1. At 3000K and 1 atm, CO2 is 40% dissociated to CO and O2.

Calculate its percentage dissociation

when the pressure is increased to 2 atm.

% DISSOCIATION=33.648%

2. PCl5(g) dissociates into PCl3(g) and Cl2(g) when heated at 250°C and 1 atm. If the density of the gas
mixture at equilibrium is 4.4 g/L, what is the fraction of PCl 5(g) dissociated?

Fraction = 0.102

3. A solvent-water mixture is to be distilled at 95°C. The vapor pressure of the solvent at this
temperature is 130 mm Hg and that of water is 640 mm Hg. The solvent is immiscible in water
and has a molecular weight of 150. What is the weight of the solvent in kilograms that will be
carried over in the distillate with 200 kg of water?

Weight= 338.55 kg

4. If ethanol and methanol are mixed 50/50 by weight at 60°C, and the solution assumed ideal, what
is the composition of the vapor above the solution? The vapor pressure of pure ethanol at 60°C is
0.461395 atm and for the pure methanol is 0.832997 atm.

% ethanol = 27.8098

% methanol = 72.1902

5. An aqueous solution of gold nitrate is electrolyzed with a current of 0.555 amperes until 1.32 g of
Au has been deposited on the cathode. If the atomic weight of Au is 197, determine the duration
of the electrolysis.

T = 58.25 mins

6. A 0.2 m aqueous solution of KCl freezes at -0.680°C. What is the osmotic pressure at 0°C?

Osmotic Pressure = 8.06 atm

7. A mixture of 0.660 grams of camphor and 0.050 grams of an organic solute freezes at 157°C. If
the solute contains 10.5% H by weight, determine the molecular formula of the solute if the
freezing point of camphor is 178.4°C and the value of K f is 38.

C10H14

8. At what temperature will the velocity of CO2 molecules equal the velocity of oxygen molecules at
0°C?

T = 102.46 deg C

9. The following data were obtained in the determination of a HC gas containing 92.3% C by weight
at -9°C at various pressure:

P (atm) 1 2 3
 ρ (g/mL) 1.45 1.7 1.95

Identify the gas.

C2H2

10. When evacuated or empty, a gas density bulb weighs 29.3215 grams. First, CO 2 gas was used to
fill the bulb at 40°C and 1.0 atm pressure and it weighed 30.0079 grams. The bulb was then
evacuated and filled with the mixture of CO and CO2 under the same temperature and pressure.
With this mixture the bulb weighed 29.9332 grams. Determine the % of CO in the mixture.

%CO=21.37%

11. A 250 mg sample containing 45% MgCO3 and 55% CaCO3 was ignited producing CO2 as
decomposition product. Assuming that the decomposition reaction is complete, what is the
change in weight of a NaOH solution used to absorb CO 2?

Change in weight of NaOH= wt of CO2 = 119.18 mg CO2

12. What weight of an impure NaCl sample must be taken for analysis so that the weight of AgCl
precipitate obtained in mg will be equal to the % Cl in the sample?

Wt of NaCl sample = 24.737 mg

13.