RANK BOOSTER TEST SERIES

12th and 13th STUDENTS

[CHEMISTRY (1)]
TARGET IIT - JEE - 2016
Date :– 06– 04 - 2016 Duration : 1 Hours Max. Marks : 60

PAPER - 1
_________________________________________________________________________________________
INSTRUCTIONS
In each part of the paper, Section-A contains 8 questions, Section - B contains 10 questions & Section-C contains
2 questions. Total number of pages are 11. Please ensure that the Questions paper you have received contains ALL
THE QUESTIONS in each section and PAGES.
SECTION - A
Q.1 to Q.8 are Integer answer type questions (whose answer is 1 digits [0 to 9]) & carry 4 marks each. No Negative
Marking.

SECTION - B
Q.1 to Q.10 are Multiple choice Questions has four choices (A), (B), (C), (D) out of which one or more than one is/are
correct & carry 4 marks each. 2 mark will be deducted for each wrong answer.

SECTION - C
Q.1 & Q. 2 are "Match the Column" Type questions and you will have to match entries in column - I with the entries in
Column - II. One or More entries in Column - I may match with one or more entries of Column - II. For each entry in
Column - I, + 2 for correct answer, 0 if not attempted and – 1 in all other cases.

NOTE : GENERAL INSTRUCTION FOR FILLING THE OMR ARE GIVEN BELOW.
1. Use only blue/black pen (avoid gel pen) for darkening the bubble.

2. Indicate the correct answer for each question by filling appropriate bubble in your OMR answer sheet.

3. The Answer sheet will be checked through computer hence, the answer of the question must be marked by shading the
circles against the question by blue/black pen.

4. While filling the bubbles please be careful about SECTIONS [i.e. Section-A (include Integer type), Section - B [Multiple type]
& Section-C (Comprehension type)].

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 RANK BOOSTER TEST SERIES_CHEMISTRY_1 Page # 2

CHEMISTRY [PAPER - 1]
SECTION - A SECTION - A
[INTEGER ANSWER TYPE] [ fo' y s
"k. kkRed i z'u i zd kj ]
Q.1 to Q.8 are INTEGER ANSWER TYPE Questions. i z-1 l si z-8 r d fo' y s"k.kkRed i z'u gS
A¼i zR; sd i z'u dkmÙkj dsoy
(The answer of each of the questions is 1 digits)
d ksesnhft
1 va ; sA
1. Howmany total enol forms are possible in 1. fuEufy f[ kr py ko; ohdj .kesadq
y fdr usbZ
ukW
y : i l EHko
following tautomerisation
gSA
O
OH/HOH Enol forms O
OH/HOH bZ
ukW
y :i

2. Calculate the total no. of groups which show

+ M effect when group is bonded to benzene 2. t c l ewg cSt hu oy ; l st q
M+kgks]r c dq
y l eq
gksadhl a
[;k
ring. cr kvksat ksfd + M i zHkko n' kkZ
r sgS
A
O O
–NO, –CH=CH –NH2, –OH, –O– C –CH3, –NO, –CH=CH –NH2, –OH, –O– C –CH3,

O O
– C –CH3, –CHO, –NH– C –CH3, –NO2 – C –CH3, –CHO, –NH– C –CH3, –NO2
O O

3. Total no. of amides of molecular formula 3. C4H9NO dsfy , dq

y , ekbM cr kvksat ksva
r j vkf.od
C 4 H 9 N O are pos s i bl e w hi c h form H-ca
/kcukr sgS
A
intermolecular H-bond with it self
4. fuEu esal sfdr us; kS
fxd , sjksesfVd gS
A
4. How many total compounds are aromatic
among given compounds.
B
B

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5. Calculate the DBE in Benzoic acid 5. cst ksbZ

d vEy esaf} ca
/kr q
Y; ka
d dhx.kukdj ksA

6. How many compounds can release CO2 with 6. fuEu esal sfdr us; kS
fxd NaHCO3 l sfØ; kdj dsCO2 nsrs
NaHCO3 among the following compounds. gSA
O OH O OH
C OH OH
C

(benzoic acid) (Phenol) (cs

Ut ksbd vEy ) (fQukW
y)
OH OH
SO3H NO2 NO2 SO3H NO2 NO2

NO2 NO2
 benzene   csUt hu 
  (Picric acid)
sulphonic acid   (fi dfj d vEy )
   l YQksfud vEy 

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 RANK BOOSTER TEST SERIES_CHEMISTRY_1 Page # 4

O
OH O
O–C–CH3 OH
O O–C–CH3
O
C – OH
C – OH
NO2
NO2
Aspirin
 Acetyl  (p-ukbVªks
fQukW
y) , sfLi zu(, sfl fVy l sfy fl fy d vEy )
(p-nitro phenol)  
 salicy lic acid  O
CH3 – OH
O CH 3 – C – OH
CH3 – OH (, s
FksukW
bd vEy ) (es
FksukW
y)
CH 3 – C – OH
(Ethanoic acid) (methanol)
OH
OH
O
O
CH 3 – S – OH
CH 3 – S – OH
OCH3 O
OCH3 O

 p  methoxy   methane  (p-es

FkksDl hfQukW
y) (es
Fksu l YQksfud vEy )
   
 phenol   sulphonic acid OH
OH

 p  hydroxy benzene  (p-gkbMªks

Dl hcsUt hu l YQksfud vEy )
 
 sulphonic acid  SO3H
SO3H

7. The no. of carbons linearly arranged in the

compound CH3 – C  C – C  C – CH3 is : 7. ; kS
fxd CH3 – C  C – C  C – CH3 esaj s[kh; foU;kl hr
dkcZ uksadhl a
[ ; kgS
A

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8. Find out the total molecules in which lone 8. dq y v.kq v ksadhl a

[ ; k Kkr dhft , ft uesafd ukbVªkst u
p ai r of ni t roge n at om p arti ci pate i n i j ek.kqdk , dkdh; q Xe vuq ukn esaHkkx y srk gS
%
resonance.

(I) (II) N
(I) (II) N
N
N H
H
H3C CH3
H3C CH3
N
N
(III) N (IV)
(III) N (IV)
O
O

NH O CH N
NH O CH N NH
NH (V) (VI) (VII)
(V) (VI) (VII) CH
CH

(VIII) CH2=CH–C  N
(VIII) CH2=CH–C  N

SECTION - B SECTION - B
[MULTIPLE OBJECTIVE TYPE] [ cgqoS
d fYi d i z'u i zd kj ]
Q.1 to Q.10 has four choices (A), (B), (C), (D) out
of which ONE OR MORE THAN ONE is correct i z-1 l si z-10 esapkj fodYi (A), (B), (C), (D) gS
] ft uessal s^^, d
; k, d l svf/kd^^ l ghgS
A
1. Which of the following pairs of compounds is 1. fuEufy f[ kr esl s; kS
fxdksdkdkS
ul k; q
Xe i zfr fcEc: i hdk
a pair of enantiomers? ;qXe gS?

H H H H
(A) (A)
Cl Cl Cl Cl

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 RANK BOOSTER TEST SERIES_CHEMISTRY_1 Page # 6

(B) (B)

(C) (C)

Cl Cl Cl Cl

(D) (D)
Cl Cl Cl Cl Cl Cl Cl Cl
2. Which of the following pair is the pair of
Diastereomers: 2. fuEufy f[ kr esl sfoofj e l eko; oh; ksdk; q
Xe dkS
ul kgS?
CO2H CO2H CO2H
CO2H
H OH H OH
H OH H OH
(A) (A)
H OH HO H H OH
HO H
CO2H CO2 H
CO2H CO2H
H CH3 H CH3
CH3 CH3
H H
H3C C Br C H H3C C Br C H
(B) C C Br C C (B) C C Br C C

CH3 H H CH3
H H H H
CH3 Et CH3 Et
H OH HO H H OH HO H
(C) (C)
H SH HS H H SH HS H

Et CH3 Et CH3
Cl Cl Cl Cl
Cl Cl Cl Cl
(D) (D)
Cl Cl Cl Cl

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3. Correct order of rate of reaction is : 3. vfHkfØ; kdhnj dkØe gS&

OH OH
NO2 NO2 NO2 NO2

(i) + Na r1  Product (i) + Na  r1  mR

i kn
NO2 NO2

COOH r2 COOH
(ii) + Na Product (ii) + Na r2 mRikn
(iii) CH3 – C  CH + Na r3 Product (iii) CH3 – C  CH + Na r3 mRikn

(iv)Et–OH + Na r4 Product (iv)Et–OH + Na r4 mRikn

(A) r2 > r1 > r4 > r3 (B) r1 > r2 > r4 > r3
(A) r2 > r1 > r4 > r3 (B) r1 > r2 > r4 > r3 (C) r2 > r1 > r4 > r3 (D) r1 > r2 > r4 > r3
(C) r2 > r1 > r4 > r3 (D) r1 > r2 > r4 > r3
4. +M l ew
g dksi gpkfu, &
4. Identify the + M groups
O
O
(A) – NH – C – CH3 (B)
(A) – NH – C – CH3 (B) N
N

(C) – C – O – CH3 (D) – O – Et

(C) – C – O – CH3 (D) – O – Et
O
O
5. fuEu ; kS
fxd dsvEy h; l keF; Zdhr q
y ukdj ks
5. Compare acidic strength of the following
O O O O
compound.

O O O O (P) O (Q)
O
(P) O (Q)
O

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 RANK BOOSTER TEST SERIES_CHEMISTRY_1 Page # 8

O O
O O
(R) (R)
O O

(A) P > Q > R (B) Q > P > R (A) P > Q > R (B) Q > P > R
(C) R > P > Q (D) R > P > Q (C) R > P > Q (D) R > P > Q

6. In which of the following compound(s) reso- 6. fuEu esal sfdl ; kS

fxd esavuq
ukn gS
a
nance is present. H
H
N
N H B B H
H B B H
(A) (B) H N N H
(A) (B) H N N H B
B
H
H
O
O
(C) (D)
(C) (D)

7. dkS
ul k; q
Xe , d l eku ; kS
fxd dksughn' kkZ
r kgS
A
7. Which of the pair of compounds are differ-
ent. CH3 CH3
CH3 CH3 CH3 CH3
(A) &
CH3 CH3
(A) &
D D H
H
D D H (B) &
H
(B) &

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O O O O
CH 3 CH 3 CH 3 CH 3
(C) & (C) &
CH 3 CH 3 CH 3 CH 3

CH3 CH3
CH3 CH 3 CH3 CH 3
(D) & (D) &
CH3 CH3

8. Which of the following compound(s) has 2R,3S 8. fuEufy f[ kr esal sdkS

ul k@dkS
ul s; kS
fxd@; kS
fxdksdkfoU; kl
configuration ? 2R,3S gS\

Cl Cl
Cl O HO Cl
H O HO H
C–H C–H
(A) CH 3 (B) CH H (A) CH 3 (B) CH
3
3
H
C C
OH O H OH O H

O CH3
O H O CH3
C H C–H O H
C H C–H
HO H
HO H
(C) Cl H (D) (C) (D)
Cl H
Cl
CH 3 H Cl
OH CH 3 H
OH

9. Intramolecular hydrogen bonds occur in :

9. vUr %v.kq d gkbMªkst u ca/kfdl esami fLFkr gS
?
(A) 2-chlorophenol
(B) salicylic acid (A) 2-Dy ks j ksfQukW
y (B) l s
fy fl fyd vEy
(C) the enol form of acetylacetone (C) , fl fVy , l hVks u dkbuksy : i
(D) paranitrophenol (D) i s
j kukbVªksfQukW
y

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 RANK BOOSTER TEST SERIES_CHEMISTRY_1 Page # 10

10. For the compound : 10. fuEu ; kS fxd dsfy , l ghva

fdr fdj sy dkcZ
u dsUnzdk
The absolute configuration of the correct
fuj i s{kfoU; kl gS
&
numbered chiral carbon centre are
OCH3 OCH3
H H
Et Et
O O

H H

OH OH
(A) 2S, 3S, 5S (B) 2S, 3R, 5R
(A) 2S, 3S, 5S (B) 2S, 3R, 5R
(C) 2R, 3S, 5S (D) 2R, 3R, 5R
(C) 2R, 3S, 5S (D) 2R, 3R, 5R

SECTION - C SECTION - C
[MATCH THE COLUMN TYPE]
[l q
esy u l q
phi zd kj ]
Match the entries in Column - I with the entries in
Column- II. One or more entries in Column - I may Lr EHk- I dhi zfo"Vh; ksdkLr EHk - II dhi zfo"Vh; ksadsl kFkl q
esy u
match with one or more entries in Column - II. dhft ; sALr EHk- I es, d ; k, d l svf/kd i zfo"Vh; kaLr EHk- II ds
1. Match the following
, d ; kvf/kd i zfo"Vh; ksadsl kFkl q
esfy r gksl dr hgSA
Column-I 1. fuEu dksl w
esfy r dhft , &
Lr EHk-I
(A) CH3 – CH – CH3
(A) CH3 – CH – CH3
(B) CH 3
(B) CH 3
(C) CH3 – CH – CH3 (C) CH3 – CH – CH3
(D) , dy dkchZ u
(D) Singlet carbene
Column-II
Lr EHk-II
(P) Pyramidal structure (P) fi j kfefM; l a
j puk
(Q) Planar geometry (Q) l er y h; T; kfefr
(R) Electrophile (R) by s DVªkW
u Lusgh
(S) Nucleophile (S) ukfH kd Lusgh

(SPACE FOR ROUGH WORK)

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Page # 11 RANK BOOSTER TEST SERIES_CHEMISTRY_1

2. Match the following 2. fuEu dksl wesfy r dhft , &

Column-I (Compounds) Lr EHk-I (; kS
fxd )

(A) (A)
N N

(B) (B)
N N

N N
(C) (C)

(D) N N
(D)
H H
Column-II (PKb values) Lr EHk-II(PKb eku)
(P) 13.60 (P) 13.60
(Q) 6.21 (Q) 6.21
(R) 3.35 (R) 3.35
(S) 8.8 (S) 8.8

(SPACE FOR ROUGH WORK)

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