TERM-I XII 2019-20

CHEMISTRY
Time : 3 hrs. SET -1 M. Marks : 70
TERM-I XII 2019-20
CHEMISTRY
Time : 3 hrs. SET-1 M. Marks : 70
General Instructions
(a) All questions are compulsory.
(b) Section A: Q.no. 1 to 20 are very short answer questions (objective type) and carry 1 mark each.
(c) Section B: Q.no. 21 to 27 are short answer questions and carry 2 marks each.
(d) Section C: Q.no. 28 to 34 are long answer questions and carry 3 marks each.
(e) Section D: Q.no. 35 to 37 are also long answer questions and carry 5 marks each.
(f) Use log tables if necessary, use of calculators is not allowed.

SECTION - A
Questions 1 to 5 :
(A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion.
(B) Both assertion and reason are correct statements, but reason is not the correct explanation of the assertion.
(C) Assertion is correct, but reason is wrong statement.
(D) Assertion is wrong, but reason is correct statement.
(1) Assertion: The two strands in double strand helix structure of DNA are complementary to each other
Reason: Disulphide bonds are formed between specific pairs of bases. 1
(2) Assertion: A low level of noradrenaline in the body causes depression.
Reason: antidepressant drug catalyse the degradation of noradrenaline. 1
(3) Assertion: Presence of nitro group at ortho or para position increses the reactivity of haloarenes towards
nucleophilic substitution.
Reason: Nitro group, being an electron withdrawing group decreases the electron density over the benzene ring.1
(4) Assertion: The acidic strength of halogen acids varies in the order HF>HCl>HBr>HI
Reason: The bond dissociation enthalpy of halogen acids decreases in the order HF>HCl>HBr>HI 1
(5) Assertion: All collisions of reactant molecules lead to product formation.
Reason: only those collisions in which molecules have correct orientation and sufficient kinetic energy leads to
the formation of compound. 1
Questions 6 to 10 are one word answers:
(6) What is the role of silica in the metallurgy of copper? 1
(7)state the significance of the number 6 and 6,6 in the polymer names nylon- 6 and nylon- 6,6. 1

OR
Arrange the following polymers in increasing order of their intermolecular forces:

Terylene, Polythene, Neoprene.

(8) Why iron does not rust even if zinc coating is broken in a galvanized iron pipe? 1
(9) Write the main reason for the stability of colloidal sols. 1
(10) What is the role of NaCN in the extraction of gold and silver? 1
Questions 11 to 15 are multiple choice questions:
(11) The IUPAC name of the compound shown below is: 1

(a) 1 – Bromobut – 2 – ene

(b) 1 – Bromobut – 3 – ene
(c) 2 – Bromo – 2 – butane
(d) Bromobutane
(12) When one mole of CoCl3.5NH3 was treated with excess of silver nitrate solution, 2 mol of AgCl was 1
precipitated. The formula of the compound is:
(a) [Co(NH3)5Cl2]Cl
(b) [Co(NH3)5Cl]Cl2
(c) [Co(NH3)4Cl2] (NH3)Cl
(d) [Co(NH3)3Cl3] (NH3)2

(13)which of the following aqueous solutions should have the highest boiling point? 1
(a)1.0M NaOH (b)1.0M Na2SO4 (c) 1.0M NH4NO3 (d) 1.0M KNO3
(14) which of the following electrolytes will have maximum coagulating value for AgI/Ag+ sol? 1

(a)Na2S (b)Na3PO4 (c)Na2SO4 (d) NaCl

(15)In the presence of a catalyst , the heat evolved or absorbed during the reaction 1
(a) increases (b) decreases (c) remains unchanged (d) may increase or decrease
OR
Which of the following is not correct about the order of a reaction ?
(a)the order of a reaction can be a fractional number.
(b) Order of a reaction is experimentally determined quantity.
(c) The order of a reaction is always equal to the sum of the stoichiometric coefficients of reactants in the balanced
chemical equation for a reaction.
(d) the order of a reaction is the sum of the powers of molar concentration of the reactants in the rate law expression.
Read the given passage and answer the questions 16 to 20 that follow:
When pyrolusite ore MnO2 is fused with KOH in presence of air , a green coloured compound (A) is obtained which
undergoes disproportionation reaction in acidic medium to give a purple coloured compound (B). most of the
transition elements form coloured complexes and paramagnetic in nature and their magnetic moment is calculated by
spin only formula √n(n+2).
(16) Write the formula of compounds A and B. 1
(17) What happens when compound (B) is heated? 1
(18) Calculate the magnetic moment of a divalent ion in aqueous solution if its atomic number is 25. 1
3+ 3+
(19)Sc is colourless in aqueous solution whereas Ti is coloured .explain it. 1
3+ 3+
(20) Out of Mn and Cr , which is more paramagnetic and why? 1

SECTION:-B
(21) Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 litre of water at 25° C,
assuming that it is completely dissociated. 2
(22) (i) what type of deviation is shown by a mixture of ethanol and acetone and why? 1
(ii) Gas (A) is more soluble in water than Gas (B) at the same temperature. Which one of the two gases will have
the higher value of KH (Henry’s constant) and why? 1
(23) State Kohlrausch law of independent migration of ions. Write an expression for the molar conductivity of acetic
acid at infinite dilution according to Kohlrausch law. 1
(24) A first order reaction is 50% completed in 40 minutes at 300K and in 20 minutes at 320K .calculate the
activation energy of the reaction. 1
(25)(i) Explain why fluorine forms only one oxoacid,HOF. 1
(ii) What inspired Bartlett for carrying out reaction between Xe and PtF6? 1
(26) (i)Why is bithional added to soap? 1
(ii) Write the name and structure of monomer unit of PHBV. 1
OR
(i) What is the role of t-butyl peroxide in the polymerisation of ethene? 1
(ii) Can nucleic acids, proteins and starch be considered step growth polymers? 1
(27)(i) What type of detergents are used in dishwashing liquids? 1
(ii) What is meant by narrow spectrum antibiotics? Give example. 1
SECTION:-C
(28) 2g benzoic acid dissolved in 25g of benzene shows a depression in freezing point equal to 1.62K. Molal
depression constant for benzene is 4.9KKg/mol. what is the percentage association of acid if it forms dimer in
solution? 3
(29) For a first order reaction, show that time required for 99%completion is twice the time required for the
completion of 90% of reaction. 3
(30)(i) Out of the sulphur sol and protein, which one forms multimolecular colloids? 1
(ii) What happens when a freshly prepared Fe(OH)3 is shaken with a little amount of dilute solution of FeCl3? 1
(iii) Why are some medicines are more effective n colloidal form? 1
(31)(I) what is the role of Zn in extraction of gold and silver? 1
(ii) Write the principle of vapour phase refining and for which metal it is used? 1
(iii) Describe the role of graphite in the electrometallurgy of aluminium. 1
(32) (a) Explain the following observations:
(i) Actinoid exhibit a much larger number of oxidation states than the lanthanoids. 1
(ii) Many of the transition elements and their compounds can act as good catalyst. 1
(b) Complete the following reactions:
(i) Cr2O72- + I- + H+ → (ii) MnO4- + SO32- + H+ → 1
(33) (i)write the state of hybridisation, shape , magnetic behaviour and IUPAC name of the complex [CoF6]3-. 2
(ii)how does the colour change on heating [Ti(H2O)6]3+ ion? 1
OR
3+ 2–
(i) [Cr(NH3)6] is paramagnetic while [Ni(CN)4] is diamagnetic. Explain why? 2
(ii) What is meant by the chelate effect? Give an example. 1

(34)(i) How do you explain the presence of five –OH groups in glucose molecule? 1
(ii) What is the difference between a nucleoside and nucleotide? 1
(iii) What is the effect of denaturation on the structure of protein. 1
SECTION: D
(35)(i) Unlike dry cell, mercury cell has a constant cell potential throughout its useful life. Why? 1
(ii) Write the Nernst equation for the cell reaction in the Daniel cell. How will the Ecell be affected when
concentration of Zn2+ ions is increased? 1
(iii) Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively are
connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the
cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited? 3
OR
(i) Define molar conductivity for the solution of an electrolyte. Discuss their variation with concentration. 2
(ii) The resistance of a conductivity cell containing 0.001M KCl solution at 298 K is 500M. What is the cell constant
if conductivity of 0.001M KCl solution at 298 K is 0.146 × 10−3S cm−1? 2
-1
(iii)The conductivity of 0.20M solution of KCl at 298K is 0.025Scm . Calculate its molar conductivity. 1
(36)(i) Draw the structures of the followings:
(a) H2S2O7 (B) XeOF4 2
(ii) Why does fluorine not play the role of central atom in interhalogen compounds? 1
(iii) How can you detect the presence of SO2 gas? 1
(iv) Why ICl is more reactive than I2? 1
OR
(i) F2 has lower bond dissociation enthalpy than Cl2 .Why? 1
(ii) Complete the following chemical reactions: 2
(a) Cl2 + NaOH (hot and conc. ) →
(b) P4(s) + NaOH (aq) + H2O →
(iii) SF4 undergoes hydrolysis easily but SF6 not. Why? 1
(iv) Arrange the following in the increasing order of property mentioned: 1
(a) H3PO3, H3PO4, H3PO2 (reducing character)
(b)NH3, PH3, AsH3, SbH3, BiH3 (basic strength)
 (37)(i) Arrange each set of compounds in order of increasing boiling points: Bromomethane, Bromoform,
Chloromethane, and Dibromomethane. 1
(ii) Which alkyl halide from the following pairs would you expect to react more rapidly by an SN 2 mechanism?
Explain your answer. 1

(iii)Which one of the following has the highest dipole moment? 1

(i)CH2Cl2 (ii)CHCl3 (iii) CCl4
(iv) What happens when methyl bromide is treated with sodium in the presence of dry ether, 1
(v) p-Dichlorobenzene has higher m.p. and solubility than those of o- and m-isomers. Discuss. 1
OR
(i) How will you convert Aniline to chlorobenzene. 1
(ii) Primary alkyl halide C4H9Br (A) reacted with alcoholic KOH to give compound (B). Compound (B) is reacted
with HBr to give (C) which is an isomer of (A). When (A) is reacted with sodium metal it gives compound (D),
C8H18 which is different from the compound formed when n-butyl bromide is reacted with sodium. Give the
structural formula of (A) and write the equations for all the reactions. 4