CHEMISTRY

Daily Practice Problems

Target JEE 2019
Class:XI (P) Time: 28 Min. Date:19-20/04/2017 Marks: 35 DPP No. 1
Q.1 Degenerate atomic orbitals have [2]
(A*) equal energy (B) same orientation
(C) different energy (D) different orientation

Q.2 The group having isoelectronic species is : [2]

(A) O¯, F¯, Na, Mg+ (B) O2–,F¯, Na, Mg2+
(B) O¯, F¯, Na+, Mg2+ (D*) O , F¯, Na+, Mg2+
2–

Q.3 When the quantum number n,l,m,s are represented by 3,3,2,+1/2, the correct representation is
(A) 3s (B) 3d [2]
(C) 3f (D*) impossible set of quantum number

Q.4 For a 6s electron the values of n,l,m,s respectively could be: [2]
(A) 6,4,4,+1/2 (B) 1,0,0,+1/2 (C) 6,1,0,+1/2 (D*) 6,0,0, +1/2

1
Q.5 If an electron has spin quantum number of + and magnetic quantum number of –1 it cannot be present in
2
[2]
(A) f-orbital (B) d-orbital (C) p-orbital (D*) s-orbital

Q.6 Any p-orbital can accomodate up to [2]

(A) four electrons (B) Two electrons in parallel spin
(C) Six electrons (D*) Two electrons with opposite spin

Q.7 Principal, azimuthal and magnetic quantum numbers are respectively related to [2]
(A*) size, shape and orientation (B) shape, size and orientation
(C) size, orientation and shape (D) none of these

Q.8 Identify the pairs which are not of isotopes? [2]

(A) 12
6 X,
13
6 Y
35
(B) 17 X, 37
17 Y (C*) 14 14
6 X, 7 Y (D*) 84 X, 85 Y

Assertion Reason
Q.9 Statement-1 : All isotopes of a given element show the same type of chemical behaviour. [2]
Statement-2 : The chemical properties of an atom are controlled by the number of electrons in the
atom.
(A*) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
More than one may be correct
Q.10 Which of the following energy level can not exist according to quantum theory? [3]
(A*) 3f (B) 5g (C*) 5h (D) 6h

Match the column

Q.11 Column I shows partial electronic configuration of an atom which may or may not be correct.
Select the rule(s) they violate from column II. [12]
Column I Column II
(A) (P) Pauli's exclusion principle

(B) (Q) Hund's rule

(C) (R) Auf bau's principle

(D) (S) None

[Ans. (A) P,Q (B) P,Q,R (C) P,Q,R (D) P,Q ]

Subjective
Q.12 A dipositive ion having mass number 13 has 7 neutrons. What is the number of electrons in the ion?[2]
Ans. 4