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Millat College Jhang

Analytical chemistry
Class: M.Sc Chemistry (1) Date: 29/05/2019
Total marks: 100 Time: 3 Hr

OBJECTIVE PART Marks: 10*2= 20

Q. 1. Write short answers of the following questions:

ⅰ) Good precision does not guarantee accuracy, why?
ⅱ) List some of measuring techniques employed in analytical chemistry.
ⅲ) How weight in vacuum is measured?
ⅳ) what general rules you should be familiarized before weighing with any analytical
balance?
ⅴ) what is meant by the terms “TC” & “TD”, which one has more accuracy and how?
ⅵ) The results of an analysis are 36.97g, compared with the accepted value of 37.06g,
what is the relative error in parts per thousand?
ⅶ) differentiate b/w allowed and forbidden transitions?
ⅷ) How dark current is produced in photomultiplier tubes?
ⅸ) Define monochromator. How it converts polychromatic light to monochromatic light?
ⅹ) Differentiate b/w adsorption and partition chromatography.
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Subjective PART Marks: 4*20= 80

Q. 2. Define calibration and calibration curve; write a note on standard and internal standard
addition methods to calibrate instruments (20)
Q. 3. What is chemical equilibrium? Types of chemical equilibrium and explain the factors
affecting the chemical equilibrium (20)
Q. 4. a) Write a note on conventional method for the preparation of TLC plates (10)
b) Write a note on column chromatography (10)
Q. 5. Define grab sample; discuss the problems associated with obtaining grab sample of solids,
liquids and gases. (20)
Q. 6. Define development. What are types of agents used to detect the un-visualized spots in
chromatography? (20)
Q. 7. Explain the working principle of Double beam Uv-Visible spectrophotometer with
instrumentation. (20)

------Best of luck------