Professional Documents
Culture Documents
a r t i c l e i n f o a b s t r a c t
Article history: Heat leakage and mechanical energy input by equipment evaporate Liquefied Nature Gas (LNG) in LNG
Received 9 December 2015 receiving terminals into Boil-Off Gas (BOG), which must be compressed and liquefied by sub-cooled LNG
Received in revised form in a recondenser. During ship unloading, there are sharp fluctuations in BOG waste resources, causing
2 February 2016
economic loss. Meanwhile, the liquid levels of the recondenser are unstable, and the consequent pump
Accepted 22 February 2016
cavitation and equipment vibration introduce risks to the operation. This study focuses on the above
Available online 27 February 2016
problems in an actual LNG receiving terminal. The factors affecting the BOG generation in the LNG
receiving terminal and the generation rules are analyzed. To find effective improvements for these
Keywords:
LNG
problems, an optimization model is built and solved using a dynamic simulation tool, which provides a
BOG reference for further dynamic research. After optimization, 0.19 million m3 of natural gas avoid being
Fluctuation flared, and the energy consumption of the BOG compressors is reduced by 4.2%, i.e., 0.19 million kWh. As
Optimization a result, annually 0.14 million USD are saved in total. In addition, pump cavitation and recondenser vi-
Simulation bration are also reduced, and the recondensing system is easier to control, which contributes to the safe
Dynamic operation of the terminal.
© 2016 Elsevier B.V. All rights reserved.
1. Introduction because the BOG fluctuates wildly and is beyond the capacity of one
compressor in some stages. During ship unloading, if the BOG is too
LNG from cargo holds is unloaded into cryogenic tanks at LNG great for two compressors to process, the excess must be flared or
receiving terminals and stored at approximately 160 C under vented, resulting in wasted resources and economic loss, whereas if
atmospheric pressure. Inevitably, the heat from the ambient envi- it is too low, the energy consumption of the compressor per unit
ronment and the heat dissipation from the equipment evaporate mass of BOG is high. On the other hand, the liquid level of the
the liquid during the processing at the terminal, forming BOG. The recondenser might be either too high or too low if there are large
typical process of an LNG receiving terminal includes LNG fluctuations in the BOG (Chen, 2012). An unstable liquid level leads
unloading and storage, BOG processing, LNG regasification, natural to cavitation in HP pumps and equipment vibration, introducing
gas supply, etc. Fig. 1 shows the LNG receiving and regasification risks to the operation of the terminal.
system. In some cases, e.g., ship unloading, the BOG increases BOG has a significant influence on the energy savings and safe
rapidly and fluctuates widely. Usually, BOG in the terminal is operation of the LNG receiving terminal. Many researchers have
compressed and then liquefied by sub-cooled LNG in a recondenser, focused on the BOG generation rules and BOG processing methods.
or it will cause severe problems. The research focuses have been on the factors affecting BOG gen-
An actual LNG receiving terminal in southern China has two eration in the LNG tanks (Adom et al., 2010) and the operations that
BOG compressors, and one of them is reserved under normal generate BOG in the LNG receiving terminal, such as ship unloading
operating conditions as it was originally intended. However, (Park et al., 2012; Srikanth et al., 2014), recirculation (Park et al.,
starting the standby compressor is required during ship unloading 2010), and the operation of specific equipment (Jang et al., 2011;
Li and Chen, 2012). Park et al. (2012) developed an efficient
design for the BOG compression process with an intercooler.
* Corresponding author. SHAW Engineering Building, South China University of Srikanth et al. (2014) established a simulation optimization model
Technology, Wushan RD., Tianhe District, Guangzhou, Guangdong Province, 510640, and provided the optimal unloading strategy to minimize the total
China. cost of unloading. Park et al. (2010) optimized the LNG flow rate for
E-mail address: liyajun@scut.edu.cn (Y. Li).
http://dx.doi.org/10.1016/j.jngse.2016.02.041
1875-5100/© 2016 Elsevier B.V. All rights reserved.
Y. Li, Y. Li / Journal of Natural Gas Science and Engineering 30 (2016) 322e330 323
10 kPaG, and then, the BOG from the receiving system feeds back vice versa. Thus, LNG with different densities can mix well auto-
into the carrier through the BOG line as a supplement to maintain matically (Wang and Liu, 2008; Uznanski et al., 2001). Otherwise,
the carrier pressure. Moreover, the pressure of the LNG tank in the the liquid might be layered, and after a certain period of time, the
terminal is kept at 13 kPaG all of the time. About 1 h before the ship stratification can be broken by strong thermal convection origi-
unloading ends, the unloading pumps are stopped one by one to nating from the bottom, generating large quantities of BOG, up to
slow down the discharge rate. The entire process of ship unloading 30 times the usual amount, in a short time, which is known as
lasts approximately 14 h. rollover (Deshpande et al., 2011; Zellouf and Portannier, 2011;
Gorla, 2010; Uznanski and Versluijs, 2007). To avoid such a situa-
2.2. Factors affecting BOG quantity tion, the terminal must constantly monitor the density of the LNG
inside the tanks.
There are various factors affecting BOG quantity in the terminal. Under vapoureliquid equilibrium, the saturation temperature
To obtain sufficiently accurate results, it is necessary to carry on a and enthalpy of the onboard LNG depend on the carrier pressure. If
comprehensive analysis, as described in the following. it is much lower than the tank pressure, the LNG might remain sub-
cooled after feeding, even if there is heat leakage during unloading.
2.2.1. Steady influencing factors If the carrier pressure is higher and it is top filling, a significant
In the absence of unloading, BOG mainly results from continual amount of LNG is likely to flash off to BOG. Generally, the higher the
heat leakage to the cryogenic tanks and related recirculation tank pressure, the less BOG generated during ship unloading.
pipelines used for LNG cold insulation. During recirculation, the With the exception of heat leakage to the tanks and pipelines,
heat absorbed through pipelines is brought into the storage tanks the other influencing factors mentioned above, such as the output
by the LNG, increasing the BOG (Lee et al., 2010). and heat dissipation of the unloading pumps, are either time-
The volume displacement of the output LNG, tanker truck dependent or sporadic. Therefore, the BOG quantity at the termi-
loading and specific composition of the received LNG also have nal fluctuates all of the time but extremely during ship unloading.
effects on the quantity of BOG. LNG output always fluctuates
because the downstream consumption frequently varies with 2.3. BOG quantity under different operating conditions
different times and seasons. The greater the LNG output, the more
the liquid level in the LNG tank decreases. Therefore, more BOG is There are mainly two types of LNG in the LNG receiving termi-
needed to fill the space left by the LNG output to maintain the nal: rich gas from Australia and lean gas from Qatar; the compo-
pressure inside. Thus, the net BOG quantity decreases. This phe- nents of these gases are shown in Table 1.
nomenon is known as volume displacement. The net quantity is the The output range of the LNG to downstream users is
part of the BOG that needs to be processed. Tanker truck loading 3.6 105e12.6 105 kg/h. The corresponding number of running
generates BOG in two ways. In addition to continual heat leakage to HP pumps is 2e7. The maximum output occasionally occurs at the
the truck, the exchange of the fluid with different densities be- same time as the tanker truck loading, the maximum of which is
tween the LNG storage tank and the tanker truck increases the BOG. 600 m3/h. There are 3 LNG tanks in the terminal and 3 LP pumps
Some components of LNG, mainly methane and nitrogen, also have within each tank (Chu et al., 2007); the LNG ship is equipped with 8
effects on the BOG quantity. With a certain heat leakage, if the ni- unloading pumps, and the discharge rate can reach 12,000 m3/h.
trogen content is constant, when there is more methane, more BOG The equipment parameters of the LNG receiving system are shown
is generated. This behavior is the same for nitrogen if the methane in Table 2.
content is constant. Corresponding mathematical models are established based on
the analyses of the influencing factors in section 2.2 (Chen et al.,
2.2.2. Variable influencing factors 2006; British standard, 1997; Kang and Sun, 2011; Liu and Zhou,
During ship unloading, the amount of BOG is several times 2007). By substituting the process parameters in Table 2 into the
larger than that during storage because in addition to the factors models, the heat and amount of BOG resulting from the factors can
mentioned above, there is heat leakage to the onboard LNG tanks be estimated. The results are shown in Table 3.
and unloading arms, as well as heat dissipation from the unloading The latent heat of vaporization of lean LNG is approximately
pumps, a cooling effect of LNG on the storage tank, output volume 503.2 kJ/kg, while the value for rich LNG is 523.4 kJ/kg. In the case
displacement of the onboard LNG, feed flash, etc. Heat leakage to that the carrier pressure equals the pressures of the tanks, the BOG
the carrier vaporizes approximately 0.15 weight percent of the LNG quantity under different operating conditions is shown in Table 4.
(based on pure methane) to BOG daily. Some of the energy input by Table 4 shows that, in the absence of unloading, the BOG
the unloading pumps can change into heat. When LNG flows in the quantity stays below 5.4 103 kg/h, which is within the capacity of
unloading line, its static pressure energy turns into heat because of one compressor, 6.7 103 kg/h. During ship unloading, the BOG
friction and turbulence resistance. Thus, the heat warms the LNG, quantity is either close to or above the capacity of two compressors.
and BOG is generated (Jung et al., 2003). The cooling effect occurs In practice, if the tank pressure in the terminal is lower than the one
because the feed is usually colder than the BOG in the tanks; when onboard, the BOG quantity is even larger. In particular, if the min-
the BOG is replaced by LNG, the tank wall is cooled, heating the imum output occurs at the same time as lean liquid top filling, the
liquid. Because the onboard tanks have a lower pressure in the full- BOG quantity peaks at 17.4 103 kg/h, which is close to the
speed stage when their temperatures are higher, the density of the measured value of 16.9 103 kg/h (Chen et al., 2004; Liu, 2009),
BOG onboard is much lower than in the LNG tanks in the terminal, and it proves that the calculation models are consistent with the
limiting the quantity of BOG returned to the carrier during the actual conditions.
volume displacement and increasing the BOG in the terminal. The
temperature of the feed might be higher than its boiling point 3. Dynamic simulation of the existing process
under the tank pressure because of heat leakage and heat dissi-
pation, and if it is top filling, some LNG will flash off to BOG. Continuous fluctuation of the BOG causes problems, such as
LNG can be fed into the tank from the top or the bottom, which wasted resources and high energy consumption, and hinders the
depends on the density of the LNG during unloading. Top filling is optimization of the operation of the terminal. To find an effective
adopted if the LNG onboard is heavier than that in the terminal and improvement, DYNSIM, dynamic simulation software for PRO-Ⅱ, is
Y. Li, Y. Li / Journal of Natural Gas Science and Engineering 30 (2016) 322e330 325
Table 1
The components of the rich and lean LNG.
Component CH4 C2H6 C3H8 i-C4H10 n-C4H10 i-C5H12 n-C5H12 N2 Total Density kg/m3
Lean LNG 92.73 6.06 0.96 0.06 0.08 e e 0.11 100.00 442.4
Rich LNG 88.77 7.54 2.59 0.45 0.56 0.01 0.03 0.05 100.00 464.8
Table 2
The equipment parameters of the receiving system.
Equipment Parameters
Table 3
The heat and amount of BOG resulting from the influencing factors.
Table 4
BOG quantity in different operating modes.
Operating mode Ship unloading or not Output Type of LNG BOG quantity (103 kg/h)
employed for the modeling and simulation of the whole terminal. generation rules for optimization of the operation.
The equipment and corresponding modules in the dynamic simu- Assumptions are set that the initial liquid height in the tanks is
lation are presented in Table 5. A schematic of BOG processing 20 m and that the output is kept to a minimum (3.6 105 kg/h)
system in DYNSIM is shown in Fig. 2. during the entire process. Ship unloading lasts from 0 h to
Because the BOG quantity fluctuates most extremely and rea- approximately 14 h.
ches the maximum during ship unloading with minimum output
and lean liquid filling, this study only focuses on the operating
conditions with the hardest controllability and determined the BOG 3.1. Simulation of top filling
4. Optimization method
Fig. 5. BOG quantity vs. pressure of the tanks and carrier with lean liquid full-speed
To eliminate the adverse effects caused by sharp fluctuations in top filling.
328 Y. Li, Y. Li / Journal of Natural Gas Science and Engineering 30 (2016) 322e330
BOG quantities at each time point are denoted Gj1, Gj2, …, Gji, …, Gjn.
The smaller the variance of these n numbers is, the less the BOG
fluctuates. Therefore, the optimization target is to calculate the
variance Jj for every depressurization time point j and finally to find
the minimum, as Eq. (1) shows:
n
X 2
J ¼ MinJj ¼ Min Gji Gj (1)
i¼1
5. Optimization results
even smoothed. As a result, the vibration of the recondenser-HP Chiu, C., Diribe, U., Hartono, J.S., 2010. Ship-Shore interaction and LNG tank piping
design considerations. In: 10th Topical Conference on Gas Utilization, San
pump system is reduced. The optimization has positive effects on
Antonio.
equipment protection and safe operation. Chu, Y.Q., Chen, W.L., Niu, J.F., Liu, X.L., 2007. The applied techniques in LNG
receiving terminal. Nat. Gas. Ind. 27 (1), 120e123.
7. Conclusion Deshpande, K.B., Zimmerman, W.B., Tennant, M.T., Webster, M.B.,
Lukaszewski, M.W., 2011. Optimization methods for the real-time inverse
problem posed by modelling of liquefied natural gas storage. Chem. Eng. J. 170
Frequent BOG fluctuations in the LNG receiving terminals lead to (1), 44e52.
problems in operation, such as high-energy consumption, wasted Gorla, R.S.R., 2010. Probabilistic analysis of a liquefied natural gas storage tank.
Appl. Therm. Eng. 30 (17e18), 2763e2769.
resources, and difficulty in operation. The fluctuations in the BOG Jang, N., Shin, M.W., Choi, S.H., Yoon, E.S., 2011. Dynamic simulation and optimi-
quantity under different operating conditions are estimated based zation of the operation of boil-off gas compressors in a liquefied natural gas
on analyses of the influencing factors and dynamic simulation gasification plant. Korean J. Chem. Eng. 28 (5), 1166e1171.
Jung, M.J., Cho, J.H., Ryu, W., 2003. LNG Terminal Design Feedback from Operator's
technology. From the analyses, we know that, during the full-speed Practical Improvements. The 22nd World Gas Congress, Tokyo, Japan.
stage, the BOG decreases by 3.9 103 kg/h for every 1 kPa increase Kang, Z.L., Sun, X.Z., 2011. Calculation method of evaporating volume for LNG
in the differential pressure between the LNG tanks in the terminal receiving station. Oil Gas Storage Transp. 30 (9), 663e666.
Lee, C.J., Lim, Y., Park, C., Lee, S., Han, C., 2010. Synthesis of unloading operation
and onboard. In other words, the tank operating pressure has a procedure for a mixed operation of above-ground and in-ground liquefied
significant impact on the BOG quantity. To minimize the variance in natural gas storage tanks using dynamic simulation. Indust. Eng. Chem. Res. 49
the BOG quantity during the process, an optimization objective is (17), 8219e8226.
Li, Y., Chen, X., 2012. Dynamic simulation for improving the performance of boil-off
built to find effective improvements with the help of the dynamic
Gas recondensation system at LNG receiving terminals. Chem. Eng. Commun.
simulation software DYNSIM. As a result, by adjusting the tank 199 (10), 1251e1262.
operating pressure appropriately against different conditions, the Liu, S., 2009. Study on Structure & Performance of LNG Full Containment Tank.
BOG quantity is kept within the capacity of one compressor. After South China University of Technology, Guangzhou.
Liu, H., Zhou, Y.C., 2007. Design of pressure safety system of LNG cryogenic storage
optimization, 0.19 million m3 of natural gas avoids being flared tank. Chem. Eng. Des. 17 (1), 7e16.
every year; the energy consumption of the BOG compressors is Liu, C.W., Zhang, J., Xu, Q., Gossage, J.L., 2010. Thermodynamic-analysis-based
reduced by 4.2%, and 0.19 million kWh of power is saved annually. design and operation for boil-off Gas flare minimization at LNG receiving ter-
minals. Indust. Eng. Chem. Res. 49 (16), 7412e7420.
In total 0.14 million USD are saved annually. In addition, the Park, C., Lee, C.J., Lim, Y., Lee, S., Han, C., 2010. Optimization of recirculation oper-
recondenser is easier to control with a more stable liquid level, and ating in liquefied natural gas receiving terminal. J. Taiwan Inst. Chem. Eng. 41
the vibration of the recondenser-HP pump system is reduced. (4), 482e491.
Park, C., Song, K., Lee, S., Lim, Y., Han, C., 2012. Retrofit design of a boil-off gas
Therefore, the optimization operation put forward has completely handling process in liquefied natural gas receiving terminals. Energy 44 (1),
solved the existing problems of the LNG receiving terminal, 69e78.
contributing to the smooth and steady operation of the terminal, Querol, E., Gonzalez-Regueral, B., García-Torrent, J., García-Martínez, M.J., 2010. Boil
off gas (BOG) management in Spanish liquid natural gas (LNG) terminals. Appl.
and large amounts of resources and energy are saved. Energy 87 (11), 3384e3392.
Srikanth, S.A., Narasimhan, Sridharakumar, Narasimhan, Shankar, 2014. Optimiza-
References tion of Unloading Operations in Petroleum Product Storage Terminals. Indus-
trial & Engineering Chemistry Research.
Tarlowski, J., Sheffield, J., Durr, C., Coyle, D., Patel, H., 2016. LNG Import Terminals -
Adom, E., Islam, S.Z., Ji, X., 2010. Modelling of boil-off gas in LNG tanks: a case study.
Recent Developments. http://www.cheresources.com/lng_terminals.pdf.
Int. J. Eng. Technol. 2 (4), 292e296.
Uznanski, D., Versluijs, P., 2007. LNG Expert: the latest evolution in LNG storage tank
British standard, 1997. Installation and equipment for liquefied natural gas - Design
management. In: 7th Topical Conference on Natural Gas Utilization, Houston.
of onshore installations. EN 1473.
Uznanski, D.T., Malvos, H., Gorieu, O., Aoyagi, Y., Benito, A., 2001. Recent advances in
Chen, X., 2012. Modeling and Dynamic Optimization of Recondensation Process at
the optimized management of LNG storage tank filling operations. In: LNG 13
LNG Receiving Terminals. South China University of Technology, Guangzhou.
Conference.
Chen, Q.S., Wegrzyn, J., Prasad, V., 2004. Analysis of temperature and pressure
Wang, L.J., Liu, Y., 2008. LNG stirring mechanism and countermeasures in large LNG
changes in liquefied natural gas (LNG) cryogenic tanks. Cryogenics 44 (10),
storage tanks. Nat. Gas. Ind. 28 (5), 97e99.
701e709.
Zellouf, Y., Portannier, B., 2011. First step in optimizing LNG storages for offshore
Chen, M.H., Cong, D.Z., Fang, T.N., 2006. Unit Operations of Chemical Engineering.
terminals. J. Nat. Gas Sci. Eng. 3 (5), 582e590.
Chemical Industry Press, Beijing.