Lampiran 2.

Perhitungan

A. Penetapan Kalorimeter

T1 + T2 – 2Ta
W = V x ρair x CH2O x
Ta –T1
Keterangan:

W = tetapan kalorimeter (J/K)

V = volume = 200 mL

ρair = massa jenis air = 1 g/mL

CH2O = kapasitas kalor air = 4,2 J/K.g

Ta = suhu akhir = 312,8 K

T1 = suhu akuades dingin = 303 K

T2 = suhu akuades panas = 323 K

(303 K + 323 K) – 2 (312,8) K

W = 200 mL x 1 g/mL x 4,2 J/K g x
312,8 – 303 K
626 K – 625,6 K
= 840 J/K x
9,8 K

= 34,2857143 J/K

Jadi, nilai tetapan kalorimeter adalah 34,2857143 J/K

B. Penentuan Kalor Penetralan

Vtotal = V1 + V2

= 100 mL + 100 mL

= 200 mL
 = 0,2 L

MrNaCl = (1 x ArNa ) + (1 x ArCl )

= (1 x 23 gram/mol) + (1 x 35,5 gram/mol)

= 58,5 gram/mol.

n
M = V

n =MxV

= 1 mol/L x 0,2 L

= 0,2 mol

Massa = n x Mr

= 0,2 mol x 58,5 gram/mol

= 11,7 gram

1000
ΔHT = - (CH2 O × mNaCl+ W) (T’- T) ×
V×M
1000
ΔHT = (-(4,2 J/K.g × 11,7 g + (34,2857143 J/K)) (306,27 K – 298 K) × 0,2 L x 1 M

= -3.449.653,29 J/mol

= -3.449.653,29 J/mol

Dimana ΔHT = Kalor Penetralan (kJ/mol).

W = tetapan calorimeter (J/K).

V = volume total kalorlarutan (L)

CH2 O = kapasitas kalor air (J/K.gram).

m = massa NaCl (gram)

T = suhu awal larutan HCl dan NaOH (K)

T’ = suhu campuran (K)