Jee Main 2019 Jan Chem

#23-3-39,BESIDE CANARA BANK,MR PALLI,TIRUPATI-517502
CELL NO.9440517000
JEE MAIN
2019(JAN)
SUPER 240
CHEMISTRY
CAREER POINT JEE Main Online Paper
JEE Main Online Exam 2019

Questions & Solutions
9th January 2019 | Shift - I
CHEMISTRY
Q.1 In general, the properties that decrease and increase down a group in the periodic table, respectively, are -
(1) electronegativity and atomic radius. (2) electronegativity and electron gain enthalpy.
(3) atomic radius and electronegativity. (4) electron gain enthalpy and electronegativity.
Ans. [1]
Sol. Down the group electronegativity of Atoms decreases and Atomic radius increases.
Q.2 The major product of following reaction is :

(1) AlH ( i  Bu )
R–CN   2  ?
( 2) H 2 O
(1) RCHO (2)RCOOH (3) RCONH2 (4) RCH2NH2

Ans. [1]
(1) AlH ( i  Bu )
O
Sol. R–CN     2  ||
DiBAl  H R CH
DiBAL reduces cyanide, ester and acid halide upto aldehyde only.
Q.3 Which amongst the following is the strongest acid ?

(1) CHBr3 (2) CHCl3 (3) CH(CN)3 (4) CHI3
Ans. [3]
Sol. Acidic strength  stability of Anion after loosing proton  EWG – I, – M, –H

(1) CHBr3  C Br3

(2) CHCl3  C Cl3

(3) CH(CN)3  NC – C C  N – ve charge stabilize by – M of three C  N group
|
CN

(4) CHI3  C I 3
3 is most acidic
#23-3-39,BESIDE CANARA BANK,MR PALLI,TIRUPATHI-517502;CELL NO.9440517000

Q.4 Arrange the following amines in the decreasing order of basicity :
N N N
H H
I II III
(1) I > III > II (2) III > I > II (3) I > II > III (4) III > II > I
Ans. [2]
Sol. Basic strength order
III > I > II
> >
N N N
sp3
sp2
H H
.p. of N do not .p. of N do not .p. of N
participate in participate in participate in
resonance resonance but resonance
hybridization of
N is sp2 (more
% s less basic)
Q.5 The ore that contains both iron and copper is -

(1) dolomite (2) malachite (3) copper pyrites (4) azurite
Ans. [3]
Sol. Copper pyrities CuFeS2
Malachite Cu(OH)2 . CuCO3
Azurite Cu(OH)2 . 2 CuCO3
Dolomite CaCO3 . MgCO3
Q.6 The anodic half cell of lead-acid battery is recharged using electricity of 0.05 Faraday. The amount of PbSO4
electrolyzed in g during the process is : (Molar mass of PbSO4– = 303 g mol–1)
(1) 15.2 (2) 7.6 (3) 11.4 (4) 22.8
Ans. [2]
Sol. Anodic half cell : Pb+2 + 2H2O  PbO2 + 4H+ + 2e–
n Pb  2 ne 

1 2
n PbSO 4 0.05

1 2
0.05
WPbSO 4 = × 303 = 7.6 g
2
Q.7 Correct statements among a to d regarding silicones are -

(a) They are polymers with hydrophobic character.
(b) They are biocompatible.
(c) In general, they have high thermal stability and low dielectric strength.
(d) Usually, they are resistant to oxidation and used as greases.
(1) (a), (b) and (d) only (2) (a), (b) and (c) only (3) (a), (b), (c) and (d) (4) (a) and (b) only
Ans. [1]
Sol. These are the properties and uses of silicones.

Q.8 The following results were obtained during kinetic studies of the reaction :
2A + B  Products
[A] [B] Initial Rate of reaction

Experiment –1 –1
(in mol L ) (in mol L ) (in mol L–1 min–1)
I 0.10 0.20 6.93 × 10–3
II 0.10 0.25 6.93 × 10–3
III 0.20 0.30 1.386 × 10–2
The time (in minutes) required to consume half of A is -
(1) 5 (2) 1 (3) 100 (4) 10
Ans. [1]
Sol. 6.93 × 10–3 = k × (0.1)x (0.2)y
6.93 × 10–3 = k × (0.1)x (0.25)y
So y = 0
and 1.386 × 10–2 = k (0.2)x (0.30)y
x
1 1
=   x=1
2 2
So r = k × (0.1) × (0.2)0
6.93 × 10–3 = k × 0.1 × (0.2)0
k = 6.93 × 10–2
0.693 0.693 10
t1/2 = = 1
= =5
2k 0.693  10  2 2
Q.9 The major product of the following reaction is :

(i) Br2
(ii) EtOH
OEt OEt OEt Br
Br OEt OEt
(1) (2) (3) (4)
Ans. [2]
Sol.
Br2
Br2 Br2
Electrophilic Addition
EtOH
(SN1)
OEt
Br

Q.10 The one that is extensively used as a piezoelectric material is -
(1) mica (2) quartz (3) amorphous silica (4) tridymite
Ans. [2]
Sol. Quartz is used in Piezoelectric material (Fact)
Q.11 0.5 moles of gas A and x moles of gas B exert a pressure of 200 Pa in a container of volume 10 m3 at 1000 K.
Given R is the gas constant in JK–1 mol–1, x is -
2R 4R 4R 2R
(1) (2) (3) (4)
4R 2R 2R 4R
Ans. [3]
Sol. PV = nRT
200 × 10 = (0.5 + x) R × 1000
2
0.5 + x =
R
4R
x=
2R
Answer should be 3 but NTA has given answer 2. Which is not correct.
 1 
Q.12 For emission line of atomic hydrogen from n1 = 8 to nf = n, the plot of wave number (  ) against  2  will
n 
be (The Rydberg constant, RH is wave number unit)
(1) Linear with slope – RH (2) Linear with slope RH
(3) Non linear (4) Linear with intercept – RH
Ans. [2]
1  1 1 
Sol. = RH  
 n 2 2
 1 n2 
 1 1 
 = RH  2  2 
n 8 
1
Slope of the curve ( v Vs 2 ) is + RH
n
Answer should be 2 but NTA has given answer 1. Which is not correct.
Q.13 Major product of the following reaction is :

Cl
Cl NH2
+ H2N (1) Et3N
O O (1) Free radical
polymerisation
Cl Cl
O
(1) n NH2 (2) n NH2
O N N
H O
O H
O Cl
Cl O
n
(3) n O (4) HN
NH2
HN
NH2 O

Ans. [1]
Sol.
Cl
Cl NH2
+ H2 N
O O
Better
Nu atom
Nucleophilic
Substitution reaction
Cl
NH
O
O
Free radical
(Addition Polymerisation)
Cl
C n
O NH
O
Q.14 The correct decreasing order for acid strength is :

(1) NO2CH2COOH > FCH2COOH > CNCH2COOH > ClCH2COOH
(2) CNCH2COOH > O2NCH2COOH > FCH2COOH > ClCH2COOH
(3) FCH2COOH > NCCH2COOH > NO2CH2COOH > ClCH2COOH
(4) NO2CH2COOH > NCCH2COOH > FCH2COOH > ClCH2COOH
Ans. [4]
Sol. Acidic strength order  EWG – M1 – H1 – I
In given example only –I of substituent is applicable
–I order – NO2 > – CN >– F > –C
Acidic strength order = NO2–CH2–COOH > NC–CH2–COOH > F – CH2 – COOH > Cl – CH2 – COOH
Q.15 20 mL of 0.1 M H2SO4 solution is added to 30 mL of 0.2 M NH4OH solution. The pH of the resultant
mixture is : [pKb of NH4OH = 4.7].
(1) 5.2 (2) 9.4 (3) 9.0 (4) 5.0
Ans. [3]
Sol. H2SO4 + 2NH4OH  (NH4)2SO4 + 2H2O
t=0 2millmole 6 millimole
t=t 0 2 millimole 2 millimole
[Salt ]
 POH = Pkb + log
[ Base]
4 / 50
POH = 4.7 + log
2 / 50
 POH = 4.7 + 0.3 = 5
 PH = 9.

Q. The alkaline earth metal nitrate that does not crystallize with water molecules, is
(1) Ba(NO3)2 (2) Mg(NO3)2 (3) Ca(NO3)2 (4) Sr(NO3)2
Ans. [1]
Sol. (1) Compounds of Barium does not contains water of crystallization due to large size of Barium ion.
Q.17 Consider the reversible isothermal expansion of an ideal gas in a closed system at two different temperatures
T1 and T2 (T1 < T2). The correct graphical depiction of the dependence of work done (W) on the final volume
(V) is -
|W| T2 |W| T2
T1
T1
(1) (2)
O n V O n V
|W| T2 |W| T2
T1
T1
(3) (4)
O n V O n V
Ans. [1]
v2
Sol. |W| = nRT ln
v1
|W| = nRT nV2 – nRT nV1
 Intercept is negative and intercept of curve 2 is more negative.
Q.18 Adsorption of a gas follows Freundlich adsorption isotherm. IN the given plot, x is the mass of the gas
x
adsorbed on mass m of the adsorbent at pressure P . is proportional to :
m
x 2 unit
Log 4 unit
m
Log P
(1) P (2) P1/2 (3) P2 (4) P1/4
Ans. [2]
x
Sol. = k(P)1/n
m
x 1
log = log k + log P
m n
1
Slope =
n
1
From graph, slope =
2
x
 n=2  (P)1/2
m

Q.19 The increasing order of pKa of the following amino acids in aqueous solution is :
Gly Asp Lys Arg
(1) Asp < Gly < Lys < Arg (2) Arg < Lys < Gly < Asp
(3) Gly < Asp < Arg < Lys (4) Asp < Gly < Arg < Lys
Ans. [1]
1
Sol. Acidic strength   EWG
Ka pKa
pKa = – log Ka
Glycine Aspartic Lysine
(Gly) acid
( Lys )
NH 2 CH 2 COOH ( Asp ) NH 2
HOOC CH 2 CH  COOH |
| NH 2 ( CH 2 ) 4 CH COOH
NH 2
NH 2
|
Arginine NH  C  NH(CH 2 ) 3  CH  COOH
( Arg ) |
NH 2
Acidic strength in solution  ASP > Gly > Lys > Arg
pKa order should be  Asp < Gly < Lys < Arg
[Though data suggest this is order of Isoelectric pH value]
Q.20 According to molecular orbital theory, which of the following is true with respect to Li2 + and Li2– ?
(1) Both are unstable (2) Both are stable
(3) Li2 + is stable and Li2– is unstable (4) Li2+ is unstable and Li2– is stable
Ans. [2]
Sol. Li2+ (5e–) = 1s2, 1s2, 2s1
Li2– (7e–) = 1s2, *1s2, 2s2, *2s2
Bond order of Li2+ = 0.5
Bond order of Li2– = 0.5
Both Li2+ and Li2– has non-zero bond order and hence both are stable.
Q.21 A water sample has ppm level Fe = 0.2; Mn = 5.0 ; Cu = 3.0 ; Zn = 5.0. The metal that makes the water
sample unsuitable for drinking is :
(1) Zn (2) Fe (3) Cu (4) Mn
Ans. [4]
Sol. Permissible values
Zn = 5 ppm
Fe = 0.2 ppm
Mn = 0.05 ppm
Cu = 3.0 ppm

Q.22 Two complexes [Cr(H2O)6]Cl3 (A) and [Cr(NH3)6]Cl3 (B) are violet and yellow coloured, respectively. The
incorrect statement regarding, them is -
(1) 0 value for (A) is less than that of (B).
(2) both absorb energies corresponding to their complementary colors.
(3) 0 values of (A) and (B) are calculated. From the energies of violet and yellow light, respectively.
(4) both are paramagnetic with three unpaired electrons.
Ans. [3]
Sol. 0 order will be compared by spectro-chemical series not by energies of violet and yellow light so
0 order is [Cr(H2O)6]Cl3 < [Cr(NH3)6]Cl3
Br
(1) KOH (aqueous)
Br (2) CrO3/H+
(3) H2SO4/
O O O O
(1) (2) (3) (4)

Br HO Br HO
Ans. [1]
Sol.
Br OH
Aq kOH
Br SN2 Br
CrO3/H
Oxidising agent
C  OH
O ||
 H SO / O
2 4
Br Br
Intramolecular
Fridel craft
reaction
Br
Q.24 Which one of the following statements regarding Henery’s law is not correct ?
(1) Different gases have different KH (Henry’s law constant) values at the same temperature.
(2) The partial pressure of the gas in vapour phase is proportional to the mole fraction of the gas in the
solution.
(3) The value of KH increases with increase of temperature and KH is function of the nature of the gas.
(4) Higher the value of KH at a given pressure, higher is the solubility of the gas in the liquids.
Ans. [4]
Sol. Solubility of gas increases due to increase in Henery const. is wrong statement.

Q.25 The compound A and B in the following reaction are, respectively :
HCHO + HCl AgCN
A B
(1) A = Benzyl alcohol, B = Benzyl cyanide (2) A = Benzyl chloride, B = Benzyl cyanide
(3) A = Benzyl alcohol, B = Benzyl isocyanide (4) A = Benzyl chloride, B = Benzyl isocyanide
Ans. [4]
Sol.
O CH2–OH CH2–Cl
||
H  C  H / H HCl
 SN1 A
C H 2  OH Benzyl chloride
Electrophile
[ ESR reaction]
AgCN
CH2–NC
B
Benzyl Isocynide
Q.26 The highest value of the calculated spin only magnetic moment (in BM) among all the transition metal
complexes is -
(1) 6.93 (2) 5.92 (3) 4.90 (4) 3.87
Ans. [2]
Sol. Metal complex can contain maximum 5 unpaired e– in d-subshell of metal
 = n ( n  2) BM
n = no. of unpaired e–
n=5
= 5(5  2) BM
 = 35 = 5.92 BM
Ex. Mn+2 complex
Q.27 A solution of sodium sulfate contains 92 g of Na+ ions per kilogram of water. The molality of Na+ ions in that
solution in mol kg–1 is :
(1) 8 (2) 4 (3) 12 (4) 16
Ans. [2]
moles of Na  92 / 23
Sol. m= = =4m
mass of H 2O in kg 1
Q.28 The correct match between Item-I and Item-II is :

Item-I Item-II
(drug) (test)
(A) Chloroxylenol (P) Carbylamine test
(B) Norethindrone (Q) Sodium hydrogen carbonate test
(C) Sulphapyridine (R) Ferric chlorie test
(D) Penicillin (S) Bayer’s test
(1) A  R ; B  S ; C  P ; D  Q (2) A  Q ; B  P ; C  S ; D  R
(3) A  Q ; B  S ; C  P ; D  R (4) A  R ; B  P ; C  S ; D  Q
Ans. [1]

Q.4 Arrange the following amines in the decreasing order of basicity :
N N N
H H
I II III
(1) I > III > II (2) III > I > II (3) I > II > III (4) III > II > I
Ans. [2]
Sol. Basic strength order
III > I > II
> >
N N N
sp3
sp2
H H
.p. of N do not .p. of N do not .p. of N
participate in participate in participate in
resonance resonance but resonance
hybridization of
N is sp2 (more
% s less basic)
Q.5 The ore that contains both iron and copper is -

(1) dolomite (2) malachite (3) copper pyrites (4) azurite
Ans. [3]
Sol. Copper pyrities CuFeS2
Malachite Cu(OH)2 . CuCO3
Azurite Cu(OH)2 . 2 CuCO3
Dolomite CaCO3 . MgCO3
Q.6 The anodic half cell of lead-acid battery is recharged using electricity of 0.05 Faraday. The amount of PbSO4
electrolyzed in g during the process is : (Molar mass of PbSO4– = 303 g mol–1)
(1) 15.2 (2) 7.6 (3) 11.4 (4) 22.8
Ans. [2]
Sol. Anodic half cell : Pb+2 + 2H2O  PbO2 + 4H+ + 2e–
n Pb  2 ne 

1 2
n PbSO 4 0.05

1 2
0.05
WPbSO 4 = × 303 = 7.6 g
2
Q.7 Correct statements among a to d regarding silicones are -

(a) They are polymers with hydrophobic character.
(b) They are biocompatible.
(c) In general, they have high thermal stability and low dielectric strength.
(d) Usually, they are resistant to oxidation and used as greases.
(1) (a), (b) and (d) only (2) (a), (b) and (c) only (3) (a), (b), (c) and (d) (4) (a) and (b) only
Ans. [1]
Sol. These are the properties and uses of silicones.

Q.8 The following results were obtained during kinetic studies of the reaction :
2A + B  Products
[A] [B] Initial Rate of reaction

Experiment –1 –1
(in mol L ) (in mol L ) (in mol L–1 min–1)
I 0.10 0.20 6.93 × 10–3
II 0.10 0.25 6.93 × 10–3
III 0.20 0.30 1.386 × 10–2
The time (in minutes) required to consume half of A is -
(1) 5 (2) 1 (3) 100 (4) 10
Ans. [1]
Sol. 6.93 × 10–3 = k × (0.1)x (0.2)y
6.93 × 10–3 = k × (0.1)x (0.25)y
So y = 0
and 1.386 × 10–2 = k (0.2)x (0.30)y
x
1 1
=   x=1
2 2
So r = k × (0.1) × (0.2)0
6.93 × 10–3 = k × 0.1 × (0.2)0
k = 6.93 × 10–2
0.693 0.693 10
t1/2 = = 1
= =5
2k 0.693  10  2 2

(i) Br2
(ii) EtOH
OEt OEt OEt Br
Br OEt OEt
(1) (2) (3) (4)
Ans. [2]
Sol.
Br2
Br2 Br2
Electrophilic Addition
EtOH
(SN1)
OEt
Br

Q.4 In which of the following processes, the bond order has increased and paramagnetic character has changed to
diamagnetic?
(1) NO  NO+ (2) O2  O2+
(3) N2  N2+ (4) O2  O22–
Ans. [1]
Sol.
Process Change in Magnetic nature Bond order change
N2  N2+ Dia  Para 3  2.5
NO  NO+ Para  dia 2.5  3
O2  O2–2 Para  dia 21
O2  O2+ Para  Para 2  2.5
Q.5 The complex that has highest crystal field splitting energy (), is :
(1) K3[Co(CN)6] (2) K2[CoCl4]
(3) [Co(NH3)5Cl] Cl2 (4) [Co(NH3)5(H2O)Cl3]
Ans. [1]
Sol. Complex K3 [Co(CN)6] have CN– ligand which is a strong field ligand amongst the given ligands in all
complexes, therefore CFSE is highest.
Q.6 For the following reaction, the mass of water produced from 4.45 g of C57H110O6 is :
2C57H110O6(s) + 163O2(g)  114CO2(g) + 110 H2O()
(1) 445g (2) 490 g (3) 495g (4) 890 g
Ans. [3]
445
Sol. Moles of C57H10O6 = = 0.5
890
n C57H110O6 n H 2O
=
2 110
n H 2 O = 55 × 0.5 × 18 = 495 gm
Q.7 If the standard electrode potential for a cell is 2 V at 300 K, the equilibrium constant (K) for the reaction
Zn(s) + Cu2+ (aq) Zn2+ (aq) + Cu(s)
At 300 K is approximately
(R = 8JK–1 mol–1, F = 96000 C mol–1)
(1) e160 (2) e–160 (3) e–80 (4) e320
Ans. [1]
Sol. Gº = –RT nk
–nF E ocell = – RT nK
– 2 × 96000 × 2 = –8 × 300 × nk
k = e160

Q.8 The entropy change associated with the conversion of 1 kg of ice at 273 K to water vapours at 383 K is :
(Specific heat of water liquid and water vapour are 4.2 kJ K–1 kg–1 and 2.0 kJ K–1 kg–1 heat of liquid fusion
and vapourisation of water are 334 kJ kg–1 and 2491 kJ kg–1, respectively). (log 273 = 2.436, log 373 = 2.572,
log 383 = 2.583)
(1) 2.64 kJ kg–1 K–1 (2) 9.26 kJ kg–1 K–1 (3) 7.90 kJ kg–1 K–1 (4) 8.49 kJ kg–1 K–1
Ans. [2]
H fusion 334
Sol. H 2O (s)  H 2O ( ) S1 = = = 1.22
273K 273K
T 273
 373 
H 2O ( )  H 2O ( ) S2 = 4.2 × n   = 1.31
273K 373K  273 
H vap 2491
H 2O ( )  H 2O (g ) S3 = = = 6.67
373K 373K
T 373
 383 
H 2O (g )  H 2O (g ) S4 = 2n   = .0529
373K 383K  373 
Stotal = 9.26 kJ kg–1 K–1
Q.9 For the reaction, 2A + B  products, when the concentrations of A and B both were doubled, the rate of the
reaction increased from 0.3 mol L–1 s–1 to 2.4 mol L–1 s–1. When the concentration of A alone is doubled, the
rate increased from 0.3 mol L–1 s–1 to 0.6 mol L–1 s–1. Which one of the following statements is correct?
(1) Order of the reaction with respect to A is 2. (2) Total order of the reaction is 4.
(3) Order of the reaction with respect to B is 1. (4) Order of the reaction with respect to B is 2.
Ans. [4]
Sol. r =k [A]x [B]y
8  (2)x (2)y ….(1)
x
2  (2) ….(2)
x=1 y=2
order w.r.t. B is two
Q.10 The major product obtained in the following reaction is :

OH
(CH3CO)2O/Pyridine (1 eqv.)
NH2 Room temp.
COCH3
OH OH
(1) (2)
NHCOCH3 NH2
OCOCH3
(3) (4)
NH2 NHCOCH3

Ans. [1]
Sol.
OH OH
(CH3CO)2O/Pyridine
NH2 1 Equivalent NH
Room temp.

C=O
Better Nu atom
on which acetylation CH3
will occur first
Q.11 The increasing basicity order of the following compounds is :

CH 2 CH 3 CH 3 CH 3
| | |
(A) CH3CH2NH2 (B) CH3CH2 NH (C) H3C– N  CH 3 (D) Ph  N  H
(1) (A) < (B) < (C) < (D) (2) (D) < (C) < (B) < (A)
(3) (D) < (C) < (A) < (B) (4) (A) < (B) < (D) < (C)
Ans. [3]
Sol. Basic strength
CH 3 CH 3
2 1 | |
CH3 – CH2 – CH 2  NH  CH 2 CH 3  CH 3  CH 2  NH 2  CH 3  N  CH 3 > Ph  N  H
   .p. participate
.p. do not participat e in reason
in resonance
Q.12 Homoleptic octahedral complexes of a metal ion ‘M3+’ with three monodentate ligands L1, L2 and L3 absorb
wavelengths in the region of green, blue and red respectively. The increasing order of the ligand strength is -
(1) L3 < L2 < L1 (2) L3 < L1 < L2 (3) L1 < L2 < L3 (4) L2 < L1 < L3
Ans. [2]
Sol. Order of absorbed = Red > Green > Blue (corresponding to L3 > L1 > L2)
 1 
 0  
  abs 
Order of 0 will be L2 > L1 > L3
Q.13 When the first electron gain enthalpy (egH) of oxygen is –141 kJ/mol, Its second electron gain enthalpy is :
(1) a positive value (2) a more negative value than the first
(3) almost the same as that of the first (4) negative, but less negative than the first
Ans. [1]
Sol. Second electron gain enthalpy is always positive for every element due to repulsion between some charge.
O(g) + 1e–  e–(g) Heg– –141 kJ/mol
O–(g) + 1e–  O–2(g) H = ve

Q.14 Consider the following reversible chemical reactions :
K1
A2(g) + B2(g) 2AB(g) …(1)
K2
6AB(g) 3A2(g) + 3B2(g) …(2)
The relation between K1 and K2 is :
1
(1) K2 = K1–3 (2) K1K2 = (3) K1K2 = 3 (4) K2 = K13
3
Ans. [1]
[ AB]2
Sol. K1 = ….(1)
[A 2 ][B 2 ]
[ A 2 ]3[B 2 ]3
K2 = ….(2)
[AB]6
From Eq. (1) & (2)
3
 1 
K2 =  
 k1 
K2 = K1–3
Q.15 Good reducing nature of H3PO2 is attributed to the presence of :

(1) One P–H bond (2) Two P–OH bonds (3) One P–OH bond (4) Two P–H bonds
Ans. [4]
Sol. H3PO2 is a good reducing agent due to presence of two P–H bonds
O
P
HO H
H
Q.16 The tests performed on compound X and their inferences are :

Test Inference
(a) 2, 4-DNP test Coloured Precipitate
(b) Iodoform test Yellow Precipitate
(c) Azo-dye test No dye formation
Compound ‘X’ is -
H3 C CH3 H3C CH3
N NH2 N NH2 OH
COCH3
(1) CHO (2) CHO (3) (4) CH3
Ans. [3]
Sol.
2, 4 DNP Test  Carbonyl confirm
C  CH 3
Iodoform test  || confirm
O
No Azodye test  No aromatic 1º Amine
CH3 CH3
N O 2, 4DNP Test
|| Iodoform Test
C  CH 3

Q.17 The pH rain water, is approximately :
(1) 5.6 (2) 6.5 (3) 7.5 (4) 7.0
Ans. [1]
Sol. pH of rain water is approximately 5.6.
Q.18 Which of the following compounds is not aromatic?

(1) (2) (3) (4)
N  N 
H
Ans. [2]
Sol. (1)
6 e– aromatic

N
|
H
(2) 6  e– aromatic
N
(3) 4 e– antiaromatic


(4) 6 e–aromatic

Q.19 The correct statement regarding the given Ellingham diagram is :
–300
Gº (kj/mol)
–600
–1050
800ºC
500ºC 2000ºC
Temp.(ºC)
(1) Coke cannot be used for the extraction of Cu from Cu2O
(2) At 500ºC, coke can be used for the extraction of Zn from ZnO
(3) At 1400ºC, Al can be used for the extraction of Zn from ZnO
(4) At 800ºC Cu can be used for the extraction of Zn from ZnO
Ans. [3]
Sol. The element whichpresent below in diagram can replace element from oxide which is present above in the
diagram. So according to diagram Al can reduce ZnO.
3ZnO + 2Al  3Zn + Al2O3

Q.20 The temporary hardness of water is due to :
(1) Na2SO4 (2) CaCl2 (3) NaCl (4) Ca(HCO3)2
Ans. [4]
Sol. Temporary hardness of water is due to presence of Ca(HCO3)2

O OH
CH3
O AlCl3, 
+
OH OH
CH3 OH OH
H3C
CH3 CH3
O
(1) (2) (3) (4)
O O O
Ans. [1]
Sol.
O O

O AlCl3 OAlCl3

OH
Friedel craft reaction CH3
OH OH
CH3 CH3
AlCl3
OH O
O
As shown answer is 1 but NTA has given ans. 3 which is incorrect.
Q.22 The products formed in the reaction of cumene with O2 followed by treatment with dil. HCl are :
OH OH
OH O
(1) and H3C CH3 (2) and H3C CH3
O CH3
O
(3) and CH3 – OH (4) and H3C CH3

Ans. [2]
Sol.
 H
H  O–O–H O–O
H
h O=O H
h
–H2O
Ph grp
migrates
H2 O
O OR O  O
OH OH –H
Hydrolysis
+ OH
O
Q.23 At 100ºC, copper (Cu) has FCC unit cell structure with cell edge length of x Å. What is the approximate
density of Cu (in g cm–3) at this temperature? [Atomic Mass of Cu = 63.55u]
422 205 211 105
(1) 3 (2) 3 (3) 3 (4) 3
x x x x
Ans. [1]
Z M
Sol. d=
NA  a3
For fcc unit cell Z = 4
4  63.55
d=
6.023  10 23  ( x  10 8 ) 3
422
 d ~
 3
x
Q.24 The transition element that has lowest enthalpy of atomization, is :

(1) Zn (2) Fe (3) Cu (4) V
Ans. [3]
Sol. Zn is not a transition element
So transition element having lowest atomization energy out of Cu, V, Fe is Cu and therefore answer should
be (3)
but NTA has given Ans. 1 (Zn)
but Zn is not transition element.
Q.25 Which of the following conditions in drinking water causes methemoglobinemia?

(1) > 50 ppm of nitrate (2) > 50 ppm of chloride
(3) > 50 ppm of lead (4) > 100 ppm of sulphate
Ans. [1]
Sol. Concentration of nitrate > 50 ppm in drinking water cause methemoglobinemia.

Q.26 The major product formed in the following reaction is :
O CH3
O
dil. NaOH
H3C H+
OH O O OH
(1) H3C (2) H3 C
O OH
OH O
(3) H H3 C (4)
H3C H
Ans. [1]
Sol.
O CH3
O
dil. NaOH
CH3 H+
When one aldhyde and one ketone is present then in major product ketone attack on aldehyde
O O

CH3 CH2
dil. NaOH
CH 3  C  H
||
O
OH O
| ||
CH 3  CH  CH 2  C  pH
Ph
(-Hydroxy carbonyl)

Item-I Item-II
(A) Benzaldehyde (P) Mobile phase
(B) Alumina (Q) Adorbent
(C) Acetonitrile (R) Adsorbate
(1) (A)  (Q); (B)  (P) ; (C)  (R) (2) (A)  (Q); (B)  (R) ; (C)  (P)
(3) (A)  (P); (B)  (R) ; (C)  (Q) (4) (A)  (R); (B)  (Q) ; (C)  (P)
Ans. [4]
Sol. Benzaldehyde Adsorbate
Alumina Adsorbent
Acetonitrile Mobile phase

Q.28 The metal that forms nitride by reacting directly with N2 of air, is :
(1) Li (2) Cs (3) K (4) Rb
Ans. [1]
Sol. Only Li directly react with N2
6Li + N2  2Li3N
O
C
NH2 (i) Br2/h
CH2CH3 (ii) KOH (dil)
O
O
(1) NH (2) NH (3) NH (4) NH
CH3
CH3
Ans. [1]
O O
Sol. Br2/h
NH2 NH2
Benzyllic
CH2–CH3 halogenation
Br
Acid
Base KOH
reaction (dil.)
O O

intramolecular
NH NH
CH3 Nucleophilic substituion
Br
Q.30 The correct sequence of amino acids present in the tripetide given below is :
Me Me Me OH
H O
N N OH
C
H2N H
O O
OH
(1) Val - Ser - Thr (2) Thr - Ser - Val (3) Thr - Ser - Leu (4) Leu - Ser - Thr
Ans. [1]
Sol. This is formed by
Me OH
O
NH2 COOH + H2N
OH +
C  OH
NH2 ||
CH2–OH O
Valine Serine Threonine


CHEMISTRY
Q.1 The type of hybridisation and number of lone pair (s) of electrons of Xe in XeOF4, respectively, are:
(1) sp3d and 2 (2) sp3d2 and 2 (3) sp3d and 1 (4) sp3d2 and 1
Ans. [4]
Sol.
O
F F
Xe
F
F
number of b.p = 5
number of l.p = 1
sp3d2 hybridisation
Q.2 Which of the following is not an example of heterogenous catalytic reaction ?

(1) Ostwald's process (2) Combustion of coal
(3) Hydrogenation of vegetable oils (4) Haber's process
Ans. [2]
Sol. Combustion of coal donot use heterogeneous catalyst
Ostwald process V2O5 (s)
Hydrogenation of vegetable oils Ni (s)
Haber process Fe/ Mo(s)
Q.3 Which hydrogen in compound (E) is easily replaceable during bromination reaction in presence of light ?
CH3 –CH2 – CH = CH2

(E)

(1) hydrogen (2) hydrogen (3) hydrogen (4) hydrogen
Ans. [3]
Sol.
Br2 /h Br
CH3 –CH2 – CH = CH2

CH3 –CH – CH = CH2
(E) CH3 – CH – CH = CH2 
resonance stabilize free radical

Q.4 The total number of isotopes of hydrogen and number of radioactive isotopes among them, respectively, are :
(1) 3 and 2 (2) 2 and 1 (3) 2 and 0 (4) 3 and 1
Ans. [4]
Sol. Total number of isotopes of hydrgen are
1H
1
, 1H2 1H
3
,
,
(P) (D) (T)
3
and only 1H or T is an radioactive isotope
Q.5 A process has H = 200 J mol–1 and S = 40 JK–1 mol–1. Out of the values given below, choose the
minimum temperature above which the process will be spontaneous:
(1) 4 K (2) 20 K (3) 5 K (4) 12 K
Ans. [3]
Sol. For a process to be spontaneous , G < O
& G = H – TS
at equillibrium
G = 0 ,  H = TeS
H
 Te =
S
200
= =5k
40
 If T > Te, G < 0 and the process will be spontaneous
Q.6 A mixture of 100 m mol of Ca(OH)2 and 2 g of sodium sulphate was dissolved in water and the volume was
made up to 100 mL. The mass of calcium sulphate formed and the concentration of OH– in resulting solution,
respectively, are : (Molar mass of Ca (OH)2, Na2SO4 and CaSO4 are 74, 143 and 136 g mol–1 , respectively;
Ksp of Ca(OH)2 is 5.5 × 10–6)
(1) 13.6g, 0.28 mol L–1 (2) 13.6g, 0.14 mol L–1
(3) 1.9g, 0.28 mol L–1 (4) 1.9g, 0.14 mol L–1
Ans. [3]
Sol. Ca(OH)2 + Na2SO4  CaSO4 + 2NaOH
100 m mole 14 m mole
86 m mole – 14 m mole 28 m mole
 W CaSO4 = 14 × 10–3 × 136
= 1.9 gm
28
[OH–] = = 0.28 M
100

Q.7 The increasing order of the pKa values of the following compounds is :
OH OH OH OH
NO2
NO2 OMe
A B C D
(1) B < C < D < A (2) B < C < A < D (3) D < A < C < B (4) C < B < A < D
Ans. [2]
OH OH OH OH
> >
>
NO2
NO2 (–I) OMe
(+m)
(–I, –m)
(C) (A) (D)
Sol. (B)
pKa order = B < C < A < D
Q.8 Hall- Heroult's process is given by :

(1) Cu2+ (aq) + H2(g)  Cu(s) + 2H+ (aq) (2) Cr2O3 + 2Al  Al2O3 + 2Cr
(3) 2Al2O3 + 3C  4Al + 3 CO2 (4) ZnO + C Coke,
 1673 K
 Zn + CO
Ans. [3]
Sol. Hall heroult's process it given by
2Al2O3 + 3C  4Al + 3 CO2
Q.9 The electronegativity of aluminium is similar to :

(1) Beryllium (2) Carbon (3) Boron (4) Lithium
Ans. [1]
Sol. EN of Al = 1.5
EN of Be = 1.5
Q.10 The metal used for marking X–ray tube window is :

(1) Ca (2) Na (3) Mg (4) Be
Ans. [4]
Sol. 'Be' metal is used in x ray tube window it is transparent to x rays
Q.11 Which premitive unit cell has unequal edge lengths (a  b  c) and all axial angles different from 90º?
(1) Hexagonal (2) Tetragonal (3) Triclinic (4) Monoclinic
Ans. [3]
Sol. Triclinic primitive cell has unequal edge lengths & all axial angles different from 90º

Q.20 The temporary hardness of water is due to :
(1) Na2SO4 (2) CaCl2 (3) NaCl (4) Ca(HCO3)2
Ans. [4]
Sol. Temporary hardness of water is due to presence of Ca(HCO3)2

O OH
CH3
O AlCl3, 
+
OH OH
CH3 OH OH
H3C
CH3 CH3
O
(1) (2) (3) (4)
O O O
Ans. [1]
Sol.
O O

O AlCl3 OAlCl3

OH
Friedel craft reaction CH3
OH OH
CH3 CH3
AlCl3
OH O
O
As shown answer is 1 but NTA has given ans. 3 which is incorrect.
Q.22 The products formed in the reaction of cumene with O2 followed by treatment with dil. HCl are :
OH OH
OH O
(1) and H3C CH3 (2) and H3C CH3
O CH3
O
(3) and CH3 – OH (4) and H3C CH3

Ans. [2]
Sol.
 H
H  O–O–H O–O
H
h O=O H
h
–H2O
Ph grp
migrates
H2 O
O OR O  O
OH OH –H
Hydrolysis
+ OH
O
Q.23 At 100ºC, copper (Cu) has FCC unit cell structure with cell edge length of x Å. What is the approximate
density of Cu (in g cm–3) at this temperature? [Atomic Mass of Cu = 63.55u]
422 205 211 105
(1) 3 (2) 3 (3) 3 (4) 3
x x x x
Ans. [1]
Z M
Sol. d=
NA  a3
For fcc unit cell Z = 4
4  63.55
d=
6.023  10 23  ( x  10 8 ) 3
422
 d ~
 3
x
Q.24 The transition element that has lowest enthalpy of atomization, is :

(1) Zn (2) Fe (3) Cu (4) V
Ans. [3]
Sol. Zn is not a transition element
So transition element having lowest atomization energy out of Cu, V, Fe is Cu and therefore answer should
be (3)
but NTA has given Ans. 1 (Zn)
but Zn is not transition element.
Q.25 Which of the following conditions in drinking water causes methemoglobinemia?

(1) > 50 ppm of nitrate (2) > 50 ppm of chloride
(3) > 50 ppm of lead (4) > 100 ppm of sulphate
Ans. [1]
Sol. Concentration of nitrate > 50 ppm in drinking water cause methemoglobinemia.

Q.26 The major product formed in the following reaction is :
O CH3
O
dil. NaOH
H3C H+
OH O O OH
(1) H3C (2) H3 C
O OH
OH O
(3) H H3 C (4)
H3C H
Ans. [1]
Sol.
O CH3
O
dil. NaOH
CH3 H+
When one aldhyde and one ketone is present then in major product ketone attack on aldehyde
O O

CH3 CH2
dil. NaOH
CH 3  C  H
||
O
OH O
| ||
CH 3  CH  CH 2  C  pH
Ph
(-Hydroxy carbonyl)

Item-I Item-II
(A) Benzaldehyde (P) Mobile phase
(B) Alumina (Q) Adorbent
(C) Acetonitrile (R) Adsorbate
(1) (A)  (Q); (B)  (P) ; (C)  (R) (2) (A)  (Q); (B)  (R) ; (C)  (P)
(3) (A)  (P); (B)  (R) ; (C)  (Q) (4) (A)  (R); (B)  (Q) ; (C)  (P)
Ans. [4]
Sol. Benzaldehyde Adsorbate
Alumina Adsorbent
Acetonitrile Mobile phase

Ans. [1]
COOH
strong
 CO2
Sol.
COOH
O O
COOH P O
2 5
 O
COOH –H2O
O
O O
OH
 P2O5
O
O–H –H2O
O O
O
COOH
P2O5
 O
COOH –H2O
O
Q.18 The major product of the following reaction is
Br
KOH alc (excess)

Ph
Br
(1) (2)
Ph Ph
(3) (4)
Ph Ph
Ans. [1]
Br excess
Alc. KOH
Ph
Ph 
Sol.
Br
This is example of dehydrohalogenation by E2 mechanism

Q.19 The major product 'X' formed in the following reaction is :
O
O
CH2–C – OCH3
NaBH4
X
MeOH
OH OH
CH2CH2OH CH2CH2OH
(1) (2)
O O
OH O
CH2–C–OCH3 CH2–C–H
(3) (4)
Ans. [3]
Sol.
O O
O OH
CH2–C–OCH3 CH2–C–O–CH3
NaBH4
MeOH
NaBH4is metal hydride it can reducte carbonyl group ( C = O ) in alchol but it do not reduces ester and C = C
Q.20 Two pi and half sigma bonds are present in :
(1) O2 (2) N 2 (3) O 2 (4) N2

Ans. [2]
Sol. N 2 (13e–) = s2,s2, s2, S2, px =  2py2  p1z

1
N 2  BO = 2.5  [ -bond = 2 ,  bond = ]
2
Similarily
N 2  BO = 3  [ -bond = 2 ,  bond = 1]
O 2  BO = 2.5  [ -bond = 1.5 ,  bond = 1]

O2  BO = 2  [ -bond = 1 ,  bond = 1]

Q.21 The correct structure of product 'P' in the following reactions is :
Asn – Ser + (CH3CO)2O NEt 3  P
(excess)
OCOCH3 O
O O NH2
H
N O O
H
N OH N
H3C
H O NH2 N OH
H3C H
(1) (2) O
O OCOCH3
OCOCH3 O
O O NHCOCH3O
H
N O O
H
N OH N
H3C
H O OCOCH3 N OH
H3C
(3) (4) H O
O OCOCH3
Ans. [2]
Sol.
O
CH2–C – NH2 CH2–OH
NH2 – CH – C –OH –H2N – CH – COOH
Asparagine O Serine
CH2 – C – NH2
CH2 –OH
NH2 – CH – C – NH –CH – COOH
O
Asn – Ser
(CH3CO)2O/NEt3
Acetylation
O O
O CH2 – C – NH2 CH2 –O – C – CH3
CH3– C – NH – CH – C – NH – CH – COOH
O

Q.22 Wilkinson catalyst is : (Et = C2H5)
(1) [(Ph3P)3 RhCl]
(2) [(Et3P)3RhCl]
(3) [(Et3P)3IrCl]
(4) [(Ph3P)3IrCl]
Ans. [1]
Sol. Wilkinson catalyst is [(Ph3P)3 RhCl]
Q.23 The chemical nature of hydrogen peroxide is :

(1) Oxidising agent in acidic medium, but not in basic medium
(2) Oxidising and reducing agent in both acidic and basic medium
(3) Reducing agent in basic medium, but not in acidic medium
(4) Oxidising and reducing agent in acidic medium, but not in basic medium.
Ans. [2]
Sol. H2O2 act as O.A and R.A in both acidic and basic medium
CH3O
CH2Cl
(i) AlCl3(anhyd.)
(ii) H2O
CH3O
CH3O CH3
(1) (2)
CH3O
CH3O
(3) (4)
CH3

Ans. [1]
Sol.
CH3O
CH2–Cl AlCl3
–
–AlCl4
CH3O
CH2
rearrangement
CH3O

In tramolecular
Friedel craft
CH3O Attack
Q.25 The effect of lanthanoid contraction in the lanthanoid series of elements by and large means :
(1) increase in atomic radii and decrease in ionic radii
(2) increase in both atomic and ionic radii
(3) decrease in both atomic and ionic radii
(4) decrease in atomic radii and increase in ionic radii
Ans. [3]
Sol. Due to lanthanoid contraction both atomic radii and ionic radius decreases gradualy in the lanthanoid series
Q.26 Water filled in two glasses A and B have BOD values of 10 and 20, respectively. The correct statement
regarding them, is :
(1) B is more polluted than A. (2) A is suitable for drinking, whereas B is not .
(3) Both A and B are suitable for dirnking (4) A is more polluted than B.
Ans. [1]
Sol. Dirnkable water would has BOD value of less than 5ppm where as highly polluted water could have a BOD
valve of 17 ppM or more so B is more polluted than A.

Q.27 The decreasing order of ease of alkaline hydrolysis for the following esters in
COOC2H5
(I)
Cl COOC2H5
(II)
O2N COOC2H5
(III)
CH3O COOC2H5
(IV)
(1) III > II > IV > I (2)IV > II > III > I (3) III > II > I > IV (4) II > III > I > IV
Ans. [3]
Sol. Rate of alkaline Hydrolysis of ester occur through nucleophillic substitution by addition elimination in which
attack of nucleophile is RDS
Rate of SNAE  the charge on Alyl carbon
so rate of alkaline Hcldrolysis is
NO2 COOC2H5 > COOC2H5

Cl
(–I) (II
> COOC2H5 > Ome COOC2H5
(I)
(IV)
Q.28 Liquids A and B form an ideal solution in the entire composition range. At 350 K, the vaapor pressures of
pure A and pure B are 7 × 103 Pa and 12 × 103 Pa, respectively . The composition of the vapor in equilibrium
with a solution containing 40 mole percent of A at this temperature is :
(1) xA = 0.76; xB = 0.24 (2) xA = 0.28; xB = 0.72
(3) xA = 0.4; xB = 0.6 (4) xA = 0.37; xB = 0.63
Ans. [2]
PA POX
Sol. YA = = O A AO
PT PA X A  PB X B
7  103  0.4
=
7  103  0.4  12  103  0.6
= 0.28
 yB = 1– 0.28 = 0.72

Q.29 The total number of isomers for a square planar complex [M(F)(Cl)(SCN)(NO2)] is :
(1) 16 (2) 8 (3) 12 (4) 4
Ans. [3]
Sol.
Cl NH3
M
SCN
NO2
for above complex three G.I. are possible

NH3 Cl NH3
Cl SCN Cl
M M
M
SCN NO2
NH3 NO2 SCN
NO2
(A) (B) (C)

and for (A) following linkage isomers are possible -
Cl NCS Cl SCN Cl NCS
M M M
NH3 NH3 NH3
NO2 ONO ONO
For (B) following linkage isomers are possible

Cl NH3 Cl NH3 Cl NH3
M M M
NCS SCN SCN
NO2 ONO ONO
Similarly for (C) also three linkage isomers are present
Q.30 Consider the following reduction processes :

Zn2+ + 2e–  Zn(s) ; Eº = – 0.76 V
Ca2+ + 2e–  Ca(s); Eº = –2.87 V
Mg2+ + 2e–  Mg(s) ; Eº = – 2.36 V
Ni2 + 2e–  Ni(s) ; Eº = – 0.25 V
The reducing power of the metals increases in the order :
(1) Ca < Mg < Zn < Ni (2) Ni < Zn < Mg < Ca
(3) Zn < Mg < Ni < Ca (4) Ca < Zn < Mg < Ni
Ans. [2]
Sol. Higher is the oxidation potential better is the tendency to get oxidised and better is the reducing power
 Ni < Zn < Mg < Ca is the correct reducing power of the metals


10th January 2019 | Shift - II
CHEMISTRY
Q.1 A reaction of cobalt (III) chloride and ethylenediamine in a 1 : 2 mole ratio generates two isomeric products
A (violet coloured) and B (green coloured). A can show optical activity, but B is optically inactive. What
type of isomers does A and B represcent ?
(1) Ionisation isomers (2) Linkage isomers
(3) Coordination isomers (4) Geometrical isomers
Ans. [4]
Sol.
NH 2  CH 2
|
H 2 N CH 2
CoCl 3    [Co(en)2Cl2] Cl
1 mole 2 mole
Cis (optically active)

en Trans optically inactive
Cl en
Cl Cl
Cl Cl en en
en en
Cl
Trans
Q.2 The pair that contains two P –H bonds in each of the oxoacids is :
(1) H3PO2 and H4P2O5 (2) H4P2O5 and H4P2O6
(3) H4P2O5 and H3PO3 (4) H3PO3 and H3PO2
Ans. [1]
Sol.
H3PO2 And H4P2O5
O O O
P HO P O P OH
H OH
H H H
Both contain 2 p–H bonds.

Q.3 In the reaction of oxalate with permanganate in acidic medium, the number of electrons involved in
producing one molecule of CO2 is :
(1) 10 (2) 2 (3) 1 (4) 5
Ans. [3]
Sol. 2MnO 4  5C 2 O 24   16H   2Mn 2   10CO 2  8H 2 O
The number of e– involved in producing 10 mole of CO 2 is 10, so number of e– involved in producing 1 mole
of CO2 will be 1.
Q.4 The reaction that is NOT involved in the ozone layer depletion mechanism in the stratosphere is :
(1) ClO(g) + O(g)  Cl(g)+ O2(g)
uv
(2) CF2Cl2(g)  Cl(g) + CF2Cl(g)
(3) CH4 + 2O3  3CH2 = O + 3 H2O

h
(4) HOCl(g)  OH(g) + Cl(g)
Ans. [3]
 
Sol. ClO(g)  O(g)  Cl(g)  O 2 (g)
 
uv
CF2Cl2(g)  Cl(g)  CF2 Cl(g )
 
h
HOCl(g)  OH(g )  Cl(g)
All the above three reaction are involved in the ozone layer deplection mechanism.
CH4 + 2O3  3CH2 = O + 3H2O [not involved]
Q.5 An aromatic compound 'A' having molecular formula C7H6O2 on treating with aqueous ammonia and heating
forms compound 'B'. The compound 'B' on reaction with molecular bromine and potassium hydroxide
provides compound 'C' having molecular formula C6H7N.. The structure of 'A' is :
OHC
COOH
(1) (2)
OH
CHO
(3) (4)
OH O CH = CH – CHO

Ans. [2]
Sol.
O
 
C–ONHCl
C7H6O2 NH3(Aq.)
COOH Heating
(Ammonium Bensoate)

(A) –H2O
(Benzoic acid) O
NH2 C–NH2
Br2/KOH
C6H7N Hoffmann Bromamide
(C) (B)
(Aniline) (Benzamide)
K1 d[A ]
Q.6 For an elementary chemical reaction, A2 2A, the expression for is
K–1 dt
2
(1) 2K1[A2] – K –1 [A] (2) K1[A2] – K –1 [A]2
(3) K1[A2] + K –1 [A]2 (4) 2K1[A2] – 2K –1 [A]2
Ans. [4]
d[A ]
Sol. = 2K1[A2] – 2K–1[A]2
dt
Q.7 The electrolytes usually used in the electroplating of gold and silver, respectively are:
(1) [Au(CN)2]– and [Ag(CN)2]– (2) [Au(CN)2]– and [Ag(Cl2]–
(3) [Au(OH)4]– and [Ag(OH)2]– (4) [Au(NH3)2]+ and [Ag(CN)2]–
Ans. [1]
Sol. Theoritical.
Q.8 Among the following reactions of hydrogen with halogens, the one that requires a catalyst is
(1) H2+ Br2  2HBr (2) H2 + Cl2  2HCl
(3) H2 + F2  2HF (4) H2 + I2  2HI
Ans. [4]
Sol. H2 + I2 2HI
In this reaction catalyst is required because I2 is a less reactive.

O CH3
(i) dil. HCl/
O (ii) (COOH)2/
CH3O OH Polymerisation
O
O
O O
O O
O
O
(1) (2)
OCOCH3
OH n n
O
O
O O
O O
O
O
(3) (4)
OH n
n OCH3
Ans. [4]
Sol.
O O–H
C  CH 3 Dil. HCl / 
||   
O–H O Hydrolysis O O–H
CH3O
CH3
(COOH)2
Pollymerisation
O O
|| ||
O O CC
O
CH3
n
Q.10 What is the IUPAC name of the following compound ?

CH3 CH3
H
H
CH3 Br
(1) 4–Bromo-3-methylpent-2-ene
(2) 3–Bromo 1, 2-dimethylbut-1-ene
(3) 3–Bromo-3-methyl-1, 2-dimethylprop-1-ene
(4) 2-Bromo-3-methylpent-3-ene

Ans. [1]
Sol.
CH3 CH3
1
H 4 -Bromo- 3 - methyl
2 3 Pent-2-ene
H
4 Br
CH3
5
Q.11 A compound of formula A2B3 has the hcp lattice. Which atom forms the hcp lattice and what fraction of
tetrahedral voids is occupied by the other atoms :
1
(1) hcp lattice – A, Tetrahedral voids-B
3
1
(2) hcp lattice - B, Tetrahedral voids -A
3
2
(3) hcp lattice - A, Tetrahedral voids -B
3
2
(4) hcp lattice -B, Tetrahedral voids-A
3
Ans. [2]
Sol. Total effective atoms in HCP unit cell = 6
Total no. of tetrahedral voids = 12
1
If B is placed at HCP lattice points then of tetrahedral voids will be occupied by A.
3
So the general formulae becomes A2B3.
Q.12 Soldium metal on dissolution in liquid ammonia gives a deep blue solution due to the formation of :
(1) ammoniated electrons (2) sodamide
(3) sodium-ammonia complex (4) sodium ion-ammonia complex
Ans. [1]
Sol. Na + (x + y) NH3  Na  ( NH 3 ) x  e  ( NH 3 ) y
Ammoniated cation Ammoniated electron
Ammoniated electron is responsible for blue colour of the solution.
Q.13 Which of the following test cannot be used for identifying amino acids ?
(1) Ninhydrin test (2) Barfoed lest
(3) Xanthoproteic test (4) Biuret test
Ans. Ans. [2]
Sol. Ninhydrin, xantho proteic and biuret test is used for test of protein and amino acid but barfoed’s test is used
to detect the presence of monosaccharide (reducing).
Monosaccharide ethonic
 acid  Red colour


Copper II Acetate
( Barfoed reagetn )

Q.14 What will be the major product in the following mononitration reaction ?
N
H HNO3
Conc. H2SO4
O2N
O
O
N
(1) (2)
N H
H
NO2
O O NO2
(3) O2N (4)
N N
H H
Ans. [1]
Sol.
O
NH
More
e– rich so
E will attack here HNO3 + H2SO4
NO2 O
NH
Q.15 The difference in the number of unpaired electrons of a metal ion in its high spin and low-spin octahedral
complexes is two. The metal ion is
(1) Mn2+ (2) Ni2+ (3) Co2+ (4) Fe2+
Ans. [3]
Sol.
+2
27Co = [Ar] 3d7 4sº 4pº
3d 4s 4p 4d
–
No. of unpaired e = 3 (For weak field ligand)
+2 7 0
27Co = [Ar] 3d 4p
3d 4s 4p 4d
For strong field ligand
3d 4s 4p 4d
–
No. of unpaired e = 1

Q.16 The ground state energy of hydrogen atom is – 13.6 eV. The energy of second excited state of He+ ion in eV
is :
(1) –6.04 (2) – 54.4 (3) – 27.2 (4) – 3.4
Ans. [1]
z2
Sol.  = –13.6 2 eV
n
22
 E = –13.6 × 2 = – 6.04 eV
3
Q.17 The 71st electron of an element X with an atomic number of 71 enters into the orbital;
(1) 4f (2) 6s (3) 6p (4) 5d
Ans. [4]
Sol. Electronic configuration of element having atomic number 71 is [Xe] 4ƒ146s2 5d1.
Q.18 The major product of the following reaction

CH3
OH
(i) aq. NaOH
O2 N (ii) CH31
CH3
CH3
OH
OCH3
(1) (2)
CH3
CH3
OH CH3
OH
(3) (4)
CH3 CH3
Ans. [1]
Sol.
CH3 CH3
OH O
Aq. NaOH
Acid base
Nucleophilic
Substitution
[Williamson CH3–I
synthesis]
CH3
O–CH3

Ans. [1]
COOH
strong
 CO2
Sol.
COOH
O O
COOH P O
2 5
 O
COOH –H2O
O
O O
OH
 P2O5
O
O–H –H2O
O O
O
COOH
P2O5
 O
COOH –H2O
O
Br
KOH alc (excess)

Ph
Br
(1) (2)
Ph Ph
(3) (4)
Ph Ph
Ans. [1]
Br excess
Alc. KOH
Ph
Ph 
Sol.
Br
This is example of dehydrohalogenation by E2 mechanism

Q.21 Which is the most suitable reagent for the following transformation ?
OH
CH3 –CH = CH – CH2 – CH – CH3  CH3 – CH = CH – CH2CO2H

(1) alkaline KMnO4 (2) Tollen's neagent (3) I2/NaOH (4) CrO2Cl2/CS2
Ans. [3]
Sol.
OH
|
CH3–CH=CH–CH2– CH  CH 3
I2/NaOH
O
||
CH3–CH=CH–CH2– C  CH 3
I2/NaOH
Iodoform Reaction
 
CH3–CH=CH–CH2– C  O N a  CHI 3
||
O
H
CH3–CH=CH–CH2–COOH
Q.22 The process with negative entropy change is

(1) Dissociation of CaSO4 (s) to CaO(s) and SO3(g)
(2) Dissolution of iodine in water
(3) Synthesis of ammonia from N2 and H2
(4) Sublimation of dry ice
Ans. [3]
Sol. N2(g) + H2(g) 2NH3(g); ng < 0
entropy decreases in above reaction.
Q.23 Elevation in the boiling point for 1 molar solution of glucose is 2 K. The depression in the freezing point for
2 molal solution of glucose in the same solvent is 2 K. The relation between Kb and Kf is :
(1) Kb = Kf (2) Kb = 0.5 Kf (3) Kb = 1.5 Kf (4) Kb = 2 Kf
Ans. [4]
Sol. Tb = Kbm
2 = Kb × 1
 Kb = 2
Tf = Kf m
2 = Kf × 2
 Kf = 1
 Kb = 2Kf

Q.22 Wilkinson catalyst is : (Et = C2H5)
(1) [(Ph3P)3 RhCl]
(2) [(Et3P)3RhCl]
(3) [(Et3P)3IrCl]
(4) [(Ph3P)3IrCl]
Ans. [1]
Sol. Wilkinson catalyst is [(Ph3P)3 RhCl]
Q.23 The chemical nature of hydrogen peroxide is :

(1) Oxidising agent in acidic medium, but not in basic medium
(2) Oxidising and reducing agent in both acidic and basic medium
(3) Reducing agent in basic medium, but not in acidic medium
(4) Oxidising and reducing agent in acidic medium, but not in basic medium.
Ans. [2]
Sol. H2O2 act as O.A and R.A in both acidic and basic medium
CH3O
CH2Cl
(i) AlCl3(anhyd.)
(ii) H2O
CH3O
CH3O CH3
(1) (2)
CH3O
CH3O
(3) (4)
CH3

Ans. [1]
Sol.
CH3O
CH2–Cl AlCl3
–
–AlCl4
CH3O
CH2
rearrangement
CH3O

In tramolecular
Friedel craft
CH3O Attack
Q.25 The effect of lanthanoid contraction in the lanthanoid series of elements by and large means :
(1) increase in atomic radii and decrease in ionic radii
(2) increase in both atomic and ionic radii
(3) decrease in both atomic and ionic radii
(4) decrease in atomic radii and increase in ionic radii
Ans. [3]
Sol. Due to lanthanoid contraction both atomic radii and ionic radius decreases gradualy in the lanthanoid series
Q.26 Water filled in two glasses A and B have BOD values of 10 and 20, respectively. The correct statement
regarding them, is :
(1) B is more polluted than A. (2) A is suitable for drinking, whereas B is not .
(3) Both A and B are suitable for dirnking (4) A is more polluted than B.
Ans. [1]
Sol. Dirnkable water would has BOD value of less than 5ppm where as highly polluted water could have a BOD
valve of 17 ppM or more so B is more polluted than A.

Q.27 The decreasing order of ease of alkaline hydrolysis for the following esters in
COOC2H5
(I)
Cl COOC2H5
(II)
O2N COOC2H5
(III)
CH3O COOC2H5
(IV)
(1) III > II > IV > I (2)IV > II > III > I (3) III > II > I > IV (4) II > III > I > IV
Ans. [3]
Sol. Rate of alkaline Hydrolysis of ester occur through nucleophillic substitution by addition elimination in which
attack of nucleophile is RDS
Rate of SNAE  the charge on Alyl carbon
so rate of alkaline Hcldrolysis is
NO2 COOC2H5 > COOC2H5

Cl
(–I) (II
> COOC2H5 > Ome COOC2H5
(I)
(IV)
Q.28 Liquids A and B form an ideal solution in the entire composition range. At 350 K, the vaapor pressures of
pure A and pure B are 7 × 103 Pa and 12 × 103 Pa, respectively . The composition of the vapor in equilibrium
with a solution containing 40 mole percent of A at this temperature is :
(1) xA = 0.76; xB = 0.24 (2) xA = 0.28; xB = 0.72
(3) xA = 0.4; xB = 0.6 (4) xA = 0.37; xB = 0.63
Ans. [2]
PA POX
Sol. YA = = O A AO
PT PA X A  PB X B
7  103  0.4
=
7  103  0.4  12  103  0.6
= 0.28
 yB = 1– 0.28 = 0.72

Q.29 The total number of isomers for a square planar complex [M(F)(Cl)(SCN)(NO2)] is :
(1) 16 (2) 8 (3) 12 (4) 4
Ans. [3]
Sol.
Cl NH3
M
SCN
NO2
for above complex three G.I. are possible

NH3 Cl NH3
Cl SCN Cl
M M
M
SCN NO2
NH3 NO2 SCN
NO2
(A) (B) (C)

and for (A) following linkage isomers are possible -
Cl NCS Cl SCN Cl NCS
M M M
NH3 NH3 NH3
NO2 ONO ONO
For (B) following linkage isomers are possible

Cl NH3 Cl NH3 Cl NH3
M M M
NCS SCN SCN
NO2 ONO ONO
Similarly for (C) also three linkage isomers are present
Q.30 Consider the following reduction processes :

Zn2+ + 2e–  Zn(s) ; Eº = – 0.76 V
Ca2+ + 2e–  Ca(s); Eº = –2.87 V
Mg2+ + 2e–  Mg(s) ; Eº = – 2.36 V
Ni2 + 2e–  Ni(s) ; Eº = – 0.25 V
The reducing power of the metals increases in the order :
(1) Ca < Mg < Zn < Ni (2) Ni < Zn < Mg < Ca
(3) Zn < Mg < Ni < Ca (4) Ca < Zn < Mg < Ni
Ans. [2]
Sol. Higher is the oxidation potential better is the tendency to get oxidised and better is the reducing power
 Ni < Zn < Mg < Ca is the correct reducing power of the metals

Ans. [3]
Sol.
O O O
OEt Ni/H2 OEt DiBAl-H H
CN
CH2–CH2–NH2 CH2–CH2–NH2
intra
Attack
molecular
Q.4 The concentration of dissolved oxygen (DO) in cold water can go upto :
(1) 14 ppm (2) 16 ppm (3) 8 ppm (4) 10 ppm
Ans. [4]
Sol. The concentration of dissolved O2 in cold water can go up to 10 ppm
Q.5 Match the metals (column I) with the coordination compound(s)/enzyme(s) (column II) :
(Column I) Metals (Column II) Coordination compounds(s) enzyme(s)
(A) Co (i) Wilkinson catalyst
(B) Zn (ii) Chlorophyll
(C) Rh (iii) Vitamin B12
(D) Mg (iv) Carbonic anhydrase
(1) (A)-(iii); (B)-(iv); (C)-(i); (D)-(ii) (2) (A)-(iv); (B)-(iii); (C)-(i); (D)-(ii)
(3) (A)-(i); (B)-(ii); (C)-(iii); (D)-(iv) (4) (A)-(ii); (B)-(i); (C)-(iv); (D)-(iii)
Ans. [1]
Sol. (A) Co Cynocobalmine vitamin B12
(B) Zn Carbonic anhydrase
(C) Rh Wilkinson catalyst [Rh Cl (PPh3)3]
(D) Mg Chlorophyll
Q.6 The chloride that CANNOT get hydrolysed is :

(1) SnCl4 (2) SiCl4 (3) PbCl4 (4) CCl4
Ans. [4]
Sol. CCl4 do not possess d orbital so it do not get hydrolysed
Q.7 The correct statements among (a) to (d) regarding H2 as a fuel are :
(a) It produces less pollutants than petrol.
(b) A cylinder of compressed dihydrogen weighs ~ 30 times more than a petrol tank producing the same
amount of energy.
(c) Dihydrogen is stored in tanks of metal alloys like NaNi5.
(d) On combustion, values of energy released per gram of liquid dihydrogen and LPG are 50 and 142 KJ,
respectively.
(1) (a) and (c) only (2) (b) and (d) only (3) (a), (b) and (c) only (4) (b), (c) and (d) only
Ans. [3]
Sol. Fact.

Q.8 Peroxyacetyl nitrate (PAN), an eye irritant is produced by :
(1) classical smog (2) acid rain (3) photochemical smog (4) organic waste
Ans. [3]
Sol. Peroxy Acetyl Nitrate (PAN), an eye irritant is produced by photochemical smog
Q.9 The element that usually does NOT show variable oxidation states is :
(1) V (2) Cu (3) Sc (4) Ti
Ans. [3]
Sol. Scandium [Ar 3d14s2] shows only +3 oxidation state so variable oxidation state is not shown by scandium
Sc  +3
V  +2 to +5
Ti  +2 to +4
Cu  +1, +2
Q.10 For the cell Zn(s) |Zn2+ (aq)| |Mx+ (aq)| M(s), different half cells and their standard electrode potentials are
given below :
MX+ (aq)/M(s) Au3+(aq)/Au(s) Ag+(aq)/Ag(s) Fe3+(aq)/Fe2+ (aq) Fe2+(aq)/Fe(s)

E 0M x  / M /(V) 1.40 0.80 0.77 –0.44
If E 0Zn 2  / Zn = –0.76 V, which cathode will give maximum value of E 0cell per electron transferred?
(1) Ag+/Ag (2) Fe3+/Fe2+ (3) Au3+/Au (4) Fe2+/Fe
Ans. [1]
Sol. Zn(s) |Zn+2 (aq)| |Ag+(aq)| Ag(s)
E 0cell = SRP(Cathode) – SRP(anode)
= 0.8 – (–0.76)
= 1.56 V
 Maximum value of E 0cell per electron transferred will be of Ag+/Ag electrode.
Q.11 Among the following compounds, which one is found in RNA ?

O O
CH3
NH N Me
(1) N O (2) N O
H Me
O NH2
NH N
(3) N O (4) N O
|
H H
Ans. [3]

Sol. Uracil base is present in RNA
O OH
NH N
N O N OH
H
Uracil (u) Uracil (u)
(Keto form) (enol form)
Q.12 Which compound (s) out of the following is/are not aromatic ?
+ –
+
(1) (A) and (C) (2) (C) and (D) (3) (B) (4) (B), (C) and (D)
Ans. [4]
Sol. b, c d are not aromatic
+ –
+
2 e– 4 e– 8 e– SP3
Aromatic Antiaromatic Not aromatic Non aromatic

COCH3
(i) KMnO4/KOH, 
(ii) H2SO4 (dil)
CH3
COCH3 COOH
(1) (2)
HOOC HOOC
COOH COCOOH
(3) (4)
OHC HOOC
Ans. [2]
O

C–CH3 COOK COOH
KMnO4/KOH H
Sol.
oxidising agent

CH3 K+OOC HOOC

Q.14 A 10 mg effervescent tablet containing sodium bicarbonate and oxalic acid releases 0.25 ml of CO2 at T =
298.15 K and p = 1 bar. If molar volume of CO2 is 25.0 L under such condition, what is the percentage of
sodium bicarbonate in each tablet ?
[Molar mass of NaHCO3 = 84 g mol–1]
(1) 33.6 (2) 0.84 (3) 8.4 (4) 16.8
Ans. [3]
Sol. 2NaHCO3 + H2C2O4  Na2CO3 + H2O + CO2
.25 ml
.25
n CO = × 10–3 = 10–5 mole
2
25
n NaHCO 3
= 1 × 10–5 mole
w NaHCO 3
= 1 × 84 × 10–5 gm
= 84 × 10–5 gm
84  10 5
% NaHCO3 =  100 = 8.4 gm
10  10 3
Q.15 The correct order of the atomic radii of C, Cs, Al, and S is :
(1) S < C < Al < Cs (2) S < C < Cs < Al (3) C < S < Al < Cs (4) C < S < Cs < Al
Ans. [3]
Sol. Size order
3rd period
C < S < Al < Cs

2nd
period
more 6th
zeff period
Q.16 Match the ores (column A) with the metals (column B) :

(Column A) ores (Column B) Metals
(I) Siderite (a) Zinc
(II) Kaolinite (b) Copper
(III) Malachite (c) Iron
(IV) Calamine (d) Aluminium
(1) (I)-(c); (II)-(d); (III)-(b); (IV)-(a) (2) (I)-(a); (II)-(b); (III)-(c); (IV)-(d)
(3) (I)-(b); (II)-(c); (III)-(d); (IV)-(a) (4) (I)-(c); (II)-(d); (III)-(a); (IV)-(b)
Ans. [1]
Sol. Siderite  FeCO3
kaolinite  Al2(OH)4 Si2O5
Malachite  CuO3. Cu(OH)2
Calamine  ZnCO3

Q.17 An example of solid sol is :
(1) Butter (2) Hair cream (3) Gem stones (4) Paint
Ans. [3]
Sol. Butter  GEL
Hair cream  Emulsion
Gem stone  solid sol
Paints  Sol
Q.18 NaH is an example of :

(1) metallic hydride (2) saline hydride (3) electron-rich hydride (4) molecular hydride
Ans. [2]
Sol. NaH is saline hydride
Q.19 Consider the reaction

N2(g) + 3H2(g) 2NH3(g)
The equilibrium constant of the above reaction is Kp. If pure ammonia is left to dissociate, the partial
pressure of ammonia at equilibrium is given by (Assume that PNH 3 << Ptotal at equilibrium)
3 1 1 3 1 1
2 2 2
3 2 K 2P2 K P2 3 2 K P P2 K P2
(1) (2) P (3) (4) P
4 4 16 16
Ans. [3]
Sol. N2(g) + 3H2(g) 2NH3(g)
2
PNH
Kp = 3
PN 2  PH3 2
2
PNH
Kp = 3
3
 P   3P 
  
4 4 
3
2  P   3P 
PNH 3
 Kp  
 4  4 
K1P/ 2 P 2 33 / 2
PNH 3 
16
Q.20 The correct match between item (I) and item (II) is :
Item-I Item-II
(A) Norethindrone (P) Anti-biotic
(B) Ofloxacin (Q) Anti-fertility
(C) Equanil (R) Hypertension
(S) Analgesics
(1) (A)(R); (B)(P); (C)(R) (2) (A)(R); (B)(P); (C)(S)
(3) (A)(Q); (B)(P); (C)(R) (4) (A)(Q); (B)(R); (C)(S)
Ans. [3]
Sol. (A) Norethindrone  (Q) antifertility
(B) Ofloxacin  (P) antibiotic
(C) Equanil  (R) Hyper tension

OH
Br2(excess)
SO3H
OH OH
Br Br
(1) (2)
Br Br
Br Br
OH OH
Br Br Br
(3) (4)
SO3H SO3H
Ans. [2] H
Sol. Due to activating nature of phenol it get tribrominated (even – COOH and-SO3H can be replaced by IPSO
attack)
OH OH
Br Br
Br2 excess
SO3H Br
Q.22 A solid having density of 9×103 kg m–3 forms face centred cubic crystals of edge length 200 2 pm. What is
the molar mass of the solid?
[Avogadro constant  6 × 1023 mol–1,   3]
(1) 0.0305 kg mol–1 (2) 0.4320 kg mol–1 (3) 0.0216 kg mol–1 (4) 0.0432 kg mol–1
Ans. [1]
NM
Sol. d=
NA  a3
4M
9 × 103 =
6  10  ( 200 2  1012 ) 3
23
M = 0.0305 kg/mol
Q.23 For the chemical reaction X Y, the standard reaction Gibbs energy depends on temperature T (in K) as
3
rG° (in kJ mol–1) = 120 – T.
8
The major component of the reaction mixture at T is :
(1) Y if T = 300 K (2) Y if T = 280 K (3) X if T = 350 K (4) X if T = 315 K

Ans.
3
Sol. G° = 120 – T
8
 for non spontaneous reaction G° > 0
3
120 – T > 0
8
3
120 > T
8
120  8
T<
3
T < 320 K  x is major product 

Cl
(i) HBr
(ii) alc. KOH
O
Cl OH Cl
(1) (2) (3) (4)
O O OH O
Ans. [3]
Sol.
Cl Cl Cl
HBr AlC.KOH AlC.KOH

Br
O O O O
Tautomerism
(phenol)
OH
Q.25 Heat treatment of muscular pain involves radiation of wavelength of about 900 nm. Which spectral line of H-
atom is suitable for this purpose ?
[RH = 1 × 105 cm–1, h = 6.6 × 10–34 Js, c = 3 × 108 ms–1]
(1) Balmer,   2 (2) Paschen, 5  3 (3) Paschen,   3 (4) Lyman,  1
Ans. [3]
1 1 1
Sol.  R H Z2  2  2 
  n1 n 2 
1 1 
= 105 × (1)2  2  2 
3  
 = 900 nm

Q.26 The correct match between items I and II is :
Item-I (Mixture) Item-II (Seperation method)
(A) H2O : Sugar (P) Sublimation
(B) H2O : Aniline (Q) Recrystallization
(C) H2O : Toluene (R) Steam distillation
(S) Differential extraction
(1) A(R); (B)(P); (C)(S) (2) A(Q); (B)(R); (C)(S)
(3) A(Q); (B)(R); (C)(P) (4) A(S); (B)(R); (C)(P)
Ans. [2]
Sol. H2O – Sugar  (Q) Recrystallisation
H2O – Aniline  (R) Steam Distillation
H2O – Toluene  (S) Differential Extraction
Q.27 The freezing point of a diluted milk sample is found to be –0.2°C, while it should have been –0.5°C for pure
milk. How much water has been added to pure milk to make the diluted sample?
(1) 1 cup of water to 2 cups of pure milk (2) 2 cups of water to 3 cups of pure milk
(3) 3 cups of water to 2 cups of pure milk (4) 1 cup of water to 3 cups of pure milk
Ans. [3]
Sol. Tf = Kf m
0.5 = Kf × m1
0.2 = Kf × m2
5 m1 WA2
 
2 m 2 WA1
Therefore 3 cups of water is added in 2 cups of pure milk
Q.28 The polymer obtained from the following reaction is :

(i) NaNO2/H3O+
NH2
HOOC (ii) polymerisation
O H O O H
(1) (2)
C – (CH2)4 – N HNC – (CH2)4 – C – N
n n
O O
(3) (4)
OC – (CH2)4O O – (CH2)4 – C
n n
Ans. [4]
NH2 NaNO2/H3O+ OH
HOOC HOOC
Polymerisation
Sol.
O – (CH2)4 – C OR C – (CH2)4 – O
O n O n

Q.29 An organic compound is estimated through Duma's method and was found to evolve 6 moles of CO2. 4
moles of H2O and 1 mole of nitrogen gas. The formula of the compound is :
(1) C6H8N (2) C6H8N2 (3) C12H8N (4) C12H8N2
Ans. [2]
Sol. Organic compound DUMA
 6 mole CO2 (6C) + 4 mole of H2O (8H) + 1 mole of N2 (2N)
method
(C6H8N2)
Q.30 Two blocks of the same metal having same mass and at temperature T1 and T2, respectively, are brought in
contact with each other and allowed to attain thermal equilibrium at constant pressure. The change in
entropy, S, for this process is :
1
 
 (T1  T2 ) 2   (T  T2 ) 
(1) 2Cp In  (2) 2Cp In  1 
T1T2   2T1T2 
 
 (T  T2 ) 2   (T  T2 ) 
(3) Cp In  1  (4) 2Cp In  1 
 4T1T2   4T1T2 
Ans. [3]
Tf Tt
Sol. ST = Cp T1
dT  C P dTT2
Tf2  T1  T2 
= CP n Tf  
T1T2  2 
(T1  T2 ) 2
= CP n
4T1T2


Part B – CHEMISTRY
Q.1 The major product otained in the following reaction is :
O OH
Li AlH4
(excess)
CH3
NO2 O
O OH OH
CH3 CH3
(1) (2)
NO2 OH NH2 OH
OH OH
CH3 CH3
(3) (4)
NO2 OH NH2 OH
Ans. [4]
O C–OH CH2OH
LiAlH4
excess
Sol.
NO2 O NH2 OH
LiAHl4 reduces – COOH, –NO2, but do not reduces C = C

O
Q.2 The correct option with respect to the Pauling electronegativity values of the element is :
(1) Ga < Ge (2) Si < Al (3) Te > Se (4) P > S
Ans. [1]
Sol. Ga < Ge
Theoritical question
Along the period, electronegativity increases.

Q.3 The correct match between Item I and Item II is :
Item I Item II
(A) Ester test (P) Tyr
(B) Carbylamine test (Q) Asp
(C) Phthalein dye test (R) Ser
(S) Lys
(1) (A)(Q); (B)(S); (C)(P) (2) (A)(R); (B)(S); (C)(Q)
(3) (A)(R); (B)(Q); (C)(P) (4) (A)(Q); (B)(S); (C)(R)
Ans. [1]
Sol. (A) Ester Test Asp
(B) Carbylamine Test Lys
(C) Ptnalein Dye Test Tyr
Q.4 For the equlibrium,

2H2O H3O+ + OH–, the value of G° at 298 K is approximately :
(1) –80 kJ mol–1 (2) 100 kJ mol–1 (3) –100 kJ mol–1 (4) 80 kJ mol–1
Ans. [4]
Sol. 2H2O H3O+ + OH– K = 10–14
G° = –RTlnK
8.314
=– × 298 ln 10–14
1000
= 80 KJ/mole.
Q.5 The radius of the largest sphere which fits properly at the centre of the edge of a body centred cubic unit cell
is : (Edge length is represented by 'a')
(1) 0.134 a (2) 0.067 a (3) 0.047 a (4) 0.027 a
Ans. [2]
Sol. a = 2(R + r)
a
= (R + r) ........(i)
2
3a = 4R .......(ii)
Using (i) & (ii)
a a 3
 =r
2 4
2 3
 a  =r

 4 
 r = 0.067 a. 

HO
(i) HCl
(ii) AlCl3 (Anhyd.)
HO HO Cl Cl
(1) (2) (3) (4)
Ans. [2]
Sol.
Cl
HO HO
HCl
AlCl3(Anhydr)
HO HO
Inter molecular
attack
attack

Q.7 The higher concentration of which gas in air can cause stiffness of flower buds ?
(1) CO2 (2) SO2 (3) NO2 (4) CO
Ans. [2]
Sol. SO2
Due to acid rain in plants, high conc. of SO2 makes the flower buds stift and makes then fall.
Q.8 K2Hgl4 is 40% ionised in aqueous solution. The value of its van't Hoff factor (i) is:
(1) 1.6 (2) 2.2 (3) 2.0 (4) 1.8
Ans. [4]
Sol. For K2 [HgI4]
i = 1 + 0.4(3 – 1)
 i = 1.8
Q.9 Which of the following compounds reacts with ethylmagnesium bromide and also decolourizes bromine
water solution:
OCH3 CN
CH CH2 – CO2CH3
(1) CH2
(2)
OH CN O
(3) (4)

Ans. [3]
react with grignard reagent
O–H
gives Br2/H2O Test
Sol.
Q.10 Match the following items in column I with the corresponding items in column II.
Column I Column II
(i) Na2CO3.10H2O (A) Portland cement ingredient
(ii) Mg(HCO3)2 (B) Castner-Kellner process
(iii) NaOH (C) Solvay process
(iv) Ca3Al2O6 (D) Temporary hardness
(1) (i)(D); (ii)(A); (iii)(B); (iv)(C) (2) (i)(B); (ii)(C); (iii)(A); (iv)(D)
(3) (i)(C); (ii)(B); (iii)(D); (iv)(A) (4) (i)(C); (ii)(D); (iii)(B); (iv)(A)
Ans. [4]
Sol. Na2CO3. 10H2O  Solvay process
Mg(HCO3)2  Temporary Hardness
NaOH  Castner-Kellner process.
Ca3Al2O6  Portland cement ingredient.
Q.11 The reaction, MgO(s) + C(s)  Mg(s) + CO(g), for which rH° + 491.1 kJ mol–1 and rS° = 198.0 JK–1 mol–1, is
not feasible at 298 K. Temperature above which reaciton will be feasible is :
(1) 2480.3 K (2) 2040.5 K (3) 2380.5 K (4) 1890.0 K
Ans. [1]
H
Sol. Teq =
S
491.1  1000
=
198
= 2480.3 K
Q.12 The de Broglie wavelength () associated with a photoelectron varies with the frequency (v) of the incident
radiation as, [v0 is threshold frequency] :
1 1 1 1
(1)   3
(2)   1
(3)   (4)   1
(v  v0 )
(v  v0 ) 2 (v  v0 ) 4 (v  v0 ) 2
Ans. [4]
Sol. For electron ;
h
=
2mK.E
By photo electric effect ;
hv = hv0 + KE
 K.E = hV . hV0
h
 =
2m( hv  hv 0 )
1

( v  v 0 )1 / 2

Q.13 25 ml of the given HCl solution requires 30 mL of 0.1 M sodium carbonate solution. What is the volume of
this HCl solution required to titrate 30 mL of 0.2 M aqueous NaOH solutions ?
(1) 50 mL (2) 12.5 mL (3) 25 mL (4) 75 mL
Ans. [3]
Sol. Na2CO3 + 2HCl  2NaCl + H2CO3
eq. of HCl = eq. of Na2CO3
25 30
×M×1= × 0.1 × 2
1000 1000
6
 M
25
eq. of HCl = eq. of NaOH
6 V 30
×1×  × 0.2 × 1
25 1000 1000
 v = 25 mL 
Q.14 A 4
KOH , O 2
 2 B  2H 2 O
( Green )
4 HCl
3B  2C  MnO 2  2 H 2O
( Purple )
H O.KJ
2C 2 
 2A  2KOH  D
In the above sequence of reactions, A and D , respectively, are :
(1) Kl and KMnO4 (2) Kl and K2MnO4 (3) KlO3 and MnO2 (4) MnO2 and KlO3
Ans. [4]
Sol. MnO2 4
KOH ,O2
 2K2MnO4 + 2H2O
(Green)
4 HCl
3K 2 MnO 4  2 KMnO 4  2H 2 O
( Purple )
H 2 O ,Kl
2 KMnO 4  
 2 MnO 4  2KOH  KIO3
A  MnO2
D  KIO3
Q.15 The reaction that does NOT define calcination is :

 
(1) 2Cu2S + 3O2  2Cu2O + 2SO2 (2) CaCO3 . MgCO3  CaO  MgO  2CO 2
 
(3) ZnCO3  ZnO + CO2 (4) Fe2O3 . XH2O  Fe2O3 + XH2O
Ans. [1]
Sol. Calciration is carried out for carbonates and oxide ores in absence of oxygen. Roasting is carried out mainly
for sulphide ores in preserce of excess of oxygen.
Q.16 Taj Mahal is being slowly disfigured and discoloured. This is primarily due to :
(1) acid rain (2) soil pollution (3) global warming (4) water pollution
Ans. [1]
Sol. Taj-Mahol is slowly disfigured and discolured due to acid rain.

Q.17 The standard reaction Gibbs energy for a chemical reaction at an absolute temperature T is given by
rG° = A – BT
Where A and B are non-zero constants. Which of the following is TRUE about this reaction ?
(1) Exothermic if B < 0 (2) Endothermic if A > 0
(3) Exothermic if A > 0 and B < 0 (4) Endothermic if A < 0 and B > 0
Ans. [2]
Sol. Thcoritical.
Q.18 Among the colloids cheese (C), milk (M), and smoke (S), the correct combination of the dispersed phase and
dispersion medium, respectively is :
(1) C : liquid in solid ; M : liquid in liquid ; S : solid in gas
(2) C : liquid in solid ; M : liquid in solid ; S : solid in gas
(3) C : solid in liquid ; M : liquid in liquid ; S : gas in solid
(4) C : solid in liqid ; M : solid in liquid ; S : solid in gas
Ans. [1]
Sol.
Dispered phase Dispersion medium
Cheese Liquid Solid
Milk Liquid Liquid
Smoke Solid Gas
Q.19 A compound 'X' on treatment with Br2/NaOH, provided C3H9N, which gives positive carbylamine test.
Compound 'X' is :
(1) CH3CH2CH2CONH2 (2) CH3CON(CH3)2
(3) CH3CH2COCH2NH2 (4) CH3COCH2NHCH3
Ans. [1]
Br2/NaOH
Sol. X C3H9N [1° amine)
Hoffmann Positive carbylamine
Bromamide test
CH3–CH2–CH2–C–NH2

Item I Item II
(A) Allosteric effect (P) Molecule binding to the active site of enzyme
(B) Competitive inhibitor (Q) Molecule crucial for communication in the body
(C) Receptor (R) Molecule binding to a site other than the active site of
enzyme
(D) Poison (S) Molecule binding to the enzyme covalently
(1) (A)(P); (B)(R); (C)(Q); (D)(S) (2) (A)(P); (B)(R); (C)(S); (D)(Q)
(3) (A)(R); (B)(P); (C)(S); (D)(Q) (4) (A)(R); (B)(P); (C)(Q); (D)(S)
Ans. [4]
Sol. Theoritical

Q.21 The reaction 2X  B is a zeroth order reaction. If the initial concentration of X is 0.2 M, the half-life is 6 h.
When the initial concentration of X is 0.5 M, the time required to reach its final concentration of 0.2 M will
be:
(1) 18.0 h (2) 9.0 h (3) 7.2 h (4) 12.0 h
Ans. [1]
Sol. For zero order reaction.
[A]t = [A0] – Kt
 [A0] – [At] = Kt
 0.2 – 0.1 = K × 6
1
K= M/hr
60
1
0.5 – 0.2 = ×t
60
 t = 18 hrs.
Q.22 Given the equilibrium constant:

KC of the reaction :
Cu(s) + 2Ag+ (aq)  Cu2+ (aq) + 2Ag(s) is 10 × 1015, calculate the E 0cell of this reaciton at 298 K
 RT 
2.303 F at 298 K  0.059V 
 
(1) 0.4736 mV (2) 0.04736 V (3) 0.4736 V (4) 0.04736 mV
Ans. [3]
0.059
Sol. Ecell = E cell  log Q
n
At equilibrium ;
0.059
Ecell  log 1016
2
 E cell = 0.472
Q.23 The number of bridging CO ligand(s) and Co-Co bond(s) in Co2(CO)8, respectively are :
(1) 2 and 0 (2) 0 and 2 (3) 4 and 0 (4) 2 and 1
Ans. [4]
Sol. Bridging CO are 2 and Co-Co bond is 1.
CO CO CO
CO Co Co CO
CO CO CO
Q.24 The homopolymer formed from 4-hydroxy-butanoic acid is :

O O O
(1) C – (CH2)2C– O (2) OC(CH2)3– O

n n
O O O
(3) C(CH2)3– O (4) C – (CH2)2C

n n
Ans. [3]

Sol.
HO–CH2–CH2–CH2–C–OH
O
4 hydroxy Polymerisation
butanoic acid O–(CH2)3–C
O n
Q.25 The major product obtained in the following conversion is :
CH3 O
O Br2(1 eqv.)
MeOH
O
CH3 O CH3 O
Br
O OMe O
(1) Br (2)
O O
CH3 O CH3 O
O O Br
(3) (4) OMe

Br
O O
Ans. [1]
CH3 O O
O O OMe
Br2(1 eqv.)
MeOH
Sol. Br
O O
Q.26 In the following compound,
NH2 a
d
N b
N
e N N
H c
the favourable site/s for protonation is/are :

(1) (b), (c) and (d) (2) (a) and (e) (3) (a) and (d) (4) (a)
Ans. [1]
Sol. In case of b, c, d lone pair do not participate in resonance (localise  p) so it is favourable site for protonation

Q.27 The hydride that is NOT electron deficient
(1) B2H6 (2) AlH3 (3) GaH3 (4) SiH4
Ans. [4]
Sol. B2H6  Electron deficient.
AlH3  Electron deficient.
SiH4  Electron precise.
GaH3  Electron deficient.
Q.28 The coordination number of Th in K4[Th(C2O4)4(OH2)2] is :

C O
2
2
4  Oxalato 
(1) 14 (2) 10 (3) 8 (4) 6
Ans. [2]
Sol. C2 O 42  bidentate
H2O  Monodentate
Q.29 The relative stability of +1 oxidation state of group 13 elements follows the order :
(1) Tl < In < Ga < Al (2) Al < Ga < TI < In (3) AI < Ga < In < TI (4) Ga < AI < In < TI
Ans. [3]
Sol. Al < Ga < In < TL
Due to Inert pair effect, as we move down the group; in 13th group, lower oxidation state becomes more
stable.
Q.30 Which of the following compounds will produce a precipitate with AgNO3 ?
Br
Br Br
Br
(1) (2) (3) (4)
N
Ans. [2]
Sol. Those AlKyl halide which forms stable carbocation gives precipitate with AgNO3
Br

AgNO3
Stable carbocation
6e– aromatic


Question & Solutions
CHEMISTRY
Q.1 In the following reaction : Aldehyde + Alcohol ⎯HCl
⎯
⎯→ Acetal
Aldehyde Alcohol
HCHO tBuOH
CH3CHO MeOH
The best combination is
(1) CH3CHO and MeOH (2) HCHO and MeOH
(3) CH3CHO and tBuOH (4) HCHO and tBuOH
Ans. [2]
Sol. Aldehyde + Alcohol ⎯HCl
⎯
⎯→ Acetal
This is nucleophillic addition reaction in which less steric hindrance should be present.
So best combination is
H–C–H + CH3 – OH
||
O
Q.2 Among the following four aromatic compounds, which one will have the lowest melting point ?
OH
(1) (2)
O CH3
|| |
OH O
OH O
(3) || (4) |
O CH3
Ans. [2]
Sol. Non polar compound have weak vanderwaal attraction force, so their melting point is lowest
Q.3 The element with Z = 120 (not yet discovered) will be an/a -
(1) Alkaline earth metal (2) Alkali metal
(3) Transition metal (4) Inner transition metal
Ans. [1]
Sol. Z = 120
Its general electronic configuration can be represented as [Noble]ns2

Q.4 What is the work function of the metal if the light of wavelength 4000Å generates photoelectrons of velocity
6 × 105 ms–1 from it ?
(Mass of electron = 9 × 10–31 kg; Velocity of light = 3 × 108 ms-1
–34
Plank's constant = 6.626 × 10 Js; Charge of electron = 1.6 ×10–19 JeV–1)
(1) 4.0 eV (2) 0.9 eV (3) 2.1 eV (4) 3.1 eV
Ans. [3]
1
Sol. φ = hν − mv2
2
6.626 × 10 −34 × 3 × 108 1
φ= – × 9 × 10 −31 (6 × 105 ) 2
4000 × 10 −10 2
φ = 3.35 ×10–19 J
φ ≈ 2.1 eV
Q.5 The pair of metal ions that can give a spin only magnetic moment of 3.9 BM for the complex [M(H2O)6]Cl2,
is -
(1) V2+ and Fe2+ (2) V2+ and Co2+ (3) Co2+ and Fe2+ (4) Cr2+ and Mn2+
Ans. [2]
Sol. V2+ and Co2
V+2 = [Ar] 3d3
=
3 unpaired electron
spin only magnetic moment = 3.89 B.M.
Co+2 = [Ar] 3d7
=
3 unpaired e ⇒ μ = 3.89 B.M.
Q.6 In the following reaction, products A and B are –

O O
|| ||
dilNaOH H3O+
[A] [B]
H3C H Δ
H3C CH3
O O
OH || ||
H H 2C H
(1) A = H3C B=
H 3C CH3 H3C CH3
O O
|| ||
CH3 CH3
(2)
A= CH3 B= CH3
HO
O
|| O
OH ||
C CH3
H H
(3) A = H3C B=
H3C CH3 H 3C CH3
O O
|| ||
CH3 CH3
(4)
A= CH3 B= CH3
HO

Ans. [3]
Sol.
O O O
OEt Ni/H2 OEt DiBAl-H H
CN
CH2–CH2–NH2 CH2–CH2–NH2
intra
Attack
molecular
Q.4 The concentration of dissolved oxygen (DO) in cold water can go upto :
(1) 14 ppm (2) 16 ppm (3) 8 ppm (4) 10 ppm
Ans. [4]
Sol. The concentration of dissolved O2 in cold water can go up to 10 ppm
Q.5 Match the metals (column I) with the coordination compound(s)/enzyme(s) (column II) :
(Column I) Metals (Column II) Coordination compounds(s) enzyme(s)
(A) Co (i) Wilkinson catalyst
(B) Zn (ii) Chlorophyll
(C) Rh (iii) Vitamin B12
(D) Mg (iv) Carbonic anhydrase
(1) (A)-(iii); (B)-(iv); (C)-(i); (D)-(ii) (2) (A)-(iv); (B)-(iii); (C)-(i); (D)-(ii)
(3) (A)-(i); (B)-(ii); (C)-(iii); (D)-(iv) (4) (A)-(ii); (B)-(i); (C)-(iv); (D)-(iii)
Ans. [1]
Sol. (A) Co Cynocobalmine vitamin B12
(B) Zn Carbonic anhydrase
(C) Rh Wilkinson catalyst [Rh Cl (PPh3)3]
(D) Mg Chlorophyll
Q.6 The chloride that CANNOT get hydrolysed is :

(1) SnCl4 (2) SiCl4 (3) PbCl4 (4) CCl4
Ans. [4]
Sol. CCl4 do not possess d orbital so it do not get hydrolysed
Q.7 The correct statements among (a) to (d) regarding H2 as a fuel are :
(a) It produces less pollutants than petrol.
(b) A cylinder of compressed dihydrogen weighs ~ 30 times more than a petrol tank producing the same
amount of energy.
(c) Dihydrogen is stored in tanks of metal alloys like NaNi5.
(d) On combustion, values of energy released per gram of liquid dihydrogen and LPG are 50 and 142 KJ,
respectively.
(1) (a) and (c) only (2) (b) and (d) only (3) (a), (b) and (c) only (4) (b), (c) and (d) only
Ans. [3]
Sol. Fact.

Sol.
CH3
|
H–C–H+Ph–CH–CH2–Mg-X
||
O
CH3
|
Ph–CH–CH2–CH2–OH
Q.10 50 mL of 0.5 M oxalic acid is needed to neutralize 25 mL of sodium hydroxide solution. The amount of
NaOH in 50 mL of the given sodium hydroxide solution is -
(1) 20 g (2) 40 g (3) 80 g (4) 10 g
Ans. []
Sol. [DROP]
number of equivalent of oxalic acid = number of equivalent of NaOH
[nf × M × V] (Oxalic acid) = [nf × M × V](NaOH)
2 × 0.5 × 50 × 10–3 = 1 × M × 25 × 10–3
MNaOH = 2 M
nNaOH in 50 ml = 50 × 10–3 × 2
= 0.1 moles
∴ mass of NaOH = 0.1 × 40
= 4 gm
Ans. is not given in options So, bonus
Q.11 For diatomic ideal gas in a closed system, which of the following plots does not correctly describe the
relation between various thermodynamic quantities ?
Cv Cv
(1) (2)
V T
U CP
(3) (4)
T P
Ans. [4]
7
Sol. CP = R which is independent of P at high temp.
2
∴ graph number 4 is incorrect

Q.14 A 10 mg effervescent tablet containing sodium bicarbonate and oxalic acid releases 0.25 ml of CO2 at T =
298.15 K and p = 1 bar. If molar volume of CO2 is 25.0 L under such condition, what is the percentage of
sodium bicarbonate in each tablet ?
[Molar mass of NaHCO3 = 84 g mol–1]
(1) 33.6 (2) 0.84 (3) 8.4 (4) 16.8
Ans. [3]
Sol. 2NaHCO3 + H2C2O4  Na2CO3 + H2O + CO2
.25 ml
.25
n CO = × 10–3 = 10–5 mole
2
25
n NaHCO 3
= 1 × 10–5 mole
w NaHCO 3
= 1 × 84 × 10–5 gm
= 84 × 10–5 gm
84  10 5
% NaHCO3 =  100 = 8.4 gm
10  10 3
Q.15 The correct order of the atomic radii of C, Cs, Al, and S is :
(1) S < C < Al < Cs (2) S < C < Cs < Al (3) C < S < Al < Cs (4) C < S < Cs < Al
Ans. [3]
Sol. Size order
3rd period
C < S < Al < Cs

2nd
period
more 6th
zeff period
Q.16 Match the ores (column A) with the metals (column B) :

(Column A) ores (Column B) Metals
(I) Siderite (a) Zinc
(II) Kaolinite (b) Copper
(III) Malachite (c) Iron
(IV) Calamine (d) Aluminium
(1) (I)-(c); (II)-(d); (III)-(b); (IV)-(a) (2) (I)-(a); (II)-(b); (III)-(c); (IV)-(d)
(3) (I)-(b); (II)-(c); (III)-(d); (IV)-(a) (4) (I)-(c); (II)-(d); (III)-(a); (IV)-(b)
Ans. [1]
Sol. Siderite  FeCO3
kaolinite  Al2(OH)4 Si2O5
Malachite  CuO3. Cu(OH)2
Calamine  ZnCO3

Sol. K3[Co(CN)6]
Co+3 ⎯→ [Ar ] 3d6
eg
t2 g
d2sp3 uses dx2 – y2 and dz2 orbital
Q.17 Poly β–hydroxybutyrate-co-β-hydroxyvalerate (PHBV) is a copolymer of

(1) 2-hydroxybutanoic acid and 3-hydroxypentanoic acid
Ans. [3]
Sol. PHBV is copolymer of 3 hydroxybutanoic acid + 3 hydroxypentanoic acid
Q.18 Decomposition of X exhibits a rate constant of 0.05 μg/year. How many year are required for the
decomposition of 5μg of X into 2.5 μg?
(1) 50 (2) 20 (3) 25 (4) 40
Ans. [1]
Sol. Rate constant (K) = 0.05 μg/year
means zero order reaction
a0 5μg
t1 = = = 50 years
2
2k 2 × 0.05μg / year
Q.19 Among the following compounds most basic amino acid is -

(1) Lysine (2) Asparagine (3) Histidine (4) Serine
Ans. [1]
Sol. Lysine
O
||
H2N–(CH2)4
OH
NH2
⎛ dE Θ ⎞
Q.20 The standard electrode potential EΘ and its temperature coefficient ⎜⎜ ⎟ for a cell are 2V and –5 × 10–4
⎟
⎝ dT ⎠
VK–1 at 300 K respectively. The cell reaction is Zn(s) + Cu2+ (aq) ⎯→ Zn2+ (aq) + Cu(s)
The standard reaction enthalpy (ΔrHΘ) at 300 K in kJ mol–1 is, [Use R = 8 JK–1 mol–1 and F = 96,000 Cmol–1]
(1) –412.8 (2) –384.0 (3) 192.0 (4) 206.4
Ans. [1]
⎛ ΔE ⎞
Sol. ΔH = nfT⎜ ⎟ − nfE
⎝ ΔT ⎠ P
= 2 × 96000 × 300 (–5 × 10–4) – 2 × 96000 × 2
= – 412.8 KJ/mol

Ans.
3
Sol. G° = 120 – T
8
 for non spontaneous reaction G° > 0
3
120 – T > 0
8
3
120 > T
8
120  8
T<
3
T < 320 K  x is major product 

Cl
(i) HBr
(ii) alc. KOH
O
Cl OH Cl
(1) (2) (3) (4)
O O OH O
Ans. [3]
Sol.
Cl Cl Cl
HBr AlC.KOH AlC.KOH

Br
O O O O
Tautomerism
(phenol)
OH
Q.25 Heat treatment of muscular pain involves radiation of wavelength of about 900 nm. Which spectral line of H-
atom is suitable for this purpose ?
[RH = 1 × 105 cm–1, h = 6.6 × 10–34 Js, c = 3 × 108 ms–1]
(1) Balmer,   2 (2) Paschen, 5  3 (3) Paschen,   3 (4) Lyman,  1
Ans. [3]
1 1 1
Sol.  R H Z2  2  2 
  n1 n 2 
1 1 
= 105 × (1)2  2  2 
3  
 = 900 nm

K
Q.25 In a chemical reaction, A + 2B 2C+D, the initial concentration of B was 1.5 times of the
concentration of A, but the equilibrium concentrations of A and B were found to be equal. The equilibrium
constant (K) for the aforesaid chemical reaction is -
(1) 16 (2) 1 (3) 1/4 (4) 4
Ans. [4]
Sol. A+ 2B 2C + D
t=0 a 1.5a
t=t a – x 1.5a – 2x 2x x
a – x = 1.5 a – 2x
x = 0.5 a
(2 × 0.5a ) 2 × 0.5a
∴ K=
0.5a × (0.5a ) 2
K=4
Q.26 Mn2(CO)10 is an organometallic compound due to the presence of -

(1) C–O bond (2) Mn – Mn bond (3) Mn – O bond (4) Mn – C bond
Ans. [4]
Sol. Compounds having at least one bond between carbon and metal are known as organometallic compound.
Q.27 The volume of gas A is twice than that of gas B. The compressibility factor of gas A is thrice than that of gas
B at same temperature. The pressures of the gases for equal number of moles are -
(1) 2PA = 3PB (2) 3PA = 2PB (3) PA = 3PB (4) PA = 2PB
Ans. [1]
Sol. VA = 2VB
ZA = 3ZB
P V
ZA = A A ….. (i)
nRT
PV
ZB = B B ….. (ii)
nRT
ZA PA × VB × 2
=
ZB PB × VB
PA 3
=
PB 2
2PA = 3PB
Q.28 Two solids dissociate as follows –

A(s) B(g) + C(g) ; k p1 = x atm2
D(s) C(g) + E(g) ; k p 2 = y atm2
The total pressure when both the solids dissociated simultaneously is -
(1) (x + y) atm (2) ( x + y ) atm (3) 2( x + y ) atm (4) x2 + y2 atm
Ans. [3]

Sol. A(s) B(g) + C(g) ; k p1 = x atm2
P1 P1 + P2
D(s) C(g) + E(g) ; k p 2 = y atm2
P1 + P2 P2
P1(P1 + P2) = x
P2(P1 + P2) = y
(P1 + P2)2 = x + y
∴ P1 + P2 = x+y
∴ Total pressure = 2 (P1 + P2) = 2 x + y atm
Q.29 The major product of the following reaction is –

CN (i) DIBAL-H
O (ii) H3O+
O
CHO CHO
CH=NH
CHO
OH O
(1) (2) OH (3) (4) O
CHO OH O
Ans. [1]
Sol. Diisobutyl aluminium hydride (DIBAL-H) Reduces cyanide & ester into aldehyde group
CN (i) DIBAL-H CHO
O (ii) H3O+ OH
O CHO
Q.30 In the Hall-Heroult process, aluminum is formed at the cathode. The cathode is made out of -
(1) Copper (2) Platinum (3) Carbon (4) Pure aluminium
Ans. [3]
Sol. In Hall-Heroult process, the cathode is made up of carbon


Questions & Solution
CHEMISTRY
H3C O (i) NaNO2/H+

NH2 (ii) CrO3/H+
||
O (iii) H2SO4 (conc., Δ)
HO CH3 O
(1) (2) ||
O
O O
O O
HO CH3 O
(3) (4) ||
O
Ans. [1]
Sol.
O O
|| ||
CH3–C CH3–C OH
O NaNO2 O
NH2 H+
O CrO3/H⊕
||
CH3–C O
H2SO4/Δ
||
O
OH
OH
|
Q.2 The major product in the following conversion is –

HBr (excess)
CH3O CH=CH–CH3 Heat ?
(1) HO CH2–CH–CH3 (2) CH3O CH2–CH–CH3

| |
Br Br
(3) CH3O CH–CH2–CH3 (4) HO CH–CH2–CH3

| |
Br Br

Ans. [4]
HBr ⊕
CH3–O CH=CH–CH3 CH3–O CH–CH2–CH3
+m Stable carbocation
Θ
Br Br
HBr |
CH3–O CH–CH2–CH3
(Zeisel's method (SN2)
Br
|
Sol.
HO CH–CH2–CH3
Q.3 ∧ °m for NaCl, HCl and NaA are 126.4, 425.9 and 100.5 S cm2 mol–1, respectively. If the conductivity of
0.001 M HA is-
5 × 10–5 S cm–1, degree of dissociation of HA is -
(1) 0.50 (2) 0.125 (3) 0.25 (4) 0.75
Ans. [2]
Sol. ∧ °m (HA) = ∧ °m (HCl) + ∧ °m (NaA) – ∧ °m (NaCl)
= 425.9 + 100.5 – 126.4
= 400s cm2 mol–1
1000K 1000 × 5 × 10 −5
∧ °m = =
M 10 −3
= 50s cm2 mol–1
∧m 50
λ= °
= = 0.125
∧m 400

CH2–CH3
NaOEt
H3C C Cl
Δ
COOCH2CH3
CH2–CH3
CO2CH2–CH3
(1) H3C C OCH2CH3 (2) |
CH3C=CHCH3
COOCH2CH3
OCH2CH3
CH3CH2C=CH2
(3) (4) |
H3CH2C C CO2CH2CH3 CO2CH2CH3
CH3

Ans. [2]
Sol. Elimination occur due to the presence of strong base and heating
CH3 CH3
| |
H–CH CH
| E2 ||
CH3– C – Cl CH3– C
Et0Θ / Δ |
|
C–O–C2H5 C–O–C2H5
|| ||
O O
Q.5 The compound that is NOT a common component of photochemical smog is

H3C–C–OONO2
(1) O3 (2) || (3) CH2 = CHCHO (4) CF2Cl2
O
Ans. [4]
Sol. Photochemical smog contain O3, peroxy acetyl nitrate acrolien but CFCl2 is not present
Q.6 The combination of plots which does not represent isothermal expansion of an ideal gas is –
P P PVm U
O 1/Vm O Vm O P O Vm
(A) (B) (C) (D)
(1) A and D (2) B and D (3) B and C (4) A and C
Ans. [2]
Sol. Isothermal expansion, PVm = const (K )
K
P=
Vm
P U
V Vm
Q.7 Molecules of benzoic acid (C6H5COOH) dimerise in benzene. 'w' g of the acid dissolved in 30 g of benzene
shows a depression in freezing point equal to 2K. If the percentage association of the acid to form dimmer in
the solution is 80, then w is – (Its given that Kf = 5 K kg mol–1, Molar mass of benzoic acid = 122 g mol–1)
(1) 1.5 g (2) 1.8 g (3) 1.0 g (4) 2.4 g
Ans. [4]
Sol. I = 1 – 0.8 + 0.4
= 0.6
ΔTf = iKfM
W × 1000
2 = 0.6 × 5 ×
122 × 30
W = 2.44 gm

Q.8 The element that does NOT show catenation is -
(1) Ge (2) Si (3) Sn (4) Pb
Ans. [4]
Sol. Catanation is not shown by Pb.
Q.9 The aldehydes which will not form Grignard product with one equivalent Grignard reagents are -
CHO
CHO
HO2C
(A) (B)
CHO CHO
H CO HOH C
(C) 3 (D) 2
(1) B and D (2) C and D (3) B, C and D (4) B and C

Ans. [1]
O
||
O C–H
|| |
Sol. Only A –C–H &C required
||
O–CH3
Only one equation of GR while
O
|| O
C–H ||
| C–H
|
B &D required
|
|
C–OH
|| CH2–OH
O
more no. of GR eq. for GR product
Q.10 If the de Broglie wavelength of the electron in nth Bohr orbit in a hydrogenic atom is equal to 1.5 πa0 (a0 is
Bohr radius), then the value of n/z is -
(1) 0.75 (2) 0.40 (3) 1.50 (4) 1.0
Ans. [1]
Sol. According to de-broglies' hypothesis
2π r = nλ
⇒ 2πr = n × 1.5 π a0
n2
⇒ 2πa0 = = n × 1.5π a 0
z
n
⇒ = 0.75
z

Q.11 Given
(i) C(graphite) + O 2 (g ) → CO 2 (g ); ΔrH Θ = x kJ mol −1
1
(ii) C(graphite) + O 2 (g ) → CO 2 (g); ΔrH Θ = y kJ mol −1
2
1
(iii) CO(g ) + O 2 (g) → CO 2 (g ); ΔrH Θ = z kJ mol −1
2
Based on the above thermochemical equations, find out which one of the following algebraic relationships is
correct ?
(1) z = x + y (2) x = y + z (3) x = y – z (4) y = 2z – x
Ans. [2]
Sol. C(graphite) + O 2 (g ) → CO 2 (g); ΔH °f = x kJ / mole …. (i)
1
C(graphite) + O 2 (g) → CO(g ); ΔH °f = y kJ mole …. (ii)
2
1
CO(g ) + O 2 (g) → CO 2 (g ); ΔH °f = z kJ mole …. (iii)
2
(i) = (ii) + (iii)
x=y+z
But in question: equation → (ii) is wrong
There fore, this question should be
Q.12 The upper stratosphere consisting of the ozone layer protects us from sun's radiation that falls in the
wavelength region of -
(1) 200-315 nm (2) 400-550 nm (3) 0.8-1.5 nm (4) 600-750 nm
Ans. [1]
Sol. Upper stratosphere consist ozone layer which protect us from sun radiation (ultraviolet) which have range
10nm to 400 nm
Q.13 For a reaction consider the plot of ln k versus 1/T given in the figure. If the rate constant of this reaction at
400 K is 10–5 s–1, then the rate constant at 500 K is –
Slope = – 4606 K
ln k
1/T
–4 –1 –4 –1
(1) 10 s (2) 4 × 10 s (3) 10–6 s–1 (4) 2 × 10–4 s–1
Ans. [1]
Ea
Sol. lnk = lnA –
RT
Ea
= −4606
R
⎛ k ⎞ Ea ⎛ 1 1 ⎞
⎜⎜ − ⎟⎟ ⇒ ln −25 = 4606⎛⎜
K 1 1 ⎞
ln ⎜⎜ 2 ⎟⎟ = − ⎟
⎝ k1 ⎠ R ⎝ T1 T2 ⎠ 10 ⎝ 400 500 ⎠
K
ln −25 = 2.303
10
K2
= 10
10 −5
K2 = 10–4 5–1

Q.14 8 g of NaOH is dissolved in 18g of H2O. Mole fraction of NaOH in solution and molality (in mol kg–1) of the
solution respectively are -
(1) 0.2, 11.11 (2) 0.167, 22.20 (3) 0.167, 11.11 (4) 0.2, 22.20
Ans. [3]
8 / 40
Sol. X NaOH =
8 18
+
40 18
1
= 5
1
+1
5
1
= = 0.167
6
8 / 40
m= × 1000 = 11.11
18
Q.15 The increasing order of the reactivity of the following with LiAlH4 is
O O
|| ||
(A) (B)
C2H5 NH2 C2H5 OCH3
O O O
|| || ||
(C) (D)
C2H5 Cl C2H5 O C2H5
(1) A < B < C < D (2) B < A < C < D (3) B < A < D < C (4) A < B < D < C
Ans. [4]
Sol. Reactivity of acid derivaties toward LiAlH4 is based upon Nucleo philic substitution via addition Elimination
process [SNAE] So depends upon LGA (leaving group ability) which is in following order
O
Θ Θ || Θ Θ
Cl O–C–CH3 O–CH3 NH2
Good LG Poor LG
O O O O
|| || || ||
Order towards LAH = C2H5–C–Cl > (C2H5–C)2O > C2H5–C–OCH3 > C2H5–C–NH2
Q.16 If Ksp of Ag2CO3 is 8 × 10–12, the molar solubility of Ag2CO3 in 0.1 M AgNO3 is -
(1) 8 × 10–12 M (2) 8 × 10–10 M (3) 8 × 10–13 M (4) 8 × 10–11 M
Ans. [2]
Sol. Ag2CO3(s) 2Ag + ( aq ) + CO 32 −
2s1 + 0.1 S1
AgNO3 ⎯→ Ag (aq ) + NO 3− (aq )

+
2s1 + 0.1M 0.1 M

s1 (2s1 + 0.1) = 8 × 10–12
2
2s1 << 0.1

∴ s1 (0.1)2 = 8 × 10–12
∴ s1 = 8 × 10–10
# 2 3 - 3 - 3 9 , B E S I D E C A N A R AP AB LALNI K
, T, M
I RRU P A T H I - 5 1 7 N
5O0 2. 9; C
4E4 0L 5L 1 7 0 0 0
Q.17 An open vessel at 27°C is heated until two fifth of the air (assumed as an ideal gas) it has escaped from the
vessel assuming that the volume of the vessel remains constant, the temperature at which the vessel has been
heated is -
(1) 750 K (2) 500 °C (3) 750 °C (4) 500 K
Ans. [4]
n1 T2
Sol. =
n 2 T1
n1 T
= 2
3
n1 300
5
5
T2 = 300 ×
3
= 500 K
Q.18 The two monomers for the synthesis of Nylon 6, 6 are

(1) HOOC(CH2)6COOH, H2N(CH2)4NH2 (2) HOOC(CH2)4COOH, H2N(CH2)6NH2
(3) HOOC(CH2)4COOH, H2N(CH2)4NH2 (4) HOOC(CH2)6COOH, H2N(CH2)6NH2
Ans. [2]
Sol. Nylon 6, 6 is Polyamide polymer which is obtained by condensation reaction between Hexamethylene
diamine & adipic acid
O O
|| ||
n 1–NH–(CH2)6 NH–H + n HO–C–(CH2)4–C–OH
–n H2O
O O
|| ||
–NH–(CH2)6– NH–C–(CH2)4–C– n
Nylon-6, 6
Q.19 The volume strength of 1M H2O2 is (Molar mass of H2O2 = 34 g mol–1)

(1) 5.6 (2) 22.4 (3) 11.35 (4) 16.8
Ans. [3]
Sol. Volume strength of H2O2 = molarity × 11.2
= 1 × 11.2
= 11.2
≈ 11.35
Q.20 The correct structure of histidine in a strongly acidic solution (pH = 2) is -

⊕ Θ ⊕
H3N–CH–COO H3N–CH–COOH
(1) NH (2) NH
N⊕ N⊕
H H
⊕ Θ ⊕
H3N–CH–COO H3N–CH–COOH
⊕ ⊕
(3) (4)
NH2 NH2
N⊕ N

Ans. [2]
Sol. In strongly acidic medium protonation occurs at two nitrogen
O O
|| ⊕ ||
NH2–CH–C–OH NH3–CH–C–OH
NH PH=2 NH
⊕
N NH
Q.21 The element that shows greater ability to form pπ-pπ multiple bonds, is -
(1) Si (2) Ge (3) C (4) Sn
Ans. [3]
Sol. Due to small size of carbon it shows powerful pπ-pπ multiple bond
Q.22 The pair that does NOT require calcination is -

(1) Fe2O3 and CaCO3⋅MgCO3 (2) ZnCO3 and CaO
(3) ZnO and Fe2O3⋅xH2O (4) ZnO and MgO
Ans. [4]
Sol. Calcination means heating without oxygen. It is not required if ore is already in oxide are (anhydrous)
Q.23 Chlorine on reaction with hot and concentrated sodium hydroxide give -
(1) ClO 3− and ClO −2 (2) Cl − and ClO − (3) C l – and ClO −2 (4) C l – and ClO 3−
Ans. [4]
Sol.
–1 +5
Cl2 + NaOH → NaCl + NaClO3
Hot
Conc.
Q.24 The magnetic moment of an octahedral homoleptic Mn(II) complex is 5.9 BM. The suitable ligand for this
complex is -
(1) CN– (2) ethylenediamine (3) NCS– (4) CO
Ans. [3]
Sol.
Mn2+ = 3d5
3d5 4s 4p 4d
sp3d2
To have 5.92 BM magnetic moment ligand should be weak ligand like SCNΘ

Item I Item II
(A) Ester test (P) Tyr
(B) Carbylamine test (Q) Asp
(C) Phthalein dye test (R) Ser
(S) Lys
(1) (A)(Q); (B)(S); (C)(P) (2) (A)(R); (B)(S); (C)(Q)
(3) (A)(R); (B)(Q); (C)(P) (4) (A)(Q); (B)(S); (C)(R)
Ans. [1]
Sol. (A) Ester Test Asp
(B) Carbylamine Test Lys
(C) Ptnalein Dye Test Tyr
Q.4 For the equlibrium,

2H2O H3O+ + OH–, the value of G° at 298 K is approximately :
(1) –80 kJ mol–1 (2) 100 kJ mol–1 (3) –100 kJ mol–1 (4) 80 kJ mol–1
Ans. [4]
Sol. 2H2O H3O+ + OH– K = 10–14
G° = –RTlnK
8.314
=– × 298 ln 10–14
1000
= 80 KJ/mole.
Q.5 The radius of the largest sphere which fits properly at the centre of the edge of a body centred cubic unit cell
is : (Edge length is represented by 'a')
(1) 0.134 a (2) 0.067 a (3) 0.047 a (4) 0.027 a
Ans. [2]
Sol. a = 2(R + r)
a
= (R + r) ........(i)
2
3a = 4R .......(ii)
Using (i) & (ii)
a a 3
 =r
2 4
2 3
 a  =r

 4 
 r = 0.067 a. 

H3C
=CH2 HCl
H
CH3
CH3 CH2–Cl
(1) (2)
CH3
H
Cl H
(3) CH3 (4) CH3
CH3 CH2–Cl
Cl
H H
Ans. [3]
CH3
CH3
C=CH H⊕ | CH
⊕ 3
Sol. HCl
[3° stable carbocation]

CH3
CH3
Cl ClΘ (fast)
Reaction according to markowinkiff's rule

O
||
NaBH4
EtOH
OH
OH | O OH
| || |
(1) (2) (3) (4)
OEt
Ans. [1]
Sol. NaBH4 do not reduces C = C bond
O OH
|| ||
NaBH4
EtOH

Jee Main 2019 Jan Chem

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#23-3-39,BESIDE CANARA BANK,MR PALLI,TIRUPATI-517502

JEE Main Online Exam 2019

Q.2 The major product of following reaction is :

(1) RCHO (2)RCOOH (3) RCONH2 (4) RCH2NH2

Q.3 Which amongst the following is the strongest acid ?

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Q.5 The ore that contains both iron and copper is -

Q.7 Correct statements among a to d regarding silicones are -

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[A] [B] Initial Rate of reaction

Q.9 The major product of the following reaction is :

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Q.13 Major product of the following reaction is :

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Q.14 The correct decreasing order for acid strength is :

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Q.23 The major product of the following reaction is :

(1) (2) (3) (4)

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Q.28 The correct match between Item-I and Item-II is :

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Q.5 The ore that contains both iron and copper is -

Q.7 Correct statements among a to d regarding silicones are -

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[A] [B] Initial Rate of reaction

Q.9 The major product of the following reaction is :

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Q.10 The major product obtained in the following reaction is :

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Q.11 The increasing basicity order of the following compounds is :

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Q.15 Good reducing nature of H3PO2 is attributed to the presence of :

Q.16 The tests performed on compound X and their inferences are :

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Q.18 Which of the following compounds is not aromatic?

(3) 4 e– antiaromatic

Q.19 The correct statement regarding the given Ellingham diagram is :

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Q.21 The major product of the following reaction is :

(1) and H3C CH3 (2) and H3C CH3

(3) and CH3 – OH (4) and H3C CH3

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Q.24 The transition element that has lowest enthalpy of atomization, is :

Q.25 Which of the following conditions in drinking water causes methemoglobinemia?

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(1) H3C (2) H3 C

Q.27 The correct match between Item-I and Item-II is :

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JEE Main Online Exam 2019

Q.2 Which of the following is not an example of heterogenous catalytic reaction ?

resonance stabilize free radical

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Q.8 Hall- Heroult's process is given by :

Q.9 The electronegativity of aluminium is similar to :

Q.10 The metal used for marking X–ray tube window is :

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Q.21 The major product of the following reaction is :

(1) and H3C CH3 (2) and H3C CH3