Jee-Adv - 2014-P2 - CAT-11 - Key & Sol's PDF

Sec: JR-N-SUPERCHAINA(R) CAT-11 Date: 12-01-20
Time: 03:00 Hrs (2014-P2) Max.Marks:180
KEY
PHYSICS
1 C 2 B 3 A 4 D 5 C
6 C 7 D 8 A 9 A 10 B
11 A 12 C 13 B 14 A 15 C
16 D 17 A 18 D 19 C 20 B
CHEMISTRY
21 C 22 A 23 A 24 C 25 D
26 A 27 D 28 D 29 D 30 C
31 D 32 A 33 C 34 B 35 B
36 B 37 B 38 A 39 D 40 A
MATHS
41 C 42 B 43 A 44 B 45 A
46 A 47 A 48 B 49 C 50 D
51 D 52 D 53 A 54 C 55 B
56 A 57 B 58 C 59 D 60 A
NARAYANA IIT ACADEMY 12-01-20_JR-N-SUPERCHAINA(R)_Jee-Adv_2014-P2_CAT-11_KEY& SOL
SOLUTIONS
PHYSICS
1.
2.
3.
Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 2

4.
5.
6.
7.
8.

9.
10.
11.

12.
13,14.
15,16.

17.

18.
19.
20.

CHEMISTRY
21. o-nitrophenol shows intramolecular H-bonding
22. Reduction of ring A leads to aromatic compound
23. Only two isomers
24. Four isomers
25. EAS reactions
26. If x is volume strength.
x
M
11.2
44.8
Initially M  4
11.2
11.2
Finally M  1
11.2
Initial millimoles of H 2O2  4  100  400
Final millimoles of H 2O2  1 100  100
Millimoles of H 2O2 converted to product = 300
2 H 2O2  2 H 2O  O2
So O2 obtained = 150 millimole
Wt of O2 obtained = 150  103  32
 4.8 gram
27. (A) 2Al(s) + Fe2O3 (s)  Al2O3 (s)+2Fe(s)
H Reaction   100   50
H Reaction  50k cal
(B) Wt of the reactant mixture = 214 gram
214 gram reactant mixture produces = 50 k cal. heat
1070 gram reactant mixture will produce = 250 k cal. heat
(C) Maximum calorific value is obtained when the reactants react completely.
When 214 gram reactant mixture reacts completely heat produced 50 k cal.
50
Calorific value 
214
= 0.233 k cal/ gram
54
(D) Volume of Al   20 cc
2.7
160
Volume of Fe2 O3   50 cc
3.2
Total volume = 70 c.c
50
Calorific value   0.714 gram / c c
70

28. Let millimole of BOH = a

BOH  HCl  BCl  H 2O
a  L.R  O
 4a  a
   
 5  5
P OH  Pkb  log
 BCl 
 BOH 
1
5  Pkb  log
4
Pkb  5.6
At equivalent point let V1 volume of HCl is used.
BOH  HCl  BCl  H 2O
 a  0.5V1  0.
a 0.5V1 O
a  0.5V1
 a  0.5V1  O 0.5V1
0.5V1
 BCl   C
100  V1
1 1
P H  7  Pkb  log c
2 2
1
4.5  7  2.8  log c
2
c  0.25
0.5V1 1

100  V1 4
2V1  100  V1
V1  100ml
a  0.5V1
a  0.5  100
a  50
wt of BOH
50   103
45
50  45
 wt of BOH
103
22.5gram=wt of BOH
2.25
mass % BOH=  100
2.5
 90%

2.303 r  r 
29. k log   o 
t  r  rt 
2.303  15  30 
k log 
30  15  20 
2.303 9
k log
30 7
3
 9.21  10
0.693
t1/ 2 
k
t1/ 2  75 mint.
Let solution becomes optically inactive after a time (t). so  rt  0
2.303  15  30 
k log 
t  15  0 
2.303
k log3
t
2.303
t  0.48
9.21 103
 t  120 mint
N 2 H 4 (g)  N 2  g  +2H 2  g   K p1 
30.
1 x  y x 2x  y 
N 2 H 4 (g)  H 2  g   2NH3  g  K p 2 
1  x  y 2x  y  2y
At equilibrium:
Ptotal  1  x  y   x   2 x  y   2 y
1.4  1  2x
x  0.2
PH 2  2 x  y
0.3  0.4  y
y  0.1 atm
PNH 3  2 y  0.2 atm
2
PH22 .PN2  0.3   0.2 
K p1  
PN2 H 4 0.7
18

700

PNH3 0.2  0.2

K p2  
PH 2 .PN 2H 4 0.7  0.7
4

21
31. Size of Al is greater than Ga
32. P is having more IE than R
33. When evaporation starts
1 2
XA  XB 
3 3
P  X A .PA  X B .PAo
o
1 2
P   0.6   0.9
3 3
P  0.8 atm
So at 0.8 atm. Pressure, evaporation will start.
34. When almost all the liquid is converted to vapours.
1 2
yA  yB 
3 3
y A And yB are the mole fraction of A and B in the vapour mixture. Let mole
fraction of A and B in the liquid left is X 1A and X B1
X 1A .PAo
yA 
P
X B .PBo
1
yB 
P
y A X A PAo
1
 .
y B X B1 PBo
1 X 1A 2
 .
2 1  X A  3
1
3 X1

4 1  X 1A
3
X 1A 
7
4
X 1B  1  X 1A 
7
P  X A .PA  X B .PBo
1 o 1
P  0.77 atm

35. H lattice  764kj

H hyd  755kj
H solution  H lattice  H hyd .
 9kj
G  H  T S
G  2.92kj
p
36. G  nRT ln 2
p1
1 V
  8.3  300ln 1
2 V2
1
  8.3  300ln 2
2
 863 joule
 0.863kj.
37. (SO3)3 is non planar cyclic
38. BeO is amphoteric, CsO2 gives H2O2 and O2
39. Bauxite is aluminium ore, CH3SiCl3 is used for cross linked silicone
40. P=2, Q=1, R=4, S=3
MATHEMATICS
41. OABC
In the shortest path
5
OA  AB  BC 10 cos 300   10cos 300
3
5
10 3 
3

42.
43.

   
44. Let r  a  b  a
     
 
 r  b  a  0  r  b  ta
  
Similarly, other line r  a  k b , where t and k are scalars.
    
Now r  a  k b  b  ta
 t 1, k 1
 
(Equating the coefficients of a and b )
  
 r  a  b  i  j  2i  k  3i  j  k
i.e.,  3,1, 1
45.
Homogenize and a + b = 0
46.
Hence, two solutions.

 0, x  1

  
x2 , 1  x  1
47. f x  
 1  2x 1 x  2
 1  x 2 sgn x 2  3x  4
     2x4
Clearly, f  x  is discontinuous at x = -1 and x = 4 in  1, 4 but f  x  is derivable everywhere in
 1, 4  .
 m = 2 and n = 0
Hence, m + n = 2
48.
49. We have,

f  x   2x 3  3  2  p  x 2  12px  ln 16  p 2 

Now, f /  x   6 x 2   2  p  x  2p 
 f /  x   0  x  2, x  p
As, f  x  has exactly one local maxima and one local minima
So, p  2
Also, 16  p 2  0 ……………………(i)
 p 2  16  0
  p  4  p  4   0
 4  p  4
 the possible integral values of p are -3, - 2, -1 , 0 , 1, 3. …………..(ii)
 the total number of integral values of p are 6.

50.
 1 3 
1  2  24 
51. r3  TA tan  4 8
2 1 3
 1 . 
 2 4
52. C3C1  r3  r1
C3C2  r3  r2
 C3C1  C3C2  r2  r1 = 1
53 & 54.
1 1 /
f /  x  y  f  x  ln f  y 
f x  y f x
putting x  0

f /  y f / 0
 ln f  y 
f  y  f  0
f /  y
f  y  ln f  y 
1  f  0  e, f  0   e 
/
ln  ln  y    y  c  c  0
y x
f  y  e e  f  x   ee
g  x   ln  ln  x  
1 1 1
g/  x   . 
ln x x x ln x
1
x.  ln x
1  ln x
g//  x    x 2
 2
 x ln x   x ln x 
1  1 2
g/ /  e   
e2 e2
 
ln  ln  x    g 2 f  x   3g  f  x    5
x  x 2  3x  5
x 2  4x  5  0   x  5  x  1  0  x   1,5.
  
55. & 56. x  y  a ............  i 
  
y  z  b ............  ii 

x.b   .............  iii 

x.y  1 ...............  iv 
    
 
From x. y  z  x.b     x y z   
     
  
From  i  and  ii  , x  y  y  z  a  b 
     
 x y z y  x y y x  a  b
   
 
 ab
or y  .........  vi 

Also from  i  , we get
    
 
xy y ay
     
   
Or x.y y  y.y x  a  y
 2   
 
Or x  1/ y yay 
    
 2 

a 

b a ab   
 2
ab     

     
   
  2  a  b  a  a  b 
ab
57.

58.

59. Perpendicular distance AB and CD

3r
2R  3r  R 
2
  
C1  2R 3, 2r  3 3r, 2r 
 3 3r 3r 
 
C 2  R 3, R   , 
 2 2
r 2 27r 2
C1C2   r 7
4 4
2
Length of the common tangent = 7r 2   R  r 
25r 2 3
7r 2   r
4 2

60.
*****
PAPER SETTERS
SUBJECT FACULTY NUMBER

MATHEMATICS Mr. RAJ KISHORE SAHOO 9738668311
PHYSICS Mr. J S R 8121496966
CHEMISTRY 9505270380
8003604326

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Sec: JR-N-SUPERCHAINA(R) CAT-11 Date: 12-01-20

Time: 03:00 Hrs (2014-P2) Max.Marks:180

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 2

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 3

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 4

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 5

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 6

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 7

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 8

28. Let millimole of BOH = a

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 9

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 10

PNH3 0.2  0.2

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 11

35. H lattice  764kj

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 12

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 13

i.e.,  3,1, 1

Hence, two solutions.

Clearly, f  x  is discontinuous at x = -1 and x = 4 in  1, 4 but f  x  is derivable everywhere in

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 15

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 16

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 18

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 19

59. Perpendicular distance AB and CD

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 20

SUBJECT FACULTY NUMBER

Sec: Jr.IIT-N-SUPERCHAINA(R) Strive for Progress, Not perfection. Page 21

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