TM

TEST PAPER _ 13th (ACCELERATION)

[FORMAT - 1]

ADVANCED PATTERN TEST_BATCH - V1,V3,V5

[ PAPER - 1 ]
Date : 16 - 08 - 2020 Duration: 3 Hours Max. Marks : 264
_______________________________________________________________________________________________
INSTRUCTIONS
In each part of the paper, Section-A contains 8 questions, Section - B contains 10 questions & Section-C
contains 2 questions. Total number of pages are 24. Please ensure that the Questions paper you have
received contains ALL THE QUESTIONS in each section and PAGES.
SECTION - A
Q.1 to Q.8 are Integer answer type questions (whose answer is 1 digits [0 to 9]) & carry 4 marks
each. No Negative Marking.
SECTION - B
Q.1 to Q.10 are Multiple choice Questions has four choices (A), (B), (C), (D) out of which one or more
than one is/are correct & carry 4 marks each. 2 mark will be deducted for each wrong answer.
SECTION - C

Q.1 & Q. 2 are "Match the Column" Type questions and you will have to match entries in column - I with
the entries in Column - II. One or More entries in Column - I may match with one or more entries of
Column - II. For each entry in Column - I, + 2 for correct answer, 0 if not attempted and – 1 in all other
cases.

NOTE : GENERAL INSTRUCTION FOR FILLING THE OMR ARE GIVEN BELOW.

1. Use only blue/black pen (avoid gel pen) for darkening the bubble.

2. Indicate the correct answer for each question by filling appropriate bubble in your OMR answer sheet.

3. The Answer sheet will be checked through computer hence, the answer of the question must be marked by
shading the circles against the question by blue/black pen.

4. While filling the bubbles please be careful about SECTIONS [i.e. Section-A (include Integer type), Section
- B [Multiple type] & Section-C (Comprehension type)].

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 (ADVANCED PATTERN) | Page # 2

PART - I [MATHEMATICS]

SECTION - A SECTION - A
[INTEGER ANSWER TYPE] [ fo' y s
"k.kkRed i z'u i zd kj ]
Q.1 to Q.8 are INTEGER ANSWER TYPE Questions. i z-1 l si z-8 r d fo' y s"k.kkRed i z'u gS A¼i zR; sd i z'u dkmÙkj dsoy
(The answer of each of the questions is 1 digits) 1 va d ksesnhft ; sA
1. f (x) and g (x)  are linear function such that 1. f (x) r Fkkg (x) l Hkhx dsfy ; sj s[kh; Qy u bl çdkj
for all x, f g ( x )  and g  f ( x )  are Identity gSfd f g ( x )  , oag  f ( x )  r Rl ed Qy u gS A ; fn
functions. f (0) = 4 r Fkkg (5) = 17 gS ] r ksf (68) dkeku Kkr
If f (0) = 4 and g (5) = 17, compute f (68).
dhft ; sA

2. If ,  and  are the roots of the equation 2. ; fn ,  r Fkk  l ehdj .k x3 – 3x2 – x – 1 = 0

1 1
x3 – 3x2 – x – 1 = 0 and f(x) = x – –2 dsew
y gS
ar Fkk f(x) = x – – 2 gS
] r ks f()·
x2 x2
f( )· f() dk eku Kkr dhft , A
then find the value of f()· f( )· f().

3. The number of solutions of x 2 2

3. sin    2x  x    1 dsgy ksadhl a
[ ; kgksuh
2
 
x 2 2
sin    2x  x    1 must be ........... pkfg, &
2

4. Let f be a real valued function defined by 4. ekuk f , d okLr fod eku Qy u gS t ks

e x  e |x| e x  e |x|
f(x) = x , range of f is [a, b), then f(x) = } kj k i fj Hkkf"kr gS
A f dk i fj l j
e  e|x| e x  e|x|
find the value of (5a + 4b). [a, b) gS
, r ks(5a + 4b) dkeku Kkr dhft ; s
A
(SPACE FOR ROUGH WORK)

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lQyrk vR;f/kd ifjJe pkgrh gSA

 (ADVANCED PATTERN) | Page # 3

5. Let f(x) = {(0.1)3[x]}. (where [.] denotes 5. ekuk f(x) = {(0.1)3[x]} gS(t gk¡ [.] egÙke i w
. kkZ
a
d
greatest integer function and {.} denotes
Qy u r Fkk {.} fHkUukRed Hkkx Qy u dksn' kkZ
r sgS) ; fn
fractional part) If f(x + T) = f(x)  x  0,
f(x + T) = f(x)  x  0 t gk¡T , d fuf' pr /kukRed
where T is a fixed positive number then the
la
[ ; k gS
] r c T dk U; w
ur e eku gS&
least value of T, is

6. The sum of all the real numbers satisfying 6. l ehdj .k x2 +|x–1| = 1 dksl a
rq
"V dj usoky sl Hkh
the equation x2 +|x–1| = 1 is .......... okLr fod l a
[ ; kvksadk; ksx gksxk&

7. If the rang e of t he funct i on x2  ax  b

7. ; fn Qy u f(x) = dk i fj l j [–5,4],
x2  2x  3
x2  ax  b
f(x) = 2 is [–5,4], a,b  N, then the
x  2x  3 a,b  N gS
, r c a–b dk eku gS&
value of a–b is _____.

x 2  y2  1 x 2  y2  1
8. If sin2 = then (x + 1)(y + 2) = ? 8. ; fn sin2  = gks]r ks(x + 1)(y + 2) = ?
2x 2x

SECTION - B SECTION - B
[MULTIPLE OBJECTIVE TYPE] [ cgqoS
d fYi d i z'u i zd kj ]
Q.1 to Q.10 has four choices (A), (B), (C), (D) out
i z-1 l si z-10 esapkj fodYi (A), (B), (C), (D) gS
] ft uessal s^^, d
of which ONE OR MORE THAN ONE is correct
; k, d l svf/kd^^ l ghgS
A

(SPACE FOR ROUGH WORK)

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 (ADVANCED PATTERN) | Page # 4

   3x      3x  
1. Let f (x ) = cos 2 x    sin   . 1. ekuk f (x) = cos 2x    sin    gS
] r ks
 3  2 4  3  2 4
Which of the following statement(s) is/are fuEu esal sdkS
ul k@dkS
ul sdFku l R; gS?
CORRECT? (A) Qy u f (x) dk vkor Zd ky 4gSA
(A) Fundamental period of the function f (x)
is 4.
(B) [– , ] esax dsekuksadh l a[ ; k ft l dsfy ; s
(B) Number of values of x in [– , ] for f (x) = 0, 4 gS A
which f (x) = 0, is 4
(C) l ehdj .k f (x) = 2 dsgy ks
adhl a
[ ; k t ksva
r j ky
(C) Number of solutions of the equation f (x)
[0, 2] es
afLFkr gS] 1 gS
A
= 2 which lie in the interval [0, 2], is 1.
(D) Number of solutions of the equation f (x) (D) l ehdj .k f (x) = 2 dsgy ks
adhl a
[ ; k t ksva
r j ky
= 2 which lie in the interval [0, 2], is 4. [0, 2] es
afLFkr gS] 4 gS
A

2. If f : R – {–1, k}  R – {,  } is a 2. ; fn f : R – {–1, k}  R – {,  } , d

bijective function defined by , dSd h&vkPNknd (bijective) Qy u gS
] t ks

(2 x  1) (2 x 2  4 px  p 3 ) (2 x  1) (2 x 2  4 px  p 3 )
f(x) = (where p  f(x) = (t gk¡ p  0)
( x  1) (x 2  p 2 x  p 2 ) ( x  1) (x 2  p 2 x  p 2 )

0), then identify which of the following } kj ki fj Hkkf"kr gS

] r ksfuEu esal sl R; dFku@dFkuksadkp; u
statement(s) is(are) correct? dhft ; sA
(A) If k  (–1, 1) then  +  = 2 (A) ; fn k  (–1, 1) gS ] r ks +  = 2
(B) If k  (–1, 1) then  +  = 6 (B) ; fn k  (–1, 1) gS ] r ks +  = 6
(C) If k  (1, 3) then  +  = 4 (C) ; fn k  (1, 3) gS ] r ks +  = 4
(D) If k  (1, 3) then  +  = 6 (D) ; fn k  (1, 3) gS ] r ks +  = 6
(SPACE FOR ROUGH WORK)

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viuh “kfDr;ksa ij Hkjkslk djus okyk dHkh vlQy ugh gksrk A

 (ADVANCED PATTERN) | Page # 5

3. The expression

1  3. t cx= gks] r c O
;atd
12
(tan4x+2tan2x+1) × 2 when x =
1  tan x 12 1
can be equal to ( tan4x + 2tan2x + 1) d keku fuEu esa
1  tan 2 x
(A) 4( 2  3 ) (B) 4( 2  1) l sfd l d scj kcj gS
(A) 4( 2  3 ) (B) 4( 2  1)
 
(C) 16cos2 (D) 16sin2  
12 12 (C) 16cos2 (D) 16sin2
12 12
4. Suppose that the three quadratic equations
ax2 – 2bx + c = 0, bx2 – 2cx + a = 0 and
4. ekuk fd r hu f} ?kkr l ehd j .ksaax2 – 2bx + c = 0,
cx2 – 2ax + b = 0 all have only positive bx2 – 2cx + a = 0 , oacx2 – 2ax + b = 0 es al Hkh
roots. Then d sd soy /kukRed ew y gS] r ks
(A) b2 = ca (B) c2 = ab (A) b2 = ca (B) c2 = ab
2
(C) a = bc (D) a = b = c (C) a2 = bc (D) a = b = c

1 x 
5. If f 2(x) · f   = x3  x  R – {–1, 1} 1 x 
 1 x  5. ; fn f 2(x) · f   = x3  x  R – {–1, 1}
 1 x 
and f(x)  0, then which of the following is
r Fkk f(x)  0 gS
] r ksfuEu esal sdkS
ul sl R; gS
a\
correct.
(A) f(2) · f(–2) = 16 (B) f (2) f(–2) = 8
(A) f(2) · f(–2) = 16 (B) f (2) f(–2) = 8
(C) f (2) = –12 (D) f (3) = –18
(C) f (2) = –12 (D) f (3) = –18

(SPACE FOR ROUGH WORK)

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ckj ckj vlQy gksus ij Hkh mRlkg uk [kksuk gh lQyrk gSA

 (ADVANCED PATTERN) | Page # 6

6. Let f (x) = x3 + x – 3 and y = g (x) & 6. ekuk f (x) = x3 + x – 3 gSr Fkk y = g (x) , oa
y = h (x) be two functions such that
y = h (x) nksQy u bl çdkj gSfd gf ( x )  = x
gf ( x )  = x and h gg(x) = x then which
r Fkk h gg(x) = x gS
] r c fuEufy f[ kr esal s
of the following is(are) CORRECT ?
(A) g (–1) = 1 (B) g (7) = 2 dkS
ul k@dkS
ul sl ghgS
a\
(C) h (1) = – 5 (D) h (0) = – 33 (A) g (–1) = 1 (B) g (7) = 2
(C) h (1) = – 5 (D) h (0) = – 33

7. Let  > 0,  > 0 be roots of the equation 7. ekuk > 0,  > 0 l ehdj .k x2 + px + q = 0 ds
1 1
x2 + px + q = 0. Also, ,  are the roots of ewy gSA ,  l ehdj .k x2 + p1x + q1 = 0 dsew y
 
1 1
x2 + p1x + q1 = 0 and , are roots of x2 gSr Fkk, l ehdj .k x2 + p2x + q2 = 0 dsew y gS
]
 
+ p2x + q2 = 0. Which of the following r ksfuEu esal sdkS
ul k@dkS
ul sl EcU/kl R; gS
relations is(are) correct?
(A) q1 q2 = 1
(A) q1 q2 = 1
p
p (B) p1 + p2 = (q + 1)
(B) p1 + p2 = (q + 1) q
q

(C) q q 2  p q2  q = 0
(C) q q 2  p q2  q = 0
(D) (qp1 – qp2)2 = (p2 – 4q) (q + 1)2
(D) (qp1 – qp2)2 = (p2 – 4q) (q + 1)2

(SPACE FOR ROUGH WORK)

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 (ADVANCED PATTERN) | Page # 7

8. In which of the following interval(s) the value 8. fuEu esal sdkS

ul svUr j ky @vUr j ky ksaesaO
;a
td
of the expression
y = 2( 2  1) sin x  2 cos 2 x  2  2 dk eku
7y = 2( 2  1) sin x  2 cos 2 x  2  2 i s
_ .kkRed gS?
negative?
   
    (A)  ,  (B)  0, 
(A)  ,  (B)  0,  6 2  6
6 2  6
 5 5   7 
 5 5   7  (C)  ,  (D)  , 2 
(C)  ,  (D)  , 2   6 4   4 
 6 4   4 

9. Let
9. ekuk l Hkh okLr fod l a[ ; kv ksa r d s fy ,
 n    
2 cos 2  r    2 sin  mr   cos mr   = 1 2 n    
 2  2  2 2 cos  r    2sin mr   cos mr   = 1 gS
]
for all real numbers r, then  2  2  2
rc
 3
(A) m = 1 (B) n =  3
2 (A) m = 1 (B) n =
2
3
(C) m = – 1 (D) n = 3
2 (C) m = – 1 (D) n =
2
5
1 5
1
10. The value of  sin( k  1) · sin( k  2) is 10.  sin( k  1) · sin( k  2) dk eku gS
k 1 k 1
(A) positive (B) negative
(A) /kukR
ed (B) _ .kkRed
cot 2  cot 7 tan 2  tan 7
(C) (D) cot 2  cot 7 tan 2  tan 7
sin 1 sin 1 (C) (D)
sin 1 sin 1
(SPACE FOR ROUGH WORK)

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eqf'dys oks phtsa gksrh gS] tks gesa rc fn[krh gS tc gekjk /;ku y{; ij ugha gksrkA
 (ADVANCED PATTERN) | Page # 8

SECTION - C SECTION - C
[MATCH THE COLUMN TYPE] [l q ph i zd kj ]
esy u l q
k- I dhi zfo"Vh; ksdkLr EHk - II dhi zfo"Vh; ksadsl kFkl q
Match the entries in Column - I with the entries in Lr EH esy u
Column- II. One or more entries in Column - I may dhft ; s ALr EHk- I es, d ; k, d l svf/kd i zfo"Vh; kaLr EHk- II ds
match with one or more entries in Column - II. , d ; kvf/kd i zfo"Vh; ksadsl kFkl q
esfy r gksl dr hgS
A

1. Let f(x)=x 2 –2px+p 2 –1. Then match the 1. ekukf(x)=x2–2px+p2–1 gS

Ar c fuEu l w
fp; ka
sdkfeyku
following lists : dhft , &
List I List II
lw
phI lw
phII
(A) both the roots of (P) (–1,)
(A) f(x) = 0 dsnks
uksew
y 4l sde gS (P) (–1,)
f(x)=0 are less than 4, if p 
; fn p 
(B) both the roots of f(x)=0 are (Q) (–,3)
(B) f(x)= 0 dsnks
uksew
y –2 l svf/kd gS(Q) (–,3)
greater than –2 if p 
; fn p 
(C) exactly one root of f(x)=0 (R) (0,2)
(C) f(x) = 0 dk Bhd , d ew
y (–2,4) (R) (0,2)
lies in (–2,4) if p 
esafLFkr gS
] ; fn p 
(D) 1 lies between the roots of (S) (–3,–1)
(D) 1, f(x) = 0 dsew
y ksadse/; fLFkr gS
] (S) (–3,–1)
f(x)=0, if p  (3,5)
; fn p  (3,5)

(SPACE FOR ROUGH WORK)

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 (ADVANCED PATTERN) | Page # 9

2. Column - I 2. Lr EHk - I
(A) The value of tan 40   ta n 1 0 0   tan 1 6 0 
ta n 20  tan 40  tan 80 
(A) tan 40   ta n 1 0 0   tan 1 6 0  dk eku gS&
ta n 20  tan 40  tan 80 

(B) If  are roots of ax2 + bx + c = 0 , (B) ; fn ax2 + bx + c = 0(a0) dsew

y r Fkk
a0 and
  b2
  , , , x2 – 3x + 1 = 0 dsew
y gS
] r c dkeku
, are roots of x2 – 3x + 1 = 0   ac
 
gS&
2
b (C) ; fn P l ehdj .kxlnx = e2x dsgy ksadkxq
. kuQy gs]
then value of is
ac
r c P fdl l sde gS&
(C) If P is product of solutions of the equa-
tion xlnx = e2x, then P is less then (D) ; fn l
ehdj .kkx2 + 5xy + 2y2 + 3x + 3y + 1
= 0 dksnksj S
f[ k; xq
. ku[ k.Mksesa[ kf.Mr fd; kt kr kgS
]rc
(D) If the equaiton kx2 + 5xy + 2y2 + 3x + 3y
|k| dkeku fdl l svf/kd ; kcj kcj gks xk&
+ 1 = 0 can be split in two linear factors,
then the value of|k| is greater than or equal
to Lr EHk- II
(P) 6
Column - II
(Q) 5
(P) 6
(R) 3
(Q) 5
(S) 2
(R) 3
(T) 1
(S) 2
(T) 1

(SPACE FOR ROUGH WORK)

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 (ADVANCED PATTERN) | Page # 10

PART - II [PHYSICS]
SECTION - A SECTION - A
[INTEGER ANSWER TYPE] [ fo' y s "k. kkRed i z'u i zd kj ]
Q.1 to Q.8 are INTEGER ANSWER TYPE Questions. (The
i z-1 l si z-8 r d fo' y s"k.kkRed i z'u gS A¼i zR; sd i z'u dkmÙkj dsoy
answer of each of the questions is 4 digits)
d ksesnhft
4 va ; sA
1. A stone A is dropped from rest from a height
h = 10 m above the ground. A second stone 1. , d i RFkj A dks/kj kr y l sh = 10 m Å¡pkbZl sfoj ke l s
B is simultaneously thrown vertically up with fxj k; kt kr kgSA, d f} r h; i RFkj B ml hl e; i j v osx l s
velocity v. Find the value of v (in m/s) which Å/okZ /kj Åi j dhvksj Qsad kt kr kgSAv dkog eku (m/s es )a
would enable the stone B to meet the stone Kkr dhft ; s] t ksi RFkj B dksi RFkj A l smudh i zkj fEHkd
A midway between their initial positions.
fLFkfr ; ksadschp e/; j kLr sesafeykusesal eFkZcuk; sxkA
2. James bond is standing on a bridge above
the road below and his pursuers are getting 2. t sEl ckW
. M uhpsl M+ d dsÅi j , d i q y i j [ kM+
k gSr Fkk
too close for comfort. He spots a flat bed ml dsvuq ; k; hvkj ke dsfy , cgq r dj hc vkj gsgS Aog 30
truck loaded with mattresses approaching at m/s l sdj hc vkusoky sxíks al sHkj sa, d l er y fcLr j
30 m/s which he measures by knowing that (bed) dsVªd i j ns [ kr k (spots) gS ] ft l sog ; g
the telephones poles the truck is passing are t kudkj eki r kgSfd Vªd ft l Vsy hQksu [ kEHkksal sxq t j j gk
20 m apart in this country. The bed of truck
is 20m below the bridge and bond quickly gS] og bl ns'k esa20 m i F̀kd gS A Vªd dk fcLr j i q y ls
calculates how many poles away the truck 20m uhpsgSvkS j ckW. Mt Ynhl sx.kukdj r kgSfd Vªd dks
should be when he jumps down the bridge fdr us[ kEHkksadhnw j hi j gksukpkfg; s]t c og Vªd i j i q y
onto the truck making his get away. How l suhpsdw nr kgSft l l sog nw j (get away) gkst kr kgS A
many poles is it ? ; g fdr us[ kEHksagS?
3. A stone is dropped from the top of building 3. , d i RFkj , d bZ ekj r ds' kh"kZl sfxj k; k t kr k gSr Fkk
and at the same time a second stone is thrown
vertically upward from the bottom of the
Bhd ml h l e; , d nw l j k i RFkj bZekj r dsvk/kkj l s
building with a speed of 20 ms–1. They pass 20 ms–1 dhpky l sÅ/okZ /kj Åi j dhvksj Qsa d kt kr kgS
A
each other 3 seconds later. Find the height 3l S d .Mi ' pkr ~os, d&nwl j sdksi kj dj r sgS
a
AbZ ekj r dh
(h) of the building (in 'm'). Fill h/10 in OMR Å¡pkbZ(h) ('m' esa ) Kkr dhft ; s A OMR ' khV esah/10
sheet. Hkfj ; sA
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4. A stone is dropped from a balloon moving 4. , d i RFkj 4.5 m/s dsosx l sÅi j dhvksj xfr eku , d
upwards with velocity 4.5 m/s. The stone xqCckj sl sfxj k; k t kr k gS
A i RFkj /kj kr y i j 5 l S
d .M esa
reaches at ground in 5 sec. calculate the
height (in meter) of the balloon when stone
i gq¡p r k gSA xqCckj s d h og Å¡p kbZ ( ehVj esa)
was dropped. (Take g = 9.8 m/s2) i fj dfy r dhft ; s] t c i RFkj fxj k; k x; k FkkA (fy ft ; s
g = 9.8 m/s2)
5. An astronaut on the starship Enterprise is
5. LVkj f' ki , a
Vj i zkbZ
t i j , d va
r fj {k; k=kh, d nwj LFkxzg i j
roaming around on a distant planet. He drops
a rock from the top of a cliff and observes pkj ksa
v ksj ?kw
e j gkgS Aog , d Vhy s(cliff) dsf' k[ kj l s, d
that it takes time t1 = 2 sec to reach the pêku dksfxj kr k gSr Fkk i zsf{kr dj r k gSfd ; g r y hr d
bottom. He now throws another rock vertically i gqa
pusaesat1 = 2 sec dkl e; y srhgS A vc og Å/okZ /
upwards so that it reaches a height h = 10 m kj Åi j dhvksj vU; pêku QS d r kgSr kfd ; g Vhysl suhps
a
above the cliff before dropping down the cliff. fxj usdsi gy sVhy sdsmi j h = 10 m Å¡pkbZi j i gq a
pr h
The second rock takes a total time t2 = 2
gSAnw l j hpêku Vhy sdhr y hr d i gq a
pusesadq y l e; t2
sec to reach the bottom of the cliff, starting
from the time it leaves the astronaut’s hand. = 2 sec y s r hgS , ml l e; l s' kq: gksd j t c og va r fj {k
The planet has a very thin atmosphere which ; k=kh dk gkFk NksM+ r h gS
A xzg dk cgq r foj y (thin)
offers negligible air resistance. What is the ok; q
e.My gSt ksux.; ok; qi zfr j ks/ki znku dj r kgS Abl xzg
value of acceleration i j xq: Ro dsdkj .kRoj .kdkeku (m/s2 esa ) Kkr dj ks?
(in m/s2) due to gravity on this planet?

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6. The position of a particle moving on x-axis is
given by, x = t3 + 4t2 – 2t + 5, SI units are
used. Then what will be the average velocity
during the interval t = 0 to t = 4 sec. What
will be the average of the instantaneous
velocities at t = 0 and t = 4 sec.
6. x-v{k i j xfr eku , d d.k dhfLFkfr x = t3 + 4t2 –
2t + 5 } kj knht kr hgS
, SI bdkbZi z;qDr dht kr hgS Ar c
t = 0 l st = 4 sec dsvU r j ky dsnkS j ku vkS
l r osx D; k
gksxkAt = 0 r Fkkt = 4 sec i j r kR{kf.kd osxksadkvkSlr
D; kgksxk &

7. A high speed Jet starts from rest at s = 0 7. , d mPp pky dkt sV (Jet), s = 0 i j foj ke l si zkj EHk
and is subjected to the acceleration shown gksrkgSr Fkkfp=kkuq
l kj Roj .kl s' kkfl r gS
A bl ds50 m
in the figure. Determine the velocity of the
py usdsi ' pkr osx dksfu/kkZ fj r dj sa-
after it has travelled 50 m.
a
a
2
2 50 m/s
50 m/s

s
s O 50m
O 50m

8. A fly had to go from one corner of the floor 8. , d eD[ kh (fly) dks, d dej sesaQ' kZds, d dksusl s
of a room to the diagonally opposite corner fod.kZ r %foi fj r Nr dsdksusr d t kukgS Adej sdhfoek, a
on the roof. The dimensions of the room are
8 m, 4 m , oa5 m gS AeD[ khughamM+ usdkfu' p; dj r h
8 m, 4 m & 5 m. The fly decides not to fly
gS] y sfdu fnokj ksai j j sa
xr h(crawl) gS A bl dsy {; r d
but to crawl along the wall. What minimum
i gqa
pusdsfy ; sbl sfdr uhU; w ur e nwj hr ; dj uhgksxhA
distance shoul d i t travel to reach its
destination? Round off your answer to nearest vi usmÙkj dksfudVr e i w . kk±
d esanksA
integer.

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SECTION - B SECTION - B
[MULTIPLE OBJECTIVE TYPE] [ cgqoS
d fYi d
i z'u i zd kj ]
Q.1 to Q.10 has four choices (A), (B), (C), (D) out i z-1 l si z-10 esapkj fodYi (A), (B), (C), (D) gS
] ft uessal s^^, d
of which ONE OR MORE THAN ONE is correct
; k, d l svf/kd^^ l ghgS
A

1. A calorimeter of water equivalent 50 g 1. 50 g t y rq

Y; ka
d dk, d dS
y ksjhehVj 30°C i j 100g
contains 100 g water at 30°C. In each of
the situations, select the option(s) that t y j [ kr kgS
A i zR; sd fLFkfr esa
] ml fodYi dkspq
fu; st ks
indicate the correct final temperature.
l ghvfUr e r ki dkscr kr kgS
A
(A) 15 g of ice at –20°C ; final temperature
210/11°C (A) –20°C i j 15g cQZ; vfU
r e r ki 210/11°C
(B) 5 g of steam at 100°C ; final tempera-
ture 1540/31°C (B) 100°C i j 5g H
kki ; vfUr e r ki 1540/31°C
(C) 80 g of water at 70°C ; final temperature (C) 70°C i j 80g t y ] vfUr e r ki 430/9°C
430/9°C
(D) 15 g of ice at 0°C ; final temperature (D) 0°C i j 15g cQZ; vfUr e r ki 20°C
20°C

2. We have three pieces of materials and we 2. gekj si kl r hu i nkFkksZdsVqd M+sgSar Fkkgesai zR;sd Vq
d M+ sdks
are required to heat each of them from 15°C
15°C l s65°C r d xeZdj usdhvko' ; dr kgS\ i z R; sd
to 65°C? Choose the correct amount of heat
required for each of the case. The specific fLFkfr ds fy ; s vko' ; d Å"ek dh l gh ek=kk pq fu; sA
heats, in cal/g·° C, for aluminium, Pyrex, and , Y; w
fefu; e] i kbj sDl r FkkIy sVhue dsfy ; s(cal/g·° C
pl ati num are 0.21, 0.20, and 0.032, esa
½fof' k"V Å"ek; saØe' k%0.21, 0.20, r Fkk0.032 gS a
A
respectively
(A) 3.0 g ,Y; w fefu; e dks31.5 dS y ksjhdhvko' ; dr kgksrhgSA
(A) 3.0 g of aluminium requires 31.5 cal
(B) 5.0 g of Pyrex glass requires 50 cal (B) 5.0 g i kbj s Dl dka p dks50 dS y ksjhdhvko' ; dr kgksrhgSA
(C) 20 g of platinum requires 32 cal. (C) 20 g Iys Vhue dks32 dS y ksjhdhvko' ; dr kgksrhgS A
(D) 5.0 g of Pyrex glass requires 5 cal (D) 5.0 g i kbj s Dl dka p dks5 dS y ksjhdhvko' ; dr kgksrhgS A

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3. 50 gm ice at – 10°C is mixed with 10gm steam 3. –10°C i j 50 gm cQZdks100°C i j 10 gm H

kki ds
at 100°C. When the mixture finally reaches
l kFk fefJr fd; k t kr k gS A t c feJ.k 1.5 gm t y
its steady state inside a calorimeter of water
equivalent 1.5 gm then : [Assume calorimeter rqY; ka
d dsdS y ksjheki hdsHkhr j vUr esabl dhLFkk; hvoLFkk
was initially at 0°C, Take latent heat of i j i gq¡p t kr kgS ] r ks: [ekukfd dS y ksjheki hi zkj EHkesa0°C
vaporization of water = 540 cal/gm, Latent i j Fkk] t y dsok"i u dhxq Ir Å"ek= 540 cal/gm, t y
heat of fusion of water = 80 cal/gm and dsxy u dh xq Ir Å"ek = 80 cal/gm r Fkk t y dh
specific heat capacity of water = 1 cal/gm-
°C, specific heat of ice = 0.5 cal/gm°C] fof' k"V Å"ek /kkfj r k = 1 cal/gm-°C, cQZdhfof' k"V
(A) Mass of water remaining is : 60 gm Å"ek= 0.5 cal/gm°C fyft ; s]
(B) Mass of ice remaining is : 3 gm (A) ' ks "k t y dk nzO ; eku : 60 gm
(C) Mass of steam remaining is : 1.20 gm (B) ' ks "kcQZdk nzO ; eku : 3 gm
(D) Final temperature is between 0°C and
(C) ' ks "kHkki dknzO ; eku : 1.20 gm
100°C
(D) vfU r e r ki 0°C o 100°C dse/; gksrkgS A

4. Two thermometers, one containing mercury 4. nksr ki eki h] , d esai kj kr Fkk nwl j sesafLi zV gS
] l eku r ki
and another spirit read same temperature.
The mercury thermometer has a lower
i <+ r sgS
Ai kj sdsr ki eki hdhmRl t Z d r kfLi zV r ki eki hdh
emissivity than spirit thermometer. Both have mRl t Z d r kl sde gS Anksuksal eku {ks=kQy r Fkkm"ek/kkfj r k
the same area and heat capacity. If both j [ kr sgSA ; fn nksuksadkspedr sl w ; Zesay k; kt k, r ks&
are brought in bright sun. (A) nks uksaesal eku nj l sr ki esaof̀) gksrhgS A
(A) The temperature rises at equal rate in
(B) fLi z V r ki eki hesamPp nj l sr ki c<+ r k gS
A
both.
(B) The temperature rises at higher rate in (C) nks uksaesavafr e fLFkj voLFkkdkr ki l eku gksrkgS
spirit thermometer. (D) va fr e fLFkj voLFkkdk r ki fLi zV r ki eki hesavf/kd
(C) Final steady state temperature will be gksrkgS
the same in both.
(D) Final steady state temperature will be
higher in spirit thermometer.

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5. Refer to the plot of temperature versus time 5. xeZdj usi j cQZdhvoLFkkesai fj or Z
u n' kkZ
usokysr ki &l e;
(figure) showing the changes in the state of
ice on heating (not to scale). Which of the dsoØ ¼ fp=k½dksnsf[ k; sA ¼
iS
ekusi j ughagS ½A fuEu esal s
following is correct? dkS
ul kl ghgS \

(A) The region AB represents ice and water (A) {kS

=kAB cQZo t y dsr ki h; l kE; esagksusdksn' kkZr kgS
in thermal equilibrium. (B) B i j t y mcy usy xr k gS
(B) At B water starts boiling. (C) C i j l Ei w
. kZt y Hkki esa: i kUr fj r gkst kr kgS
(C) At C all the water gets converted into steam.
(D) C l sD DoFkuka d fcUnqi j t y o Hkki dsl kE; esagksus
(D) C to D represents water and steam in
equilibrium at boiling point. dksn' kkZ
r kgS

6. Consider the shown case of a freezing lake 6. ekuk fd fp=k esan' kkZ , vuq
l kj , d >hy okr koj .k ds
due to negative environmental temperature _ .kkRed r ki (–°C) dsdkj .k t e xbZgS A >hy dh
(–°C). Thickness (x) of ice layer is small in xgj kbZdhr qy uk esacQZdhi j r dheksVkbZ
. (x) de gS A
comparison to depth of lake. Rate of increase
x esaof̀) dhnj c<+ sxhA
in x will be greater

(A) if environmental temperature increases (A) ; fn okr koj .kdsr ki es

aof̀) gks
(B) for larger thickness of ice layer (B) cQZdhi j r dhvf/kd eks VkbZdsfy ; s
(C) if environmental temperature decreases (C) ; fn okr koj .kdsr ki es
adehgks
(D) for smaller thickness of ice layer (D) cQZdhi j r dhde eks VkbZdsfy ; s

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7. Three rods of length 3m, 2m and 1m, area 7. 3m, 2m o 1m y EckbZdhr hu NM+
saft =Qy Øe'k%
uds{kS
1mm2, 2mm2 and 3mm2, thermal conductivity
3
3 2 1 1mm2, 2mm2 o 3mm2 r Fkk r ki h; pky dr k
W/mk, W/mk and W/mk respectively 2
2 3 4
are joined between 2 reservoirs at 100°C and 2 1
0° C i n p aral l e l . C hoos e the correc t W/mk, W/mk o W/mk gS
] l ekUrj esa100°C
3 4
statement(s).
(A) Their thermal resistance are in ratio o 0°C i j j [ ksnksÅ"ek' k; ksadschp t ksM+
ht kr hgS
a
A l gh
12 : 9 : 8 dFku@uksadkp; u dhft ; sA
(B) Their temperature gradient are in ratio
(A) mudsr ki h; i zfr j ks/kksadk vuq
i kr 12 : 9 : 8 gS
A
2:3:6
(C) The temperature at their mid points are (B) mudhr ki h; i zo.kr k dk vuq
i kr 2 : 3 : 6 gS
A
in ratio 6 : 3 : 2 (C) mudse/; fcUnq
v ksai j r ki ksadkvuq
i kr 6 : 3 : 2 gS
A
(D) The heat flown through them are in ratio
(D) mul si zokfgr Å"ek dk vuq
i kr 6 : 8 : 9 gS
A
6:8:9

8. At 0°C a body emits: 8. 0°C i j , d oLr qmRl ft Z

r dj r hgS
&
(A) no radiation (A) dks
bZfofdj .kugh
(B) electromagnetic radiation of single
(B) , dy rja
xnS
/; Zdhfo| q
r pq
Ecdh; fofdj .k
wavelength
(C) electromagnetic radiation of all wave (C) dej sdsr ki i j oLr ql smRl ft Z
r l Hkhr j a
xnS
/; Zdh
lengths that are emitted by it at room fo| q
r pq
Ecdh; fofdj .k
temperature.
(D) dej sdsr ki i j oLr ql smRl ft Z
r gksusoky hfofdj .kksa
(D) electromagnetic radiations of lesser total
energy than are emitted by it at room
l sde dq
y mt kZoky hfo| q
r pq
Ecdh; fofdj .k
temperature.

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9. A metal cylinder of mass 0.5 kg is heated 9. 0.5 kg nz

O
; eku dk, d /kkfRod csy u 15°C i j , d dej sa
electrically by a 12 W heater in a room at esa12 W dsghVj } kj kfo| q
r : i l sxeZfd; kt kr kgS
A; fn
15°C. The cylinder temperature rises uniformly csy u dkr ki eku , dl eku : i l s5 feuV esa25°C r d
to 25°C in 5 min and finally becomes constant
c<+r k gSr Fkk vUr esa45°C i j fu; r gkst kr k gSA ; fn
at 45°C. Assuming that the rate of heat loss
Å"ek á l dhnj dksokr koj .k dsr ki kUr j dsl ekuq i kr h
is proportional to the excess temperature over
the surroundings,
ekukx; kgksr ksA
(A) the rate of loss of heat of the cylinder to (A) cs y u dh 20°C i j okr koj .k esÅ"ek á l dh nj
surrounding at 20°C is 2W 2W gS
(B) the rate of loss of heat of the cylinder to (B) cs y u dh 45°C i j okr koj .k esÅ"ek á l dh nj
surrounding at 45°C is 12W 12W gS
(C) the rate of loss of heat of the cylinder to (C) cs y u dh 20°C i j okr koj .k esÅ"ek á l dh nj
surrounding at 20°C is 5W.
5W gS
(D) the rate of loss of heat of the cylinder to
(D) cs y u dh45°C i j okr koj .k esÅ"ek á l dhnj
surrounding at 45°C is 30W.
30W gS

10. When we consider convection with radiation 10. t c ge U; wVu ds' khr y u dsfu; e esafofdj .k dsl kFk
in Newton's law of cooling while temperature laogu i j fopkj dj r sgS
] t cfd oLr qdkr ki okr koj .kds
of the object in consideration is slightly higher r ki l sdq
N T; knkgksrkgS Ar c m"ekgkfu dhnj dsfy ; s
than the environment temperature. Choose
l ghdFku dkp; u dj ks&
correct statements about rate of heat loss
(A) mR ltZd r kdsl ekuqi kr hgksrkgS
(A) directly proportional to emissivity
(B) LVhQu dsfu; r ka d dsl ekuq i kr hgksrkgS
(B) directly proportional to Stefan's constant
(C) directly proportional to surface area (C) l r gh{ks
=kQy dsl ekuq i kr hgksrkgS
(D) directly proportional to temperature (D) oLr q, oadej s
adsr ki kUr j dsl ekuq i kr hgksrkgS
difference of body and room

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SECTION - C SECTION - C
[MATCH THE COLUMN TYPE] [l qesy u l qphi zd kj ]
k- I dhi zfo"Vh; ksdkLr EHk - II dhi zfo"Vh; ksadsl kFkl q
Match the entries in Column - I with the entries in Lr EH esy u
Column- II. One or more entries in Column - I may dhft ; sALr EHk- I es, d ; k, d l svf/kd i zfo"Vh; kaLr EHk- II ds
match with one or more entries in Column - II. , d ; kvf/kd i zfo"Vh; ksadsl kFkl q
esfy r gksl dr hgS
A

1. A vessel at –5°C contains 100 gm ice at – 1. –5°C ds, d i k=kes a–5ºC dh100 gm cQZHkj hgS Ai k=
5°C. The vessel has water equivalent of 40 40 gm dkt y r q Y; ka
d j [ kr kgS
Al w
ph-1 easfey k; sx; s
gm. List-1 gives quantity and temperature i nkFkZdhek=ko r ki fn; sx; sgS Al w
a ph-2 feJ.kdkvfUre
of substance added. List-2 gives fi nal r ki o l a
?kVu dksn' kkZr hgS
ALr EHkksadkfey ku dhft ; sA
temperature and composition of mixture.
Match the column.
lw ph-I
List-I P. 30ºC i j 10 gm t y
P. 10 gm water at 30°C Q. 10ºC i j 4 gm t y
Q. 4 gm water at 10°C R. 100ºC i j 1 gm H kki
R. 1 gm steam at 100°C S. 100ºC i j 20 gm H kki
S. 20 gm steam at 100°C
List-II
lwph-II
1. Temperature > 0°C 1. r ki eku > 0°C
2. Temperature = 0°C, Ice partly melts 2. r ki eku = 0°C, cQZvka f' kd : i l sfi ?ky r kgS
3. Temperature < 0°C 3. r ki eku < 0°C
4. Added water freezes partly. 4. fey k; kx; k t y vka
f' kd : i l st e t kr kgS
Temperature = 0°C
r ki eku = 0°C
2. Entries in column I consists of diagrams of 2. Lr EHk&I esar ki h; pky d dsfp=kksadhi zfof"V gS Apky d dk
thermal conductors. The type of conductor i zd kj r Fkk Å"ek i zokg dh fn' kk mudsuhpsl w phc) gS A
& direction of heat flows are listed below.
Entries in column II consists of the magnitude
Lr EHk&II esaLr EHk&I dhfdl hi zfof"V dsfy ; sÅ"eki zokg
of rate of heat flow belonging to any of the dhnj dsi fj ek.kdkeku fn; kx; kgS A; fn r ki kUr j l Hkh
entries in column I. If temperature difference fLFkfr ; ksaesa(T1 – T2) gS] r ksLr EHkksadk fey ku dj ksA
in all the cases is (T1 – T2), then match
column
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Column-I Column-II Lr EHk&I Lr EHk&II
3R
T1 2R T2
R
(A) (P) 6 k 0 R ( T1  T2 )
(A) k0
(P) 6 k 0 R ( T1  T2 )
eksVk csyukdkj dks'k]
izokg v{k ds vuqfn'k

3R
k 0 R
(B) (Q) (T1  T2 ) T1 R
T2 k 0 R
3 ln 2 (B) (Q) (T1  T2 )
k0 3 ln 2
eksVk csyukdkj dks'k]
f=T;h; izokg

2R
2R
(C) (R) k0R(T1 – T2) R
T1
(C) k0 (R) k0R(T1 – T2)
T2
eksVk csyukdkj dks'k]
f=T;h; izokg

3R
4k 0 R T1
R
T2
4k 0 R
(D) (S) (T1  T2 ) (D) (S) (T1  T2 )
ln 2 x
ln 2
Bksl csyu izokg v{k ds vuqfn'k] k,
k = k0(1+x/(3R) ds vuqlkj ifjorhZ

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PART - III [CHEMISTRY]

ATOMIC MASSES
H =1, He=4, Li=7, Be=9, B=11, C=12, N= 14, O=16, F=19, Na=23, Mg=24, Al=27, Si=28, P=31,
S=32, Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59, Ni=58.7, Cu=63.5, Zn=65.4,
As=75, Br=80, Ag=108, Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.

SECTION - A SECTION - A
[INTEGER ANSWER TYPE] [ fo' y s "k.kkRed i z'u i zd kj ]
Q.1 to Q.8 are INTEGER ANSWER TYPE Questions. i z-1 l si z-8 r d fo' y s"k.kkRed i z'u gS A¼i zR; sd i z'u dkmÙkj dsoy
(The answer of each of the questions is 4 digits)
4 va d ksesnhft ; sA
1. Find out total number of representative
elements in the given elements : 1. fn; sx; sr Roksaesai zfr fuf/kr Roksadhdq
yla
[ ; kKkr dj ks%
Cd, Nb, Ta, Te, Ra, Mo, Po, Pd, Tc Cd, Nb, Ta, Te, Ra, Mo, Po, Pd, Tc

2. How many pairs are, in which first species 2. fuEu esal sfdr us; qXe gSaft uesaf} r h; Li h'kht dhr q
y uk
has lower ionisation energy than second esai zFke Li h'kht dhl cl sde vk; uu Åt kZgksrhgS a
A
species : (i) N r FkkO (ii) Br r FkkK
(i) N and O (ii) Br and K
(iii) Be r FkkB (iv) I r FkkI–
(iii) Be and B (iv) I and I–
(v) Li and Li+ (vi) O and S (v) Li r FkkLi+ (vi) O r FkkS
(vii) Ba and Sr (vii) Ba r FkkSr

3. Total number of element(s) which have only 3. , sl sr Roksadhdq y la[ ; kKkr dj ksft uesamudsl a
xr fLFkj
single oxidation state (other than zero) in ; kSfxdksaesadsoy vkW
Dl hdj .kvoLFkk(' kw
U; dsvykok) gksrhgS
A
a
their corresponding stable compounds : Cs, Ba, F, Zn, Be, Al, S, Ga, Pb
Cs, Ba, F, Zn, Be, Al, S, Ga, Pb

4. How many oxide are amphoteric in nature 4. fuEu esal si zd f̀r esfdr usvkW
Dl kbMmHk; /kehZgS
a
A
MgO, SnO, ZnO, PbO, SO3, CO2, Cl2O7, SO3 MgO, SnO, ZnO, PbO, SO3, CO2, Cl2O7, SO3

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5. Use the foll owing data to answer the 5. uhpsfn; sx; si z'uksadsmRr j dsfy , fuEu vk¡d M+
ksadk
questions below: mi ; ksx dhft , :
H2
 H = – 28.6 Kcal mol–1 2

H
Ni H = – 28.6 Kcal mol–1
Ni
excess H
 2  excess H
 2 
( Ni) ( Ni)
anthracene H = – 116.2 Kcal mol–1 , UFkzkW
l hu H = – 116.2 Kcal mol–1
Calculate the resonance energy of anthracene
in kcal/mol.
, UFkzkW
l hu dhvuq ukn mt kZdhx.kuk kcal/mol esadhft , \
6. Among the following compounds: 6. fuEu ; kS fxd ksesa:

(i) (ii) C8 H 82 (i) (ii) C8 H82

(iii) (iv) (iii) (iv)

(v) (vi) (v) (vi)

(vii) (viii) (vii) (viii)

(ix) C3H31 (x) (ix) C3H 31 (x)

(xi) (xi)

Numb er of comp ound s whi c h are ; kS

fxd ksad hl a
[ ; k fd r uhgS
at ksukW
u&, sjkseS
fVd gS
a\
non-aromatic in nature ?
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 (ADVANCED PATTERN) | Page # 22
7. Consider the following groups. 7. fuEu l ew
gksaesa
]
–NO2, –CN, –OCH3, –NH2,  O  C  CH 3 , –NO2, –CN, –OCH3, –NH2,  O  C  CH 3 ,
|| ||
O O
   
 O ,  NH ,  C  H  O ,  NH ,  C  H
|| ||
O O
How many groups can show –I effect ? fdr usl ew
g –I i zHkko n' kkZl dr sgS\
8. Find out number of C-atoms present in 8. IUPAC fu; e dsvuq l kj eq
[ ; dkcZu Jà
[ ky kea
smi fLFkr
principal chain according to IUPAC rules. C-i j ek.kq
v ksadhl a
[ ; kKkr dhft , \
COOH COOH

NH2 CHO NH2 CHO

SECTION - B
SECTION - B
[ cgqoS
d fYi d i z'u i zd kj ]
[MULTIPLE OBJECTIVE TYPE]
Q.1 to Q.10 has four choices (A), (B), (C), (D) out i z-1 l si z-10 esapkj fodYi (A), (B), (C), (D) gS ] ft uessal s^^, d
of which ONE OR MORE THAN ONE is correct ; k, d l svf/kd^^ l ghgS
A
1. Which of the following pairs of elements have 1. fuEu esal sfdl r Ro ds; q Xeksaesamudsckgj hd{kkesl eku
same number of electrons in their outomosust by sDVªkW
uksadhl a
[ ; kgksrhgS%
shell ? (A) Mn, Fe (B) Na, Sr
(A) Mn, Fe (B) Na, Sr (C) As, Bi (D) Se, Te
(C) As, Bi (D) Se, Te

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2. Electron affinity of the elements or ions 2. fuEu esadkS
ul kr Roksa; kvk; uksadsby sDVªkW
u l keZ
F; r kdks
shown correctly ? l gh: i l sn' kkZ
r kgS
A
(A) S > O– (B) P > N– (A) S > O– (B) P > N–
– – (D) N– > P
(C) O > S (C) O– > S– (D) N– > P

3. Consider the following reactions :

3. fuEu vfHkfØ; ki j fopkj dj ks%
(i) O(g) + e–  O–(g), H1
(i) O(g) + e–  O–(g), H1
(ii) F(g) + e–  F–(g), H2
(ii) F(g) + e–  F–(g), H2 (iii) Cl(g) + e–  Cl–(g), H3
(iii) Cl(g) + e–  Cl–(g), H3 (iv) O–(g) + e–  O2–(g), H4
(iv) O–(g) + e–  O2–(g), H4 r c nhxbZl w
pukdsvuq l kj l ghdFku gSa%
Then according to given information the
(A) H3 , H1 r FkkH2 dhr q y ukesavf/kd _ .kkRed
correct statement is/are :
(A) H3 is more negative than H1 and H2
gSA
(B) H1 is less negative than H2 (B) H1 ,H2 dhr q y uk easde _ .kkRed gSA
(C) H1, H2, and H3 are negative whereas (C) H1, H2 r Fkk H3 _ .kkR ed gSt cfd H4
H4 is are positive /kukRed gS
A
(D) H1 and H3 are negative whereas H2 (D) H1 r Fkk H3 _ .kkRed gSt cfd H2 r Fkk H4
and H4 are positive. /kukRed gS
a
A
4. Which of the following is correct order of 4. fuEu esal sdkS
ul kl a
d sr dsvuq
l kj xq. k/keZdkl ghØe gS
\
a
property as indicated ? (A) Na < F < O < Ne < Ar : i j ek.kqvkdkj
+ – 2–
(A) Na+ < F– < O 2– < Ne < Ar : Atomic size (B) Br < Se < As < Ge : /kkfR od i zd f̀r
(B) Br < Se < As < Ge : Metallic character
(C) Na < Al < Si < Mg : vk; uu Åt kZ
(C) Na < Al < Si < Mg : Ionisation energy
(D) I < Br < Cl < F : by s DVªkW
u l keZ F; r k
(D) I < Br < Cl < F : Electron affinity

5. Which of the following is/are correct order ? 5. fuEu easl sdkS ul kl ghØe esagS a%
(A) Atomic radius : F < O < F– < O2– (A) i j ek.kqf=kT; k: F < O < F– < O2–
(B) 2nd ionisation energy: C < N < F < O
(B) f} r h; vk; uu Åt kZ :C<N<F<O
(C) Electron affinity : I < Br < F < Cl
(C) by sDVªkW
u l keZ F; r k: I < Br < F < Cl
(D) Zeff (effective nuclear change) : Al < Al+
(D) Zeff (i zHkkohukfHkdh; vkos'k) : Al < Al+ < Al3+ <
< Al3+ < Al2+
Al2+

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6. Which of the following belongs to +  group ? 6. fuEu esadkS

u +  l ew
g l sl a
ca
f/kr gS\
(A) –O (B) —OCH3 (A) –O (B) —OCH3
(C) —COOH (D) —CH3 (C) —COOH (D) —CH3

7. Correct order of +I effect is/are : 7. +I i z

Hkko d k l ghØe gS%
(A) –O– > –COO– > – CMe3 (A) –O– > –COO– > – CMe3
(B) – CH2D > – CHD2 > – CD3 (B) – CH2D > – CHD2 > – CD3
(C) – CH3 < – CH2Me < – CHMe2 < – CMe3 (C) – CH3 < – CH2Me < – CHMe2 < – CMe3
(D) – CH3 < – CD3 < – CT3 (D) – CH3 < – CD3 < – CT3

8. Which of the following pair has first having 8. fuEu esad kSul s; q
Xe esai zFke d hvuq
uknhÅt kZf} r h; l s
more resonance energy than second ? v f/kd gksr hgSa\
NH NH NH NH
(A) (A)


(B) 

(B)

(C) O
(C) O
O
(D)  O
(D) 


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9. Which of the following is/are aromatic 9. fuEufy f[ kr esadkS

ul k@l s, sjkseS
fVd ; kS
fxd gS\
species?

(A) (B)
(A) (B) 
 N O
N O H
H

(C) (D)
(C) (D)

10. Which of the following is/are true for stability 10. nksl a
j pukvksadschp LFkkf; Ro dsfy , fuEu esal sdkS
ul k
between the two structures ? l EcU/kl ghgS\
O¯ O¯ O¯
| | O¯
| |
(A) CH 3  CH  CH  CH 2 CH 3  C  CH  CH 3 (A) CH 3  CH  CH  CH 2 CH 3  C  CH  CH 3

CH 2
|| CH 2
  ||
(B) CH 2  CH  CH  CH  CH 2 CH 2  C  CH  CH 2 
(B) CH 2  CH  CH  CH  CH 2 
CH 2  C  CH  CH 2

CH 3 CH 3
|  
|  
(C) CH 2  C  CH 2 CH3  CH  CH  CH 2 (C) CH 2  C  CH 2 CH3  CH  CH  CH 2

O O
|| ||
(D) O¯ CH 3  C  O ¯ O¯
(D) CH 3  C  O ¯

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SECTION - C SECTION - C
[MATCH THE COLUMN TYPE] [l q ph i zd kj ]
esy u l q
Match the entries in Column - I with the entries in Lr EHk- I dhi zfo"Vh; ksdkLr EHk - II dhi zfo"Vh; ksadsl kFkl q
esy u
Column- II. One or more entries in Column - I may
dhft ; sALr EHk- I es, d ; k, d l svf/kd i zfo"Vh; kaLr EHk- II ds
match with one or more entries in Column - II.
, d ; kvf/kd i zfo"Vh; ksadsl kFkl q
esfy r gksl dr hgSA
1. Match the column :
Column - I Column II 1. dkWy e dksfey kb; s
(elements) (periodic properties) dkWy e- I dkW
y e -II
(A) F (P) maximum ionisation energy (r Ro) (vkor Zxq . k/keZ
)
(B) Cl (Q) Maximum electronegativity (A) F (P) vf/kdr e vk; uu Åt kZ
(C) Fe (R) Maximum electron affinity
(B) Cl (Q) vf/kdr e fo| q r _ .kr k
(D) He (S) Variable oxidation state
(C) Fe (R) vf/kdr e by s DVªkW
u l keF; Z
rk
(D) He (S) i fj or Zu' khy vkWDl hdj .kvoLFkk

2. Column - I Column - II 2. Lr a
Hk - I Lr a
Hk- II
(A) –NO2 (P) – I (A) –NO2 (P) – I
(B) – NH2 (Q) + I (B) – NH2 (Q) + I
(C) – Cl (R) – M (C) – Cl (R) – M
(D) – CH2CH3 (S) + M (D) – CH2CH3 (S) + M

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