular solid
(D) Metallic solid
15. Coordination number of Zn in ZnS is
(A) 4 (B) 6 (C) 2 (D) None of these
16. A substance AxBy has FCC lattice in which atoms ‘A’ occupy corners and ‘B’ atoms occupy face
centers. Identify the correct composition of substance A xBy
(A) A3B (B) AB3 (C) A4B3 (D) None of these
17. Frenkel and Schottky defect are
(A) Nucleus defect
(B) Non crystal defect
(C) Crystal defect
(D) Nuclear defect
Space for rough work…
18. The crystal system of a compound with unit cell dimensions a= 0.87, b = 0.87, c = 0.504nm and  =
= 900 and  = 1200 is..
(A) Hexagonal
(B) Cubic
(C) Rhombohedral
(D) Orthorhombic
19. If Z is number of atoms per unit cell that represent the closest packing sequence ABCABCA..the
number of tetrahedral void in the unit cell is equal to
(A) 4 (B) 6 (C) 8 (D) 12
20. Zn converts its melted state to its solid state. It has HCP structure then find out nearest neighbor of
Zn atom
(A) 4 (B) 6 (C) 8 (D) 12
21. The Ca+2 and F- are located in CaF2 crystal respectively at face centered cubic lattice points and in..
(A) T.V (B) Half of TV (C) OV (D) Half of OV
22. Schottky defect in crystal is observed when…
(A) Equal number of cation and anion are missing from lattice
(B) Density of crystal is increased
(C) An anion leaves its normal site and occupy interstitial site
(D) Unequal number of cation and anion are missing from crystal
23. Which of the following is a molecular solid
(A) Dry ice
(B) Quartz
(C) Rock salt
(D) Diamond
24. Sodium chloride, NaCl usually crystallizes in a face centered cubic lattice. How many ions are in
contact with any single Na+ ion
(A) 1
(B) 4
(C) 6
(D) 8
25. Percentage of free space in cubic close packed structure and in body centered packed structure
respectively
(A) 74% and 68%
(B) 30% and 48 %
(C) 26% and 32%
(D) 32% and 26%
Space for rough work…
26. Copper crystallize in FCC with a unit cell length of 361pm. What is the radius of copper atom
(A) 157pm
(B) 128pm
(C) 108pm
(D) 181pm
27. An ionic compound is expected to have tetrahedral structure if r +/r- lies in the range of
(A) 0.414 to 0.732
(B) 0.732 to 1
(C) 0.155 to 0.225
(D) 0.225 to 0.414
28. in which of the following crystal alternate tetrahedral voids are occupied
(A) NaCl
(B) ZnS
(C) Na2O
(D) CaF2
29. Density of a crystal remain unchanged as a result of
(A) Vacancy defect
(B) Interstitial defect
(C) Schottky defect
(D) Frankel defect
30. The appearance of colour in solid alkali metal halide is generally due to
(A) Schottky defect
(B) Frankel defect
(C) Interstitial position
(D) F center
31. What is the coordination number of sodium in Na2 O
(A) 8
(B) 6
(C) 4
(D) 2
32. Which is not a correct statement for ionic solid in which positive and negative ions are held by
strong electrostatic attractive forces?
(A) The radius ratio increase as coordination number increases
(B) As the difference in size of ion increases coordination number increases
(C) When coordination number is eight, the radius ratio lies between 0.225 to 0.414
(D) In ionic solid of the type AB (ZnS) the coordination number of Zn+2 and S-2 respectively are 4
and 4
Space for rough work…
33. Which one of the following compound exhibit both Frankel and Schottky defect
(A) AgCl
(B) AgBr
(C) AgI
(D) All of these
34. A compound formed by element A and B crystallize in cubic structure where A atoms are at corner
of the cube and B atoms are at face centers. The formula of compound is
(A) AB3
(B) AB
(C) A3B
(D) A2B
35. A p type material is electrically
(A) Positive
(B) Negative
(C) Neutral
(D) Depend upon the concentration of p impurities
36. A unit cell of NaCl has four formula units. The edge length of unit cell is 0.564nm. what is the
density of NaCl (in gm/cc)
(A) 1.2
(B) 2.16
(C) 3.64
(D) 4.56
37. AB in an ionic solid. If the ratio of ionic radii of A+ and B- is 0.52. What is the coordination number
of B-?
(A) 6
(B) 3
(C) 2
(D) 8
38. For a crystal, the angle of diffraction (2) is 900 and the second order line has a d value of 2.28 Å.
The wave length (𝑖𝑛 Å) of x-ray used for Bragg’s diffraction is
(A) 2.28
(B) 2
(C) 1.613
(D) 4
Space for rough work…
39. If AgI crystallize in zinc blade (ZnS) structure with I - ions at lattice point, what fraction of
tetrahedral void is occupied by silver ions
(A) 100%
(B) 75%
(C) 50%
(D) 25%
40. If the distance between Na+ & Cl- in NaCl crystal is X pm. The length of edge of the unit cell is
(A) 4X pm
(B) 2X pm
(C) X/2 pm
(D) X/4 pm
41. In a face centered arrangement the number of atoms per unit cell is
(A) 1
(B) 2
(C) 6
(D) 4
42. In an antifluorite structure , cation occupy
(A) Center of cube
(B) Tetrahedral void
(C) Octahedral void
(D) Corner of cube
43. The coordination number of metal crystallize in hexagonal closed packed structure is
(A) 2
(B) 4
(C) 6
(D) 8
44. Total number of O.V in 0.5 mol of compound having HCP structure are
(A) 6.022 X1023
(B) 12.044 X1023
(C) 18.066 X1023
(D) 4.516 X1023
45. The number of carbon atoms per unit cell of diamond unit cell is
(A) 8
(B) 6
(C) 4
(D) 2
Space for rough work…
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