1.

047 𝑔
𝑛𝑁𝑎𝐻𝐶𝑂3 = = 0.01246 𝑚𝑜𝑙 𝑁𝑎𝐻𝐶𝑂3
84 𝑔. 𝑚𝑜𝑙 −1
2.473 𝑔
𝑛𝑁𝑎2 𝐶𝑂3 = = 0.02333 𝑚𝑜𝑙 𝑁𝑎2 𝐶𝑂3
106 𝑔. 𝑚𝑜𝑙 −1
𝑛
𝑛 = 𝑐𝑉 => 𝑐 =
𝑉
0.01246 𝑚𝑜𝑙
𝑐𝑁𝑎𝐻𝐶𝑂3 = = 0.1246 𝑚𝑜𝑙/𝐿 𝑁𝑎𝐻𝐶𝑂3
0.1 𝐿

0.02333 𝑚𝑜𝑙
𝑐𝑁𝑎2 𝐶𝑂3 = = 0.2333 𝑚𝑜𝑙/𝐿 𝑁𝑎2 𝐶𝑂3
0.1 𝐿

[𝐴− ] [𝐶𝑂 2− ] 0.2333

𝑝𝐻 = 𝑝𝐾𝑎(𝐻𝐶𝑂3 ) + log ([𝐻𝐴]) = 𝑝𝐾𝑎(𝐻𝐶𝑂3 ) + log ([𝐻𝐶𝑂3 −]) = −log(4.7 × 10−11 ) + log( )=
3 0.1246
10.32+0.27 = 10.59 = 10.6 (3 sig figs)

50 mL is half the initial reaction vessel volume.

∴ half the amount of material = half the number of moles in consideration. Concentration is the
same until 10 mL of 0.05 mol / L HCl is added.
∴
0.01246 𝑚𝑜𝑙
𝑛𝑁𝑎𝐻𝐶𝑂3 = = 0.00623 𝑚𝑜𝑙 𝑁𝑎𝐻𝐶𝑂3
2
0.02333 𝑚𝑜𝑙
𝑛𝑁𝑎2 𝐶𝑂3 = = 0.011665 𝑚𝑜𝑙 𝑁𝑎2 𝐶𝑂3
2
𝑛𝐻𝐶𝑙 = 𝑛𝐻3 𝑂 = 0.05 × 0.01 = 0.0005
Also could have worked out cv = ½ cv (mole balance) and proceeded with this method instead.
Now

𝐻𝐶𝑙 + 𝐻2 𝑂 ⇄ 𝐻3 𝑂+ + 𝐶𝑙 − (Dissociation)
𝐶𝑂32− + 𝐻3 𝑂+⇄ 𝐻𝐶𝑂3− + 𝐻2 𝑂
𝐶𝑂32− 𝐻3 𝑂+ 𝐻𝐶𝑂3− 𝐻2 𝑂
I 0.011665 0.0005 0.00623
C -0.0005 -0.0005 +0.0005
E 0.011165 0 6.73 x 10-3
The math predicts all the Hydronium is consumed.
0.011165 𝑚𝑜𝑙
𝐶𝐶𝑂32− = = 0.186 𝑚𝑜𝑙 /𝐿 𝐶𝑂32−
0.06
6.73 x 10−3 𝑚𝑜𝑙
𝐶𝐻𝐶𝑂3− = = 0.112 𝑚𝑜𝑙/𝐿 𝐻𝐶𝑂3−
0.06

[𝐶𝑂32− ] 0.186
𝑝𝐻 = 𝑝𝐾𝑎(𝐻𝐶𝑂3 ) + log ( − ) = − log(4.7 × 10−11 ) + log ( ) = 10.32 − 0.286 = 10.55
[𝐻𝐶𝑂3 ] 0.112
= 10.5 (3 𝑠𝑖𝑔 𝑓𝑖𝑔𝑠)
 𝑁𝑎𝑂𝐻 ⇄ 𝑁𝑎+ + 𝑂𝐻 − (Dissociation)
𝐻𝐶𝑂3− + 𝑂𝐻 − ⇄ 𝐶𝑂3− + 𝐻2 𝑂

0.02 𝑔
𝑛𝑁𝑎𝑂𝐻 = = 5 × 10−4 𝑚𝑜𝑙 𝑁𝑎𝑂𝐻
39.99 𝑔. 𝑚𝑜𝑙 −1

𝐻𝐶𝑂3− 𝑂𝐻 − 𝐶𝑂3− 𝐻2 𝑂
I 0.00623 −4 0.011665
5 × 10
−4 −4
C -5 × 10 -5 × 10 +5 × 10−4
E 5.73x10-3 0 0.012165
The math predicts all the Hydroxide is consumed.
5.73x10−3 𝑚𝑜𝑙
𝑐𝑁𝑎𝐻𝐶𝑂3 = = 0.1146 𝑚𝑜𝑙/𝐿 𝑁𝑎𝐻𝐶𝑂3
0.05 𝐿

0.012165 𝑚𝑜𝑙
𝑐𝑁𝑎2𝐶𝑂3 = = 0.2433 𝑚𝑜𝑙/𝐿 𝑁𝑎2 𝐶𝑂3
0.05 𝐿

[𝐶𝑂32− ] 0.2433
𝑝𝐻 = 𝑝𝐾𝑎(𝐻𝐶𝑂3 ) + log ( − ) = − log(4.7 × 10−11 ) + log ( ) = 10.32 + 0.327 = 10.64
[𝐻𝐶𝑂3 ] 0.1146
= 10.6 (3 𝑠𝑖𝑔 𝑓𝑖𝑔𝑠)

𝑝𝐻 = 10.80
[𝐶𝑂32− ]
𝑝𝐾𝑎(𝐻𝐶𝑂3 ) + log ( ) = 10.80
[𝐻𝐶𝑂3− ]

[𝐶𝑂32− ]
log ( ) = 10.80 − 10.32 = 0.48
[𝐻𝐶𝑂3− ]

[𝐶𝑂32− ]
= 100.48 = 3.0199
[𝐻𝐶𝑂3− ]

The volume is approximately 100mL = 0.1 L

[𝐶𝑂32− ] × 0.1 = 0.1 × 3.0199 × [𝐻𝐶𝑂3− ]

 0.1𝑛𝐶𝑂32− = 0.30199𝑛𝐻𝐶𝑂32−
We do actually need to use the molecular weight of Na2CO2 and NaHCO3
 0.1𝑛𝑁𝑎2 𝐶𝑂3 = 0.30199𝑛𝑁𝑎𝐻𝐶𝑂3
𝑚 = 𝑛𝑀

 0.1 × 106𝑚𝑁𝑎2 𝐶𝑂3 = 0.30199 × 84𝑚𝑁𝑎𝐻𝐶𝑂3

 10.6𝑚𝑁𝑎2 𝐶𝑂3 = 25.37𝑚𝑁𝑎𝐻𝐶𝑂3