UTS TERMODINAMIKA

Nama: syarif kurrahman

NIM :19.01.0511.001

Soal Ujian Tengah Semester MK Termodinamika Metalurgi

1. Tin (Sn) transforms from grey to white tin at 286K. The heat of transformation (∆𝐻) has
been measured as 2.1 kJ.mol-1.

Sn(grey, 268K) -+ Sn(white, 268K)

a) Calculate the entropy change of the system (Tin).

b) Calculate the entropy change of the surroundings.
c) Calculate the total entropy change of the universe (system + surroundings).

2. Tin transforms fiom grey to white tin at 286K and constant pressure of 1 am. The
following thermodynamic data are given :

Cp = 21.6 + 18.2x10-3T, J mol-1.K-1for both grey and white tin

Heat of transformation (∆𝐻) = 2.1 J mol-1at 286K

a) Calculate the free energy change (∆𝐺) of the transformation at 286 K and 1 atm.
b) Calculate ∆𝐺 of the transformation at 293 K and 1 atm
c) Is the transformation at 293K spontaneous?

3. The following equation shows the temperature-dependence of the free energy change
of a reaction:

∆𝐺= -1,750,000 - 15.7T log T + 370T, J.mol-1

a) Calculate ∆𝑆 for the reaction at 500K.
b) Calculate ∆𝐻 for the reaction at 500K
c) Will the reaction take place spontaneously at 500 K?

JAWABAN
1. Diketahui :𝑇 = 286 𝐾
 𝑞 = 2,1 𝐾𝑗. 𝑀𝑜𝑙 _1

Ditanya : a .∆𝑆 𝑠𝑖𝑠𝑡𝑒𝑚 … . . ?

b.∆𝑆 𝑙𝑖𝑛𝑔𝑘𝑢𝑛𝑔𝑎𝑛 … … . ?
c.∆𝑆 𝑠 + ∆𝑆 𝑙 … … … ? s+ ∆S l………

Penyelesaian:

a. ∆𝑆 𝑠𝑖𝑠𝑡𝑒𝑚
𝑞𝑟 2,1 𝐾𝐽 2100 𝐽𝑜𝑢𝑙𝑒
∆𝑆 = = = = 7,343 𝐽𝑜𝑢𝑙𝑒
𝑇 286𝐾 286
b. ∆𝑆 𝑙𝑖𝑛𝑔𝑘𝑢𝑛𝑔𝑎𝑛ungan
−𝑞 −2100 𝐽𝑜𝑢𝑙𝑒
∆𝑆 = = = −7,343 𝐽𝑜𝑢𝑙𝑒
𝑇 286
c. ∆𝑆 𝑡𝑜𝑡𝑎𝑙
𝑞𝑟 − 𝑞 2100 − (−2100) 4.200
= = = = 14,685 𝐽𝑜𝑢𝑙𝑒
𝑇 286 286

2. Diketahui :𝑇 = 286 𝑘
𝑃 = 𝑘𝑜𝑛𝑠𝑡𝑎𝑛
𝐶𝑃 = 21,6 + 18,2 × 10−3
∆𝐻 = 2,1 𝐽𝑚𝑜𝑙 −1
Ditanya : a.∆𝐸 𝑝𝑎𝑑𝑎 𝑇 = 286 𝐾 𝑑𝑎𝑛 𝑃 = 1 𝑎𝑡𝑚 … … … . . ?
b.∆𝐸𝑝𝑎𝑑𝑎 𝑇 = 293 𝐾 𝑑𝑎𝑛 𝑃 = 1 𝑎𝑡𝑚 … … … … . ?pada T=293 K dan P=1 atm………….?
c.𝐴𝑝𝑎𝑘𝑎ℎ 𝑡𝑟𝑎𝑛𝑠𝑓𝑜𝑟𝑚𝑎𝑠𝑖 𝑝𝑎𝑑𝑎 293 𝑘 𝑠𝑝𝑜𝑛𝑡𝑎𝑛 … … . . ?

Penyelesaian

a. dc = dH-Tds
𝑐𝑝
ds =𝑇 𝑑𝑡

21,6 + 18,2 × 10−3

= (286-286)
286

21,6+18,2 × 10−3
= (0)
286

=0
 dc = 2,1 J mol -1 – (293-286)
= 2,1 J
b. ∆𝐸 =∆𝐻 − ∆𝑇
= 2,1 J𝑚𝑜𝑙 −1 – (293-286)
= 2,1 – 7
= -4,9
c. Tidak spntan karena pada transformasi pasti membutuhkan selang waktu untuk
mencapai panas tersebut.
3. Diketahui :∆𝐸 = −1,750000 − 15,7 𝑇 𝐿𝑜𝑔 + 370 𝑇 , 𝐽 𝑚𝑜𝑙 −1
dh = -1,750000
Ditanya :a.∆𝑆 untuk T = 500 K…..?
b.∆𝐻untuk T = 500 K…..?
c. apakah reaksi akan terjadi secara spontan pada 500 K…?
penyelesaian.
𝑞
a. ∆𝑆 = 𝑇
dH = dq
−1,750000
∆𝑆 = = −3500 𝐽
500
∆𝐸
b. ∆𝐻 =
𝑇𝑠
−1,750000−15,7 (1,349,485)+370 (500)
=
500
−1,750000−21,186.914535+185000
=
500
−1,586,186,9145
=
500
= -3,172,373829
c. Tidak spntan karena padat ransformasi pasti membutuhkan selang waktu
untuk mencapai panas tersebut