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Table Final
Table Final
b) Phase transitions
and their
predictions are of
prime importance in
the study of matter
and they constitute
the cornerstone of
many processes
encountered in the
science and
technology. Of the
three phase
transitions in
macroscopic
systems consisting
of simple
molecules, solid–
liquid,liquid–vapor,
and vapor–solid,
the latter two are
well under-stood
and the related
predictive statistical
mechanical model
shave found
numerous practical
applications. There
has been a wealth
of research activity
in the development
of predictive
models for solid–
liquid transitions
~both melting and
freezing!since the
mid-sixties and it
has resulted in
advancement of a
number of
quantitatively
accurate predictive
models.
c) Phase transition is
determined
primarily by orbital
repulsion and
molecular
gravity/attraction.
Molecular attraction
is responsible for
glue molecules
together in liquid
and solid. The
orbital repulsion
works against the
attraction to break
solid into fluid as
temperature
increases. The
transition from solid
to fluid is the point
where orbital
repulsion force
breaks even with
the molecular
attraction force.
The residual net
attractive force
beyond the
solidifying curve
provides the force
for viscosity in fluid
and surface tension
on the liquid.
Beyond the critical
point, there is no
attraction force to
provide viscosity in
fluid. Since there is
no attraction at all,
there is no latent
heat and no
distinction between
liquid and gas,
known as
supercritical fluid.
Liquid is just a
special gas under
pressure.
4. Phase John S. Our study of phase a) For comparably Electronics
Equilibriu Hutchins equilibrium between the sized molecules, – Google
m and on liquid and gas phases has hydrogen bonding Scholar
Intermolec opened a door to a world of attractions are
ular information about how approximately ten
Forces / molecules interact in a times stronger than
2013 liquid. Recall that we would dipole-dipole
like to relate the properties attractions or
of individual molecules to dispersion forces.
the properties of bulk Those molecules
samples of a substance. which are capable
Our studies of the of hydrogen
properties of gases were a bonding indicate
little disappointing towards hydrogen bonding
this goal. We found that the dominates
properties of a mole of gas intermolecular
molecules are the same, attractions.
accurately predicted for all
substances by the Ideal b) The boiling point of
Gas Law except under a liquid is the
extreme conditions. This temperature at
means that the properties of which the vapor
individual molecules are pressure of the
largely irrelevant to the liquid equals the
properties of gases. external pressure
By contrast, we now know applied. Other
that each liquid has a molecules’ boiling
characteristic vapor points can reveal
pressure at each the trends in the
temperature and a strengths of
characteristic boiling point intermolecular
at each pressure, and these attractions of other
properties differ from one molecules. The
substance to the next. liquid with a higher
These differences must be boiling point has
related to differences in the stronger
properties of the individual intermolecular
molecules in the liquid attractions.
phase. Furthermore, we
developed a model for c) From the dynamic
phase equilibrium based on equilibrium, the
a dynamic view. The rate of higher temperature
condensation must equal to is required to
the rate of evaporation at provide sufficient
equilibrium. And the rate of kinetic energy for
evaporation must differ from liquid molecules to
one liquid to the next and overcome stronger
must also vary as the attractions between
temperature changes. the molecules.
These experimental clues Overcoming these
will help us develop a model attractions is
to account for the necessary for a
differences in physical molecule to change
properties arising from phase from liquid to
differences in the attractions gas.
of individual molecules in
the liquid phase.
In this study, we will further
develop the concept of
phase equilibrium, including
solids in our discussion. We
will experimentally
determine the conditions
under which one of the
phases is the most stable
and conditions under which
two or all three of the
phases are stable at
equilibrium. We will then
build a model to describe
the interactions between
molecules, accounting for
which types of molecules
have strong attractions and
which have weaker
attractions.
c) Due to the
intermolecular
forces present in
between the
molecules of water
the surface of water
a blade can float
over its surface. As
an ice melts, the
volume reduces as
it starts occupying
lesser space
making the water
level of the glass to
decrease.