CHEMICAL THERMODYNAMICS MOCK TEST –I

(QUESTIONS BY PRITAM MANDAL)

FULL MARKS:40 TIME: 1hr 20 min

1) Density is an extensive property of any system---comment on it . 1

2) What is adiabatic process .Derive the expression for adiabatic reversible work done
of an ideal gas . 1+2=3
3) Derive the expressions for the variation of enthalpy of reaction with temperature. 3
4) What is enthalpy of any system? What does it actually physically signifies? 1+2=3
5) Derive the expression for an one mole of an ideal gas : 𝐶𝑝 -𝐶𝑣 =R . 3
6) Mathematically show that dq is a path function. 3
7) U remains constant in every isothermal reversible process in a closed system—prove
it applying thermodynamic 1st law . 2
8) Prove that isothermal reversible work done is greater than irreversible work done. 2
9) Derive the expression for isothermal reversible work done for n mole of an Vander
waal gas expansion . 3

10) Deduce the relationship between ΔH and ΔU . 2

11) Show that adiabatic P-V curve is more steeper than isothermal P-V curve. 2

12) What is the difference between closed and isolated system. 1

13) Work done in a reversible isothermal gas expansion is the maximum work done---
justify it with appropriate explanation . 2

14) 2 moles of Nitrogen gas at STP is compressed reversibly to 10 litres. Calculate the
work done by the system if (a) the work is carried out in isothermally and (b) adiabatically .
3

15) Write down the expression for thermodynamic 1st law . 1

16) What are the definations of isochoric and isoberic process . 2

17) Derive the various expressions of Joules experiment on the basis of ideal gas. 3

PRITAM MANDAL .

(ASST. TEACHER OF BENIPUR F.P.S)