JEE ADVANCED - TEST SERIES

FOR 12th + 13th STUDENTS

FULL TEST – 1 [PAPER - 1]
Date : 15-8-2021
PART - I [MATHEMATICS]

SECTION : A
1 2 3 4 5 6 7 8 9 10
ABC BCD BD AB AC ACD D B C B

SECTION : B
1 2 3 4 5 6 7 8
9 65 17 5 12 9 00014.60 00058.32

PART - II [PHYSICS]

SECTION : A
1 2 3 4 5 6 7 8 9 10
ABCD ACD AC ABCD BD ABCD D A C B
SECTION : C
1 2 3 4 5 6 7 8
01.00 04.00 02.00 03.00 06.00 25.00 30.00 18.00

PART - III [CHEMISTRY]

SECTION : A
1 2 3 4 5 6 7 8 9 10
CD BD AB AB AD AB C C C C

SECTION : B
1 2 3 4 5 6 7 8
32 00937.30 114 0.37 622.40 104.50 675 106

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 PART - I [MATHEMATICS]

Section – A 3. BD
1. ABC 2 3 3 3
(A) Clearly f  = and f   =
(A) We have 3 2 2 2
.So, f (x) is many one function.
N = 1800 = 23 × 32 × 52 Also range of f(x) = [1, ), so
At least one 2, one 3 and one 5 f(x) is onto also.  (A) is incorrect ]
must be taken
Hence, total number of ways = 3 · (B) f(1– ) = 1 = f(1+) = f(1)
2 · 2 = 12] But f (1–) = – 1 and f  (1+) = 1
(B) We have cos  – sin  = cosec  So, f (x) is continuous but non-
1  derviable at x = 1  (B) is
cos  =  sin  
 sin   correct.

1 (C) f (2+) = 1, f (2–) = 2

As sin   b2  does not exist.
sin 
Also jump of discontinuity = | 2 –
But | cos  |  1 1 | = 1  (C) is correct
so, no solution exists. ]
1
(C) As d1 = 2R cos A, d2 = 2R (D) Clearly f (e) = (verify)]
2
cos B and d3 = 2R cos C
Now, (d1 + d2 + d3) = 4. AB
2R(cos A + cos B + cos C) 5
2 sin–1 x0 + tan–1 x0 =
 A B C 2
x  2x0  15
= 2R 1  4 sin sin sin  0

 2 2 2 5
2 sin1 x0  tan1 x0 
1    16  (x0  1)2
 2R + 8R   = 3R Ans.] 
5
  
8 4

5
4
(D) We have log10(2x + 1 + x – 37)
 x0 = 1 is only solution
= x(log1010 – log105) or 2x + 1 2
for x = 1, y =
+ x – 37 = 2x y 1
x = 37 – 2x x = 5  number of y2 + y – 2 = 0  (y + 2) (y – 1) = 0
values of x is 1 Ans.]  y = 1, – 2
y2 + xy = 2x  2yy1 + xy1 + y = 2
2. BCD
y'(2y + x) = 2 – y
Given integral 2y
= y' =
2y  x
  x        
 6x5  x5  5x4  x4  4x3  x3  3x2  x2  2x  x  1  
6
2 1 1
y ' (1, 1) = =
ex dx 3 3
4
= ex(x6 + x5 + x4 + x3 + x2 + x) + C y ' (1, 2) =
3
f (x) = x6 + x5 + x4 + x3 + x2 + x = 5. A,C
(x + 1) (x5 + x3 + x) = x(x + 1) (x4 +  z  z1  
(A) arg  
x2 + 1)  0  z1  2
 g(x) = x4 + x2 + 1 z z
 1 is purely imaginary.
 g'(x) = 4x3 + 2x = x(4x2 + 2) z1
z1  z z1  z
 g increases for x > 0 and So,  =0
z1 z1
decreases for x < 0.]
z z
  =2
z1 z1

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(B) By applying rotation, we get (ii) k(x) = p has four solutions.
zp  z1 p
i
 p  (0, 2) ]
 e2 ……(1)
0  z1 r
i
9. C
0  z1 r 1 1
Also  e2 ……(2) m1 = 1; m2 =; m3 =
zp  z2 p 2 3
 On multiplying (1) and (2), we get 1
1
zp = tan A = 2 = 1·2 = ;
1 2 3
1
2
(C) As equation of tangent at A(x1, y1) is 1 1

xx1 + yy1 = 4 1 6 1
tan B 2 3 = · = =;
 Slope of tangent 1 6 7 7
1
= 6
x1 2x1  z  z1  1  z1  z1  1
  i 1 1
   2 3 1
y1 2y1  z1  z1  i  z1  z1  tan C = 3 =  · =
1 3 4 2
(D) Clearly tangents are parallel lines. 1
3
(As A (z1) and B(z2) are ends of diameter of
1
2
cirlce.) 2 tan A 3 = 2 9 = 3
 sin 2A = =
1  tan2 A 1 3 10 5
1
6. ACD 9
g'(x) =f'(tanx)sec2 x-f'(cotx) (cosec2x)
For increasing g'(x)> 0 y
f"(x) < 0  f'(x) is decreasing for m1 m2
  
tanx <cot x  x   , 
 4 2 m3
 f'(tanx) > f'(cotx) A

   B C
also, sec2x > cosec2x  x   ,  O 1
x
3 2
 4 2
L3
  3  L2 L1
 g'(x) > 0  g(x) is increasing in  , 
2 4 
1
 3  2
similarly g(x) is decreasing in  ,   2 tanB 7
 4  sin 2B = =
1  tan2 B 1
1
3 49
also g(x) has local max at x = .
4 2 49 7
=  =
7. D 7 50 25
8. B 2 tan C 1 4
sin 2C = = =
1  tan2 C 1 5
(Sol. for Q. 7 and Q.8) 1
4
3  2|x| Clearly, (sin 2A + sin 2B + sin 2C)
f (x) =
1 | x | 15  7  20 2
= =
25 25
10. B
3
Now, abscissa of circumcentre (p)
2 x sin2A  x 2 sin2B  x 3 sin2C
= 1
 sin2A
–2 –3 –1 1 3 2 3 7 24
9 7 
5 = 135  49  120
2 2 2 2
= 5 25
3 1  2  2
(i) x = ±2, ± ,± ,0  25 
2 2  
7
 | xi | = 8 64
= = 32
i1 2

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 For abscissae of orthocentre, 3. 17
x tan A  x2 tanB  x3 tanC 2 1  1 0 1 1 
h = 1 Suppose A1 = 
tan A tanB tanC =   + 
1 0 0 1  1 1
1 1 1 = I + B (say)
9   7   6 
3 7  2  = – 42
=  
n
2 1  n
1 1 1 hence A =   = (I + B)
   1 0
3 7 2 n
 As ΣtanΑ  ΠtanΑ, if ΑΒC  Π A = 
2 1  n n
 = C0I + C1B + C2B
n 2
Hence | p + h | = 10 1 0
+ nC3B3 + nC4B4 + ..........(1)
1. 9
Let x = t2 1 1  1 1  2 0
now B2 =     =  
1
1 1 1 1 0 2 
In =  2t(1  t  t 4    t 2n2 )(1  3t 2  5t 4  
2

0
= 2I
+ (2n  3)t
2n 4
 (2n  1)t2n2 )dt Hence B2k = 2kI and B2k+1
1 = B2kB = 2kB
 2(t  t
2n1
= 3
 t  t
5
)(1  3t  5t  
2 4
n
2 1
0 now  
+ (2n – 3) t2n-4 + (2n – 1)t2n–2)dt 1 0
Let y = t + t3 + t5 + … t2n–1 =
n
( nC0  nC2 ·2  nC4 ·22  ...)I  ( nC1  nC3 ·2  nC5 ·22  ...)B
 In = 2 t dt  n2  
' X ' say
 
' Y ' say
0

 I9  92 = 9 n
2 1  X 0  Y Y 
   =   +  
2. 65 1 0 0 X  Y Y 
(n  2) 2 X  Y Y 
Tn = =  
n(n  1)(n 2)(n 3)  Y X  Y
n(n  1)  3n  4 2 1 
n
= Hence a12 in 
n(n  1)(n  2)(n  3)  =Y
1 0
= 1 3 4
 
(n  2)(n  3) (n  1)(n  2)(n  3) n(n  1)(n  2)(n  3) a12 = nC1 + nC3 · 2 + nC5 · 22
Now,
+ nC7 · 23 + ........
Lim  Tn =
x 
1 n
  1 1  3  1 1   = C1 · 2  nC3 ·( 2 )3  nC5 ·( 2)5  ........ 


   
 (n  2) (n  3)  2

 (n  1)(n  2) (n  2)(n 3) 
 
 2  
Lim
x  
4  1 1 

  
3

 n(n  1)(n  2) (n  1)(n  2)(n  3)
  1  (1  2)n  (1  2)n 
 
=  
2  2 
1 3 1 4 1 1 1 2 |||ly a22 = X – Y
 ·  ·
= =  
3 2 6 3 1·2·3 3 4 9
= (nC0 + nC2 · 2 + nC4 · 22 +
12  9  8 29 m
= = =  m  29 ; nC · 23 +......) – (nC + nC · 2 + nC ·
36 36 n 6 1 3 5
n  36 2 n 3
2 + C7 · 2 + .....)
 (m + n) = 29 + 36 = 65 Ans.
(1  2)n  (1  2)n (1  2)n  (1  2)n
1 (2n  4)  = –
Alternatively: Tn =   2 2 2
2  n(n  1)(n  3) 
2[(1  2)n  (1  2)n]  [(1  2) n  (1  2) n]
1  (n  3)  (n  1)  =
=   2 2
2  n(n  1)(n  3) 
( 2  1)(1  2)n  ( 2  1)(1  2)n
1  1 1  1 1 1  a22 =
=     
2  n n  1   2 n n  3  2 2
a12
1  1 1   Lim
=    n a22
2  n(n  1) n(n  3)  
Now proceed. (1  2)n  (1  2)n
= Lim
n
( 2  1)(1  2)n  ( 2  1)(1  2)n

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 2x +  = nx = n   ; n  I
n
1  2 
1
 1  2  3 2 6
= Lim    5
n
1  2 
n  in [0, ] x= or
( 2  1)  ( 2  1)  3 6
 1  2  Max.
 
10 Min.
= = 1 2;
2 1
Hence l2 = ( 1  2 )2 = 3 + 2 2  5
3 6
= 9 + 8 . 3
0
Hence a + b = 9 + 8 = 17 Now f (0) =  sin  d
0
= cos   = 1
3

4. 5 1 1
  – =
OB · OC  3 2 2
 4

(3) (2) cos  = 3 3 3
f ( ) =  | sin  |d =   sin  d
 
1
 cos  = 4 3 1 1
2  f () = cos   = 1 =
 2 2
  = 60° 2 3
 3
A (a ) f  =
3 3
 sin  d = cos  
2 3

4 1  1 
=  =1
2 3 2  2 
 O 7 6
 5 
3
1
60°
2 f  =
 6  5 6
 | sin  |d

C ( c)  7 6
B ( b)
=  sin  d    sin  d = 2  3
Now  = 1 + 2 + 3 5 6 

1 1 Hence minimum value m = 2  3

 = (3) (2) sin 60° + (3) (4) sin  +
2 2 and maximum value M = 1
1 m + M = 3  3 = 9  3  p  q
(2) (4) sin (300 – )
2 p = 9; q = 3 p + q= 12
3 3
= + 4 sin  – 2 3 cos 
2 6. 9
3 3 a a a1 = (28)1/4; a2 = a1r; a3 = a1r2
max = + 2 7  b 7
2 b etc.
 (a + b) = 5 b1 = 1; b2 = R; b3 = R2 etc. where r and
R and the common ratio of the two G.P.'s
5. 12 
1 
x

now given    bn
n1 an
3
x  [0, ]
n1
f (x) =  | sin  | d
x
;
1  1 1 
for maximum / minimum f ' (x) = 0

a1 1  r  r2  ....... 
 
  2 3
f ' (x) = sin  x   – | sin x | = 0 = (1 + R + R + R + ...... ¥)
 3
1  1 

 
sin2  x   = sin2x a1 1  (1 r) 

 3 1
= (R = b2 = 71/4 – (28)1/4 + 1)
  1R
sin2  x   – sin2x = 0
 3 1  r  1
14   =
   (28)  r  1  (28)  71 4
14

sin  2x   · sin = 0
 3 3 (1 – R = (28)1/4 – (7)1/4)

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 r (28)1 4 r 1 8. 00058.32
 =  Tr+1=6561Cr(a1/3) 6561-r
(b)r/9 = 6561
Cr (a)(6561-
r 1 14
(28)  7 14
r r)3
14
(b)r/9.
(28)1 4  71 4 1 1 r 6561  r
= 1– =1–   Tr+1 will be integral if and both
(28)1 4 r 4 9 3
r = now, a1 = (28)1/4; a2 = 2 a1 ; a3 = 2a1 are integer.
r = 0, 9, 18, ……, 6561.
1
area = a12 2 sin A ....(1) Number of values of r =
6561
 1  730.
2 9
1 So, number of irrational terms = 6562 –
( bc sin A)
2 730 =5832
3a12  4a2
also, cos A = (cosine rule)
2 2 a12
1
=–
2 2

1 7
sin A = 1  =
8 2 2
(In a triangle, sin A > 0)
(28)1 2 7 2·7 7 p
 Area = · = = =
2 2 2 4 2 q
 pq9

7. 00014.60

Given point is corresponding to t = 2 and

dy 1
= 6t  slop of nomal at t = 2 is -
dx 12
 equation of normal is y – 6
1
=- (x - 1)
12
73
 a = 73, b =
12
a + 12b = 146.

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 PART - II [PHYSICS]

Section – A 4. ABCD
1. ABCD 
K rdr
The above lens mirror combination is an 4r
2 R
(A) v   0 2
r  (3R) 2

40
equivalent converging mirror.
y
2. BC
30°

30° B 3R
30° 4R
60° r x
30°
A
dr

 mV
Arc AB = r z
3 3qB 
K rdr
 1    T m 4r
2 R
Time =      (B) v   
 2  3  6 3qB 0 r 20

3. ACD 5. BD
At equilibrium positions, friction must be evdB
zero at both surface as net torque on (Fm)net
disc = 0
×
vnet
So N2 = 0 u
× ×
Torque about A = 0
vd – euB

g × × ×
kx Wmagnetic = 0
N2 m,  To maintain the current work has to be
 done by battery
mg A Wbatt    nA euBvd dt
N1 I = neAvd
l
mg sin = kx l sin
2
= IB udt 
mg WBatt = IBh
= kx, as mg = kl
2
x
l 6. ABCD
2 At constant temperature, decrease in
l
as x = l(1 – cos) = molecular mass causes flattening of the
2
graph. For same molecular mass of gas,
1
cos = increase in temperature causes flattening
2
 = 60° of the graph.
1
P.E of spring = kx 2 
1 kl 2 kl 2

V  mp T
1
 Vmp   T2
2 2 4 8
T1 T2 T2 MB
K.E of system = (P.E)mg Loss – (P.E)spring    
MA MB T1 MA
l 1 k12
= mg  cos    kl 2 
2 8 8 MB
But, can be less than or greater than 1
MA

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 MA T1 9. C
Similarly, 
MB T2 The image distance of A is

If gas A is O2 and gas B is N2 , then MA

>MB . A F B C
pole  
V 
mp T
1

 Vmp  T2 x x
T1 T T M
  2  2  B
MA MB T1 MA (f  x)
VA   ( x  t)
xf
[(2f  x)  f]
7. D The image of B is VB  
(2f  x)  x
f
8. A Solving VA  VB  4f we get x 
2
(Sol. for Q. 7 and Q.8) x f
Let the initial temperature, pressure and  required time t  
u 2u
volume of gas in ‘A’ be
T0,P0,V0 and the area of the position A 10. B
and B be a, 2a. Now gas in chamber ‘A’ Section - B
1. 01.00
undergoes adiabatic compression whereas
at plane surface image of object is
gas in chamber ‘B’ undergoes isothermal
xR
expansion.   4 distance at current surface
12
Now solving for gas in ‘A’  xR 
 
u   4  R
P1A V1A  P2A V2A  P0 V0  12 
 P2A 0.25V0   P2A  8P0 v= ROC= –R
r  i r i
Solving for gas in ‘B’  
R ν u
P1B V1B  P2B V2B  PIB V0 14 4

 P2B  2.5V0  P2B  0.4PIB R  xR4 
 12  R 
 
Also (P2A×a)=(P2B ×2a) for gas is
x 1
chambers 'B'
 8P0 a  P2  2a  P2  4P0 2. 04.00
 0.4P1  4P0  P1  10P0 dT
H  K.2r /
dr
Now comparing the moles of gas in A and B
P0 V0
nA 
RT0
10P0 V0 R
nB   10nA 2R
RT0
mB =10mA =10×100gm=1kg
Again for gas is A,Q=U+W
 0 = U + W
 V 
 P V  8P0  0  R2 Hdr T2
 0 0
 0  U   4 
 R1 2rl
 K  dT  H
T1

 (   1) 

 
 2lk  T1  T2 
 Hi  Hf
R2
 U  2P0 V0  2  10  10 5 2
 2000J ln
R1
5 –2
F=8P0a = 8×10 ×10 = 8000N
3. 02.00

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 dNA dNB VA cos θ  Vp cos 45  5 5m / s and θ  60
 1NA ,  21NA  2NB
dt dt
VA2 sin 2θ
dNB  AB   25 3
NB  maximum 0 g
dt
21
 21NA  2NBmax  NBmax  N 7. 30.00
2 A
Consider equation of torque about C
21
 NBmax  N e1t  2  4R  mR2
2 0 mg  
 3  2
8g 8g 8g
4. 03.00   
3R 32R 30R
T the FBD of any one rod is
T
8. 18.00
No current passes through capacitors in
steady state. Assume
N R R R
1
mg 
37°
N P
C C
T = N --------(1)
mg = N --------(2) C
Taking torque of any one rod is
R 2 R 3 R
L
mg cos 37  TL sin 37
g 4
V
mg 4 2mg
T   2V/3
2 3 3
2mg 2 1 2
 mg   
3 3

5. 06.00
1 3  1 1 
   1   
fL 2   20 20  3 V/3

 FL = 20cm potential at point '4' to be zero.

1 1 2 1 Then points '1' and '2' are at same
  
f 10 20 5 2V
potential
1 1 1 1 1 1 3
    
 30 5  30 5 Hence C1 and C2 can be taken in parallel
1 1 1 V
For lens   The potential at point 3 is
 30 20 3
 Equivalent circuit of all three capacitors
6. 25.00 is shown Hence
2
PQ  15  20  25m 2 potential difference across capacitor C3 is

VP2 sin2(45) 2C  2V V  2V
25   VP  5 10m / s    
g 2C  C  3 3 9

 VA2 sin2 θ  2  10  12.5  (5 5)2

 VA sin θ  5 15m / s

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 PART - III [CHEMISTRY]

Section – A 9. C
1. CD For nth order reaction
It is polymerisation reaction. The chain 1  1 1 
k nt    n1  …(i)
termination occurs after only isobutylene n  1  a n1
a0 
molecule has been added. This is due to   1  
n1 n1
the high concentration of water, the 1  2  
Hence knt1/2        …(ii)
intermediate carbocation loses a proton to n  1  a0   a0  
 
water it can react with another alkene
molecules. a0
as a =
Hence (C, D) is correct. 2
At t3/4
2. BD  n1
 1  
n1
1  4  
The above reaction represent the case of knt3/4          …(iii)
n  1  a0   a0  
ArSN (aromatic nucleophilic substitution)  
which occurs through the formation of a
benzyne. For the formation of benzyne a  0 at t3/4
4
intermediate, it is essential that an H From equations (ii) and (iii)
should be available in on ortho position to t1/2 2n1  1
the halogen. 
Hence (B, D) is correct. t3/4 n1
4  1
t1/2
3. AB Hence is a function of n.
t3/4
These copolymers are formed in steps
and hence step growth polymer
10. C
4. AB 1
t1/2 
Bronze contains Cu = 80%, Zn = 10%, n1
a
0
Sn = 10% whereas brass contains Cu =
a   
n1
80%, Zn = 20%. t1/21 02
Gun metal and type metal do not contain Zn. 
a   
n1
t1/2 2
 
Hence, (A) and (B) are the correct answers. 01

n1 n1
 4280  1.1  11
5. AD      
 885   0.5  5 
XeF2  2SbF5  XeF2.2SbF5
Lewisbase Lewis acid Solving we get n = 3
 –
XeF4  SbF5  XeF3  SbF6  Hence order = 3

XePtF6 was first real compound of Xe. Section – B

6. AB 1. 32
210 206 4
Gold number is the index of protective 84 PO 82 Pb 2 He
power of lyophillic colloidal for standard a-x x x
gold sol. 2.303 a
t= log
 ax
7. C
1
nEº 2 1.23 V 2.303  138.4
logK    41.62 69.2 = log 210
0.0591 0.0591 0.693  1 
 210  x 
 
K = 4.210 × 1041
Calculate x (no. of moles of He produced)
8. C V = 22.4 × x = 32 × 10–3 L = 32 ml
DG° = -nFe°cell
= -2 × 96500 × 1.23 2. 00937.30
=-237390 cal/mol Let the electron be boosted to n th level,
=-237.39 k cal/mol then
G 237.39 Number of spectral lines
Efficiency=   98.5% =  n  n  1  15 . Given,
H 241.00

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 1 Cell constant
Or n  1  n  15  Resistance 
2 Conductivity
n =6 0.206
Thus electron is boosted upto 6th energy =  622.36 ohm=622.4  
3.31 102
level from ground state. Therefore
1 1 1 6. 00104.50
 109737  2  2 
 1 6  –Gº = 2.303 RT log10K
 = 9.373 × 10–6 cm = 937.3 Å Gº = Hº– T Sº
H S
 logK   
3. 114 2.303RT 2.303  R
i.t ...(iii)
Eq. of metal = (i = 10 ampere,
96500 From equation (i) & (ii)
t = 330 sec) K 5800
log f  5.457 
1.95 10  330 Kb T

E 96500 5800
Emetal = 57.0  logK = 5.4857 –
T
At. wt. of metal = 57.0 × 2 (metal is 5800
bivalent as salt is MF2) logK =  + 5.457
T
= 114.0
...(iv)
From equation (iii) & (iv)
4. 00000.37
For a given aqueous solution S° = 104.48JK–1= 104.5 JK–1


Tb  Kb  molality 7. 00675.00

 Let n moles of gas be present
Tf  K  molality
f
PV 1.6 106  0.0083
Tb K RTb2 1000 f  n    5.33
  b   RT 8.3  300
Tf Kf 1000  v RTf2 5
Given, CP  R ,
Tb T2   f 2
 b2
Tf Tf   v 5 3 3
 Cv  R  R  R   8.3  12.45 J / mol  K
2 2 2
 Tb = 100 + 273 = 373 K
Heat supplied at constant volume
 Tf = 0 + 273 = 273 K
= n × Cv × T
 f = 80 cal g–1 ;
 T = 375 K
v = 540 cal g–1
0.1 373  373  80  Final temperature
  = 300 + 375 = 675 K
Tf 273  273 540 

Tf = 0.362 8. 00106.00

Tf = 0.0 – 0.362 = – 0.362ºC Br

|Tf| = 0.362ºC
CH2CH3 HC CH3

5. 00622.40
Degree of dissociation
^
  mo
^m O3/2H/H2O
o
 ^m  ^  m (A) (B) No gometrical
K  isomers(C)
o
 ^m   a  (by Ostwald dilution law)
 C  CH2CH3
=
CHO
1.8 105
390.5   8.82 ohm1 cm 2 mol 1 HCHO+
0.04
molarity  ^m
Conductivity= (D) (E)
1000 Also A and E are identical
= 3.31 × 10 ohm cm
–4 –1 –1
M. Wt. = 96 + 10 = 106
1 Number of geometrical isomers = 0
Also conductivity Cell constant ×
Resistance x + y = 106

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