TM

JEE ADVANCED TEST SERIES

ADVANCED PATTERN TEST [FORMAT - 1]

FULL TEST - 2 [ PAPER - 1 ]

Date : 22 - 08 - 2021 Duration: 3 Hours Max. Marks : 264
_______________________________________________________________________________________________
INSTRUCTIONS
In each part of the paper, Section-A contains 8 questions, Section - B contains 10 questions & Section-C
contains 2 questions. Total number of pages are 28. Please ensure that the Questions paper you have
received contains ALL THE QUESTIONS in each section and PAGES.
SECTION - A
Q.1 to Q.8 are Integer answer type questions (whose answer is 1 digits [0 to 9]) & carry 4 marks
each. No Negative Marking.
SECTION - B
Q.1 to Q.10 are Multiple choice Questions has four choices (A), (B), (C), (D) out of which one or more
than one is/are correct & carry 4 marks each. 2 mark will be deducted for each wrong answer.
SECTION - C

Q.1 & Q. 2 are "Match the Column" Type questions and you will have to match entries in column - I with
the entries in Column - II. One or More entries in Column - I may match with one or more entries of
Column - II. For each entry in Column - I, + 2 for correct answer, 0 if not attempted and – 1 in all other
cases.

NOTE : GENERAL INSTRUCTION FOR FILLING THE OMR ARE GIVEN BELOW.

1. Use only blue/black pen (avoid gel pen) for darkening the bubble.

2. Indicate the correct answer for each question by filling appropriate bubble in your OMR answer sheet.

3. The Answer sheet will be checked through computer hence, the answer of the question must be marked by
shading the circles against the question by blue/black pen.

4. While filling the bubbles please be careful about SECTIONS [i.e. Section-A (include Integer type), Section
- B [Multiple type] & Section-C (Comprehension type)].

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 (ADVANCED PATTERN) | Page # 2

PART - I [MATHEMATICS]
SECTION - A SECTION - A
[INTEGER ANSWER TYPE] [ fo' y s
"k. kkRed i z'u i zd kj ]
Q.1 to Q.8 are INTEGER ANSWER TYPE Questions. i z-1 l si z-8 r d fo' y s"k.kkRed i z'u gS
A¼i zR; sd i z'u dkmÙkj dsoy
(The answer of each of the questions is 1 digits) d ksesnhft
1 va ; sA
1. Number of 12 roots of unity which are also
th
1. bdkbZds12th ew
y ksadhl a
[ ; k] t ksbdkbZds18th ew
y Hkh
the 18th roots of unity, is
gS
] gksxh
a
2. Let ai , i = 1, 2, 3, ......, n denote the integers 2. ekuk ai , i = 1, 2, 3, ......, n Qy u
i n the domai n of funct i on f (x )
 4 x  25 
 4 x  25  f(x) = log 1   dsi z
kUr ea
si w
. kkZ
a
d ksdksn' kkZ
rk
= log 1   2
 x  21 
 x  21 
2
gS
] t gk¡ai < ai+1  i  N gS
A ; fn j s[kk
where ai < ai+1  i  N. If the line L :
2 x  a1 y  a1 z  a3
2 x  a1 y  a1 z  a3 L: = = , xy, yz r Fkkzx
= = meets the xy, yz 4 a2 a5
4 a2 a5 l er y ksal sØe' k%A, B r FkkC i j fey r h gSr Fkk ; fn
and zx planes at A, B and C respectively , pr q
"Qy d OABD dkvk; r u V gS ] t gk¡'O' ew
y fcUnqgS
and if volume of the tetrahedron OABD is V,
where 'O' is origin and D is the image of C in 9
r FkkD, x- v{kesaC dki zfr fcEc gS
]rc V dkeku Kkr
9 7
the x-axis, then find the value of V.
7 dhft , A
ln x
3. If Rolle's theorem is applicable to the func- 3. ; fn va r j ky [a,b] esaQy u f  x    x  0 i j
x
tion f  x  
ln x
 x  0  over the interval j ksy i zes; l R;kfi r gksrhgS
] t gk¡a,bN gS
] r c (a + b)
x dkeku gS &
[a,b] where a,b  N then the value of (a+
b) is
(SPACE FOR ROUGH WORK)

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cM+k lkspks vkSj gkjus ls er MjksA

 (ADVANCED PATTERN) | Page # 3

4. A quadratic equation with roots  and  4. , d f} ?kkr l ehdj .k¼

ft l dsew
y  r Fkk  gS
] t gk¡ =
where  = 4, satisfies the equation
  a2 – 7
  a2 – 7 4 gS
½t ksl ehdj .k   2 dksl a
rq
"V
  2 Number of integral val-  –1  –1 a – 4
 –1  –1 a – 4 dj r hgS
A'a' dsi w . kkZ
a
d h; ekuksadhl a
[ ; k] ft l dsfy , ,
ues of 'a' for which ,   (1,4) is equal to
  (1,4) gS] gksxhA
5. Let p(x) = x5+x2+1 have roots x1,x2,x3,x4 5. ekukp(x) = x5+x2+1 dsew y x1,x2,x3,x4 r Fkkx5
and x5, g(x) = x2–2, then the value of g(x1) gS
,g(x) = x –2 gS
2
] r c g(x1) g(x2) g(x3) g(x4)
g(x2) g(x3) g(x4) g(x5)–30g (x1x2x3x4 x5)
g(x5)–30g (x1x2x3x4 x5) eku gS&
is……

6. Two sides of a triangle are in the ration 3:5 6. , d f=kHkq

t dhnksHkqt k, ¡3:5 vuq
i kr esagSr Fkkr hl j h
and the third side is 16. If  is the largest Hkq
t k16 gS A; fn  f=kHkq
t dkvf/kdr e l aHkkfor {ks=kQy
 
possible area of the triangle, then = …… gS
] rc = ……
20 20

 sin 3/2
x  cos3/2 x  dx  2
 sin 3/2
x  cos3/2
x  7.  1/2

7.  1/2
dx  2  3 3
sin x cos x sin  x  a 
 sin
3
x cos3 x sin  x  a 
1 1 
 cos a  sin a cot x  cos a tan x  sin a  c  , gS
]
1 1  P Q 
 cos a  sin a cot x  cos a tan x  sin a  c  ,
P Q  r c P2 + Q2 =
then P + Q = 2 2

d  8x2  bx  c 
d  8x2  bx  c  8. L im    2m, gS
] rc
L im    2m, then
x  dx  4x  f 
8. x  dx
 4x  f 
1
1–x
1
1–x lim 2–2 =
lim 2–2 = x m
x m

(SPACE FOR ROUGH WORK)

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 (ADVANCED PATTERN) | Page # 4

SECTION - B SECTION - B
[MULTIPLE OBJECTIVE TYPE]
Q.1 to Q.10 has four choices (A), (B), (C), (D) [ cgqoS
d fYi d i z'u i zd kj ]
out of which ONE OR MORE THAN ONE is i z-1 l si z-10 esapkj fodYi
(A), (B), (C),(D) gS
] ft uessal s^^, d
correct ; k, d l svf/kd^^ l ghgS
A
1. The two conics x2 cos2 a + y2 cot2 a = 1 and 1. nks' kka
d o x2 cos2 a + y2 cot2 a = 1 r Fkkx2
x2 sec2 a - y2 cosec2 a = 1 sec2 a - y2 cosec2 a = 1
(A) have same focii (A) dhukfH
k; k¡l eku gksxh&
(B) have same length of the latus rectum (B) dsukfH
ky Ecksdhy a ckbZ; k¡l eku gksxh
(C) have same directrices (C) dhfu; r k, ¡l eku gksxh
(D) intersect orthogonally (D) y Ecor ~i z
fr PNsn dj sxsa
A

2. Let E and F be two independent events. 2. ekuk E r FkkF nksLor a

=k?kVuk, ¡gS
Abuesal sBhd , d ds
The probability that exactly one of them 11
11 ?kfVr gksusdhi zkf; dr k gSr Fkkbuesal sfdl hdsHkh
occurs is and the probability of none 25
25
2 2
of them occurring is . If P(T) denotes ?kfVr ughgksusdhi zkf; dr k gS
A; fn P(T) ?kVukT
25 25
the probability of occurrence of the event ds?kfVr gksusdhi zkf; dr kdksn' kkZ
r kgS
] rc &
T, then
4 3
4 3 (A) P E   ,P F  
(A) P E   ,P F   5 5
5 5
1 2 1 2
(B) P E   ,P F   (B) P E   ,P F  
5 5 5 5
2 1 2 1
(C) P E   ,P F   (C) P E   ,P F  
5 5 5 5
3 4 3 4
(D) P E   ,P F   (D) P E   ,P F  
5 5 5 5

(SPACE FOR ROUGH WORK)

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vius 'kfDr;ksa ij Hkjkslk djus okyk dHkh vlQy ugha gksrkA

 (ADVANCED PATTERN) | Page # 5

3. A circle of radius 2 has centre at (2, 0) and 3. f=kT; k 2 oky s, d oÙ̀kdkdsUnz(2, 0) r Fkk, d vU; oÙ̀k
another circle of radius 1 has centre at
ft l dhf=kT; k 1 gSdk dsUnz(5, 0) gS A , d j s[kk i zFke
(5, 0). A line is tangent to the two circles at
points in the first quadrant. The equation of pr qFkkZ
' kesfcUnq
v ksi j nksoÙ̀kksdksLi ' kZdj r hgS
ALi ' kZj s[kk
the tangent is dhl ehdj .kgksxh&
x y x y x y x y
(A)  1 (B)  1 (A)  1 (B)   1
8 2 2 9 8 8 2 2 9 8
x y x y
(C)   1 (D) x  3 y  9 (C)   1 (D) x  3 y  9
8 3 8 3
 
  1  1    1  1 
4. Sn = Lim    x   x 



4. Sn = Lim    x   x 



x  
x  
 4 n 2  4 n 2  1   4 n 2  4 n 2  1 
 

1/ n  1/ n 
 1   1    1   1  
x  .... x    x x  .... x    x
         
 4n 2  2    4 n 2  ( n  1)     4n 2  2    4 n 2  ( n  1)   
 

,nN and for  = 1, L = Lim n.Sn  and for ,nN rFkk  = 1 ds fy,, L = Lim n.Sn  RkFkk
n  n 

 = 2, M = Lim n.Sn  then the value of  = 2 ds fy,, M = Lim n.Sn 

n  n 
[L + M] is - gks, rks [L + M] dk eku Kkr dhft;sA
[Note : [y] denotes the greatest integer
[fVIi.kh : [y], y ds egÙke iw.kk±d Qyu dks fu:fir
function of y.]
djrk gSA]
1
(A) (B) 1 1
2 (A) (B) 1
2
3 3
(C) (D) 2 (C) (D) 2
2 2
(SPACE FOR ROUGH WORK)

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 (ADVANCED PATTERN) | Page # 6

5. Let f (x) be a real valued continuous function
satisfying f 3(x) – 5f 2(x) + 10 f (x) – 12  0
and f 2(x) – 7 f (x) + 12  0. A ray of light
coming along the curve y = f (x) from positive
direction of x-axis and strikes the inner
5. ekukf (x) , d okLr fod eku l ar r ~Qyu gSt ksf 3(x) –
5f 2 (x) + 10 f (x ) – 12  0 r Fkk
f (x) – 7 f (x) + 12  0 dksl a
2 rq"V dj r k gS
A, d
i zd k' k dh , d fdj .k x-v{k dh /kukRed fn' kk l soØ

surface of mirror y = 2 3x . If l is the length y = f (x) dsvuq

fn' kvkr hgSr Fkkni Z
. ky = 2 3x dh
of the reflected ray contained within the vkar fj d l r g l sVdj kr hgS
A; fn l, i j oy; y2 = 12x ds
parabola y2 = 12x then the value of 12 l is - var xZ r fufgr i j kofr Z
r fdj .k dhy EckbZgS ] r c 12 l dk
(A) 75 (B) 225 eku Kkr dhft , -
75 (A) 75 (B) 225
(C) (D) 25
4 75
(C) (D) 25
4
6. The sequence a 1 , a 2 , a 3 , .. ...... i s a 6. J`a[kyk a1, a2, a3, ........ ,d xq.kksÙkj Js.kh gSA
geometric sequence. J`a[kyk b1, b2, b3, ........ ,d xq.kksÙkj Js.kh gSA
The sequence b 1 , b 2 , b 3 , ...... .. i s a
4
geometric sequence. b1 = 1; b2 = 7  4 28 + 1;
b1 = 1; b2 = 4 7  4 28 + 1;  
1

1  a1 = 4
28 rFkk    bn
a n n 1
n 1
a1 = 4 28 and    bn
a n n 1 ;fn Hkqtkvksa dh yEckbZ a1, a2 rFkk a3 okys f=Hkqt dk
n 1
If the area of the triangle with sides lengths {ks=Qy p q ds :i esa O;Dr fd;k tk ldrk gS tgk¡
a1, a2 and a3 can be expressed in the form
p rFkk q ijLij vHkkT; gSa] rc (p + q) dk eku Kkr
of p q where p and q are relatively prime,
dhft,A
then the value of (p + q) is - (A) 14 (B) 7
(A) 14 (B) 7 (C) 28 (D) 9
(C) 28 (D) 9

(SPACE FOR ROUGH WORK)

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 (ADVANCED PATTERN) | Page # 7

5 5
7. If 2 sin–1 x0 + tan–1 x0 = , 7. ;fn 2 sin–1 x0 + tan–1 x0 = gS,
 x 02  2 x 0  15  x 02  2 x 0  15

dy 2x dy
then the possible value(s) of
dx
to the rks oØ y = y  x ds x = x0 ij dk@ds laHko
dx

2x eku gS@gSa
curve y = at x = x0 is(are)
yx 1 4
(A) (B)
1 4 3 3
(A) (B)
3 3
1 1
(C) – 2 (D) (C) – 2 (D)
2 2

8. Consider the function f(x) = x3–9x2+15x+6 8. ekuk1  x  6 dsfy, ] Qy u f(x) = x3–9x2+15x+6

for 1  x  6
min f  t  / 1  t  x,1  x  6
min f  t  / 1  t  x,1  x  6 gSr Fkkg(x) = 
and g(x) =   x – 18 for x>6
 x – 18 for x>6
Then which of the following statement(s)
gS
] r c fuEufy f[ kr dFkuksaesal sdkS
ul kl ghgS
&
is/are corret?
(A) g(x), x = 6 i j l a r r ~gS
(A) g(x) is continuous at x = 6
(B) g(x) is differentiable at x = 2 (B) g(x),x = 2 i j vody uh; gS
(C) g(x) is differentiable at x = 5 (C) g(x), x = 5 i j vody uh; gS
(D) g(x) is monotonic in (1, 5) (D) g(x), (1, 5) es a, d fn"V gS

(SPACE FOR ROUGH WORK)

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dk;Z m|e ls fl) gksrs gS] euksjFkks ls ughaA

 (ADVANCED PATTERN) | Page # 8

9. Triangles are formed by joining vertices of a 9. , d v"VHkq

t ds' kh"kksZ
adksfeykusl sf=kHkq
t fufeZ
r gksrsgS
ar c
octagon then number of triangles f=kHkq
t ksadhl a
[ ; kgS
&
(A) In which exactly one side common with
(A) ft l esaBhd v"VHkq
t dhHkq
t k dsl kFk mHk; fu"B , d
the side of octagon is 32
Hkq
t k32 gS
(B) In which atmost one side common with
(B) ft l esacgq
Hkq
t dhHkq
t kdsl kFkvf/kd l svf/kd mHk; fu"B
the side of polygon is 48
(C) At least one side common with the side , d Hkq
t k48 gS
of polygon is 50 (C) cgq
Hkq
t dhHkq
t kdsl kFkde l sde mHk; fu"B , d Hkq
tk
(D) Total number of triangle 56 50 gS
(D) f=kH
kq
t ksadhdq
y la
[ ; k56 gS

10. Let x and y be unit vectors. If r is a 10. ekuk x r Fkk y bdkbZl fn' k gS
A ; fn r , d l fn' k bl

 
vector such that r  r  x  y , then i zd kj gSfd r  r  x   y gS
] r c&

(A) maximum value of r.x is 1 (A) r.x dk vf/kdr e eku 1 gS

1 1
(B) maximum value of r.x  y is (B) r.x  y dk vf/kdr e eku gS
2 2

 
(C) maximum vale of r is 1 (C) r dk vf/kdr e eku 1 gS

1 1
(D) minimum value of r is (D) r dk U; w
ur e eku gS
2 2

(SPACE FOR ROUGH WORK)

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izR;sd vPNk dk;Z igys vlEHko utj vkrk gSA

 (ADVANCED PATTERN) | Page # 9

SECTION - C SECTION - C
[MATCH THE COLUMN TYPE] [l q
esy u l q
phi zd kj ]
Match the entries in Column - I with the entries in
Column- II. One or more entries in Column
Lr EHk- I dhi zfo"Vh; ksdkLr EHk - II dhi zfo"Vh; ksadsl kFkl qesy u
- I may match with one or more entries in
dhft ; sALr EHk- I es, d ; k, d l svf/kd i zfo"Vh; kaLr EHk
Column - II. - II ds, d ; kvf/kd i z fo"Vh; ksadsl kFkl q
esfy r gksl dr h
gS
A
1. List-I List-II 1. lwph-I lw
ph-II
(A) Let P(x,x2) be a point (P) 6
(A) ekukP(x,x2) i j oy ; (P) 6
on the parabola y = x2.
y = x2 i j fLFkr , d fcU
nqgS; fn
2 2
If f  x    x – 3 
 x2 – 2  2 2

2
f x   x – 3 
 x2 – 2 

– x2  x2 – 1  2

and maximum value


– x2  x2 – 1 
of f(x) is N , then N is r Fkkf(x) dkvf/kdr e eku N gS ]
(B) Number of divisors of (Q) 7 r c N cj kcj gksxk
25.32.53 which are divisible (B) l a [ ; k25.32.53 dsmu (Q) 7
by 2 but not divisible by 6 Hkkt dkasdhl a [ ; k] t ks2 l sHkkT; gks
and 8 is
i jar q6 vkSj 8 l sHkkT; u gks] gksxh
(C) Let f(n)= nC0 nC1 + nC1 (R) 8 (C) ekukf(n)= nC0 nC1 + nC1 (R) 8
n
C2+ ......+ nCn–1 nCn
If 4f(n + 1) = 15 f(n),
n
C2+ ......+ nCn–1 nCn gS
then sum of all possible ; fn 4f(n + 1) = 15 f(n),
values of n is r c n dsl Hkhl a Hko ekuksadk; ksx gksxk
(D) The number of solutions (S) 10
(D) l ehdj .k (sin   cos ) tan  (S) 10
of the equation
 sin   cos   tan   sec2   1 dsva r j ky
is [–3, 3] es
agy ksadhl a [ ; kgksxh
 sec2  – 1 in –3,3 

(SPACE FOR ROUGH WORK)

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 (ADVANCED PATTERN) | Page # 10

2. Let a differentiable function satisfies the 2. ekuk ,d vodyuh; Qyu lEcU/k f(x – y + 1)
f (x) f (x)
relation f(x – y + 1) =  x  R and f =  x  R dks larq"V djrk gS rFkk f '(0) =
f ( y  1) f ( y  1)
'(0) = 2, f(0) = 1.
List- I List - II 2, f(0) = 1 gSA
lw
ph- I lw
ph- II
ln 3 ln 3
(A) The value of  f (x ) dx is (P) 1 (A)  f (x ) dx dk eku gS (P) 1
0 0

10 d10   x  
d   x  (B)  f    dk eku gS (Q) 2
(B) The value of  f    is (Q) 2 dx10   2  
dx10   2   x 0
x 0

(C) The number of solution(s) of the (R) 3 (C) lehdj.k f(x) = x2 ds gy¼gyksa½ (R) 3
equation f(x) = x2 is(are) dh la[;k gS
f ( x )  f (x 2 ) f ( x )  f (x 2 )
(D) The value of Lim is (S) 4 (D) Lim dk eku gS (S) 4
x 0 sin x x 0 sin x

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 (ADVANCED PATTERN) | Page # 11

PART - II [PHYSICS]
SECTION - A SECTION - A
[INTEGER ANSWER TYPE] [ fo' y s
"k. kkRed i z'u i zd kj ]
Q.1 to Q.8 are INTEGER ANSWER TYPE Questions.
i z-1 l si z-8 r d fo' y s"k.kkRed i z'u gS
A¼i zR; sd i z'u dkmÙkj dsoy
(The answer of each of the questions is 1 digits)
d ksesnhft
1 va ; sA

1. Find the charge on the capacitor C = 1F in 1. fp=kesafn[ kk; si fj i Fkesa/kkfj r kC = 1F dsl a
/kkfj =ki j
the circuit shown in the figure. vkos'kKkr dhft , A
10V 10V

2. Let a total charge 2Q be distributed in a 2. dq y vkos'k2Q dksf=kT; kR dsxksy sesabl i zd kj for fj r

sphere of radius R, with the charge density dj r sgSafd vkos'k?kuRo l EcU/k(r)=kr l sfn; kt kr kgS
given by (r)=kr, where r is the distance from t gk¡r, dsUnzl snw j hgS
Ai zR; sd –Q dsnksvkos'kksaA r Fkk
the centre. Two charges A and B, of –Q each,
B dksds Unzl sa cj kcj nwj hi j O
; kl r %foi j hr fcUnq
v ksai j
are placed on diametrically opposite points,
j [ kkx; kgS A ; fn A vkS
j B dksbZcy vuq Hko ughdj r sgS ]
at equal distance, a, from the centre. If A
and B do not experience any force, then
r ksa=x R gS
-1/4
A x dkeku Kkr dj ks&
a=x-1/4R. Find the value of x.

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lQyrk vR;f/kd ifjJe pkgrh gSA

 (ADVANCED PATTERN) | Page # 12

3. A circular wire loop of radius R is placed in 3. R f=kT; kdk, d o`Ùkh; r kj yw

i ft l dkdsUnzew
y fcUnqO i j gS ]
the x-y plane centered at the origin O. A
square loop of side a(a<<R) having two turns x-y r y esaj [ kkgS
AHkq t ka(a<<R) , oanksQsjksa(turns) okyk
is placed with its center at z = 3 R along , d oxkZ
d kj yw i o`Ùkh; r kj ywi dhv{ki j fp=kkuql kj fLFkr gS
]
the axis of the circular wire loop, as shown ft l dkdsUnzz = 3 R i j gS
AoxkZ
d kj yw
i dkr y z-v{kds
in figure. The plane of the square loop makes
o
an angle of 45 with respect to the z-axis. If l ki s{k 45o dk dks.k cukr k gS
A ; fn yw
i ksdschp vU;ksU;
the mutual inductance between the loops is
 0 a2
 0a 2 i zsj.k } kjkfn; kt kr kgS
] r ksp dkeku Kkr dj ks&
given by , then value of p is 2p / 2 R
p/2
2 R
45o
45o

3 R
3 R

4. Two wheels each marked with a dot on its rim 4. nksi fg; si zR;sd bl dhfj e i j , d fcUnqdsl kFkfpfUgr gS ]
are mounted side by side. When the wheels are
at rest, the dots are aligned. One wheel is given i kl &i kl y xk; st kr sgS
A t c i fg; sfoj ke i j gS
, r c fcU
nq
 
a constant angular acceleration of rad / s2 la A, d i fg; sdks rad / s2 dk, d fu; r dks.kh;
j sf[ kr gS
2 2
and the other is given a constant angular 

l j sdks rad / s2 dk, d fu; r
Roj .kfn; kt kr kgSr Fkknw
2 4
acceleration of rad / s . The time after which
4 dks.kh; Roj .kfn; kt kr kgS Aog l e; (l S
d .Mes )a
sft l dsckn
the two dots will be aligned again for the
first time (in seconds) is ……[Angular acceleration nksuksafcUnqi gy hckj (first time) i q u%l aj sf[ kr gksa
xs] gS
are in the same sense of rotation) ……[dks . kh; Roj .k?kw
. kZ
u dhl eku fn' kkesagS
A)
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 (ADVANCED PATTERN) | Page # 13

5. The orbital velocity of an artificial satellite in 5. i F̀ohl r g dsBhd mi j , d or̀ h; d{kkesa, d Ñf=ke mi xzg
a circular orbit just above earth surface is u. dkd{kh; osx u gS Ami xzg dsfy , t ksi F̀ohdhf=kT; kdh
For satellite orbiting at an altitude of half
the earth’s radius, the orbital velocity is 2
vk/khÅ¡pkbZi j i fj Øekdj j gkgS
, d{kh; os
x u gS
,
N
2
u , find N
N r c N Kkr dhft , &

6. A long straight wire carrying current of 25A

6. , d l h/kky Eckr kj ft l esa25A dh/kkj ki zokfgr gksj ghgS ,

rests on a table as shown in figure. Another fp=kkuql kj Vscy i j foj ke i j gSA 1m y EckbZ , æO ; eku
wire PQ of length 1m, mass 2.5g carries the 2.5g ds, d vU ; r kj PQ esal eku /kkj k fdUr qfoi j hr
same current but in the opposite direction. fn' kkesai zokfgr gksrhgSAr kj PQ Åi j r FkkuhpsfQl y us
The wire PQ is free to slide up and down. To dsfy ; sLor a =k gS
A fdl Å¡pkbZi j PQ l kE; koLFkk esa
what height will PQ come to equllibrium? If
vk; sxk? ; fn Å¡pkbZ , h=x mm gS , r c x dk eku Kkr
the height, h=x mm, find the value of x
(take g = 10m/sec2) dhft , (g = 10m/sec2 ysa
)

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viuh “kfDr;ksa ij Hkjkslk djus okyk dHkh vlQy ugh gksrk A

 (ADVANCED PATTERN) | Page # 14

7. The arrangement as shown, temperatures of 7. n' kkZ

; hO ; oLFkkesafl j ksP r FkkR dkr ki 200°C r Fkk0°C
ends P and R are 200°C and 0°C. The lengths
gS
ANM+ ksadhyEckbZ ; k¡n' kkZ
; hx; hgS
ANM+RS dhy EckbZnL
of rods are shown. The length of rod RS
gS
, ; fn QS l sgks d j dksbZÅ"eki zokfgr ughagksrhgSt gk¡
is nL, if no heat flows through QS where n is
an integer. Find the value of n. n ,d i w . kk±
d gS
] r c n dkeku Kkr dhft , A

8. An inductor of inductance 2.0 mH is connected 8. 2.0 mH i zsjdRo dk , d i zsjd 5.0F /kkfj r k ds, d
across a charged capacitor of capacitance 5.0F vkosf' kr l a
/kkfj =k dsfl j ksai j t ksM+k x; k gSr Fkk i fj .kkeh
and the resulting L–C circuit is set oscillating at its
L–C i fj i Fkbl dhokLr fod vkof̀r i j nks y u esaO
; ofLFkr
natural frequency. The instantaneous charge on
fd; k t kr k gS Al a/kkfj =k i j r kR{kf.kd vkos'k q gSr Fkk
the capacitor is q and the current is I. It is found
that the maximum value of q is 200C. Calculate /kkj kI gS
A; g i k; kt kr kgSfd q dkvf/kdr e eku 200C
the value of I in amperes when magnetic flux gSAI dseku dh, Ei h; j esax.kukdj kst c i zsjd l sxq t j us
through the inductor becomes its maximum value. oky kpq Ecdh; Qy Dl bl dkvf/kdr e eku gkst kr kgS A

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SECTION - B SECTION - B
[MULTIPLE OBJECTIVE TYPE]
[ cgqoS
d fYi d i z'u i zd kj ]
Q.1 to Q.10 has four choices (A), (B), (C), (D) out
i z-1 l si z-10 esapkj fodYi (A), (B), (C), (D) gS
] ft uessal s^^, d
of which ONE OR MORE THAN ONE is correct
; k, d l svf/kd^^ l ghgS
A
1. A transparent thin film of uniform thickness
and refractive index n1=1.4 is coated on the 1. n1 = 1.4 vi or Z
uka d r Fkkl e: i eksVkbZdh, d i kj n' khZ
convex spherical surface of radius R at one i r y hfQYe fp=kkuq l kj n2=1.5 vi or Z ukad ds, d y Ecs
end of a long solid glass cylinder of refractive Bksl dka p dscsy u ds, d Nksj i j R f=kT; k dsmRr y
index n2 = 1.5, as shown in the figure. Rays of xksy h; i `"B i j y sfi r (coated) gS A fQYe dsek/; e l s
light parallel to the axis of the cylinder
ok; ql sdka p est kusoky hi zd k' kdhfdj .ksat ksfd csy u ds
traversing through the film from air to glass
v{k dsl eka r j gSa
] fQYe l sf1 nw j hi j Qksd fl r gksrhgS a
]
get focused at distance f1 from the film, while
t cfd dk¡p l sok; qesat kusoky hfdj .ksafQYe l sf2 nw j hi j
rays of light traversing from glass to air get
focused at distance f2 from the film. Then - Qksd l gksrhgS a
Ar c

(A) f1  3R (B) f1  2.8R

(A) f1  3R (B) f1  2.8R
(C) f 2  2R (D) f 2  1.4R
(C) f 2  2R (D) f 2  1.4R

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 (ADVANCED PATTERN) | Page # 16

2. Two vehicles, each moving with speed u on 2. nksokgu] ft uesai zR; sd dhpky u gS
] , d ghl h/kh{kS
fr t
the same horizontal straight road, are
approaching each other. Wind blows along the
l M+
d i j , d nw
l j sdhvksj vkj gsgS
a
Aok; ql M+
d dhfn' kk
road with velocity w. One of these vehicles esaw osx l scg j ghgS
Abuesal s, d okgu f1 vkof̀Ùkdhl hVh
blows a whistle of frequency f1. An observer ct kr kgS
Anw
l j sokgu esacS
Bsgq
, i zs{kd dksl hVhf2 vkof̀Ùk
in the other vehicle hears the frequency of
the whistle of be f2. The speed of sound in dhl q
ukbZnsrhgS
A fLFkj ok; qesa/ofu dhpky V gS
A l gh
still air is V. The correct statement (s) is (are) i zd Fku gS¼
gS
a
½
(A) If the wind blows from the observer to
(A) ; fn ok; qi z
s{kd l sL=kksr dhvksj cgr hgS
] r c f2 > f1 gS
A
the source, f2 > f1.
(B) If the wind blows from the source to the (B) ; fn ok; qL=kks
r l si zs{kd dhvksj cgr hgS
] r c f2 > f1gS
A
observer, f2 > f1.
(C) If the wind blows from observer to the source, (C) ; fn ok; qi z
s{kd l sL=kksr dhvksj cgr hgS
] r c f2 < f1gS
A
f2 < f1. (D) ; fn ok; qL=kks
r l si zs{kd dhvksj cgr hgS
] r c f2 < f1gS
A
(D) If the wind blows from the source to the
observer, f2 < f1.

3. The pulley as shown in the figure, consists 3. fp=kkuq

l kj , d f?kj uhl eku ' kkW
¶V l st q
M+hfHkUu&fHkUu O ; kl
of two discs of different diameters attached
dh nkspdfr ; ksadks/kkj .k dj r h gS A j Ll h ml = 1 kg
to the same shaft. The rope connected to
æO; eku dsCy kW d l st ksM+
ht kr hgSt ks, d fpdus[ kw a
Vsds
the block of mass ml = 1 kg passes over a
smooth peg, while the block of mass m2 = 3 Åi j l sxqt j r hgSt cfd m2 = 3 kg æO ; eku dkC y kW
d ,d
kg hangs vertically from one disc. The moment pdr hl sÅ/okZ /kj : i l syVdkgS Af?kj uhdkt M+ Ro vk?kw . kZ
of inertia of the pulley is 0.2 kg m2; rl = 5 cm 0.2 kg m2 gS ; rl = 5 cm r Fkkr2 = 10 cm gS A j fLl ; ksaesa
and r2 = 10 cm. Find the tensions in the
r uko vkSj Cy kWd ksadkRoj .kKkr dj ksA
ropes and the accelerations of the blocks.

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ckj ckj vlQy gksus ij Hkh mRlkg uk [kksuk gh lQyrk gSA

 (ADVANCED PATTERN) | Page # 17

T1 T1

m1 a1 m1 a1

T2 T2

m2 a2 m2 a2
(A) a1 = 0.527 m/s2 (B) a2 = 1.05 m/s2 (A) a1 = 0.527 m/s2 (B) a2 = 1.05 m/s2
(C) T1 = 10.3 N (D) T2 = 26.2 N (C) T1 = 10.3 N (D) T2 = 26.2 N
4. One mole of an ideal monoatomic gas has initial 4. , d vkn' kZ, dyi j ek.kq
d xS l ds, d eksy dki zkjfEHkd r ki eku
temperature T0 , is made to go through the cycle T0 gS
, t ksfp=kkuq
l kj pØabca l st kusdsfy, cuk; kgS A; fn
abca shown in figure. If U denotes the internal U vkUr fj d Åt kZdksi znf' kZ
r dj r kgS
] r c l ghfodYi pqfu; s&
energy, then choose the correct alternative.

(A) Uc  Ub  U a (B) U c  U b  3RT0

(A) Uc  Ub  U a (B) U c  U b  3RT0
9 RT0 3RT0
9 RT0 3RT0 (C) U c  U a  (D) U b  U a 
(C) U c  U a  (D) U b  U a  2 2
2 2
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 (ADVANCED PATTERN) | Page # 18

5. A battery consists of 2 identical cells each 5. , d cS

Vj h i zR; sd E fo- ok- cy ds2 , dl eku l S
y ksadks
of emf E connected in series. The battery is
j [ kr h gSt ksJs.kh esat q
M+sgS
A cS
Vj h , d i zfr j ks/kd R l s
used to charge a capacitor with capacitance
/kkfj r kC ds, d l a
/kkfj =kdksvkosf' kr dj usdsfy ; si z;ksx
C through a resistor R. Then
(A) By connecting it across the terminals of dht kr hgS
Ar c
the entire battery, the amount of energy (A) bl dksal Ei w
. kZcS
Vj hdsVfeZ
uy ksadsfl j ksai j t ksM+
dj
transferred from the battery which is not cS
Vj hl sLFkkukUr fj r Åt kZdhek=kkt ksl a
/kkfj =kesal a
fpr
stored in the capacitor is 2CE 2
ughagksrhgS
, 2CE2 gS
A
(B) By connecting it across the terminals of
(B) bl dksal Ei w
. kZcS
Vj hdsVfeZ
uy ksadsfl j ksai j t ksM+
dj
the entire battery, the amount of energy
transferred from the battery which is not cS
Vj hl sLFkkukUr fj r Åt kZdhek=kkt ksl a
/kkfj =kesal a
fpr
stored in the capacitor is 4CE2 ughagksrhgS
S
, 4CE2 gS
A
(C) By connecting it first across a single cell, (C) bl dksi gy s, d , dy l S
y dsfl j ksai j t ksM+
r sgSfQj
then across two cells until it is again fully
nksl S
y ksadsfl j ksai j t c r d ; g i q
u%i w
j k vkosf' kr u gks
charged, the amount of energy transferred
t k; s] cS
Vj h l s LFkkukUr fj r Åt kZ d h ek=kk t ks
from the battery which is not stored in the
capacitor is CE2 la
/kkfj =kesal a
fpr ughagksrhgS
, CE2 gS
A
(D) By connecting it first across a single cell, (D) bl dksi gys, d , dy l S
y dsfl j ksai j t ksM+
r sgSfQj
then across two cells until it is again fully nksl S
y ksadsfl j ksai j t c r d ; g i q
u%i w
j k vkosf' kr u gks
charged, the amount of energy transferred
t k; s] cS
Vj h l s LFkkukUr fj r Åt kZ d h ek=kk t ks
from the battery which is not stored in the
la
/kkfj =kesal a
fpr ughagksrhgS
, 2CE2 gS
A
capacitor is 2CE2.

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eqf'dys oks phtsa gksrh gS] tks gesa rc fn[krh gS tc gekjk /;ku y{; ij ugha gksrkA
 (ADVANCED PATTERN) | Page # 19

6. A ring of mass M, radius R, cross section 6. M æO ; eku, R f=kT; k, vuq i zLFk dkV {ks=kQy ‘a’ r Fkk; a x
area ‘a’ and Young’s modulus Y is kept on a
eki ka
d Y dh, d oy ; 2R vk/kkj f=kT; kr Fkkv/kZ ' kh"kZdks.k
smooth cone of base radius 2R and semi
vertex angle 450, as shown in figure. Assume 45 ds, d fpdus' ka
0
d qi j fp=kkuql kj j [ kht kr hgS Aekuk
that the extension in the ring is small. Pick fd oy ; esai zl kj de gS
A l ghfodYi pq
fu; s&
the correct alternative(S)

(A) The tension in the ring will be same (A) oy ; esar uko l oZ
=kl eku gksxk
throughout (B) oy ; es
ar uko bl dhf=kT; ki j fuHkZ
j ughadj sxk; fn
(B) The tension in the ring will be independent oy ; dhf=kT; k2R l sde gS A
of its radius if radius of ring is less than 2R
MgR MgR
(C) The extension in the ring will be (C) oy ; esai zl kj gksxk
aY aY
(D) elastic potential energy stored in the ring (D) oy ; es
al a
fpr i zR; kLFkfLFkfr t (potential) Åt kZ
M 2g2R M 2g2R
will be gksxhA
8 Ya 8 Ya

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7. Three bars of different materials but same 7. l eku yEckbZr Fkkvuq i zLFkdkV {ks=kQy ysfdu fofHkUu i nkFkksZ
length and area of cross-section are joined. dhr hu NM+ st ksM+
ht kr hgSAl a
;qDr NM+dk, d fl j k2000C
One end of the composite rod is maintained i j cuk; sa j [ kkt kr kgSr Fkknwl j kfl j k350C i j cuk; saj [ kk
at 2000C and the other end is maintained at t kr kgSAfofdj .k} kj kfl j ksa(sides) l sÅ"ekdhgkfu ux.;
350C. Loss of heat from the sides by radiation : i l sde (negligibly small) cukbZt kr hgS ALFkkbZvoLFkk
is made negligibly small. The temperatures of esal fU/k; ksadkr ki eku fp=kkuq l kj 110 C vkS
0 j 800c gS Ar c
the junctions in the steady state are 1100C
200 0C 1 100C 80 0C 35 0C
and 800c as shown in the figure

1 100C 80 0C (A) (B) (C)

200 0C 35 0C
(A) A r Fkk B dsÅ"eh; pky dr kvksadsxq . kka
d 3:1
(A) (B) (C)
vuq
i kr esagS
A
The coefficient of thermal conductivities of (B) B r Fkk c dsÅ"eh; pky dr kvks adsxq . kka
d 3 :2
(A) A and B are in the ratio 3 : 1 vuq
i kr esagS
A
(B) B and c are in the ratio 3 :2 (C) A r Fkk c dsÅ"eh; pky dr kvks adsxq . kka
d 2:1
vuq
i kr esagS
A
(C) A and c are in the ratio 2 : 1
(D) A, B, vkSj C dsÅ"eh; pkydr kvksadsxq
. kka
d1 : 3 : 2
(D) A, B, and C are is 1 : 3 : 2
vuq
i kr esagS
A
8. Three mass ‘m’ each are kept at corner of a 8. r hu nzO ; eku ‘m’ i zR; sd l eckgqf=kHkq
t dsdksuksai j j [ ksgS
a
equilateral triangle and are rotating under r Fkki j Li j xq
: Rokd"kZ. kcy dsi zHkko dsvUrxZr ?kwe j gsagSA
a
effect of mutual gravitational force -
(A) nz
O; eku } kj k vuq
l fj r oÙ̀kh; i Fk dhf=kT; ka/2 gS
A
(A) Radius of circular path followed by mass
is a/2 Gm
Gm (B) nzO
; eku dk osx gS
A
(B) Velocity of mass is a
a 1.5Gm 2
(C) Binding energy of system is 1.5Gm 2
a (C) fudk; dhca
/ku Åt kZ gS
A
a
a 3
(D) Time period of mass is a 3
2Gm (D) nz
O; eku dkvkor Z
d ky gS
A
2Gm

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 (ADVANCED PATTERN) | Page # 21

9. Charges Q1 and Q2 lie inside and outside 9. vkos'kQ1 vkS j Q2 cUn xkml h; i `"B S dsØe' k%vUnj vkS j
respectively of a closed Gaussian surface S. ckgj fLFkr gSAekukE, S i j fdl hHkhfcUnqi j {ks=kgSr Fkk
Let E be the field at any point on S and  be  , S dsÅi j E dk ¶y Dl gS:
the flux of E over S: (A) ; fn Q1 i fj ofr Z
r gksrkgS
, r c E vkS
j  nksuksai fj ofr Z
r gksxsaA
(A) If Q1 changes, both E and  will change (B) ; fn Q2 i fj ofr Z r gksrk gS, r c E i fj ofr Z
r gksxk
(B) If Q2 changes E will change (C) ; fn Q1 = 0 r Fkk Q2  0 gSr c E  0 y s fdu
(C) If Q1 = 0 and Q2  0 then E  0 but  = 0 gS A
=0 (D) ; fn Q1  0 r Fkk Q2 = 0 gSr c E = 0 y s fdu
(D) If Q1  0 and Q2 = 0 then E = 0 but
0   0 gSA

10. A solid sphere of radius R and density  is 10.  ?kuR

o vkS
j R f=kT; kdk, d Bksl xksy kk cy fu; r ka
d dh
attached to one end of a mass-less spring of , d nzO ; ekughu fLi azx ds, d fl j sl st ksM+kt kr kgSAfLi azx
force constant k. The other end of the spring
is connected to another solid sphere of radius
dknw l j kfl j k3?kuRo vkS j R f=kT; kdsnw l j sBksl xksy s
R and density 3. The complete arrangement l st ksM+ k t kr kgS
A l Ei w. kZO
; oLFkk 2?kuRo ds, d nzo esa
is placed in a liquid of density 2 and is j [ kht kr hgSvkS j l kE; koLFkkesai gq ¡pusdhLohdf̀r nht kr h
allowed to reach equilibrium. The correct gSA l ghdFku gS @gS a&
statement(s) is (are)
4R 3g
(A) fLi a
zx dhdq
y y EckbZ(elongation) gS
3
4R g 3k
(A) the net elongation of the spring is
3k 8R 3 g
(B) fLi a
zx dhdq
y y EckbZ(elongation) gS
A
3k
8R 3g (C) gYdkxks
y kvka
f' kd : i l sMq
cks;kt kr kgS
A
(B) the net elongation of the spring is
3k
(D) gYdkxks
y ki w
. kZ: i l sMq
cks;kt kr kgS
A
(C) the light sphere is partially submerged.
(D) the light sphere is completely submerged.

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SECTION - C SECTION - C
[MATCH THE COLUMN TYPE] [l q
esy u l q
phi zd kj ]
Lr EHk - I dhi zfo"Vh; ksdkLr EHk - II dhi zfo"Vh; ksadsl kFkl q
Match the entries in Column - I with the entries in esy u
Column- II. One or more entries in Column - I may dh ft ; s
A Lr E
Hk - I es , d ; k , d l svf/k
d i f
zo"Vh
; k
a Lr E
Hk - II ds
match with one or more entries in Column - II. , d ; kvf/kd i f
zo"Vh; ks
adsl kF kl q
e f
syr gksl dr hgSA

1. A neutron moving with kinetic energy K

1. , d U; wVªkW
u K xfr t Åt kZl sxfr dj r sgq , ew y voLFkkesa

collides with a hydrogen atom at rest in foj ke i j , d gkbMªkst u i j ek.kqdsl kFk VDdj dj r k gS A
ground state. Assume mass of neutron to be ekukfd U;w VªkW
u dkæO ; eku gkbMªkst u i j ek.kqdsæO
; eku ds
equal to that of hydrogen atom. Match the l eku gS A U; w
VªkW
u dhxfr t Åt kZdksLr EHk– I esafn[ kkbZ
kinetic energy of neutron with possible l EHko VDdj dsl kFkfeykbZ ; sAewy voLFkkesagkbMªkst u dh
collisions mentioned in column – I . energy of Åt kZ– 13.6eV gS A
hydrogen in ground state is – 13.6eV Lr EHk– I
Column – I (Vdj kusoky sU ;w
VªkW
u dhxfr t Åt kZ )
(K.E. of colliding neutron) (A) K = 10.2eV
(A) K = 10.2eV (B) K = 13.6eV
(B) K = 13.6eV (C) K = 20.4eV
(D) K = 22.0eV
(C) K = 20.4eV
Lr EHk– II
(D) K = 22.0eV
(P) i z
R; kLFkVDdj gksl dr hgS A
Column – II
(P) Elastic collision may take place (Q) vi z R; kLFkVDdj gksl dr hgS A
(Q) Inelastic collision may take place (R) i w. kZ
r %vi zR; kLFkVDdj gksl dr hgS A
(R) perfectly inelastic collision may take place (S) gkbMªks t u i j ek.kqvk; fur gksl dr kgS
A
(S) hydrogen atom may get ionised.

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2. Match The Following 2. fuEufy f[ kr dksfey kbZ ; s&

Column – I Lr EHk– I
(A) a point charge moving along equipotential
(A) l efoH ko xksy h; i `"B dsvuq fn' k , d fcUnqvkos'k
spherical surface
(B) A negative charge moving from Lower to xfr eku gS A
higher potential In the electric field (B) fo| qr {ks=kesafuEu l smPp foHko dhvksj , d _ .kkRed
(C) A unit charge moving along Perpendicular vkos'kxfr eku gS A
bisector of line Joining two fixed charges +Q (C) nksfLFkj vkos ' kksa+Q vkS j – Q dksfey kusoky hj s[kk
and – Q
(D) Three negative charges being Brought
dsy Ec v/kZ d dsvuq fn' k, d bdkbZvkos'kxfr eku gSA
from infinity to the vertices of an equilateral (D) r hu _ .kkR ed vkos'k fcuk Roj .k dsvuUr l s, d
triangle with out acceleration l eckgqf=kHkq
t ds' kh"kksZr d y k; st kr sgS A
Column – II Lr EHk– II
(P) external work is equal to gain in potential (P) ckg~ ; dk; ZfLFkfr t Åt kZesaof̀) dscj kcj gS A
energy
(Q) fo| q r {ks=k} kj kfd; kx; kdk; Z' kw U; gSA
(Q) work done by the electric field is zero
(R) Acceleration is directed perpendicular to (R) R oj .kl h/kkxfr dhfn' kkdsy Ecor gS A
direction of motion (S) fo| q r {ks=kdsdkj .kcy } kj k fd; kx; k dk; Zxfr t
(S) work done by force due to electric field Åt kZesaof̀) dscj kcj gS A
is equal to gain in kinetic energy

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PART - III [CHEMISTRY]

SECTION - A SECTION - A
[INTEGER ANSWER TYPE] [ fo' y s
"k. kkRed i z'u i zd kj ]
Q.1 to Q.8 are INTEGER ANSWER TYPE Questions. i z-1 l si z-8 r d fo' y s"k.kkRed i z'u gS
A¼i zR; sd i z'u dkmÙkj dsoy
(The answer of each of the questions is 1 digits) d ksesnhft
1 va ; sA
1. AO2 disproportionates into AO4 and An+ ion. 1. AO2, AO4 r FkkAn+ vk; u esa fo"kekuq i kfr r gksrk gS
A
If the mole ratio of AO2 undergone oxidation vkW
Dl hdj .k r Fkk vi p; u l sxq t kj usi j AO2 dk eksy
and reduction is 2:3, the value of n is vuqi kr 2 : 3 gS , r ksn dk eku gSA
2. The Schrodinger wave equation of hydrogen 2. gkbMªkst u i j ek. kq d h J ksfMat j l ehd j . k gS :
3/2 r0 r0
3/2
1  1   r0  a0 1 1   r0  a0
atom i s :  2s  4 2  a  2  e ,  2s  2   e , t gk¡a cks
 0  a0
 
4 2  a0  a0  0
j dh

where a0 is Bohr's radius. If the radial node is i j ek.kqf=kT; kgS
A ; fn r0 i j f=kT; fcanq(radial node)
r r
2s be at r0, then the value of a is 2s, gSr c a dk eku gS
A


3. Iridium was plated from a solution containing 3. bZfj fM; e] , d fo; y u t ks2.0 h dsfy , IrCl6y dsl kFk
IrCl6y for 2.0 h with a current of 0.075 A.The 0.075 A dh/kkj kj [ kr kl sfo| qr y sfi r fd; kgS
AdSFkksMi j
Iridium deposited on the cathode weighed , df=kr bfj fM; e dkHkkj 0.36 g gS A; fn IrCl6y esaIr dh
0.36 g. If the oxidation state of Ir in IrCl6y is vkW Dl hdj .k voLFkk x gS] r c (x + y) dk eku gksxk &
x, then the value of (x+y) is (Ir = 192) (Ir = 192)

4. Consider following reactions and write total number 4. fuEu vfHkfØ;kvksa ij fopkj djsa rFkk mu vfHkfØ;kvksa
of reactions which give major product as dh dqy la[;k fyf[k, tks vfHkfØ;k esa n~'kkZ;s vuqlkj
mentioned in reaction. eq[; mRikn nsrh gSA
(a) H3C–CH2–Br + Ag–CN  H3C–CH2– (a) H3C–CH2–Br + Ag–CN  H3C–CH2–
CN CN

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 (ADVANCED PATTERN) | Page # 25

O O
18  18 
(b) H3C–O–S NO2 + OCH3  (b) H3C–O–S NO2 + OCH3 

O O
O O
18  18 
H 3C  O CH 3 + O–S NO2 H 3C  O CH 3 + O–S NO2

O O
CH3 CH3 CH3 CH3
(c) C + SOCl2  C (c) C + SOCl2  C
H OH Cl H OH Cl
H H
D D D D
14 14 14 14
CH3 CH3 CH3 CH3

(d) D OH + PCl3  H Cl (d) D OH + PCl3  H Cl

H D H D

Ph Ph

(e) H3C OH + HBr (e) H3C OH + HBr

Et Et

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cM+k lkspks vkSj gkjus ls er MjksA

 (ADVANCED PATTERN) | Page # 26

Ph Ph Ph Ph

 H3C Br + Br CH3  H3C Br + Br CH3

Et Et Et Et

Cl I Cl I

(f) + NaI acetone

  + NaCl (f) + NaI acetone
  + NaCl

5. How many compound(s) can give +ve Lucas test 5. fdrus ;kSfxd +ve Y;wdkl ijh{k.k dejs ds rki ij
at room temperature? gksaxk ?
OH OH
OH OH

OH OH

OH OH

OH
OH

OH
OH

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OH OH
HO CH HO CH

OMe OMe

OH OH
6. The number of molecules among the follow-
6. fuEu l Hkhesal sdks.kh; l a
j pukj [ kusokysv.kq
v ksadhl a
[ ; kgS
SO2, SOCl2, SnCl2, CO2, NO2, H2O, NH3, N2O,
ing having angular shape is
BeCl2
SO2, SOCl2, SnCl2, CO2, NO2, H2O, NH3, N2O,
BeCl2
7. 1 L l a
r Ìr foy; u esaAgCl [Ksp(AgCl) = 1.6 ×
7. In 1 L saturated solution AgCl [Ksp(AgCl) = 1.6 ×
10–10], CuCl [Ksp(CuCl) = 1.0 × 10–6] dk0.1
10–10], 0.1 mol of CuCl [Ksp(CuCl) = 1.0 × 10–6]
is added. The resultant concentration of Ag+ in the mol fey k; kx; kgS A foy ; u esaAg+ dhi fj .kkehl ka
ær k
1.6 × 10 gS–x ] r ks"x" dseku dhx.kukdj ks&
solution is 1.6 × 10–x. The value of "x" is
8. The total number of possible geometrical
8. v"VQy dh; l a dqy [M(AA)abcd] ds fy , l a Hkkfor
i som e rs for the oc t ahe d ral com p l e x T; kfer h; l eko; fo; ksadhdq
yla[ ; k2x gS
Ax dkeku D; k
[M(AA)abcd] is 2x. What is the value of x ? gS\ ((AA)–l efefr ; f} nUrq d fy xs.M; a, b, c, d–
((AA)–symmetrical bidentate ligand; a, b , , dnUrq d fy xs.M)
c, d–monodentate ligands.)

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iwjs fo'okl ds lkFk vius liuks dh rjQ cM+ks] ogh ftanxh ft;ks ftldh dYiuk vkius dh gSA
 (ADVANCED PATTERN) | Page # 28

SECTION - B SECTION - B
[MULTIPLE OBJECTIVE TYPE] [ cgqoS
d fYi d i z'u i zd kj ]
Q.1 to Q.10 has four choices (A), (B), (C), (D)
i z-1 l si z-10 esapkj fodYi (A), (B), (C), (D) gS
] ft uessal s^^, d
out of which ONE OR MORE THAN ONE is correct
; k, d l svf/kd^^ l ghgS
A
1. Zeolites
1. ft ; ksy kbV~
l
(A) are microporous aluminosilicates
(A) l w {efNfnzr , Y; w
feuksfl fydsV~
l gksrsgS
(B) have general formula Mx/n(AlO2)x.SiO2 .
mH2O (B) l kekU; l w
=kMx/n(AlO2)x.SiO2. mH2O j [ kr sgS
A
(C) have pore sizes between 260 pm to 740 (C) j a
/kzks; kfNnzksdkvkdkj 260 pm l s740 pm dse/;
pm j [ kr kgS
A
(D) act as shape-selective catalyst (D) , d vkdkj &p; fur mÙi zsjd ds: i esadk; Zdj r kgS
A

2. -maltose (C12H22O11) can be hydrolysed to 2. -ekYVks

t (C12H22O11) dksXyw
d kst (C6H12O6) esanzfor
glucose (C6H12O6) as: fd; kt kl dr kgS:
C12H22O11 (aq)+H2O (1) 2C6H12O6 (aq) C12H22O11 (t yh; )+H2O (1) 2C6H12O6 (t yh; )
On the basis of following data identify the fuEufyf[ kr vk¡d Mksdsvk/kkj i j vfHkfØ; kl sl EcfU/kr l gh
correct statement(s) related with the dFku@dFkuksadkp; u dhft , &
reaction
 fHC 12H22O11(aq) = –2238 kJ/mol,
 fHC 12H22O11(aq) = –2238 kJ/mol,
 f H Co 6 H 1 2 O 6 ( a q ) = – 1263 kJ/mol,
 f H Co 6 H 1 2 O 6 ( a q ) = – 1263 kJ/mol,
 fHHo2O(1) = –285 kJ/mol
 fHHo2O(1) = –285 kJ/mol
Time (min) 0 50 100
l e; (min) 0 50 100

Conc.of   maltose(M) 0.4 0.1 0.025   ekYVks

t dh l kUnzrk(M) 0.4 0.1 0.025

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 (ADVANCED PATTERN) | Page # 29

(A) The hydrolysis of -maltose is exothermic (A) -ekYVks

t dkt y vi ?kVu , d Å"ek{ksihi zfØ; kgS
A
process.
(B) -ekYVks
tds1.0 eksy dsngu esaeq
ä Å"ekXy w d kst
(B) Heat liberated in the combusion of 1.0
mole of -maltose is greater than the heat ds1.0 eksy dsngu esaeq
ä Å"ek l sT; knk gksrhgS
A
liberated in combustion of 1.0 moles of (C) r ki eku c<+
usi j ] ekYVksl dst y vi ?kVu dhl hek
glucose.
(C) On increasing the temperature, the extent
de gkst k, xhA
of hydrolysis of maltose will decrease. (D) ekYVks
t dk t y vi ?kVu i zFke dksfV xfr dhdk
(D) The hydrolysis of maltose follows vuq
l j .k dj r kgS
A
first-order kinetics.

3. A cylinder fitted with a movable piston 3. , d xfr eku fi LVu dsl kFkfQV , d csy u 25C i j t y
contains liquid water in equilibrium with water ok"i dsl kFkl kE; voLFkkesanzfor t y j [ kr kgS
A25° i j
vapour at 25C. Which of the following
operation(s) results in a decrease in the
fuEu esl sdkSul hi zfØ; kdsdkj .kl kE; ok"i nkc esadeh
equilibrium vapour pressure at 25C ? gksxh\
(A) Moving the piston downward for a short (A) de nw
j hdsfy , uhpsdhvksj fi LVu dksxfr dj kusi j
distance.
(B) ok"i dhdq
N ek=kkgVkusi j
(B) Removing small amount of vapour.
(C) Removing a small amount of liquid water. (C) nzfor t y dhdq
N ek=kk gVkusi j
(D) Dissolving some salt in the water. (D) t y esadq
N y o.k foy s; dj usi j

4. The normal boiling point of a liquid ‘X’ is 400
K. Which of the following statement is true
about the process X(l)  X(g) ?
(A) at 400 K and 1 atm pressure G = 0
(B) at 400 K and 2 atm pressure G = +ve
(C) at 400 K and 0.1 atm pressure G = –ve
(D) at 410 K and 1 atm pressure G = +ve
4. , d nzo ‘X’ dkl kekU; DoFkuka
d 400 K gksrkgS
AfuEu esl s
dkSul kdFku i zØe X(l)  X(g) dsckj sesl R; gS\
(A) 400 K r Fkk1 atm nkc i j G = 0
(B) 400 K r Fkk2 atm nkc i j G = +ve
(C) 400 K r Fkk0.1 atm nkc i j G = –ve
(D) 410 K r Fkk1 atm nkc i j G = +ve

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 (ADVANCED PATTERN) | Page # 30

 CHCl  CHCl
H 3 H 3
5. N  (X) 
OH   (Y) Major 5. N  (X) 
OH   (Y) eq
[;
 KOH,  KOH,
H H
Product (Y) is mRikn (Y) D; k gS
&
CO2H CO2H
Cl Cl
N N N N
(A) (B) (C) (D) (A) (B) (C) (D)
N Cl N CHO N Cl N CHO
H H

6. (
i ) Hg ( OAc )2 / H 2O
    CrO 3  M
(ii ) NaBH 4 / OH ¯ 6. (
i ) Hg ( OAc )2 / H 2O
    CrO 3  M
(ii ) NaBH 4 / OH ¯
Which reaction(s) can produce 'M' as one of the
product. dkSulh vfHkfØ;k¼,sa½ ,d mRikn 'M' cuk ldrh gSA


(A)
H  / H 2O
  
 PCC (A) H/
H 2O
 PCC


(
i ) O3
 (B) (
i ) O3

(B) (ii ) H 2O / Zn
(ii ) H 2O / Zn

Cu / 
(
i ) BH 3 .THF Cu / 
   (C) (
i ) BH 3 .THF
  
(C) (ii ) H 2O 2 / OH ¯
(ii ) H 2O 2 / OH ¯

Hot
 &
 (D) Hot
 &

(D) conc .KMnO 4
conc .KMnO 4

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dk;Z gh lQyrk dh cqfu;kn gSA

 (ADVANCED PATTERN) | Page # 31

7. In which of the following Ester will be obtained 7. fuEu esal sfdl esamRikn ds: i esbZ
LVj i zkIr gksxk \
as a produced.
H
H (A) CH 3 COOH CH3 CH 2 OH
(A) CH 3 COOH CH3 CH 2 OH
O
O Pyridine
Pyridine (B) CH 3 C Cl CH 3 CH 2 OH
(B) CH 3 C Cl CH 3 CH 2 OH
O
O
CH3 C
H
CH3 C (C) CH3 CH2 OH O
H
(C) CH3 CH2 OH O CH3 C
CH3 C
(D) CH3 H
H COOH CH3 CH2 NH2
(D) CH3 COOH CH3 CH2 NH2

8. /kkr q
@/kkr q
, ¡t kst y h; NH3 esa?kq
y u' khy gS&
8. The metal(s) which are soluble in liquid NH3
(A) Na (B) Ca (C) Sr (D) Be
.....
(A) Na (B) Ca (C) Sr (D) Be

9. Correct statement(s) among the following 9. fuEu esal sl ghdFku@dFkuksadkp; u dhft , &
is/are (A) CO2 , d i F̀kd v .kqgSt cfd SiO2 , d t ky h;
(A) CO2 is a discrete molecule while SiO2 is a Bksl gS A
network solid.
(B) R2SiCl2 dst yvi ?kVuh; cgq y hdj .kdsnkS
j ku Jà
[ kyk
(B)During hydrolytic polymerization of R2SiCl2,
R3SiCl is added to control the chain length.
dhya ckbZdksfu; a
f=kr dj usdsfy, R3SiCl dkst ksM+ kt kr kgS
A
(C) Silicon has no graphite analogue as it (C) fl fy dkW u] xzsQkbZ
V dk dksbZl er q Y; ugh j [ kr k gS
does not form p  - p  bonds itself.. D; ksa
fd ; g p  -p  ca /kLo; aughacukr kgS A
(D) Trisilyl amine is less basic than trimethyl (D) Vªkbfl fy y , ehu] Vªkbes fFky , ehu l sd e {kkj h;
amine. gksrkgS A

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10. X-ray films in hospitals waste are recycled
by treating it with dilute nitric acid so as to
get transparent celluloid sheets. The solu-
tions obtained on treating the films with di-
lute nitric acid, is mixed with dilute NaCl so-
lution. The white precipitate thus formed can
dissolve in
(A) Dilute HNO3 (B) Con.NaCl solution
(C) Na2S2O3 solution (D) KCN solution
10. vLi r ky ksaesav i f' k"V ea
sX-fd j .kfQYe d ksr uqukbfVªd
vEy dsl kFk fØ; k } kj k i q uZuohuhd r̀ d j d si kj n' khZ
l sY; w
y kW
; M' khV i zkIr d ht kr hgSA r uqukbfVªd vEy l s
fQYe d h fØ; k d j kusi j i zkIr foy ; u d ksr uqNaCl
foy ; u dsl kFk fey k; k t kr k gS A bl r j g cuk l Qsn
vo{ksi ?kq y u' khy gksr kgS&
(A) r uqHNO3 es a (B) l kUnzNaCl foy ; u esa
(C) Na2S2O3 foy ; u es a (D) KCN foy ; u esa

SECTION - C SECTION - C
[MATCH THE COLUMN TYPE] [l q
esy u l q
phi zd kj ]
Match the entries in Column - I with the entries in Lr EHk- I dhi zfo"Vh; ksdkLr EHk - II dhi zfo"Vh; ksadsl kFkl q
esy u
Column- II. One or more entries in Column - I may dhft ; sALr EHk- I es, d ; k, d l svf/kd i zfo"Vh; kaLr EHk- II ds
match with one or more entries in Column - II.
, d ; kvf/kd i zfo"Vh; ksadsl kFkl q
esfy r gksl dr hgSA
1. Match the column
Column-I
1. Lr EHk l q
esfy r dhft , A
Lr EHk-I
3 O
(A) CH3 – CH  CH2 
  (U)  ( V ) 3 O
Zn (A) CH3 – CH  CH2 
  (U)  ( V )
Zn
CH3
| CH3
O3
(B) CH3  C  CH  CH3 
 ( W )  ( X) |
O3
Zn (B) CH3  C  CH  CH3 
 ( W )  ( X)
Zn
O
|| O
H O ||
(C) Ph – C – O – Ph 3 
 ( Y )  ( Z ) H O
(C) Ph – C – O – Ph 3 
 ( Y )  ( Z )
CH3
| CH3
O3
(D) CH3  C  CH  C2H5 
 ( W )  ( X) |
O3
Zn (D) CH3  C  CH  C2H5 
 ( W )  ( X)
Zn

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Column-II Lr EHk-II
(Product differentiate by) (mR i kn fuEu } kj kvodfyr (differentiate) gksrkgS
)
(P) By Haloform test (P) gs y ksQkW
eZi j h{k.k} kj k
(Q) By Fehling test (Q) Qs gfy ax i j h{k.k} kj k
(R) By aq. NaHCO3 (R) t y h; NaHCO3 } kj k
(S) By Tollen Test (S) VkW y su i j h{k.k} kj k
(T) By Br2/CCl4 (T) Br2/CCl4 } kj k

2. fuEu dkfey ku dhft , &

2. Match the following : Lr EHk-I
Column-I
(PAIR OF COMPLEXES) (l adqy dk; q Xe)
(A) [ Fe(CN) 6]3– & [Mn(CN)6]3– (A) [Fe(CN)6]3– r Fkk[Mn(CN)6]3–
(B) [Fe(H2O)6]2+ & [Fe(CN)6]4– (B) [Fe(H2O)6]2+ r Fkk[Fe(CN)6]4–
(C) [Ni(CN)4]2– & [Ni(CO)4] (C) [Ni(CN)4]2– r Fkk[Ni(CO)4]
(D) [Ni(H2O)6]2+ & [NiCl4]2– (D) [Ni(H2O)6]2+ r Fkk[NiCl4]2–
Column-II
(Property which is similar in given pair) Lr EHk-II
(P) magnetic moment (fo' ks
"kr kt ksfn, x, ; q Xe esal eku gksrhgS
A)
(Q) Geometry (P) pq Ecdh; xfr (Q) T; kfefr
(R) Hybridisation (R) l a d j .k
(S) Number of d electrons at central atom (S) ds fUnz; i j ek.kqesad by sDVªkW
u dhl a
[;k
(T) EAN (T) EAN

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