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CHAPTER 1
1. INTRODUCTION
Vegetable oils have been investigated to replace petroleum-based lubricants
due to its environment-friendly characteristics and these oils have become an
important source of bio lubricants. A lubricant is very important role in industrial
world. Because it is mostly used in transportation and machinery. Lubricant is used
in order to reduce the friction between two moving surfaces or reduce metal to
metal contact. The current rate of bio-degradable lubricant production makes only
a very little fraction of the total production of lubricants.
Base oil (SAE20W40 Engine oil) makes over 60% and the vegetable oil
(Cotton seed oil & pongamia oil) makes around 20% for each oil.
Hence exploring ways for substituting the mineral oils with more eco-
friendlier options has become a primary concern of resources performed in the
lubricated industry. Vegetable oils are mainly comprised of triglycerides whose
molecular structure is made up of three long chain fatty acids linked to hydroxyl
groups through ester linkages. The triglycerides structure of vegetable oils offers
desired qualities in the respective lubricant products. The strong interactions
between molecules tend to be re-silent to temperature changes offering a high
viscosity co-efficient. Longer polar fatty acid chains offer higher strength films of
lubricants that can interact strongly with metallic surfaces. Thus reducing friction
and consequently wear.
These oils are able to offer good lubrication because it helps in minimizing
the co-efficient of friction. The optimization blend was done to obtain lower rate of
wear and higher film breakdown temperature value; giving the Cotton seed oil &
pongamia oil with mineral engine oil (SAE20W40).
The optimized blend was further investigated through pin on disk tribotester
using the image processing technique.
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CHAPTER 2
2. LITERATURE REVIEW
Abstract: The amphiphilic properties that result from the fatty acid composition
of vegetable oils contribute to a better lubricity and effectiveness as anti-wear
compounds than mineral or synthetic lubricant oils. Despite these advantages,
vegetable oils show only a limited range of viscosities and this constrains their use
as suitable bio lubricants in many industrial applications. For the reason, ethylene–
vinyl acetate copolymer (EVA) and ethyl cellulose (EC) have been added to the
vegetable oil-based lubricants studied .To address this issue, the frictional and
lubricant film-forming properties of improved vegetable oil-based lubricants (high
oleic sunflower (HOSO), soybean (SYO) and castor (CO) oils), blended with 4%
(w/w) of EVA and 1% (w/w) of EC, have been studied. It has been found that
castor oil shows the best lubricant properties, when compared to high oleic
sunflower and soybean oil, with very good film-forming properties and excellent
friction and wear behaviour. This can be attributed to its hydroxyl functional group
that increases both the viscosity and polarity of this vegetable oil. Regarding the
effect of the viscosity modifiers studied, ethylene-vinyl acetate copolymer exerts a
slight effect on lubricant film-forming properties and, thus, helps to reduce friction
and wear mainly in the mixed lubrication region. Ethyl cellulose, on the other
hand, was much more effective, mainly with castor oil, in improving both mixed
and boundary lubrication.
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2.2. Tibrological Features of Refined, Deodorized And Bleached
Palm Olein With Mineral Oil Blend
Mohammed Hassan,Farid Nasir Ani& S.Syahrullail.
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the wear rate for a load of 100N for all lubricants was almost always higher
compared to lubricant with a load of 50N. The results of this experiment reveal that
the palm oil lubricant can be used as lubricating oil, which would help to reduce
the global demand of petroleum based lubricants substantially.
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CHAPTER 3
3. ENGINE OIL
Engine oils are derived from petroleum based and non-petroleum-synthesized
chemical compounds. Motor oils today are mainly blended by using base oils
composed of hydrocarbons, poly Alpha Olefins (PAO) and poly internal olefins,
organic compounds consisting entirely of carbon and hydrogen.
3.1. Types
Motor oils can be segmented into four basic varieties. They are,
i) Synthetic Oil
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3.2. PROBLEMS
The usage of engine oil as a lubricant for machineries causes severe threat to
living organisms in the environment.
• Non-Degradable
• The addition of used engine oil in the sea, causes erosion to the coral reefs
• The disposal of the engine oil in the water bodies effect the aquatic life in
them.
• The work done in machines using engine oil as a lubricant may cause some
allergy, skin disease to the human being.
• Engine oil is obtained from crude oil, since crude oil is obtained from earth;
it is a non-renewable form of energy.
3.2.1. Toxicity
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Crude oil is a mixture of many different kinds of organic compounds, which
are highly toxic and causes cancer. This type of Oils are "acutely lethal" to fish,
so that it kills the fishes quickly, at a concentration of 4000 ppm(0.4%). Crude
oil and petroleum distillates causes birth defects.
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Tamilnadu pollution control board (TNPCB) says that booms were laid at
the Ernavur site to prevent oil from spreading. Due to the wave action and the
southern current, the spill spread over 34 km till vettuvankeni in the south. 40 tons
of oil sludge is removed from the Ramakrishna nagar beach near Ernavur. It leads
to death of many aquatic lives.
Coral reefs can come in contact with oil in three major ways:
• Rough seas can mix lighter oil products into the water column (like shaking
up a bottle of salad dressing), where they can drift down to coral reefs.
• As heavy oil weathers or gets mixed with sand or sediment, it can become
dense enough to sink below the ocean surface and smother corals below.
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3.2.4. Oil Causes Skin Allergy
Mechanics and other auto workers who are exposed to the used engine oil
from a large number of cars have experienced skin rashes, blood effects (anemia),
and headaches and tremors. Persons breathed mists of used engine oil for a few
minutes had slightly irritated noses, throats, and eyes.
3.2.5. Disposal
Fig 3.6.Disposal
When waste oil from vehicles drips out engines over streets and roads, the
oil travels into the water table bringing with it such toxins as benzene. This poisons
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both soil and drinking water. Run off from storms carries waste oil into rivers and
oceans, poisoning them as well.
i) Dynamic viscosity
ϱ = m/v
Where,
m - Mass (kg)
v - Volume (m³)
ϱ - Density (kg/m³)
3.3.3. Flash Point: The Flash Point is the lowest temperature at which vapours
of a volatile material will ignite, when given an ignition source. The flash point is a
descriptive characteristic that is used to distinguish between flammable liquids
such as petrol and combustible liquids such as diesel.
3.3.4 Fire Point: The Fire Point is the lowest temperature at which the vapour
will keep burning after being ignited and the ignition source removed. The fire
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point is higher than the flash point, because at the flash point the vapour may be
reliably expected to cease burning when the ignition source is removed.
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CHAPTER 4
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Fig4.1 Redwood Viscometer
The dynamic viscosity of fluid is defined as the shear required to produce unit rate
of angular deformation.
It is that point of temperature at which the asphalt will flash for one
second under specific situation.
Fire point:
1. To find out the type and quantities for the availability of un desirable
materials in the asphalt.
2. To find the safe point of heating the asphalt during the construction
process (to protect asphalt from burning).
APPARATUS:
2. Flame.
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Procedure:-
Start the test heater to heat in a rate of (5-6)⁰C/min.
Before the expected Flash point by about (28⁰C) start to close the
flame from the samples surface each (1⁰C) until (104⁰C).
Continue with step (4) after (104⁰C) but in intervals of each (3⁰C).
Compute the flash and fire points when they happened.
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CHAPTER 5
5. VEGETABLE OIL
Vegetable oils are the oils which are extracted from the plant seeds, dry
fruits, grains and nuts under pressure to squeeze the oil out.
Vegetable oils have traditionally been applied in food uses but recent trends
suggest their economic usefulness as industrial fluids. Increasing crude oil prices
and emphasis on the development of renewable, environmentally friendly fluids
have brought vegetable oils to a place of importance.
5.1. Types
Vegetable oils are classified into two major categories based on the usage
and application.
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5.2. Uses
Cooking, Cosmetics, As fuel, Medical purpose
2) Corn oil
3) Cottonseed oil
4) Olive oil
5) Sunflower oil
6) Groundnut oil
7) Safflower oil
8) Soybean oil
9)Palm oil
2) Jojoba oil
3) Pongamia oil
5) Linseed oil
6) Castor oil
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8) Neem oil
9) Orange oil
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CHAPTER 6
6. OIL SELECTION
6.1. Detail about Selection of Oil
In our project, three oils are selected for preparing lubricating oil. There are
following below.
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Fig.6.1. Pongamia Seeds
Cotton seed oil is cooking oil extracted from the seeds of cotton plants after
the cotton lint has been removed. Cotton is an important fibre crop of global
significance and is grown in tropical and subtropical regions of more than eighty
countries. Cotton is primarily cultivated for its lint or fibre, in other words, lint is
the main product of cotton crop. Now, cotton seed oil is also widely used for
human consumption. Thus, cotton has become a fiber cum oil yielding crop. Its
seeds also contain 20-25% protein. Hence, in future, cotton will become a source
of fiber, oil and protein. There are four products of cotton plant viz.lint, seed, stalk
and leaves. Out of these, lint is the main product and rests are by-products.
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reaction, and temperature were found. This cottonseed oil-derived biodiesel was
tested in a direct injection, naturally aspirated, single-cylinder diesel engine. The
diesel engine was operated from no load to full load condition. Effect of this
biodiesel on engine parameters, namely, fuel consumption, electrical efficiency,
lower heating value, and engine speed, was examined. Also, the physical and
chemical properties, including specific gravity, moisture content, refractive index,
acid value, iodine number, specification value, and peroxide value of the methyl
esters used in this study, were estimated. Based on electrical efficiency, the methyl
esters obtained from cottonseed oil were found to be a good alternate fuel in
internal combustion engines with electrical generators.
In comparison with mineral oil and synthetic oils, vegetable oil based
lubricants possess the properties such as low toxicity, high lubricity, high viscosity
index, high load carrying capacity, excellent coefficient of friction, good anti-wear
capability, low emission into the environment, high flash point. Because of polar
groups in the structure of vegetable oil and presence of long fatty acid chains
obtain both boundary and hydrodynamic lubrications. Many of the researchers
have used vegetable oil as engine oil, but only few of the researchers have reported
vegetable oil-based lubricants for automotive applications.
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Fig 6.2. Cotton seeds
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CHAPTER 7
7. PREPARATION OF OIL
Mixing Of Oil (Our Oil)
Base oil (SAE20W40 Engine oil) makes over 60% and the vegetable
oil (Cotton seed oil & pongamia oil) makes around 20% for each oil.
Hence exploring ways for substituting the mineral oils with more eco-
friendlier options has become a primary concern of resources performed in the
lubricated industry. Vegetable oils are mainly comprised of triglycerides whose
molecular structure is made up of three long chain fatty acids linked to hydroxyl
groups through ester linkages. The triglycerides structure of vegetable oils offers
desired qualities in the respective lubricant products. The strong interactions
between molecules tend to be re-silent to temperature changes offering a high
viscosity co-efficient.
Longer polar fatty acid chains offer higher strength films of lubricants that
can interact strongly with metallic surfaces. Thus reducing friction and
consequently wear.
These oils are able to offer good lubrication because it helps in minimizing
the co-efficient of friction. The optimization blend was done to obtain lower rate of
wear and higher film breakdown temperature value; giving the Cotton seed oil &
pongamia oil with mineral engine oil (SAE20W40).
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CHAPTER 8
8. TRIBOMETER
A tribometer is an instrument that measures tribological quantities such as
coefficient of friction, frictional force and volume between two surfaces in contact.
8.1. Types
Four ball tribometer
F=µN
µ- Coefficient of friction.
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Pin on disc tribometer consists of a stationary pin under an application of load
in contact with a rotating disc. A known load is applied along the axis of the pin,
and the friction. A force is measured by the force transducer restraining pin
motion.
The elements of the tribometer included a “pin” sliding on the flat face of a
“disc” rotating in a vertical plane, with provisions to control the load, speed, oil
temperature and to measure friction.
The test oil was contained in a tank in which the disk rotated and the oil was
swept up into the contact area by the rotating disk. The oil temperature is measured
and controlled by a double-shielded thermocouple.
The load of the pin against the disk is applied by weights on a pan hanging on a
thin steel cable over a pulley and hooked to the arm. Thus, the weights pulled the
pin toward the disk. Tangential frictional force and wear were monitored with
electronic sensors and recorded.
The load of the pin against the disk is applied by weights on a pan hanging
on a thin steel cable over a pulley and hooked to the arm. Thus, the weights pulled
the pin toward the disk. Tangential frictional force and wear were monitored with
electronic sensors and recorded.
MATERIAL SELECTION
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CHAPTER 9
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9.2. Sliding Velocity 1 m/s
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9.3. Sliding Velocity 1.5 m/s
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CHAPTER 10
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CHAPTER 11
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Fig.11.3. Sliding Velocity 1.5 m/s
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CHAPTER 12
12.2. Applications
Automobiles
Chemical industry
Education/research
Electronics
Material science/nanotechnology
Minerals/mining/raw materials
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CHAPTER 13
13. CONCLUSION
The friction and wear characteristics of our oil were evaluated at constant
load of 70N. By varying sliding velocities (0.5m/s, 1.0 m/s and 1.5 m/s), the
friction and wear characteristics were analyzed.
From the above results, it can be concluded that our oil is a suitable
alternative lubricant for conventional engine oil.
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PHOTOGRAPHY
Discs Pins
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REFERENCES
2. Yang Jiao & Yong Kang Chen (2014) Tribological Properties of Zinc Borate
Ultrafine Powder (ZBUP) as a Lubricant Additive in Oil, Science
direct.57:425-434.
5. Hidayet oguz & Hayrettin duzcukoglu (2011) have done a research on The
Investigation of Lubrication Properties Performance of Euro-Diesel and
Biodiesel, Science direct. 54:3, 449-456.
6. K.Nantha Gopal & R.Thundil Karuppa Raj (2015) have done a research on
Effect of pongamia oil methyl ester(PME) diesel blend on lubricating oil
degradation of di-compression ignition engine, tribological transaction.220 pp
2027-2040.
8. Mohammed Hassan, & Farid Nasir Ani (2015) have done a research on
Tribological features of refined, deodorized and bleached palm olein with
mineral oil blend, Science direct. 69,6 pp 11-14.
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9. F.Sundas & H.H.Masjuki (2016) have done a research on Analysis of
tribological properties of palm biodiesel and oxidized biodiesel blends,
tribological transaction. 57:3, 408-415.
10. Yuan Ching Lin & Tsang Hung Kan (2013) have done a research on
Tribological Performance of Engine Oil Blended with Various Diesel Fuels,
tribological transaction. 56:6, 997-1010.
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