Part A Part A Part A Parta - Chemistry Chemistry Chemistry Chemistry

PART A – CHEMISTRY
Sol. [1]
Sol. [3] Θ Θ
RO R–S
Ozone absorbs UV rays from sun and not size size
infrared radiation.
B.S. B.S.
N.S. N.S.
(2) specific rotation
Sol. [1] Sol. [3]

p p Fact
r∝ ∝
d M
1/ 2
rA P M 
= A  B 
rB PB  M A 
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1
Website : www.careerpointgroup.com, Email: info@careerpointgroup.com
Sol. [1]
0.01 1
m= = = 5.55 × 10–4
60 × 0.30 60 × 30
dwater = 1 kg/dm3
at 27ºC is –1366.5 kJ mol–1. The value of
Sol. [2]
Sol. [3] ∆H = ∆E + ∆ngRT
Vmp, Vrms, Vav. ∝ T ∆E = ∆H – ∆ngRT
= –1366.5 – (–1) (8.3 × 10–3) × 300
= –1366.5 + 2.490
= –1364.01
_~ –1364 kJ
Sol. [1]
δ0 δ δ
δ+ Sol. [2]
OH OH OH OH OH
+ H–CH=O Bakelite
NO2 –M
+H CH3 –I –I
+I
(A) (B) (C) (D)
D>C>A>B
2
Sol. [3] Sol. [4]
CH3 C CH3 CH3 CH2 CH O
1 1
O pH = pka – log C
CH3 2 2
1 1
CH3 C CH CH2 CH3 5= pka – log 1
2 2
2-methyl-2-pentene pka = 10
ka = 10–10
Sol. [2]
Cl > F > Br > I
Sol. [3] Order of electron gain enthalpy.
4NO2 + O2 → 2N2O5 ∆H = –111 …(1)
(g)
4NO2 + O2 → 2N2O5 ∆H = ? …(2)
(s)
––––––––––––––––––––––––––––––––––––
2N2O5 → 2N2O5 ∆H = 54 × 2 ...(3)
(s) (g)
––––––––––––––––––––––––––––––––––––
(1) – (3)
∆H = –111 – 108 = –219 kJ
3
Sol. [1]
ν H = ν He +
 2 1 1   2 1 1 
RZ  2 − 2  = RZ  2 − 2 
  n1 n 2  H   n1 n 2  He + Sol. [3]
1 1   1 1  ∆Gº < 0 spontaneous reaction
2
− 2 = 4 − 
n1 n 2   4 16  so Pb +4 → Pb +2
1 1 1 1
2
− 2 = − Pb+2 > Pb+4 (stability)
n1 n 2 1 4
∆Gº > 0 non-spontaneous reaction
n1 = 1
n2 = 2 Sn +4 → Sn +2
Sn+4 > Sn+2 (stability)

Pb+2, Sn+4
Sol. [2]
π1 = π2
c1 = c2
5 1 Sol. [2]
=
342 M Ksp = s(3s)3 = 27s4 = 1.6 × 10–30
342 4
M= = 68.4 1.6 × 10 −30
5 s=
27
4
Sol. [1] Sol. [1]
∆
LiNO3 → Li2O + NO2 + O2 According to spectrochemical series increasing
order of strength of ligands is
NH3 < en < CN– < CO
Sol. [1]
1000 Sol. [2]
λm = κ × (κ = 1.3 S m–1 = 1.3 × 10–2 S cm–1) H2SO4
M C2H5OH C2H5–O–SO3H
110ºC
1 l 1000
= × ×
κ a M 140ºC
C2H5–O–C2H5
1 l
κ= × 170ºC
CH2= CH2
R a
l
= κR = 1.3 × 10–2 × 50 = 65.0 × 10–2 cm–1
a
1 1000
λm = × 65 × 10−2 ×
260 0.4
= 6.25 S mol–1 × cm2
1 1
= 6.25 × × m2
100 100
6.25 × 10–4 m2 S mol–1
5
Sol. [3]
− Ea1
k1 = A1e RT
Sol. [4] − Ea 2
k2 = A 2e RT
Ea 2 Ea1
k 2 A2 − +
= e RT RT
k1 A1
There is no continuous resonance thus it is non-
Ea1 − Ea 2
aromatic. k2
= Ae RT (Ea2 = 2Ea1)
k1
Ea
k2 − 1
= Ae RT
k1
Ea1
−
k2 = Ak1 e RT
Ea1
+
k1 = Ak2 e RT
Sol. [4]
Calcium carbide is a ionic carbide
⇒ Ca2+ [C≡C]2–
It contains 1σ and 2π bonds.
Sol. [2]
4r = 2a
2
r= × 361
4
= 127.61 ~ 128 pm
6
Sol. [3]
XeF2 has maximum number of lone pairs
(3 lone pairs)
Sol. [2]
gm eqv. = gm. Eqv.
of of
Mohr's K2Cr2O7
salt
NV( ml) gm
=
1000 E.w
(0.6 × 1× 750) x
=
1000 294
6
0.6 × 750 294 75 × 294
x= × =
1000 6 1000 Sol. [1]
= 22.05 gm NH2 N=N–Cl CN
NaNO2/HCl CuCN
Sand
mayer
reaction
Sol. [2]
3+ 3+
Sol. [1] NH3 NH3
Na2O + H2O → 2NaOH NH3
Co en Co en
en
en NH3
cis trans
It has geometrical isomers.
7
PART B – PHYSICS
Ans.[1]
Sol. I =4I0 cos2φ/2
IP = 4I0 cos20 = 4I0 ….(1)
 π  4I
IQ = 4I0 cos2   = 0 = 2I0 ….(2)
4 2
IP
=2
IQ
Ans.[3]
1 2
Sol. K.E. ∝ t i.e., mv ∝ t
2
v∝ t
dv 1
a= ∝ , F = ma
dt 2 t
1
F∝
t
Ans.[1]
Gm 2 mv 2
Sol. =
(2R ) 2 R
GM
v=
4R
m
R
8
Ans.[1]
r r r
Sol. Magnetic force F = q(V × B ) = 10q ˆj
Ans.[3] r
Sol. F1 = mg sinθ + µmg cosθ ...(i) and electric force in direction of y-axis F = q ˆj
F2 = mgsinθ – µmgcosθ ...(ii)
FNet = 11q in direction of y-axis.
θ
F1 tan θ + 1 2µ + µ 3
= = =
F2 tan θ − 1 2µ − µ 1
Ans.[3]
V AB i × ρ
Sol. φ= = = 0.1 volt/meter
Ans.[1] L A
Sol. R = R1 + R2 + R3 +R4 = 400 Ω
∆R ∆[ R 1 + R 2 + R 3 + R 4 ]
% = × 100
R 400
20
= × 100 = 5 %
400
9
Ans.[3] Ans.[2]
Sol. Sol. ∆Q = mCpdT
  T  
3
v = (100 × 10–3) × 32 ×    [100 − 0]
  400  
v' = v cos 30º
θ = 30º r = H = 0.002 KJ
L = mv′r T2 Q
β= = 2; T2 = 300 K, Q2 = 0.002 KJ
T1 − T2 W
 v 2 sin 2 30º 
= m(vcos30º)  

 2 g  If T1 = 20 K, W = 0.148 KJ
mv3 3 1 T2 = 4 K, W = 0.028 KJ
= ×
2g 2 4
i.e., amount of work will be between 0.148 KJ
3
3mv to 0.028 KJ.
=
16
10
Ans.[4]
Sol. It is free expansion of Ideal gas which is both
Ans.[1] adiabatic and isothermal process.
Sol. T → constant, so for the isothermal process

P1V1 = (P2V2)
P1V1 = P2 (2V1)
x P1
L P2 =
L 2
Restoring force FR = (L2x)ρg ... (1)

2
In case of SHM FR = mω x ...(2)
From equation (1) & (2)
mω2x = L2xρg
(d)L3ω2 = L2ρg
dLω2 = ρg
ρg
ω=
dL
dL
T = 2π
ρg
11
Sol.
OR gate NOT gate
NOR gate
Ans.[1]
Sol. I1 = 4I0cos2φ/2 = 4I0 …. (1)
I2 = I0 + I0 = 2I0 …. (2)
(for non coherent sources)
I1 2
=
I2 1
Ans.[4]
Sol. W = q (∆V) = ∆KE
q –q
A B
q –q
Kq Kq Kq Kq
VA = + − −
a a 2a 2a
VB = 0
2 Kq  1 
W= 1 − 
Ans.[2] a  5
12
Ans.[3]
0.693 × R × 2C = 10
Sol.
C
0.693 × R × = T
2
2 / 1 10
⇒ = Ans.[2]
1/ 2 T
4 10
⇒ =
1 T Sol. Actual depth = (h1 + h2)
T = 2.5 sec
h1 h2
Apparent depth = +
µ1 µ 2
h h 
Shift ⇒ (h1 + h2 ) −  1 + 2 
 µ1 µ 2 
 1   1 
⇒ h1 1 −  + h2 1 − 
 µ1   µ2 
13
Sol.
λ/4 λ/2
O 3λ/4
Y1 = A sin (ωt – kx)

Y2 = A sin (ωt + kx)
→ → →
YR = Y1 + Y2 = 2A coskx sin ωt
λ 3λ 5λ
So, nodes will be at , , .....
4 4 4
Ans.[2]
Stress
Sol. Y=
Strain
∆L L α ∆t
Strain = = = αt
L L
Stress = Y α t
Ans.[3]
Sol.
dx
x
q
M = i× A= × πR 2
T
dq
dM = × πx 2
T
σ × dA
= × πx 2
T
Ans.[4]
14
σ × 2πx dx × πx 2
dM = ω
2π
∫
M = σ × ω x 3dx
R
 x4  σ × ωR 4
= σ × ω×   =
 4  4
 0
Ans.[3]
Sol. Volume of big drop = total volume of small
drops
R = 21/3r
Surface energy of small drops U = 2T 4πr2
Surface energy of big drop
U' = T4πR2
Ans.[4]
= T 4π(21/3)2r2
Sol. γ = 3α = 3 × 23 × 10 = 69 × 10 /ºC
–6 –6
= T 4π(2)2/3 r2
U' = T(2)2π 22/3 r2
4 3 4
Q V= πr = π × (10 × 10 −2 ) 3 U' = T(2)8/3 πr2
3 3
4
= × π × 10 −3
3
Change in volume (∆V)
V' – V = Vγ∆t
4 
=  πR 3 × 69 × 10 −6  × (100 − 0)
 3 
= 28.9 cc
Ans.[1]
15
2r 2 Sol. Acceleration to momentum conservation, linear
Sol. V= g{d b − d l }
9η momentum of both point is same So
wavelength is also same.
V1 η2  d − d1 
=  
V2 η1  d − d 2 
10 13.2  7.8 − 1 
=  
V 8.5 × 10 − 4  7.8 − 1.2 
V = 6.25 × 10–4 cm/s
Ans.[1]
Sol. Time is not dependent on modulation.
Ans.[1]
Sol. e=B×v×l
= 0.30 × 10–4 × 5 × 20
= 3 millivolt
Ans.[4]
Sol.
lA lB
l = lA + lB
lA 2
=
lB 3
1
K∝ ... (1)
l
1
KA ∝ ... (2)
lA
From (2)/(1)
Ans.[3]
16
KA
=
l p1 → 0 n1 + +1 e 0 + v
1 44
K lA 1 42444 3
K {l A + l B }
KA =
lA
 l 
K A = K 1 + B 
 lA 
 3
K A = K 1 + 
 2
5K
KA =
2
Ans.[1]
1
Sol. = (µ − 1)( k )
f
f∝λ
fR > f V
so increases.
Ans.[2]
Sol. Maximum energy = End point energy
= E 1 – E2
Three particles at least required
0 n →1 p + −1 e + v
1 1 0
1 4442444 3 Ans.[2]
17
Sol. Statement-I → Polarisation Ans.[3]
Statement-II → Raylegh's criteria Sol. a1 = 2a, a2 = a
1
Scattering ∝ 4 ω1 = ω, ω2 = 2ω
λ
So statement I and II both correct statement-II I ∝ a2n2 (for same medium)
is the correct explanation of statement-I.
So I1 = I2 statement-I (True)
Statement-II
n → constant
I ∝ a2
I = ka2 (statement -II True )
But no correct explanation, because of
frequency.
18
PART C – MATHEMATICS
Sol. [4]
If H is scalar matrix
x 0 
H=  
0 x
x n 0
Hn =  
0 xn 
ω70 0  ω 0 
⇒ H70 =   =   =H
 0 ω70   0 ω
Sol. [2]
f(x) = (x – 1)2 + 1 = y
(x –1)2 = y – 1
x–1=± y −1
x=1± y −1
f–1(y) = 1 ± y −1
f–1(y) = 1 + y −1 Q y≥1
Statement 2 is true
f(x) = f–1(x)
(x –1)2 + 1 = 1 + x −1
Sol. [3]
(x – 1)2 = x −1 1.5 1 2 1.5
∫ x[ x ∫
]dx = 0 dx + ∫ x dx + ∫ 2 x dx
2
Solving these we get x = 1, 2
0 0 1 2
Statement –1 is true.
19
2
 x2 
( )
1.5
= 0 +   + x 2
 2 1
2
 1 3
= 1 −  + (2.25 − 2) =
 2 4
Sol. [1]
There is no change in mean deviation if each
observation increased by a constant number
while mean increased by that constant number
Hence
Sol. [2]
A.M. = 30 + 2 = 32
(0, 3) M.D. = 2
(x, y)
(a, 0)
a b
x= , y=
2 2
⇒ a = 2x b = 2y
dy −b
& =
dx a
dy − y dy dx
⇒ = ⇒ =−
dx x y x
dy dx
⇒ ∫y ∫
=−
x
⇒ log y = – log x + log c ⇒ xy = c
Q it passes through (2, 3)
∴c=6 Sol. [2]
∴ equation of curve is xy = 6 x+y=±a x+y=|a|
ax – y = 1 ax – y = 1
(1 + a)x = |a| + 1 ax + ay = a|a|
| a | +1
x= (a + 1)y = a|a| – 1
1+ a
a | a | −1
y=
1+ a
20
| a | +1 a | a | −1 Equation of PQ
>0, >0
1+ a 1+ a x −1 y + 5 z − 9
⇒ = = =λ
1 1 1
⇒a>1 ⇒ Q(λ + 1, λ – 5, λ + 9)
lies on x – y + z = 5
λ + 1– λ + 5 + λ + 9 = 5
λ = –10
Q = (–9, –15, –1)
PQ = ( −9 − 1) 2 + ( −5 + 15) 2 + (9 + 1) 2
= 10 3
→ → → → →
a + 3 b i s collinear wi th c and b + 2 c
Sol. [4]
p 1 1
1 q 1 =0
1 1 r
p(qr – 1) – 1 (r – 1) + 1 (1 – q) = 0
pqr – p – r + 1 + 1 – q = 0
pqr – (p + q + r) + 2 = 0
Sol. [3]
r r r
a + 3b = λc
r r r
b + 2c = µa
r r r r
b + 2c = µ(λc − 3b )
r r r r
b + 2c = λµc − 3µb
r r
(1 – 3µ) b + (2 – λµ) c = 0
1 + 3µ = 0 2 – λµ = 0
1
µ= − λµ = 2
Sol. [1] 3
P(1,–5, 9) λ = –6
r r r
a + 3b + 6c = 0
21
 1
sin , if x ≠ 0
f2(x) =  x
 0, if x = 0
Sol. [2]
A (2, –3) B(–2, 1)
Centroid, (h, k)
Let third vertex is (α, β)
2−2+α −3 + 1 + β
=h, =k
3 3
⇒ α = 3h
⇒ β = 3k + 2
Q 2α +3β = 9
2(3h) + 3(3k + 2) = 9
6h + 9k + 6 = 9
6h + 9k = 3
2h + 3k = 1
locus 2x +3y = 1
Sol. [1]
Max. traingles = 10C3 – 6C3
= 120 – 20
= 100
∴ N ≤ 100
22
Sol. [3] = 7.λ + (k7 – k)
f1(x) = x is continuous every R
= 7λ + 7λ′ = 7.(λ + λ′)
 1
sin ; x ≠ 0
& f2(x) =  x is discontinuous at x = 0 which is divisible by 7.
 0 x=0
∴ Statement - 2 is true
⇒ product of f 1(x) and f2(x) is continuous
∴ St. (1) is correct and (2) is false Statement -1
n7 – n is divisible by 7
⇒ use it put n = n + 1
(n + 1)7 – (n + 1) = 7λ True
⇒ [(n + 1)7 – n7 –1] + (n7 – n) = 7λ
= Stanement -1 + 7λ′ = 7λ
statement-1 is true and statement-2 is also
correct explanation of Statement -1.
Sol. [2]
Points will be end of diameter
(x – 1) (x – 0) + (y – 0) (y – 1) = 0
Sol. [1] x2 + y2 – x – y = 0
By induction, to proof
S(n) = n7 – n is divisible by 7
Let n = 1
S(n = 1) = 17 – 1 = 0 ÷ 7,
Hence it is true for n = 1
Let the statement is true for n = k
⇒ P(n = k) ⇒ k7 – k is divisible by 7.
⇒ k7 – k = 7λ′.
Now to proof the statement is true for n = k + 1
⇒ P(n = k + 1) ⇒ (k + 1)7 – (k + 1) is Sol. [2]
ae = 2
divisisble by 7 e=2
a=1
[1 + 7C1 k + 7C2 k2 + ..... + 7C6 k6 + k7] – k – 1
23
b2
e2 = 1 +
a2
4 = 1 + b2
b2 = 3
x2 y2
− =1
1 3
Sol. [1]
Let quadratic equation be
x2 + bx + c = 0
α+β=4+3=7=–b
b=–7
α . β = 3.2 = 6 = c
∴ correct quadratic equation
x2 – 7x + 6 = 0
(x – 1) (x – 6) = 0
x = 1, 6
Sol. [1]
∆ ≠ 0 for trivial solution.
1 −k 1
k 3 −k ≠0
3 1 −1
k2 + k – 6 ≠ 0
k ∈ R – {–3, 2}
24
Sol. [2]
100
∑a
r =1
2r =α
100
∑a
r =1
2 r −1 +d =α
100 100
∑
r =1
a2 r −1 + ∑d = α
r =1
Sol. [3]
β + 100d = α
dy y2
α −β =−
d= dx x−
1
100 y
1
x−
dx y
=− 2
dy y
dx x 1
+ 2 = 3
dy y y
1 1
∫ y 2 dy −
I.F. = e =e y
1
x.e −1/ y = ∫y 3
.e −1/ y dy
1
∫ t · e dt t=−
t
=–
I II y
{ ∫
= – tet − 1.et dt }
xe −1/ y = – tet + et + c
25
1 −1/ y
xe−1 / y = + e + e −1/ y + c
y
1
x= + 1 + ce1/y
y
at x = 1, y = 1 1 = 2 + ce1
c = – 1/e
1 1
x= + 1 − e1/ y
y e
Sol. [4]
Statement-1 is true
Statement-2 is false
Sol. [4]
|A'| = |A| ⇒ true
( f ( x)) 2 − 9
lim =0 |–A| = (–1)n |A| ⇒ false
x→ 5 | x −5|
Limit can be zero only when Statement-2 is false
lim f(x) = 3
x→ 5
26
π 5π π 2π 3π 8π
(1) , , , , ,
4 12 2 3 4 9
Sol. [4]
y2 = 4ax & x2 = 4by
16ab
Area bounded by these curve is
3
Sol. [4] here a = b = 1
16
2 sin 4θ cos 3θ + sin 4θ = 0 ∴A=
3
sin 4θ (2 cos 3θ + 1) = 0
1
sin 4θ = 0 cos 3θ = –
2
nπ 2π
θ= 3θ = 2nπ ±
4 3
2π
θ = (3n ± 1)
9
Put n ∈ I
π π 3π 2π 8π 4π
θ= , , , , ,
4 2 4 9 9 9
27
Sol. [3]
A B A ∧ B A ∨B A→B [A ∧ (A→B)] S→B
T T T T T T T
T F F T F F T
F T F T T F T
F F F F T F T
Hence [A ∧ (A → B)] → B is tautology
Sol. [2]
Since we know in neighbourhood of x = 0,
tan x
> 1 & f(0) = 1
x  A∩B 
∴ x = 0 is point of minima Sol. [4] P 
f ( x) − f (a)  C 
& f ' ( a) = lim
x→ a x−a P( A ∩ B ∩ C )
=
tan P(C )
−1
f ( x) − f (0)
⇒ f ' (0) = lim = lim x P(C ) − P( A ∩ C ) − P ( B ∩ C ) + P ( A ∩ B ∩ C )
x→ 0 x−0 x→ 0 x =
tan x − x P(C )
⇒ lim =0
x→ 0 x2 = 1 – P(A) – P(B)
∴ St. (1) & (2) both correct but (2) is not
correct explanation of (1) = P( A ) − P ( B ) or P( B ) − P ( A)
28
P(3, –1, 11)
L
Q
x y−2 z −3
= = =λ
2 3 4
Q = (2λ, 3λ + 2, 4λ + 3)
D.rs of PQ = 2λ – 3, 3λ + 3, 4λ – 8
Q L ⊥ PQ
⇒ 2(2λ – 3) + 3(3λ + 3) + 4 (4λ – 8) = 0
⇒ 4λ – 6 + 9λ + 9 + 16λ – 32 = 0
29λ = 29 ⇒ λ = 1
⇒ Q ≡ (2, 5, 7)
Sol. [4] PQ = (3 − 2) 2 + (−1 − 5) 2 + (11 − 7) 2
0 = (a – a1) – (b – b1) + (c – c1) …(1) = 1 + 36 + 16

2 = (a – a1) 4– (b – b1)2 + (c – c1) …(2) = 53
p(0) = c – c1 = 2 ⇒ Q (x = – 1) is only root

∴D = 0 of p(x) = 0 ⇒ p(–2) = p(0) = c – c1 = ?
To find (a – a1) 4 + 2 (b – b1) + (c – c1) = p(2)
Let a – a1 = x and b – b1 = y
∴ 2x – 2y + 4 = 0 …(1)
4x – 2y + 2 = 2 …(2)
⇒ x = 2, y = 4
= 8 + 8 + 2 = 18
Sol. [3]
29
Sol. [4]
Statement -1
A = P–1 B P
PA = BP
P = {(A, A) | PA ≠ AP in general not
reflexive. So not equivalence relation.
Statement-2
(MN)–1 = N–1M–1 True
from defination.
Sol. [3]
x 2 f (a ) − a 2 f ( x ) 0 
lim  form 
x→ a x−a 0 
Applying D.L.
2
lim 2xf(a) – a f '(x)
x→ a
= 2a f(a) – a2 f ' (a)
30

Part A Part A Part A Parta - Chemistry Chemistry Chemistry Chemistry

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Part A Part A Part A Parta - Chemistry Chemistry Chemistry Chemistry

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PART A – CHEMISTRY

(2) specific rotation

Sol. [1] Sol. [3]

Sn+4 > Sn+2 (stability)

Sol. Sol. ∆Q = mCpdT

Ans.[1] adiabatic and isothermal process.

Sol. T → constant, so for the isothermal process

Restoring force FR = (L2x)ρg ... (1)

OR gate NOT gate

Y1 = A sin (ωt – kx)

Change in volume (∆V)

Sol. [4] PQ = (3 − 2) 2 + (−1 − 5) 2 + (11 − 7) 2

0 = (a – a1) – (b – b1) + (c – c1) …(1) = 1 + 36 + 16

p(0) = c – c1 = 2 ⇒ Q (x = – 1) is only root

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