1/9/2020 (1) (DOC) COURSE CODE : CHM 138 EXPERIMENT 6 REDOX TITRATION-DETERMINATION OF THE MOLARITY AND CONCENTRA…

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COURSE CODE : CHM 138 EXPERIMENT 6 REDOX

TITRATION-DETERMINATION OF THE MOLARITY
AND CONCENTRATION OF IRON (II) SULPHATE (FeSO
4 ) SOLUTION BY TITRATION WITH POTASSIUM
PERMANGANATE
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COURSE CODE : CHM 138

EXPERIMENT 6

REDOX TITRATION-DETERMINATION OF THE

MOLARITY AND CONCENTRATION OF IRON (II)
SULPHATE (FeSO4) SOLUTION BY TITRATION WITH

POTASSIUM PERMANANATE
STUDENT NAME:

‘ARIFAH BT MUHAMMAD KHAIR 

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1/9/2020 (1) (DOC) COURSE CODE : CHM 138 EXPERIMENT 6 REDOX TITRATION-DETERMINATION OF THE MOLARITY AND CONCENTRA…
MATRIX NUMBER : 2016606136
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NAME OF LABORATORY PARTNER :

1!  NUR AFRINA BINTI OMAR 2016605806

"!  NURUL ATHIRRA AKMAL BT ZOLKIPLI 2016663044

3! NOR ATIRAH BINTI OTHMAN 2016611318

DATE OF EXPERIMENT :

17 FEBRUARY 2017

DATE OF REPORT SUBMISSION :

24 FERBUARY 2017

LECTURER#S NAME :

MADAME FAEZAH BT MOHD SANI

$) OB%ECTI&E

  To determine the molarity and concentration of iron (II) sulphate (FeSO 4 ) using redox
titration

') INTRODUCTION

Redox reaction involves the transfer of electrons, and an acid!ase reaction involves the
transfer of protons" #ust as an acid can !e titrated against a !ase, $e can titrate an oxidi%ing
agent against a reducing agent using a similar procedure" &e can carefully add a solution
containing an oxidi%ing agent to a solution containing a reducing agent" The end point is
reached $hen the reducing agent is completely oxidi%ed !y the oxidi%ing agent" T$o
common oxidi%ing agents are potassium dichromate (' r O*) and potassium
permanganate ('+nO4)" The colours of the dichromate and permanganate anions are
distinctly different from those of the reduced species"

  r O*   r -

.ello$orange /reen

  +nO4   
 +n-

  0ight purple 1in2

Thus these oxidi%ing agents can themselves !e used as an indicator in a redox titration
!ecause they have distinctly different colours in the oxidi%ed and reduced forms" Redox s
titration re3uires the same type of calculations (!ased on the mole method) as acid!ase
neutrali%ations"

In this experiment, '+nO4 solution of 2no$n concentration $ill react $ith an acidified
solution of FeSO4  of un2no$n concentration" This reaction involves oxidation and reduction
reactions (redox) in $hich electrons are transferred from one su!stance to another" In this
redox reaction, Fe- is converted into Fe- and +nO4 is converted into +n-" The change in
the oxidation state of manganese in +nO4 to +n- causes a change in colour &hen the
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1/9/2020 (1) (DOC) COURSE CODE : CHM 138 EXPERIMENT 6 REDOX TITRATION-DETERMINATION OF THE MOLARITY AND CONCENTRA…
the oxidation state of manganese in +nO4  to +n  causes a change in colour" &hen the
reaction is complete, and excess +nO 4 is added to the reaction mixture, the solution turns
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) APPARATUS

 ea2ers (56 m0)  urette clamp

 7olumetric flas2 (56 m0)  Retort stand
 1ipette  1ipette filler or suction !ul!
 onical flas2 (56 m0)  Filter funnel
 /raduated cylinder (86 m0)  9ropper
 urette


  ) CHEMICALS

 Iron (II) sulphate (FeSO4 )

 6"65 + standard potassium permanganate solution, '+nO4
  + sulphuric acid, : SO4

 
e) PROCEDURE
1. urette $as $ashed $ith distilled $ater and then rinsed $ith a!out 586 m0 of
'+nO4 solution, the second rinsing runned through the !urette tip" The !urette
clamped to the retort stand"
2. The !urette filled $ith '+nO 4 solution" +a2e sure the tip is completely filled and
contain no air !u!!les" The initial !urette reading recorded to t$o decimal places"
Since the colour of the '+nO4 solution is 3uite intense, you may !e re3uired to give
a good estimate of the !urette volume"
3. On an analytical !alance, ; g FeSO 4 $eighed accurately using $eighing paper" The
mass of FeSO4 recorded"
4. &ith the aid of a filter funnel, the FeSO4 transferred carefully to a 56 m0 volumetric
flas2" The filter funnel rinsed $ith distilled $ater into the volumetric flas2" <sing a
graduated cylinder, 86 m0 of  + sulphuric acid added into the volumetric flas2"
9istilled $ater added until the cali!ration mar2 (use a dropper to add the last fe$
drops of distilled $ater)" The volumetric flas2 sha2ed !y turning it upsidedo$n a fe$
times in order for the solution to !e homogeneous"
5.  =!out 56 m0 of FeSO4 solution poured into a small !ea2er" 6 m0 pipette $ashed
$ith distilled $ater and rinsed $ith FeSO 4 solution (all rinsing solutions must !e
discarded)" 6 m0 of FeSO 4 solution pipette into a 56 m0 conical flas2 (ensure
there no air !u!!les at the tip of the pipette)
6. 86 m0 of  + sulphuric acid added into the conical flas2 !y using a graduated
cylinder"
7. onical flas2 $as placed on a piece of $hite paper or $hite tile (9O >OT <S?
FI0T?R 1=1?R) under the !urette and the !urette tip lo$ered into the conical flas2"
;" The titration apparatus $as setup" This solution titrated $ith the standard '+nO4
from the !urette until the end point reached" 9uring the titration, the conical flas2 2ept
s$irling" The end point is indicated $hen the solution turns to a 0I/:T 1I>'

permanently"
TITR=TIO>" The final !urette reading recorded" This is the result of the RO</:
@" The titration process repeated until t$o consecutive titrations (meaning, one titration
after another) agree to -A 6"86 m0 "


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  *) RESULT

  +) DATA

NUMBER OF   ROUH   TITRATION 1   TITRATION "

TITRATION TITRATION
 Final !urette  6"B    6"B    6"B
reading (m0)
 Initial !urette  6"66    6"66    6"B
reading (m0)
 7olume of   6"B    6"B    6"B
'+nO4 used
(m0)


 +ass of FeSO4 used C 8 g

 7olume of FeSO4 solution(pipette volume) C 20 m0

 oncentration of standard '+nO4  C 0.025 +

  =verage volume of '+nO4  C 20.6 m0

  ++) CALCULATIONS

8" In this experiment, +nO4 is reduced to +n - and Fe- is oxidi%ed to Fe- " The

reaction happened in the acidic solution" &ith the help of ionelectron method,
!alance the redox e3uation"


Fe- - +nO4    Fe-  - +n-

 :alf reaction

 Fe-    Fe-  (oxidation)

 +nO4    +n-  (reduction)

 alance

 Fe-    Fe-  - e
 +nO4  -  ;:  - 5e   +n-  - 4:O



 om!ine the half reaction

 5Fe- -  +nO4  - ;:-    5Fe-  - +n-  - 4:O



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

" 9etermine the molarity (+) of FeSO4 solution
 +olarity C moles of solution
   liters of solution
 /iven that mass C ;"6 g
 7olume C 56 ml A 6"656 0
   +olar mass of FeSO4 C molar mass of Fe C 5B
   +olar mass of S C 
   +olar mass of O C 8B
 Total molar mass C 5B--8B(4) C 85g
 onvert gram to mole C ; x 8 mol C 6"65Bmol
   85
 +olarity C 6"655
   6"656
   C 8"65 +

" alculate the concentration in gA0 of FeSO4
 oncentration C mass
   7olume
   C ;"6g A 6"65 0
   C 8B6gA0

  g) DISCUSSION

i"
The result that $e got are same $ith the theory said" Reduction of purple
permanganate ion to the colourless +n- ion, the solution $ill turn from
 dar2 purple to a faint pin2 colour at the e3uivalence point
ii. The initial and final readings of the !urette is recorded and repeated three times
includes rough titration" The final !urette reading of the titration are fixed to all the
titration" So, the result that $e got in this experiment are accurate"


  h) CONCLUSION

   From this redox titration la!, $e $ere a!le to determine the un2no$n molarity of a
su!stance that $ent through a redox chemical reaction" For our la!, the concentration of
th solution $as determined to !e 8"65 +olar" =ccording to the listed concentration of the
Fe- solution, $hich $as given to one significant figure at 8 +, our ans$er at one
significant figure had 6D error" This ans$er reflects the precision of the given un2no$n
solution, not our measured precision, as the tools $e used to measure our experimental
value $ere more precise" =s a result, the un2no$n molarity of the Fe- solution $as
determined in this la! through the use of a redox titration"

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  I) ANSWER THE QUESTION

8" &hy did the solution turn to light pin2 at the end of the titrationE

 In this experiment, +n- has a visi!le colour at the concentrations, so the purple '+nO 4 
is reduced to +n-  it seems to disappear" =t the endpoint, one drop after the e3uivalence
point, that drop falls in the conical flas2 cant oxidi%ed any more Fe - and that purple drop
stays unreacted in the flas2, it spreads out and gives a light pin2 colour to the solution"

" Identify $hich species is oxidi%ed and reduced in this experiment"  
 Oxidation is the loss of electrons or hydrogen atoms or gain of oxygen atom" It $as
identified that Fe- is oxidation species" +ean$hile reduction is the gain of electrons or
-

 hydrogen atoms or loss of oxygen atom" It $as identified that +n is reduction species"

" 9ifferentiate !et$een oxidation and reduction"



  OXIDATION   REDUCTION
 Oxidation is the loss of electrons or   Reduction is the gain of electrons or 
hydrogen atoms or gain of oxygen atom hydrogen atoms or loss of oxygen atom
 Removal or loss of electron     =ddition or gain of electron
 Removal of hydrogen     =ddition of hydrogen
  =ddition of oxygen    Removal of oxygen
  =ll the a!ove reactions releases   =ll the a!ove reactions store energy
energy


  ) RE!ERENCE

• httpGAA$$$"maHordifferences"comA68BA64Adifference!et$eenoxidationand
reduction"html"&'@r<l7@*I<

• httpsGAAsites"google"comAaAstudent"roundroc2isd"orgAredoxtitrationla!Adataand
calculationsfromthela!Ala!sconclusions


• httpsGAAans$ers"yahoo"comA3uestionAindexE3idC66;6@868*4==JB&hd






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