WELDING METALLURGY Module 8

Module 8

Welding Metallurgy for the

Welding Inspector
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1. Introduction

Metallurgy

Is the science that deals with the internal structure of metals and the
relationship between those structures and the properties exhibited by
metals.
 WELDING METALLURGY Module 8

Basic Metal Structures

Solids vs Liquids

Solids Liquids

Energy (Welding Metallurgy ) Energy (+)

Atoms in a fixed position Free to move

Each atom has a specific “home”

held in place by the attracting and
repelling forces

The atomic configuration determines

their physical, mechanical, and
electrical properties
WELDING METALLURGY Module 8
 WELDING METALLURGY Module 8

Basic Metal Structures

The atoms are not however stationary in this positions. In reality they tend
to vibrate about an equilibrium position to maintain a balanced spacing.

Any attempt to force to force the atoms closer together will be

counteracted by repulsive forces which increase as the atoms are pushed
closer together.

Similarly, any attempt to pull the atoms further apart will result in a
counteracting attractive force. These attractive forces, however, tend to
decrease as the atoms are pulled further apart
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Basic Metal Structures

The atoms exhibit a very specific spacing at given temperture.

The internal energy of a metal is increased when its temperature is raised.
The atoms to vibrate more which increases their interatomic spacing

The metal to expand,,, if heat is elevated the vibration and spacing

continue increase,, the solid metal then transforms into a liquid
WELDING METALLURGY Module 8

The portion heated expands and is restrained

by the portion no heated, the bar tend to bend

Begins to cool and shrink

Residual stresses
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METALLURGY
Basic Metal Structures

Crystal Structures

The smallest number of atoms that can completely describe their orderly
arrangement is referred as a “ unit celd”

When a metal solidifies, it always does so in a crystalline pattern. The most

common crystal structures, or phases are:

1) Body Centered Cubic (bcc)

Weldin
g Metallurgy
iron, carbon steels, Cr, Mo, W

2) Face Centered Cubic (fcc) Welding

Metallurgy
Al, Cu, Ni, austenitic SS.

3) Hexagonal close packed (hcp) Welding Metallurgy

Zn, Cd, Mg
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Basic Metal Structures

Solidification of metals
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Basic Metal Structures

Alloying

The proprieties of metallic elements can be altered by the addition of other

elements, wich may be or not metallic

Example; metallic zinc + metal cooper = the alloy brass

Nonmetal carbon is one of the alloying elements added to iron to form the
alloy steel
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Basic Metal Structures

Alloying
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Basic Metal Structures

Microestructural Constituents
of Carbon Steel
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Basic Metal Structures

Microestructural Constituents of Carbon Steel

Welds Under the Microscope

Steel exist in several phases, typically Austenite, ferrite, perlite, bainite,
and martensite. See, Figures 7.5 – 7.7.
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Basic Metal Structures

Microestructural Constituents of Carbon Steel

Welds Under the Microscope

By altering the cooling rate

from the austenite range

we can affect the phases

of steel
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Metallurgical Considerations for Welding

The critical cooling

rate is governed by the

carbon content, and

for alloy steels, by

their additional

chemical composition.
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Metallurgical Considerations for Welding

Heat treatments

Furnace Oil Water Brine

Normalize Quench Quench Quench
Anneal

(Welding Metallurgy ) (+)

Cooling Rate from austenizing temperature

Quenching the steel results in a martensitic structure.

Slow cooling forms Ferrite and Perlite.

Faster cooling forms Bainite

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Metallurgical Considerations for Welding

Heat treatments

Steels quenched to form martensite usually require a “tempering” heat

treatment to lower their hardness and strength, and improve ductility and
toughness.
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Metallurgical Considerations for Welding

Heat treatments

Cooling Rate

Slow Fast

Hardness (+)

Strength (+)

Ductility (-)

Toughness (-)

Susceptibility (+)
to crack
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Metallurgical Considerations for Welding

Welding Chemistry of Specific Base Metals

When the carbon content increases, weld ability decreases

to 0.30 %C Welding Metallurgy Easily Weld able

About above 0.30 %C Welding Metallurgy More difficult to weld and may
require:

Weld ability also decreases with alloying elements such as Cr, Mo,
Ni, may require the use of:

 Preheat
 Interpass temperature control
 PWHT
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Metallurgical Considerations for Welding

Carbon Equivalent Calculations (CE)

CE= %C + %Mn + %Si + %Cr + %Mo + %Ni +%Cu

6 5 15

CE >0.40 Preheat 200 – 400 º F (93 – 204 ºC)

Low Hydrogen Electrodes

CE >0.60 Preheat 400 – 700 º F (204 Welding Metallurgy 370 ºC)

Low Hydrogen Electrodes

There are many different CE formulas

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Metallurgical Considerations for Welding

Heat Affected Zone (HAZ)

Factors that affect the HAZ properties:

 Preheat (Figure 8.15)

 Heat Input

Heat Input is the amount of energy supplied by the welding arc to heat the
base metal

Heat Input, Joules/in = Welding current x Welding Voltage x 60

travel speed, in/min

As the heat input increase the cooling rate decreases.

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Carbono equivalente
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Metallurgical Considerations for Welding

Thermal Expansion

It is often necessary to remove these residual stresses by a PWHT

referred to as stress relief

There are three methods of removing weld stresses:

1) Thermal Treatment Approved by Code

2) Peening

3) Vibratory Stress Relief

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Metallurgical Considerations for Welding

Thermal Expansion
1) Thermal Stress Relief

 The part is heated uniformly

 Temperature below its transformation temperature

 Held for a prescribed time period

 Slow uniform cooling to room temperature

 Relax residual stress because the materials strength is reduced

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Metallurgical Considerations for Welding

Thermal Expansion
2) Peening
 Mechanical distortion of the weld
bead trough mechanical means

 Usually when the metal is still

hot

 Only on the intermediate layers

 Should not be done on the root

pass (crack) nor final pass of a
weld (interfere with later VI)
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Metallurgical Considerations for Welding

Thermal Expansion

3) Vibratory Stress Relief

 Imparts high vibratory vibrational energy into the part

 Prevents the buildup of stresses in the weldment while welding or

 Removes the stresses after welding

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Metallurgical Considerations for Welding

Thermal Expansion

Preheat
One technique that may be used to reduce the need for PWHT is preheat

 Slows cooling rate

 May eliminate the need for PWHT

 More ductile structure with lower residual stresses

 Reduce or eliminate hot cracking

 Aids in removing moisture

 Helps to remove Hydrogen

 Retards the formation of Martensite

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Metallurgical Considerations for Welding

Diffusion

Under certain conditions, even atoms in the solid state can change
positions.These changes of atom position in the solid position in the solid
state are referred as diffusion.

Example Pb and Au

Example Hydrogen Welding Metallurgy underbead or delayed cracking

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Metallurgical Considerations for Welding

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Welding Metallurgy of Commonly Used Materials

Stainless Steel

In severe corrosion environments, many of the SS corrode at very high rates

SS are defined as having at least 12% Cr.

The four main classes of SS are:

 Ferritic

 Martensitic

 Austenitic

 Precipitation Hardening (PH)

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Welding Metallurgy of Commonly Used Materials

Stainless Steel

Austenitic Grades
Very Weldable with available filler metal composition.

Very Weldable with available filler metal composition.Can be subject to

short cracking which occurs when metal is very hot this problem is
solved by controlling the composition of the base and filler metal to
promote the formation of “delta ferrite” phase.

Typically cracking will be avoided by selecting filler metals with a delta

ferrite percent of 4 – 10%. This percentage is often referred as ferrite
number and can be measured using the magnetic gauge.
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Welding Metallurgy of Commonly Used Materials

Stainless Steel

Austenitic Grades
One of the common problems to be encountered when welding
austenitic grades is referred to as carbide precipitation, or
sensitization.

800 – 1600 º F (427 – 870 º C) form Chromium carbides.

Most severe temperature for their formation is about 1250 º F (677 º C)

These carbides are typically found along the grain boundaries of the
structure
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Welding Metallurgy of Commonly Used Materials

Stainless Steel

Austenitic Grades
Reduction of Chromium content within the grain Chromium depletion .

In certain corrosive enviroments, the edges of the grain corrode at a high

rate Intergranular attack .
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Welding Metallurgy of Commonly Used Materials

Stainless Steel

Austenitic Grades
Sensitization can be attacked by several methods:
 Reheat Treating
 Addition of stabilizers to the base and filler metals Ti (321) and Nb
(347).

 Reduction of carbon content in the base and filler metals Welding

Metallurgy “L” %C as less as 0.03.
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Welding Metallurgy of Commonly Used Materials

Stainless Steel

Ferritic Grades
Weldable with the proper filler metals

Martensitic Grades
More difficult to weld and often require special preheating and PWHT.

PH Stainless Steels
Weldable, but attention must be given to the changes in mechanical
properties caused by welding.
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Welding Metallurgy of Commonly Used Materials

Welding Chemistry of Aluminum Alloys

Very tenacious oxide film on their surfaces – protect against corrosion.

The same oxide interfere with the joining process.

Alternating current is used.

Reformation of oxide film is avoided by shielding with He, or Ar gas.

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Welding Metallurgy of Commonly Used Materials

Welding Chemistry of Cooper Alloys

Unlike steel, pure cooper and many of its alloys can not be hardened by
quench and temper by heat treatment.

Usually hardened by “cold work”

Welding softens the cold worked material

One of the major problems when welding cooper and its alloys is due to
their relative low melt point and very high metal conductivity.
Considerable heat must be applied to the metal to overcome its loss
through conductivity, and the relatively low melting point often results in
the metal melting earlier than expected and flowing out of the weld joint.