(WWW - chemistryABC.com) QUANTUM - CHEMISTRY - Sahender - Sir PDF

QUANTUM
www.chemistryABC.com
CHEMISTRY
Hand written notes
om
.c
C
B
yA
tr
is
m
he
\
.c
w
w
w
By Sahendra Sir(In India's top 2 Educator)
1 Download all notes by clicking here- www.chemistryABC.com

PHILOSPHY OF QUANTUM MECHANICS

The behavioral sti.ldyofmatterwhenit is in moti~n. Behavioral studymeanstodetermine the value ofdiff~rent
observables such as position, momentum, kinetic energy, potential energy, total energy etc. If the study of
•. matter is at macroscQpi5' ·sr-ale .then it comes under the study of clasmcal mechanics. Otherwise if it is at ·
microscopic scale then it comes under the study of quantum mechanics.
Quantum mechanics is the study of describing, explaining and predicting behavior of matter at atomic and
molecular level (fl!Wlf:lJHl meshaAics. It is the theory that d~cribes the dynamics of matter at microscopic seal~.
fheory is based on several statement called postulates. These postulates are assumed not proven. It may seems
difficult to understand the entire model of electron atom and molecule is based on assumptions but die reason is
simple because the statements based on these assumptions leac) to prediction about atoms and molecules that
agree with observation. With agreement between theory and experiment is so abundant, the unproven postulates
and accepted and no longer questioned. The statement and equations based on _these postulates agree with
experiment and so constitute an appropriate model fo~ the description of subat.omic matter, especially electrons.
When we study the bahaviour-of matter at microscopic level or when Materials is reduced to the nanoscale can
suddenly show very different properties compared to what they show on a macroscale. For instance, opaque
om
substances become transparent (copper); inert materials become catalysts (platinum); stable materials turn
combustible (aluminum); solids tum into liquids at room temperature (gold); insulators becpme conductors
.c
(silicon)
The Main idea 1s-
C
B
According to De Broglie every moving particle have wave nature. If mass is larg~, than it is difficult to.
yA
associate wave nature in heavier particle ..But if mass is s_rriaU than it is, very easy. to observe wave
properties if electron h.as the wave properties then there must be a wave function to describe the
tr
electron wave just as wave oflight, sour:id and strings are'described. This wave equation was purposed
is
by Scluodinger and the role of this Schrodinger equation is analogous to that of Newton law in
classical mechanics. The solution of wave equation is wave functioit So behavior of electron may be
m
· described by Wave function and it contains within it all possible information that can beJcnown about
he
the system. Wave function are not arbitrary mathematically wave functions but must satisfy certain
simple conditions like as they must be continuous.
.c
QUANTUM MECHANJCS CLASSICAL MECHANICS

w
Quantum mechanics is the theory that describe Classical mechanics is the study of matter at
w
dynamics of matter at microsco ic scale macroscopic scale

w
It is invisible world It is visible world.

Theory is based on assumptions called Classical theory is well packaged theory
postulates. These- postulates are unproven but Eg. Newton's mechanics Maxwell's
accepted and no longer questioned. electrodynamics Einstein's relativity
Eg. De Broglie and Schrodinger e uation
Observables can be determined by using There are formulae to determine the value of
interplay of wave function determined by wave observable in case of classical mechanics for
equation and the operator defined for every every type of motion.
o_bservable is core area of studying quantum
· mechanics.

. . · :-•:~~.. . . ~~M . ·t11«..ha},ia · ..···
ttif-L , : . . . . .. · ··.· . ·... www.chemistryABC.com
. (J) ~<I. r\t~atueol f'vi 1.uaKlum ~~
@ opotUoir a,. rcnrn ' . . ·/: 111~' 1

. l_ ore:. .· lf tJ/.fln:" . ._ (!) .o,m ~r PropeJ..i~
{2j .Harrnrricnr1 Tt,f!P1YJ
::; :dfn" ~ e,n ~~ t'V1~

@ N~rm l.L~ ~ pb"Cb:lJ;,~~
ID ~re.cbm:.,v, va.lu.l ~ a..uf?_~•vq_lu.t_
om
.c
C
B
y A
tr
is
m
he
.c
w
· .spiJ1 �q��· momeµlvw1 � o,s-b1-1a-l q1fta'«r 1ll1 om�

w
'
w
�te.�o.l paJnrtc.cr p'dOh�
. L��,To��

--- Ap�xfmab011 IYldUcel in (J.m (www.chemistryABC.com).
P<h...fuma:J/O'YI m�- 'U-o"l(oiJ.'¥ fodv�or,
C �ufr at- /)kaG oJ.dl-q f ndtm}

Jin d o -acllYf:lNfo,r/::ciHC¥J � ;�
a.pplicaHOYJ
vOJJ..6d-10'Y\at F'1¥ z... •,+� appltca:Jfm.
fH,omfc .-6+7S'Ud:u--<� � --&F-�<Df1f-

<
.
fH(tw1� .
t· e:�M S� mt.>ol
0 "' mo le.w.krir
om
� �
, C.'\l'll'G!fOvdfYl'a' {a t-lllhthcf'l'l
.
Sd.Ldi<M ,A.u.U.
t e sf<-!V)
.c
• . JY\aV\ C
F"!nJ'ptL C emapr 1 .spinJ
B
. fb.uli- 1'11-<M�tv1 ..i �
yA
tr
-
is
� tca.1__ Btmd.Lnf r111 d1'a:Jo»,i(_ fYltJ i.J. t..LJ.h

1
m
rnc T� \J 8T
� oc.t vH-um . h1 ec.n �. -t,s-ea:t
mem:l-- .
he
,cm 1 rno "T, (., V 8T

.c
Corv1pa.--t [Sr.
w
H'u 1�e1 M..0 Th�� tth ctpplL�CM/2 +o

w
a... annu1-e1ne.A.
w
· CP�u� ,C)�

• r�' Q.k :_
' -�- "i
rnab?emllffcs tnvoru� www.chemistryABC.com
cl (i) ��mcdt'1Yl � · ( -ve.)

@
CD .=!_
qx
�,, - nx.11-1
�
lz'
� d
- C. ::::.o
cl:x..
0
@ � �) -::/:-0
dx.
@
e
I. l1
_9_ l/ L:x.) \.J'" ex)
q:;t.,
om
(l) -Vt.. ..-vc.
e r 1 r-----,
� SiYI ?(., = CM X s-c.3
.c
-V�"I(.- ve..-== -+u-e
6 dx.
(_-V C)
\q
-4\J <
C c.-s
f:,c:, G:,/2x. =- - StY1 .,c.
B
0 r 1
3
-- l<l
yA
�
(:-'Jt) L ,+V�
tr
0
is
0
m
�
he
®
.c
�
w
w
�
w
@
�
-::::. Cl e.Cl.?C.
9
.�
Ct:}
-a) sJ
e -a.x.2.. E:
•
G :: :>(2...
q:x_
• - e,-a.,c.2..
• 0
- �q:,c,
• .1 SL'hax. a.. Ct>.&ax:.

•
_,
e,t,t
• 5
€J 7[,:.,
x. - � GtSrna.:,c.
o/ �aDownload all notes by clicking here-
0
' www.chemistryABC.com
(f) j x'>lcJ~ ~ [~,]
J j ( 1_ (dT J Jf
& J 1./(l.) \TL'll) ,:/x_ :::
[
(1)
1./(,C)
(rt}
IJ"{;,t) dx - 1.1(,c)
(Il)
lst=t"}<IX Qx
1 Si\-ix_ d:x. :: - GM.x.
J Ce@<_ c/,c_ =c srn:>t
om
.c
C
B
yA
nna tzomeby-, -
tr
is
(D St rt"'8 -:::. I- C&>.5 26

m
2-
he
UP>20 :. '_,.. CJ,,,!, U}

.c
'2-
w
.s,ne U>lB .:::. sin2s

w
2.
w
0
6l 9o..
1
S1 YJ
0
0 ),,!l..
(
-:ii ~
,, ~
G,.5
~ 1 l;
T::,...
b
~l'J- 5'f',..
e
-t-1
0
0
•
e
-, -
3JI"
:l-
,~~
@
@
6 Download all notes by clicking here- www.chemistryABC.com e

•
'~
;-}.,ti·•/
~ .. f"' ~I
' "'.;.
i : . .~. f
Sin ( ~' . I
Siw, (_ 1f 1 :i.'Jf, . _r. n,r) -:::..0
S1~1Sf!)..1~) = I
+1 0
-t
(o_;l"l}f:::. _.., '11-('.\JeN, · ~
om
loJ..-n{"=- I 'lll-ac4:J f ~
.c
(J C
B
yA
C
0 @ ,Bfn(_MB) -::.- SIV! A~ 8-t UJ41'1Si11.B
tr
0
is
(ff) W,c_ll-rB) ::: &.,!ICMB - S'ir1II.Sir1B

m
0
he
(1.) J&in-,.b"-~"" J 1- ~~'-cht "' -H?(J _ ½[ st vi:;,~

.c
~
w
-i[?l)-~ [ S1l12.bx]
w
w

·.-
C>pe:1£alo'"'( fJ.> QV\ ~\ttli' fLta±- ope..-irctt<:A oYt a if tAd:fan.Qyto/

je.Yl~ a. neUJ -to'Vl~ 01<. a c..mtt e ~
To d.d-dmiv1e. ~ "a.lu.t_ ot"- cpe.~Y OA.J!<ra.o<- o.fJ- ope-1ra:loY
we_ v,acl a 1fV\d:tC1>1 ii
{_ ope.i!a:lcra- wr11->ou:r a -i;tJV1di"tM i,,s UAd.,.,y) ~
om
I
--l oq,e~a:¼oY Qe.l'ltttallif d~or~ bd' t.l\'
.c
C
B
yA
tr
is
m
he
.c
w
w
&1,fc. ChazradesJ1>·ti'cJ-0/s= crp:.,i-g:/or -

w
@ opt..7f'~ a.M. ciL'"ll't!..of,"r.tn::J. ln v, afvre l. <!:.. ha.A.Jc::.

6p~ 'i..f:[c. ol.bte~.
e3 - .!:L .x.:3 = 3:X 2..
V ( or?fa.locr ~e.V!t~~
b'<l"OfV1 ii-te
op~1rr:d:t:J.,.
u.ft .&iau.. 'i~ 1fV1d:itl)J ()

or~,r i~:
~11::'·'
•• 1-· ~6feYQ;Jo7t·
1
.~ --vtt"'· ,'fOUJ<!.Jt tnc!t:lH6 · O~

"Yl .fi°Me>...
• t,
A 2.
II tlxJ =
"" ...,
11 t'I tCx)
.
G
@
(ix, +;_/·icxJ = (i.fxJ( l+ 1)f&.J
• -t
•
@
( :!2. .J. ,,_..+ cl :1.. ;( ~
~,. • d",,,RY
~
@
® To ~v~ OfW',Va.blA. f.-i c..la.¼iail rviec.lnav,ics -fi,tc:cre
~
Co~~paVTdh aVt ope-,rcdo,r i YI Q.M.
om
®·
~
.c
0 C .:x."
B
0
yA
1
't 'ii
tr
z
is
:: - t~ f,c..
m
'\
(Y101>1e.wJuM&_ P,c
he
~~l
,1
::: -<-li.sL
,,~
P;J,
.c
d'f
ti-;; . . ,
w
~ -=-- t4\L
t
w
d2-
w
0 r,-,..,Jf _sL
Q ::, - =--.- J1'-
l
•• ~
41 ~
-:-
l
J'X-
•• !"-,
h )-:
Ji,.' J')(..,
V~::: V.x.
"'I
~-;: \J't
• '1
•• \.lz =- Vz.
••
• 9 Download all notes by clicking here- www.chemistryABC.com
. Ill
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _..;,.__ _ _ _ _ _ t~
fJ
or-e:ra:J:1'7- (}YI QJ/1 a?;bff,-~ touch½ ~
1, ex) @
om
.c
C
B
y A
tr
is
m
he
.c
w
kf\11.e:ktc.. 0te..!'ft cpewa:lo¥ -

w
w
i:: J
px._ :::. - 0
t 'YI h(_
p'il -- - (,tj_L
-
d} { ·.' /> =mtr) I
~ - -, t <I;, .1.. ~
Jt 0
Q
2-M
•
e
®
@
10 Download all notes by clicking here- www.chemistryABC.com @
•
• www.chemistryABC.com
G
•--------~---_ ___:_ _________________
0 Po~a.l. i111 ~ or'TCCttCo- t>. bn - T1, pM.WOVI ~
@ '\ ..: - J-l-wtu.. .&.'4ow
~ \J,t ::_ \JX fVl u.l:lfp LLctlWl? 0 p-eirCffldYJ
.•
,'\
\/j -=-
~
'\tz, '::::
"t
"z.
0
0
•
(J
A
H :: r<.12.r-+pe. ·
m
€) H~ = k:x..4-- vt..,o -
o
e
.c
t)
C
B
0
yA
e
•
tr
is
0
m
$
he
@
.c
I
@ -~2.. ~2+ V
w
~
w
@ j
w
e
QI
••
G
••
•e
••
......
Lz. ~ :,t_P;t - o,~
G = -0n [ x~-1h]
o m
.c
• •
l J C
B
yA
p,t.....
tr
is
~ f [ ~Pz- z~J _.. ] [ Zfk] ~ 1 [ :,'¾-~P,J

m
X.Pz-
he
l ~ 1.7-z-- ~ I + J Czp..c - x_h.) + K( :x.Pr ~ P....)

.c
f..
w
w
w
@
©
@
••
0
@
,::::. q ::x.. ~-+ 3 X. 2-
@
12.)l 2... -::. 12x}·
~
•
•• www.chemistryABC.com
•• S~R (7} ::: S~~ (3+4)

e <-It'( f; 2.S'
0
0 (llJ
•
"
0
@
e
tJ @
*
om
0 CC>mmu+a:kiY -
v.. a n,:rl1itc.n,\ltn'cnl. op-e.~
e
()
,~~\l\~c.. '°f1>.4.
,Oil ..Jt.a
G,m~u~Y
r~i+rUV\ ct "f>~o:loY,
'
{' ~TIO'Y1 , , ~ '\Jo.lu.o.. Al!V\a.l 1,V,. ....f..a fY\ e.
B
;J,teYJ
C
.c O
tfr ~
r~-ira:knr ,~
,0
~,r, (.,, u.tdcll\ w~
~
..1
Ca ULOI Co MM ure
•
yA
"• 1t -turts-- o-p(.~ urnM\J"k. +tite.Vt ;w.. cM-<Ava blt.. un"~ l'°,,,,dll
tr
4-o 11,te. orc.1S"crknr M°1 be cl.tt-o.mikld ,.g.tn,uti:-o.~ ~ ' ft Q_tn, l t-

is
e
-:I:t- -t,.,.Tc ope.,rcth:,y d:3 m rMUfe
m
Lj) JV1M\)tC. ca Y\ \+ be.. dJ.l-c.is-mt Vl~.

0
he
e ~ ufoUJ.±e ~ keQ.~be"1' UV1~~ pcif>1U~lt.

.c
•
w
.., J\ .1, ...
[A, 8 J
w
G -==- ,i 8- B'll
•
w
G [ 1-1, s] -= o
0
• RB- 811 =-o
d1(.
e ~
•• 11-13 =- an --rh e,v, n~8 a rG ~ -fo be
•• 7./r
-r'1f"
Fl-
CoMMU~
&, 8
D
LJl)1>1J11u-l-e., ~ Op&e\,VQbU.
,o -.,
••• W McJ-t O {>e"'lf eQ(J1'

bc,_cl.u:vJnfll>C-tl s rmct.!fct Vl.t:.ous
I~ ~l Ve.w 1Yla>j
't
. 1t>}cl ll,B]¥"o' -~'," •; '·.
l www.chemistryABC.com
11-~S Commute
4A1..... 'Yto-r
~} ~ s H~ewha'/ u n ~ rJn:1[4.
~u4- f"'-q ~ vatu'--of a,vv,w,~cf
(x,1J
om
.c
C
B
yA
tr
is
0
m
0
he
.c
w
w
w
c,nre . . ,2.1JtJ8 or=17on '>Ir i.}

----- 11,.
il>XJ ~
C,,w,fllu-/olo"t' { x./ O'J1 pn,&,p @

:
€)
t{'I, iJ) .c, - ~x11-l
"*
(J flrofe.,,-tie& ~ CDMJ>'I~ - .
om
o CD MT"cl IE!"~ -
.c
@
@ If l7'J :. 4' t...,._) S\j fVlf'lehfc.
C
B
yA
tr
is
m
he
.c
w
w
w
[A, f3J = - [B,11]

[ 11,8] "- [ 116- 811] "' - [ 811 -118)
:-.- [s,11)

om
.c
[ -l'1f;;: I :x"] B
C
- lr, 'Y/.Al'J?,,..I
yA
' <1 ·
tr
E.t'' J : : ,{,t:,
is
I f;>x -n;,(11-1 ::- - [ p,,

m
he
e,- - [-:tj, t>,t.] c. cdi, ax2...

.c
w
_ l(J11 ax?-
/?x r?lj ] -::.
w
[
w
llnemJ-f:t-
0, s+1] = [il,B]-i-[a,cj
[F1+8, c+o]:: [11,cj+[11,DJ~[B,C] + [B,DJ
fH~,,~J
[ l'-(,v+Vc><)1xJ" [1'<,,.,11x]-½-{!?oJ,xJ

,,,
•• @ !?_~-hr1b~~~~-
[11,s;Jc;.-1- ~[11,f)
•
@
[..t7, ~} ::
)!IJ, c) -" 13.[11,1:J t- [~ c].$ 1
:: N),u:x.]-+ [P><-,xJpx
- d1<
x, r><J px...,.
<;:_ 1..,,[ x, p,: J
::::. Cf7 px_ +- px. t~
om
0
:::: ~ l11 ~
.c
[ x, p)] C
B
y A
tr
is
A
V
m
1
he
St1Y'ilct~ i
[ x, t,,Z'] :: 1-1 l,I;\ ~-
.c
w
-=:.. f-t; ¥!~:1- 1

w
EJ
w
0
[ x'Ylt1,>1.J :: --+ l-t:, n.x'>1-l
~(_ I i,:!]-= -+ i-~1 n p,2'1-)

(9)
. . . , , .•···• ...?· ·. . .
o,>et~'2f (Jfn11Ylufe wltt? , ~ aNJc/ · w1Tfj, ·~·

,. . . ....·.... ·· ' . .•·. ~" k :. . : . . . ,.
p~r ·
j • •
,
[19,A) ~ 0
•'•
[~,~t}:: {) t
I
@
I
[ix, i:]=o ~
[i, ii]=u
om
.c
of?P..,J
:.:...:-- C
B
[~, P,t)
yA
{i)
tr
is
[~ 1/Jx]
m
he
~ [ ~~f,<.1 ::::.0
.c
w
w
w
®
®
@
®
t)
e
~
•
@

••
•
.. ,.,, ~
·./..•.
!"; I
l.
~ri
,·-~·.··.
~-.j DPP 1 Quantum chemistry

J.-'fhe value of A 2 [if A= x-(d/dx)] is
i
••
2 2
(tif(d2/dx2)-2x(d/dx)+x -1
2
a)x + (d /dx.2)-2x(d/dx)
(c)-(d2/dx2)-2x(d/dx)+x2 -1 · (d) x 2 + (d2/dx2) ~ 2x(d/dx)+ 1
3
•
,;: flhe value of commutator (x , Px) is equal to . GATE2010
!
~ ~x2 (b) _ 3ih x2 (c) hx_ ( d) h. x2
2rci 2n 2m 2m
;..-, Which of the following pairs of operator commute GATE 2006

2 2 2 2 3
a)x and (d/dx) ~dx) and (d /dx )+2(d/dx)(f)x (d/dx) and (ct2/dx ) @x and (d/dx)
~ e value of commutator (x,Hx) is
s,-{fi2141t2m)(cf/dx~(Q) (h2/8,i2m)(d8/dx"_} ~(h2/4n:2m)(dD/dx1) @ -(h2/81t21n)(d1/dx4 )
om
iS--1."he commutator of kinetic energy operator T x and--the momentum operator Px for the one.
• dimensional case is CSJR JUNE 2014
• .c
i (a) (ih/2n) (b) (ih/2n) (d/dx) efo (d) (ih/2n)x
C
•••;
/
(
'6:-'The value of commutator (x2,p/ ) is equal to
B
A
l (a) (ih/2n)(XPx +pxx) ~h/11:) (XPx +pxx) (c) 0 (d) 2ih/n
y
q,"' Consider the statement

tr
2
A 2 f(x) ~ F
is
! i)if A is linear operator then the value of [A J(x)]

•: f"
m
'
~The value of commutator [x,(x,p/)] is equal to 0.
•:
he
iii)The multiplication of two linear operator is linear. i

~ iv)Square root is not linear but square is a linear operator r°
••!
.c
I
w
I The correct statements above are (a) i and iii (b) ii and iv (c) i,ii,iii (arri'i only (e)I only
•·
w
. 8 Consider the statement
e;I
w
: i)Theconunutator of d/dx with x is a unit operator "'f -

I
•: ii)Differentiation and integration operator are linear because for being a linear · operator
.i.,
,: . A{C1f1(x) +C2f2(x)}=C1Af1(x)+C2Af2(x) is the condition 1
iii)Linear operator always commute with any number. l
The correct statement above are (a) I and ii (b) ii and iii W'i,ii,iii (d) none
..,!
i
~ value of [x,py], [Px, py] respectively are (arbitrary fun~tion state function)
~ (b) O,n~t zero (b) not zero ,0 (d) not zero,not zero
'1-6:fhe SQRT and SQR operator·
• o I
~ommute with each other ~ o not commute with each other (c) can not determine
11.Given 2 hermitian operator A and B we construct the following four operator
AB,~,i[A,BJ,A2B Choose the correct option from below CSIRJRFNET
a)All these 4 operators are Hermitian
b)Only 3 0f these are Hermitian
~ l y 2 of these operators are Hermitian
. , • I
' : J
d)Only 1 ofthese operators is Hermitian

12)Identify which of the following operator is not HermitianCSIRJRFNET
a)(h/2ni)(d/dx) ~(d2/dx2) (c) d2/dx2 (d) x2
13)The value of Qommutator [L.x, py}is
m
(a)(ih/2n) (b)(ih/2n)x ~ih/2n) P.z. (d)0
o
.c
14)Thehermitian conjugate of d/dx is CSIRJRFNET
ef-d/dx (b) d/dx (c) x (d) 0 C
B
15)The degree of freedom which value depends on the volume of container is (MSQ)
yA
~ranslational (b) Rotational (c) vibrational (d) electronic

tr
16)Consider the statement

is
I Hermitian operator always·cornmute to eac~ other. F

m
he
iiHermitian operator have real eigenvalue always. 'T

iiiEignfunction correspondingto hermitian operator are qrthogonal. f
.c
The correct statement above are (a) i,ii (b) ii,iii (c) I,iii (~ii only (e)iii only (f) none
.
w
w
17 Consider the statements

-r
w
(i) If A is hermHian Bis hermitian than (AB-l:1?A] is hermitian but [AB-BAJ is antihermitian.
(ii) If A is hermitian B is hermitiai@A+BJ}s antihermitian and i[A-B] is hermitian. C?> r'
(iii) The multiplication of two commutating hermitian is hermitian."i
Which of the above statements is true (a),i (b)ii (c) i and i i ~ and iii (d) i,ii,iii
@uncertainty in the velocity <°f an eiectron if uncertainty in its position is 100 pm is
........ m/sec 5. 2.S1,.to -M ls
19. When we operate the operator (d2/dx2) on co sax +sinax than eign value is ... .-:-:-a~-.
20. when operator /dx is operated on 100e5x then eign value is .. .5. ..... .

r., • C
(§) (A~"~ ~ C.w»H~ www.chemistryABC.com

Wt°-ff1 CDW.-/oMJ
~i,d:,"?J. . ... . .. . ·. .
[n, qJ -: : . o . · ~ 11~,p - QRl/1
{t:cJ~
~
. [ X 1 { X1 px) J
-)
[ :ti l·n) -=7
-t
o m
ll>tt&ftt
.c
C
B
[:x-J {x/;x)_}
yA
tr
>
[ x,?ihx}
is
m
~ih [x,xj-== 0
he
.c
1:fr · both ofe_-i'aloY have. -/ttt. Mul:hfu°aihirn a.g itt.,.. 0~

w
t:::t_
w
-tkA.n Uf)mt11v-/e b«a.UAe. mu..1:b'"pu.·cattd),1 ffae..lf,

w
CJIJm.,.,v\a:l:i e.. .
[ :x..,y]lf('4J} c ;,<.d 'ltz,«:J) - f-X '-/1(~,:J)
Bu.J.- 'o/ 'ilx_,
_!:
'
- .- [ ')(, ~] 4'(,c,3} -:- 0
Bo-th. k:{ue. m.u.tfC,,Llca:E'1111

~ ope.ira:bC1Y1 •

• i
I www.chemistryABC.com
[atsJ+.:: tts+aft = o
==:i a \.d:fc.oM,'\,\l.rtc.
J'l13 + g A- i:1:- "O

t;.yf
=- I:: i+F) ,, (
-::!'( >.,lrl-'<::t\dtCOM~ : t11 c-1x)
-, J+ fJZ, diutlYlbf A-r-utd ~ -=- - {,I;, ::l
ol,t,
a.us- 1:-1- ct,>a'a:foir' lx., c.-x, 17~ >Ju rd..wfim1 ==) H,(zrM i nd.M
lo\41.,,-
@) ( ~x. C-x; r J 1 •
?C.t,, ~,P) j
•
(bJ [
= (-1rnr (:,,_i,)t :
om
(_c(-[ p, ( ~L~f>) J = - ct'l.. '
.c
t., 2.
~ di_L I
[d.) [ ,:>t_, (_ ?L7, pJ] C He, mrt"TCt-11 I
B
=)
yA
J Atiict~ j I
.•
tp.,, :! qJ A-t91ol<t
tr
OR
is
'
Jir".4 ach:_:: Jd A-4d,t d-C
m
•
r~ 2p,J
he
&----------'-------.•
:: [ ?'-,
.c
w
:::- ~tl-1 L bx) •

w
?l I
••
w
2 '.)C,p-2- ~~
= ~4A Litlit) -::, -c:z~
[r~, taj
' ~ un,&lt, (=>C,px)=- -t- U,
•
®
'
~ o
••
e l ~r, iii] "'o ••
,;:
@ - [ p, l~ f) J. lf -= ~TA, [lxJj
<C I otll#JL)
-==-d?lh {-lV •
•
(:x-, -1-c,llh7!.J (-xi 'JI] .::.11
G) ::: ,xih
-:::: . -olJ, 'L__
;.•
·•
.' ct;' o;,~:dl1-tbna~~·"· pu-mo.,,.
~ f-1.,,,....
u)}ief~ . lilit\1, · 1111o&+
'I'S if"~
a.lJ,n
!,e.;•. ,f{c.~fti21h} , · · ·.·
.MAL \lCllW.. .,-1',www.chemistryABC.com
,..; u.11/,!,
➔ A-n o~""a;Jo,r H~ -lo ~c Jte.,(tvlitfa.,y, t?Yt1 u.Jht!IYJ _
J4'-tt Al.f d -r. ,::: JwA If' d-C:: It II:;
~ -t,f<-
Jd Aict-r J i 11~43»- J-G
,t C
~
?I" -::, c..n1F ortU"F-
0 •
L--,-L
0
ll) := A--+l &

.
4)* ~ 4-Le
.
➔ S \.,ou.Ji1na:l- ope.,ra:¾oa ~ u tt<.'lfmman
om
.c
C
B
"it f1,
A
Lu~ J,,_a.ue --1-e ,!,ltl,,w ~,c, l,..t_yM*a.M
y
~oO +co ,t
Ji.ft,,_ ip • d-X. " j IJJ k,! 'I'

tr
If cl.,,_
is
-.-c::,
-o0
m
he
L·H·.S -
=---
.c
w
0.0
-: -;__;, J o/ ~
w
~ cl:K.
w
J,L
--o
-+-0 ..,. oO
• ~ _ lfi [ ('-1'' ~~ - Jt;:

-,,o
lV d"-] ~
G
G
@
••
•
••
. . . .
. , • r(//�l/11.: = �
.
• ..
I
•
i
J LI' (_-- 01,i} * tp* dx.
::: f¥, J lJJ c!.J!_� cl."-
J 7L 1fV\.d::icm va,., >�11 �
�
.®!
at ,..,frrki.te
--
H�crmf-liam a.at)?'�_ ( H(1rmi11a/Y1 cn,fv�)
om
[)+- � a_ n1o:ll1�ma:bco.l art.cra±i<M. �
r\1V01ue ope.ira:.b'°cm -hso.vgpc:,JJ.e �ltld um1f>UX Co�u-Fe f,,., it.
.c
g,t- r� d.t'Yl a+col h �t' (�a.'ff'tt:o) C
B
<f
yA
Ba, u,sfvt( tf-e.�mH1am a.r{jcifrK.t we 041 cw.cl<

tr
H �ismi-H c.1.i,, °i a i1 � pc:<fafo "f.
--J o
is
m
J �.., 11
1
i d-C ..(,,.,,1�qtf. d-r..
d
he
.c
J@
w
w
Ji If tcJ:t
w

·iJ ~,d-14~: ti~~m~ ½~°' ~ - www.chemistryABC.com
fr ~tc. FP~
,
CD (At) t:: 11 (t) fl ,~ l-letrmi-hQM t»tt;f wheA?
,1t ::::}1 '
( ., i J fl ~ F/wr/,.. M:..1rmrlrOA1 thlb-l,,
•• © 011/1 ~ a1t11t
w J,u.n,
nt C -fl
- ti
0
o e (R+sl"" 11t+st
: © (fl tJ -n ~ { r:r,,;f
: © (#:1J1 = -:x
om
6) x_t ::.
.c
t) X
e @) ~ t) -11::. 0-·'1/ C
B
0
yA
0 ~ 8Jttuw f1l(J.t f,t r/2 Hami-nahl

tr
e
is
-
m
Q
he
0
.c
~
w
@
l~ {-2.)
w
& - J:,c.
w
(.} -:::. - ;1,,J

G J,L
e
€)
()
()
"e ~
@
J2..
•• - -1i'l.
- -
Jf'II J::,tl-
:: }<-,c_
• 25 Download all notes by clicking here-

=.) www.chemistryABC.com
t4a,,.,i-lia,t1
{};)~ -lx}t
-- -}}, -{t-x)
=--
--h
e-};'/"[
om
(ij)
.c
flt=- 1l-
(~sJ r =, 13tnt
C
Bt::- B
B <.fu~
:::: BA
yA
AB n°f- Htrm'rlwn
{(!el -:t- 11-B
tr
is
m
,i(. ~ 111. uJlltltadtav, '1 -/wo W.,i--mrliM? of=a:loY.s ,,~ w,f-

he
.c
JvA mi+tam
*TfYli+t('.lNJ ~ wJitW\ opeya:/tJ~..s·
w
01u.JfipLtcatrov, \/2
w
Com'f'YlU+e MCCI.V\I:. 'Mu.t±-fpt.tca±r~ 'i- furO C..mmvt-akve..

w
~ M,'11<1/Yl eipe-crct:hnr ~ n.ecrm1-fia.M.

(ABY¾J t :: Rrat At
- /t113R

[ £
11 8
] r.~ ·[Alf ~g t , ., 1 ,st'l/t,1tr www.chemistryABC.com
= 811A
.c (!31/j Nor f/<.TNttnaHJ
@
(iJ ( fl. 8-t BA/ '°
l811 + 1/13) . H<T1>1~a/Y1
{ BII - II {J J No f H<.rMifiahJ
~ e-6ft} t- ,,
e
i::9 0 .,e,l ::
{_!-Bf'°
e
om
0 f{ /M.. uammu+a:/:o¥ '1J- +wo h.Wt,(f-,ahl c,~ 'If l!. &,d:,._H~.,. mil-,0/11
.c
C
11 =-- 11 1 ·
e
.
C .
B
8t : :. - B
&
A
0
8 ~ 8 II} _, fl..,,,.J,,umi-1,c,.,,,,
y
e
tr
is
@
0 . 1/( tl,...t o.ddL'Wdfl a:114 ~ub-5h-a.t:h1m °D -fwo t...JA1nrlltVYJ t:Jfe?IO:ftJ'l:S
m
IA harr,1;f,a/)1 I.. c (1_+ 8) t.,_ (ft -f3)

he
0
.c
@
[III B] ~ f!kl,"!.-fl(.7,MM'7Cl/J?
w
©
w
0 l { II, B]= Ht.7rfflflh"a.-n

w
~
t)
G
~
e
I@
e
Cf
C
•
l':t 27 Download all notes by clicking here- www.chemistryABC.com
i
.
www.chemistryABC.com C
G
''
[L~'a] - i-ti z. lL:x- l Pa J ~i,2.. Lx, L:J) :: iif L:z..
[ L1,z] -
0
l~ x:. [L~ Ip.. J c.ikJ>~,. [ Lg, L-z,] = i"1 Lx.
I
[ L~,~J - IJ;, 't ~%/ p,c.J i~p, -c

[Lz, L~ -::: lb; L'I ~
~
om
CML q:>t-~ f ,,,co, /,u.__ O t'IC ~ y ..: /'ti• .,, { lhj;} 16+ - fl "f" lo.Y (_1.,x) ~
.c
fYlow,eM}v~ (_ L:x ) qn=,/ o11A»..-
C lx. 2nd - u ld'
iA, F'ftO'Vl ('ef) ,ti1(.M.\.._-... ~~~M Pt
B
2.~ r '),;; -
yA
wH.1. k p~1-h~WI (-z.J f{~u.Lt..- IYIDYrl~"(h} ~~Ll!t - L"2.UI~) [

G
tr
is
~3,LJ ~-tbip,,_ · l~,1.,.,J =-ll,~ :

m
he
.c
9pfr1 M1'j!.t.tA--1Y1t>meu;/:1;»1-
w
w
~ {y) « {~52.
w
( s~, 5-LJ =- th ~
~,Sx) ~ it;St

• f [~, :x] t;cxJ ,,.., .·::=! ':· Lx_ -x '<l'lit.J -- 1<c\l)L-'-"{jtJ ,
••
e
:: - r;, { 1JzL - z i } x. W.>c.;-
d';f
x {-th 1 1,1.. _
L~ Jz
z ;_ )~b
dj .
@ - 0
€)
@
• 0
:: - t1; ( 'J A--z_f.J) :f l/liX,yJ - /j [-th{!Jfz-71:;) I~
(}
1 rr '()
@
®
-:o lt; z "fy '? 4'(x,~) - l '}a7J ·q; tX,J)
~
::: t't? z. [ d' d l/1(;}( 1!1) ~ lf(-x..J) ~J
om
@
t1-;f def
0
.c
e - th Z.'J B
C f.J 'l'l7t.,!:J} J
0
yA
c-~
-::: t't12. [ 'J d'4J(-x.,<j) + lJJ{:x,:11) _ t-hy ~ d 'P(-X,J)
....t,::i.Y
tr
. d~ rJ';f
is
r,,,
m
:J~~- d •N(:r.,,J r]
he
-== L°-tt z [
~ -+- l/l('f.,'jJ
~ Ya'f
.c
w
~"' ,;,j4't7t.t;f- "" t~z. 4'~,'.J)

w
w
t)
Q
0
[ [Lx ~J 1 cc l1i~1
()
G
[ Lx 1 ~
1] "' itifz.
~
Q
[ '//2- - <-IJ, I}) == ['JPz_, P1J} -[ P'I' fil) 2
• [ 'J1Pu Jfz + 1[ Pz1? J - [ z, P; JP't

• ==
• - z[ Pf1t1}
•
~- 29 Download all notes by clicking here- www.chemistryABC.com
Cir btkl ~ u «:UrMomt.UIPn,,~
L+ - Lx-t- ll't S+ ~ S:x.+ tsd' -Sp4n ~t1r

• . ape~?f (i
8-::: S.x-iS;; ] @
<lpfn lOUJcu.,-
cpeoa:lo¥
[NtT]
~us. - {W
- crpe-t~ s± r~ dJ.f,fVla::l ~ St::: S.:x. t i5t
om
W/Aw_ Sx OMdft a.AL UJIYlf"neuf "{; Afin ~lVL-rnomeu:lom
.c
C
B
-
yA
Sor>1
[ ~ / $.,_ + is;f]
tr
,_ ez. rs.._]
is
J
m
-t [ S2. 1 ts/I
he
= tt,sl + l [ h.. ,s,yJ

.c
w
~ l#.S:f + t (_-tJ;.s:Jt)
w
w
a {ti.SJ + 11 Sx_
-::: -II {s~ + 'fl)
f_-11~] @
@
[ .S+,S- J e
0
S;x, +ts'f, s,- ts'f
::. [S){, 1Si + [ Sx. 1 -t1j} + [ i"Jt,S,J{u,,-1fl}
•
C
®
II I/ ®
D O
30 Download all notes by clicking here- www.chemistryABC.com ~
•
'• · .· '(:JF•···•. · ::;'"' ~· t[1t't]'•·. · 4 ;{1f;s,J ··
.:,. '
' .
,.• ::. ~ t[ .t,i;,sz] --f t[_u.szj

'I : : . _.;i'-4iS:z...
• -=-o2_#52-
••
• 1'(. ..f!),e~ \Ja.lut gr'>1 -
•
om
.c
C
B
yA
tr
is
m
he
.c
w
w
w

' .. ...
~
· · ;.'.lf r& o~ ot .,-w_ lVl e:tl«I -t1,a:I- t).. w e.\l'\L4 ~ -ro·• ~,.l,if '
11,,e 1J<1) I... 1-- o!M Cl,. \JQ 1-,lt_ hif u,61,- 0 l7 e..~ a:m- .°ii" ob), OIVCl bu. .
41/\Q 1;'Mdiav! ~ ~ . . · ·
;:!_ t:'.'.(c,&4.?(..
d'X- .
- ci.:2 si11.ax.
J·etitJYt
➔ A .tun~
~
I
om
_t.& J11of alc.ud1f a. d~ f'rtd:tqyi
.c
C
B
A
' .
y
. ..s{:-. _St'1QX. ::. ~ a?·SttiQ.x ~qLm "'Fvtch<f'YJ

tr
f
. . d=x.2.- . . q . \
anr
is
. ➔ .~ i?DL1l.,l:J.• (~ a.H<Lw.>£l wrfti -fw_ . ~ -fv>1d-,";M {f-<:_(o~l?lf-. I·

m
he
- ~ -fttt.e_ et~ ~ ' ' ..·

.c
5
.. :.eq_. - cl e "- -::. ... (§)e•s;>t...
• -a- rcP- . ...
w
w
.. ''ct ~ 1cro ~sic.::: ·• @) 'ttrO ~~x -

w
1:t"",c.. ; ·.' ·. . . _,.::·,. . . '
. cl (J)
-
dg . . . .
/a?ro eSJG
JOTb-e5=t=
.
a.lfa.~. wf1'vl -~ pe_~t:do'l{ 1 .-tt,e.,J;\
I
I
32 Download all notes by clicking here- www.chemistryABC.com J

DPP 2 Quantum Mechanics
1Consider the statements

lXA+At) is hermitian and i(A-At) is hermitian. ..,
2)KxPxand Kx + Px is hermitian operator. T
3)eax+b is an eign fu~ctioll.for an operator d/dx.. i
The true statements above are W-,,2,3, (b) 2,3 {c) 1,2, '(d)2,3 (e)3 (f) 1 ·
2 Consider the statement
1) lf'ljf 1 and \j/2 are the eignfunction of operator A with distinct eigenvalue than c 1'\j/ 1 +c2'\j/2 is not
an eign function of operator A. f 1' , Lx _ h'~ismi-nQ\1 L?t.l .f ~ Lx = H
2)The operator Lx_Ly + LyLx is Hermitian operator. a L~- Ht.1,m;+foii, 0
3)The operator [x,(x,H)] is-(h2/4n2m). 1
The correct statement above are (a)l,2 (b) 2,3 (c) 1,3 (tiYf),3
3.Consider the statements
m
l)Any two eignfunction of hermitian operator that belongs to different eigenvalue are
o
orthogonal. 1
.c
2)-i(d/dx) is hermitian operator. -f
3) Commutating operator have common set of eignfunction.,-
C
B
The correct statements above are (~,2,3 (b)2,3(G) 1,3, (d)3 only
'5.{(-h2/8n2m)(d2/dx2) +(h2a 2x2)/2n2m}e-«x,. = ·c(h2/4n2)e-ax2 (h,n,a,m constant), value of C is
yA
2
(a)2a/m (b) a/2m (efa/m (d) a /m HT JAM -2.x.1-
tr
'6)!2 If an operator {(d2/dx2)-16x2} is operated on an function e_2 J-than corresponding e

is
eigenvalue is a) -2 'ff-4 c)2 d) 4 e) none HT GATE

05
m
?)The.kinetic energy corresponding to given function (1/L) sin(nx/L) ( for.a particle in 1 D

box oflength 2L (-L to +L) is
he
'af(lj2n2/2ml2) (b) (lj2n2/ml2) (c) (1j2n2/4mi2) (d) (1}2n2/8ml2) (e)none

'8)When the operator--0\2/-)(d2/dx2) operates on a function e-ikx the result is
.c
~n2 e-ikx b)ik2n2e"ikx c)ih2e-ikx . d) t?e-ikxHT GATE · .

w
9)Consider the statement i:0g1ttding ,tJ)il» bt)t'\,e.

w
l)Evefy,fonction used in quantum mechanics should be an eignfunction. f '° CJJ..Vt.\Jr be. _\\.\J-. co,fV\-
.' . c:):trJV\
w
p ~-
2) The function f=O is never allowed as eignfunction for a system. 'f ~~ ~ ~
3)All eignfunction of Hermitian operator must be real functions. r t<r Ge] =::..o
The correct statements above are (a)l,2,3 (b)2,3(c) 1,3, (d)l,2 ~2..
10)The value of [x,px] is equaj..kr" IIT JAM2015
~ (b) lj/i (@r-'ilj (\t)-lj/i
11 )consider the statements regarding operator ACS IR CHEM
i)The multiplication of operator A and its hermitianadjoint is always hermitiaµ. I
ii) The multiplication of operator A and its hermitianadjoint is nothennitian F
iii)AA 1 +AtAishermitianbut)AA 1 -AtAisantiliermitian F
The correct statements above are (a)l,2,3 (b)2,3(c) 1,3, (d)l,2 ~
!
I
I·
.'
12) If operator A=-(d/dx)+x then CSIR

a) A is hermitian b) A is anti hennitian \ef"AA t_js hermitian d) AAt is anti hermitian
~nsider the statements '
_L The normalization constant for function eim+of a rotating particle is 1/(2n)5 . -r
].. The normalized wave function is dimensionless.' T
3.The probability of finding particle in I D box oflength L between the limit Oto L/3 in first
excited state is 33%. f
The true st~tements above are (~,2 (b) 1,2,3 (c) 1,3 (d) 1 only (e) 2 only (f) 3·~mly
1-.t:e~msider the statements . ·. .. · · .
J.. The normalization constant for a wave functidn sinnx between the limit O to 1 is (2)'5. '\
2.The average value of momentum is O for a particle in 1 D box means,that momentum is 0.
3. Uncertainty in momentum for a particle in 1 d box of length 1in ground state is h/21. -r
om
True statements above are (a) 1,2 (b) 2,3 (c) 1,3 (d) 1,2,3 (e)l only (f) 2 only (e)3 only
.c
I .Larger the region of the box larger the uncertainty of finding the.particle in the region.
2.The value of commutator [Ly,pz]=(ih(21t)px: 1'
C
3.The average value of (momentum}2for a particle in 1 d box oflength 1 is n2h /4i2.1""
2
B
1
A
Correct statements above are (a)l,2 (b) 2,3 (~)1,2,3 (d) 1 pnly (e)2 only (f) 3 only
y
16. Consider the statement

l .If a Junction is normalized at t=q it would be normalized at every time."\
tr
is
2.For stationary state the probability density is iildependent of time bu! function is dependent on
time:-f ·
m
3 The complex conjugate and Hennitianadjoint of momentum operator give the same value. f
he
True statements above are (SJl,2 (b) 2,3 (c) 1,3 (d) 1,2,3 (e)l only(f) 2 only(g) 3 only
l 7Consider the statements
.c
1. The uncertainty in kinetic energy for a particle. in. 1 d box of length is ~ero.--f
w
. " .
2.The particle of massm is confined to move in a ld box of length 2 nm the uncertainity in

w
position in ground state is.independent of mass. '1 ·

w
3, The particle in 1 D box 6f length 1 have orthonormal set of wavefunction is orthonormal. 1.'
T~e statements above ate (a) 1,2 (b) 2,3 (c) 1,3 (afl,2,3 (e) all (f) none (g) I (h) 2
1S-For the_p~icle in a box probl~m in (O,L) , the value of <x3> in.the n-.co would be
a)L3/6 ; ) L3/3 . - ~ 4 (d) L~/4 CSIRJRFNET
l 9)The angular momentum operator Ly would be CSIRJRFNET
a)(-h/2ni) (yd/dz - z d/dy) ~h/2xi (zd/dx -x d/dz) (c)-ih/2m (d/dx) (d) none_
I
2.!Vfhe operator S± :±::: Sx ± iSy Where Sx and Sy are components of spin angular momentum
operator The commutator [Sz ,S_] is
--!
(a) hS+/21t (b) hSJ2n . (c)~hS+l21t (d1'-hSJ2n (e)none

{j)
om
.c
C
B
yA
tr
,n
is
- ~2. .. k al e-tkx
m
- l a,(J
~/YI
he
:::. _~2 l01< {-ik Ct~

.c
cQm
w
w
w

i .
• i
ij
@ (i) ftl}~ (/l ,l

::: HIit-
(_w.) [11tl + 11+11Jf ;=, f! 11t/,- (ttll}t

::: lf1+Jt-" ,- + ,r'{~1 f I,-
::::. 11 II+ + ,r,..A
om
t"f_ 11(
.c
1Jf :: (!!ff/-: (11?1)"
B
C
~ 1111f:.- . . . ~ 11+11
yA
tr
is
m
he
111' "' . .i + ?L -7 Ml+ h.u.Jn iHa,,,

.c
{I . oli.. .
w
t . t
(-t+1 {J-./1/
w
(-i+x)( i~+~ ·~
w
Sz." "1
s_-: s~- rs,
[ S2., Sx..- ts.uJ'
[.sz,s,J-[ s ,-ts1 ] 2
, iii~ - i l -ihfa]
i '1 Sif -r lhSX;
; ·' ' ~ ~r~Jr' tkrm i~apgalo:t- .•
: 6) er -vol.tu.. eon-~~ -/-o Ho rni-livi,, e re?f o:Joy oU

alwOJf A~• .
Lt¼ u! C0\'lA~ A r~ an heJimrlr<llYI t:Jfnra:ka- w 1'1111 ~ valw.
etr"Yf ; I.JI :::, a (JI , /.}Jf-v~ !:" a+-'!';1t

As ;, f1:, UWYJ"rhCI.M
j If If /fl 1/'dT = j I/'/l_,.'l'~c/7.
~
0.
j If'* 4 f/lc/T,, =- j '-F Q~ ff'?r cir:
e
m
'
o
.c
0
C C
B
e
yA
~,
tr
••
is
® Nol'I- d"'t'-rnk ~ fmdi'(IJ// OJ~fdl'/CU_•.,, -k, /1,«mrh"'am o ~

m
a;e orlttlo ry,aj

he
0
e Acp, -:: Q, 4', ~ t- lP:..
.c
w
•e
w
w
"It A4',.:: at.P, ti, L 4J:2-

..,
• fl 4',. : .: q l./J2- airt!. o1,-e.11~irate.
e
• 1Jorrcb°Ol1,
• ~a- r- [ I 1l
r:, r:z.
• t,x.
•• H 4' p,<.. : G 4'P-''-- lf!hu lf~lf 2- Lfp-z.. ~lfe.
•• H '{P~ ~ r;, q, P'f ~ea etrYa:re.
HIll f,z. <- G ~ p-z-
•
➔ 0rl1't~~ www.chemistryABC.com
ii fut/V\ ~
I
®
rwo~v,ctTOY1 {l)Mf. l/J')'l a~ ~-+o k ~ oytt,,o-rd.l ~Whe-J? @
j 4':!; tp77d-C ~o
J+- M°a' l,e_ CO\'lc..a..pu4ul!~ ~ t~dfc1)7~ (f1f':' dtire..clr<n1cJ.. IJI)
om
yta.:b,.rl( e.. &.. a.cl- ~ V eclo "< <~ ~ -two '\red.a¥ R-Rr- B cut.
.c
C>~~al_ ~ Wklh? _.,
ls == o C
B
G:
A
4. g :.: ,t:/ 13{.I!, lJ

y
ra~
tr
B ~c,o· (_
is
m
-, _,
~·. II• B =-o
he
~ w- "~ ~rclt.l... ~
.c
;!u, nlfl1.~e:ruh e.!,pn tuncbd'M Ca~

w
-fo. 11u.~mt\i'.am opeircdo1r A m..t lfm &- 4'n ~ -tw.. eo~ prrn~
w
etr
w
vo..lu..l.& <lJ.J.. Q.o, g_q..,

"\
A l/1111 :::. C/rYt lflm
'I
Fl y/7'{ c 4')? q.J,,,,
i°'lr HefTV'l~ ~1(<:.UC t(
j t(,J trnd-C = j "'//-1~ tt,:c/1:

j (J);,, q,, Ifn t:1:r: 1'-rn qn,* lfm Je ol-C.
,:=.

l .
',
Oltf j '(: ~~T- a:, j tin %,led( "' t:l
(a;,-qtt1'1() j l.flm* 1/4, dL = o

•
~ Bwt q;,;/=- qfl1
0
@
. ·. q..,- q/ + 'O
0
e
0
m
O~·- - - - - - - - - - - - ~ - - - - - - - - -
o
.c
@
C C
B
1-two ~e.\'\,dl-e. etui!Nt t,l".d:ie'M f.A» alAo Q. e.l~ -tuittdta'>)
yA
@ -~ SuM
0
G Co~cSift&pcm.d!d' -to haxv\-C. ope.,rak>"~·.
tr
11
ll 4-'i '=- a l/11
is
0
m
e If
A 4',__ ::: a l.fl--
he
@
AL YI, -1-y)L , -=- cw~ tp,;
.c
0 q
w
@
su..t- m1 -two no l i t ~oate- ~ f.>v,dt'o,,,, ,~
w
/2u 111o-f
E1J
a etrm
w
e -to v,dio-n,
e
11" LJ' I tJl1
•
0 fl
-:
1./1.,_ -==-
Q,
ci,.. cµL-
e
0
••
•
•
•
···· •
www.chemistryABC.com t
1( Twt> crp•e:"~ ~~p~ -to &cume. Ae.t of, + ~1· -Jl "_ fill. •
1
ifVl dfCIY1 a.M. C4>mmvta:lfue. .
a,a:.
rwc, CoMrvtuia:lt'°ue. c,pf.ir~ ho..\le. c..mmd'l1 &et a-fr
~1fndYC1>1,
,,...,
A Lfi .= Cft 1(/t
8 I.ft ::. b/ l/li
A~ 8 tMt. ee mw-fr:IP"lie-
om
,1 (\ ,., ...,
AB 'l't = 8// 'Pt
.c
If Id/ lft c 8 a: I.ft•
C
B
'1
0 ;) ii,'= Cl/ 8 Ill/
yA
tr
is
m
he
{L f-!S =,wi)
.c
w
'::::!/ 1-1 ~ 8 C@mMuk .

w
w
--------------~----··"--
aJ.w~.i ,,·.
•
G
·. ® ;, r<.e.aJ.'~ wi-11tt rnu.llrptlf:d&rn ·~
tu.>Jr,; ff4/'rJ
4ft!M.lrtn1 tg
:/
e.;-
•
@
fo),mt"hJ - (?<')
<£) j l.f _, x t.// di. ::::- j lJI.A!.*ff' 1(-<:.fT

e
••
@
~, @) 1L_ MIJJJ-fpuaxh"oY'I '-t -lwo Ct>mlY!u~ve. Mmt1'lan, Oft.YO::lao f,&
WJ., mi#Q/¥1
•
om
1Jcb{t"#th1 amd &uf?.J.>kt:ufido/1 1-fw{j ~mif-/% a~~ r~
.c
JuJ.mtt-i<l/'>1
C
B
c, - - - - - - - - ~ - - - - - - - - - - -
yA
0 <P( Nomno.lfuxrtll11 Xr-- P~bilL"';f-

tr
e
is
C P'ZS'oba bt U-tc.,_ - .,; e,,,L., _.J5'

m
<[ Ac.c..-to rnct-,< ~ t~~dzcnoYl °lf u.tW U.....1Vlu 1C"YJ

he
G
e
tt,,i,(_ t111dfoY> oloet,1'11t ~fY'liiu_ ttAJ. ~atr ~ 1-
.c
e m.it~ec pic. p=odtd.4. ( e} d.uMYt~ -t1,c.J._ mc--\m-1 f11 ahd" /4 «rit!.m , ;+ rn,ro1c1JJ...
w
-tl,\e Fbal..Lfl\,"c. ~fO"Y7 fvt 111te.-t1rM 1-- rw:dl,,e.M&cal. e.1-pr~kn1

w
e
w
e b
e p~ j lp~ t.pdr
G Q
e Q. +ob ~ ol~i-reol ~iCM fn wW6'i we. h.aNe +c d.J~miJA..t

9 tw.. pcro bet b,Lt 1t.
~
4J r~
•• 'fJV1ct10\.'l .&.. t.pit f,S Ctm-1pltx &mjUr-e.,
olT (A votu-me. e.4.me,,ut
• 1JO -is- t O -==- q :>l
• if11'Polq,, eo-o-&'vlalu - 2D ==-dx¾

•
~- 41
c.{1: ~ A~ Sn,_ eJc\e cf¢>
Download all notes by clicking here-
30=-~
... ·. ·. ,./; , . / ; 0 • .
Mo'b1VlaU~av, - www.chemistryABC.com
A t,ncG.,» tp tb ~-le·~ narMJJ.l?.Ju:J/ ~ WJ,vn

-fk«. re~biU~ 1 if~ ~ pa.,d:'fd.t ov~ e..k:i-iis-c. ~p°'-uo-t-
itu ~r=-+~ l iF"' Wtu.Ck i)u\'\clbvl r~ d.J!:o,-mtl'le:l) rh -e.r.,ua.1 -k> (Me.
p :: j 'f'~ lp clT -:::. I

CJ'Vi!J..e.,-..:h~c
Spu,
(}us- Cw.ck-Hna:1- i°l'ldi'C"n 4'c,o=- x, f~ nOTMo..lL~ <rR i,ot
om
'rw 1'W..- um\r o -\:z) l .- ~ llla+ ·ytc!r(Mail~ 1t.
.c
C
B
yA
J WZ Lp,tclx=
?(
tr
.?!-. I
is
D
m
he
.c
0
w
w
w
l)
.J.
::; 3

•• I
j· 'I~ q,dx
o, .
:::. J ·- ' _1. _,
I
,Tj
e
C) N(llf Mallz.uJ -
~ l/;fx.J = [3 X
•• I
© J IA X, X ./3 X., d ')(,,,

6
0
•e :; J
0
l
3 :>c.'2.J;Jt,
~
~3
om
0 [-tt
.c
~
• C
B
e
y A
e
tr
••
is
m
••
he
.c
••
w
w
w
••
•e 0
j
l
Al. tJ.l Al 1/lq o/x.
•
••
6
I
N 1- J l.f4 CfLL d x.
•• 0
•• "'~ (
{j'tp4~
-
• 43 0
Download all notes by clicking here- www.chemistryABC.com
:* To ~ · i4 ,,~l'\dfcm ··•·~ t~·fVLoJ,;.e. t:t
1
,, f;nc:blftl ·~~rn1~1lu4•~ ·.
1~+ 6-fr oil. w~ wW. ~ l \ ' l e j 'f tt"(JlcJ -C

0 Y~Gl(tt'r('.
Sp~
~ 'VCUU-l ~ a) ~ f+ f/4 NoaMa.11-ao/
J:ts-- ,+ i,g vt<>+(D -t'tt\~ wW-eu-q be_ "11N! v-al.u..lai- JLP* (Jlq-C
w c.. w r..u /.J.. v eN,. e.. 1+ Q "'d -iq t<S ~ sa R7 ~ ttu. v-o..Lu..t <tllf:/
~~ ~ valJ,.,..t.. wi-f'v\ itu.. if V'ld:fO"Y>,
om
.c
N\')~ -t'u.t.. wo..ue. -t, "'-d.id\tJ -
C
B
4'tx) = 8h,11'x.
yA
I
tr
j Sh, if x. Si 11t ~x. cl >e.-

is
o
m
J
he
.c
SI Iii .2Gl ix_.: 1.). {?l ]- ~q

J_ [.s 1n .ZO.'tJ1
w
w
_l [ ?t] l - j_ [ &'vt 2..0..>i..j I

w
~.. O ~~ 0
-H,.,1' - ~ ( ~1111 l-<l_ - a] ~J
1- tl;{ [ SrnvrJ ®
@
:::=- J...J- Ci
I)
•
@
@
G
••
•
•
G
e b
• Ja. _L
;<..~
dx..
•e
0 ri:1:
• :; rs+tJ -t I
•
• l--sJ
om
•
C [
•
.c
-
,...
C
•
B
•
yA
••
tr
is
® r-JKMatl'u tw wo.-ue if"'U'OYJ tfc><J =- Si"~ t'1' a fa,Jtck law/yl....,,j ./,,

•
m
•
he
Q M c,J(e:. f V1 0 fo .,l
•
.c
"1 S1J11 ,r_x.

L,
•
"f'l<K) -::
w
l
j t"'~r Sti<"i:o/x.
w
• €fl
w
• -: . J
C, .{
• £IV) L,r)( oJ 'J{
•• -C:
~xt
l,
-½ [ -x] -1._ $' [ sfvt

•• 0 0
fl-o 1 - ~ [ S.'n~ .t - Sivt !£: a J

•• c.. --&_
~ -½
•
• V,,,t'>IJ :: fl Sfn '!I!:
•
., .... ,
'j S:n h~ 4&hx el"- "' · ~ £: [~z.b"-] .Sin& eo,,\ e == s,1_.a ··•
,
9
•
•
-
Gus.- No,r,w,..lk.e. tw.. UJOJJC. -(fV\d:,C1ll)
1-1vJ -L+oL
@
~
4':::::. ,/~~
~7('X... Vf
~
-;:f)_
~
JW...,__ b,.u:l><- .:. f [,.J i-1o [ Srv, b ,{J
-1- 2 ti
j4'~4Jd1: -:: JUl.\~,wi1:c{x_

•
~
@
om
@
.c
@
C ~
B
yA
®
®
tr
is
,ra&,,-------:---~--:-:-::-:;::-~~;-;---:---~-------~
m
t~~,,, Cdl.lcu~ ;w_ Fbab'tlf~ 1 t~a -tv..L ~ -o/w o-to¾ Q

he
-it- pcvJfc.lL ~ Ul"1J~ -io Moue. fvt ,n bu~ 1 ~~ 0 4o,1_

.c
w
fll1 tr~1JUV\cl ~We-.

____,---------
w
JT
-::r. c,,,n n_:::r
w
l ,1 - )[""X
···n1 - <:.:J
-=- j~ ff .&lv,1115:t Ji g/111 ~ d>c

0
- ~ j¼ Ci"Vt 2- ~ olx
7 ~
c)

¾- -j__
•• I [. ,._l
--:1.. I at,th
.l. Si .,r. et l,,cl¼
.
•e <C -i [ -f; -D] - ;;11 [ 6 ~11•o1.h-6) - [Sh,._ Jl: oJ

e
@
-
-
L - J---l
4 o?.l~
i ·s;,,. ~
::Z
xd]
Lt
•••
e
0
e
• st.k v f a r-1_ e:,aL e,< pre161dYI -/., d.t.reJ.m ;,,,_ +t...,_ ,.,,.,,~ hjLl-+y- wttr,,r.,, ClJ,l't
•e "1i:,-(i a.wl +' awt °fr -({•""'4\Q -tt,..._ ra.\:Ji<H -t-t,,al--Y~ eovrfri......J
m
A.-lnk,
o
-f-o rv,o\l~ f-vt t-l) 1:,o)C 't .J_ wrt1,, l/loirMo.il.ud wo.ut..if \lldr0'>1
.c
e
•• ff st-,,,~;,(., C
(o c..:x:.,<. )_)
B
"' l&
yA
.• -
tr
• Sol'YI-
is
m
•
he
•e f- J Sin 2h_1"- d.,c..

.c
w
w
•e
w
•• p -
•• Yl"=- I
i t..f -fr, ut/
•• pu¼ n-=-t ~
d-o.,i-r e.al. ~ ult
.Ltmm f n o..ho-ue.. A.t.iu.t.±- we.. alo-/-aJ.11te.d
•• _!_ [ -x.J!)/"- .l- [ Sin ~

3
x] ~
-t '.¼ ~ ,vr .(_ '-½
•
om
.c
0 J.
ta.. [E] C
-~6/.'
B
u.tf- nai+- ~ 0 .--h, ),,2- -::: .l
0 >-
yA
@ ~r~-~-=. lh i. -:::. J - ~oJ,

tr
:;2..
is
~lvcJJJ~-- e,-lo ¼ ---?' J._ .L

m
& ll o?.f
he
Rf~..-l- 4._vct'l'"-kY-:= ~ .+o). ___,, ....L _ J., ~ o. oq -=J q/.

.c
-,-· lt.. L( o[',r

w
111ldJ.k ~ "' ½._ - ~ 3'. -+ rt

w
+o
w
-- ).% fo 3~!c.- ;r -= a. t""J. "-lt:if.

-..( ..1::i. -1- 1. @
p,
4 ~ ~
d. - -½ to
.::t ~
*:,_ ,. ,l.;:3
~ ~
(1)
@
A/3 +o ol1-3 ~
""fdJilt <Q. ua.m..?t -=- 4:1- - ½ +o i. -+ ~ ~
¥ -lo 1
.2- 2-
_ _,.=, -t; ~1u

::: 47 J.
••
Lt.lst ~1f~ ~ o-fo J./s -, l q.~).
•
f(, '°'f".J' tml -#U°'r't/ ( 1 ),; 1 -It, ), ..--) /Cl.fl
©

; it,,J~ IJf~bttMl£"! 1J "6t~ "f1d , ~ fP, ft., Mj,4ofe
[£ -+ trJ ·
e hdwa.,,, ·@ - ~ .fu n ,.
: (!9 o -1v --k- " [-b -+fr]
el
0
@) rv,'dd.lLl<DJ/; 6/ b~ =,> -·h. --hi .1,.,,__ [f-1-¾J
0
iJr' 4 paill~ CIMir°.-ie.ol -lo move. 1n ID box 1f IJMdft, -,..,l fo,,l
e wt Tl-1 Ntl¥Ma.ut:.td. UJO..lJe toV'dh,
0 t..pYJ ~ ...L ~ 4 x. _L, [. ±[x] -1- ~ [ Sin1bx]}

: .[-t ,.P,l .,t ~
•L-------~---------------
e flv~e va.J.Lu oR e.x,~aa:Fbn valtu-
om
e
•e [ <r.i-;:, : j If'~ Nf q,'d7:]
.c
C
B
• T~l4Sla¼z"'ay?ai morne.t,t/vTVJ
yA
•• J4f ~ -1 c/
tr
c::::::_ 1Yl Drr1~1>1 / -:: 'If (_ fY/rJ m./lMJu>"A) l./4--,f 7:,

is
•
m
• 1o ckleJ.ml11(._ -tt.1c.. vcl.Ultl. '% ob&0tvabLL fft" a\l\d' we. o~-raf:e-

he
Mvti'OYJ
• cr~'oa:t-oY ~ ob&eAvabu_ O'Yl itu-1f'Y\d··t"'O)i 1 rna+id)'J &- cL.J....tl<

.c
tw..
• +
w
~ t~ ~ vetlu.L ec,'Y) "7<._ o/lo+ r ii- if- ~~

•
w
~ va.L.u ~ ct- LJb>~e,. vabll

w
•• ~
Ca'Y!~fclll.o.d
lo"Ot')tlartCMal 1,.(2 ·
al:. i,J,c_ vet.lt..u-
M, be_ crh+afvrd '-1 crpe,ra:ftw,r

•
ti
6f~" °'6 r,.(Q. <M fu_ w4ue_ tvVld,°OY) o-fr ioall>~ lttl·l'C!Yld /VIO+II)
@ (_ optal-~ i)tf/Wl pi; 8 rnvcW)

0
l<.:x_ X lfT¥ -:::. ~ ' V ~ \l'Ty
•
•
~
- ~
2
~,.., dx'l-
~ [ ti:stn .2.111r.
.../ :t..
1
-rx.
J-:.. x-.?f"' ~2-E s,t1 '>?.f?(
.fmL'.).. ~
2
T
• .JJ
• olrx a..vq h'-t._
• 49 Download all notes by clicking here- \la.Jut,

,,,, \ ~~oi- ~-~~rutcl 1frdiC'IIJ,~~~a~n~ .· ;
~ etr '1alut J.J.ltJ:b'cr,,1,/iJp ~ ·we U&e · ex.pe,J-aJ.-,iJ'YJ va/JJ.t 0
r,,~ -Iv chf-o..miJ,t.t.. 7fd. vaJu.t '1f, ~e>.vctbl.t ~ U.>..t1Aef"'

apt-"'~y '1f ob.&~utbu_ 411\.di'tM °5 mahm CJMeJ.vc:,blL vaJJu(IYI)
Mtoj b<- ~:.=~::.......:::a&::_-_ _ _ _ _ _r
J 'f'll: M t.pdT
j 4'¥ t.pd-r.
om
.c
C
B
yA
.3 t- C~ uo"'ttf>tolise.cil i'1r()w, ~
if"'c! tw- aveur- valu.t
tr
{2u~:
is
a v ~ v ~ ~F't.M.1cn,,
ot- 1Jir t.AJQV~ iuvt d-,C/YJ
m
?(..
~~ t\.'\ e.to.me.tJo.~ c.bJ&eA
he
4'{7t) e :x,
<'..:x.7: X,i, -rX..i 61. ""· · -
u,.,,,:I- ----~-
.c
beitA.J <.vn -ftt.L aIt, j_

ir+{'l .. .. ~
w
w
'ft.?l, -: : X
2.. :>t..i. ii
w
t l
lf" ("-> -:: j ?t.d"" -: : : 3 :Eii
0
j ?tid:t
~-~~-[,,-)-~.-~
Jo cb(_

_,r.-• • • '1 •;w~~:.-' • · •• ',F.,,..
<·,p:t, . #·f
, < :
'(/wJ·1'W.· av~e v4'w..."fr ·. <!:..~L'71 <px'//, i('.:x.>-11 q. i;,tlf.:J,~ , •';,{;

• • I " • • •I ,
~~~ -to JfY10\1e_ w, 10 boy 41- ~ .t wt'n, 1'1o-rMcxlL-u.d IAJQUc.
ti V)c±-i CN) .
cv" ~ K st,,~.'£
(ii) Bd u1)7 Qbou~ a.v~~ \Kl.1J.,,..R- v ~ 1,A.t. H-e.i~etnber-d"
Un~/ni'ntlfu,
t
L
ui'./ I Jh#t,uMef It½ ~ Ti
,J~
Sin11,rx..
-:Z-
itS t,'rlv!,o\l\~n-tc:tl~e.r at wa.uc..
®
0
(} -
Sol~-
m
(J
o
.c
®
© C
B
G
yA
(;
tr
0
is
0
m
he
0
e
.c
e
w
w
@~
w
l Cf?:1<-7 ::::.. ,0
~
e [ 0(_2/ = ~-~
..3
--
eR.::q.,e....,1(2- ]
G
•• l<pJ 7
-=..
1'1~2-
---::-
L{ ,l 2,.. ] }fl, 2,
.;/2-
•• c::l'-;t) ::: ,, :l.,r.2.•
cfl/Yl.J...!1,..
d"P.. --
....
fsJ>U.2..
•
\ ' I ••
••
-- www.chemistryABC.com f
G
=:i
. l
J s,,,, £ ( - !1; 1xl cfin 1Mx dJG
•
@
0 ...,l.
~
(
= -i (:- l9'/ j Sin 17~~ A smJ' ®
•
>tclO(_
t)
@!
-=- :!
-'--
t_- th)jl Srnb>L ..l S?nh~ d~
d~ .
w
l) @
=-_d_ (_-th) j '- ·Sinb)t; b ~hx..4x.

'
~
,.IL Ii ~
t. t:s
om
::: .ti. {-ih Jbj 8tn hJ{_ ft,1., t>>t_c/x (:f~
.c
""- i\
J..
el.. (- t1;) h [- J__
-::: .,.,__ C [ w., 2ox]]
B
4b
yA
- {....t. lit; ) xj_ ~A 2-bx..] e

tr
4 ('-- . t,
is
m
he
.c
w
w
w

·,11
.:
.ii
l
• DPP 3 Quantum Mechanics

z. If an operator {( d /dx )-16x
2 2 2
is operated on an function e-2x1--than correspo~ding ~ig~value is
}
a) -2 b) -4 c)2 cl14, e) none GATE EXAM

1 When the operator-(li2/2m)(d2/dx2) operates on a function e-ikx the result is
2
~e-ikx b)i ~e-ikx c)~· -ikx d) n.2~-ikxllT (;ATE . ·.
2.M . .2.JII\ . lM
J_ Consider the statements regar ng operator A CSIR CHEM
i)The multiplication of operator A and its hermitian adjoint is always hermitian. '1'
ii) The multiplication of operator A and its hermitian adjoint is not hermitian y
iii) AAt + AtA is hermitian but) AAt - A 1A is anti hermitian(,
The correct statements above are (a)l,2,3 (b)2,3(c) 1,3, (d)l,2 ~
1:.. The angular momentum operator Ly would be CSIRJRFNET
a,(-h/2:n:i) (yd/dz - z d/dy) (b) h/2:n:i (zd/dx -x d/dz) (c)-ih/2m (d/dx) (d) none
ff.. The operator S= = Sx ± iSy Where Sx and Sy are components of spin angular mo,mentum
om
operator The commutator [Sz ,S_] is
~S+/21t (b) hSJ21t (c)-hS+/2:n: (d)-hSJ21t (e)none
.c
Q.The value of[x,(x,px)] ·is equal to CSIR JRF
a)ih/2:n: b) -ih/2:n: c)ihPx l'ij1} C
B
z. Consider the statement regarding
yA
1) Every function used in quantum mechanics should be an eignfunction. f

2) The function f=O is never allowed as eignfunction for a system. '1'
tr
3) All eignfunction of Hermitian operator must be real functions. F

is
The correct statements above are (a)l,2,3 (b)2,3(c) 1,3, (d)l,2 ~ 2 .

em

I.The normalization constant for a wave :function sin:n:x between the limit Oto 1 is (2}5• -1'
h
2. The average value of momentum is O for a particle in 1 D box means,that momentum is 0.

.c
3.Uncertainty in momentum for a particle in 1 d box oflength I in ground state is h/21.1"

True statements above are (a) 1,2 (b) 2,3 (c) 1,3 (d) 1,2,3 (e)l only'(f) 2 only (e)3 only
w
2. Consider the statements e J..,d lmu I

w
I.The uncertainty in kinetic energy for a particle in 1 d box oflength is zero. -T b~o-z.. l<'..· · ,v--
ea.r
w
2 The particle in 1 D box oflength l have orthonormal set of wave:function 1' -va.lw.. ~l'l1
3 The.value of[x,px] is equal to ih/2:n:. --t" · :ii 2c:..,ro \ J V I ~
True statements above are (a) 1,2 (b) 2,3 (c) 1,3 efi,2,3 (e)l only (f) 2 only (g) 3 only
JO.Consider the statement " ,~L!
1. If the wavefunction for system is an eignfunction of operator associated y.rith observable A
than <A~ =<A>n l
2.The probability of finding the particle in 1 o·box of length 1 within the middle half of the box
in first excited state is 82 %. -1 · .r
2
3The value of commutator [LxLy,Lz] is (ih/2:n:)[Lx - L/] . - "T
True statements above are (a) 1,2 (b) 2,3 (c) 1,3 (df1,2,3 (e)l only (f) 2 only (g) 3 only

(f~) :·cr--ij), (HJ
p2-Q."-·
. . ,4 A. A '4
JJUnder wha~co~tions do we find the.same result of (P + Q)(P-Q). as in the case of ordinary

algebra ... l'~.~.Ql~ ... CSIRJRF,:. ·
12 Consider thestatements
1. The normalization constant corresponding to wave function x between the limit O to I is (3)05V
2. The average value of x for a particle that is confined to move in 1D box (of length a to h) with.
· wave function 1/x is ab. 't'
3. The average value
. of momentum for , a particle that is confined to move in 1 d box oflength
.
l
is zero, means momentum
. is zero. 1 .
True statements above are (a) 1,2 (b) 2,3 (c) 1,3 (d) 1~2,3 (e)l only (f) 2 only (g) 3 only
J3Consider the statements
L Momentum and kinetic ~ergy may he determined simultaneously but momentum and total
energy can not he determined simultaneously. "'(' . .
2. The normalization constant fora particle that is confined to move in a: box of length 800 nm is
0.2 (nm J112• ::::. c,.os{!,m(r'l- . ·
m
. ·
3.A wave function becomes zero at infinite. -r
o
.c
True statements above are (a) l,2 (b) 2,3 (c) 1,3 (d) 1,2,3 (e)l only (f) 2 only (g) 3 only
14The wavefunction for a quantum mechanical particle in a 1 dimmensional box oflerigth 'a' ii{
given by 'lf=A sin (xx/a) . The value of A for a bo,c oflength 200 nm is IIT GATE C
B
• ! ·• "' •.
yA
· (1)4xl04 (nm)2 (2)10 v'2 (nm) 112 (3) ✓2 /10 +-l/2 . (efo.1 nm· 112
"'
U,,S'uppose, the ground stationary state ofa·harmonic oscillator with force constant 'k' is given
tr
. qio=exp[-ru.:2] . Then; A should depend on k as CSIR JRF

is
(a) A cc k"112 ~ cc k 112 (a) A cc k 113

m
(b) A cc k
he
J 6The probability of finding the particle in a one 'dimensional box of length 'L' in the region
3
between¼ and : for quantum number n=·l is .CSIR JRF
.c
1 .. 1 ~ . ·1 1
. -+-, (c)---
w
. (a)2
.
~ 2·• 7r · ·2 re
w
iiFoi any,operato~.A and its adjoint A\ the INCORRECT statement is: .

w
(a) AAt is hermitian (b)AAt + AtA is hermitian CSIR JRF

(t) A ,;r At is hennitian .. ( aifA- At is h6mitian
I
18 Fill in the blanks . ·
&-._The average v~ue oh_ in the ground state for a particle that .is confined to move in a one d box
• oflength-1 to hs ... ~... P.... ; · • .
2 The uncertainty in position may be considered as deviation in position then expression of
•
uncertamty • pos1tton
m . . 1s• ..... .ft.r.... - J<::_)tl / - <.:,c."']
~ .LJ 7C. ,.. . l-'·
3 The uncertainty in position for a particle that is confmed to move in 1 d box of length 2 nm is
.. (!,j&
4The nonn.alization constant corresponding to wavefunction r-sin(1tx/2a) between the limit -a
to a is ......... ::Fci· ....... ;. ·· · ·· · ·

m< ~· k ;L
o!tt. i, ".#if
linary
'2..~ 2.
11 J1 '
.;....:.--
:th I . 4.).. 2..
al
mis
om
'1 /,,c. .,_ ~ '7 --4w z..
: :. j ~
.c
a' is
1,:-J'f"' 1i 2::_ 0 C
B
· ~ .
yA
tr
is
m
he
.c
w
w
w
)X
.ti X- if' ~ -=- I

tix_= ..tr.L _ _J_ - ·1:::1/ U//1 oJrh:zl7 lrr,,.-tzffl pallh·m
,.J 12 «if':,.. -t
·'!! x.c'J~ }_/2, ,jir-.l-

:,.le
_.. I -
~~ · tJlat, ? O•,St>'fi
. "'•---~:>;•:··!:'~_:I-:':;:".1_1}~;"?Y·\/:.~~i:::,-.:·-~·: - _ , -~\tr·-(.!:.-.· · __-_. :_ ::r.:- -· .o - · •· -. ·-
· f>o~l~'4'~~~(!g~M m«J.~n,t~ - .. ·.
'
.cD Tue_~~ -·<1 ,a_ er~ ,l'.1~~ClNt\Ca..t- ~tf!IW1 ~ . ·dnvtr~·- ~

Mt--1 ba rOYI 4' /A.,{1 -th:d- ollj,=~ Ol1 c.-cr.cllviak Y\dtO"v7 ~ -ttu.. t1\II f ~ ptt,~ l~C.
4'* {Ju+ J lP (,«, ,-1:, 7dT

~ -fttte paiJ:fcJ.L tl~ i~ volurn~ ·wvwt.-u:A olt ~ a:1- L
•• I
cd:---ft1VK -t
I
i°vtlitt1Yl '-P(At t) i.f> ccm/$r&i111.lt

.
°b ~b ~ lp(A 1 a_ 41 U-)
.
twt ,,aJJ,.u. °t \l'l~l ,~ ~\'\~~ o ~ ~ -=finne__ 1~cl.Md-
m
/2CJ.1~Vt~a o;_~ il.- -tlAe- ~-aluA.. l'1 U.Atll\d"
at-- lVt-l-.7 i~ of:ihlW2c\
o
.c
po-&-h.>lcd:c. © ~ · ctu:.c..s-ibe. --t:'wi.. c../Jta11\.3e. 111\ valw..ot, -to)1chan
w.-·"A.- +ime.
C
B
. ·
yA
(£) To ev~ ob~~'\JQ.blt f111 cl~ictd rnecJ/la)llllS ~e.>..L~pnlid&

tr
is
Q 1utndorv1 .me.cJro..n1cal J-,r,vt~ h-e..YMl"tia.M b~1S'tU0Y•

m
he
. cJ~_fCQl 1Vl<-cl-an'tc..s ~ w,tt,,, {u,..,t,J-:} eatld

.c
.. ~mic. 1/lll-,Lablt.. ~vu-, ag ~if!'qy,, mome,JvM, ct~vby

w
w
fl?ome,,JvM I t'Yt~~, •
w
A rne.aJ,u~a.h"- d.yn~rc v<l.Md t,lt.. ,~ '- calL.c/ (!)~~-vqblt._

.··~~ okt.-fo - one_ .AJA,.-hav,t hip b1~ o pe,ra.:.k,,r Q>1c:t
ob,&e,,'\lq bfe .

., ;;\:'-:",\
@\ · ·~ a~ ;~eo.\,O'ffl\eMf , 'itti·o~i<=Avq,~ :~o~, ,41,f#l,f ~pt~~t A
•• +t.L
,,!
0>1~
-let&l5'f -/tu_
vaf iu -n..i,J-
IJ1q},C)?
id'A Ix CJb.s e;., v<d Q/\1._ d'f"1 va.1w. , w 4JL'1
0 ,,,
•
e
If 'P-=- q (/,I
:T'v, poa-vlcde (J) t°+ f~ nal- rne.,,,,,J;t:f't1-ftll.J- ct --5~ mv-1,-I- b~ in

•• a 1:,-+ak. o/..1.u.-i-fb~ h; a,;, el~ -(junchcm
0 ll-t1., will be.11)'-\lrd "frnchon ih ~ pDMtbla. UXUJC. ~'"on
e«e.~ o--i, ~<f>+em,, -t-t,a!- ~ 1'1
G
It- we. ~m)ine. -tw. val.Lu..1
e
G a ),~ dw._Ttbecl b;J, 4' ---rwrl- f~ ~ elr -t;undtdYI 1 < H
fJ ~ob,;e..v~ wtu be. ~--ttu YaJ 11 1. t2-n wkldtt
om
'\fa.Jiu C>Vte.
C OYIC- 4i 1+- wttl be.. (av,t+ be. pi,c.dfc:J=,I wrtlr1 w.:fcu.~
.c
e
0 :tt- '17 l~ -tlA~ ~or,11 C
1,.u,,-a-oca,.O., elf~ H 'I' ::::. 6 I.Ji -Ht?f!/Yl j:cr
B
. H
e.,_r tu ncl?crn
A
G ,0 ,#
a ~ /2olv~hlt. .-!~-te/WI 4' ~ aJox.i<f

y
e
tr
e (ft,cro.,pUYlCU? -lo H.
is
GJ 'ft a .1, r,+-, (,, .

m
G fn q .tkJe. oW,C:1' iherJ b;t CL -no ~al.lud wavi:

he
,e 1frtcffdYJ lJJ, -/1AVv1 --1-W- av~~ V<l1.u.t o-(;- obi.o;v1:1blL --1a.J.u..t

.c
0
uns;1So,pmclfYf -to op~~ A I.A
w
e
w
•e
w
•• 1l a_v,
~ ~ va.lu.,.__
ore"&lXleY at ob¼'V<lblt s.. 9,.,
°'('>1 , -,w,,,, t1,,.L
crf:i mo+/'<n1 t,vidfO'l?
vaL.u. ol:,-tcuwui!. bet efr'7
•• i° "'-tl{'m 2.-- oR <'.l b1c,.iwu:l b Oo.v ~ v a.1,uJ. rvtdt1P d fb
• ~ .A CUYl-E::,
••
••
:{~:;,,~-:T{·.:1?·l:'rff~~t:•.:.;,;, <:·(· 1 l Y'.:if;'· :•. ~ · .._', .. ···--. .. ·. \;·,)er; ·: ~~~>
~y··Y·':'<lJdii~f.ill\~OJ1. .. ~ ·..:s-f'<tle.·· f?~crt:A-1
• •-1 { : ' . ,.. ·.s . :: -. ·• , ,
~'Q· ~~fe,,wl eJ(VtJ/Ve ;·[17

#me. acccrai.l? fo +lme_ ~t,IJ1d.ud- ~t.kn,d..l~ tvqv('. o/'Y)

.., tlJ
H :: l-t; J c.p
"t" 'Jt
t-v,J_~ -=- E 4'

.¼t"
g_ 4-'
nJ \.J):. tv,
JJ'-J'w-- Je ~
dr
om
.c
C
B
yA
tr
is
m
he
.c
w
w
w
-, J?,ro bo. bl Lt~ d!M~~ f~ 4iMC:. t'.~d.JM±-

P?ro b4f:: ~ dJm~\t;, -:: lf': o/T
• --Ii' .. ~
= (__4'U> e-Lc.yi:i) tp$\. e-LE.yir
@
- ~t:'}/. - t El:-
-=- 4' ~ e t-C.;cl; ~ 'f;._ 0
~ ll't4',t. •
~
@
~
•
'• .!
r
, . !;,,'' ·, '. ' '
1 ·· fttrlr'on
·i':,g,;,'
c,n;aF'~
··.·. ';:: ·.---' .. ·-- -.' .
-to ,s-ta;Hor,~
' ' . ;, .,. ' --, ' ,, '' .. ·.., ,·,
"cl-a£· l},;'+fl\'IC1~·.
',, ,'. "'
' ,.
•• am p?r01:x:tbt t!~
1\1\~cJJM±. .
ur·ca~ptmdln~ -fo &,a.:liO'Y\a11f /4-fa:t~ f~-time. 1
• ' i"Vld-to,,, r,,, = i,-i- J..tM<ill'½ l1o~maJf-a.d

•
e cl ev~~-nm~. ~ va,l.u..l
no~-,,.,1 a:H
ot ob~eA.vqblL f~ a.lbo -Hme.
•• {Y\~
e
0
e
e
•e
om
.c
G- ~ - - - - - - - - - - - - - - - ,
C _________ __:__
e °t"
B
(52. t'rl. +~e«k rneMf ~c.h,rodi~iey ~uaho,, -
•
yA
e.,'Yl
• Sch~~"" t~ -t'lt\~ ~ va.lu.J_ 4v, oi; e.l/l4!"rft MCQ.~
tr
• i1A~ ~ '\Jalut. fn w ~ €trm valu.L ~ <.l1e~1'f

is
~'Y>
••
m
a Yl~ opc-"Ya:tt>--6 i~ tta_ rvtthmia.-r,,

he
I\
H 4J-::: E 4'
•e
.c
H=- 1<.+V
w
H ~ --!1 2
w
• 2.1V1
"1 +V
w
•• ( - ~~-q
2
+v) 4' == e ip
•• - ~ ,q '2-4'
<.rrl
+ V 4/ -= E.4'
• - ~ "'11.4/ -= Elf) - V 4'

•• 2.IY1
••
••
~· 59 Download all notes by clicking here- www.chemistryABC.com
'\
, .•
•
~
@
"1 'l. - d2.
d~2-
@
a.,_ G
--q2- - -
Ji
ca.,,, -t-- -dzj l- -
""1 ';)... -=- a1.. J'l- ..,1..
8 ► +d-z.2..
-
-J:v-- ~ au -30 ,,
om
.c
C
B
yA
tr
is
m
he
.c
w
w
w

--o
.::s
li
0
@
®
()
m
el)
o
.c
0
© C
B
yA
0
()
tr
is
0
m
€)
he
@
.c
0
w
@
Q
w
f) I\
-s-
w
1\
0
Q ~
@
[)
sn
0
@)
@
~'
©
1f
e
e
~· 61 Download all notes by clicking here- www.chemistryABC.com
. . "·. ,' '. ',•: '· ' .·· . . . '··11
j S1Vt•&(o&~8- cl& = ~ www.chemistryABC.com
11
0 3
4
4
~
@:l
0,
G
f
@
C
I
~
om
[IJ (ll.J {t:II) @
.c
@
C
B
c)
@'.~
yA
C
G
tr
is
€5
m
1)
Ci
he
e
.c
@
w
w
w
t'ZJ
([J
(Qi
Nois M ailze. -tlA.t_ W-0.\l e t, VlcH'M e.-~ i1>Y a l'1 C: f 11 1S O,s- h f-kJ. ~
°h \,4- o.!om, Cl it1c\ i;W ~ °'- (.~°"t<' '.tctluJ. 1 A._ ~ A-2..
\J ®
J4' \f' 'It cA-c (j
j cS iv, tJ qff Jl/f'c/.~

ca -1"" ~ 0
0
j C A, C -L ~-2-·ol
~ 0
-=(!!Y
•
~
q,r J
i)
2
A,2. l.- I,,d._lv ~ I( I( l( 1!
(i}:2+1
~ l/. A' X ~
8
~
:::: JI"'" $
@
•
G
•
@
® <.A.'I : f t.J;:A- Lf,,c./T
oD
0
G
-: j J_ e~ ~ .L CJI.....
.fir J;p
A..-2-c{}._ . 4/i
e 0 o{)
0 -= 4 J("j A3 e- 2.. ,,._ di....

f
0 0
Q
0
0
om
-:::.. L( 1f ~'1'Z.~,
€J
7f Jl,
~
.c
e :: .2.l/ p C. ;J_ "
/f, ,:J..
C
B
0
E7~~iJ
yA
0
tr
e
is
e
[< ,,.;- cc _J
m
C
he
0
.c
@
w
e
w
i")'(nY) t:a.JJ-~t'a.M u,-(J"("diw:ti:e -frJ polM. ur0rdJ.'IADJ!e

w
C A:,. wkn Wl move.

6 ~ ~eve,.al GWJ.11'~ -+ct k~ pb.u. j.., ~ val.ut t1- ope-ya:Jor 1-
•
.~
ob-tth\A hlt. ~ if c..fioy, 1 J\llo+tbY),
co /2tu4t-
\I)
--h-un~ lili'°~ct 1r,

0
bt-a1-icrnlll. mv-h"{M l.;Jc_ u,{e_
~
© (hy\:-eJ::.\~ c..o -o--cd.l\Ntte__~ ~ t S ~ ~~ e.. ettd>-ov>t°c.
• we_ UA e_ pol<lY ea-ordi~

••
••
...,
'%
px..
om
.c
C
B
yA
(fr}V t:D
~b7 V =1:,lt%2..
tr
is
m
e--A Si\19 <:-IL CQS fJ

he
,,,, Ii 2A
J1J s,vte c.(½r~e 1..2.cJ1,.Sf111eJ.l>c/f
JJJ
4/("'2.,f"
.c
e"-
eAui4 l,} e-~~e A-2dl...
w
l) O 0
w
0 O
a Sii1Gc/Bd~
w
J A."eU.cJ.t.Jto~26 s,11e4r;}d¢
d> )('" cf>I:"
J 0 o 0
'l1 l
1 '®
(5)'11+1

·; J('. ~·•.•~ dt.~v~·f _ <&1<:p~ <.A~!,~~, t<M,~:, ,<K·t1<v1 fi,,¥
c, a.YI e:- fn l's o..-bi-/QJ.o-i H--aJr.m. , · ·· ·
··
• '-JI,. :: J_ . f.. e- ¾0 ~ 4no I:; <:la':
·~
qD 2, I C:,,r.z.q'F)O
.., J:i' qo-r:,. Me.2- -
Vl.ir~ -f'1,-.Q.. u10 faJ -+1,tea>,s-m b u,!,int_ above. A,tl, ullii,1 Ct.t.&C "1J' H aJt:/HI
G
e <&:,; ,,. <: l<•E:.'r- = 1 <. Afe.u:#4'.. t!>?erCJ1!>
G
•
G
l< =--..L<:.._V?
aR
.l..
0:::::T)':=-.l<V>
:,.
0
•
••
om
t>
0
.c
e
G C
B
e
yA
0
tr
is
C
x.q.,,1/.
-
m
3X.2.,<.I
C ~ X 8~ ~ X
-- C/03 116
he
G qb.o (t! .. '

• 3
.c
= _qo
.:i..
w
0
w
e
w
0
0
e TV\ -tw,. ve..~ .&tm< wru;,
e
~
~
t~)~ <>Clo~
e
-•
•• 65 Download all notes by clicking here- www.chemistryABC.com
z;~)' ': "JJJ•>1a;; e~\~ \~~¾.
0 6 0
, t~~ ;,'l~e~r- www.chemistryABC.com
~ +{}t·-A-/4. -:=. -},., e-%. + i e-,t./4,
= - l. e-vqo -t .1
a h
~-¼o
11
om
' d>
j
.c
-==- -.!::L [h
a./,
e-,,t.lt~o{-ltt¼o
4'o
-1-1~-A./4,/
.A-
~,.dA.-
O C
B
: -*.s tr, J;:-~¾o "- f -i_
yA
2 d.(-t e.-a/q, J,..Ld.,._]

tr
is
0 0
m
he
.c
w
w
w
-::::
-
- 0

., J qo
•··•·
/.
i·~7 -.::b···• . · .
•• ~A.?':/.
<. 9...2. 'l :::.
-i.
3qo i.
<t:{7 :::. 0
<-z.7 :::. 0
•,,e <. PA' ::... 0

d/..-:: p;-:;;;2..
L.
<.,#>A."> - -
41.2..
Clo
2.- : - po..'-- -% Qo ;_
()"
•
0
L: 1<> -:::
- 71 .1...
~ M." D :2..
.<lA. ,: :,: -.fj /I
.2.
,o
·O .C.v7 - - - . J_
'C:. 2..
4ffto Qo
om
,/:!:',,
l,:;;J
.c
C
B
A
0
y
e
tr
is
@•
m
6
he
G
.c
0
w
"
w
fl
w
~
e
6 < l<> -=- -l .::: - l
& <.V)
:l-
---- 2-
e
&
•• .c::::.E> ::
-
~ k-, -t <.V>
<. K, -lC:. K;:,
• ~E-;,, -= - ~J<>
••
,t
No,rm4'lu. -ff,u... wa.ue. i1' Httr'on
lf '" ~ -.A.13~--+ l(j, G>t e
~ ~ ~
= j
0
A
2
e-2.~Qo d~ j ~&'-S<Sivtl:Jcl{}j c/tp
0 0
2. . 2.;;r
3
om
.c
C
B
yA
tr
is
0
m
G
he
~
.c
f,
w
w
z. = l
w
t
(21
©
0
•
@
@
@
68 Download all notes by clicking here- www.chemistryABC.com @
f
. .
.
DPP 4 Quantum Mechanics

1., The average value of the radius <r> in the Is state of the hydrogen atom is (a 0 is Bohr radius)
June CSIR
(a) ao , ~.5 ao (c) 0.75 ao (d) 0.5 ao ·
2 The ground state)energy of hydrogen atom is -13.598 eV. The expectation values of kinetic
energy, (T) and potential energy, (V), in unit of eV, are June CSIR
(:r'f<T} = 13.598,{V) = -27.196 (b) {T) = -27.196,{V) = 13.598
(c) (T) = -6.799, (V) -6.799 (d) (T) = 6.799, {V) = -20.397
3.A set ofN vectors X 1,X2 ; ............. Xnsatisfy the eigenvalue equation for an operator A with
scalar eigenvaluesA1, A-2, ••••••••••• An (i.eAXk= AkX0 The linear combination vector 4'-:. 2. C:~
where Ck are non zero scalar coefficient TIFR Ai,:: ~, )(-,.
a) is not an eigenvector of A · S !
b) is an eigenvector of A only if the Ak are all distinct (no tw~ eigen'values are equal)
o}1s an eigenvector of A only if the Ak are all equal
om
d) is an eigenvector of only if Ck are equal
4. If 'l'x,t is considered as product of two function f(x)g(t) where1(t) has the form e•iEtlh then it can
.c
be shown that probability of finding thepa11icle between x and ·x+dxTIFR
C
a)Equal to 1 1:fjis independent of time c) can be obtained by the solution of time dependent
B
schrodinger equation d) can be obtained by the solution of time independent schrodinger
equation
A
5. The mathematical expression e i(kx-wt) represents TIFR

y
tr
A) ':»'ave stationary in space but oscillating in time

Bfa travelling wave moving in the positive x direction
is
C) a wave stationary in time but periodically varying in space

m
D) a travelling wave moving in the negative x direction

he
(§)The vibrational Raman eff9ct was first reported by Late Sir CV Raman in 1928. The intensity
of the individual vibrational resonances observed in a Raman spectrum is proportional to TIFR
.c
i) Number of molecules ii) Polarizibility of the bond iii) Wavelength ofradiation used iv) a
w
considerably weak scattering phenomena

w
Correct statement above are a)I,ii,iii b) I,ii,i v c) ii,iii,iv d) all

w
7 In a spherical polar coordinate system, a point A at (x, y, z) in the Cartesian coordinate system
can'be describ~d by (r, 0, q,) where r, 0, and <p have their usual meaning. Expression for the
volume of an infinitesimally small cube confined by dx, dy, and dz in terms of the spherical
coordinate system is given by TIFR
2 2
A) drd0dq, B) rsin0d~d0dq, C) r sin 0drd04q, 9J r2sin0drd0dq, E:::. -.!._3-b ~ 2 cJ/
8 Consider the statements '- .. 'Vt~
2) The energy of hydrogenic atom is directly propotional to µZ 2. -r

3) The energy of 2s and 2p orbital of hydrogenic species is equal Il!.eans they are degenerate
-
1) The enrgy corresponding to 2s orbital of hydrogen atom·is -0.125 a.u. -f 7:;; ~ -o ,S-;z_ 2. a .u.
1,1'2.
according to schrodinger equation. T --t

I "',U, -:::. ~7. ~V ..2..
Correct st~tements a~ove are (a) 1,,2 (b) Z,3 (c) 1,J (4) 1,2,3 ( e)none ..,
3+ i6 6Wlh\d.t.u.o1-rw:d- -
ehth·ki)l d.d .(.. 1>1°"3 iu.:hc.-f{dd aJ..L
Cm1plJ1=~ ~~w--

J.r'Fill in the blanks

i) The normalisation con~ant corresponding to wave function ~ = e-rt2ao + iq,cos0 is ... /.
ii) The virial theorem corresponding to hydrogenic atom is .. (.lc;,,£"1. .":".½:_.~ V)° I[
h. ~, .}1..
iii) The average value of r for an electron in 2s orbital of hydrogen atom ... . ~ .. ,£to
iv) Average value of kinetic energy for an electron in 2s orbital of hydrogen atom .. ~.,~t-\/
10 The correct statement about both the average value of position ((x)) and momentum ((p)) of a
1-d harmonic oscillator wave function is June CSIR
a)(x) =f:. 0 and (p) =f:. Ob)(x) = 0 but (p) =f:. 0
~) = 0 and (p) = Od)(x) =f:. 0 but (p) 0
11 . · The energy of a harmonic oscillator in its ground state is ½hw. According to the virial ,
theorem, the average kinetic (T) and potential (V) energies of the above are E. :. LJit-+-1) hv
,.,.C 1 1 1 3
(911 = 4hw; V = 4hw (b) T = i./1w; V = 8hw Dec CSIR .fhV'
om
. 1 3 1
(c)T=hw-
'
V=--hw
2
(d)T=-hw·
8 '
V=-hw
8
.1.n
,1.-
2
. ~A
t-2':"Show that wave function 1s and 2s are orthogonal to each otl)er ,for an electron in
.c
hydrogenj.c atom. C.V1s.:::
0
iif.q
3/:),. c.-.,._/qo 4'2.s =-~I-<-.;&;).
e-,/y:2.q0
U.Consider the statements
C .:z4q),- Cfo
B
. :::. -ta.(. Jt,:;.I i) As electron move away far from the nucle~ then velocity decreases. 'i
yA
::- l, u H::::.~ ii)If we replace mass of the electron by the reduced mass in hydrogenic atom the bohr radius
becomes ¼ of its initial value. f . ·
::: - '· S .,::::.3 iii) Virial theorem apply o~ the the gro~rid state only ~
tr
is
~ =- ... €:: l~ f. The correct statement above are a) I,ii b) ii,iii c) I,iii d) I,ii,iii c:l1f only f)ii only
I:
em
~or hydrogen-like atom with a nuclear charge Z, the energy of orbital with principal quantum
, -= ?i·lf ·number 'n' follows the relation. June CSIR
K .:: ,.~ zZ
h
"-""l"E
\"V n
cx:--
.c
n2
l.8"Consider the statements

w
i)The average value of r for an electron in IS orbital of hydrogen atom is .8 A 0 • I

w
ii) The energy corresponding to He+ in 2s orbital is -0.5 a.u . ..-r

w
iii) The value of potential energy for 2s orbital in Li2+ is -2.25 a:JThe correct statement above are
a) I;ii b) ii,iii c) I,iii - 8:(I,ii,iii e)I only f)ii only
Ur-Fill in the blanks - .z:xrg. 6~J2-
3
l) i) The Value.ofp~iential energy in c.ase ofBe. + is .. HSf.:.4.~V - - 111 !l-
2) The uncertamty m r for an electron m IS orbital ofH-atom is .. . ~ ~ ./1.~o.. ...
3) Tlie commutator of two hermitian operator is . :b, ..... (Hem1itiaIDantil'retfnitian)
_ / 4) The probability of finding the electron in IS orbital.of hydrogen atom within first bohr 4 m-E
J.;C _ ~ radius is .. .:02..... %.
-,.-r11t -.;,,\- -~ Three 2 p wavefunction h~ve ·,· ............... (~am'0differe1!!:) radi~l factor. · .
J. 6) The zel"o value of energy 1s .............. (possible I not f)dSsible ) m quantum mechanics.
\,1)\-\"t, 7) Uncertainity in momentum for · an electron in 1 S orbital of hydrogen 'atom is
~
D"""'q"
··::····;··¾;······_-··· . _s- t:lY,f Q C
8) Vmal theorem 1s applicable to ......H ~ ~ ~ o d e l and ...... L'P.'1.p.LL..~.m ........C. ... 28. ... •
tll.tdd
,.
.JJ . · . • -,t- p710f;x::tl::>i~ 15- IS O'lre>/'./aL
Jqj~;r
~,}~'e-~¼. L''l. c~ A-2-J,tq8Si11t1J-<i?
J~ · Di4ot'~
tJ-fo .Dao
p-- 1- e-w {_2 02.+2.1>+1
)
.
0 l)
70
~
. ~ t "-2..e-¼o J.;.., =- I--!,,2-

.
0
'=--
S1]
-
o+o fqo ~ _!-"".S ~2.

;v;-/•-- ~'./-~~"•\··
:'q;i.i~; ,l1). •· .. www.chemistryABC.com
LV;>
1f"@
LJh.1
rnV
m
Lh :vr
l.~A
o
~~
-
.c
H
C . He-t''
B
, ·u.2..+'-
yA
•Bf!!!+++
tr
is
m
he
.c
~-::.tl?°4'Jr~;
w
A.It::. 2,.
w
w
J.J-:::- mJ, .,v

h1J, +TYi,.,.. .
e=
"'1p ·7? 184'0 MlT
A=- . IJ!j;,1)11.r ~ Mtr
¥-I

om
.c
C
B
yA
tr
is
r
m
he
.c
Tl= P.
w
w
[k~ -k a:
w
~ . - 3X.l. .[if
-1/ 1.:>/2-,, ._ ~ :,...
--!

. . . . . . ;;,.,\\; ,' ··\-
➔ NoisJftCAilt:.L {1..u... wtt.Ue.1,°nd?cm ... www.chemistryABC.com
-.2.:::t. 2...
qJ:.::. e
ot>
o,D
J
-""'
::x. " e..-4.:>c.2:. dx.,
o m
.c
I~
C
B
-i.
-.:fir
=F- I
yA
2.
tr
is
m
he
.c
'2.
w
N (2:J<..=-.1) e.--:,½
w
j ei,/) :J.
I'.'. -.:t/~ ( ~ >t':..1)
2
w
(2.x2=-tj e..- ><,7,_ e/-'L = I
-""
oD :.,.. x2..
j (c!(x..:1--1) e- dx,
- t::,i)
ol>
j C'·"'-"+ I - qxo..) ~-:,,_2..cl'"t.

- j"° 1p1. e- ,,. -1-J x- t._,,_ cl"- +-j - 1.1~ ,.e_ ""-cl>L
c:,O
I.{
,. di> 0 2. J.
-6' -~
4._1.1. R + J'Jt-4.J...J;j
73
- +
Download all notes by clicking here- := ikwww.chemistryABC.com ~Jt
--@ ffeco(1'1t, a v ~ °o <x'?-~ <,t.2.?, <P.,,_'J 1 <f;,x..'->, <(<.~ I < V :>: \ <)!J:)t); (/.J p.,,) :
if"" ID SHO in 1-x,v>VJ~+Je.. d

4'o =-( ff}~ c-Q"'-/._
"
~
@ v ~ Heu.,em/::,e.711 untl.Ab:d~ r1ndp" ~
f
@ v ~ vi,ria/ ~ j
C:.k7 ::::: <.V) ~
~
fu
..J,, ~
(<<la.hon o/w ,v) attcl <I</ ·~
fn a,.&e.;-- a.
om
'(;:
-, l< ::1" -::: -{ V

f-1-ahrn rv,oelt! -
.c
l<= -r -=- V ~
SHO - TV)Od..tl __,
C
B
Bu.¼ Tn al.A e_~ ...
yA
'P'I g £.:. R,licl >a-!o1t

tr
V .::..,V
is
:. • t,..Jo ··irTta.l µla:/,r/YJ

m
he
~= (i,,~,!;) hv :::. l 'V\-f-t,) A~trh~

.c
w
~0+±Ji;w
w
w
b<7" j {~ f e:- ~'¼ x[.f;,/4e- ex,,: o/x

_ oe
o()
- L~lz),D
- rv
-
~
Hi
-,_

•e L..0 =- 6
.C::::. K}> : <. p<';:,www.chemistryABC.com
-.2..n't -
- J$-l:,2..
'-I 111)
- -
0
• <.p,i./ =- 0
~:>CJ') =- ~
<::._ V) -::: ..L l< <x,2 ) .= _!5_
2. 4,(3
0
©
G
@rt
=f~ -o
o m
.c
C
B
yA
tr
is
m
he
.c
w
w
w
=- _L hv
4
\/ =- -I<- -.... -- l<

rev.
L,(
t,;
-
lf~

m
~ PaJ\..-\id.L fvi Box rnoclt.l -
o
To ~~--tw_~~la.:l-idVl.a..l tvlo-ncn,, °-fr
.c
~d..t llll bauV1dl.d_ ~f'7\ll ~ rvtocW. w~r~opos~. C
B
::i:\I\ ck_f\l\\sry -tf,u_Moue.rvt~ "'t- rr t::.- rn u•\lb,~
yA
~'cf e..~a.MplL-
e\l\.cl ~ ~ co..~bUYJ 4'b 011,,\.ecr ~"'d at- eq...-bm,. ,ru
~
tr
..&.~~'Dcl(:)IV\ ~V\e.
is
m
he
.c
w
w
w
Ac.e. •..\c r3o'"1- op pEA1 h e.irt1 c"lf

\JJ:- V~ LO'l1A14U.\.. q 1_)-Y-et pa1J-td.t 1/2
(D/..-tO~ -tt....t. tia.M.la.:lioY)
IV\trnuvi 1:, rvt't C.~top il. ~d(
Co\h f>l\11 <:ol -to l\17 out: t vt Cl l D - bo ')( 1 lw1 I'f11
~
we. \~ i+- tlt\OU...\)et;\clw!- 45' [ {) (. ?C. <L J pa.A:1:iclL u F ' @
Otluy 11'\~ I, e., Ro+, Vi b .
Pa.b+i'c..lL t& 1:J-Y-ct... 'l!:lE ptU:tt'c4 '\1_ O ~ Q {A $
.&:. ~ \ c.. rvtoftav,
[
Q.tti( OYL ft- po+eufia..t_ ~ tA. UI/Jilt,
a
•
qi,,q
-to Cl~kJ Ma:h,ieMth~ ~~ltca.:tr<N?

pu:k V .::o J V-::..0
e
G
e
@
•
DPP 5 Quantum mechanics .

Q 1 Tunneling is a quantum mechanical phenomenon,consider the statements about it
l).On increasing mass of the particle and-height of the barrier tunneling decreases•
(2) Particle with energy close to the height of barrier have more tendency to cross the
barrierA' (3) If tunneling corresponding to electron is e-20 then corresponding to proton is e- Ir
480 l
Correct statements above are (ll}'i',2 (b) 1,3 (c)2,3 (d) 1,2,3 (e)none
•., Q2tonsider the statement

(1) Virial theorem are applicable to atom and molecule both. T
(2) According to virial energy contributed by potential energy and kinetic energy are equal. f'
-
(3)For first excited state in SHO the energy contributed by kinetic energy is .75 h v. 1"
Correct statements above are (a) 1,2 (b) 2,l(c) 1,3 (a:,1,2,3 (e)none
I Qa"Consider the statements
I I) The value of <x> and <px> in case of ID SHO is zero. -r
- 2) The wavefunction corresponding to ground state in 1 D sho is symmetric and d_ecreases

..,li.
om
rapidly if mass of the atom is more.T
~ I
3) The energy gap between SHO is always equal. -r fyop~°i-
Co:rect statements above are (a)l, ,2 (b)2,3 (c) 1,3 (d) 1,2,3 (e)none a.uSSi<Ull u, vrdicfl,
.c
4
Q,<."Cons1der the statements .- <I i ,-

C
(1) A standing wave has nodes that are at fixed distances independent of time, whereas
B
the nodes move in time for a traveling wave. T ·
A
(2) For the ground state, it is much more likely that the particle is found near the center
y
· of the box than at the edges T · ·

tr
Correct statements above are (a)l, (b) 2, (eri,2 (d) none ·

is
Q5. J:'he transmission probability of a particle encountering the barrier is e· 10 if mass is

reduced by ½ and width of the barrier is doubled , tunneling probability would be c.$'1 ~-':IRf-_
m
j__'lrje-10.,/2 (b) e·20 (c) e·20.P (d) does not change

he
Q6(Consider the statements

(a) quantization is the result of boundary condition. T 'tao< vt"2-
.c
(b), As number of nooe increases the value of energy increase in I D box model. -r ·
(c) The length of the box is thc:dnfe-gralmultiple of half of the wavelength . 1.·:::: A;:z..
w
*(d) As we move towards higher value of n quantum and classic<1l prediction are same 1 _
w
· . True statements are (l)a,b (2) b,c (3) a,b,c {efa,b,c,d (5) none ..J, &t<t'ir <on~~~
w
Q.-Ttonsider the statement . _-. · - pirri'ltl'p{t

'I. the condition that V=0 inside the box is the result that we are using free particle T
2 V=oo is considered elsewhere to avoid tunneling 1
3 The enrgy of quantum mechanical particle in PIB model increases with increases in mass. F
True statements above are
~1,2 (b) 2,3 (c) 1,3 (d) 1,2,3
.s-:1\ particle is confined to move in 1 D ho~ of length 1, if the boundary ()f the box is removed
than ". I • • I_ •
efnoquantisation (b) quantisation retains (c) particle remains within the same region (d)none
~onsider the statements

..,..
i) bound state· give ~uan~ en.ergy level ii) Qu.antum num~~.L:in PIB mo_d~l is a res?"iction
rather than assumption as m bohr theory of hydrogen atom T ni)the probability of fmding the
particle iii the lefthalf of the box in every ·state is equal to half. The true statement above are
a)i and ii b) i ,iii c) ii,iii «{i,ii,iii e) none T
~Consider the statement
i) AE/E becomes a smaller fraction of the energy as n-Ho . This result shows that the energy
spectrum becomes continuous for large n. T . ·
ji) zero point energy approaches zero as l approaches infinity. In this ·limit, the particle becomes
free. 'T .1-:::."""' ~ ::..o
· iii) probabilityof finding the particle in the central third of the box if it is in its ground state is
0.6. T
true statement above are a) i,ii b) i and iii c) ii and iii d) i,ii,iii
~consider the statements ·
i) For sufficiently small!, the energy E may become greater than the depth of the potential well.
such a well will not hold themici;oparticle. T . IZ-1'- - r o , - , ~ 1'&\ · ·
m
ii) The wavefunction of a heavy particle decays more rapidly inside a barrier than that of a light
·. pa,rticle:1 ·. · · tp
o
iii)that nyo wavefup.ctions belonging to different energies are orthogonal. I . ._. . .__
.c
Thetrue statement above are (a) i,ii (b) ii ,iii (t:)'f,ii,iii (d)none · .__ __
~onsider the statement C
. • · ·
B
i) the uncertaintyprinciple requires a particle,to possess kinetic energy if it is co$ed to a fmite
1<.f-:::-o =) 6x.~ C'lO ·-=) 'P41tfldt Ot'lboo-r>d ·
yA
region. j
ii) Energy is quantized but other observable are not quantized in quantum mechanics. r
iii)'PIB model is the basis of the treatment of the electronic structure ofmetals and a treatment of
tr
conjugated molecules. T · ·.· · ·. · · ··

is
True statements above are (a) i,ii (b) ii,iii (efi,m (d)l,ii,iii(e)none
m
~oµsider the statement ·

• i) Tunneling is a real, detectable quantum phenomenon. It is not predicted by classical mechanics
he
ii) The aver~e value of the position of the particle in a box is a/2 for any value of the quantum
number n. -,- .
.c
~,iii)l:feisenoerg does have restriction on knowing average values of the position or the momentum
r
w
also
·*
w
T~~tatements above are (a) I, ii (b) ii,iii (c) I,ii,iii (d) none • • · .
~rite the formulae for probability of finding the particle between 0 to.Ozor a particle in box -
w
•. fo(ti,.th state is ... :ti} ......... · · ·

· Jj/Uncertainty in position for a particle confmed to move in a box of lenth 0.2 nm is
el, 031..?lttThe wave function corresponds to n=2 for a particle in a box oflength l (-1/2 to
--k- ~ Srn 1-vr.x .
- +1/2) is . . . .
., r -z:
flllaM o-,00 ~ Tunr,eili'1''6J:1 ___;:, T~IM-f\1JS.Ydl? ii;1=('-
J
4' ba,-'lf't e..,r 1¥- ~ y., cl) . val.w. 45Ff -!
dt~ f87f'

'V= o0 &&~wluhi- [ ·-:~~~::~::.:~i.~•~3& q-~~M
IY1i~('.IE)J:>r c. p~dt h~u17 e.-r e"'rt ~ it,,M-J

0
:tion 11,u· ~Yte,tTf ~ paf-ec,ct,•oJ ~o.-zsy1e:y L,,()JJe.. Tk4_

; the
fe.lllcl,t.11~ -to c.~.s.s --rtA.t_ bQ,n--\C'.3" ·°fr
ergy
i"ihl~ wicttt,, r~ "- Ylo-W Vl ~ -tolf't \1 e.Ul~
,mes
e...<I- ~ edlvt'} 1 -<- pcvb"'ti..t. oa-rrm -yo.ol.l"o.dtvc.
Nu c..W' Ct:, exqn-, p Lt 4 4o l1l't e.11.b-td"'
te is
it t\'\1C.Yo&c.epfc. pa..>Jieb.. m~.:: IY1 £11e1t't;J'==-E.'
bq'2rlr'ic.ir ~ w~~==
.:· .
Pe+. v l:>9-ins(~...- L
1-te¥-
light
m
T·= C~2)2Nt(V-E).
fJJ r§l Afr
0 y• ,.
o
16
.c
V=:.oCJ T=-0 . ' ' '_,:' ·,
inite C
B
yA
otof V ::,.oD
tr
is
m
. -;. .
nics T1 _01.-.-.----...J)_ >
e, '>1
he
ltum : Sc.J,,7r~
.c
Ltum
w
i
' .
w
box 1r'" ID-- Stf'r e.twi ' C a . ~ (j) -O"'IC olt.,Qfa ' :'Q 2. = d"
w
' ' ' c::l:x. '2.. .

tn is
12 to
-1
,-- .
,·
; '

11-trlj ~tt~a1.-a,n l;Qvt!~ &olvn~ .
I
.
4' -=- 1=1~ tk.=-:.+ se.-!r-c.x
'
l 4? = l't--Sivik>c.+ 13 ~ l<:,c. J -- {D
~
Ap~ia Bau~ eevdj;;~-
(D · X-::..0 @x:::...i
<IJ 4':.. 0 4'-:: O
o:- o+ la,)
[t3 ~oJ
o m
"1 i., e, <D
.c
Pu.ti YI 13::.. l? '
=-
C
B
4' ,q Sin kx.
yA
flpp~r~ CfWtcil--h¼
tr
'.l.\f\.q bUOYldQ~
is
::>( = .1. q> :::. 0

m
he
.c
So Sl"\1 kt..l::: o ~ Si"Y111Jf'° 4

w
c~~~ ◄
w
i,(_, ~tv)a:h~ 4
w
O
l/J-::. f1Sfr1t<..,l-+ 8&~ kx.
')\ C
[
d..Uow~ buJ: --no+ 4
A Sin 11.,-x. 4u 0.\Qt) n.., 1V\e.t.liaMi~
-:z. j ~vo.M:lu rv, wte u,. .(.(..f.hrtc:H'O)).s ◄
7n., posecl 0')1 a 'no. r~ ◄
Afr~ Noismo.U -rad.-,°crn ~.d.t"-h"""t
•t
JlJJ f' lfalt ==- I
t
l
.. j.
liSin?'!5_ x 11-.Sin. >'!!!;x :::. J
.). J!.
{)
~'-J' ·Sin -1ur
--:L
2
x dn~ I
.
11~)T
- Jl
•
•$
e
••
0
Q
C
0
fj TaUfSlfs ~d-tn'} 1LJY);,d}i~ _
om
C
0
T == -et2} ~"" (V-€J - L
.c
""'
•
e
ItB
C ~ J M(v-Ej. L
,bt
/.t., Mare TU't'1"1dlfd'
is~f
yA
0
~ ::1
tr
e T4--
•
is
L1t ,
m
e ~ tS--1,,T .i,
he
11,- E. 1' ] T 1\
•
.c
f) E _.. -c. nt!""'rt ~ J:>aA.id.t.

w
t V -, &lcnrrey n¥
w
••
w
l -, Sa.T"r fc,r LU fd.±1.,
M.-l 01"-k 1 pa.,J, dt

•
•e
0
••
•
••
t 81 Download all notes by clicking here- www.chemistryABC.com
'IP
••
•
~
,~
®
$\
fJl
.Si'n ~ ::.+J
.St VIS_!"~+ l
;l--
om
St""GfJf" ~ + l
,:.
.c
C
B
yA
-:;J Z==- 2..s t.. ( &J-°6 btru11~

tr
➔ 4? ih ~ w~ -
«CApfal)
is
N1J1
S'"''-"x=-0
m
-::,:..
he
.c
w
w
w
EJ
00
®
~
@,
@
4)
@
82
c-:{J
~
•
•
0
- www.chemistryABC.com
•
(&
e
e 8~?---+---"--_,_--'
•
0
Yl~::I
0
e
G
fj)
om
(J
.c
C
e C
B
yA
tr
•
is
m
0
he
0
.c
••
w
w
~
w
11.:1..~
0
•
f, ~-, No,1 V\o~: ~-LJ
'n.::3~
. ..
. ..
------:.
~
-¼_ +Ali::: l.. b(jt) 111da1

e
C .,, ~ +~ == ½. = }1od.(
•• ,,
•
,9
\
om
l) ~ - - - - - + - - - " t Jl.
.c
C
B
yA
~ F~~ ~ PI 8 mooW.- (y _ . CJ)

tr
f"'"•""' ~ A.t.Ulffcn,, b/w °1) --ttu. bax (.- ~ w o . . ~

is
(j) l..tM~
m
r+ ff> cJ~ tt,u;d- l.J.m~ 1 -ft.u. bo~ ~ 1t-d~ rnuJ.f-t--,,LL 1 J/:l-

he
qs - E ::: n2.vt2...
.c
@f'llt.,t1-
w
w
1vC = l:>2-
w
oltM
_Ac
%
,~ - i,
,A
h,,_
le..£ C.
~~2- - ~
112. >,L
- o!-
8-rYl,.l '- -
h '2..
~ 2..
1. -::. -nA
__,
::,...

· · 1 -=- - YiA., ~em - - :ith1td-f(Wj b~ e ~- · b/LU JlfV':,+ ~ l1. -,,~
• :lb- . o-
<>:,.~ - ) .
~ www.chemistryABC.com
C b«a.u.&e.. of"eY ev~ '½. {v~d-1c-n b~GS "UAO,
•
©
[ !-.to.- °1) Y1 od.v. =- T-.aw. Jcd-rc-.t 1· No -1 7
(~
CJ
@
•ro 11ad.l.::..o
0 'Yl:::: 2 .-l= ~~
~
e 'l1oelt:: I
C)
om
e G) ~c_; -tw- box
t~d-r"OY1 4', ,4' 3 , 4'5 C1.A.L ~
0mmeh,tc. W,h,f,
.c
~ lJ,. ,
G
C1/}(+-:,t_} = l.f(--xJ
B
C
i._ if vidi '-P, , 4' 4 , '-P, 19 v.:h -A~ m wie:h-1 c.
0
w . 'lS" ,.+. °fJ bo x
yA
0 C/)1\ (MJ.__ C4M:J;y <:.
•• C!.pl+ qi(-><))
tr
7l)-; -
is
•
m
he
e
e
.c
••
w
w
w
••
••
•
e
• I
•• ir---------='--~ ).
1
St:JIYI .
••
' · (!) , .4i ~ ◊olil.tif ~Odlt '.;4 ~1' '" t1r et.-&<!.; , ~ · 4'fi~. www.chemistryABC.com
. 'Y\odt.-=-- '11. -I
'"I\=:. ~oell:+1
:Z:V'\ 11Ae. rru~ct ~ffl:te. p ~ .s r~d~ ML>St 4,- --fkt_. +tme. wth-rr.,, i1,,e_
Mid4,lt._ ~ov, M«o.!tl!, '11011--e>i,,~" i 11 oti&-hi-ibu-ti°D>? '4 11,, ~ ~ :
f V\ --t'w. \ OW"-~ l.t.'id._ · 1k, -tin"- Va h u.. 'i, 11 1 -e,., it,,,_ '-"'l.lf.-r,.,,["';f
fvt -t1-u:..ctl&fa--tobu~. &.. Q.k. v ~ 1'111' va.lw. ~ "11 /?a.A.¼r°d.t
~ f<'-1Ad ~ aL MoSt i_ua.A- -ti fJ/l"(__ ct1--· -c_ v ~ ~ \OY\. 'ii- r-o bctbt U..1/'
mea.\l'V:) ea.\.U"tuvu.~ ~Vt-e.,.-~, c.L:..,v..i~ he.l.i.a.\J Tot.ns-" evre1""?..tl.
om
He,,nu. &his- Co1(Y~ p~"' ,=ns-itu.i:pk 1'.J~( F1f v°<f' "'-'-'r',
.c
'\ta..l.u.t.. "fi '1'1 ttu_ p1r"e..ol.Ic:l-iot1 TYl.a.d.L
B
C h'! 1uanfum ,new,q,,,,r<..s
i'A ~ame.. ~ <::.ta.M,ica.l m~c:u,fcs pTcd.i.d:,,)
yA
tr
is
( i.J eYT.=- l\~~2.. ;::., h 1 h2-

m
aft111/..-,,. Sn,,l1.
he
et1. . ,-~,,, =[ ~+,;,._.,,j-;:,.2-

.c
w
~ @vt+-1)~
w
w
'8fY1,l:2-
---
{ iii) -,.t +t.i +A 1,J ::: r:TSin n;r:x. -, n::::. evfhJ

't'J1 J:X oft). 12 : : . n 2. 1,2..... <1>1 -::--o 8
~A).2- C,
. . __ n.-:z. '), 2.. <pa? ::.2m.E: t]
3.2. w,,..t.2- <?(.t;> - ? ~
.
•1
•J
•
el
1
· DPP6 Quantum Mechanics
1. Consider an electron with energy E, mass m tunneling through a·barrier of height V>E and
width w ,the total time t electron spends inside the barrier TIFR
•• !
I
~{~V-E) b)wx (2~n/E)0'~ ·. cf{2m(V-E)!n} 0 ·5
d) {4in:7(V-E)/n}f;5
(l)If the total energy can be written as a sum of independent tenns corresponding to different
i
~
• !
degrees of freedom, then the wave function is a product of individual tenns, each corresponding
to one of the degrees of freedom. 1'
•
(2) number of states, each represented by a distinct eignfunction, that have the same energy is
~ degeneracy of the level.1' _ _ \It;:
@the wavelength of the light emitted when an electron in a one-dimensional box of length 5.0
nm makes a transition from n=7 to n=6 is 6.34xlff6 m. 1 1) .. vi::
•-
~·
Correct statements above are ( a) 1,2 (b) 2,3 (c) 1,3 ~2,3
m
3.The smallest observed frequency for a transiaon between states of an electron in a one-
'dimensional box is 3x 10 13 s·' the length of the box is · R.'t _ ""'-
o
l,>1 ~ 0 - ,r::
• i
~)3 nm (b) 30 nm (c) 300nm (d) 130 nm (d) none
.c
'
• I (9"he movement of n electron in a conjugated system is considered as a free-electron model. _

C
Using the same argument, si, ;&at the length of hexatriene can be estimated to be 867 pm. "11b ~ =::...{.
·°n
B
4
•: Show that the first electronic transition is pr~dicted to occur at 2.8 x 10 cm·'•. ,2<1-C3
yA
••
! (Vfhe difference in the ground state energies (kJ/mol) of an electron in one-dimensional boxes of 2,.
lengths 0.2 nm and 2 nm is _ _ _ _ _ _GATE Chem ~~ ::. "2!!-

tr
I
~onsider a particle is confined to move in a lD box under the potential V=O [O<x<l ] and <&MA 1-
is
••• V=infinite elsewhere .GATE Chem ' LlG ~ h\l::. n.f..

m
. i) When the particle in its lowest energy state the average value of momentum <px> is - .• ·ti
· .c..kJ.c'i?
he
~ b)h/2a c)h/2na d)h/a
•~ ii) The uncertainity in momentum l'.lPx in its lowest energy state is

.c
a) 0 ~2a c) h/2na d) h/a

7.The lifetime of molecul~ in an excited electronic state is 10· 10 s The uncertainty in its energy in ~ed+=-11
w
•• eVapproximately is GATE ~chem l-/.')C/o-1q J':::: r-e.v L/J

w
5 6 14
a) 2><10- ~x10· c) 0 d)l0-
w
8 :A particle is confined in a lD box oflength 1 mm iflength is changed by 10-9 the percent
••
I
change in energy is GATE Chem A,-::. \bg M
4 7 2 1
a)2x10 b)2xlff c)2xlff &fO ..t~=......t.t+d)..-=:. to-3+11.~,- 2.M
9. If [x,p]=in then the value of commutator [x3 , p] is GATE Phy (2 -~r
•
••
a) 2inx 2 2
b) -2ihx ~inx 2
d) 3inx 2
2-
10 A particle of mass m is confined in the ground ,state of one ~imensional box extending from
-2L to +2L The wave function of particle in box is 'l'x=\jlocos (nx/4L) where 'Vo is constant
e., "-
l \3"0
i) The normalization constant\jlo of th~ function is GATE Phy

a)(2/L)°- 5 b) (1/4L)°- 5 ~(1/2L) 0 ·5d) (1/L)05
••; ii) The energy eigenvalue corresponding to this state is

a) [n 21c2/2mL2] b) [n 2 n 2/4mL2 ] c)[lln2/16mL2] tff[n2n;/32mL2 ]
.'.
·-··.j.
I

iii) The expectation value of operato(p2 {pis momentum operator) is

a) 0 b) [1'12n:2/32L2] c.¥[ti21r2/16L
. . ~
2
J . d)[li2n:2/8L2 ]
. .
11 A particle is confined to move i:n a ld box oflength-a to +a the wavefunction CQrresP._onding

/-~ ~
t t · ~=--.LL.uw.L. · .U-.;J 1 ~= ,.1 :..L. &1n >1Jf.l:.
toground sae1s <..,"'··:· _.GA"·. TE. Ch.· em -,,.i
w~u.•~~ ...,,,, ..r,:: . .!/.L-
~alculate the wave ~ngth correspondmgtq lowest energy exc1tat10n of an electron confined to
move in a 1 D box of length 1nm. IITJAM lt.. o3Jlo-,rn ·
la"'Given three systems, A, B, .and C, what could be they if the spacing between the neighbouring
energy levels in A decreases with increasing energy, while that for B is constant, and that for C
increases with increasing energy?TIFR 2013 · ~
A) A= particle in a one-dimensional box, B= harmonic oscillator, C=electron in hydrogen atom
~A= electron in hydrogen atom, B= harmonic oscillator, C= particle in a one-dimensional box
·· C) A= particle in a one-dimensional boxiB= electron in hydrogen atom, C= harmonic oscillator
.~A= e. ~ectron in hydrogen atom; B= parj:icle in a one-dimensional box, C= harmonic oscillator
om
·.· (!J..,tons1der the statement .
I.Probability of finding the particle in right half of box is 0.5, if the box length is 21 ( -1 to +l ). I
.c
··. 2 Themaximum value of function for a particle in 1D box of.length 2 nm (0 to.2nm) is 1 nm· 5 • •
C
3Stabilization because of resonance and Red shift~ conju.gated ~ay be exp;ained by PIB model.
B
The correct statements above are (a) 1,2 (b) 2;3 (c) 1,2,3 (d) none·
_15 The location of node for a particle that is confined to move in a 1 D box of length 3 nm in the
yA
~ond excited state is (a) 0.5 nm ,L5 nm (b} 1 rim ,:66 nm (c) 0.5 nm, 0.66 nm (clYn,one
·u,,zeropoint energy of a ~articleco~firied to move in 1D box of length 1 (-1/2 to_+l/2) is
tr
SofY
is
2 2 2
(a) n h /8mi2 (~i2/8mi2 (c) 0 · (d) h /32mi2 (e)none
m
· \.'-\tfC. Irusing Heisenberg un<?ertainty principle (l.erive an expression for ground state energy of
~ ' "• . ......
,,.,,., , ,- ...
" '' ,, .,·'
B(l
he
. ~icle of mass in 1D box of length 1. UT JAM · .

.., ~ f nelectron in butadiene molecule bellaveparticle in box model and length is taken 1 the total.
.c
. ground state energy of n electrons in theground state is·.

w
(i) 9h2✓4ml2 (b)7h2/8mi2_ (c) 5h2/4mi2 (d)2h2/8rn.J.2 (e)none

w
19FoLa particle of mass m tonfi~~d in ibox'ottength L assume ~x=L, assume further that
w
. 11prnnt=(p2) 112 , Use the uncertai,nty prin~iple to obt~n the estimate of ground state enrgy of the
particle.The valpe will be . ·. · · · · . CSIR Chem
2
a)[h /8mL ] ajri2/8mL ] ·c) [h /32mL ] d)[h2/2mL2]
2 2 2 2
20.A quantum ~echanical partide with energy ~ 0<V is allowed to strike the following four
barrier separately TheTransmission probability is maximum in CSIR Chem
G} ax. LlP -= ~
2...
2A
4 Ap
L
~
11..
..zL
J,;
::... ~fl.
'(k2/'~ , , ~
e = . dl_(Y}
k.,2... -- ,p,-Z.
8ML.,_
'
. ~'&!. · ➔ •·. ·~.ir··1wL . e_~~'1f' wva ~. ~ rx, bablUt;f ~ ~ faMcl.t °t" . ._,_.
M~ M.
'
6
"°'-.~c UJ\'\~ q ~ ( 0 box Z/1:. dtpicl<d b,-
ing
- ).. ~ ,,( (-21.J

m
IX
V -::::.. 0 (_ h,,,.,,\cit.)
)f \J.:. c0 ~w Lu."'l"'e.
)f
om
).'
••
.c
el. '1-=.o l i.,,,~idl)
d~-+- e .'+1 C ~ -t
B
le ~JV\ -.::.-0 - ~2q,,:::o
dx.,) . "'11'\~ . d :x...:a.. .
A
Sof'l'\1~'\l\~-
y
lp:::. ,:J.Srvt~ +- 8tv.i. kx · - CD

tr
is
Bcfd w:! a. '>?J ~-lid'VI~ .,.

m
, -:x :::.. -,.,1... 4' .:::-o

he
tal
.c
A Si\, l<.(-.L7 -+ 13 ~ l<:.tL1 :: 0

w
- AS'ir1k..l ..+ •8 ~ k-t =- o -a)

w
w
@ !><..=1:-l 4' =. D
~Stv,\<.).. + 8~ l<..l = O -@
~ 2. B uA~~ c.o -@
<f]) ~ fr ~u =o --(i)
A-£ B ,,dmu..l:la~ l'tLYtA. be:.. .~tXU .+o 7JAD otw.cr-Wi..te.. f111tth'lm
b e..lOWl e,, -wa6> , ~ J:I
· :::..o 01{ 8 -:.. 'D · ·

•
1./1 ==--,II, ..SlYl k,t.,
[If= 8 {.~k,t.
+ 6{o9<.X,
J •
41
4
-1~
D- et,i"1@
l
. (3UY3
s;eo ~)
kl =:-:.0
~ }q_J... =-0 ••
da,&k_,{ z_
. ~...(_ =:. }?Jr

~11!1"
~ ••
o<
•
k =- ~.r
~-l •
4
\ IJ) =- B ~ '!if] en -=- I , 3, s. . . ... ~
om
,11 ''
.c
B=-D /J4 0
Lf ~ r,~inJt.~+B~kx.. C ~
B
J •4
yA
[ qJc= T)Sinl<x
tr
is
4
m
t
he
4
.c
4
w
•
w
.t
w
-
•
◄
/2::::.. 4
t
-
•t
-/
4
-1.
•
1
••J'••'"
• ,t .i
••
e
fj,
€j
••
e
~
LJ..k U5 U\IV:.td.br Q 1,"rCLpa>J:l"'c.1.L rA. ·~{~-to
f\,\e>Ue r\I\ a .2.. ~o box D <. )(. <. A(:x,.) , 0 <cf<.. lc..'J) . PaYNclJ.. ~ 1flS c..t. V =-o
om
v =- "° ~c..w It\ e..Ye •
.c
.5c.,Lr~oc..l.JJAAe.y
- 0
e, 1>'1 ...
~ 2 q., -+ .2.M C
(.E-v J 4' -=-o
B
..-i,,-:a.
yA
"')
2
15°0 1D- S'f>_f-~ -
tr
1
"'22.-=- aL a 2..
is
...i..
~~
m
~~.,
he
1vte.Jll
.c
w
w
w
d2 L{Jtx,YJ ,-t J:z.ll!l:'4~) ~ ~ 2 . £c.-:x.ij) 4'lXij);:::: D

J?t.~ J ~'l- 4-t
't>1Aditm 4:' C.:xLj) A.t.fG~~ tl,,e mo+tO'YI e>f; pa.kA-ft:li.. ,~ rno...-e ~ ~
&pa.;l:iaJ.. OU.IY1e\.1J!Jm.
r....--IJ)-lX-t)j-J-.::..-lJ'~

~x + {::t] www.chemistryABC.com
➔ '{o~dt<M J..tp-u..e.ia_., -n,,e W1:l.ue '"'1 Mu.i.¼?J>!.t.C<U1°ve ~ eYt~ ,i, e.x'fc1,gM,:

{' li(J ~ -;> Add.l+r'Ve
IQ
/t1 e., >:)
J2. lf'l7(.)4'~) --r .Jz..'-Pl."'-J'P(~-+ d?_!:t [£(x)+ £<.::11] 4'c"- tp,. =a

d ~ .x.,:l-. J;f a. '1-,2-. J ~J
{/)QI J J ~l~)
d.l.,.
+- lplx) cl 2.(,l.'(y)
J(l 2.
-+ ~
,fJ 2-
[ ~) + ~fj)] 4l.-x) 'f'Ct.1) :: -0
"
To ~epe..1'a±-e--tf,,..t 'VOJ\.tab LLd.i'uk=U. b~ 4't'>«) \VQJ) u..e ?-f-
om
_J_ a2-'l'c.x; + L d,Pc.~J 1'" & IV1 ( ~ "-.+12t}} ~ 0
.c
4Jc~, Jx:a.. 4Jl!:JJ a~ y 11.).
C /2 - ~ 11? .Q"f
B
+ d7f'l'd) - - &m -@
_J_ J"-LPtx.J _L
'z/,_
yA
ll'l~) -;fni. f.JJcyJ {;t;l. x ,J;,, J-
at
tr
Mo4iOY1 -r'Af-pa.k};clL ln bYle. dfrne11l~iCM }A f\rc.ltpe~ °b MOTie.M e-f;

is
~ c k (Ill ot\Ao..Y OUJM~A>~,

m
C
he
Sl>+e.~m<1l? ~btdLcrf;- ~l'7@ U ~ual -lo~~0>1M?14"~blt°1,e,>1 ·

.c
w
w
w
2
_L d 4Jtu) A':J
__:::! :::.. ..-cil_n1 ~ ~
W0J d~~ :.P,i ~
M~ be_ uJ1rt tre11 QJ-
d7 4' l" )' _,_ ~ l::.(?t) 4'l:>t) ::: o @

cl'>t. l-- ,i,-, ~
(W.. Sol'YJ 1- a bov ~'Yl I& - e

a
4'taj:::: J¾_,&tn 1tn11 ~ ~
e
"' .::
<::. ,,2.Pl...
. ()(,. ,, @)

@
•
DPP 7 Quantum clie,;,istry ~

2
J::rrhe degeneracy corresponding to energy of2D square box with energy 101c2 t,2/2rnl is
(tif2 (b)3(c)4 (d)5
~The lowest ene1·gy level that exist both in 1 D box and 2 D square box of length I is
(~5t,21r212mf (b) 25ij 2rr2 /8ml 2 (c) 5frr2/2mf (d) t,2,,r2tmi2
3 The degeneracy of quantum mechanical particle of a cubic box having energy four times that
of the ground state energy is IIT GATE
a)3 b) 6 e,1 d)4
4. The degeneracy of quantum mechanical particle of a cubic box having energy two times than
the ground state energy is CSIR JRF
'Qf3 b) 6 c) 1 d) 4
~ f cyclobutadiene molecule is treated as particle in 2D square box of I nm, then the energy
requir<::d for the transition from HOMO to LUMO, write also the wave function corresponding to
degenerate state. · . IIT JAM
om
@rhe porphyrin molecule (considered planar and treated as 2D square box) has 26 n: electrons.
If we approximate the length of the molecule is I 000 pm, then what is the predicted lowest
energy absorption of the porphyrinmolecule. Sh"- '1-- c. 2,,q 1- t,-,q.:r
.c
"1":for a particle undergoing quantum mechanicai1tfnlhe1 ing Tl f({
C
i)the amplitude of the wavefunction after passing through the barrier decreases with increases in
B
width. --r
yA
ii)Tunneling barrier height increases the tunneling probability decreases I

iii) The energy of the particle after the crossing decreases wi-th increases in distance. f
tr
The correct statements above are ~i,ii (b) ii,iii (c) i,iii (d) i,ii,iii (e) none (t) a1l .
is
{iJA. proton is confined to a cubic box, whose sides have length 10· m. What is the minimum kinetic@~
12
m
energy of the proton? The mass of proton is l.67x10· 27 kg and Planck's constant is 6.6xl0-34 J-sec.
he
a) l.l x 10· 17 J b) 3.3 x 10- 17 J ~.9 x 10· 17 J d)6.6 x 10· 17 J Gate PHY
~ free paiiicle of mass m is confined to move in a region of length L. The de Broglie wave
.c
. ' associated with particle is sinusoidal in nature as given in the figure the energy of the particle
ti
w
isIIT JAM PHY vi odd,-::. a. :::!/ · 11od.\..+I:::.: l1 = 3

w
w
~ particle is confined in a one d box oflength 2a with potential v=infinite x<-a , x>a and v=O
inside the box .Energy difference between the level n=3 and n=2 is - ~ -lo Q,
2 2 2 2 2 2 2 2
a) 5h /8ma b)9h /8ma c) 9h /32ma df5h /32ma CSIRJRF CH E.=-~
~ h e probability of finding the particle in one dimensional box oflength Lin the region g.2.t'Yl)..:z..
between L/4 and 3L/4 for quantum numbern:I isCSIR JRF CH ,. r£ S'-v1"1Jt.?t..
a)½ ~1/2)+(1/rr) c)(l/2)-(1/n) d)2/3 . , q., - ,J ;£ t T
12 A particle in 3d cubic box of length l has the energy l 4h2/8mt2. The degeneracy ofthe'state is
a) 2 b) 3 ~ d) 9 CSIRJRF CH

fflorthe eignstaies of the hydrogen atom which of the following relation between the
expectation v_alue Kinetic energy and potential energy is true CSIR JRF CH
a) <T> <V> 'f552<T>=~<V> c) 2<T>=V d) <T>=-2<V>
~ - electron of mass m confined to a one dimensional box of length b make a radiative
transition from second excited state to ground state the frequency of the photon emitted is
a) 9h/8mb2 b)3h/8mb2 ~/mb 2d) 2h/8mb2IIT GATE
15 The.ground state energy of the Hydrogen atom is-13.6 eV. The energy of the second excited
~te_isa)-27.2eV b)-6.8eV tj'-I.5eV d)-4.5eV
~ particle of mass m is confined in a two dimensional square well potential of dimension a.
This potential V(x, y) is given by V(x, y) = 0 for--a < x < a and -a< y < a, V co elsewhere The
energy of the first excited state for this particle is given by,Gate physics
2
a) lj21t2/ma2 b) 21) 2 n /ma2 ej') lj 2n:2/8ma2 d) 4 lj 2n:2/ma2
17 A particle of mass mis in a cubic box of size a.The potential inside the box (0 s x < a,O sy <
2
a,O s z <a) is zero and infinite outside. If the particle is in an eigenstate of energy 14lj ~ a2
om
its wavefunction is CSIR Phy bit ft(l.13
12 2
a) ,v=(2/a)3 sin(3nx/a)sin(5n:y/a)sin(6n:z/a) b) ;J!=(2/a}31 sin(71tx/a)sin(41ty/a)sin(3n:z/a)
.c
c) 'F(2/a)312 sin(4nx/a)sin(8n:y/a)sin(2n:z/a) \df''V=(2/a}312 sin(nx/a)sin(2n:y/a)sin(3n:z/a)
C
HrA. particle is in the ground state of an infinft~ square well potential given by, v== 0 inside the
B
box -a<x<a and v=infinite otherwise The prQbijbility to find the particle in the intenral betweeri
yA
-a/2 and a/2 is (a) 1/2 (+if(ll 2) + (l/n)(c)(l/ 2) + (lht) (d) 1/nCSIR Phy
-1'.-~ WAn el~_tr~n is in t~e ground state of a hydrogen atom. The probability that it iswithin the ,()-f:o Pqo I
tr
1-e.2''{2.o~
1* Bohrradms-1s approximately equal to (a) 0.60 (b) 0.90 (c) 0.16 (afQ.32 CSIRPhy
is
20 A particle is moving in a two dimensional potential well V=O O:<x<L ,O<y<2L,

m
V=infinite eisewhere which of the following statements about the ground state energy and
ground state eigenfunction q,0 are true? MSQ
he
IIT JAM Phy

2
a) E,=tj2n /mL 2 b')E1= 5lj2n2/8mL 2
.c
2
· ~2'L ./L) sin(n:x/L)sin(n:y/2L} d) (2/L)sin(muL)cos(n:y/2L)
w
(1pfhe operator [(d/dx)-x] [(d/dx)+x] is equivalent toJEST Phy

a)(d2/dx2)-x2 b){d2/dx2)-x2 +1 ef(d2/dx2)-2x(d/dx) +1 d)none C
w
22 .The zero point energy of a particle of mass m confined to move in a one dimensional box of
w
2 2 2 2 2 2 2
length l is (a) 0. b) ij n: /mL ~1Jj21c2/2mL d)31j 1e /2mL
23Thelowest en<?rgy level that IS the example of accidental degeneracy,for a particle confined to
move in a 3D cubic box of length a is
i) 12 lj n /ma2ii) 12 lj 2n /8ma2 ~ tj2~ma2iv)27 lj n: /8ma
2 2 2 2 2 2
·
·24 Fill in the blanks (t) (i) · (1) ·
l)The degeneracy corresponding to quantum mechar/ical particle l'ta 3D box of leRgth 'a' with
~l .... ... .. ... .
- 'J n:2;m L2.1s .. -~-
energy E-33i,.2 ..,c. •• ~ 1
l :+., .+ ,
4~12.-1-,~
u 52-1-52-,.12.
2) The wave June ti on corresponding to ground state of a particle in a 2d box of length O<x<21
and O<y<2l is .......... p;.sm
11~b<.. rft
Sn "':t~l>;r
3) Average value of momentum for a,quantum mechanical particle of mass min a 3D cubic box
lS .............................. .

om
.c
C
B
yA
tr
is
m
he
--
.c
OPP-1 O<..?CC::::.L
w
a< :r <. ~ ,_
w
w

· 'ti( Ctiti~f ~ &ilp-rnra_!# ~ , .
s~rn-e. ~."o.W-t ~--.w tuncbd)IJ

J . ~ '
e.~c_,s'flvaiu.,_ . S-kd-e
In~ e¥le.,rtt u.vel ~1Jtl.M '1f" an~ - 0 ~rhm if-u-- ('\t~ ~

L,.:ucl. em~ ~~ /2./-a.k ( one .. .,JJ,pa:1:W tYlcHcm)
f" ~ 20 n< nit!u.r Apcdra..l d.uw~wg~ 1:,1-tem 'i we., i ~ C L

-tw. ~cri 111~ f rt tw... PI 8 m,,.,W 1/,,e,,yi ituAL ~ be._ ntOTC- -/1,c,N, <llt<e
..t-l<>:k aR.. r,,o-.:c_ ~ CIYl~ ifndr"a,, --fr<. fhe. :<11>1c._ va.J..ut ufi e.tt~1{
~""--"J' (S~bcdi'e} ·V.. 111e. A-t!.u.Lt-"fr J~di'rM j-s(""M~
om
t11 Pt8 modd,
. When we. fuho<Wa 11,,,,.. l.cf/'1/m~ 1n .2rD box, i-1- kG»t"'5
.c
20- ~1u-afr'e ba?t oJ. be..-=- ~a C
=-..1..,
B
..
yA
tr
is
m
he
.c
w
w
w
-I

� · . · /il�\ ; ff�ilf_ll11¥M."ft}"�":t�/O�i:_1fff,f5A'ty j>'f?',
P
. ,
•
®
2.
E ::: (_ -.,..:_'+ �J2} 'h__
� 8tYU. 2..
e (41/)
•
()
/:_,V---
e (J,13J
0
@
fj
e c.1fSh1 �x Sin�}'
om
______ (t,lJ q,
0 €. = U"'-f, 21_e, :z..
.c
=--�,1,i1-.
e C 'Q-fllU.2.. �Mi�
e
B
yA
0
e
tr
OPf--1
is
..:;;...;---
C
m
G
he
□
G
.c
e
w
e
w
e
w
•
•
D
e
•
•
•
• 8 X '7,I X {o-31 :X (!y, to·<f_).,_
• ¾, Sh, 1:,x Si11:fd"; o?S,nKx.Si/172.,iff €if3
•
• 97
� &in!§� Si>1��
Download all notes by clicking here- 'J
:: ./S1 n2lf' si,v1;; <E5!J
••I
G
'rt:-+~~ .:. . /1)
I
.gl.+ ,-i ::-1'0 @
(i9 0,1) (1, '!) I

@
I
-:---~~~~~eh.I~-. ~p~-=----:--,--~=-------
wi.e.. W<- iu:1,o,,wa SJffl1YI ( 1'1 a-o bt.x -./Jc Sp~"' lv,c:.\u<U!,
~
@:
he::: Ad'-:: Az c...l ~\'\Y~
bc.t:Aw\~
Tu box ,"i, eiw,1,ial.JAA.d aA a D-- wbic. bo~ dcrubu.
IOY)~ - O vt~ ~ i'½

£ ;:: 11; i.,2.. ~ ~2. lrr l. + hi J., 2..
f<."IS M
~ ,.,,,t 2.. ~ t:.-hb::.-.
om
8 rn .l :i. s-mi.)..
- {~-+ ~2+l1..£} h2.
.c
8-M..t. 2.
C
B
yA
tr
is
!::
g: c.tYl~x, .Stn Yjf! ef' Sivi >1~ Tl z_
-
m
....t ...(_ .....t

he
-1
.c
a [ ·., ,1_3- V = Vo/u Me_]

w
w
w
~12..t~l (1 13,.2-) (g,1,2.) -

(:i,1 1 3) (.2,3,1) <~,h~
€ .=: 1LI ~ "2.
-
8TV)JJ.
®
( 2.,.2,.2.? @
0::1 E.'= /2~2..
&.mt"l-, e
3:::~ (3,,,n
t::. "%,.,,1.. 0
a _3
C
{_!,~ t l)
@~ 2.,v
( \, \t3}
(2rlt2.}
--.
( (,2,2;
t:= -
qJ,2...
&,17.2. •
@
3~3 G" = 6 h'2,
rm,2. ? lJl2,1, I , ~'I' @
~I 12-) (l12., 1} ( 2, 1r 1)
t.pI, II 2-..,__ G
~ ,z 1 €.: s~~
98 ( Download
'-, 11 l} all notes by clicking here- s·,rn 2. ~
CJ},, I, I www.chemistryABC.com @
•
e
€)
G
@) ha.ue.. .3 ~rrYa, wi-tJ,, ~We
(}1
71 1
C:: ( ) ] <ammo n d eqen"<t"qat,.
(1,-rJ a o
(JJ
ls,sJ
@
e (__,,,J(s;,s) ~ (1,7),,Lr,~J~ lfccldltJral
om
(-;
,, ol1e>1r~
0 111
--
3D
.c
0 C
B
(]
A
(0
y
tr
0
is
Q
m
he
.c
w
w
o-1-t:, D<:10
w
I - e..-2 D ( 2 l) 1.-,.. 2D ,+I)

(:g)
@
€>-ro lD
f}.)
2
(f?, - l---e- ( 1/_-t 2-ft)
@ l -~e-2.
6 -2-
e --- /- 5 (2,7)
@
••
. "' :* ·. ·~~f~ ~ftll _,,
?1::. ' www.chemistryABC.com
•I
(~d."10~~
jJ.
~~ t.t"'-.~)
H t-4<.+
u-++
8 <.~ +-+
z:. 2.
z= .3
-z. :::. lf
•41
t
8 u.+ z =- 5
I
i
1vi
i~ ~
3--D mb ,t;Ul1 ot- po lo.,r C.o -c.nrdt'Vl.a:tf!. ~ ta.pta..t..1.aJJ,,J 'i?e.,'lJ" c:tlo.....- "' .i..
bd A.tf'o...tlnd"
•
~ ~ -'i.... Srn a .Stvt cp
Z::::...A™e
l\l\ lctp 1(tC.ta.YI cpe_,sa.fo'"lr 1; LQ..,sf~b.l-i C.o-o~dl n~, g_ l ) J e _ ~
om
±,. t,._ "-.,_f,._ + i-s1 n -& .sl111. + ~I ru, ~~
.c
",,_ = tJ 13
C
B
T111e.vi ~Y\d:t~ will. be.. ,
yA
1i 01.Jh, cpe-~ o " t~ ~\A.L~ 1 -'..1 iJ i. ~ Cb -ols"d.u,,~

tr
is
OtJ1 i;onctfCJY?~ et.Uo d.Lp~ On Ate ,4 CJJ ... 0'1SC/J11cd-a

m
[ H~-:;~~+v]
he
.c
V::: - Z~ 2.
w
1.,1,f~oA-
w
w
~
~ Stv1'~J..
( _L J_ ,,t~;L + J_
A.,_ a.. J1,... ,,t>·.sl ne Je- J&
+ J__
A '!£1n•e-
J': ) lJ-1
J ., •
+-d2rn
lA ,e, ~} ,t.,•
{e f z.e2.}
t/.f"t,
1
~ +./°;~
~
•
@
®
@
@
•
...
•
\" . c'. • . i
To dJJ.:.C.'lrt be. '1 ua\lttt.> M me.cl!!· ,g~ 1 ·~d,of"Y' ·L.i. t<..~

Apecleb
@
•@
we. "'u.cl a_ ~V\d-i:M.. 4? wLo.c-V\ de.~d,.,
( 3 -lt>-o ~dk.ah=sJ. i ""udu.t.A e ti:) fFr e)

O'Yl ({j t111d.tpe..nc(~ va.u~blu
~ ·-
~
@ I tp = I/'.,, 'Pe J
@
@
lf'Yl oli.ff!htcM 6Yl ~diviccfe. 'i ~e_ <fi ma.j~ ~ <Pe... ;~ Ctvt?6tdifco{ ~
Ci hJ-~11al (!o-o,soil~a , .SZc.ha-o~~ ec,71 ,ll<?...pe...~ flA:b:) +wo ~

(; Ok.l ifJ.... rnu~ &.Qlr\e_ 7)°~ C.
@
-nil f'.._~C.~11-cdlll\~ e&f \-1 1- € ® p lo:r- U>-01rdl\'\_cd~ /2 I e, ~ q,
/ ~rvo/u~ O
@
@ {1.J_ t.>t,d:tovt Ile. d.t~d~ OY1 A-- . ~~e ~ p ~ °i. wttue. [j C21:n1 11
m
i!.";s_,
o
'0
.c
€) C
B
-==-7 4-'n,MJ.
yA
0 Ru~ 1 ::: Rv,7..l :!. Rvi,..t '-1,t.tfYI

(] " LB1 ti)} :: Y,,l_,M
tr
dt.p<M.d~OY1 l'\~,.l, pccn11t±d vtlu.J..°15" /')'1. t/2 1, 2;-3 . . ~- ~..L 11:, o-to n-J
is
()
pomOl'lal -to
m
© ~ -rkA- \J c:tl.u-L. 6ir R 'l'I 11- t,s ~

he
®
.c
@
w
@
w
e IJ...l_ ./- I cl ~.J.+I

w
who-e __..:; /e.u3eirY<!: p~nomit:Jl. :. Ln+A.

e L~H-1 dtif"-:+I
e d-.,-,..1
G l""' +...t ::: et'.. e'- e- e
cl ~11+..l
e
~ - e -::::: ~z.A.
G '1.1qo
•• IS- '11::: l J.-::::..0

L2.XD+I - L,=&Y6U-
t+o
l
L,<ilb.f) = L~ ~ {2~)
-
• 2.5- }'l ::. 2. ..t:=-0
2.+o )?qG
• 11 = 2. ..e_:::. I
~ -=- ~wdl.
• 1t-
www.chemistryABC.com ',~-
••
ft1,0J
•
@
~
©
•
l R .. N e.-A./q, l e
@
Ro.dfoo ~ 1 ~-
om
.c
C ~
B
@
yA
@
tr
®
is
©
m
he
(Z:
~t:.t4lPtpcut:°b 2p- @
.c
w
'Yl =- I @
w
.l-= I
w
{<.. 2., ( ®
GJ
~
G
•
®
®
~
••
DPP 8 Quantum mechanics

1. Compare the difference of energies of the first excited and ground states of a particle confined
in (i) a 1-d box (8 1), (ii) a 2-d squire box (82) and (iii) a 3-d cubic box (83). Assume the length
of each of the boxes is the same. The correct relation between the energy differences 81, IJ.2, 83
for the three cases is June CSIR
(1) !J. 1> 82> 83 (~1 82=83
(3) 83> IJ.2> 81 (4) /J.3> 81> 82
2 Consider a two-dimensional harmonic oscillator with potential energy V (x, y) = ¼kxx 2 +

¼kyy 2 • If'¥ux(x) and'¥ny(Y) are the eigensolutions and Enx. and Eny are the eigenvalues of
harmonic oscillator problem in x and y direction with potential½ kxx 2 and ½kyy 2 , respectively,
the wave function and eigenvalues of the above two-dimensional harmonic oscillator problem
are Dec CSIR
IJlnx,ny == IJlnx(X) + IJlny(y)
(a)
m
Enx,ny"" Enx + Eny
o
.c
IJlnx,ny == IJlnx(x) + IJlny(y)
(c)
Bnx,ny == Enx + Eny
C
B
3 The difference in energy levels of n ~ 2 and n = 1 of a particle in a one dimensional box is 6
yA
units of energy. In the same units, what is the difference in energy levels on n = 3 and n = 2 for
the above system? June CSIR
tr
(a) 4 (b) 5 (c) 9

h;~n (RH = Rydberg constant).
is
4 The energy of a hydrogen atom in a state is - The

m
degeneracy of the state will be Dec CSIR

he
(a) 5 (b) 10 (d) 50

.c
5 The energy of2s and 2p orbitals is the same for DecCSIR

w
(a) Li CtS}Li2~ (c) Be2+ (d) Ir

w
&}If the ionization energy of H atom.is x, the ionization energy ofLi2+, is JuneCSIR
w
(a) 2x (b) 3x (c) 9x (d) 27x
7 Which of the following is true for the radial part of the hydrogen atom wavefunctions Rn1(r) (n)
principal quantum number and the nodes associated with them? Dec CSIR
11-J.- I
(~ The radial part of only s function is non-zero at the origin ru;id has (n-1) nodes.
(b) The radial part of s function is zero at the origin and has n number of nodes.
© All radial functions have values of zero at the origin and have· (n-1) nodes.
(d) The radial parts of all s functions are zero at the origin and have no nodes.
(!!he most probable value of 'r' for an electron in 1s orbital of hydrogen atom is

I l"J_
'{\/'I"'-
(a) a,/2 (b) ✓-)~ (a) 3a,/2, Dec CSIR
9The orbital with two radial and two ~gula~es is - ~t Dec CSIR
(a) 3p ("1'5d (c) Sf (d) 8d 'V\.~
~he hydrogenic orbital with the form of the radial function June CSIR
r 2 (a1 - r)(a 2 - r) exp[-pr], where a11 a 2 and P -:::. o @
. '1'\-:.i.-1 (O'
Are constants, May be identified as a
(a) 3d orbital (b) 4f orbital ~ d orbital (d) 5 f orbital
0
1 lA hydrogenic orbital with radial function of the form r exp[-~r] and <!>-part as exp[-3i ~]
corresponds to June CSIR
(a) n>4, -l'.>3, m=3 (b) n>4, f.::%3, m=-3
(c) n>4, t=3, m=3 ~=4, t=3, m=-3
12The angular momentum operator Lz = -in. :i/> has eigen :functions of the form exp[iA~]. The
om
condition that a full rotation leaves such an eigen functiog. unchanged is satisfies for all
the values of A. Dec CSIR
.c
(a) 0, ±½,±ii, ±1, ±:;, . . . (1,J'O, ±1, ±2, H, ... ..
B
C Gr;},,:. {) ,,f:-1
1
f: 2 . • ,
1 3 . 135
yA
. (c)0,+z,±1,±2,..... (d) o,z'z'z'·••H

13. If the angular part of wave:function is sin2 0 cos0 e Zi q, then the value of 1 and m respectively
tr
are Gate chem

is
a) J1/ "73,2 c) 2,3 d) 2,2 · · ·

em
.id,.,/ ~he un-normalized wavefunction of a particle in a spherically symmetric potential is given by

4
~ w=. zf (t) where f (r) is a :function of the radial variable r . The eigenvalue of the operator L
2
h
(namely the square of the orbital angular momentum) is Phy .

.c
. (a) tl/4 (b) 0 (c) n?/2 ('E!12ti2

w
· ~ven that operator Pr= -in[(o/or)+(l/r)] the uncertainty ~Pr in the ground state of hydrogen
w
atom is ._
✓wao
w
b) nl2ao c) 2nlao d) OPhy

fJl!:e normalized ground state wave function of a hydrogen atom is given by
'1'=(1/✓41t)(2/a3Y2)e-r/a where a is the Bohr radius and r is the distance of electron from the nucleus
the expectation value of <lie> is Phy
a) 4/a2 b{2ta2 · c)4n/a2 d)2ru'a2 -
17. Consider the statements

i) The normalisation constant for radial part of the wave function for the ground state of wave
• • .. :2.
function 1s ............ N-!:.. ••~~~.2- .
ii) The normalisation constant for the angular part ?f wave :function of Pz orbital is .......... .
iii) The presence of radial node in:2s orl>ital ofhyqrogen atom is at r = .. ~ 8 .••••• -1

. t•':T}•·•'/l:'~1-~:J~rv,/ivt>,. lrl ·#-.,,;?e ·~ ·~pfneul d-ft tief,J~
. ,/YI oit,eMfr,,,.,, -ht,?tOV'f'- 1ic.t arn r www.chemistryABC.com
[ Lz=~
(\
to -v ~ -f1J,/2--vah.,.,.t_ lz !::. m,J, Clff '</ Lz Y,,t,JVJ
/'.,,, V,t.,r,,. "- -w r ~;.,10119 ~'--l"'l0 e l111~
-=- Sn,
- trvrJ
.e
[JJ,,/·--/Mlr.
(:7
-l~[ ~
J e tmp)
J . •
Ll\ff4:)
om
-= mn ( ~it, 1MI ~-{-(Ml~ e,
.c
........
C
B
y A
tr
is
m
he
.c
w
w
4! C A.G,~etflt}
w
,Sin°s ~g 1€:} e 1" <> ::. s,t''e ~ l-/rnl e. i1vJ~ .

J. ::; 1

·1tt~·~~~· www.chemistryABC.com
'-l1 = A...(oC.-A-J e- ~q 0 · Sin G "'1.&·e e. bf>
€
L2.
Lz
,11or &' Ro.dial. .no¼
140·.- ,r <:t n9urc~a noelt
41,,. '
Palrl:.1 bu.. rttjd~eMU: ~r:;,eci~ I.Jarme.

--
Sol'l1 ➔
.
"YI ::: 4
~ iVI~ - (-<.J. J .::-n
,,1.. :: .2.
om
m ::. I [ }t.::o(}
.c
'Y(-;,.l- l C I
C 'n::-l/
B
yA
- Zlu · - · ,e~~ae
e ht"?o -
tr
is
-- _,g.~ (u., -- 2..

m
.
L4) l-
he
Sr t .e V .
.c
C ..._,/
w
. . 2-
w
. LZ...: ~ lt+I )4f

w
~ ~ ~+I )-J, 7-
Ft C t;-,;iJ
lz. ::. m#
0~37
- l t;
f .,1 ,mr/47;->-,adi== j_ J
@

• f<aP,td. 11liill.8. - . ';fl)
.... ~cl( f/ltl ,f:Qh'f.r:vr1 W'.\. . Tlf' ~a• •~~';"l~C;,,,paf'' .
•
@
~ ,s] - R~. o~ paJJ- o-6 w&J,_ ifv-il<HU>i=d . ,i_
.o fr ..'.:,
•
@
N. e 'Y'llo-:::. --0
G N 4=-0
@) -=J e - A/'4 ~ o
i)
•
0
.e-""/41) = e-di>
e
0
@
e
f)
om
0
.c
~
() C
B
yA
0
~
tr
e
is
m
C
he
e
.c
@
w
©
w
G
w
e
8 6J1.e__ /../>d 1°al. rnod.l 1fn5 2-_s
:[Ei]-
•
••
••
•
•
(J.Hle,n W'e. t."l..fe.,m -ftu.A !..&.ih ~ ..u.dAI fa.J.i- '>f ~C'. f,n,Ji;,, www.chemistryABC.com
to?f 0
V(W. ~ oybf;a.l' w~ I'd:-- ~ A.r,,..t:llJ. pa.if°' -l;v nd-,m

bc..c..owt,q -u.>,..e) ( "1 -,.{_:_ I J -H M-€&
at- A-=- a
m
-9 f<Acllo.t fXl-A-±- "1r i':v,cho-n r~
R111,I 4 ,u
o
11.°"'---LtA.e>a:l- ~,},n,
.c
1. ~ J, ~ 3 •• , {,f.-:.#,o, ~ p,cl, i-o-cb'rfaib) C
B
yA
af A_-=..V
tr
is
R11 ,rt:::. o
m
==? Radl'a-l pct~ 1 i°"'dtG),) ~

he
-u..A-0 Qj- '1s°"(fn

.c
C'.) t
w
w
w
it A..-=- 0
it o(,r--A ::: o
t1f o<'i .. ti_ .!::_ O A.:::_ o(~
i6 e- 81r-=- c) .A.:=.... o.D

.-t(. No-zrm4ilud-itn1: C.n,st!. 'F- ,raiJllaJ ~ 1 t.,JOJJ<_ r.d,<m Jo1t 'tJ~vu>I &~-e.-· ~
•@
R1,0 ~-Ajqo
•
Ca(
@ R1o -=-- N ,CA/ao

~
(!) f R,,o Rr,o aT:::::.. t
••
(;:,
fe
0.0
() N 2. ~o ~ 2-dA.. =- I
@ 0
I}
om
0
.c
~
e C
-
B
N2..:::. 4
C
A
qa.3
y
0
Ne 2
tr
(J ~31'.2-
is
0
m
he
()
@
.c
w
@
w
e
w
C
e
•
D
e
G
••
•
••
: .. . .,' '
'!1,v/tU1 paJJ:-1 ,tAkWe tvvidi6>1' Yf_ e- 1 q;) 1/:. d..e.feM..qlL,j.J CM e ( tp
e rald-'i L,u-{iu~ -tun~ ~ a l Q}1 ,l_ ~.!:::!... -~ f fa.d1-

wo..ue_ -tv11cficrf1 ~c/(> em rYI OYl~,
B -t;unc:HO'Yt Cltf0tdr, ~ C1Y1 ma.gn,rvdJ 9/ m, cltJ~ nc;f- d.JJCot°he..

-/1,,J,_ a11 .,.wbdY! , wt,; u/iJ4,
Q
t~ :;;
~-/m
r;;w crv,.aJ -ki
Y1., rv1 0( Sfn e ~ e e lMiJ>

T
)._:: o
om
l'Yl::::.Cl
.c
C
B
-;
yA
I
tr
CJ
is
m
he
.c
w
w
{i) _±!:._
w
R -::_ l rv?-= (J
). =- I 7V1::. +1
)._ C. I m::. - I
\ ( ,h
'( ,,
1
::. N.S1v,0 e -r
j "'11~ Y,,' clT

r:,.,. s· ~-·.,,..
•• .. .-.
/:,;•r~··~"
'\:'.~·~(""". (/1".i,/'{X: \
'"'ff,,··:f
po ). ~ l I mfD v,,o ""( C.&0- www.chemistryABC.com
,;
.s,~ae.-t+
•
0
~I
,.l.
-l e
::.
.I
l (VI
M=-tt
~--1 Y,, - I
\/1, I C(
a(
Stv?B e iq,
f'.J- I
-0 ,,(-:..:2..m=- I 'I 2, I °( St ne GJ,&a ~ ;4
@. 42 t
A_-:: 2. fVI =-l V2,-r o< .s,ne ~8 e-t<f,
0 cf...,
•
(fj
cl 2..
c,1_,_
.,(_
A.-=-
-- 2. ty1::::.2..
2... 01:::-2.
'I- :2., 1..
Y:i.,-2.
o(
e(
.S1 n-2~ e 21 4>
S; ~ 26 e- .2.i4>
0
cio -'-:.. 2. M:-:.-0 '12.,0 '"< [<3CD&'G -,]
0
0 ~ 1fw:1 1fAL 11a.lut 1; ?1,~,m 1 1f cr i1te 1fnc:h(J'YJ
om
0
.z--~) e-.ijA., Cose
~
--
SoJ'>'I - f.Jl,..,,,,1.,m o< (
.c
CJ
+ C
B
()
yA
Q
tr
()
:z. ...& ' : : ._ 0
is
G C{\'.>
m
~ ~ :v-?a J ~ 'YI~
he
e .c:;7 "i1 ...J.. -f -== I

.c
e
w
'11-- I- I :::. I
w
G
'YI-= 3
w
e
6
••
•• · OPP-%
8
&. -
•• ~ -=-3 fog -l-ln,b
• ::::..UM oli
••
·-\~ $t3-n'tffoorttL 1· ~!~; ;, ,t.im_ -- -<
(i) 71,_,. Finuf~ 11X4rlom -ns.@ aluo.J.~ -tt.e.. =~"'"'la , ..,- iYJ
~cl~ l.il,c /2pe-u~ a_rd_ Y~ ~fueNt bt
t .::.
15 ~
om
~
l?i:.. 2- 2s 2. p u ~We
(±
.c
J.., _I q ,,!,~
'}'f ;:._3 3S 3 t' 30f @
~i
C ~
B
-'n==L-f t4S Lf P 4ol
yA
8
6
tr
is
@
m
C
he
(§
i
.c
/2.111e,so/t e fV\ Mtjab-0·?'¥7iG o.;kum ou.r,evdt ~ (1Y1@ 'nof O)t) @

w
m lf'e ( d.tcbmic 1;-:nrsbOYJ) w~ ~a.~ va.J.11 o 1J- @

w
,t g__ ~'-'S cul

. fP"'I(' &zr bf--tc,..t ~
w
@
'Y\ bu±--~ va1u_a_ °D ;t ~ rvt u~ dqffl!ra±-e. J.e. ~
tJ
Vtt::Ne ~0.M~ --e....'n.-e..~1a, ~
(1,vs ~e
()
~€.Y\TO~ °fr- Ocn!>rfa.L t'?( 0r-v~ vah.J..J.trf- "Y)
@:
@
II::. h. 2-
~
w kJN1 /S €= --e.2.. -z.2.. @
~ 7fl:--,,qo
~
e :: - e-2- -z..2-..
32. /fro4o ~
fd..::.. --~2.., -z_Z ~

"12.-/f Esq fj @
•
• 7k rr+o/ ta:_:_., . 1 q_Tsf- ,., ~ ~..,,,+,),,.,,.~ /.;wY) ...
•• tf- ~ COl1Aid~ '1li\a:t' ~c. i;d.d ~ l)t~C
f d.d QM Clw,,f~·
®
• ob~,
1/; 1:f'ln
.
1 -tt,,,__ C CU&o lr,clvolu,/ -it,e,,n dJ-rnry he_umre cl&V6~
.
€)
€3 {Jn= 2n
2
"J ·
•
© @ - -Z,O q,u l8irr/Yl)
-2. O Q.IJ = - 0 ,S' Q•l..f z..2..

}'\1-
om
.c
[ETI B
C
<il) - '.3. lJ e.\J CJiV&n)
y A
(0
tr
is
0
m
0
he
e
.c
0 ::. LI
w
0
w
e @ · w a21mut'1o.l t.Ja.M:ftJm
w
l\Jo. d.tbc.,rrbe -fhe -1u1-a1· a.Y!tukl-a- rnon1e4.du Mo-tr,

e 1
® e -tvnmu~ n. -tvte ~r~ ;a)'?
® c- = 1. C.t ,,., )112...
€;
~
11d -va!u.l_i,_J..,_ _,___--e:. cl.tAived l"'y(/M Afe_CMJll tif''c.. ferm
0 S - - .S.~a:irp
@ t p - p-tfnc.t pal.
® 2 cJ - cliifp.&e
®
3 t .-- i;vrd4me.Yrkll
.e 4 'it
~ h
[: 113
6 1Download all notes by clicking here- www.chemistryABC.com
'··\;':'.. · , ' ,. ,,
~ ~ "fr e· ,. c:. ,L(),i-1?,ti'- m.cf liLvoJft hi/ ~"J' il,,c_ www.chemistryABC.com
op~,ra:knr '1 12- OY\ ~ WCLU('...,if~dtO"VJ a 4-1VJ,..t,m cm 'ft.,rv,

1L- ~~ p Mdt,. '\)~Alt i/2 )_ ( l_,1- f}-;? 'l-
z-:2- C [ J_ J StnB J -+ J__2

Sit?e Te "Je 1J Bm kJ4> 2 J
¥0,0 ::. () v,, 0
..(::. 0
M•~
Y,,-o -=-~~2v,,o
.)_:... l
om
m..:::..o
.c
C
B
yA
tr
is
m
he
.c
w
w
w

.. I
DPP 9 Quantum mechanics
Lin a spherical polar coordinate system, a point A at (x, y, z) in the Cartesian coordinate _system
can be described by (r, 0, <p) where r, 0, and <j) have their usual meaning. Expression for the
volume of an infinitesimally small cube confined bydx, dy, and dz in terms of the spherical
coordinate system is given by . . TIFR 2012
A) . ~
2
drd0d<p B) rsin0drd0d<p C) r2 sin 0drd0dcp f1J r2sin0drd0dcp .
2 The degeneracy of the energy level 12hi /8mitof a particle in a three dimensional cube oflength "a" is
',olefi B) 3 C) 6 D) 12TIFR 2012
3 What is the degeneracy of the energy level with n=6 (n being the principal quantum number in
a hydrogenic atom or ion? A) 16 B) 9 e,1"6 D) 25 '3'1:::
TIFR 2013 111.
4 Which of the following statement.is not true TIFR 2015
i)The state function w(x,t) is always ~ual to a function of time multiplied by a function of
I
om
i
coordinate. f
'
7 '·
ii) If f 1 and f2 areeign functions of operator B then C 1 f 1 +C2 f2 must always be an eignfunction
.c
ofB. where C1 ~nd C2 -are constants. 'F.
iii)The operator L2 commute with Lx + Ly . T
a)i,iii (b) i,ii (c) ii,iii (d) only iii C
B
©our particles of mass 111 each are insid~ a two dimensional square box of side L. If each state
yA
obtained from the solution of the Schrodinger.equation is occupied by only one particle, the
minimum energy of the system in urtits ofh2/mt2 is ·
tr
(a) 2 (.wf'S/ 2 (c) 11/ 2 (d} 25/ 4 IIT JAM Physics

is
6The ground state energy of a particle of mass m in a three dimensional cubical box of side L is
m
not zero but 3h2/8rhL2 • This is because 'TIFR Physics 2015

he
(a)The ground state has no nodes in the interior of the box. (b) This is the most convenient
choice of the zero level of potential energy. (4-f'ositionand momentum cannot be exactly
I
.c
I determined simultaneously. ( d) The potential at the boundaries is not really infinite, but just very
w
II
,. large.
w
7 A particle is confined in a 3D cubic :well of width L with impenetrable wall

w
! i)The sum of the energy of third and. fourth energy level is Gate P
2 2 2 2 2
' arlO 11:2t'i2/mL b)lO 11:2ti2/3mL c)l 1 n ti /2rnL d)l5 ·n:2ti2/2rnL 2
ii) The degeneracy of fourth level is given by
a) 1 b)2 tj'1 d)4
8 ln an hydrogen atom the coulomb degeneracy for the n=4 state is Gate P
a) 4 iefj.6 c) 18 d) 32
9 An atomic state of hydrogen atom is represented as \j/=(l,12ar})°-5 [1-(r/2a0)] e-rt3a0cos ® Where
ao is a constant value The quantum number of the state are Gate P
a) l=O,m=O,n=l b) l=l, m=l,n=2 ef=l,m=O,n=3 d) l=l,m=l,n=3
10 A particle of mass mis confined in a two dimensional square well potential of dime~ion a
.This potential is given by V=O for O<x<a and O<y-:Ca , V=infinite elsewhere
The energy of the first excited state is Jam P

C
" .
. . r .
2 2 2 2 0
·a)n ti2/ma · "b)2x2h /ma 'eI51i2tb2ma2 d) 41t2h~1iipa2 . . ·

<(DThe grou11d state wavefunc~io11 't' of hydrogen atom inspherica] coordinates has no angular
depend~ncehutonly radial dependence The 'I' is an eignfunction of Gate P
~k,Ly and Lz simultaneously b) Lz.· but not of Lx. and Ly
c) none ofLx,Ly and Lz d) Pz only
12 The e11egy of second excited state of the hydrogen atom is
a)-27.2¢V b).;.6.8eV x{.;.1.5eV d)-4.SeV· .
13 The one.electron states for non interacting electron confined in a cubic box of side a are
Eo<E1<E2<E3 ...· . )
etc . .
i) the energy of1he lowest state is . Gate P
a/o\.,";_ ,Cf : b)1t2ti2/2ma2 2
efx21i
c) 11:2n /ma2 2
12ma2
ii) The dege~~racy (including sein) of the level E3 is
- a).2 · . :/;b) 4 . ~6 - d) 8 • _
m
· 14 An electrq11 in the Li2+ atom is in a state whose energy is -3.4 eV the degeneracy f1f the state
o
is a)4 : ,b)f6}-e,36, d)'.11one . .
.c
15. Tµe nurp"b~r of radial node of the radial wavefunctioii for an atomic electron R(r)=A[2 7-
, · ..· ',' ··2 "Y'~r/3 ::· ·" . . . . . .. . . . . . .
18r+2r le: is
Gf2
C
B
a) 0 _. _· _·_ .·..._.·. b) 1 .d)3 _
16 Thef-a.di~fwvefunction of the.electron in the state n=l l~o in hydrogen atom is R10=(2/ao 312)e"
yA
r/a0 ) The ~b;tjpfohable radius for r in ls Orbital of hydrogen atom is Gate P , C ·

tr
. sef1~o_,:."/.b)_2ao. , e)4ao d)8ao

is
·11. consiae~~tlle"statements
i) the taaiJtpifrofwave function of S orbital of hydrogenic atom is nonzer~ at origin because
m
radialpart}i~containing of r! terms.· i
he
2
ii) The :aig~Abritcy corresponding to energy value -e /72rr.so ao for an electron in an orbitai of
hydtog11fat~iµ:is 9; 1 . _. _
.c
iii) Ifari;tlii:if part is c~mtaining of only cos0 'term than the value ofl=O . C:-:
w
-The.ctid-~9F~temet1ts above are 'a) I~ii b) ii,iii c) I,iii d) an e) none

w
HPWhiiillofthe/~llowing.function is acceptable for an electron in hydrogenic atom which

w
motion is go;enied by polar coordinate (r,0,<p)

a) ·e•rtr · . b) e-rcos 0 sin0 sin( :ej>/2)
CJ e"r sill(htj>)\, d) e-rcos 0 sin0 sin cf,
19 Fillin the blanks
i)The eigenvalue corresponding to kinetic t;:nergy operator for an electron in 2S orbital of
hyd:rqgen atom is ..... :$...4< .e.Y.. ·
ii) The most probable radius for an electron in 2p orbital of hydrogen atom is ..'i4..;.
iii) The average value of radius for an electron i11_ 2p orbital is .......... (higfiedlower) than the
average value of radius for an electron in 2S orbital of hydrogen atom
20 Find the most probable radius for an electron in 2s orbital of hydrogen atom .wave function -1
corresponding to 2s orbital is given to yo'u. _ 2.90

•,·_ ' ' ;~~: ,~r1r -:: :;!·
FW
1
. ;,:,•;
--- • .
t-,2.
/4-rv,q 'l-
• si, 2 -
. , ~ma.')..;
A.!:!..'l.. .·.
&Ma:i-
. .
:2 ~2. + 2.. ~~2. + ~ 11,2...
Q-WO .i.. iMa 2. 6 MO..)_;..
prc~"lr\al A t . p i s ~ ~ °'b -11,.L avtuk:\,y; .~ 6b w~ue ,to111<.h°ow v1~

wt* o b~eo:z.- ;l't" ~ 1M-1a1r11 ~ t~ tt, . . ._ . . .
m
MfY~ i-°,.~™,O,U~ -
o
So +o _ ~~al ~p...--d.c:..t..da:h~OY, ~e.:J:~4.u-e_
.c
tMi'~~11- r-,a,J-· ·bd 4Cl~lll\d· ~ - c.e>n,,ht°11tah~ 1-wa.ue·t,J/\cli4l?
•&-rt~ia,Jc_ C/DJ1~f~atr> (_.1))~n1¢h<(>1 ln'Z_ ~ubAh~d-,~-- 1f ft-uo.11-ll'f'J
C
B
yA
tt::M:~ :;:r~1:;:~k:,ot {~:h,·~···~~~ 0

tr
is
q - .
~•n
. ~~~M 'It,, -+ '-l, 1_, --= Si t-1 C)e_-f f
l.},.. ,1
·
, I
.·
m
el -'-
he
. "'
s,n G- el t +c-lf
.c
l
w
w
w
eiMf :: ~rVlf
--~ -tl1i/4 CJ:J rv,,..;na:bon w~ .~ CI.A,dfr,.p,Je. . _e-tr11p =- Sirt "'1 ~
.e. tMtf> =- ·. U..&M1
-e- tn1~ -:: Sinrn r

~ .... •~
-x :ts, V1 e e,,~ f
fj ~,.,Ii
@.tl,f +
-z.=•~e
- pz..
.,_ ·
P~ ....,,,~, o1. s;vi0ci+ - s1V10S>14> _.. Pt
1
s,"' ec.&e u.L c; cl';)( 'Z.

Si"vH~ Me, e. r~ -
c.
a, - 'I .2., ,.~
SiVle CJJ).,8 e--

1• - Si)18 Ct,~ 0 Slvt4> :: . cid'z.
~
ol-1 'I ;;t, - '
_,
om
S. iY"t 1 B ~ :up c.bt.2.~ t11..
Sh\:l-G ~~l~ -
"'12.,2.
-
d-2. o(
.c
St1'\2 f9 c ...2.tc)
S.i ~ 2.9 S111t1.q ,- cl~
'q_-:i.; .. 'I :2.,- 2.. -< C
B
yA
l.LV\~
Avlt>lo.tlff.a.>k
e&Y\"\'b\~
4& l>,)Q.V C.
tr
is
~· l°n.dicm
m
he
0
.c
w
-t I
w
d::: h,.Sin.6 lV(kJ) o(Sinftwtf

w
'11,,-Yt;l S.lvnp
'i'r,-i -< s1111ee-i4
-\ o{ Si~tStV1~
\
'1'\0+~
M '2G ~ ~ell ,t;sc.&2&-J
'#2, 0o( g Cs,,!>'2./!; ... , --to -z:.. '2-
L 0
Si'1e-<6'd> (~~T-j ~s,11&C.S
'h,1-< Si'lel,g&e.ict .•.
'\.J-.it\ ,t-'12-l
o( .Si~ e-(J).&~
v:::,l-:z_
Ctz,g,,,
2 \ -t
' '12.,.-t•< Si" 9 C.&& ,r f4'

"i2., 1•Y2, ... I . +e.-tc.U. fo fvc\~~
.
Si'!"t.!i
o(
s,1114>
.2.. -t
K s 1vu~ ta>J&S'itt.i ~~
'l:z,2 + '12.,-:J.. q :x?--'d'J.
(9'cJ-x~tfy si,,ti"-,
1 oe. Sl n'-!J e~itp
:2.,:::)
-+ '2--
.z ~cb~)-< Si .,1-~~
1,
"V r,;,. o<, 5i"'-a.t,e__..Jil 'I 2,,2....'Y7-.t-2

118
2 . .
Download all notes by clicking here- ' www.chemistryABC.com
t· .... - 2. .
.
,w,llo.l,. ~
·- ,-Ji".-
" <ii: Plo\- i 1 IA.kW~-tf~ - www.chemistryABC.com

@ '
e (tJ
0
Ra,o vs A-
R,,o
()
11!, vJl!M we pl.t- -tw ~,,a.pi, 'i -r-aill.L"al pa.JJ-"t -f;mdi'm vs A.~~
® -ttA«t R\ I O 0. l'\cl -\11,e d WiA~ RI;';; IA ,wl.'I.fMU M a.f- ,.{..!' 0 ( a:.f--O 'g°'iJ.1
CJ (~ r Q.V\ £' ivt IS o-rbt-fal)
om
go!- t+ do~ n.or ~'"\(tbe 1'11\e. ).J.DL p;c/:t)-v-e..
.:!Yl ~ r., O."'f ~~
.c
7o duc...-ibc. -f1,,..e. roP'lbtlt1 1 f~
C
u.J e pl.-+- Cl ~ -.q rn
btw .t.Adl"hl ci..ll. t.i b.JffUYI 1t V! J:f'rn { )._ R2,, oJ V fS ),..
B
2.
y A
~ r-,-.oh<IPi Ll~ 'i 1 ii~ e-

tr
.41, t,..1e l<.111o-W

is
0
m
t)
J j ~(/.! Rw</1,. "-- j /.'-R"'cl1>.-
he
P(!.)dl.. ::
.c
r0.0~ ~R3
w
w
w
MIi&~ P"" l:,ct bl.t. cUJ.,-\M,CL L --n,.,,_cLll..+a.,., tt. a.I- w 1,u"c,I,, tka. p,o ba bf I.A~
11 ~w:U.q C\n € iY1 a "1 o..-bi!to.1 l ·v., ,w,.11in.,0111 J m~ be
o~ed bt a.pp~tYl. l'lll'\1t.imc:t qa.,d Mtl"irrvtcr GmdJ.._,_,(1)1 dYI ~DF

0
PU,, r-'i rvt4)(t n,\UWl iV\ +e.irM 1- "-- avi~ w~€.11,,
~ PCA.} .. o
--a-;:-

r '
I
www.chemistryABC.com (I
~os+ 1~ohohu.. '

t
i
~1Cll>1 UL
I (~SJ I
'' ~
,,
~
4 A.,,'L eZ-1/q
q! r ,,
IAJ~'(',t w. "'(..t,
om
1ll:; ~~
.c
C
B
yA
tr
is
m
he
l/
.c
w
w
w
Q:q.J
120
[1..~p= c0
•
®
®
@
@
@ J[i,r 4'.l ,O, 0
om
(j Rz.,o
e
.c
0 C
B
@
yA
0
tr
G
is
0
m
e
he
•
.c
w
0
...l,
•
w
w
•
• l
••
•• --1 Mo).,~
"
p-a-obabu. ~s-
(_R,t>) : Je -½qo -!;.Qo e-A. I:.
• j -t
••
•
•
t 121 Download all notes by clicking here- www.chemistryABC.com
~ .. -~~::. · ·· ·. · : -:rfr· · ·. ··\,-
~ a.
J~~,. ~'N-M~
l •. . .. , • c
l+.'fl.:;o v/s A-· I
-----
Mo.S.f- (>ToOQJ.,l.t. d.iJ.~u.,

1fir R. 2., o M°f be o bb.1111 eJ
bd'-
whe.n we ~oPv~ ii- we. ~

...t::. 0
..\.:: ( 3-- Js )q0 - ( hn,e:t mo..~tMQ )
om
A :: ( 34-fs) qo - ( ou:h:.Y Mt\'X.11\10./
.c
A.::. 2qo
C
B
yA
(t=,-oirbi-la.l)
e''
tr
is
-< A e-¾q.
m
R.2,1
Cfo
he
.c
w
w
w
A➔

/'!fl/"
•
e
•
~j
N 'Z -A,3 e -..t✓-
q a.
rq.
D
@
@
w :: 0
®
[ ~=- 4Qo]
C;,_~,, =- 4~.J
om
.c
~
() C
B
0
A
r, .,..,.,., "
y
'
tr
, I
I' I
0 . I '
is
e
I ,·
'
m
I
..
he
0 ~
• /I
,
t. .
I
,
I
h,.~1,o I
'
0 ,. /
.c
\
f
I
w
e ,...... '(2.,:,\ I
•
,
.J
w
e I •
· / .=. I l
w
'
e ~
a-.rs!'o .2.GI. ~
(/QD
_, lo+.tsJct,
~
•• ::Il'\VJO" MQ.)Ci'Mq c.-,c.pfa.i:n-h,e c.lose.~eM. 4l ~ c c ~ ~ -to .2,S
• O"trbt-fo! >1 ~ 1\,,~ lit ucl.t.us.
••
••
•
ifA.. c::::: A,2.;,
om
L..Az.): nf..f'!!:.a[ 1-1-l(l- ..l.(,l-l-1)-1}
.c
z 2. ..,., ...
C
B
yA
tr
is
em
-tt, e A.-lcd:-"-- 'i ''!')a.Ado M 1'11\ ~t.l,afl ica! ,,S,'f-f e. M ie. Ill ( . ~
h
a_ )'.-!.
.c
dJJ..c..~fbul ~ /i.-y,e.,u,, Ce1Vtbh1a:hW> ct 1/aJ...t.~ po-¼ihl.t ~-bic&

w
w
TVI w "'1A, 4'f-"n!M "ti/\ be ct~c....-il,ec) ri,..clM~~-

w
' le¼- W.. . C.O M lilu. if ~dfm 4' ~ -hie. Lo,, QV,.,, &M 1:,r11(U'l'Dl-, 1- t1iii
o~oV\O'\"Ma.l ..s.d: °f> u.>a..u-e. if nc:h"'o;,, cp, ~ c/,.,_ ~
4J ::. C\ c:fo, + C2... c{)l--
J¢, ¢ 2. ol.T ::. o
Jp, tf>,d r ~ ,
j <p,.(};.2.clT.<-l
~····.···
•• ' www.chemistryABC.com
•~ Quantum mechanics
tlhe relation between average radius <r> of orbital ·2s, 2p, 3s respectively are
~
•• l
d) none of these
• '2('rhe average value of <r>2 for an electron in 3d orbital of hydrogen atom is
•• a) 3a.o2 b) 6a-o2 c)4a-o2 d) none of these
3) The wavefunction '11 is the linear combination of function (J)1 and cp 2 as given below
•• !
I i«f ½
'¥= (1/{2) <p 1 + (1/{2) (()2 The probability of finding the particle in state I (i.e <p1) is
b) ¼ c) I d) none
-
om
4) The Norrnalisedwavefunction of hydrogen atom is denoted by 'l1n),m where n,l and mare
1.~· respectively the principle ,orbital and magnetic quantum number respectively now consider the
II c,z.-1-r.: ~ (.~a. :: q ::: I
.c
electron in mixed state ·
••
; q
C
'¥= (1/3) '111,0,0 + (2/3) '112,1,0 + (2/3) '1'3,'.l,-2
B
The expectation value of energy.<E> of this electron in eV will be approximately is
A
•• none:0) 2 f13•l)t{_1i,)(:'JJ )1\/2{!¾')

y
a)-1.5 eV b-(-3.7eV c)-13.6 eV d)-80.1 eV e)

tr
~ hydrogen atom is in the state

.l
•.
is
'¥= ({8/21) '112,0,0 - ({3/7) '112,1,0 + ({4/21) '113,2,l

m
· 1
wheren,l and mare respectively the principle ,orbital and magnetic quantum number respectively
he
The average value of L2 corresponding to function 'I' is ... .. -t.. .... Ji
•~
I
.c
I '6f"An energy eignstate of hydrogen atom has the wavefunction

w
w=(l/8I{rr)(l/ao)l.5 e•(rl3aO}+i(phi)cos 0 sin 0

w
~
w
· 1. Find the value of energy , total angular momentum and z component of angular momentum
-l,
9i '
2.fmdthevalueofn,l,m.
'-,
-1,scv
-V
b-il
2... L,
111
I 3. Find the degeneracy , number of radial node and number of angular node
I, 7) Fill in the blank ~(1) '® ~
I
•
~orrnalisedwavefunctionof hydrogen atom is denoted a~
'¥= (1/2) '111s + (1/{2) '112s + C3s'l13s Then energy corresponding to function'¥. is ':"".~,.M.~,U.
I ii) The uncertainity in position r in case of an electron in 2p orbital of hydrogen atom .. ~<'.lo. ..
•• iii) Magnetic quantum number corresponding to Px orbital i s ~ . . .
••
~

om
.c
C
B
yA
tr
is
m
he
.c
w
w
w
-I

* <1 ~ C:2. C:2t11t be.,.

t~iV'1-r't
-: Ct ct"· -+ C.z. c-: - J
"i'tA-e. p--ro ~ b rUlf °'fl -f/V\d1111't -Ht>e ~ 'f>+evv,

12.
..
cLu.:. c." ibe>..
o,~ -po)'-db,t ;.:, ,',-lo.:h:. (D .. 1
2. - s.~e..@
p1 = j c 4> C, ~,dT
1
; C.2- j <p, q,dT
o m
.c
C -- ~,
,,,. 2..
B
y A
tr
is
m
he
.c
w
w
w
-- .

C,I 2.-1- (2-2. 4- tt :; }

I .+.1...,.,.(
-c; ,_ 3
1
.::. I
½52--= -4
6EIJ
/ti
-
111 Q,11.
om
.c
C
B
yA
tr
is
em
Cl -c_r
h
.c
. C:2. - c2.~;
w
C/· + c;::. I
w
w
..
J(c,tp, -'-C.'2.4>2.)7t• l c._t\l,-1--~4.2..}d't'-::. I

J £.st tt.+ c.'J.*<t>I) ( <:1 ct>,+ c:~ cf>~ J. dt =- r
c.1 c.ix J<1>t,h ctT + Jc;,i
. .tJ..,~ . .
~f
"-c/,,_ + c: c,_ J+/' IP,_ cl.:c +cJ_*c,} 4i;,cl-r:=1
., . 1I , I
l . I
[ Ct c.'II" + c,,__ ½"" nI j

·. P'?rd~oltL~ ,~.d>~pm.cU~ -le b ~ 1; . ··
P, ::. J(c, 4>,}~ c, 4', ct-c ·

-=- c,* <,_ J 4>t 4>, cl,: .
[ P, = cfc1 !
Piro~bili~ ~Pw,cll"t ;o ~We:.~
. P1 =- j (S_<t>~J~ Ci. 4\.d,:
om
.c
C I
B
l"JJ ,_.: .1. . J.. -f" ~ 1--1! ~ ~
A
p( II. ll. f&. :
.'.)..5"
~
y
/~
tr
p:2.. C. ~
2$
is
,~
-
m
~ !:.
: lS
he
~ 4: ½J'l. .,. L.,Z:: J_~

.c
w
t:.-+ '-::J,,_ ::. L'J..- lz-1

w
w
::. ..{ ( l +1},t,,2. - ( nlf11 )-i...
~ ..t (.t+t)·t{· -M2..Ji ~

l,-1-l{..,._q+2.. :l- I
@--
1/i
. I 111
'<_:i,o,. -,
~ Jil
2 tlJ
-.:,_,II '
_,_ 3 ,_,"' .,· +
,11T, Jf ,o - mw-r:,., ,,-1
A
Q-3
:::. I./ - 2 / 11
1'· 7Z
-
©
r
m
JI.JI ~
o
L..z7 · C I.Ji dT
.c
f J,("
"-JfJJ1C '¼DA.Go.8 9
.,,0
C
,qe..-1"'4. ,(~ Sh-11• cl ocl ~
B
yA
f)D£l
tR-r
oa
J ~a.sine cl e J
;f
tr
- 11.~ j A-a e-~. ,:,/G

is
~ ~
m
. 0
'; .J,
he
GE)
.c
l:a, -,...£ ~~4

w
3 (., 3,
w
~-'
w
J.. -b ..,.~·· ~
(fj) 3, ·3{ 3.l
.-faa, ::. ;g
s
<f"
---
f;_fi/
. &-1
:..--
(J.10 -I

om
.c
C
B
yA
tr
is
m
he
.c
w
w
w

om
.c
C
B
yA
tr
is
m
he
.c
w
w
w

,; ,;?:(: ~em~li. H~ir~tc. owiliclc.A.. 7" 1o h ~ ~r9ir4:#'tm4l M1rtraY1~ · .-
fl 1>1rt.,rcw:,,pk pa>.Jlt.h.. .
lJ).,, c.: li [,_,,_7,,_

t O ,;_ i 1-rJ {2_'YI ~ ( 'J1 +f) hV
<./,x-;, ::o
L... :x..2.;;, ::. _L

2.(3
~ t:,,t >: .
-
~~2.
1-
m
l.l{ 7 =- L J,,-v
4
o
.c
~v> =L
I./
brr
C
B
yA
tr
is
m
To oh+a..1111 -tw.. \Jtbiro.:tim,al -e.111c."'11' 1---t1tte. u~ t-,. fl.1o-ti£1Yl 1 MJC<Jt,~41pic_

he
~c.Lt. we -tz:t l<:.e_ -t\Ac. /4.C..\,,.iro~ 9~ °b 1-JJ ,.(~te,»t 1v, 1ftt1Y1 cf

.c
C,c;;t.1f1""~l0.Vl C...b- OTdJ.vta.:\:~

w
f q,S
w
v::: J_ k:>'-2.. (S.Ho)

w
'l-

•••••
•'1
•~
@;g
Tue &o lu+fon at ~ e,"" ~ he.. ~ !·::';/ l.tv>1 ve,,vh"°s,,,l l°f l1'tfo 1/AA.
ifOTl'\.11- t-fe_,rn,\tc.. f>~OMta.l? Qw::j We... ia -rlnc:. ;$,C,fY/ Q.b
om
.c
~ C
:= (:-1 )r, e ~ dn e-
2. 2.
B
H-n/~) ~~
yA
tr
is
'Yl_-=....o Ho(fc.):.I
m
'>1-=- I H, lft} -= .l~

he
2
.c
f)t::::. 2. Hi ( ~) := 4~ - 2
w
w
liY we:.F ~ =-- ~ 117~1

w

• Jn ~tlFi,r'Y I)If/ !br(~) ~ - ~/:L . www.chemistryABC.com
D
• ?!:::.O tr. = ( f.- 1 /'-- ( {, f H./t, l - [ ~ i
0
!)._
e
4' = {!ti" ,:'. -'$/,.
@
D
(j
~
e
e
0
~
e
€}
om
© :::
.c
0
el C
B
yA
0
C
tr
is
@
'l'l ~ I 'l1 :: ?1
t
m
0
~ !,J~xe~ 4Jn(.4.)=(fa1){¾ftni~]e-'<
he
0
.c
e CJ
w
0
f) ~:.:~C? 0
w
0
0 <::.p;x) 0
w
0
e t1+±}7:s
e <;x..2) ½~
• <..~,t) !$~
(11-+~) ~ t, 'l..
•
9<1<.,c.)
rztt2. -
~
~vYJ
-
l~w
4V1
~4 ll!t
m
.2 - .3 ,_,, ~ ·3 -r.w 111-+.J.-)
- 71 ,, v 1j n \ -
~2..M
ii2. :::. ~+1;_) ~
'.:l-
·~ LV:,t) I< _ J_ •~ v := ../2 tl;w ¾\ = fn'-'==f'>w -iK [-n+~)q=~

•
.CE)
~
-:h:_
- 4"1
hv
-r
2--
•
••
·w
't
i
~
(j
~
'
~
rl
e
~-
lfll,t,_2. - 0
., ~
[7(;:~
~
?c.~±, = l47\e~a;2,
om
~
~
.c
C
B
yA
rwoYI i1,
tr
IM'1(imu'IYI o¼ x.co cu,<i d.t..-etlll.~ q,.Poy,-t.MI:,~ ,..,rt,, """/kt.

is
'"\10,W-l ~ h~ t11U'YY1 o ·
m
?<.
he
.c
w
w
w
?l.-=- 0
lf, ~ 0
{uv,ctfl»1 'H bi! COWi~ ~ a.±- x..::...0
/IS -fk.o 'Valw.. 1X t-a-crwt -u).JD

6~
r+i/.J.A.+- i~ c.y CA6.~ -th 6,\ q, C.7 ~~

4', lx J -:: x.e- S.:x.7':)..
?f.!!:-f/ LV,(1).::: ;J>-e-ll/2,.
tp, (-J):: - e-81')...
�MMehtc. www.chemistryABC.com
AKH -�Mmd,,tc
(f''?Sobabtl.L�J-
om
,. / .... ... '\
.c
I C
B
I
0
yA
, /.
( l
',...
____--.:..:::..
\
J'
{J ___
----------4:___
__ ,,. .,
tr
-
G
is
X--?
m
{)
he
* 1 cia.M.fca.l �c,l�vdom rt\e.�vircal !SHO -

.c
@ ColV1F�it:.1<n:
w
@
w
@ .._
'' /l
w
e
r -.._
I
l J
•
,r \ I
'' '
••
l
_.,. .. �
\
/ I I
\
(
-
I
\ ::--
V'
••
•
•
•
•• ,.

~fllt""'-'"'r---• - . ___...
~
le..£.,
· V,::.IIIQ.1.
oJ :x.::o
Spord Ml t1 -#ntt:a.@
f~o.i.-
(D ,;ram -tine. 'r°P~ 'i- 4!.f.cp2. vs x. rn Qm.SHo i+ 1,s ll~11Aa:1-
pvJ:tcJ.t &pewtck Ml1'7m l;f)') -flme.. at- e, rn ~ i-HU>? {tLO£ .::o) /J1 --ltu__'fvtlncJ
om
Ai.4o.te hecou~e. ifv,d-rC>? ~ rno:x. aJ- ::x.= o
.c
&J:- 1'V\ c.\aMa1cal SHo ~c.lt. ~~ mrn, +tme_ t::tf(:x.:::oJ
B
C ee,111rH1o>?,
yA
® ZVl c. ku,~Jad SH o 1<, B l p~1l. • rn~ he -u.M hu:J- ln t:J.m .SHo n-el'#uJ-
tr
k. f, 7..VJ). 't'l6'f" p.f;_, -zva.o . .

is
1Vt.clt:J.¼(ail 81-/0 ;+ 'ts t.tm4~

m
°1) ui b,cJ-r
he
k.it_ :::.. c., al- -e.:x t-rc. JYtt,M UYJ
e =-- 0
.c
p, aJ:- X :::.D (_o.:t cc:;rw)

w
w
~ TV\ c..\cu(<J°cal 8"10 paJJ/cl.t Vt.®t!-1fYlirc ampu~ 'i uib-do:Hcrn

w
~ flA 0.M SHc ~ "'lalul ~ ifVld:-,dn e.xlsl- -9-'w --o -to f-0
So r1'\ Q rvi SHO 71A eu. ~ -HA e. (!_,M w-q-e. 'i 1/-nclt~ paxtl~
l"' Ltll..¼i=l iF'biolOU/1-t ~<YY>, H ~ Calla.a -tunnel.uh(' :..,,...
---tt,i~ fovw,~ pwt.:a..bili~ -Ji.~ t,urfl,, "1'~ fn va.1..ut1@
bc.c.o -z-. OJ:> @ ~d:> <:...let.-¼ i co..-l be..l,,icr\f io-t..tA. 11~ ,

• w.e.. r:,t"-liuJ- (1) lairr-m~xl°ma c,J, exm.rnu01 '15 vfbira:Hn,, ~ a no,
•
G
"'b .;m.a.tl.. JYIO.">'1l>'a b/w -ttui...,_ -1,.,.,o 1a-,. c:. m~"1.!ma 1'111-E!Q ).½ ivH,_ p-.cb<t 1:,; ~
0 "fi il"'clmef ~cl.La± c:.Jeh-emuM 1- uibisa±i,rn, ~ja:J bei.av.ki..
~
c.m~e>.. a. Bo 1,-.- 's C_o 1><r'°'f"ndahru ~:Jl.L~'I\ c.J: i
•
e
@ S'j1>1rvt9/ °6 * wave t,nol-rOYI 1"& cf'VO..~ ~ Herrrmk "p~noniiaJ
(j
0 a1.:i. e,v1-..- 1yi; n dfm t!, CJ.n1kd,,..l'~ -11.vo fci.kX'

•
0
lf :: H., ( f) e- 'E'P,~
e 1
m
0
'fl:tw~ S<fmmehlc
o
•e
.c
Ho(~)-=-J
C
B
J-11 l~7-= ~~ =-~J.e 11 lf,::. akti~rrv,e:h1°c..
yA
•• =
tr
H1. l ~) ::. y Q_2. 'l,._ .:2_-,c• tp 'L = Sc1mmeht"'!..

is
••
m
~ He.,s-Mi~ c..oNt-\cuvl ?'-e'Vt,¥t i°nd:-i'CM ~mrVJehrtC.

he
if
• ?Lod._c) yt d:{CIYI Q lld:i ~mme:blc..
.c
,, ., , "
w
0
w
•
w
•
•f
•
•
G
••
e
••
(1f'r '2.~ o trR 3- P)
w~ we.~,
LU~ ha.u e
£iay-Mank ~~Y
-lo ckv/2 ~ S Ht>

F ~
dirweMw,-s
f vr --!wrJ l!ot:tt!..fO~ ,
({) /l11isohopiL AHo @ :J:&o~pr'- SH-o
..},
v><-= v~-:::. Vz::. ~v
{3,c_ ==- 13t::::: .,"Z.. = ~
~ .2.- p QV\t&o~p;£. SYQ -
o m
II-Ai. ow, ham tt:hrnia l'l ~ 10--- Matte,,,,
.c
r.b c>-fr -two hamil:lonnm
~orv1Mcd-iOV1
C
B
oF-'""ol.r:rir tfa 1- D moh"'C;yJ 1-tkvn ~
yA
A.U.uiln u¾- i;uvt(:KtOY)

tr
is
ff )"'e::J -:: . LPx +'-l't

m
he
.c
w
w
w
q> (,<1~) :: 4'Jct I.pd'
" (~/'" ~tot~tf( Hn,.[EJ e-'V:)

x(Bt )j I (. 2.
-;;;"J ~(~) .f,)l) e- ~/4.
••
./
. J'.'.
~ . (~x ~ i) h½c_ + (
'6
£<'<,JJ ~.f 4.) hvt ' www.chemistryABC.com

.•""l .
•
c, ~ 20-~0Jl0P-k SHo~
e /(if)
: 41,.b = [!rl {«-k~)~1¾( f.} e-f./2
0 /(!!p I
: )( {: J~ (fa; ~1) ~~~)L~Je-~

•
•
•
om
0
•
• .c
C
B
e
A
•
y
tr
is
m
he
.c
w
••
w
w
•
f
• s., 1
••
~o
Ir 3 l!J, l/ '2., 2.
[s'1v] 3-=~
•• .2yJ
(2,07
,, 2. 3,o
(II l)
-e,,~ lE!:11) ( r= 4
••
(Dl2.)
@h;JJ ,-:.:3
(t,o) Co, l)
[~'1,/7 ra =-
• l o,02
2.
• 141 ;, w-
Download all notes by clicking here- 01<l!ii] 'j=
J
(%0} ~-o. "

'il::J ::.0
'>1%..:o
o m
.c
C
B
yA
tr
is
m
2 , 0 ,1 1, o, 2 1, 2,0 o,,, 2 o, 2, / '1, 0 , • o,1,0 o,•J ~ ,.,,,

he
lt, o, I) (1, 1,0} (/, ",I} ( 21°1•}, (•,2 10), (_ o,o,i) [-if m] · @
.c
w
0o [1 J.i,1]
w
I O)__ (?, I, 1J) (0,9:!2

w
(i:;
- (J_+1}Ll+2.J.:= ..s
,,
e
2-
•
®
®
142 Download all notes by clicking here- www.chemistryABC.com ~
· 1.Consider a .~lassical harmonic oscillator with a mass m and a force constant k oscillating whh a
frequency v. Which of the following statements is NOT true for this system? TIFR 2013
A) v increases if m decreu,ses. 1 . V =...L ·JK
~he oscillator is most likely to be found at its equilibrium position. f 2/(' In.
C) The acceleration is maxihrnm at its turning points. - T
D) v does not depend on how large the amplitude of the oscillation is. -r
2.For a harmonic oscillator in its ground st!tei.e v=0 the enegy is giv.en by 0.5 hv where vis the
vibrational frequency. This is due to its TIFR 2015
(a) its kinetic energy (b) Potential energy
efsum of kinetic energy and potential energy (d) heat of formation
3. Which of the following statements is true TIFR J015
m
. (i)For a.harmonic oscillator potential, the spacing between adjacent energy level remains·.··
constant with increase.in quantum number. 1". ,. .
o
(ii) For ·M.orse oscillator potential the spacing between adjacent energy level increases with .
.c
increase in vibrational quantum number. E=, . · , · . ,, ·
•I
(iii) Harmonic oscillator are used to explaiilbond dissociation P C · >
p ·q
B
.-,I
. (iv)Morse oscillalor are used to explain'the OSCillation. T
~\..J~
yA
(a)i,i~,iii (b) i,iv (c) i,ii,iv (d) i,ii,iii,iv -a q.
••
4A free particle of mass 'm' is confined to a region oflength L. The de-Broglie was associated with the t)?:::3
~h
tr
particle is sinusoi1:1 as given in the fi~re (should be discussed in class). Th~ energy of the particfe is Bn::.
is
'
! ........................':llp-"$1Yl/ (2.. . ITT JAM rhys1cs . •. 32.IYJ
~nsider the statements . . . .
m
~ .
· i)Pure s~bstance are required for studies by Raman spectra ,studies by IR spectrn do hot require a
I
he
of
:
high•4egree
:,,, \
purity. " ' .. ,
ii)Water can be used as a solvent in Raman as. well as in IR spectra.

.c
iii)for intense Raman line concentrated sol~tion is required.

w
. Correct statements above are a) I,iii b) ii,iii c) I,ii,iii d) nor\e ·

. :. : .r" , ·. ,. -·-- --·.-- . . . .. a
w
:i ,l~O.,,,§The quantum mechanical. virial theorem for a general potential V(x,y,z) is given by (x a:+
w
~ y oy
av
oz = 2T where =l
+ z av)
~ ; ;, .. · t \•: · ~
.. h k.met1c
1s t e
. energy
. d . d. . . . . 1
operator an <> m 1cates expatiation va ue.
This leads to the following relation between the expectation. value of kinetic energy and
potential energy f9r a quantum mechanical harmo.nic oscillator prqblem with potential
~ :, • , t •,~• I ': '" ! ' •• • ' . '•, , .,. . ·
Dec 2013 CSIR
(c)(T} = 21 (V) (d) (T} = ~(V)

7 The most probable value of 'r' for an electron in ls orbital of hydrogen atom is
. ·I .
(a) ao/2 (a) 3aJ2 Dec 2013 CSIR

8. The most probable radius for an electron in.2s orbital is{i1ino ..(~:':!}7.~~-
9Consider the statements . ·. . . •· · · · ': , ·
i) wave function dec~ys more slowly as E-'>Vo in case oftuimeling process. T
_ii) T~e.noqnalization constant in caseofshois dependent on mass -r

•1,.
, i'ii)Molecular spectra is much more cpmplitated than atomic spectra 'T
--
. .
. ' : ~
Correct statements ab@ve are a) I,iii b) ii,iii c) I,ii,iii d) I,ii

OP
IO . Combining two real wave functions <!>1 and <j>2, the following functions are constructed:
A=q:> 1 + ¢;2, B=$ 1 - icp 2 , C=icp, + <!>2 D=i(q:>1 + <Pz). The correct statement then be Dec will
2012CSIR - -
(a) A and B represent the same state .· (b)Aand Cfepresent the same state
lefA and D represents the same state
om
(d) Band D repf~sents the same state
· 1L The energy of a harmonic oscillator in its ground state is{ hw. According to the vi vial
.c
theorem, the average kinetic (T) and potential (V) energie.softhe above are .
·
(-a1T=-hw;
1
V=.-hw
1 .· ', · i' ·.
(b)T=-fiw; ··V=-hw
B
C < 3 ·
Dec2012CSIR
· 4 4 8 .·:8
: , .· · · 1 · "3 · · 1
yA
, (G)T =J1w; , V = ~-,"z,hw (d) T = 8n(J); _·. V == 8 hw

12 S,uppose, the grom;d stationary state of a harmonic oscillator with force constant 'k' is given
tr
by lflo=exp[-Ax2 ]Then, A should<lepend onmandkas.. .

is
(a) A e<k"wm 112 (b)Aoc km ('d~k \n 1 112

·- ·.. (d)':A 'cc k113in
m
13If magnitude of tl'ansitiQr.i dipole is considered same for all th>e of transition then the lifetime for
he
electronic transition in fhe proper order is · ·· ·

. Af_ (>f- :=- !!-
~eCtrOruC<\<ibratiori:;t} <rotati OOal (b) vibrational<rotationa.1 <,electronic " · 44"
.c
(c) Electronic>vibrati onal>ro tati onal {d)'Electronic=vibrational<rotational

w
. . '. ".,.~,.~{;·: . ,,
· 14The fundamental vibration~~ frequency v of a homonucl_ear diatomic molecule with atomic ftl ·
w
massm and force coi1stant k 1s ·· · ··. · . · · · _uc. ~,.,..

w
·;. "l
a)v-=(1/2x)(klm)°- 5 (~(l/21t)(2klm.)°-5 (c) v==(l/2x)(k/2.pi)05 (d) v=(2/2n)(klm)°- 5 Mc.c M~
15 At a given temperature , for a rigid retor, the probabiticythat a system is in the rotational state . ..u c ~ ,
J=O is 0.6 f,n state J= 1 is 0.3 , and 0.1 · in J=2 ..The average energy of rotor at the given 2/YI
temperatur~ "'r, ~;
ilp~ 2:'e7:: p0 eo+ + Pi.f::,...... ~e,
a)6.0 B ~ 1.2 B c) 3.6 B d}4.8BTIFR . . € ,.. g::,C:T+I) ..
16 The correct staf:ement about both the average value of position ((x)) and momentum ((p)) of a
t-d harmonic oscillator wave function is June 20 i5 CSIR
a) (x) f:. 0 and (p) f:. O b) (x) = 0 but (p) :f. 0 .ef(i) == 0 and {p) =b . d) (x) # 0 but (p)° = 0
. 16)~iH intheB!anks . .. . . .· . . .. . ~)
a) The degeneracy corresppndihg:t~ 3D isotropic SHq_iy\th'~~~rgy 4.5 h vis .. ta .... '. · ·· ·
b) ftJy ('hkfat1v~dA tfi ~ . !;t1r,; l'>'t'f;!lLin
.f¼. ½.:!lltu.. lh(~~/) 7< > 4
3(.,,
. . I '1 M,t ?l __,, ey.'J tt~~t wi i,)_jj/ .kH. .,,> , ·

?7 .-4 t5IO o-to i -
~ex"' 144 ~ l(~~t Download all notes by clicking here- www.chemistryABC.com
q1' ::;,(;!-1-1} M+2.J -:::. i:

·. ;i_
C[=-i]
of'P _,
:....:---
D.:
. r(lo-rl.>e'..
~al.
om
H~~'S •b.»J~
.c
V !!, J_ 1( -x.'l..
..'.L C
B
yA
tr
is
'
~·;f .~i--'> 1?:;~ &Mt!U

m
a
he
2.~ . .
.c
De,_ oli )/4oll.a:b"oYJ ' ·. : . · '

·~~
w
. • . · •.· ..•..
w
~
,ttvli-
.
£=- (i',-1-J,:)hv-l<n.,.l }'1-h~:>ce -r,,... ~a:I- -tw:_pc+-wm=
w
: m,..
ti: m.~
2rii ~-·a"' l1a1rn1rn iu°~
6Dti~ ,
c~=~J
¥1 =- l<t, 't
~ .:::- ~-z.-
J~ .
om
-'X. l<.:;I(_ ')( + if kg d.+ 2. k.z -z. =- ,;;_ T
.c
{~?e --t 1'1 tf~ -1- ka, z. :i-_ o1. T C
B
yA
o!V::::. :l.T
tr
V= T
is
*
m
7111 Wl'..~.;_Htflx,pn -
he
.c
.. LT7=-l.<.v>
. ..:2. ..·
w
w
V=··· --(.2.
w
l.t t:o £,cz.+tj ~ aJ '

-----
If '2 Y2.
A2 = -::,c..2...+&2+z.2.
..t..:::. r ✓C..?..+(12.t z. 2-

: :if; www.chemistryABC.com
•
•e
• 11{ fl/ld Kofo't' [dl_,neMfa~ t°dll-l)
•• /kc. -k Hunr,ilcmiaM C)~A,_ -/J°-r hyd~1<.
e
,fg
••
om
e
.c
G
fJ C
B
yA
G
e _To 6-fv~ --H,,iL M-fair~cd_ mfrftuv, 1 mr/Jy(J~ {g) plc_ pcvd,ch. we_ !~d.od
tr
•e
is
-/vM a.-na,vb~ morvteMl-vm of'-oaio?t /n H4rn!A::h:J'Ylia,,y, aj

m
he
0
.c
0
w
~
w
e
w
e -::.
•
•'•
•
lj
•
••
•
. ;
. ..
~
.
~ ~
1
~ MoeltJ --~ 171°f>O!J.~ -~ r.,f,.,"'f /JJf-rd-,(MJJ) )ntJt7CA?

~ A.::. ii><ed =) 1/ i/x.«JC: .
co auo-fcl ma11,,eJYtcd-fcal. C..olV\ ptf<n±i011 V:::: o
H4' -=-- ~ LP
dlI
= ..l (,l-t I) 112.tp -:::. E LP

al:.
om
.c
C
B
yA
tr
is
m
7L- {v-8/HJuM t1'10r I~ t~wei:J) dlj_.t,v~ dwJ7 ~ ~fv~ tj-

he
mfr.:;ro~ ~ll fa.Ah"'d.J eh._c.:hrrnt<. ~tool.tjl-na

.c
r17a-l-,"'VY1 1 ?70W WC ~1'('.'.

w
-th.tf><M/t ~ Ir/ 6)
w
hltrfl'oYI, we_ Mfla.11.. ,l i.- 3 beh.av-e.8

w
.&fTl'lt \a..i- -+c, J..

::r ::. 1
'MJ = 7, ·O 1 - I
-;J:::. ' el-::: :1 s if .::, 3 -

'J' . . 2- (2-:,., :::. 6B 1~s
=12g 'i} -:;-
~,.. 3 I:? 3 7

W .. .· .. .· :·: .. ,, . . . : .... :,.,· . . . , ·. . . , . ·,. . ·.··· . ·o·w1·
8 ~US·. 7h valw 1 ·e11e ~jxmd,"7 1D "· ;,IJtiM/rJM mJ'. ~~ www.chemistryABC.com
: . poJJldt. 1',,,. f.! IP/"" 1ft,_c.! -ti.l. ~-ya°f .. .

0
E)
~
•
6
~dJ ~ d_J+l
-:::.. J..¥ll1" I
m
U0J
o
.c
C
B
k
yA
() f 0+0'\:hal s~fa pcrable.M _

e~
tr
d) po+ Ba~ie.cr P'b't)bl(.M wi-tv, t\lliriu+c wial:Jf,p-

is
0
m
0
he
~
.c
,,,
0
w
w
e
~ <VJ
w
'(D
()
@ E .:: V
•
0 R~ ( p, - P:1.)2.
fJ (p, .f-p:) 2.
-
(}
••
•
/
© p~ bo.nfew ~ fJwi Wfti. "6tWk v.iiotfh ;.._ www.chemistryABC.com
f4- >I
L...
:::::. U E (_E-V J
T
ex.o.d:
om
.c
C
B
yA
tr
is
m
he
Sc.1'rrt>el.i.vi-t.~ ~"YI Uct'ir~roY!d..Lnq' ·""tO move.MM

1 F1d.t tn 1. ,,_,.,..~;CY/
.c
d?.(p + ~ (£-VJ lp.= o

w
q :x. ,_ -Jr l,.

w
I11t 1A>t ~'°IN? V ~o

w

e ~
•• Sop?
= C.e it,~x+ De-i~x
€)
:::. Cetf.0'i1 -+oe_tf?..a.~
0 L-? J.,t_r~ -fiu_ mavemw¾-°{ ~ d t r,,,
G - 'VC X. aJxe.dfcm iVl n ~itl"r? ~ l1~l.J..cf«.
•
e
•••
if" q Fr,_ bt-rrf~y 'j; ~ 1P>tf1-1
b~ c..a..u.J..C.
pa.xl:tlli t""
' YI Il' ~ ' dYI fVlOv<:.m e.t.d-1f
-x. d.J..'-'11(.diCTVJ ?tot 1-q f4~ p&.u
om
e
e "To ff'Vl.d ~ NltJ.EoYt .b/w 11,B~c.. qPP1 CiMcll-hGN1
.c
btr0Vl~
0 ax:- ?t.-= 0 o/1:. :: 4J.II C

B
e
-
yA
G --
d?L d')(.,
••
tr
CD ~rJ.x.:::.o = l4Jrr J)(.- o

is
m
fie. Lj:•,o/-1; -t 8e.-il"ro/'t; - Ce iP,·6/t;;
••
he
0~s.:C] - uJ
.c
••
w
dth) _ (q_ 4'n: )

w
(
• d:x./ :x.:. ()
w
d.::,l-f1<;::.. o
•
•• "I Ce. Ll~x.
L <..1_
••
••
••
•
Tu vah.u_ er/J 8 1n iUf n(j) f,A.

fd '1" (%) we
fn ~t:..
p,rJ - p, (c.-Ff )= t~c

f, f1 - P,i C. + f1 fl :=. fl C
[/>t+/J,}c :: df r, r-1
B -::. ( ft - P~) It
[0+ 0-)
om
P-a" h4 bi LL°1 ~ w~eM.k- OU1>11:. f}
.c
J :.:. _!_ [ lf'ltv l/J - 'fl,qyJJf- C 7
B
J
~tm
l
yA
g:
~ c/~ lf"t .:L t/J - V.JL ~ 7
tr
t l"t1 c}rl d x. j ii;

is
;;.
(1.,,
~~
m
Ji: G ft /1'/a- l!. 1812.. IA/?-:::. JI I! 'Jr

G
he
("' ~M 1
~~~ tvqv~
1
"I11~ t.,J-o.,vc 1f3f ::..- 88~ {Ji;
.c
/C/7...-=- Cc~
f=lcJ
w
"J'u - :z. ~)
"" ~ T'Tc.t ~ M; tJ. t:.4
w
w
T-ira mn1il¾Cl!Ylu.
T= .£i /Bl'-
m -
f::>1 /'A/L
rY1 ID
::::
1-1'2. ~12- Q
•
::::.
R:: (J,, -p3/2-

••
~1-rr) )-
•···
•
",.~.:; •.'..T' . .
· . Pot~ ~~~~
.
b.
ffob/J.m wrf:,~~IAl.~
. o- . w~-'~ · '
.uk
.··r~·
] .•·
lJAi. www.chemistryABC.com
(DfVl~fdJ..,s- 0. Q~
· , •..ii
•• pa..>J;1dL "6 m~ m, encr~ 8, u,Ui~ wrrh rot· }:x:nn·fc,r 1,- h¥V
e
e (o<x<LJ w.. €~~lv}~
d S d - r r ~ &j 'n f11 Rea-ld>? 1 - »; L ,t;. l
•• cl2.t/lz ~ ~
dx2..- 1f ~
C€-o) t/z ::. o
€)
~ + ':?. IYl ~ 4'z ::.. o
d')t.,,_ -Pt 2.
0 we. o.1S <- Jsfu~1via, Tu 'Vl.,eU~
•
C,
p~07on?e:t,,1 ..:rYJ -
m
fa.Afid.L ww f( e Ytt:.:<rrf U M ~
e
o
ffAJ- -c.1n a1t 4r b a--nrrt:. er hew t:.
.c
.
~
e C
-tl,u.. ""tt!:r\d.JIYI~ --tri c1r0ss --t'w- ~nnr~ir
B
i/2 l,1110UJn ~ -Iv vtvtdlv,.'f . .
e
yA
tr1'
fj
tr
To ~ -fkc. paJ.J:Jd,_ tl'I cla.Kfo:al

is
0
ifrrb,~ 4-rdYl c.s -1-o11vie.LL~
m
ff)
Sc.n~LY a,'l"I in 1l ~.'1m-
he
~
e ~
• ~ (_ £-V) lfa. =- o
.c
d1.o/.iI -t
c(,c..), ti~
w
"•
w
_,_a.
dl.laJ
1< /· tf n =D
w
J-
•• d.:x:>-
~
•• l<.2. ::.
11
.::: P:i...
~
• f le,, x
oe - {ls.?-L
• Ce ...,.
-•
~
-- Ce i~2-~ -+ !}e- l/tl2->y-Jr
••
,,,,~'&h~ .a,>i'in JJJ ~~ _ ·
www.chemistryABC.com 'I'
o12~ .
- ·- -r
c1,o- 1i 1- lE-o J l.f/lJl = o.
'1i!!. •
@
d" tp£il..
d 2. ).,
~ .r1...t:tL €,
# ,_
t.plll =o •
®
d
2
'tttl -1- k, 2.. ,_,;az -= o ~
t
•
@
flpf~'7 &vt?4a.~ un,,ci.L~fitT>1& _

C.Umrt'MJ- c/.vr,/417
om
,;.. - ('I / f-1 ,2-.__ h /8 / 1
.JI - - m
.c
/11
:far = .lJ 1~, 1-. C

B
/YI
yA
l<.'frlLcftll'1u - -% /1312-
tr
::::
is
_b_ I fll1-
m
rv1
he
Tra-a Vl/2 tvl171M'l u. c 1-., I€ l2.

--~-;;}
.c
J1rt
/:>_, 1,,
w
7M
w
w
~
~£ (V-E} ~
1 =
4 e ( V-€)-+ V2..S,'v,-/,,2..(l<2.L) •
•
1i
Sin h(]<2.l) -=- e k -. . L -e -k
.z.
1 L
••
@
@
----------····-- @
•
.,
•
e
•
d - J2.m cv-EJ
•• ~ ,f;,_L ~ la~c,e, mc:a ~ 1=i
dlv.e.Y V 1a.17- t:rfl. L /a'7~ ~ bsni la°7

0
ef<it >::>.,. e- ~,._L
e
• 0 T _ l/E (_V--€)
0 4-V"" (eh~)
om
L/E (V-E} 2.
•
•
.c
T:: 16 E (_V-€}
e 16 €(V-F3) + 'lt ie:2.ki2..L C
B
••
yA
tr
•
is
••
m
he
••
.c
w
••
w
v tair3e, -Mit:vn £
w
fl.s f,,s
%V
•• 11.S Va.lu_t l~(l'~!.&,,
••
••
• V 'f\ T.J,
•• m"4
L1" Tl,
TJ
• 155
£ 1' T t
r~ J~fl(~-v; www.chemistryABC.com
;
., .
••
. i
_E.. ~ j 2»-t ( E-v J
[ 2M(c;::vJ _
,<fVI
•
®
J~tnE
r~
rr
=--11-
:::=:; f:}! = .L
•
~
£ Lf !JA;
@
I - V - _J_
e -
t...t
~
.t. -== r-1<./ ~
om
E;,
~
\J
.c
~ -::::.-3 @
€ 9
C • (§
B
yA
@ @;
,.
It ~ tk?(, ();
l.f=
tr
,t;/"•
is
cJ
p, ~
m
k,= -1;; ::.
tr
A e i'k1J<+ .B<:.-ik.,2<..
he
c,
t;;;;;
.c
p, ©
"J, =- I Al 1 ~ p,
w
/Bl 1- t??i
~
tY1
w
.M
w
~'fYJlf ;t(2-
0 T~ l/ p, P:i... ft::. f.2JVl~
C!tP>-) "- f2- :=_ J2M(E-=;J

-- LI. ft f4lE-i;
4 ..rs Ji ,~. 6l/
(_~ +JE-v) !)_ !_ .rs+J3. J '2-..
-.... 13,3 ~

. DPPJO
1.Consider the statements ,

(a) Each wavefuilction is orthogonal to all of others even if the symmetry of two function is
·,;anie:~ · . ·' .· ·
(b)The particle in box function differ from the harmonic oscillator function because in PIB
model turliieling phenomena does not exist but in SHp it exist."'f'
(c) A particle with wavelength M strikes theJ>otential barrier-. with region of2M wavelength the
ratio ofV and Eis 2/1. f'" 1 w,tt,.;:t\;::~ .
The correct st3:tem~n,trabove are (a) i,ii (b) ii,iii (c) i,iii (d) i,ii,iii (e) none (f) all
2.The probability cfu:r~11t density corresponding to function 'I'=Aeikx is
(a) hk/211:m ~211:n1)A2 (c) (2n/hkm) A 2 (d) none .
..3. An electron with energy 5 eV strikes a potential barrier of infinite width and with height 3 eV
m
then the transmission, coefficient is
{a) 0.1 (b) 0.3 (c);0.5 (d) 0.6. (e)norie
o
4 When a particle ~th energy higher than potential barrier strikes the barrier with infinite width
.c
then the expression oftransmission coefficient is · , ··
e:f2m(V-:E).L/'fi C b)T= ✓ zrn(V -E). L/h

B
.a) T=
yA
c)T= e-2 ..jzm(V.-E).L/'fi

tr
51 Consider;the statement .·
is
'-. '
i) :function 'Vo and 'l'l are orthogonal to each other in lD SH0. '1 .
-r
m
. ii)The average value of kinetic energy in first excited state in case of lD SHO is 0. 75 hv.
. iii)Maximum amplitude in SHO is· a ~lassical t~rm that may be obtained by equating potential.
he
ene~gy t~: thekinetic,energy. f V~bf . ·· •· .-

.c
The correct statements above are (a) i,ii (b) ii,iii (C) i,iii (d) i,ii,iii
6. Considerthestatement .
w
i) The spacingbetween n energy level and ground state in SHO is hv,',:: '>1h1' ( \VI tsdh01'1l.S1
w
ii) The.degeneracyconcepfin SRO occur when we discuss anisotropic SHO. ~.

w
iii) -.As we niove towi:\fds higher vibrational quantum number tunneling probability in SHO
decreases "\ · ·
The borrect statements above are (a) i only (b) ii only (c) iii only (d) i,ii (e )i,ii,iii (f) none
7. Consider the statements lYI l[).5~
i)The spacing between the energy levels is ljroand there is a z~ro point energy at (1/2)t)ro. In
1900 Planck's treatmentof blackbody radiation predicted the same arrangement of energy
levels. "'"f .• '
ii) The spacing between rnergy levels of an osciUator with. a large force constant k is higher than
~acing betweenene1¥level~ of an·oscillatorwith a small force ~onstan~k. ,,,-. y !!'A,J(
m)'1'2p-1 and '1'2p1 <!f~e!;_gnfun91J.Qn ofLz but'lf2px and '1'2py are not eignfunct1on of I,,;. T · /YJ
TI1e correct statements above are (a) i,ii(b) ii,iii {c) i,iii (d) i,ii,iiifo)none
.
'to 1
. .· . . . . ·.
a,,e. . .·
· [1./J ·, ,
.
· 11,ivdm,,diuv . . · .· ·
2p l .
o<. S1vt!J c ... , f'
c<. S i,tl e. •
• I
. ...
.
. .. r-,-,_t Lz..
. -~·.
lfl • ·· ~.,'J·. - · · (p1p·H · · · Stl1 e-16&1 > ·
157
• . P~ f L~ . . .
.. :taiff~~~;~i~!ifr{:!~~
.
:~
. . .
e.1 - ·tlJ~ hv €0; ~

.l- www.chemistryABC.com
--
t(.).:::. ,QJ l{.3 ..... /6, 1 1.
:2. .
!t
~
16
~he strongest infrared band of C 0 occursat2143cm· 1 the force constant of 12C160 is
~
12
· (a) 2155 Nim (b) 1855 Nim (c) 1658 Nim (d) 2056 Nim
9 fill in the blanks . .
l
!
i)The term degeneracy is applicable to the eigenvalue of any operator not just the'.; }1,;urrJi!/trriaM f
ii)The function \j/2pz is zero in...~t:.plane. •. · . · ·
4
iii)If the harmonic oscillator wave:functiom.jfnis an even function than \jf n+ 1 is an QdJfunction.
iv)The n=IO harmonic oscillator has :.;tQ....... nodes
v) For n=l harmonic oscillator; tJJ..~ m9st likely position of particle is at: ............ ..
•
4
vi) The IR spectrum of 1H 35 Cl h~- its str~ngest band at 8.65x 10 13 Hz the approximate zero point
VI'bm1ona
1· 1energy C'. 1 35
:t~ .
,._.a.v..,... ,,.. . - , ,.,Y,/0 -3 4 ){ S'- l.S1.fol 3
1.0r H Cl.IS •••••••,1..1.. .
lOOut of Px, ,Py an~rbital of hydrogen atom which of the following is an eignfunction of
-~ . . . .
m
(~y Pz is the ;ignfuntion (b) only Px (c) Px and Py (d) all n.. t:r·H) .
:::Ji -Ji:
o
11 I.Consider the s~atenients 15'-:::.
i) The energy of a rotating particle is 28~2/I the degeneracy corresporiding_to this energy level is
.c
15. a'· . . .
C
ii) The probability corresponding to J=O state is 0.1, probability corresponding to J=l state is 0.6
B
and probability corresponding to J=2 state is OJ th~n average value of energy is 3 B.. 1
yA
iii) The value of magnetic quantum number of Px orbital is +1. P

Correct statement above are ( a) i,ii (b) i,ii,iii (c) ii,iii (d) i,iii ·(e )none
tr
12.Considerthe statement
is
i)The wavefunctions ·correspotiding to hydrogenic atom are real function when m=O ,and I
m
complex function otherwise:-{ ; . 2VI :1.. 1

p(! l-G &?'J"'~
he
ii)Tlie probability of fin.ding the elctron in ls state outside a sphere of radius 3ao is 0.062.
iii)In rigid rotor potential energy is taken is zero because:no. hindrance in rotation.
0:- .3 i -r
.c
'l • ... ...
The correct statement above are ·

· fflii
w
(b) ii,iii (c) i,iii (d) i,ii,iii (e)none

w
:(fpuppose that the ,wav~function for a system can be written as

(3+: 2
w
' 'P = (1/2J<1>1 (x) + (1/4)<D2(x) + i) <!>3 (x) then

(i) The functiori \jf is not normalised because imaginary part is present. f
(ii) Function \jf is not normalized but can be normalize. f'
(iii) Function \jf is normalized. If the energy corresponding to state <D 1 (x) , <D2 (x) and <D3 (x) is
E 1 , 3 E1 and 7E 1 then the energy corresponding to state (!)3 (x) is 7E1/l 6.
Tnie satatement above are ( a) i,ii (b) ii,iii (c) i,iii (d) i,ii,iii (e)none (t) ii only
14.A hydrogenic 3 p orbital has the following form of the radial wave function (o.i <:0nstant)
a.1-r) e--u2r (b) r2e•o.Jr (c)) r(C4-r) (o.5-r) e-116r (d)) r3 e-o.7r
onsider the statements ·
., J ere are;exactly 21+ 1 different wavefimctiomvn,l,m for each En,1,m• .
-'.ii)Thete are yxactiy l(l+ 1) different wavefunctiomvn,1,mfor each En,I,m
iii)E11, 1,mdoes not depend on 1 a1;1d m for the Coulomb potential.
~ [p,'Y't-J· ;.J'i.1),~t-f c.ii~f!f "1'£; (tt') ·~, Ji / lb_; (J1'_ ) 1T) l(a;J- ,',, o,:,,; f ol>f L fii J
_Je~ 1T\fr,,e) <dJ~ M~d ;C,?,:: ;~ ,Y ·lM-l;J

158: ... 1 • Download all notes by clicking here- www.chemistryABC.com
- 11,rio;;maRtn, rndhor:J l~-~M -- www.chemistryABC.com
TVlr>!:>'r p,rohu..YYJ 1VI- 0-,DU'lll~a.u:I iJ? &ilYl CQIII v,or be...~lu~ e.:x.a..~ .
•
;®
~e:!e ~orn 1 --&v,~c.Uv\~ ~ l1 ;~ LJ<l,S t- ~ C( ifw ~ ~~Ten1
© 5o q 21Jb. 1J piro b/lVI o/unif- v,av~ ~o..t± .-!:.o'/Y/,, 1;::rr itta&e.. p1SO{:,ltm w~
€9
V\_cu..,(_ --lo ift:,us OYl. pro-xffl,tccte. ~or: J4 Vlb ~ i mdz,,o-eJ ~ Pe..LIVJ
•e
q
()
. oU\J"W-f -r ~f~ plh.po-4,e.. ~ l'.Glll/21cle:,( Cf f p~1Cl1YI~ f'\;te..tl,i~
0 iwJ: dutl. Wt--fln / 2 ~ ~ ,6-fcd,e_ (.p"T~poirpuq -1o
6 tlVV'l(!_ tl1d..tpe.nct-£Mf' -Ha.MLl.:tOI/\ ta.Y7, to <b~ paobltrlt\ ct-

e
e ~ +a-kfQv\a7 6~ w ~ i°c_u.seo/ OY1 @ rn .e.tltocl
om
0 Ll J - pe.,rlvcr ba.±:icvt
.c
e (i 1.J \J Q.)\La;OOV,
.e C
B
e ·tit 1J W1~ -LA. uAed wtie..v, i1-1e_

m
G
dt.viecl!ovi lrw r.--ohl.t.rvt& l ,oua.l ~-e:x_q_<:.±-} ~ ~TYta.Ll ~ ;+- h~d
he
-fu,.JD
0
••
.c
cM -itA-L ~~p-han it,a:¼ -ft,,_e_ P"°blem t>J'e. tu:tLd:- +o ),.O(l'.)e. f,g.

w
0
A>~~~ t7r01Yl
w
ct. p~Ple.n1 -t¼a:l: ~"' 'be. ~otud ex~

e
w
e ::1-¼- r~ ~uf~b\.t -ifcS' Cl;l..l_c..ulcd-t'-"1-fi,e.. ~t-d::-is-tbui-i 0v1 ~ociA.i:ed
•• . ~+vi ~ d..t u ta±iCIYl, tL1 i'h u ~hutioYt (! a..olc..l ~ ct unr~di~
w a.u e. tu v i ~ 1
• -to e.:11\C."l{"~ ~ e...'¥. c t ~ .i:,DI v ~ i u.. Hq rY1ilkrvl talYl,
• for1"V'Y~71-\e.o'd" u~-c_ C.7\Q...t.X 6ofl'1 -to Ob>4aivt qPrX-IM.Ct:.tt:

•• /400.
•
••
'1
H C/4r
0
:::.. e.,,,"' J ,.J 0
't'n
~ OiS"'ft~al Hatyift:JovtiCVYl H",, Ot!-1fnct1 j;o11t~ 'I/:, ( ul/7~-rbeai)
om
e; - <.xa.cl- .!,or1'1 o.fs !.,c.J1"n10U.V1r'i{ ei,,c.yrr
.c
C
B
yA
Tfr Man1~ia.m 11.. .e.,u,W:-°"/ pc·.rtt..rrc.D{ 61'. tCJH ~C4Ja"re.J:,7't1Ytcl1n'I

tr
is
ch:u"<r'- lvt C'..lf\~ 1A t1e

m
he
.c
w
w
f' es-'->f- o1!0Uo

w
Cttnr<e_tl:zetY1 ~ i 'YliYl .1oto.k:e. ~ e.n e.¥:1<f' , i~ ,-,at e!b c:. but-

~ b~ ~1alt.o~ ~ -e..1-rc.~Ovl v~ c.ant,r~pD ~7'-fo
Fo'11-)-Y l:,~ pcu± °i ·rktmUfcrniai,,, L,ul,,e.11\ LUC:. -fee.kc.. U7pe..Ttu¥b~
pw..k ;V\ ttw1&1c{-e.¥a:f:icrn o. ~ba-1
~re
11e¾' ~ j if; .tJ H w!, 01

dT
_j.
U'?~·hnrh<&>I
~vnr~· .,,.,jv.-1,<ol'

,.
~;1•9
. .·~ If?, 0 !:.
.
e"0 ~,.,. ·..,. . .. www.chemistryABC.com
•• 0•+(JH)(~ rcJ IP} ~ (e,; J-LJG) ( 'I',,,•,_"' 1/-'}

@
0
C
•• to-ft:d (.>')~Yr/ 66 nfh

t}
0
s~ a.tttk- -ftu.. 'ijf~<,s-
@
f' c.1r-iuabcd::bva ,
e
C Ie.a:b.Jire_ 1: ~+- c)"{cll"'" ef!.-rtU, ha±t'ovr -
mo
()
ti) Jt e. 6o/v q bf.t_ 6 t5fert1 }is /?ey-/-r;;y-f>cs>/ bd CD~ ti:. v Q,).,LQ /r, u.
.c
"Ko.~
G
0 -then. vaJ,.,.< °f C
e..,,c""l't c,,,..-~dia,,, bi:._u= ~ pcrlc:rrha:b';,,,, ""'o/
B
b'f !Mu.ht 1J f({t) l'Ahi!l?J,
yA
0 be_ oh~
C
tr
e
~ 1t ~cLt ih CJJJ111,t}~ +o box o-k,l..
is
m
e
he
G
.c
0
w
0 .1.
0
w
e & Q peoit-'ir bcd-,ern f6 f ¾!~ch; c.td a,b

w
•• O< :>l <.

-l 1-t1:::. V
•• 0 V
Y:z.
';_ C:::::.X <L
:)..
V =D
•
•• ""1\,e.VI e.'Vl~ CoaYe._t±:ian -to -,....,,e. nfi-t A.-+aie bt:'..u:ur~e. 1-
• ~ oird-!.Y p~ba:t"ldn
I
ie
•
l: 161 Download all notes by clicking here- www.chemistryABC.com
~H:.. V
.'/
o+ob
;i
l)
om
= V
-
.c
C
B
yA
(!
°b
tr
:X.. 1 1°he.V1 1} M 4- OTd.LY Cc,r,s-ec;;b~ o~-fD ~~<:.7tf't ~ -zcrc, ~

is
~
m
ul- H t O"'R.. <JH :::: :x:.3 i4.. fn-h-c cW~ a.I) 11,.,e.. p'(_......-tvr ho:b~ C
he
lvt l ...-0 S Ho
.c
w
w
w
ts
@
~
e
fJ
•
•
©I

•
••
.• %.ru.-Jv~W £s ~ •1•r,,.ffl;,,,, ~
••
@ ...
a,~ ht:. oh-la1111 ed
pt>A.t- "1, HtJmiiJ.rM.i,,_.,
p,w~--r 1 f",,_;-,,u,,
l:,t us7
~ --fhe,,,i
-ft,..,_ e11 c:r'Yf
--fke a Vt:Y~e y a.J.tu. ~

c,n-ed:t<r;J
t,
•• e-, · - 7-fr- wt. irt-hroduu pe.1,:lu-rbe.s:/_ paJ.l, '1J '1liMU..:7'on,4HI fJA /-D b1Jx
•• A.~e:.
'1, o-fo L ,
~
7ht!/n t>Mf t:rrei.tY e. n e_ytt G:,~d:/(/J,1 -Jo -ttv.. nf1,,
C
0
••
e
m
0
o
•e
.c
C
B
e
yA
••
tr
is
• @ 7f; peJJvyb~ pvJ-°IJ °6

m
HamilJzmiaNJ 1)/'--,rq(. d.L/t4 t;v11c:.hon

•
he
-H,,,l!!Yt -ti, e:... -e..v, e...~ esrcr?s·e_ dltYY1 b-e..c..a...uA ~ 'iJ-- pc:.,d-oot>~ ~
• 1
.c
••
w
¼-b_~taVl t..A:> o btcu..1A4..c:l h<f ma::l: "1e.~ ope.accl:fon °fy--

w
w
0 i~a. c. d.t.l:b:l tuV\c.:licrn,

•
••
• j iJ
00
-fr Co)
• ~J ,I(zj 4:x- "'
•• _ot:,
~
_J,.
(x-o)
•
••
•
• ii,~
J is
CX;I .
0c.1i (x.- 4.) i,lx}c:l~ www.chemistryABC.com
- -J;
:,t...:::.C, .
h
J /Jl"'-) cS (:x.-mJclx :::.1.
Q
o m
.c
C
B
yA
tr
is
m
he
j
.c
,.,./1)
~l::'1 = lf{ O.d H ty1 O _,
ut"T
w
w
-l
w
-==- j0 J-f StVP l ~ S(:x- ~J J-L.2.. 8r'VI ~ aJx.

L
0 @
j, e
Di?ra:e.. :l;- u ~ y va.Lu.t. r(;- .:;(_ ~ a
•e
@
@
@
•
•
@
e
e ==
-2..
L.
••
@
C, o
0
H?1 4'11
0
= £ 11o Ill
..,,-n
•
• ---rfi, c Aolu+itm &1nr~pt>11 d.f a' .fa •e. :x. Ott.k &Jl'Y1 1 ~Jnrodii,e"'l(
•e 1t b't <::JI-I
om
we. pe."b'-\'\.nrb~ ~t!. Harvii):}:o-niam
.c
V ,J,e.. VJ-e.u.> Ha MLllo111;av, f.&
e C
B
1-m= ~-+ tJH
yA
0 \
e t\1..-o..u -tu Yl cttt1YI 1--',
tr
e 4''YI -::: LtJ; +, l1 l./J

is
m
e
he
e Nau e -v,. e..11'{ -va.ltu. t/2

.c
e ~'Yl. =. ~ Qt10 + A£
w
~
w
e
w
e
e
if 1'1Ch~<m
•e So ltlew
al.be ~
rb_ n1 UJ-,,,,,jcm ,
&-b Y e ~ ,
h eu.,
h'?t::..ct~
q i,icl i,,eu., e:1,., "-1f'ft rvi us t
•
•• ~ t.p."¥1 =- Gn lf,.,
( H.:.,_ +,!H-l) l lJJ-n + tJ t.p) ::: & J Cl.f',,,, -r ~ Ip)

• O '1 0 -1- LJ E. 0
•
•
•
•
••
:: e..;-~. -/. Q;d q.,.,,.. d E,,, 1r,,
j
• 0
_,. r.:1 e..,,<J cµ 11
f,7tAt T<-Tm ~'lllol. /ajf fc.TM aAt.. vr~c:t:eD{ b(:ca.u~
om
OH fA J..Mo.t.l
,::1 l.J) 1A. hMal.l
.c
c1H tHJ) ~ if "?Si1,,i!.-Y /2"'1 all_~
B
C
v,~ch:s:J.
e.-, -d 4'
yA
6"1
t.:l -, 111 d'LLi¾e:/ V
tr
is
a
m
he
r,
w'
ea.cllt fe.c(1V1 f v, ci::> r~ il,i.e._ MLLL:ti p L L ~ 1J 0>1c. u11 pe..'1f'TUYb~
.c
~"11
w
,fe,,.,m ~ o111e..1 p.e."o4or-b~, ~1::> 11,-,, C!. ~ N..f,,..~~ f'1!1.e_

w
w
~+-~,r /:?<-'Y ~bc.d:iim,
To cl.J.¾~mi~e iiJ... 1Ja.luJ_ 1, .:1 t'n mu.J.fip"f bi t.p; ,r- O?tOVJ1 11,u__ lJ(rt',,&~ 0
~ ru:i-,~ W~'"?S'"~+ d_t a.J

• 12..
•e www.chemistryABC.com
•
G J~ ,;w,:' a(/J,n: - j w,,
···,
0
'1: e,,,•<J IJ!o/r -t j 'I?,,,°
~
.aH Ju,• d-C

•
G ~ ,() e,, f y;,;%c d-c
••
e
0
•e
e
om
••
.c
e J a '-P C H110 - g;) ~ 4'.,,,,o Jr cl r.
B
C
0
'd
A
H;, "-1;1-,,,• e,:

y
() / d (J) {_ 'lf - 'If' vi; 7:

tr
e
is
m
0
-:::. 0
•
he
••
.c
w
•
w
w
G
•
•• LJIE'dt) ::: J lPo (j).-1 tPo c/.;it'.
• -:- J lfo 1../Jo c/X.
•• =- t'1. }
;'/:X.
Lfo X lfo o/-'(
•• .::::.D
•
om
:::::.
., + v, -'
V I .I:
.c
'..l- 2 2
C
B
yA
-
tr
is
m
he
.c
w
w
E= ( "\•'bc.2.-+ 11~2+11n..; '!j2--

w
imf 2-
@
Vo l.3 J (;,L-0, 2.S L) A C!:J-o. 7Sl} CJ
••
••
•··.··· www.chemistryABC.com
•e J .$i>1 ~ [, (
L
¥
,.
G
0
,t.-o.:i.s) L S/>1 c/2.
•• Sivr 7f ,b
e 1-· '-I
()
e ' ~ Sil1~
S,),1 ~ StV\3:_ s;,,, 3;r SiVI~
•e - 8Vo . .,., L.t 1:i 4
St"t
"I '1
om
0 -:::. 8Vo )(l.
8
•
.c
- Vo C
B
yA
tr
•
is
:::: ~ .+-Va
m
O ~mt.~ - ~ ocM d:/ O

.-----------✓-:::
he
:@
.c
w
w
•
w
••
••
•
••
•
••
• • 169 Download all notes by clicking here- www.chemistryABC.com
. ' ;, .
"(f/l·fq J ·f ~ www.chemistryABC.com
. i
Cl
~5/2.
•
I
I
~
I
(j)
e. 2.. + e E C.-&0
l!Jf€D~
L -I
~cka:J
m
o
AE,:s_ <1 j lf-', s 40{ ~
.c
==- lPr.s 1.1'-l
C ,r
J S A"~-"¼. J &..e.s,ne cl&Jclip
B
..0 .,,,-.r::!Jt ,21("
"'a j
yA
'b-.?> a o
tr
is
m
he
.c
w
w
w

•
,:Jr ,a
@
~£~" = j ~ t311 QJ1do.: www.chemistryABC.com
•
@ : : .J
q
4'1 ( bq.- bx) \V ,~>t
-4
·~ 'f
@
@ "j 411 bq_ <JI1 <b<. - j '-Pt bx ..V, cl 'C.
-a -Q
@ 'l q
Cj ::. ba. J c.p, t.pJx -b_j '+', -'<.. lfJ o/-x,
-a -q
om
(;, @
() Lott!,.,,,,
.c
{1 ~ -Zn ae.Y\oral LU~~ a. ~f--te_M. c::l.U-h..n-b a-R un,-~cm //4 mo.ol.L •Vi °'°'~
r&. +uc. C t~ adcl.L-h.~ °ti-.
B
f3 ,6o/va.bu. o°ct''tf/Wl -tt,,01. , + berO-L'&e... -t1,t~,.<-
yA
C) H.a.milhm\a.Y> po.,..:r f\l\ 1J,u_ -e.xa~ --oolva. b Lt. Hct.tnulrtn i~n . (_ Xrtt
tr
: Ht,~LJ>.l ~ -tw.. w..ku 'i .tJ H ~ be_ -/.,J~cy/ - v~)

is
m
0
he
G
.c
@
w
0
w
w
0
G 0
••
½>
• j '-PYI t1 H <,I,., a/T
•• i)
j !t,.. £;171 S 'f'n ol:t. j 1/4t (-G) ~ cl.T

••
J.
i)
• - a:f -Si_
®
@;
•
®
®
@
•
~
om
®
2!-:a h~ + ~ Vo S'i:~2 ~ ~
.c
31_mL'l- -C ~L
~
; C
B
@?)
hz.i.,l- w~
yA
(£ -.::. -,.. 0 11.~ eJ\Jt!N1

~
g2.n'\ l-:2-
,,, ~-=- o-t:{c/
tr
t/V'9
:.--
®
is
L.,..
m
e
he
0~ +e, 0!3 @C '

.c
~ l
w
o rw -t rn B
w
· OM.-A.P'
:.(
w
'-x:2.. ~ 'l ~ .-1- 9.:2-

';I, ,:2.
.f.-q .,t-+q
2..
--
172 -,..
,(_...q
DPP 11 Quantum Chemistry . ~!' "'-
1. The first-0tdetcofteet16n°to energy for the.gr~undstate ofa particle-in-a-box (<J to L) due to a

CSIR MODEL PAPER ·
•
i perturbation).;x·woitld:1>e:(~11,E/2 (b): 1L{cf 2Xt (d). 2
2. A particle in a one dimensional harmonic oscillator in:x-direction is perturbed by a potential
'A,x (A is a number). The first-order correction to the energy of the ground state CSIR, June
('Qfis zero (b) is negative (c) is positive (d) maybe negative or positive but NOT zero.
3 A particle is confined to move in a 1D box of length L, the left half of the box is perturbed by
V 1 and right half of the box is perturbed by Vi/2, First order correction to the ground state
energy because of perturbation is . Pl-4vsics
(a)Vr/4:{#f1V1/4 (c) 5Vi/4 (d) 3Vi/2 (e) none _
4. Ffud:the.exact energies and wave functions of the ground and first excited states and specify
. theird~g~"era.ciesfoifuejnfinite cubic potential well V=O [ O<x<L, O<y<L , O<z<L] Now add
3
o o
~~iQll'.~\lipert~#~on: to the infinite cubic well Hp =VoL (x-0.25L) (y-. 75L) (z-0.25 L) o
'f4~r
om
Using· '-- : pertjrrbation theory 9alculate the energy of the ground state.
. 5. 1\51:f· Jt~'isitovenied by the potential V=(k/2)x 2 + (y/6)x3 + (b/24) x 4 usin,_g a hannonic
oscill<ltOr~aiiunpeiturbed problem; calculate the first order correction to. the ~riergyof the
.c
grotU.1qJ@eillsimpleharmonic oscillatoris ..........,:,:..:-, . _ {,~'111 : z . ~ _. .
C
6A hydrogen atom is in an electric field of strength € The Hamiltonian operator for .this system
B
is asgiyen,.JI= -(tj2 /2111e) A -(e /41tE 0 r) + e€rcos 0 ,,Toe first order conection to ground state
2 2
enetgyofhydrogen atom is (a) ei (b) en12 (c) e ~ € none e.€ h..41A8

A
:1. C2~~i9~19~ ~temerits . _.· . · .·-. >-vi,~ G' -i. .

y
{<lhMH:st,'qrd~rcorrection to the ground state energyjs the expectation value corresponding to

tr
pertut}ietf:pID't'ofliarhiltonian when we take perturbed part of function info consideration. f

is
-·. Cb);WA@,j'.qeyalue of first order energy correction because of perturbation becomes zero then
w; ~ppfi@.efgn.tl, orgyI" gr, highe.r .order perturbation; T
m
. (c) pdrturbation method generally apply when the deviation of the real system from ideality is
he
large. ~ <:'/ ·. ·-. · · ··

· Corrt!<;i·~hi'.temen& above are . .
.c
·.i) a;b~'(ii):W.b;(iii) ~li;fr(~ only(v) a only(vi) none

w
. ·. ··-., . . .
· ~ \Vhen~~pperate.P¢rturbed part of Hamiltonian H1=Psin <Don roatating particle Than first

w
order corre.'c_•_·_pon to tht! energ:y_,!f/, , . . ._ _ · _

w
(a)P · (b)J'>/2n (c) F2/4n2 -.\ca:J O . .

J).. Wie:q w.~:p~mrrbed.Swiple hainwnic oscillator by odd power of X then first order and second
f;;;; order energy c'orrection becomes equal to · · Zaro
'<--:, a)Constant (b) zero (c;) nonzero ( d) can not calculate
i ·-,.
1,0 Partic[ei~:confinecHo move in a 1D box of length-L to +L, the system is perturbed by b(a-x)
then flm(grder corr~tion to the ground state energy is ..~ .... Gate phys
•1'·'·1 11. A oD.~ensional box potential is perturbed so that it is raised by a constant amount, in o,
• the left half of the.box~ and lowered by oin the right half then first order correction in energy
••
. . (a}Zei'o in ground state because it'is symmetric but non zero in first excited state because it is
· ~tisymmetric ' ·".,. · ·
. . . ·. ~
. (b) Non, z:~9 ii;i_gi:9.u11d ,§ti:lte, b~caµs,e it is symmetric but zero in first excited state because it is
ai1.tisyminetric ·:(c)'Zero in both ground and first excited state
(d)non::.zef§mliotliground and first excited stafo

Ql2. Consider the statement

(a) first-order correction t<J the energy is the expectatior(value •for th·e perturbation
operatorcalc:ul~tecius{ng the wav~function ~f 1:he perturbed systel!!: •· ···••··F"
is
(b) Particle is confined to move in 1D box oflength L box perturbed by amount )...x.2 first order
correction to the energy is )..,I;/3. F
~When perturbative correction is applied on the ground state, the second order correction to
energy is.always positive
The correct statements above are (a) 1,2 (b) 2,3 (c) 1,3 (d) all (e)none ·
Ql3 Using first ...order perturbation theory, calculate the energy of the nth excited state for a
spinless
of
particle of mass m moving in an infinite potential well length 2L, with walls at x = 0 and x ==
2L: V==O in.side the box and V is infinite elsewhere ~qich is nwdified at the bottom by the.
om
· . folJowing perturbation V p =),V0'6 (x.:.L). ·
Q14. Determine the first order correction to the energyin!"iound state.frop:1. the following.
.c
figure(discuss~ i~Jhe cl~s) · ':\/i' >· . · . .
C
Q15. Calculate'the first otd~·correction to CIJ.ergyfor.apart,i~le in a 1-D box oflength a with the
B
potential V = xla inside the box and V =oo outside.. · . <?> .. .
yA
2
Q 16. Consider theJ!'fle-particle, )D system with potentiafet1ergy V = h / mz2 for , l/4 <x< 3l/4,
V=O for O<x~114 &114:.i}xt3V4 \\'hat result do you expect:(to first order) if the potential n?!ml2 is .
tr
treated as a perturbation. · · ,. /<" · · , ·

is
Ql 7; A particle is confined to move in 1. ;D box oflengtb_L Y=O

is inside· half of the wavelength
m
,V=0.1 E1° in the other half and V= infinite otherwise. Wh~re E1 O is the ground state energy.
in
Q 18.A particle is confined to move 1 Dbox ofleiigth,i~;(-a<x<a) if the system is pep:urbed <Yl::: 2.
he
byV='f>{x~(a/2)} then first oder energy correction to ;firstexcit~d srate is .. ~-- Gate Chem· ;;:::::::::
.c
Q 19 When we operate pertud:,edpartofHamilt01liaI1H1ffcos <l) on roatatingparticleThan.

first order correction to the m th state ofenergyis .~ ..... }:;;£ ...... (if 'I'==' (2nJ112elllllp for rotating
w
;~~~ ::::i:::) n ~ 1\. ~

w
confined to ;t~e ~~e. box of len.• if syst.em is perturbed by O{x-(1/2)}

C_:0
w
Then first order energy correction to the gro:und,stateis~llt::!1?:;..~Jt,.. .. CSIR CHEM

Q 21 A pa,rtic1e in a 1D harmonic oscillator in X directi()Il,IS"perturbed by a potential AX 0\, is a.
number). The first order correction to the energy of the ground state is CStR CHEM
· a}{s zero · ,. · b) is negative ·.· · · · · .
c)is positive d) may be negative ,p.Qsitive but not zero
22.Consideran infinite, one-dimension~ pptentj.al welloflength L, with walls atx= Oandx~L,
that is modified at the bottom by al'- perfurbatiori
,, £ ,
Vp(x): ·. ·
I'{ ) fv, 0 < :r < L,
l
x = oo, elsewhere,
· Using first order perturbation theory Find ~e value of Eu.. · ·

1
·'23 First• order
•
perturbation.
• • . • • •
correction
• 3
L\Eu.• " to the
•
energy
"
level En of a simp1 e hannonic oscillator
C '" ' • • • '
.. ;due to . anharmonicity perturbation yx: is gfl,eriby ·. .. . Gate Chem

1 1 1 1
a)L~E1/ =y b)~En = y2 c)Af1n =f ~ =0 ·

C(!§Y' . ~!' .
. j
,• ..
: q. www.chemistryABC.com
/J~~,, :: j tp11 V lp,,,. dz

0
tr '
-: : · j l.})11 ~ lP., d x
c)
- .Lx g_
q 2-
:::..l .
.2.
3¥4
J
¾
:. ·~ t~
om
1/,J'
lt'J/..2-
.c
C
B
y A
tr
is
m
2.
he
.c
w
~
w
w
-I

www.chemistryABC.com ··,:·
'
.J
J
:1
:1
:1
I
I
I
I
,, I
,.
om
:I
.c
C t
B
;.I
yA
tr
·•I
is
m
••
he
.c
w
••'
w
iv\ 1§-r'.&t' e x ~ ,&--(cde ots-

w
2.\'\a ~dJ;y C..o-nrt!t:H'dYI ll:'1 i!.V{(..1fo// I-- o Box-

,..,,,.. 2. l
•'
:,/
(J lJJ, dH 4{ciT); { j{¥3 .1H~ci-c)~ 1~ 4H<p~cl-r)2.. 4

t:z.--G ·f'z,_;'£3
""
C:2,.,... £'{ "'-· ..•
•
•
, '
·- DPP 12 Quantum Mechanics - --

@)An unperturbed 2 level system has energy eign value E 1 and E 2 and has energy
eignfunction[~] and[ ~ ] when perturbed its Hamiltonian is represented by!: :Z
i) The first order correction to E1 is (a) 4A (b) 2A (c) A (d) 0
ii)The second order correction to energy El is (a) 0 (b) A (c) A 2/E2-E 1 (d) A*2 /E2-E1
iii)The first order correction to the wavefunction is
0 A *I E2 - El O 1
(a)[A *I E2 - El ] (b) )[ O ] (c)[ 1 ] (d)[ 1]
Q2.Consider a particle in a one dimensional box of length 'a' with the following potential @
V(x) = oo
V(x) = ocG ,L
x<0
V(x) = 0 0 ::S x ::S ~(x) = V1 a/2 ::S x ::Sa

Dec CSI
"'
-:;::,
m
Starting with the standard particle
-
in a box Hamiltonian
-
as the zeroth
. order Hamiltonian
and the potential of V 1 from 'a/2' to 'a' as a perturbation, the first-order energy correction
o
to the ground state is
.c
(a) V1 (b) Vi/4
C
B
Q3. The unperturbed energy levels of a system are E:0 = 0, e: 1 ~ 2 and e:2=4. The second order
yA
correction to energy for tpe ground state in presence of the perturbation V for which V 1o =
2, V 20 = 4 and V 12 = 6 has been found to be June CSIR
tr
~6 (b)O (c)+6 (d)-8

is
- - '
m
Q4. For non-degenerate perturbation theory for ground state, with E(O) as zeroth order energy,
- 0 - --
he
E(l} as the first-order perturbation correction and Eo as the exact energy, which of the·
0 - - - -
.c
following is true? Dec 2011 CSIR -

w
(a) (ECO)+ E(l)) is always equal to Bo

w
- 0 0
tAE(O) + E(l)
w
E0 ) (d) E(O)
Ii _WJ \ 0 0 0
Q5. The following\areith~ three statements about perturbation theory June CSIR
Ii (A) Second order perturbation correction to the. ground state energy is ALWAYS
negati;~.--1' •
(B) Sum of the zeroth order and the first order corrections to the ground state energy is
I' oY e.i:t,\)al:\o -(.1.....0 - (AtwA'Y§kreater than the exact ground state e~ergy. .,-
(C) Sum of the zeroth order and first order correction to the ground state energy is less
than the exact state energy. f
I'
-1
I 1
From the following which one is correct?
! ;

[
(a) Only A is true · (\l113oth A and Bare true

(c) Only C is true ( d) Both B and C are true·
~ A particle in a I-dimensional box oflengtli Lis perturbed by a delta function potential, o(x
U4), in the middle of the box. The first order energy correction to the ground state will be
[Hint: f 00 f(x)o(x - a)dx = f(a)]

J+oo
(a) 0 (b(I/L (c) IJ2 (d) 2/L
Q7.An eigenstate of energy satisfies H'l'n = En'l'n• In the presence of and extra constant potential
~ . . . .
. Vo. · ·. June_CfilR
a)Both En and 'l'n will change.b)Bqth En and the average kinetic energfwill ·change.
-
om
. . . ~
"':}()nly En will, but not 'l'n d)Only 'l'n will change, but not En.
.c
Q&.A paqicJe is in a one-dime.nsional box with a. potential V=O inside the box and infinite
~ outside. An· energy state corresponding to n O (n: quantum n~ber) is not allowed
because CSIR C ·
B
'
A
'
a)The total energy becomes zero b)The average momentum becomes zero
y
~hewave function ~mes zero everywhere d)The potential Vo= 0

tr
Q9. A hydrogen atom.is in an electric .field of str~rtgtld:'. The H~llliltcmian operator for this system is as
is
given H= -(lj 2 /2II1e) !.12 -(e2/4xE0 r) + e€rcos 0 , The se.cond order correction to ground state energy of
m
hydrogen atom (till 4 term) is ...•........

he
Q lQA particle is con.fined to move in 1 D box of length L V:c,::O i.s insi4e half of the wavelength ,V~0.1
.c
E1° in the .other half and V= infinite other wise. Where E 1° is the ground state energy. Find the first order
· . and second· e>rder energy correction (till 2·term ) .in perturbation theory. And write also the wave.function
w
corresponding to second order.perturbation

w
@})A particle in a I-dimensional box of length L is perturbed as given in figure the first ,orqer
w
c:orrection 'in ground state energy is . ·
(figure shoulctbe giv~n in the class)
a)V b)V/L c)V/2L d) None -0

~ i.,::::::..---~-
0
lv
6iz)consider the stat~ments
i) Variational method does not :require the knowledge of simpler Hamiltonian which solution is kno~..
exactly. · . ,---.. ,
· ii)Trialwavefunction in variational principle should taken int9,account all the physical property of that
states for which function is taken as trial wav~ function.
iii)Variational parameter are adjustable in nature ,that is used to minimize the en:egy that is calculated by•
trial wave function:

••'""'"°''"'"11!1i-:;·~~i:,~:~·)'~12. .
·..:."',',
L - 0' "10 : 2.
'C:.O -
V.,2.o :: LI
. .
v12. =6
()Ef" " ( j ~ tJH

to - c,
'fo:!_-rJ ~(!~. 4H %
- el> - £
'Y: .
l-
2.. :a. 2....

:::. df-110 .dHzo -1- ~H3,o
+ __.
t,l>..-1:., e,-€2.. .eu--e.3
·,
. .
. 2,
-- v,6,.. V.2:0
+·
----- .
~
£,,_;.£, "'" E. ;..€J.

~
om
.
.c
C
B
yA
tr
is
m
he
<!. 4',: dH i.p,:,ctt > (. l/,..; '1/:/ ,p; c/T'?

.c
~91-E1t1
w
w
w

..
j '11.s dH tp,.s t:/'-C --:=. O
J, i
./Jl8.{; Si>18c/~ =-~
1)
om
J W=4,._ <! H <P1.s <-l t 4--v
.c
4 -t . JS1n6c/~c::b/> C
B
". fM ft
yA
C.~c
f
tr
u.i-e sinec:Je = '%

is
D
m
he
.c
w
'If> .
-ai<-Yft tt:. al ••·l::l ~ -ye

u
w
w
.,,fi1J = 1/-',.. tJH i.p.,, ort) '2-.

£1) - r;IY}

e 4'M "? < 4'm l<3H 14'.,,;;,

0 O O
•
© e,;-£,n°
®
~ ~
~
® !.I{ .dH l/1, c/ T o/.. + 4!a IJHt.pdt '-P-3-,.. ....... .
C) G. ,- £:i f,- €.3
om
.c
+
C
B
y A
tr
J.<'.:
is
€JV =- % " 1-l yi!,t' I'

m
he
...- <..4-J,,," tJH trfV\ > ~ taH I "J:PY1"?

.c
,:::
w
....
I;;.. )1- (:.,/VJ
w
w
tid." = j if,,, bH ~d-r -

¼,

,e{iJ 1
.:', E'n°~:GM 1 ';i . .
I
_/2.7 -
~l:.? -
LJ,.,.,~ o. l n 2.
@:rvtt:l...
g , -::. J.,.2.
~rvtl2..
12. .Sf VI 2. 7f 3(
.J t: L
om
.c
C
B
yA
tr
Iv
is
m
he
0 ..J
i:}
X.
O V:::: 0 @;
.c
'?(-:::.
l "* vx
7: '] ,c_::::. L V -
w
7:i - u
V (@
w
{"£0
'iJ- -=- /YIX. "-..::: L V:::.. t/
w
~
1%~
0
(~
~
@
®
~
•
~
®
@j
•
•
E 2..
I www.chemistryABC.com
w,cc [U ~C, f ~J
H n]" r:,[t J
H [ ol J f:2-(~J
c:
J
dH
[~':J[~J =-
..,
fi1
tJ""/\'
XI + ll'l! ~
-+ €..1 'Xt>
J [~,J
0 e.,
] [~~J
om
0
[:, ;J [0 ~ [ 0><6
1( o+ r-xu
r,
+ E..z_X1-
.c
e
() C
B
lrii>
A
0
W'
y
0 < 4', .dH 4', )'

tr
(i>
< uf P· ~J[~]
is
'7
m
~ ] UJ 7
he
< [t o) [ ~"
.c
0
c,o] c;,.J /
w
© <
w
0
w
0
Q
@
~ 2..
@
"
€)
@
(fi)
----
< ltt OH '-1'1
e,.-£'2.
<[~ ]p-.. 1JO J) : ( [
/
D I ] [ ~'t ] J 2-
@
C
0
~
~-
* 183 Download all notes by clicking here- www.chemistryABC.com
~;;'"\laxialt"~ Atiilldp~~q - · ·
.. , .. ... . . /><:vto.Ji"'ir;, 1f'- lohwf~ r~ ·la""?e· www.chemistryABC.com
7t,a--e ~ts.+~ "f\11.tJ "' I" ~te.w, i 111 Q. M w 1.u.'cM i"'1 .,,, U.:kM k:tJ.? ;~ k"' o-w;,
h,.J.! ~ ea.Ml+ be. ~ol\Jed e.~~crfl... b{ pe>dt,~btrl-tve.
~eu.r t,e. -tl,uh.L ,~ vto ~~ ~ H4mil:.km~ -HN:J-
CoVJ be.. ~o ll)-eol exo..~ <:rI<. q pp/...A:>~ r~ ~ f e_y fu"T bo.:b"'tm
-/W.D~. lJYle_ 'i -f1.-o_, ap p..oxiMa:1-lO'Y? ~ ~ ~ t,.t.u:/Ql,U
if'<> A,ol \J fnr ~e P'° {:, U 1ll1S , /2 'Y a.,.la..:Hrv, IVl,dl,,«I.. ~ Y1A dtttx:J
dtJ ~ 'nor ~\Y< l<.tyll)U.) !~ °1r .-61 MP Lt. 7 Ha rni..lto'>? ,'cv,,, ~
Col)lt be -6Dlvecil e.x.a~ &o t+ M CIJ)n~ich.A.ul ~ a.tta"Yltd-e. to
A.Ut~ ~ e,
om
'l?,
<f),1- t~ q n!f R.:-- .fls-lal " ' 1 ~ fn w w.Lh we 1qf<~ q h-lo.J
.c
b,Jo..,e t;un.Ji"tfYI -ib ci,l,e;,.m ,•J,,u_ -/tu. a v ~ 1/a.l.uJ... "Q o 1
B
C ey'J1 -,,;
Ln~'"'i't "ti m4.1. m~»1uA.f-be_irre:a:la
yA
1tu- va1.t.u.1 ~ ~
°6
tr
t ¥.Acf- /41/?'\ 7i, CRJ. wlair. +t,,, m I~,;,,, v JH e.J?(.~ , w~ tl>Yi& blt.-
is
~i~ @) /2fe.p,'>
m
11.u.
he
(f) ~ fiu.- hiaJ. wa1v~fJ'-ncl:l:m-,

.c
8~ 17117W ph~iui.1
w
~~
f11f!Mlv-fiC1Yt r,1q_l<:.e.
1ut!J,/2 °fr w::nr~V1.drv>1
w
Qv, t:!4.
w
~ ~k.e,_, t \d:-o O..t<:J)Ui,d:- a.ti -ttu.. p~l°CAJ (->~/Vlete.,t!, °f) 74.e.

,/2W-~ ( Sz1rnrvi~1 'l-1~1 be.l!lt:t.Via-u.A- a..t:- fw1)t4 ), W-e a.QI:)
tV\ c.. \ udJ. &.cm, e. ac.( Jl.JA+ct bLt. f>a:"<S am e4,e 7t 01{ and' ~ rb,°u.°tf
°5 Un 1t')'ltMJJ'l1 r~r~ q nd --fo MIYli ~;<t:..t -th~ e_'ne~,

·•~
{Qus-1 ff +,;ioJ. Wt:We if ncGen, (/I = ~ (A,--'X) l:S p--ropo~e;J fr' q
ptuJ-r'°cu fyt C,'J,tl- D /-:,ox ~ /1,,J_ valw 1r ~Vteirrr if'ott,,,~ wa.v~'Jlldl0>1

1..s
( lJ e =- i,, ~
fi& 1Y1l 2..
( :2..J
-
Sol'Y1 -
o m
.c
C
B
::::.
yA
tr
e..V1cirrt 15 Ma.I.. .IA.}d,vt: & J11tbbn wW

is
m
Ju._ ~ 4 t/A4M ~ 1 .t.x~d-

he
~ tv YI d:fth) ~'Ytti.J.J.l,
.c
w
(Ws - 1 If- ·-hrta.1 WaJv~ ft'Vl d-101 t.p l '1 ) =' x{_~ ,-'X ) (,l- ~
w
t• T~ va.lw. j ~
w
1/2 fV-.pw,c,,/ ~~Ll.t_ iYI l~D box,

~ fuih w-o.N!_ tu Ylttlo-Y1,
t.f)(~, =- ?(({-:}{) {.t-?t)
to cw.Li< -fw.. 'Y!erdt - C/J c.: 0
?l_-:::--0
x_-c.0 b, uhd4o/
,,_
) -'JC..:;_ 0 ?(_ :::..~ _, ?1 crel.t -, €!!>-===? Slt:lfe,
2-
2..
?r-2..
)_-x c. a ?(;:::_..,..(
b-uV 11, al_4,<I
6lus- 3 /fl Mal t.,JONe.'/;.mWm ,.-i..,t t's P,,,f70!.""1 1/'-ra,y, d . J ~ :
1tJd~1c a:l:rm,, f,s N (.3-a-) e:.- P,,- a.111cl -ftu. t:.',/'Je~ ~ , . ti

~ ~ l,tJfW(:. t;,n,t.:fi&v1 iff , T1A..J.. ~-x:a.d- ~-N:/ ~-lcd-e... l.JJO..Ai+ndio-r, ~
Clr(Tar7°"7' fr; fw- hyd~K- a:bm itS N,e-o- wi-rn ~Id,
[tu. Dr'lfS.f- t:.,<a'°+e4 ~-/t:Je._WON~ t;unCft1'>1 6tro1rq~-#7 -/t:J ¥~c
c.,A-ctw, lh N-:,.. (_ 2-:--) e.- dl(a- w I 11,,,, ~ €:;_
°6 ~ u-r;red-
om
wJ.t.tc.h 0),1.,I. ~t)Y)~
.c
e:i. 7 G / e, . C
B
Lb)
yA
(c.,:; € i. :: E 7 €1
tr
is
W l '?t;,_
m
tp ::: AJ { 8-c:-) e- ~er

he
.c
1'J ( 3-cr) e. . . ea-

w
e-acr:. 0
<£i£) rYiodL
w
fi~) h!un~
w
➔ £nc~ i 0
~Al LuQ,ye j;-;nc:h lTY) wW be dm?p~~eo/
-re -e\'\er-c1, 'i -<.~a a- ff 11t:bm 1 .«:,me. ,&-/a,k

,,;':,•~ '&f .· .C!t41wlllli ·thi 61~-r-ft/ ~··~ . f&Sfutti:tc if Qn.j~ · · QU
•
• €4> C . J tp H tj:)dT
& J cp cpclT-
@
@ we tlf fw. ,v a.1uJ. 6t 72 f n -te<>'YI~ ~ Pf', f>
: @ To m1n1ml'u 11,u. va.lu..l °6 €Me?f'ft d.ttft--r-l!M:ha:1:e. -tt,..,. ~ f
c) e..1t1c'"'t! w . 7r,.+. o4ju&-klhu.. ~?s"a Md€'¥' cr.;(., !$) ~ ~ ~ val..u.tcrfr
,.., °'1) u6-tt:t b l.t bllo"4 rn ~o-.
e
-J"' -- o
de l
@
~ =O
0. Jf
m
e
o
8a tJ.iJ'°7
.c
0
(j
® vaLw "6 -r',8 de. ln ~ ~ 8?r~,C we F
r.,, f'O(.J,1,,1,. ci) . we~ f!_±n
B
val.tu "t 0Uhft
yA
()
@
tr
is
Q
m
0
he
e -
-Ii; 2. /) -t- (YJ w 2.
€
.c
@ -=- --- L. _____.

elm · 8C
w
e 0
6) if~ ~ va.Lu.Li va.>J.a.;b"'cMCLl pa.J.a.Mele1J

w
@
w
~ .2. ,. " r.2.

E)
k r, .::.0 =!) Y/ .... ~ :: CJ
Q JC.. ~ ~c,_
•
G
mwa. _ 172-
-
8'C 2. -
- d(/il
•• C "- =
, L 2- .rr_
,,t;"Pi~ al_cc_'f_rr........_--.1::_)
•
•
•
• -
•
~Lt -k'!>S 2.::: t m 2w 2-

8. 2- ;::_ J!5:Jj.P1D
om
.c
C
B
yA
tr
is
m
he
.c
r:
w
~ .::
w
w
lf-;, '2-
~'l-
ei
fnGo(. ,
--
J'fti 2-
;tfllt..
'1 fY1{ l, '2..
o( C ____..-:
ll &el["-/; z_.

t1H. 'i;' €o [-°t'j;ri) Y,,8 a {Jr} "-1 e . .r ;2. . ,
e,fJ ::. Jl/{ - t.p~c/'1..

t!JH :::.
J l ~ Cle_ ,. l' 1-fg)"( :£2.
(-<.. .2.) k - <~
r,-;. ff I
Y<I. .;.. a(_J
e
: : (-<2..J½. ~ {!. j 1f e-~2.~.2. ::c. 11 e-~~A .·

Jr
0
to '1 -Gil! J:•.,c:'' e _ o.e'lx '2...
"'•'.
, .. ·., .1
.
DPP 13 QUANTUM CHEMISTRY .
. . . . -::-#0
I.The first order correction m the function m perturbation theory for nth state 1s ••...•••. :. . •• ••••
I:)
. ·~ { lll7'. <.lf)~A"i~111>
~
•
e.,._- EM
2.The wave function for a 1D SHO is 'l'o (a 2ln)2 5 e--02xzt2 for the ground state, perturbed by Eo
(axil 0)4 .the first order change in groµnd state energy is Gate Physics
4 4 4 4
(a) (Eo/2)10 (ef3Eo/4)10 (c) (3Eo)l0 (d) (Eo)l0
3.A certain 2-level system has stationary state energies E1 and E2(E 1<E2) and with normalized
wave functions <p 1 and <pz respectively. In the presence of a perturbation, the second-order
correction to the energy for the first state will be CSIR Chem
~<P,IVJ'h) 2. ~"1IV1""2)
l. E.t.-Hz Ei,,-E,.
' \k"' [{1P,IVI.P.2)F
4•
l(q,,JVl9>2H"'
• E~-Ez @'1-IS':.)"'
4. Calculate the variational energy of a particle in a hard one-dimensional box oflength a, using
.. Jhe variation function ¢(x) Ax(a x). i: ~ fYi el'l~'Y~
om
i)Variational principle is valid for ground state only. F
.c
.,..:,i,i) If the variational function is orthogonal to exact solutions to the Schrodinger equation that·
..ht~ . correspond to allthe states oflowei:.energy than ~e ~tale Wf? ~ interested in, the variational
-~ . principle. .
~ iii) Th Ritz method resents a special kind of variational method. The trial function <D is
C
· . ➔ C.i,,oli.11M1 -tl,,ar Va.N.td!Kn1 'f"'nUJ.7U. GtppUc..:.{ fO ohu.1r .&~,
B
\:Y
A
re ......... ,. ..,".... the known basis functions {'l'i} with the (for the moment)
y
u
tr
The correct statements above are

a)i,ii i,(ii,iii c)i,ii,iii d)i,iii e) i only
is
.
6) A trial function used in the variational method for the hydrogen atom had the form: 'I' =
m
exp(-c1r) +c2 ~xp-r/2). From a variational procedure we obtained:

he
a)cl=c2 0· cl=·l c2=0·c)cl 0 c2 l·d)cl=l c2=1

' , ' ' ♦ ' '
7 In the Ritz method (M terms) we obtain approximate wave functions only for:
a) the ground state; b) the ~round state and M excited states; ~states; d) one electron
.c
systems.
w
§..Ina variational method, four,,,class~s-of~tpal functions have been applied and-the total energy
w
computed. The exact value of the energy is equal to-50.2 eV. Choose the best approximation to
w
this value obtained in correct calculations:

'c!)-48.2 eV; b)-50.5 eV; c)-45.3 eV; d)-43.0 eV.
9. In the Ritz method (cl> stands for the triaL:function, AH the Hamiltonian, E0 the exact ground-
state energy, 'l'o the exact ground-state :wave function, a= <DIHAcI>/_ cI>lcI>) the trial function cl> is
always a linear combination of:
a) orthon9flllal functions; b) unknown functions to be found in the procedure; c) eig~mfunctions
··•; of'H; llj1mown functions
•.•
·. . I
I 0Variationalmethod cl> stands for the trial function, H the Hamiltonian, Eo the exact ground-
state energy, and 'l'o the exact ground-state wave function, a= cl>HAcI>/cI>cI> If c = Eo, this means
' :., that:

2
~O= cl>; b) lcI>l = 1; crwo
=cl>; d) 'l'o= Eo
;~ : . :11. A trial wavefunction used in SHO e-cxz was used and energy value was obtained
2
as
(1} C/2m)+(mro2/8C) The minimum value of energy that was obtained by variation~ principle is
.. i

·: I.
. .
-I
I
I
i .'
•(~/2 (b)lj.ro (c) ljro/4 (d)21jro

· j 2. Which of the valiational function have acceptability for a particle confined to move in ID,,,
2 2
box oflength Lis (a) x (b) x ('6Yx (a-x)2 (d) all are acceptable
13.A trial wave function for SHO was proposed i.e 'l'=(~x2 - l)e•~x2 if the energy calculated by
this function is E than ~ich of the below is correct
(a)E >0.5 ljro ~ > 2.5 ljro (c) E >3.5 ljro (d) E >4.5 ljro
14.Assume that for a real system a real function is a linear combination of two orthonormal set of
wavefunction Where the energy integrals are Hu= -15, H 12 =H21=-l, Evaluate the. approximate
~ue of energy of real system and determine the coefficient of the expansion 'l'=C 1 <D 1 + C 2 (l)2
~onsider the statement l-12.!Le - 3>
i) energy calculated by perturbation theory may be higher or lower than exact value of energy.
ii) Ruckel method is an assumption, in which 1t ,O' part oftqe bonding in molecule can be
separated.
m
iii)Inhuckel approximation all the overlap in adjacent atom is considered as Zero. T
o
Correct statements above are (a)ii,iii (b) i,iii (c) i,ii fd) all (e)none
(1:nt
.c
5
.. ~normaliz~ slater orbital ~or IS orbital in Helium atom is '111s= (Zetr /ao)l.5 e·Ze/a Its
leads to-followmg energy e /ao[Zetr- (27/8)Zetr] Treat ZetraS a vanattonal parameter
C
B
. caIJul~te the min energy.
):]By using trial wave function e.ur the energy calculated by variational principle is (m:;2/21Dea)~(tl/4€0a 2)
yA
.;Jhe value of variational parameter a is ...................... And the minimum value of energy obtained
. . frolll variational principle is ............... .
tr
. ·::., · 0 .. ,• - : : -~:.: ;:J" '\\.~• .' ..

is
·: ~he energy calculated for a multi electron atom using variational function is E=(alj 2 /m)-a21j
m
,, ...· · TJ:te.yalue of variational parameter a is

;,:;;:~:,,~~4-;'?.~-~~~(f:~.~--'~ . : ·: .
he
t;\t:"',(a.\)¥:· Mijl2m (c) 21j/m (d) ljm (e)none

r,·___ . ;'c,J '~,·omzation potential of hydrogen atom is 13.6 eV. The first ionization potential of a
.c
"'"suming that energy of its outer electron can be represented by H-atom like model
.
w
clear charge 1.84

.
is .
Gate 2007 Chemistry
w
1.5 eV (c) 5.1 eV (d) 2.9 eV .

w
ction used in SHO ~xe•~xz was used and energy value was obtained as
2
' /8~) The minimum value of Pis
;(m(o/li c) 2m(o/h c;I) none of these ~

ments \ "V\o,elk . / Mt>
" ,,,,,,... ::.,;:-- I
:on{2-r)e-nr is suitable for an electron in 2p orbital. r
)ul~f the energy calculated with arty function(? obeying the same
·· th<'?correct system wave functions cannot be lower than ~gs. -r
· · ·!h more than one parameter can produce impressive result but price we
· y~alculation. -r
t;_ a)i,}i,iii b) ii,iii c) i,ii d) i,iii . ..,
~I,.Jti~e5.wave functio9,is given asr(a-r)"Pr (a and~ are constants). This .
,·✓~,- • . a) 2s b) 3p c) 4d d) 5f
.
_.,~.:,~f:8 .......

... ·. . '' . 1l'

., '
1'(1Ddn,-:: 2. .
< @ To ~ -ttnc. atc.e.ptabHl~ °cr lJ.JO,rj/f!, 1fnd:lrm

-=fi'a'St- 1,- a.LL ~mine. -f1.-..t ,rol.u.t a{, -e..Ytq1J
a""cl -ivle\11 ca.lwb!-e. X ~a'lllqe. lYI c 'YlC'l"'r;f ~ f+- ~ +-vc
roo"'d>1. ~ v~c/.
om
.c
C
B
yA
tr
is
m
he
lei
.c
w
.·j {-.b_.
•~ L )-xa.. c/x
w
:Jl 1.. :2..

~Jt? JXz. .
w
J XL?<¾dX
f. x._'L
. l
/_1,2.
cfli"/
..2.)c:lx.. /
/j '>tYd,;x..
.
we
- '1
' /1111
1
J ,c,ric:l-x
.
i'his
j:xlfdx.;

. . --· '
.: · .Q~eaA- ·v ~ 4 1 . f>?r:inclpl!:-- www.chemistryABC.com
11 bF 1:Jpe- ~ \fctJt1a:bm1
wfd_¾ u~ .f.,, ~~ ~ ,Moltw.iD 1~ ~o Coll~ u1,1eQ.A
\j~CMCU.. if,vtdic,1,1, C\ UII\~ C011'1bino.:h'°O'Y,1 ~ 1'7 fn~

~VJ t:ft WI i, i ~ · · · .· i'YJ (o'f>~ t.d-a \L o,r bi-\ctl ) -rt,.tl ~od:,.1:..-rt M
-tlJ- b\lO'Yl c\d."t eomdf hon o-fs- p~ bu. m,
t V\ d?tCIYI YV\ ~ ·1,, e.__ ~ l::le.'v\ ~
4! ~ z. C.i '6i
tw.. ~~ -e.A.d: C.i. Ct.A.t ~ pb..hO. n,,e}--ui_ e"a\11 b c.. ~ lVI i ~ bi
... ..
('Y1lY\ 11V\.t~ l
"' ..,I
vi..a, ~ e.._\1e.~,
om
'l'V\ Lu,\~ '\i~U\.1cJ. ~tlllU plt. 9 ~ -h,:,a.( l..aJt«Uc:. fiuv,d,'trv)
li~ d.L,x- 1'1 d l-\d- O'V\ 1l,\e. pa..1t"a_ md-ey s
.c
-
1
. '
App~- C
B
Gtp pli.CQh u. · LVl ~+ud.f~ mo,; vr3,; 1-1 Mo7
yA
t.uid~
/?t.d- m"-:J ·h~ pf~ --fo ,-s iYl-1 plL ~ <f-k1V1 a.Ju,.
tr
C-f.
is
~we_-i"C\.k ~~~if'\f\~D\-\ if"" ~ ~1VV\pll.Y ~~teM1 °-6 P7B 116

m
he
(lJ 4-' ~ C 1 =t.(_,l-X)

L J
.c
J.. Li iJ 4-'::: c, ?( ( 1.-:X.) + Cl.-xY...t-;x.) 2 1

w
(i_i.,) tp ~ Ctxt....t-~] t c'l.::,c(,(.-xJ-i.+~::,c_3(l-~J3 4

w
I
w
i+- ~ ifu-vicl ~ ~ -tw. 'Ylo. °t '\JaJJh:.b"'~ pwzro.meA:e_-r1l~
-tt,u._ a..c._('__u1(~°t °'ls ~utl- ·fntcl'eLU..~ mea~ l~«' fw. u-uu°-,., a&--
~ -hrfa.L l.l.Xl'-l:1J'Y':t:H'OJ1, C.l<½-e.o: t+~ ~\rle,s-~ ~ -tL,...o. ~:x.ctc.± e..ne"'~
SJ-p1r1'dtL we h.A.UE>- ff>_ p~ i;., LiM~"thd' rno:t1'1e_rv1a:h°CJli e.o1_wl41Lm?.

_ -t:.D ~ev,eml~ we UJ.»e Cib1Y1pu+e.-< Fq-?r4nm,J '1' jf r_ -fti ~ pu-
0
11 po&e.

- -i-wo ~i¢J. W(J)/t! 1JuV1dftTH11,
.. ~
c, :,t (Q ... :::ic_) -=. 4',
. 2../', 2.-
Ct x. (4-x) -+ <1.::>c.: \...q .. x) = tp~
f Ve. o= V1 ol ,(,1-al "-- "--'ti>~ tr K,. r ,_ 1f-.- q Mb• I,(; r,,"(.. pru:1:t'"d..t. ,..,,
1- o 8• "· B<f u,. f "'3 1/lV,J°,:,J,utw1 mdt,,rr;/, I.fr- <1C<t d- ~nd .t.+.:J:e
e"' ~ J1:. G C, w hAl- !'1:. -/iu. MJ.a.t,~?
~~
A naJ.Jich. f.,,, 1-D Bolf
r-- ha.! 4-am,nc/ 1oWt:.
u
~e~
-,q
i;a = D~"-
~~
tfM- e. i<(X- ~-rn),"c,,,i V "1w., ct -fw.. Q ho V C Hq r>11'ik-il 0 , Lu l ,-,_, f I? d-1~
m
4Jt_-x.) = X l'X-Q ) 'diek/.. £ I
o
u.i.1Yl'J' '15- -lw-~ eJVeM f;u.,, t-hi:,,,,J .r
.c
<1 /,tne4.,1.,, &yy, bt'mHwi :x.t:x.---a.) ~>(-x-4
obW,,,, tw. min en<.Y'71 e'J- . C

B
J.>)e._
A
c., x l?l.-4)
y
411.::. - £, I
tr
= CI ::d..11.. --4 J ../- <l. x,::1- ( :l'..--<U" ~ 6'J..

is
Ip 2-
m
et)<- £':l- < g,

he
.c
</!, 7!e- .A.of! °t ~e:,.t... v ~ if"c:t,c,,, !J.A#-!. -k, Sec.ul':"Y

w
e beh:irmi»o.l:e-
w
•
w
le.l:- 0.1:. C.0¥\~fd.t"ll' LV ,~ C\. U-Ytea.J... va.>JD.:H~t,11CHdl?

• ~ 4>:i~
• f~ ,&UMM cd:fO"V) -two o..ia.ue. trvicJ:t""OYt q>' 4
•• [ 4J = c., 4' I H2. h l

•
••
•
•
•
•
1(C1 i + C;,_<f>,J H ( (,4', .j. <i<t>S"'T . www.chemistryABC.com
~-
•11
Jlc, 'Pt +~4>:,.J ( (, 4,..,. c..l-<:1>l,J ctr .fi
•
~
J Ct~, H c,4>d-r~ J~cp 1 H(,._tp:,.d:t rjc_,d> 1H(~d,~d.T1 C2-'P,l-f<,c/drti

,C.;,
~
J c, ct,, y 4, cl L 1c.J, 1- c.,_ ~q nJ Lt ftc,J,,,_d-r +J cAc, ~,J-c •
-...
om
.c
C
B
yA
tr
is
j
m
cp i H 'PJ ol '!. -= HfJ

he
j <4>,
.c
<f',,H cf>;i...°''t -=- 1-11 1 = IH1<pl-,'7

w
j , ,

w
!)., H .f,, d.-r. ::: H.:J..t

w
J 4>t <f> l ol 1'. =Sri ] ov tJJ.qp maM,l.'x eh.mt.Mr IC)yo_ /Qp rW:-,-,al.
Jc/>i q>j o/7: -=- s u '
~
~
e
•
•
•
•
®
l Hu - f. Su Jc.,+ (l--112. - f2St:i.) C.2.. :: o
G
() (H.1.1 - £ S:u )c.., -t ( H2.2. - G.S:1.1) C2..::: o
&
@
q
I
C" q
0 .s,, H,2. - tS 1i.
1--1 11 - G c, :::o
@ ca..
HJ.,. - t.S!>.,.
@ H2.., -<E.5i.t
(}}
om
f)
.c
®
C C
B
A
G
y
C
tr
H·u -::...-<
is
CJ \.-t l 1- .e ~
m
@
$u,; I
he
fJ
•e
S,2. 1 ::. 0
.c
w
w
•
w
•
•• Hu -ESu
•
•• . - ... . - -
••
• .. ... - - . "" \
•
!ff:,_',;;,.'u1H11· ~mi:.,,~ cam·•.· bt.·J.&~· +o obktlvt{~;~~r~ ;·~~<; .
4 ' ...
lJ..11S1fttV\1 e.cl f-v1 1~ C.1" eAJ.:."'a cn-d.l.!o at C.'W\~ e..ca.t.i;, ~ L.o._uc. ii.'\<..
-e\n~~ l l l ~ -t1AaLM. i1,t.o. -hu.t. ~Y't't bu.I:-

in vaAU:t.:b'°tnll #tt:Al-M IAlt!

,I
t
t.l,61);!£ mi)'l}mum vai.uL 'iJ e M ~ 1 &o &rna.Llu. -f ~ol?? (itrOf) 1 ftu. .U:,l? ®
~ f Y<!. 11A.a. e Vl.t..~
~ l 1n cl4!kt -ftu. val.tu 1J St'i ~ .Sfi f& mu!-3-tv&11 f!AIA1 -thvn w-e
Off1;/ &mdL~l-trin a/; o'otnf>11oama.J /4ef &ii = I .StJ =- o
rlM..-hs-fa.l W-4.Ue. if"d::iav, oi- a 6~~ f-4. ~~pet)1d.J.cJ~

qJ -=- C.' 4> t .+ (. :l--cl>'l.,
m
< cpI H q,, ,. = D
o
.c
@]
~ CF1. P·-1 I 4J, ? = .2. ~ C < tp'I- l HI 4>.1 > ,_,it a"R. Ht 2.. ~
B
yA
< 'Pl. HO 4>,. > = 3 -== 1-122.

tr
is
m
he
E' :::
.c
w
w
w
:::. 0
_3f:-tE.2-Lf =.. O
E'2._ 3 E -4 ::..o
0
E2:..4E + t; -4-::.
196
t;: ( €-<.t} + f (€'-ti) :;
0
@· OPP- l3
@ 1~ ~~ a,wibtY\a:t\hYt 4u.,o1fY1dia-n ,aµU-l be 1J-
({)
•
@
~ a W\11 e.. ciA.o."2l'a~2(,
(J c1= l
C::1.= D
u, -= e-A... -+ e.-.It/:.>- (i)
om
,l -1,
4', ~ '-"1.S
.c
C
B
yA
tr
is
m
he
.c
•• (l!,, + £5.11) (1 + (!J,-,__- fl5/l} (,_ "' D

w
w
w
• (ti,_, - t.S1,) C( f CHU rt s'l-,) (.'J. C--0

•
••
•
••
••
•
. : . ' '
•••
Hfjd~ii·~·www.chemistryABC.com
. r£&'jS~ •
"•
@
~
c -- , '3. 1:, x c::,. st.1J2--

C!) 2-
om
H,1 ::. -IS
.c
H12. ::::. H:u:: -I
tit,,_:::; -3 C
B
yA
tr
is
m
he
.c
w
-,
w
-rs-£
w
-I -3 -E
(Ls+e) (_g--,.eJ -1 =0
lfS + l8t.-1-E -.,... ' -.::. 0
~
1=.2--+ 18 t .+Lit./ :::O
0
G
~
€)
e
••
DPP-14 QuantumMechanics
(a) 2pz and 2px orbital have same radial part of function, but 2s Orbital has different radial part.
(b) The maximum angular node corresponding to e in orbital of H atom which have the radial
part of function r2e•r13a0 is 2. The degeneracy corresponding to this function is 9.
(c) The degeneracy corresponding to energy of rotating particle with energy 56 B is 15 where B
is rotational constant.
which of the above statement is true (1) a,b (2) b,c (3) a,c (4) a,b,c (5)a only (6) b only (7)none
~onsider the statement
a)The first order correction to the ground state energy of SHO when it is governed by potential
2
energy 0.5x2 (k+bx2) bx is O.
b)The tmmeling is niore sensitive to the width of the barrier than the height of the barrier.
Inorrect statement of above are (1) a,b (2)b, (3)a only (4) none
¥A quantum mechanical particle of mass m free to rotate on the ~ace of radius r is in the state
m
with energy 1Qtj-2tmr2.The degeneracy of this state is 'E:,-:. !
Jtyt\ IIT JAM 2010
o
a)20 (b) 10 ~ (d) 4 . . . :l~'-' ~~~~\ . · ,, . _
.c
4 A particle in 1D box (potential energy between to infinite outside) has the ground state energy
2
C
E=(0.125h /8ml 2) The expectation value of !the above Hamiltonian with 'V(x)=x(x-a) yields an
B
energy E 1 Using a linear combination of two even function x(x-a) and x2(x-a)2 , we obtain
yA
variation minimum to the ground state energy as E 2 the reJation between E0 Ei and E 2 is
a) Eo < Ei <E2 b) Eo < E2<E1 c) E1 < Eo<E2 d) E2< Eo<E1 CSIR NET CH
tr
5 For some one electron system with l=0,m=0 the :function N 0e-a and N 1(2-o-)e·012 refers
is
respectively to the ground state energy Eo and first excited state _energy level E 1 . If a variation
m
wave :function is N 2 (3-o-)e-<J yield an average energy Ethan it will satisfy CSIR NET CH
a) E~ 0 b) Os; E:s;Eo c) E1 d) Eo<E :s;E1
he
'6-4:'he ground state energy of the attractive delta potential V(x)=-M(x) where b>0 , calculated
.c
with varatfonal trial wave function 'l'(x) = A cos (nx/2a) -a<x<a is CSIR NET PY
2
a}~(mb2/n2n2) b)-(2mb2ht2n ) c)-(mb2/2n2n 2) d)-(mb2/4n2n2)
w
7.For a particle in a box problem in (0,L) an apprnximate wave :function is given as x (.5L-x)
w
(L-x) The average energy E for this state is CSIR NET CH

w
2 2
a) (h /8ml2) <E<(h2/2ini2) b) E>(h /2mi2)
c) (h2/4ml2) <E<(h2/2mi2) d) 0 <E<(h2/8mi2)
2
8. Two trial wave functions <!> 1= c1 x (a- x) and <!>2 = c 1 x (a- x) + c2 x (a- x)2 give ground state
energies El and E2, respectively, for the microscopic particle in a 1-D box by using the variation
method. If the exact ground state energy is Eo, the correct relationship between E0, E 1. and E2 is
(A) E0 =El= E2 (B) EO< El< E2 (C) E0< E2< El (D) E0> E2 = El IIT GATE
"'-9'1f the perturbation H' =ax is added to the infimte square potential V=0 for 0<x<n and
V=infinite otherwise The first ordercorrection to the ground state energy is. NET PH.'{,
.a) an/2 b) ax c) a1t/4 d) an/2°.s
10 Write the principle of variationalprinciple .
11. An electron is in a state described by the wave function

.. '
www.chemistryABC.com 4
~
~
05 I
'¥=(1/4n) (cos0+e-i'1>sin0)R(r) Where 9 and are the corresponding angle.
~
I
i)What are the possible value of Lz t
ii)What is the probability of obtaining each of the value ofLz.
12 An leV electron got trapped inside the surface of the metal. If the potential barrier is 4 eV
and the width of the barrier is 2 AO calculate the probability of transmission.
13 Evaluate the most probable distance of the electron of hydrogen atom in its 2p state what is
the radial density at this distance.
14 The unperturbed wavefunction of a particle is trapped in a 1 D Box of length a , if the floor

of the box is raised by constant amount V then what is second order correction to the ground
state.
0
~ particle of mass m confined to move in a potential V=0 for O<x<a and V=infinite other
m
wise the wavefunction of the particle at time t==0 is · L tE1/K
\\' t?<. '-) ~
o
l\) t,I)
'l'(x,0) = A[2 sin(nx/a) + sin (31tx/a)] '!Co.
.c
t
(a) Nonnalise thewavefunction at t=0. (ii) find '¥(x,t)

C
B
10
. t{f. An electron is confined in the ground state of ID SHO such that L\x= 10- m., assuming
yA
<T>=<V> find the energy in electron volt required to excite it to first excited state .
tr
. fl1\t time t==0 the wavefunction '¥(r,0)= 1/(10)°5 [2'1'1,0,0 +'1'2,1,o +(2) 5 '1'2,1,1 +(3)05'1'2,1,-iJ .where
is
subscript are value of quantum number n,l,m what is the expectation v~lue of eriergy of the
system, what is the probability of finding the system with l=l andm=l.
m
he

i) Schrodnger equation for a quantum system is linear differential of the type second order in
. space and second order in time.
.c
·
ii)The expectation value of z, coordinate in the ground state \1/=Ae-t,a is 0. CSIR NET PH
w
w
Correct statement is (a)i, (b)ii, (c) i,ii (d) none

19 The root of determinant in case of ethylene molecule in Huckel theory is
w
(a) a.+ p,a- p (b) a+ 2p,a- p (c) a.+ 2JJ,a-2p (d) a+ p,a-2p CSIRNET CH
20 .Consider the statement
i) Coulomb integrals for all the carbon atoms are assumed to be identic~.CSIR NET CH
ii) On-diagonal elements incorporate the Coulomb integrals for each atom and Off-.diagonal
elements consist of the resonance integrals;
iii) for an n-atom chain, in which each atom contributes one atomic orbital to the conjugated 1t-
system, there will be n overlapping atomic orbitals giving rise ton molecular orbitals.
Correct statement above are (a) i,ii (b) ii,iii (c) i,iii (d) i,ii,iii

•Vif!:HtiiftJr Theii>'!'3,,1'' · · ·/ ·
• . .. . . .. . ·. .,...Huclal -/1,~~ 41 -tk.l W,,-,._

I'& a 41V1pUecl v~bvi www.chemistryABC.com
: vOJ\L:lir,,,., TV1dl.oc/ w/.u'.'c.J., ~vi be Qf>pU <cl -+,, .1,.in1plt eo-ruu9af~ .

e if-~f>~rn. (o-J c~) . .
e, we.. a.¼UMe ~f31'V1'!l- pie:. ~c.p<::.:7!0.b?l..l-f<; w lJci;i rn-eatv,,s -thcd nuc.lti.,
e es °i; i'"#AL a:tt>MlC ~, rtivte,r ,ai, ~ and AJJc.ah.secJ rr btn?cl~,
8 p'l"9utoU a.n e.tsif cltve i/i!W in wl.u"u, -fw. Ai rv,a.1 n1YI ~ 7r e move
•e
(j c,,s-bi-W. aJ.:. lf:ne.a..t. f
Q> Wl1? V1 a.:.b"' C1vt °1i" a.:ic mic. a,rb i 7Q.). ,
0 :z:.., a. Mt'YliMa.l ~d:- ca...l{_ula±roY1 ,r q p1a'hnecS" Ct>..,Ju~
e
'1\jd.1r0ca.'(Jb'l-vr ~ OYt~ a.¾ornfc. c,~61-!dl wi--,t, ?f'-~t}MMttr:/-
e
om
0 ciht.. 2p c'.'.)'1$ b 1-fd.4 O'Yt. earrt;>m.
.c
0
G * µudte! MO -Ms-ea. bVllMi ~ -
B
C
G
A
Ei:1.ll~l.aie.. C.H i-:::::.

e l.H.'2-
y
tr
•
is
G
m
•
he
•
.c
w
•
w
w
•
•
•• 0 Lt [ ~J i,ot c.U.1red:-
CIII 'YlYle.dc.c/
•
••
••
•
~ ~t }
·'-·:> '~.· . '
... -".:;,,
www.chemistryABC.com 41
Cl
I
::.. 0
::: 0
om
.c
C
B
yA
tr
---
is
(2
m
+-~
:Xt:-+l E -- a(- ~ _..,f!
he
t =- c:(_ ..,_ ~
.c
-:Jl=- - l -111 -<-+.(3 ®

w
w
w
o(_ • ih ~W>~ ~ eneo'r;" 1 Uo7aked 7f elttbron
So 7f bond i;o~Ma:ttm -e..Y1.<-~n
-=- -'ll"'--+ ij1 - el-<

- c!o(-tot,6 - ~ e>(

··••.
• 1•
•
•e
€1 To ~min~ -ttu.. va.l.u..t. °b um.ue. if, Y1d:rtn1 41 -
C
~Yd. -the... va.l.uJ.. ~ <-, 0..1,,d. c:1- cu...
G
e 4'-:: <-1 ql -1,.Ci.1.i.
0
@
@
0 -CD
e
om
e c., C:1-
•
.c
• X. I C
I :::o
B
I I ::>l .
A
fj
y
e
-
tr
c, :>(. + ('l- -= 0 @
• .So
is
• ---{J)
m
c, -+- Ci-:,'- :::. a
•
he
•• E ::. -<-+ ~
.c
~ Y1 (i) &,<3)
w
'X. ::: - I puf: -ft,,~ \1alw. \Yl

w
•
w
•
••
•• c, 2..+ c.l,2 =- J
cl 2. -+ ,.2- =- '
••
••
•
I <P,,. if "'·+:k f>j www.chemistryABC.com
Tf 1$ e.ne..~ u.ve.l. t: .=.. -<.-_ ~ .x..c: .+, p '-1..i:- ~ vc:J.u.L i"1 et:J11 G) (G)
C, + <'1..C..l J ::. o
c('- +C ~2-. =- l
c._;1--+<;1..::.
C1 z. I ,,. .... ..... I

~
'-.2- - -
.J3_
om
.c
C
B
yA
tr
is
m
he
•
.c
=tr ,uldl A~+e.~- CH 2. -CH-CH

- . .l.
w
G)
w
C:.\.-ti-=- C.H ,- c..r--, .:L

w
G)
(H.1.-== CH.- (H.1.
Cu c,2. c,.s "'<-t 0
C. :.?;f (2.3.. C.1..3 .$' =<-E =:o

~
Ca, C32.. (s.g 0 o(-f ~
•
fis
•
•
@
•
,l!IIJ' :::,
•• '1·¥,
•'
' 'elL
Diut·
~ I 0
•e If>
o{-e
15
I :: 0
~.
0 ~ 0
~
?(._
X I :::..-o
0 I ::K
CJ',
®
0 = :)(_ (.-,c..,2._ f ) - I( 'X.-o) -I- O
~-·
C,,'>.//j
om
0
e
.c
(}
C
B
0
yA
~
tr
0
is
0
m
e :K:::.-o c,2 ::;..o(

he
G 1£ =
.c
?C..;; .fi. a( - Ji. {J

e
w
•
w
w
••
••
••
••
•
if-- Bmol jj!moi-t"tm ·•~-
~ W?t!!J
Dc:.1 o ~ O Y l e:Jnex'lf-
8 ltlex~ "fi ~ l a:idfOl1 - e_ Vl ~ ¥crf °6 I eh,'J l.u,,e
~(t(-+4.fila)- ~lo<..+~)
m
:: ~Ji~ - ~~
o
.c
:: ~~(Ji-I} = ~~(D.t.Uq)=O•&.2.g~
C
B
!¥bJfamiUYJ_:-
yA
1f ~"te!"'t ()d I:) c.a..lisa:bon eY1e~

tr
.if~ baY\ cl 1{~'tnoY\

is
L~ l ol. + 5~)+-t<}- '-lo(

t ne.o~ °ti-o.ibq1 a. vi~,tM - e.)\t.~ °If ,~ Ullc. QI
m
2e
~'1<1 - r~ co(--f Ii) +:2..--<.]
-t
r°' c<.,. Ii iJ
he
,::: JJi.l!:!. -+
.c
w
-::: alJi ~ - 2.~

w
= "· 82.<a ~
w
- ---------------------~~---___j~;
fWlf:~CQJ.-
if..- bo'Vld 1f1rM cd:to-n e:v,e""ft

•
•
e
~
®
•
e
0
0
To cl.tte>i..mf n~ -Hne. ~ 111d:icn-
©
&) 4'-:: c, 4>, .+ ('.l.. <P2 ..f (a cl,3
om
fls wt kt)1trUJ [ ]
Q c( ~ Ci2...+<.:l· = r
.c
f)
" C
B
()
yA
0
0
tr
0 .X::.o - - -
is
@
m
D { .:,(_
e
he
•
.c
w
0
•e
w
w
c, (-13.) -+ C2 -=- o ~
G C.1 + Ci(-J'i) + (_g::: o-@

C2...-.= !ic3
• C. 2. _,_ (3 (Ji J ::: 0 -(!J)
•• Pu.a- i "1 i"' e.,<i)
~
• c,2.-t {E..c,)2.+ ( 1 ~ e I
•
•• C,-q-1
2.._
• G:1) C2 -- - I
./3.
E ::: o( c, (;>lJ ..,.. ea. ,;::..c)

:x:::.o <-1 4- (,._(:,.)+ c3 : o 'l +<.3-= D 9 <,:: -C.3
C2,. .,_ Cg (x:>::: o C,2.:::. o
AJ..t!f v,1' '"" ei:,n {j)

c?+ c,2-:::..t
<fl.(.. /1.. :: l c, = r,_
J_
_j_ A.l -
.(i 't' J..
JI J-.
'1'3 l
om
.c
C
B
yA
C, + Ii C:,. .+ Ca ::: o
c, = c.s
tr
C.a,.+Jl.<.3 ::O
is
m
pu.J:k,~ Tr1 ~-n(J)

he
c12 -1- (_13-c,) 2 + c, 2... c. 1/,

.c
w
w
w
c,:: ....L
2.
Jl~J2 - - - - -
-<
208
I A..
2
"¥1
-1-
a "' r
I A.
2
-J.. l ,.J..
w.3
r ':•'~"'~~:{ : 11
•
•e
e
@
@
•
~
C. It c,i. c,.s
2.. 3
--<-E ~ f.
0
q ~ ""<'.-E =}
e C.2., C.:u. CL,! ~ ::::. 0
e ca, C32. C.33 4 --<--£

e
om
()
.c
G
€) C
B
yA
() :X.. (xlJ.-1 J -J { :X. -I) -1-1 ( /-?l} -::: 0

::>l
I
I' / ::. D
I) ;:t, 3 _ :x. - :x + I -1- I .,...;x_, -=... o
tr
l :x.
• G3- 3~-+2..e-oJ - CD,
is
•e
m
:>(.Cl
he
::r.--1:::..0
•e
.c
w
::. ~-, J lx2.-+:x.-2) :::. o

w
• 0-u l :x 2.+ ~-x+-X- -

w
J :::c:>
•
2
• ~~I) ( ::>t:..+2) (::i..+J} ~1)
•• !X.::::..l)
::,(.~.2.. .
• :;>L=+/
•• ::x. t:.- 2.
E:: o<+2~
•• --
:,(. C I
e == o(-~ "'(-~ -<-p
•
••
--
7c. := I
£ :::: o(- ~
-<+28

4'11. = :ti 4>, - Ji 4.>3

ll.11 -= ..L Ji 4 .2. +
<Pi + J.
1,..,
_L ~0
2-~
om
.c
C
B
o<--a -
yA
tr
is
m
he
.c
w
w
w
111

:: 0
om
e
.c
0 ND vi- 9d d.k. -
0 £ ::: -< + :2..~ (DJ:,. IQ..}\' C
B
11-+l
0
yA
•
tr
•
is
•
m
•
he
-< + ie u& ~
•• £ ::;
.c
.3
w
f:{ ~ I E :::. c:(-+ 2...£$ ~ 1/.:3
•
w
w
••
••
• E .... -< + 2.~ w ~[..
•• ~1 x.f :: "<t' ~
4
c..&1ft ::::. c< +../"1..15
•• kt -: :. 2. -:::. o(-+ .2-~ c.,,,,,. ~

I./
::::: o(
• J,z -= 3 :::r -<+ 2.!$

-u
Uld $1"" ::::. c,(- Ji f,
E.:;:.... o(4- 2& c..,,,,, w- - -<+ o, ,,a~

£= c:{ A- .2.Jl 4b~ = o(- 0, '1% ~ ~ tor
5
r;:::.. o(-+ !2. J:t ~ 4 .{'

r - o(-1·''&-~
om
.c
~ -::.. 0 I °i 11 ± 2 l t 3 • • . , ~• , • .. ,
C
B
@I 1
yA
tr
is
m
Ee
he
.c
w
w
w
(ii)
□ '11.c. 4
~
E - c,(_-l-- 2..(3 ~~kt..;
~::.::: l) -- o( + ,fl_ q
-er
••
e
~-:::. ±:J - o(...J.~~ Co&~
Lt -- o(
€}
~-= +'J. ::: o(-+ -,~ ti>J. {l,f" c o(-~~ (a
1:]

••
. -c/.f~ " _,
·'fl
••
)·'
(Iii)
0 8 www.chemistryABC.com
•• k c.-o ·-:::::. o<+1~ ~~

6
- -(.+.2.~
e
I:?.-= -i:-1 - o( 4-:2.Jcl~~~ C o(+2.£l ~ ~ :: -(+$
~ k.::±2. - -<.. --+ 2.,& C-b 1../ A

6
- o( -+ 2 ~ ~ it
a - c,(- ~
• ,< --+ "l-1{ c.~ 6!£. - P('..+2.ij {J. ,If"" -<- 1.{3
•
:::
k-=+3 :::
A"'
®
(;j
o m
.c
C
B
yA
e 7f - /':Xl"Ytd :M"' ~ e.n'-~ -

tr
•
is
.::: t.t, ~ ~u>a, · - °n iSD lc:d:ecl ~ e

•• £' Y I ~ Q
m
--- -<-1-'1&~
: . c~-<+ u.~,2.~) -Lia(
he
- - - - "'{'-0,6fg-~
••
.c
-c -to., !S-~
w
•
w
411 • -(-1- (. '1ft~

, Reg. 0 YlO..'VI CL eJr1 e_~ _
w
•• - t 1, s b vbcUcmc.- ~ 1< G:n e~ °1f I ~ltMe.
•• - Lt-< +LI. U '12.. ~ - :2. [
::::.. L<c<-+
2-(o{-+ f.i)] 1
• \.,\,4'11 ~ - ll~ .- Ll,{3
••
•
•
•
•
ol.t looaJl-mli ov, =
~o<+ll ~ + ~-(. - ~ (_~r;,f__ ~ i~)

-:: ll-<+4,e- L/.ot.-l/~
=o
om
.c
-<.-- 1.1:, It ij C
B
yA
-(-C, l,fi ij
tr
/Jl, o(-f 0,61% &

is
€:::. O,t.#71~
m
::: o.q;.z"X1S
he
= as ·4 ~.,. 1nu l
.c
w
w
w
f.,,r =- loo< + f 3. 6 i ~
di.I om.Lfo:di oY\ ~ ;::_ /o-< + 13. U -H { '2 (-<+(J))

~ g6g-~
..-----<._.-2.~
_.i)_o{ c?lo(

•• to oUl~~W! ,tuv,~ t:u1Mro..p~--to e.V1e.irtt lt,ve.l we..~

-\o ~ fY\~Vte. O'"'C b ~ C.o 1{tc.ie,vd: •
e
e)
(0
@ C.s °<' .Sivt,rks f')1 -:::... ()10. 4, CiJl~ PO'YI a:lo M
"11.+'
~ = b~eoJ 0"'1 -e..l-1 e....,11 Lt.-vd.
s= -1? ~ Ca.. "l t>O'>'l a:krw,
e,3. c, === s=I

c..'l- : : . s =-- 2-
o m
.c
C
B
yA
tr
is
m
CJ.,../ Si YI ,r ,., c, -i rJ.

q,
he
<>(
'
3
.c
Cz '4_
w
w
w
Ltl- '-'~ o.mh.td.Li we. ~a.ue. .-to olt:b.mi-ne i1,,l..t. val.ut oi c, e':) ~ C3 io-a- \i~~f-
e:v1e1r~ MO ~ '3 CQ.1rbw\ c..lAaf-rJ ~~3)

(l,(.-::::3)
Cs-< -
S i1-1;r K.S
11.+ I
S-::: I
c,
11-:: 3
K==-3
Sc:2-
-::: Sfn If.I
___,.
l.f - Sin31'f -::::
7;
__
*,
c.).. ==- Stlll ff -=- SinM =
'2-
4
S:::.3
215
~ re:: Sin 't"f'tt -- ~
42-
- .•
e
•
I
~
~
"""'
om
.c
yl{ 7c o/Jl-evYif"4A.. -11lc. cltia.~ ale.Jn£1-Jtt 2.- Bon<J o~,- ~ Hvc1.<el. -
C ®
B
@
at t..wJ.,ryt- dt/YJ~r"f
yA
To ~ 1ttC'. -ttu. 'Valu.t. lue Leo~ -It)

©
1J,CUA tm ocrbHal ColJlla't!Mf
tr
~ p r m ~ io ~roo, 7b wJtJt.J, ff;

is
we_ havt. -to oldt:Am1nt: tMtlY1fr::. o/J..,,,,/41+;{ 11ne>no. 1 € /?'a~l?.M:f- €

m
Qnc)_
€
he
111 1tu. ev °1 ~ 1.:,W<! C:

.c
®
w
tA -
C/.l := €770, b e G,,,t2... ~;J
w
w
G)
<..H:2..-:::.. t::H- Cl-I.a.
e
G
e
•
@
•
••
c; t e ~~ c;
' ~-'.::7_'--"__,
q,, " , 171,. &6 i 11. -1- ....,. , ic _,_ 110. 'll e
-,-
- at t<(-:k)~
~x.l :::.. I
,;)...
om
.c
C
B
yA
tr
e1'
~;;
is
m
he
.c
e
w
w
0
w
0
ti)
0
e.d - ll1La l ca±,OY1 -
P1:2. ~ ~ 'X 17( -fl..+ 0 X 1 )t O -1:- 0'?< ½~ {-:hJ

Pi~= ?i.
f23 :: <"X -h ~! + Dl\tJ X {---~) f- () X~Xi_

··@~ www.chemistryABC.com
® ,,. 41,::::.
om
.c
C
B
yA
tr
is
m
he
CH2..--. C..H - C. H =- C..1-1 :i.

.c
w
Q.£.: 0 • t..411.~ 0,£. = o. 8.2.8 ~

w
4 2
w
:=- C>, l l 8~ =-O,

-41u~
-:
(£)
-<- .fif
-<
~-& - ---<:-'~
_r1i . -<+.13.-~
All - -(+2-(l

•tct"'.' '"lf., '\: ~ .. -<.-.2 C . HOMO
c=o<.--~---(~2.~
';
- 2.(> -:: : tS'-o

- _!l.L
-(-ff
•.(+$_
LOpto
ft4wto
::::...s~
- ! $ i .2.:1.'S" a• -<-1- 26 ·
·opp 15 Quantum·mechanics
L The energy for a single electron excitation in cyclopropeneumcation according to Huckel
theory . .
(a) p (b) 2p ~ p (d) 4P CSIR NET
2.The resonance inte al for benzene _in the Huckel model is -75 KJ/mo!e the energy required for
r transition from HOMO to LUMO and to the highest unoccupied MO respectively will be
( ~ and 225 KJ/mole (b) 75 and 150 KJ/mole (c) 150 and 300 KJ/mole (d) 75 and 225
Kl/mole UT GATE
3 Simple Huckel Molecular Orbital TheoryCSIR NET
(a) consider electron electron repulsion explicitly (b) distinguish cis butadiene and trans F
butadiene · • ~
~istinguishcis butadiene and cyclobutadiene (d) has different culomb integral for non F
••
i
equivalent carbon · · · , .... · ·. ·.
I 4. As per Huckeltheory , 1t electron energy of cyclobutadiene ateIIT GATE
{a) a+ 2p,a+ p ,a-·
p,a-2P (~a + 2(3,o.- f3 ,a-1l,CI~2(J (~T2p~a: ,u,a-2P ( d) a + J3,a- p ,ri- p,a.:·
•~
m
~ .. . . . .
o
5.Consider the statement
~e
i) Coulomb integrals for all the carbon atoms ~.'.3SSUITled to identical. I
.c
ii) On-diagonal elements incorporate the Couiomb integmls for each atom and Off-diagonal
•• elements consist of the resonance integrals;-r r ·. ·· C · ·

B
iii) for an n-atom chain, in which each atom cgntributes one atomic orbital to the conjugated 1t- ·
yA
system, there will be n overlapping atomic orbi4ils giving rise to n molecular orbitals. a'
Correct statement above are (a) i,ii (b) ii,iii (c) ~iii('dYi;Ii;iii .·.· . .
0 6 The root of determinant in case of ethyl~n.e m~(ecule inHuckel theory is CSIR NET .
tr
() (11Ja+ p,a- p (b) a+ 2p,a- p (c) a+ 2~,a.:.2{3 .(d) a+ p,a-2p . ·..

is
7 consider the statement •. · , • . ... . . · ·..

m
0 i)The concept of1t bond formation energy is different than delocalization energy. T
!~~ The 1t bond ~off1;ation energy in benzenei~ 6ti. F . . . . · .. ,,<.-,.g~ _ (o(-:: 6 ~
he
0 m) The delocal1zat10n energy for cyclobutad1enemolecule 1s zero. -r

Correct statement above are (a) i,ii (b) ii,Hi(-e,:t1ii (d) all (e) none
.c
Q' 8. '{he electroni.c charge corresponding to cen,trafcarbon atom in allylcation is

w
(tiff (b) 0.5(c) 1/¥2 '(d)noneCSIR'NET · ·

w

i)Huckel allow us to determine the energies and wavefunction for the 1t molecular orbital without
w
specifying the Hamiltonian operator .:i

ii) The d~localization energy ofbutadiene is oithetorder of 65 kJ/mole. f
iii)Compared with the 1t electron energy of three ethane molecule the delocalization energy in
benzene is 3 ~- f
The correct statement above are (a) i,ii (b) ii,iii (c) i,iii (d) i,ii,iii
i) The delocalization energy corresponding to cyclobutadiene molecule is 0.472 (3. F
ii)The total 1t electron energy of naphthalene Ex= 1Oa + 13.68 Pdelocalization energy of it is
1.68 p F 5 ~lutf uitlt _1
iii)Secular determinant simplifies if the trial waveJimction is the linear combination of
orthonormal function. -r
(j
0
0
Q
.. •
0
c
Toe correct statements above ar~ (a) i,ii (b) ii,iii (c) i,iii (d) i,ii,iii
I I.In case ofHitckel molecular orbitaltreahnent ofberi~ - ~ @·
i)The total 7t electronic charge onrith carbon atom to b~So we see that n electron are
uniformly distributed around the benzene ring. F ·
ii) From the bond order (P::c:2/3) calculation in benzene we find that aH bond are equivalent. i
· iii) If p=-75 kJ/mole then benzene is stabilized by about 150 kJ/mole. -r
The true statement above are (a) i,ii (b) ii,iii (c) i,iii '( d) i,ii,iii (e )none
i)The delocalization energyJor aJlylcation, allyl anion and allyl radica! are same but stability for · ·
. all these species differ, so Ruckel method can not ex:p lain the stability order of these species.· F' ~ )
..·.• lji) If the energy of two electron one in each side of two isolated non interacting 2pz atomic . .
t}tl~Groital is 2a then net gain in ene,rgy on. the formation of ethylene system is 2p.• T · :(_ l.(.+ B 'J - "<o(
rf' iii)The ground state of ~yclob11¼~i~n~ is a tripletstate.biradiacaL T ... :J,it·,,:,:,if . .· • :=. 211
m
; The correct statement above are (a) i,ii (~i,iii (C) i,iii (d) i,ii,iii (e)no~e ':/ . . .
o
,~;u;::::;:;:::;~il~do._~~by ~ a) · · .
.c
deloca!rnltion (relative to ethylI):iJls much less
· t< ~-oqjugated than ~llylcation.~ · . ·. _·. ~~~E~. ·.
C ·.
B
u)Huckel theory IS an approximat10n formulae , the concept ofbathoch.rottnc shrft that was
yA
studied during 1t -n* can not be explained by Ruckel metho'd.f · · ·· ·

iii)The value of Huckef parameter a and p ate different in c~e of hetro~tofu. T
tr
The correct statement abo~e aie (a)i,ii (b) ii,iii{c) i,iii (d) i,ii,iii (e)ii (f}.iii(g) i .··
is
l 4U sing extended hu~kel theory det~rmine the lilleat or the triang~lar :~~:9fH3
+ i,s the more .
Il3-.
-='i' f!x~HP1~9f~~o.pfllc.qblt t11'J
m
stable sta_te._Repeatthe calculation f()r H3 and

15. Consider the statement · · ·. · .· · . · · @1ovuo/ ~,.:-'", '
he
i)Huckel molecular orbital theory is based on ~Mt seperability. -:T. ·· . . . .· . .

.c
ii)The value of resonance energy generally remain in the form of resonance integral 1
iii}The approximation of consicl.ering overlap integral zero in Huckelm9h:~t4lar orbital theory Is
w
a bad approximation. 1 $11 !:- l ~• 2: c.D• 2.s St3::: ~oq .. ➔-t~J:t ~ 'li\i-4-t.l:-.:.d
w
The correct statement above are (a) i,ii {b)ji,iii (c) i,iii (efall (e)none '(_' ;,/ · . · .
w
16.The bond order between first and second carbon atom in allyl radical is;·:····
17 The energy required for the transition from homo to lumo in ethylene moleculeis .. JS.9 l<j'/n,oJG
19 The energy level corresponding to allylcation j

18 The energy level corresponding to methylene.irnine if uwq,+0.5 pis .... 11!( -:r.l~ q
as ...... ... ... ..••........ ... .•• -< - •. -rt I
C.tt.lJ-.cNH
-/

·se.hif .·-ttu·· ,Huc.l(d attta.rn~-tso~rvr 15'-'is:•.me:nr?f'~e.d.i.fmf11e:.
~?t ~ 1fvd -tl/\.e.. uv~po1't~ e.ltle..~ ttud 1,& O('N ::: o( + o. .s iS
').~ 1 2 .·
C.H:2.=-NH ec--N= /.o~
C.u
~1
~~
(. .2.::2.
i I ?
~N-C.
c<.,•£ Qt-N (
o("'-E
=0
I~
o(.-E
-E) ~
o(:t. 5-6 -E CJ
"cf' "'(-r
D1u·1dJ.. ~
--- I
om
~
c,{-.,f; . :: I> ~ :::: (
.c
~·
..<_,+O•S°'~ -£ C I ~+D•S
. ~ .
B
~
yA
tr
is
m
he
.c
w
w
w
2q (:::_,-J
=. -O.f: ± j :z.s-- LIX;(-0

.2
:::x!:. - I, 18
?(_ C. 0 , ( ~
£:::: C(-l-1•2..8'~
If :::. c:t( -{> .. 18' {S
.f 221 Download all notes by clicking here- www.chemistryABC.com

· r/tJe:kel llit&l~ (···~olllffri~oc °l\\cai~J
. ..
' /.-1 moT l~ ~ppLl~blL ~,s- pb'l'l'Vle._""¥ eonjvF~

hMcl'2tC>cat,s--b11'11 'Y\1t)t.u.,,Ja met-Lt&~ d¼U1V\~ -nuu- · ,& ~ 1-r.l .· ,
.u · 1
. ,71- r:, -o Ctn-o\J~ I
~ ~ . V>tb~l..l.lM. ~ be__ h ~ iw>l..t..p">ld.~ '>i- il.u. u--b,ndief' I
i
;r-~ a-.,:. d.L lo CAlls.~ av ~ tl-,e = i ~ Wlla I:: 1 n,,o lt.tuLL ct. 11to/ p7j,- I
i M r<11f-to-,,d- .,_,;,lo.. !n e_v""'t ,l.,(-1<."! "Tl<, <T ,e ca,,,, 1-:,,, Cwlt,i°d.v.,.J.. <2-'> :
µ_lccE v~ UJ1., µ.ath ve. . ~ h,vn..al ·t~rn~ UJ"tJT"l:. Li.~ ii? ~(cf p lClM..e.
0
I
atY\ci 'l.p,<. A. 2.p't C)'1fbt;-a..l WW. tXed -le aJ1.1hi'W& 11,u__ 11.~ b'tfc)_ ~Qb?~ I
tv1eM 2.P2- o"<rb1-p.l O"Yl eacl-1 ca.11rhm a:kom :1~ ~-li.LJ... a..ua..tla.hlL ~~
,,
I
bcsvt~ a--- If" /4~r~:isq6f LL~ ~ r~-miMi'.'bu.. -t,cr -p1~n~ llllYlJUa-oi-ec/ I
~i?l'-ed 4flfd1vc eh.t.J?fD.J,-ra:}-,°c pofe-ultaJ.
om
/4~fe-m. ,r .-C 1#7Y/o'le l'n CJ I
t'l!<lme- =k ' -tw,.k /n"" lc/e. /cd-'F"'7 1f'"' :

.c
d.iu.. ./0 ~1,f'/13 ,,. .-ti,,,. p
C
••
B
yA
# I-{ M.0 met-rnor:J ~c.ltt ca.~1x,-n a±om Cu\,d_~, bufeJ.. O'Yle.. 7f-e a.VPI. one
tr
I
a:b'Mtc 6?s'bi-W-(u~lJ~ 2-pz.) --ie-ftle 1Ytoluufta"-.O~b~ "{y -tlrte.
•
is
m
61~ wl-ti".c~ ~ ~rpAD'XiYVl~ bt LLviea.L CD'W\'6iw:tht1n1r~,..c..

•
he
o~bt./al. (_ U:.>qo) p~oCQ.a.uM. A.1t1c.l u~f-,, lLn~ Va..>u.°okon ptr111llfl1..__CL!l _

I
.c
I
w
I
w
w
••
I
.
wviett-e. .-t--w- ~um e:xi-~ ~ '"n ° · 'i c a ~ ' ~ l '"l'l J ~ 44 t& · ••
--tw- 1.p:L a.¾arnfc d1rbt~ la> ta:ted at- CQ-r-D?'Y! OX .u.. I
••
--1
fYl o/e._tul tA. a ()'"lfh rfa.-l_ e.l'l.<.--r-'J1 m~ be_ O bfa.bt.ed Pcf li.n ~ V4.A.t a/10>1
p--itnliplL
•
l
ti
'.fr ..
•'
,""~
:rV\ Hu L.k:ll n,c.th.~ -tw. , 4..-a1 chd:~ ~ Ha""~ lOM. ~ CY V\.\Q rJ 1.JJo},
~,~MptLt;t~ OJ.
(LJ \\t\e..O\l~\a\"-Mt ~u;l~ t>'"" (3) a.:fcrvYlt(. <'.l"TbiicJ l..cCOi¼d. d'"Yl 6)
~ um4,re ·~ -ft!l~ 4-o he. c:w:>.
J<P.u f)y ol-C -::-o S..Llv :: o
@
@ (ii) '2p.z. a.:leMtC. o"\rht-lo.A. l1Vl 1'l-u. ~amt" Ca<fhWI a.tom lV\.t.. norrr,q_J.lzu::}
c)
om
S.,u..u. :! I
G
Svv I
.c
==-
@
0
1 ove,...\<lp
C
- f ~ ~ etvc.- ~;,.,p~t"~ji,,,,
B
N"?l.u:H"'~ fl,. i+ft,
yA
~i'dJA.«1 1n frv~pp1rorrial-e /210'lpfiii'~.

tr
~ '\\,A,XYO..ctt°"'
is
b/w a:¼oMIIC O'\rbt-W Ire. 'P~ (, tt>t' G.IYttrc.olaf ..ti. ~v

m
d.J{1Y1ed 1t'\ Hmo Tuen<f ~

he
a.JJ_
.c
j 4>Lt H ~vd-r == < ci>-L.d 11 I 4v > -=- H"'i, -i::- ~

w
w
Tu iA .At..pa~M" -ttuL i ~th"'lhl (:lfteio/t b1u.J ·+wo a:bm,,ic c,yb,,/,::J.,( -~..a g__~9
w
'
~~ o.t Ll_ &._ V J..J.-&pedfv~ ~ +e._1rme_d ~ JlJ.btmaJn.t.1 ftJ.saTa/
it .L{ ~V Cl.h.t \llot-,-~,e_a,.J '11e.t~bo-uQ, bf &v,v~ ~ fufrq~
f,t,. \I\ ,lti¼-ed
j ¢,(,.( 1--t tv dT ::::. -o ( ncv,. -~~~ ltlel.f1btTW,...J
71,,ie._-eYle..w 1 e mouh~t D.Ct... --1P ~,c__ tYr{dkd. ti.)./_ in~ 6rLl.d.. ;-

ry'l uc.i.l.u)., Q.:f-- ftu t.tMl-AL A t;&

J4'u H ¢>tr tJ/T.. =- < 4>,t.1 H PJ..t ) ::: · /iuJJ : :., o( www.chemistryABC.com
1iJh M.p~~ Tu.. e."v\e.,r.fd' i ~ t 1t1 Q./11 a:hm,,i( o-rbriUJ ?» ~ a:fA

~ ~ ~ :~CJWb iiJ:~.
u,ui.um/-:> 'tk.1-c.ra' l#(. 7 1is 1tu.. m-eru,u··one-uJ-cr/; h1J1cii~ e,,.,etJJ'rrrt 2-p e

°b 1'u.- Cot),/':XIY}
-r---!----f--fc7tl-i/4-a:n~un-e-11t'.._,S_o/d_]
-riws -tf1.t.. , v ~ °IJ- 0( c:JJ...p~cl& 0">1 iub~+,tv-h"'n, a.J:fotk +o 1tu. Cdt~l:x,,, e....
k;Jb4, ~ CMl:un~ Jf- i/2 ab;c, qff.hX)m~ a.& V~u._ o~t~ :ZfJJni.seJ-,dYJ
m
e..w~~.
o
.c
TIA.it a).humpt,~ -tLuu-- all ~un41>'1lL valu.J.1 f 'tv-r- c_.....c b<:IVfcl t& q_~
ov~fMp%1~.
C
B
yA
It/> f vaku.. v~ iurtt,,i -/IA.I.. bvn.ol. ~ -'" t!) va.J.w.. 6i ~· .1!.l.tM.iliz/ l:,e..
tr
1fo Hertu e..vtA.. i°t1 v~«f a(_ ~-¥

is
l.Jh<.4 hu,/-a._ci.Jt/y/e . ~11Y1plt.. H IY?o f1?q'!,,,e-e/ aJ)

m
in a Ci:JAhvn or,l-e-w, ~ .-/q/tt'M ~ Aame.

he
p-,.
o< r~ 1w.. - -v (!_ 1 ,D11 is~'7Yl -e "'c: ~ , ~~ ~ u ~ -v ('.'. Va.J.w...

V
.c
p-t,m_ ~
w
$ o/J.&c-ir-ihe__7kt.. ad~*"'OYtal ,,;.-k!hli.~a.:1:-,'c,,y; 47Ii/4t"1"

w
ob_ /ocalt~"em ti 7k-LP dy~ 'Vlet1(vlb~ ~r(_ 0'1rh1"-la.u

w
~ 11, all. 0 -'V£- bed- ~ rrr,J.Lu.. ma.a 'h! ./ualt. ~ --/1,,,.. o< - 7iu. ~ l . f . . f lfl'lt/; :
"( i /2 u&. e..c.l Qh ~ q_ poi.J ~(::::::. o ~ ---/tuJ 'Yai.l.u o/J 41er~ <f- ~
~
\)a.lw._ i ~ et-a-e ~m111ed 'b(" e?ffe~ )')-?~ ( t:;~~fsfJ 7'ho-rr,omd!j) O
1;co C- C
[ <s_:::___7._S-_1_<T/--rvr-ol-e]..,.,

•
(tJ SJ.tu- :::. o l Sµ,u =- l Svv:: I
H.J.Jv-== o (_ 'YI 11+- ollY e~ a.!tc.d,,,eof)

(lb H.uv -=-- ~
r
( ti.i) kvv ~ o< 7 HA.IA.I.=- O(' .!
lvni!IY? ~ vai.u.L tL.U:_ /...t pla..u.4 t?,tn'Y? lt YuJ.1:A.1L

fn !sev:la..Ji. dd-e.,,m,nt:de 0
vo.;..l.a:lion po {'YI a;,u. , 1tu tunum p+r,oon ~ ~ r"' ~ t'Y11 ~wd&t-e :
R-Al O ' Y ? ~ ~ dJ.me.,,d1?, be._f.4#1e c(--r
. !J/l- ~ a l e!J.me-u:b, o/w ?1-etp,r,xrt,JM7 a;/t;w, be(#(YteJ ;, 0
m
Ftli-t'l1f.u.:A... d..l..~ :::.0
o
.c
s3 Mvi>1f --hut, ddevrl1'14Mf Wt:. ,,s l./-- vp itu- er,~>r;J ~ n 4/11.e/ /:y
'1 t..1f• C
B
CP.l_tu.Ltd:7' 0
O'?Sb1'!/ol. l,L)e_ ~t!f..mine. f;vrtd-i&r"I U'ol"t!!-!,fJDnalt~ -fo
yA
-e_rv~ ~ .,1.Me,
tr
Hu da.l Me::ti,a:J '1J.u w1'd.t Qff 1-l ~'l:lu "7/ f., ~m'"inl '-? 1 ht?Y70( o ~
is
0
m
G p d.vn6i7, al.t{oco.Ji zJ-i'c,.,,. et-Te.rr-j, clipkwl:JYJ,f-ud- ~ -en-e..'¥'11q 4unr-<r/

he
~.
,t-o ?S" Jf .-- ~ ftd:rc,_dr."dYJ, a.4o,
.c
0
w
@
S, ;Nf Fl.L Hmo th Ltmif~ 1o pl4'Y1M·nr h~+Gt'Yt ~~nf I- cltt/,-~a:k: ht1.u
w
0
rm~ °i ciL-e_1n~.
w
CtA &- .~Ylh

C
e
•
(1
@
0 #
1n CQ.oc.. 1 It~ a;:/t;rn ftu.. F'"lr°-~YS. ~ ~ o( oUM~ ~ ~el')e..~
•• ~~\J~
,.
lY'\ -t1AA.. +e.oYYl °b o( ioY CQ.of:,py, ~ -f;o b" C- c..
(_LJ ~ Heho :: c:<c: + h ~

0
• Ob « 8 C-J.u.lyo = .A-~
I"( ~ <:.-c
•
•
{::;~:,
tM- vob.Lt 'i ~me!t:Ji ha.. b. aiL. -~<:&/·ctn ~dw:&t1c. .cf--

C
@ L@ ·
1.,u.J-t..u:, a:/-on-1,
tJAL 3ivdWI,
..-fz,c)o
cu.p~'1
od-tS <>(; va1J.U.
0\,
1f>A /;ul.,wia.::b:,fl?
w ~ ltu::h-oa:b,W> ~6u~ ( crp.__
/4ucl,,, '16
:i.. ~ in
•
@
@
~ 641:ife-m,
I- nt ~
t-,10• -\)
/
6
...(N (,? = -<g+o.s?] 4i
~
°(N (2.J c. o(<:. + t.S- ~ 0
N
o( O t.2..) C.
om
~C.--'N = O,'a ~ ]
.c
~l::. N ::: LO~
C
B
yA
~CAO "' o.8~ } e'

tr
:: t, 0 ~ €
is
~c=-o
m
he
.c
w
w
w
e
••
e
@
@

••
,,~;,,: 1t;;,r>?oltw~~~bilztl 71,~ - · ( moT)
• ~- ~-:kso€
-,;, o1unon;.,t?l2k ~ va.;.l,:J.fli:mo.l [>oindj>IL q f?rlai. Wd. ~ l;u 11 c:H'(h?
om
.c
C
B
yA
tr
is
A
m
4'1 s +IJ'g~ H 4':.is - LPss o{"t

he
.c
w
w
w
--
2

. . -~~ -
~2. - f.,,4>2. J..:i ~,. cl.'t. .
2..
€t
e
H,~ -: j ~, H Ql .2. d T ~
- ~ [ j ~ IP:,f'IJ,sdT- j
@
4',s~:o/T-1- j~ 5
°cl'C @
- J4!3~ ,_, l&s cl 'T: ~
om
~
.c
C
B
yA
tr
is
m
he
__
.c
w
- 3,4 (II-¥;)€
,,.
w
,_
w
@
~
e
•
•
e
®
©
®
·-•
': ~ !!!!}I- www.chemistryABC.com
• lfmn ::: · C, lft + C-2-4':z.
Two ctl:um!c crirbN·,d 1, ~ tP:2. a,\L l.tnu.v..~ C¥tV/l;>f'l?ed -It:, j;c-,.m mo!J.~
tJ~bi-lal fV nt:flon '-//
'tmO Cs vi aomaJlu..cl ~ wJtm
Jlfmo if Mo a/T. = I
a'R
J(c, ¢, +( ,':l.) 2 Cc, </> 1 + cicb.,J dT-==- I
j c1 '{>1 C1 r/;, dT -r j c, t$, c1 c1> 2 d--c -t j Ci4'2-C,cb,cJT +j Ci~,_ ~~J.-c/t :::.J
om
C1 • J4,, ~,~r- + c, c,,. Jdi, ~,.d.T + C, c,.J qi, 1
J
d.l + (_z 4i,<$,_ ct.t-= /
.c
<1>.,_
C
B
y A
tr
is
m
he
vS - 4'1\1O -::: 0 , l{ .<:J flll () a-/s ~ ;C 1111 tJl.u:ot.!
1/ldcr-Molizaol, ~ o-veJi..?a.p ~ ~ -?- ~
.c
LJ11,,\..!WcJ:-e..1 4\ & w~
""ii.,,~ @ -=- r
~M ~-,. . C\"YC
c OVG\ l~ PP'1t ,~~; w ,
w
w
lo.~)~ +
w
-t)(o~l.4 ,<o. is +~·2s) 2--::- /
S-=- o.31
--
•
0
P(l{)t:ab, u.4a- ~~prnclii1'<f
Can:0r~pOY\alfQ -fc Cf) cdo1Y1
-to tt ,.e. p-a-obo.b·,u~ 11111\~e
I 11\ 1\10 ~@ ~
Q
e
••
e
Pr+ 'f'.2.. =--
• J
•
·. '''Q1.15.: 'lf:1' =="~: (Me IY1t5~~t1rd 1, rolM. ~lt.c.ult ~ 8 kaJ ~,.,
@@-- l www.chemistryABC.com
~ elf. Wt .(.. la if& ~ 'f,r- ( '-Pe tM..t. 11 v 7rl)1 o.li-u.J
IHa»1 i c. 0Tb t+ol CDMbr~ ~ ft ~8 " Th.e. e 1,-, ~ 0,1:>i!r:J t5

ifvnc) a.:hsw1 B w'l-th fhO fu!:lll1;J q Di, · l)J~"11:,~ ~
OVJ <JYVt_b_p
a p~1biL W- t1;- l,f t LB U
-=
Ctr = j · I~ e, .. 3 .2
c8 c J}.- =,41r
om
.c
{ Cff- '° "· 32. <e. = ts. qs]
C
* 1°
B
~ fo W-a-t~ LAm, u ~ nttl'tw1 1Je_Y MO - ~
yA
di~ic. molLu.d.t. vtQ.vfv,, te ('H;!) 7'kt.. W"d.ot.1Juv1c#o,,,,.

tr
~~/?6Ydl111d' t,~d--lon
is
wa.u"'- -to 1+
m
he
.c
w
w
w
J 4'mo lfMti* d. 't c 1

I
c.,-:::: c..,_ C Bo-th a 0 < fLtfl')f)rm}
~c,2- C,..,.~7 ~-0
c ,. l -
( - J~t.f.S)

@
() 1( -:In V81 o1ia:bnn;c. w ;-11n ,e (_ t.Jor f~ 1b u)« klcl t '\1 cui4
. ...J,
8@z... vl3T
0
~s 1'>1011 ,,_.llM..ht, c.
(D (fJ a.rrOQUA
om
11- 13
.c
cj)A (1) {fg (o.} C
+ </>11 ("- J ,P8ll) (Bo~)
B
. (_l f/m- Bmdl~
yA
O
= cp 1t o J tPs t-i.J - tP1t t 7 4ie
2
J
-----------__:__:__:.____.._
tr
is
()
Q -K 1,,/,ru.1 -ft, w-r;f-h:. -f/.A_ 1,<J'1Nt' '(rnth~ &«Trt"'J ·--to IY1olLu.Jo.Y a1rbi-laJ
m
he
.c
w
w
w

ft~,,, :' r-i.--
~ uJ,- Vh 11ou-t>'l:.it:u ~ e (urt~ lrnv.fmdl"j .7" V87 'f,Y -<-6:M?
o?€ 15, c.y.:.+em
J4'veT %sT c:ft. " 1

~
j N [ ~tto J ,P,/'-J +<f>,l2J +-lpac, 1/ N[ (JttOJ?Bt2J 1--/J, i~J ~(,(/:I f;
,£ N 1J 4>,,(1)¢al2.J- ;" 0) !Je(l.)t:/T -+ j t/>1roJ¢sl2) fl11 w ¢Js0J
•
@
+ j 4>11 L2J q>8 c1) cpf/(2) it,8 (I) tj 4Jn-L2) ¢8 lt) 4)11 U) ~B (2)~c/ 0:
I
~
om
j 4>fl 4'11 :::. l
.c
JtPa4a= 1
C
Jr/>n d>e
B
-=- s
yA
tr
N2[
is
I + s2.+ 1+s1.J =I
m
he
N2 [ 2..:+ 2.s 2.] -= l

.c
w
w
w
71.t &im-p tu.f '3tY01.Jl'lcl /2--fa:!e \/ B w a.u e.tv nct-io>? 6i q

d.ia¾c M tc mo LL tu.lt l1 ke Hd l~ cl iVe¥1 a&
4J = 4'H (1.stl) (fl'..f ( 3pz. 12) -1- B
L,Une-re. r--..fallcltS 1f1t

8
CD 4-'1-1 ( 3 p-z- t 2 J t.p 4 (ts, l J @) lVa ( I.S, 2 ) 4-(. ( 31'-z, ()
@/' 4--'H Cl.51 2-) l.fu ( 3p-z., l) 6) {Jla Cl.5, 1) Lf'H l 3J,z ,2)

•• ½2 s. + C2.. :i..pz. .
c.eJt-~a:e,d- °b 1Jaam4'1-u.d 1fi~m °!J -ft..t.qbove Sp ktj~ 011br1oi

• 7'/t.t..
½-"' ;t: :Ji { c/?-c/- ::_,]

@
CD
~ C1 ~ JI
@
{!) C/ ,1. c_,._ = ;tl
e C
1- '.:L
(9 c, -=-- ..t,.,.
Ji (,2.. = -ti~
,2_.
@ C1 :; ..L
.2.
c.,_:: ± .1.
Ji.
om
LOf1P1S1.~it1Yl =i MoT ~ V 8T -
.c
Bd"-fr< t" ,.,(' i i.d:o cun,,. ..icl.t.15t'd-i0")7
two o.:roJV'l @;) €, A>~ttM, C
B
yA
W:: u/2 ~ fck,r @a:lom ti:,) e- /2 'f>-te!W,

tr
lr1mo-= [4JA-<.J Jt4>e'-rJJ [ (/>11l2J + 4J8ci:]

is
m
he
'-Pvar = [ cJ>flw 'Pal'-J] [ tP~c>-J i/la 0 1 l~ t. Co-v~

.c
w
:.J, Q:nta.lvt,J-
w
w
CtavaltMk
5' oi, Cava.ltA..J:-
~ o/, rm;t:.
0 Ace.to Mo - H1. -, ~
I .J-'t l..J -
r:1
1-t H
: 7w. Wll.U{ t,-.. drrn Co~e.!, Po~ -fr, /Y/V T , IfMo i,s tuJ,iiw11 06(,
o Uf'/~ ~ 1-erm ( fP11 ll} t>8 ('1-) f /)8 a) q, £2.) i g tSo/, lcm!c TC'i1>')
••· 11
ii..
,.So Q.(C, +o MDT wavef;11cGIM fIJ'IAtm FJUQt..t.iL w;_ c/iM.l) <.lai:e-
~ Jg Jr..a-t.,.h}_ br. s-07, CW)JJ.i u <1, (rlT 1-1- ~ S?J I . Ci.JiJ. Wjt2.. <r/ HH
bur q~mLttl-~ 1.vec1"7'""'1 -fwo {ii) -&,~ w~ Hi_ · ·
"' L ,o P ,,, ..L. '
YVIDU..lldL d.l'MlJ o.. a.,r::e 1 &0 1n rnoT , on1 L fCa-111 t1::, ov~a..rnphti:,i ~ ~ t)
Ff f.>Vl<rt<l<l be. 111•.difed, Jf--//2 c,,,-inreclc:/ d>f--/-qki7' ~

Corl UfJf-°6 tlwt6t;vra.l-,on tu..hra.cl:,d'YJ iu::1ti a c cev kf,
1YI V BT t<na.{ 1f Y\dial". lp l/2 c.cnd-allA1~ °b urya..l.JM.t f ~

bul:- /Y/ 0 ltu..d.L ¼{) -cx,s+- a.o lanfc, .st) we_ ~v-e_ 10 ~ed-J°-1-- b'j- ~;
om
.c
rl r~ 11-iu. rao'C{rnd.e:t ~ d.d:eA_Mfk.J>-:. ~ , .. °o/-
B
C r°'rnrc.. citat~cla"
~ ~ Cr 2.-1-ea:--=- 1 '1 c/-+ C,:-=/= l ~
yA
LI! iA 'Yt nma.11-u.ol

tr
A.Iv~;- va.Lu '-

is
~
m
s.6) RT ~ MJJ.JJi P1
he
Witt,,, t;un~
.c
w
w
w
. I
l,
- ----~-------------~--~~~--:-~--1,.·:c
·;;:·
Qu_s _ 1n tt..i f'o7Y!tlM? "t H-2- mol.a.tu.LL t,-,m 2-H a:hwl pb.l{,,J af q
p~1fc6'n f\ ~ B ctht /2~~~ b,cf 4- cl.A-kvnu. A_f-1B a.. paJd" 1f
Spa.tta..L Wtl V (. ton d:i"on
Q!::: tp19 o) ?p'l2} + t/Jtf!--? ~8 C2.)

:,::1,i:z~t",•'·':•"':·''it;(v ~
1
:'7:& eotaJJAAJ- lvtm Ctno/ i.6 impb~ ·, /2118:~. oo·
e ® 7kt',,s 1'I ftm,° C 9, ,, , ',

ff 119
,, ,,
'
1trY'll
,, c ,, ,,
R =- r~uCWLL ~ ~ L L
b;w-+wu ~~
om
.c
C
B
.A ---=> G S 1'~ M.o'T 1'~
yA
C
fj -, 'IVYlic.,cam
tr
e
is
m
{)
--------,-~--------,
he
a
.c
@
w
€}
w
w
G'l 4a}f.-)(JC8 ~
~ WtJ.Nt. ~i,,c.:b~ °6 a wa.lvmic n,tJU..lWJ ha..&~ -o .... --.,
(;
'
lp::: O·~9 t.p~vo.LtMi- t- c:,. 4S <r'tmic.
@
~ ~ a f1,u,.f boTh ell c.htrn °6- 1kt. b l1YtCI wtu. be tpu 11d err, -f/,-t.l
G
G !-,cl~ll'.! f11 f ao in}.)pe_c.lt~ °b ~ mollwl..t qppcrox1Maldy ti.
e t°CIYlfe
@
{tJ. l/S) 2 x1tTD :::: 0,2..62~ "XltfD
••
'Iii.·,
i:i,. ThGcn1l#coJ. j : : ~ °i ·mo T~ . ·.• .
... ·.,_
··· . I'
•
·
LCJ/o - mo mocld , f n 11,u.r,J'>;f #J ;~ ~~
moT i1::. bCl.heJ (1Y1
'1N. p-ts-inupu. °Ir-
wrttA. a w<:-.tu-ct,ndJcrw
-
-ftu;rl- ~ ou. uoca.li ~ ~°'- ~ ~ ~e rvtollu.J..L JV! ea11 mo IS ctNl._
l?~C.. , ry f J?vo/trc fr/or<=- -/t,AM O'>?e "»ucluu ww.•u_ Ro!.s
4»-. mo-no UM:/~, ~ , - tnVolvc ~ Ct11<- nvc.l.u..µ,
~ 1
IY/.0 s. tUJ... cltuet.iped b'J -fw-o lr!ell.tlle/ Lc.,qo i,,,. UtA..t."1+=1
ct:kom mctlit.,...,J 1 LCR-o ~ a c;o=/ cuA)_ 6fJ ,i.Ymf(<.n·l7Y w?1t,,
\ ) ~ o.. bdYlcl 111 e:tt, o::I 6
om
1
LCI/D - <Lu. Lr.m1 b,-na±t~ bA..J -h.oo o--ib~ o/w lfl w?)J
.c
f3
/?L ~ch~v-e_ i1 1tu. ~,°~@) CCtwid1:nt1)1tS 4rc ~~!'Cs)

B
yA
~}1e."'to/if (E)
tr
is
EDS .
Ov~tQpp f n{ ( o) _
m
he
stfmm~ C~,
.c
w
G) &-r,, Di-..cd.,. ~ WO\Jctunc.tiw> h In~ be 1 um'l'f"'7r0/,,u._ elil~1a-

w
w
@ AS'f' tfc__a,J--, txtu,.1--ofr Ovo..lcip rid )1~,
/ff;) leJ.~i ~ biiJ.a lqo 's (l1u/:;,r ha.A ..&qrt,\t ~rm¾ w.o:+,.
b orol a.x. i P>
~ we_ c_m\OW.. ~me Luu.lt
~ Hctrvri.bhrrt1a.n °ti -tf1e--.Moltu.ili.1.b
+ft! -irz ~z - -e.z.. - e z. .,.;,. :!::::.,
..2. rn e.. l/1f'G ~ l/.l(f::a.Ii h iiJ/e1J<

.. . ' ; ' : . . :.. . ''.',.! '. '. . '·.
~~ V~ :fl - Jffl]l.t .
.\.
7'fA_t_ lso/71 aj. . ft,u_ Wt;/ V efv n UNOH o/ v~un p..;/11 U.f lt_ ~ fo
;;c.c..u(ct1! ol.el:eY'mi nCt.M.t--'
-::. 0
Ht I = J'Pa, H 'Pa. ctr~ o< 1

H1,_J 4>a tf Q)b clt:~, 5 1:2- -J <P4 cpb c([_ -::S
Si.2. = SI( ~ j 4>tt t/,4 dT ::.:. /
o m
.c
E a-Es
c,{-
E+ = <'('4(3
()
. -
:: {J
C t-t.S
B
.&-E'S -<.-E
yA
C: E- = -(4--~
l+S
tr
'2. 'l.,.
is
f::!:-e7 -~-€SJ = ~
m
-<--12 :: ± ~--f'.S
he
.c
w
w
w

. ✓ .
. .
.
...
'"" t'/'. :H~~;~t~~ °1/-~111, r.iotaicd . H a:hs,rt ~ www.chemistryABC.com
ti
G
~
.f-10::. - k.2..
1,1'1
~2. -
4,r,c)Pa.q •
~
.so @ -:r~~ ot- c.1.uo.HC/'t? dwo+e,, 11.u- t!..IA t¥1't cf- 1.s Cry/-::,1 ft:J 1-
tso fCtl---col ® Q)c IVl ;+ i.sl cl.tM.ol--~ ~ @ ,
°1TM.. l.1'\ot t.J:~ W1. ~ 1 ~ -tt..t_ elt_U)Q~-W--,c. 7u:loa~:f,'Cl'J,IA q.,w Js e9
~ @) ~ Yl uci I u 6 (Q ~ ~,jcl.uJ.ol ~ ~ w,b d.t~-k.:b'°c.
t~oY\ ~ cl4.vtd-~ bd' @ 2.- ~~ -ve. 9.va~
[ ..( = Ew+ '.J -t L.{;~ R J

om
.c
@
C ®
B
Q
yA
C
tr
G
is
m
G
he
€2
.c
w
w
tfi
w
C}
Ttu. ~oV\aMtt. ftd:~ fA CtDVlAi-&-M~ 1 t~~rn e.xll-llllll,e. hd~ f1
C§;
11,\ctk: M~ be.. ob+ru.~ b( h"6"CllA~~ 1ia1Vlt~ ievr, ope.lfcdoY ~
CU:. e
e
••
J LP,.s caJ 1-t° l.fH t.J:>J d 't e
G
41
eH Jlfts Y1 .s o,')Cl -c ~
j ij) Is Cl!i) ~H 4!,sl~J clT
eHs •
•
:9:'" :·•;"·''."'.~+ ·b:,;,~, Nf>Y-O..e.i.J:-A'
-·lt., . . . ·.,,,,_~W!tE,.~.~'.~-,J:.-'C';y;•.•'s;q,·.M,,_t. '>.r,_
t1
..
' •. ..,t,;.;:;:.• . ,,,,. . '
71,A.(_
.
ov1,f11ta.l·-
' '·.
1
' ' _i•·s., ' ' ..,,_.
~,wWtmtQJ>?.·. ·o~:"~J/4,,fOYf
' •·. ••·• ~·.·\": ·_:·-~-.··.·"-·
.,.._..... '. ' {"''2.
r~
e c.!w.,@ . <')10
• J 4',s ca > H • 'f'c~ CJ'=> J d 't. :: e_H S

@
@ :.2.Vlcl l~'Ya.l drv L 1IA.t -e:>( c.lAa\t\~ t~al.. t< , wk.LCM u,1),1,,!, id.LL..
() -e..xtM.a.~ ct P h/w 11 uc..l.J..l{ C{ &- 6, p ~ i ~ if ~t/Jlf.d/!, oYJ
~
ove;.,fo..p "t o~biWL' r-1- I~ -'V<!. ,t.JdM:l,} ,"+- IA t1-v~ MdximuM
Ji fu..t 01r b~ -fd 6-v<A 1a.ppi11J- ~ 11,u_ A.a me t:14~, w ~ we_ ~la.at ~
v4.l.u.L c(. g__ ~ in <--y.. p7t'<f./JoYI
€+ = o<.+ 13
l-t-.S
om
f- - o{-6
-1-.s
.c
,e2... .+ -::Y-+1<..
E ::: E ,-., .+ -q,,-,oR l....f-S C
B
r
yA
--
E _t.. ..,_ J-t 1<. j
tr
H + R t+.S
6+
is
0
m
he
e_H +i -t ::r-1,
£_ -::
1:-..S
.c
w
r'/11,~
w
Ji 1,.< hctL, a.A.{ -v~ lua1t1-tifit;g,

w
11,u \Jdlu.t. et :J 1 1< ~S a.Uo E~.:;xp-a-el¼cd flA +e1r1Vlls 1- R ~

:T = - £iii+ ( I~ (l+R)e-iRJ J
k -:::. - ( , ..,_ ~) e- R.

... :.·' ·.. •··
'
f
,< • '
I'.~~~
~
1
'~~;"-: ' ~ 1;
.<.1.&~%·,- URo~ rllP>T -
.,. . - t f \ 'I'
;
t ~ • > • I
·.
t I
•
••
I
- · Moltwb.--.oabfM aJ..t....cttuc..t.-rd
t"lSUM i'tt1e. al:omt C. 0~ 61~ w Lclct1 Y1 vc.w. Cl.ht. cJ -tit~ 1:/x. ~ 1:>oA. r-+ta)1, @
11.ou1J1f1 ~ LC.Ao mduoc/, -11,vs ~MO'S Q.]\l_ p~u..,¼h;c.. ( i1Avo1ue.. tr)
°ii Mo -ftto.k- L,~ ~ tnrm 4' .=- '4. q,Q -+ Cb 4>b
wi-f1.1 t¾ ph°'-Jo~-% A-o's l& lo--W~~ 1'1ct"'- i1Acd- arts- to-we.-r- ~7l1.'}'01rb1tt:td.
b~ .(Jg+ ? -tt, i/2 Mo ttS coJ.b<J btl\l\.dl.vv6;
-nu.. ~ e . ~ °t tno wtuclA It\.~ fwt ~
om
lp =-- (.Q..fq - Cb tJ, b
.c
Lut~uu±-1 ph~e., A-o u itrq~ ~ Y l ~o.t-- 1 i,,q~ ½Jiw.r
oft,v,, Tc. o,-bi-1,,1 ~ de- '1'111 i,,, V, ~ aicli-1,rm
C J.u,ir mo
B
1
yA
@cJ
tr
~c ~tp4.--l1:>C/h
is
m
he
.c
w
w
w
4':::. (q_.ct-+(b<lib ~
l<'t-1-l <:. l/.)r.. J 0
6£+ a... LJ£.- rlllcJ.J.A&~ wrft-t 1tv.. ov~lo.p 1--tw 1V1 ~~ ~ au.o~ ••
hto,k~'ic.aJ --t1.-u. vo..Lw '1 df.-t- t, L1£_ca1,1 I:,(! Wwlolec;J_ by
•
~rv,jvJ d' v-ol.Lt...t. 'i- J ( k:. •
G
•
@
•
"l~'"".T'th~~ihu-litnt 1 llo· f-n 'Mo iA rr/ea.,. uAt,J !~r ~~'~v...
\d-1
o CPt.fd· c" tt. cb v fk,lA ~ aiM be_ CJliculo..&cl bl ~eQJl°'-r -,~.

•e \ 1:UJ0 JI<) rs lna..ue. it\c._ /2a.me... ev,~.:ir'rf tfAevt iku"lS" o~- aJJ....
0 ~ual, bu¾:- t1 e-lf\e."'@t 1 Rots cw. ltlot- ~ucJ tf-u.. rtll°t]v,,°+udt_ 4
e
G ~· 1 low~ ½ft'v\~oo,-b(--tnl l,\ ir~·e.ol.e."lr f,,., hrndl~ mo ~
e s fY\a.Ut.--r 1Vt a. I.di --6 rncu '11\t mo .
me. p,ro~btl.t.~ itd" -tfn-e. #=> ~c:-()·tb~ ~ mo ~ l o ~ on (> 1;c.(.
°1) 1W.. two a:ioM 1"- roro-rl,~oJ. "70

t.
C.1 -+ C 1 C:2..S
om
ci_-t C, C.:i.S
.c
fh~c. rolxtbr li:H'~ OAA..-eiu-o.1.. t.fi hoi1A ocrb f-kJ.. aJ.(. ~an?e z.. 11tot Mme..
C
i)tlAd.i.'1\f 11,u. eEJ 0>1 ik-t. a:J-om wrf'1-1 law·cct a:.tcm?il
B
-rt-l~l/\ [>1r0bi.bilt~
yA
6'1S bi.fa.-t e. ne. r;o/t J~ kt# fJJ& fn btn1olfn~ A:.+ob:- ~ law o.J'vt ~
tr
K:ti-,~cllr,d
is
OJ A +r:J.e'
m
No· 1 Molt..wlar O'l"hf~ a-ire. et:tucJ.. -to -fO-ku nor~ 1fots

he
.c
F a"" ~v~ a:rmb,11a¾-ictvt ert flat~ ~ rno.5sf-A+ol,~

w
w
:l2~ COYldi+bvt,
w
De_~e.\l\ &~ 0'),11 -ft, e. av o.. Ia p t111{~ mo Q-U ~W,.-esJ. a>::,

11, o'Ylcl.i.1j l a 1>:lH,tm di. "d ~ -,, o '1 ~ bu,,c/J."'113-
@
.s ;, o h oncJ.i.~
©
® .S < o . fl u:b '"- 8~'1'
e
• s ::::__o Wf/Yl- btMdl.o/
•
•
.
•. 241 Download all notes by clicking here- www.chemistryABC.com
· . 11.t{-tt~.:i: Mo is· ML 1-'\~ll'la.u:-u.J a.-,
o~4tili. Ct.AA_ mu+u~ ~ ~ t t l •
'b,m~ ~i.d:t-1:>~di"'t
•e
~u,11:&hvdt·on °i rnois e- a.A.t tr:.Ll,..o/ acc._-r-fo f-ltbcu.J {.-
•
fl!
0)
faull ftiYt.¥U. .
i
!Ylb lg ~ ah.:,c, °'1;,0Nd l,f io~ 't~IY1 '/10. ,~ lftlJ ($, '
•
~
M J. ::. -,..l -fo ..,_)_
t5
t-l ~ +L Q'.
® Qe.~ex""<! a <W. Adofn~

'n 11,tJ. I,. ta.Jfl"? fl(),~ ~ ~
~"J't)'YVI
@
a:~
W"b
hci.u e. AA me. Jt:. Tfr1'1/COIYl u.. ikt m °i'iutic. 11.Xl.MtU"fVI 11.o - °iJ MO
1
om
a:1re_ ~'T~~ b't ,;t
.c
if"' :: tLu.. a-rs-bf~ ~ ~~nuhfca..l a.~l1ol ~~
11 0 C
B
axi~ ~ ~ o-tfr-1-lal
yA
~u_ eailo..a
ifa .tl ::: -±l ~ ~

tr
- ;f 01rbrtol
is
m
tl::.. t '2.. - ~ o~bt..fo.!

he
~ -ttAe:.. 1)-oln'"i'vl f u ~ m 'Vt0 vt~ m-e /2 fa '1/Ctl.Jiiu ~ f Ao 1..s.

.c
.. ~Gt l1 111
w
(v ba-nd o:~i~ o'VeAappi'-i 'i 1 ~be- l_ 4b.e_

w
w
{2) 1~und- t::l, Yl><_+2-vk
~ bm~ - l/L :+ 'IL

if hwr.4 .- t /.JJbt_ +- 6 l.,d::,e.
S-cn,btW. co_~ l.\cw~ ~ @ 4;jpe iuh-a.tfim

p - - - - - - - - a-- g_~ boft,,
d rr,,r2<,~
i er I Jr1 & <t. p tJfl- f i.dYath~.

'-,( !tthrod.udt(f)J °& 9.:.pf-r, it-1 V8 T -
GLL c.ho 'Y\ ~ p1n 1r-f?a.u..ll r1rfn ~ -

lf 1f' u/dtt, 7ut'Ut/vm nD, udb.J
-spfV\ ~ m n°, ii.> 14u,~ w'1e,,,, -ft,,t.L ~\Jis+r°c.. mottCM ~ t€J
CJ._?(<':_ -ft:tlc.C'Yl ,t.J-o ~~td..t~~- 7L...1t U1YIC:Lpr 615- .e{=) -"PIYl w~ ~rol~
~ yotd~Mr f- ~ Uhl~bClc..l< i-n 0~ -ro--e.xplaiYl ~ 1}1/J... ~-h-uclare.'1,
l..Lvte_ &pe.h-~ "t a.lt<al.L cd:om, e.1, - "Th.Jt. ~od.wm O -l...C1'\.th uJLJ1J,, ~ a
om
-t'i'OVV\ it1e_ --hs-a.v11:>rt1~ o/w 3S ~ 3p o-obfto..u ~~ eurobt.d- t -to
.c
e.x r W,Y\ --\1Af1, cl oubW: I i>' M.T .ff 1111,:_ Uri~ B
C 1 A.pin i\drod.oaii/
\JXlJ.,
n-- r.., -tt..... 1111.t,,,lw.k r,op~ "D J\?k'!O'?.a,pl'c. pwid.o.._ Jl.,. twu.. 11,. no
yA
c..ll'l.¼. Tcal O.V\°"'t -to --t'L,u_ Apt'Yl ~ f+ Lh ;5,{,-y'(~ a._ 4ueu,dom 111e<..J..?.
tr
is
f>1Ae.YlOYl'l€.11\oV'l, 11 MlL~urp;'c_ pc,.;Jfcl..L lAa_ut:. ~rlYl .,-t\41 itt-tsu.. ~

m
he
~~pavd!V\O tptvt o.11\alct't\ 111on-1eu:lon1 a.1>,o~~f.!+=• i-6 T1A..w_t£

.c
f::. f\'V\ -t\A..w._ Lh funecJ..ud:iW\ °a Ldtt c,ua.M.fu M 'HV, l~ V ' { ~ , -So

w
w
6-Htl: poA-tult!t±--el!> lV\ Qrvt Lu~ fu..:b-ccluu..D} +o cbfJiJA... -tk.t~plh ftV-.f

w
'
€)
i fl,u ,,,.~ ivi +ow W<Wt:. iJ.,ndi,n,i ~ 7l<A bpe...-cdcrl(' ~~
e -lo ~pin Q 11\iU~o mo meuh.JM we,;, p--;op~e.q 1 --ft,,_e_ -frro [ UJs.e4

0
t)
1f1r tt.A"~ pu~~e. ·fA ca.Lu.d Mal-Ar)( me.<l1e(.111rc.s. ~ bc.;.,fc.
~ lo.tea °(i ~ rn<::<ltaVtlu.. i~ TO -4..tp~u.. u-e_ 1F'"c$1111 wttf1 lA.)(l
•• "- ve.t:./Pir In ikl ~ °6 tpc "'~ tlA.{ ~ F a ~

Mc,,/--M~ ,
e bd mcwJ,.,_, &. if' 1-1 dfl>VI c,.u O kp--4,~ ~ l'>(__cd;ti-'I( ~o
••
••
•
~
"11 - [ C :r] •
@l
~
a"z = ( ~ ~] ~
•
@
sf c ±1r r't
S z., -- ll- n ,--7 ~
om
°o /2p1J1 a:rnri~r momGvtivM 4
6pe--ra:fo1r ~1r-l!d!Mi-e&/ i,'f ~.
A prn ,~x . ~-1- ~ cu.m~1tlY) 1u.1s.
.c
<1"~ t a-~ 2.- a- z.
C
B
Tu lqlS', p. Oi-rac cuvd.Jlp"' q AJ-}A.f,v/J.,hL fhu,~ ~rn j'>f/YJ1 WZu()r.4
yA
urrot /4frY1
tr
flu_ UJ1 rl?e.~ofer/ t11afvT~

is
m
[ <r~, ~ ]
:: ,;/ I"' cr-z_
he
( er~ r-z.] -
1'
.c
oftl a-:x,
1
w
tlt(f"'t
u~J
w
c:;
~z,
w
@
2
~ ~ J[ ~ u:[ ! fJ t)
0c :c ~ca-~ :c [
•e
.,-\12-- C ,r'd r/1 :, [ r -: J [ i -:'1: nfJ •Q)
crz ~ ::- d1L · rz. ~ {t fJ U f j ~ { ~ ~J ®

e
@
•
:w: •,r'-'f~ff~~t~~?"?r:\~;~-· ~ ~ '--,·';:,'f~;-: .,..... .· ., .· --~- : .. :
''{"
~~,~ iS~) ~ l 1lr.5:z. -\ .

• i www.chemistryABC.com
b, ~J = i1f s.%
~2., s.:f.] :: ·itr s't
= -¥ f ti cr-z.
-17;
== i# S2.
A
l'(',,
~f''Yl paJJ-°IJ --H.u. w-o.urcttdYJ -~
om
wt?en Tu:hro-e.u.H..Ld 1Yl it,..t.-to+o.l
1fr1c.ft~ ~ -ft.,u. ~~rnr>1li:'f ~ wa.ue.1fvY1diC/YJ ~ me«bnv-4
.c
~~e_ 1
1Y\ po,;fu(cde.@ C ·
B
yA
f 06 +vw-e(i) r"-'-- 70fcJ WIJ}Je 1JUYI dtCl'Vl Must- be a td1---~'d'-m lklflc.,

tr
,it.(. . .
ti"' u ~ a
is
w :'f,r• -fo 1Jt.J-QtkA~ er-fr (l)jrrniVYJ w,'-r/A rtvJ-

m
1 a~~ [1-A-rnttM,
he
.c
tlit!. pcwJ1 CXC.W/2ldYl p7J(Vlupl..t l,uwl.M A.~ -f1AJJ± '1110 fwu ~ t)Jrft,)11)
w
r'l"
w
Q.\I\ a:1:o~ C'£H1 tt- haJJe. .Jal'V!e. ..<cl- °() ,LX:l.Mf-om Y'{_O• ~- r-&
w
a_' cliTed ALJ..u..U:-°i iW..& Q\A:H~aO'lfYl e:o-t c

0
p-Jndplt..
l 2
A. ~ ci,l q 1- - A.
G
(;) (/J
(/) rr
(J
a- Cq,q.,J - - er- ( 1 l_fl,J { ~f 1>1Ma->t'{)

cirtCf:)..
1-/J ~ ~q,,_ ~ CJ, er(_ q, ,q, ) ../- tr'( 4,q,) ~--0

·~·~ {m,4~,,;I> i, &. 'j;<lhL &-cnsdAi:da 1-w~ptmchi-ro e (J)@
. ~ ·~
:
,1/u, -In pal..lv ltl1-e. (!) tt..i. Wc:weJu..-id:,~ fllllJl,-f- b,e_ a,,Ji_..~r,1,w/»'c ®
~ all 'do% /1..i!v,,c/,.,m 710, , W-Utdv1'u'dd &,r,qp,.,,~-fo p, ~"12-:

® ~al ~ @
'111-:;_ q.,_ C CJ;, G
q-C'"t,1,) == - o-( ~1J
tr( '1, iJ =-- - u-( q t'1J)
om
o- C1,17 4--c-( 't,,<t,) CV
.c
cf) rr( '}, Cf,} ~c) C
B
yA
=) a- =-- 0
tr
1( ,sri11 pt:vd: °'ff &,11ciicn 1':-!. 7.M.t> (. o) ~ -Mo/; tf/1/dtcyi

is
wQve
m
btU'Wlt:.. -w..o ::::p '11.of- cu:.c..qft:tblt.,

he
.c
w
w
t_p7 111.ust- he QW:f-J!:.'?"HA.d,i~

w
1rr< o. 1Jurnicrn ~
A~~.
iC>'lf ~o . alcm -two e /?. ~-few,--
@ (i):: ~.,_ lt) ~b (.2.J
e,b,~ Q:q_(z)~bLJ)
S~mm q>q cufhl2.) + t/Je, {2.l t/JboJ

6
'fh,,P-5t1tl~ C/>q Cl) ~b l2? - fPt!i'l2? q, b LJ)
: f·pS -~· ··1W«/·'~-,i»~~ ~~· a.a· ,~tih. po4t~ ~wJl&. www.chemistryABC.com
G . ~ ~
O o< Ct 1 .o( ( 2..J_ '1' 'f\ ~ r>tJ'V'.t.bi'- <J.9
0 -- ~~ ~..i @)
@ d!e ~ "( CrJ 6 (l. 7 'JI..), J {f14l jJ m~,
@ 8 (J l -<. (i 7 -1.. 1' ir'll,<lh(c.
~·
(:)uJ:- 6i-1t1~e 4 t!:>pi1n &Me tfM+ ¼a l_ ..( (l) -<.l'i) 1 .(3(1 J, t.t_ {2,J aA.t
~ c3V1 & dmrne:1-n'°c. ~ W c_ ap ,e Qcd:c:. ~ p I V1 -~:x <'.!Ma_~ 0 p-t..oQ.:/u y
om
OY\ -ttu. tu 111 d-fc..v, 4 11d c '1e.,r ..,, ~ -ttu. .1::. rr,,., A.t...n1 lUL-1 ~ 4-»?
.c
C
B
yA
tr
is
0
m
he
.c
T1,u.. Ad'~IV\¾ ~ ~ A ~ . ~(J) ~tn .!..-- be.

w
~(t)o{ (2-) Can. l"lot

w
d.t!:~tvte.. be.CAU4~ Dre.ya:tt! 1>p7n e?<.c.l,1.a,v,de c;x-Yccto"(("

w
W~f'M We -tt,u_
O"n -\-tu.__ 1}JV\ c:,\{C"YI '1_ el:.~ r ~me_ ~ n t1¥ ·We ,a-~ ll. me_ W i1t,
-Ve. [ 1.e_ ct\ld:1.-AljTVltvleh't'°~)
P12. -<.t 1 J ~l<--) - ~ (2.) <"(lt} 111-el,twJ. 1::.'dmmdrrc.

1'..t, -i.~ a.1.d:-r":..hd m1N:bt'°c
-:::
'Ylo'Y
Pi2. o( t.1.-t ~ u' -.::::. GUJ e<.,(2-)
1--.J, -c:: 41'

"to ~··\t.!f_ 4lf mm~ 1--ti<t' &~~ ;W~,!,,_tc:C. 'ftµ_ ~ ~ .
. . '::.-<~??JI
Can,,bf~(dit1Vl 1;- ctbtrtlc... -tw-o & ~

•
@j
o((1]~('2..) + ~ll}ct(('2..J 4
<I
4(lt11tl2., - elt)-(l1.J
i
W fMM W c_ o-pe..d-e. ~pl~ e_XciltCU'lc;<- op('.,ra:h,1( 01-1 ~ ctbo \J ~ ~ o b-tah:. (1
we F e
-=<.
Pn. (
(l 1 & t:z..J
o(. l t
+ ~ <.t Jc( {2.J
JJ.l l 2. 1 + ~ <..t J C( (. 2..)

Stj mm~ c.
J = -< c::z.J~ lt1 + .q_ (, 7or lt )

'
@
om
.c
C
B
Li.iJ ft.2.[ o((l') ~c.2., - ~OJ o((1J] ~ o(l2..1 ~ tt1 - ~l21o< lt..J
yA
t ..i - ,{,~ = - [ ijl12.J<(O - -c (2.J~(tJ]

tr
is
=- .,L.~-1~
m
he
==- - [ ,r.~ - -J, -, ]

.c
w
c( C.,, -l (.'.l..)
w
w
~ LO ~l:t1
A[ •(ll' t12.) -+.&(I),((>-) J

f ,_ [ "( CI ) I{ t 2.) - ~ (1 1'( ( J ]
'1.) -I ~f ~ f1ll,(i,. ie

,i!"X1¥0c:;,,,::' \"""
•• l'"rh ~
e uJ'/.uh? we_ --r~ TfAR_ +ofed !:ip1v. Clvtril~r
O
1>1~»1~ c,fv....cdz,-t S 2.. G'Yt
. ..!+c=t.l"~ l 6r ya./..,uJ.. t!.o'T'o~ptrytclJ."'Ylt -fr;, e&l.Uli !,Aft:_ a?#~
/ls 11-u. ~ v~ CtnYY~pw,oU~ +o L 'l-.:- ~ ( ,t..,+ 1);, '2-

ln v°1' i.$aW?e. wa'1 ~ va..Lu..o. ~pmdi. ~ s'2-..: s(S4-1J,1?2..
Sc I
o m
.c
C
B
0( (l) o(_ (t.)
yA
a (l, Ll (l.J
tr
c(_(J J ~ f.Jl} + ~ ll)a( liJ

is
m
&J "7111 -ti,.., 'V ~ ~~ o~ .S .2. 0 p=a1oA. ,m ---]tu_ !..-hle

he
&,{ 111 IAJ I?~"' we_

.c
q' (1, fl L2. ') - .& ll ,~ (..2.)

w
w
(} S 2-[ '((l) ~ ta.) - ~ (I J "'((2.J] :::: 0 [ =((l} ~ (2) -~(? )o(_ (2.)]
w
C
G S CS+!) 1')2 :=.. o
•
e
G
e
••
1•
•
l! 249 Download all notes by clicking here- www.chemistryABC.com
· ·A4Kli. f ij Im> toff
©·7'l1ai.wo.u~+ 'i-i clluw 1fr .o P,-rniim e.,Jul,,, ;"'t •
&'f!,~ Mu.s+ be._ aldi- ~~f'VJ~ .e:.h-t..,c. . ·
Tu. p o,(,I.( l,I.,__ LU<u,e._iv In df""' ~ a bo uc ~ pa.tial q .,cl .Ir.pi.,

~-trc...t:-~ a.AL
t,J
'1'T,ll iJ1 ::- J.,A
i.y...._
{J' A\, (~ X
't'b
-<'.(I J lt ('l. , - ~(JI e( (2.)
(p.Q.lt.J "'- OJ 'K -<lt) ~ ('J..) - ~(.1Jc:i((I)

'-f-r I ~ ldt : 'fob
tr'r,C(v.£ -:. 'PQttJ cpb(2?+ 1at1...J 'P1oOJ )( a(l.0 ~ t2-1- &_l.2.J e((t)
'l'T I a. !An := [ 4>4 l11 41,,('l. J- <fiql ._ 7 qb (I J] X' [ a( ( I) "( ( 2.) J
om
L.p'T, cu,..H : [ Pa(I 1 4ol2.? -4>q ("l..) t/Jblt}] )( [ ~llJ ~ (iJ J
.c
C
B
yA
tr
is
;.. s la..t'(.~ De::b:.,r M f -na.\.\X -

m
We. 1u.ho::iuc.tol lsf>lfYI t -ftvtt- ~

he
'114U e_ W(.. l,.l).)Je ~-fJN,
au.±t~~ ~ll\A dnit- t.Aftlue_ -(rne:b'°on, ac c-J-c poJi:f-vl<le..©

.c
we_ rv1u~ t ~e_

w
,ill ilitJ-.<m\,: wet \.lee_ tf 111 d-ttfYI n1 LlSf- be_ a.lA:ti~ ~ "" , Jf- ;,,. ~'t +o
w
t.,:n,tk-e. . Q.\dl ..../2/j»l ~ t-, Ill di~ 't /~A pe_df'7YJ W

w
Wt:I.Ll e b
16 we.. l\CUJ Q.. a btt °b
-0 ..
w wJ:, <'Y\ .-- .{.Fl l1 O?f1-::>1+r11! ~ we_ tu.t.d_ 1o @
Onilt~d Q\A au.+L-~cf' q~ ~ wcwe. 1;ovi J:-i'dYJ , ,v. ~ l~3o @

~
~locfd..- ?wbrodot.LJ 1td.. ~e 1J ~m1>1a!J;s 4c ea~+rtJd
au.M- ~~W\~t wt1~~ t,;vtcJ:!crv,, 11 we_ Ut&e.
lStl) lSC,) [ c((D~l~) -~Ct) o(_(2..)]
~ 2e-4.'"r~

• ·~:''r';c:,~.. , , ; I,. , ., ,
•·· . we Ctt"' w,d ie " . \ www.chemistryABC.com
: f!ijs,_] ts. •W J
.So Jb tole.~ M:-e\ 1Y? i na.«±- i p, c.ndi Stwt v,, el-rte. LA.J(W e__-ff Y>dr~ 1t,ud"'
9-.Lp~~ -itu. ~IC U1tl \Jt'.c ~ YI ctTDY\ ~ ~ 1h.,._ pu,di 0
- e:tdu~~
pJ nuplt. I
~ ~ f-{01.JJ --tn U21Yl&-hrud- ct wa.ue. 1f nililM U/4f.,,q d.J.fe.J.,:mina.Mr'

I)
:,=liss+- we. CJJ-tM>frocl- ct Md.t)U"I( o&-
om
~piYl 01>bt-tal 1 1n f;lMr NW °D MaPJtJ)( w~ pu.1- 7h-A... trrh)W r/Ao.t-
.c
-h,.,_ fir,,f- e ell-,, l)CLU fO ~ QM.,ri· -ff,u_ Jjr<',(.fE" -ltr/'1,,en,,, 11,i,,.,i.
C 71-u...1/'lf~-r
B
tor He. I' tve /AQve (!) o'2sbi-\-o.l ls(-< J &.. 1S(I$) 1
yA
'1f01JJ 1 rnab.lx bc~e

tr
1s(_i<Jl1) ,s (f (, J
is
m
1111 f1,u_ ~e..egy,c) f..l!Ju.J °b ,nci/;J!J')( we_ pu± 1tu. ..{.~Me cnrb,+.J. bui-
he
a)l..ftn ~ -to --t1,u2_ 2-.hol e ;1!1n 4- 1W_ 2.""( p; a.l.Ao e,,,.,J..t} b-e._ 1n
.c
w
w
w
1..S C-<JlO
1 1 Sc( (1)

. ,
.M- IJ:tWe fndt~

. . ... '. \·~0--.. :'· .--- --_:✓· -__ -;·•: ,, ,, -. · •. .:
y.,r,OaA.J:-cd ·~ d.dv.rt/iY/4kl-. wi/.J .be. a.hJI..U.(1-mmehlc

•• _ : .. __ r....:·\ · . '.'"/.-.~/<·_( :-:-. · ---:ll1:\\i'• . ·.: ·
"'~I-
Wt.. eam ~ Q. ~ b~~e. ?~7- ·6-fr e.G. t,,, WQu c ff nett~ p>od.tx.t. · ••
~am.e...w1;1,\ .-ve ·~~, it m~b< ~u,,ralu,J;- [.Al..p-r~eA.d:eci) ~ · ~
---tLu- f?rO~ 1f~t.hq~arnd t /lcWS f)? ft,d mabJ~, ~ we,

(f$
Cluw,r- At,uJs rn 7f4.t. mc,J-.J,l')( ~ tf M~6 W( aN... qaFNJ'

10 tiuAJAffl eP wt.it.bi cham,-e +tu. /4.irn i wt!Jfe fund-ton,
~ ()) I I ~ (l..} l
"JJA i"tfl~ ~e_ 'i
I -<. (J ;,
o( l'l..') 1l(2.J
cl:tVi.tuM we:.. 02rv1,i;huci-4 Ma.Wx wrtt,, 711,--et.

~
ci( (.2.J
. c(_ (I) . ~(I)
om
l a-W ~t-- C>AJ o.l.,1t,. h l1 -&pln o"rt>i+t:tlJ. l5 o( t. 1s ~ , .2 s -<
.c
6u.t:-~f- d"UW w,'ll be
C
B
yA
l.Sc(Ct J ts~ l! J cl..S-< UJ

tr
..g__ o-w-,... 2..v-d. ~s~ MW wUt b~, we pu.1::- zl?d tt 3-r-d r ftJ
is
m
~am c o -obf~
he
.c
l.£ "'( l3)

w
w
w
f,)

r~;~1:wt:·:·•
lo Jd= Wn-{/;c_ ,ft«_ d,f-.e,..mf>i~ Wtt'V~ #" cl/n1 fo "1-~
Y a:lom
1jMf "/J oJJ. we .LIM· au,(. @ O'lfb t+alJ. ( f,, Q2. %. .. . )
~ 1111 at&e. 1 Be. 15 -:a.2.s2. wi-#1 1.1e8 ~ka¼ ~pfv, 0~1'°f1t.l Cmtl.olwe
U.~~ ? 15--< lS~ 2.S -< 2. l3
:z..r,d
1:2 C1J · • · ~ ~ · ftw (t}

fj
om
(
/J~
.c
C
B
yA
tr
is
m
he
.c
w
w
q), (YJ) 4>.2..l 'Y17 .... ., 1,y'J{'Yl}

w
111 u~ 01.tA tlal-e.1r Mal-Af ')l ~ 8 e 1~
/.S"((tJ lS.~(I) 2.~<l{(f) 2S ~Ct)
l .5-(' (1) t~'-1('1.) J..s ~ (.1J o?~ ~ (2)
\S"(C37 1S ~ l37 is o< t3 J 25 $ {3)
is o< C.4) 15 .(S {__L/) 2So((4) QS~(Lf)

.···. .
·.. :··::-;-,
•
••
Tu ~ ~/-c.p 1.»e J,,, a vc lJft i1s fo No~malJ.-07:ul -flu.. weu, e.
~
.ff nt:H f.1YI I if- ,~ ea! 't ~
@
To o/(o TM a.l!u.J 1 1f'o •'>l <-® cd-orn rn u..l:R p~ bY-- L
W<::.._
(I Jn~
-t-o
•
~
@
@
~
@
li -=-
-
_J_ @
om
J 3{ @
.c
~
C @
B
yA
®
G
tr
is
@
m
©
he
(;;)
.c
®
w
w
w
@)
@
~
•
0
-- t)
•ft)
fa
I}
254 Download all notes by clicking here- www.chemistryABC.com ••

DPP 18
I .Consider the statement
(i) For one spin system there are two spin state ,for two spin system there are four spin
wavefunction. -r
(ii) a, a.2 and Pi ~2 are symmetric wave function whereas a, ~2 and~, a.2 are antisymmetric in
nature with respect to spin exchange operator. t= ·
(iii) fu triplet state the function corresponding to ms= 0 does not exist.f
The true statements above are (a) i,ii (b) i,iii (c) ii,iii (d) i,ii,iii ~ only (f) ii only (g) iii only
2 Consider the statement
(i)The spin operators satisfy the same general equations that we developed for the angular
momentum operators. "'f ·.
(ii)The value of commutator [Sz, S+] is -(h/2x)S. F
(iii) normalization constant of an N x N Slater determinant of orthonormal spin orbitals is
1/(N)0:5 :f . », ,
The true statem~ above are (a) i,ii (b) i,iii (c) ii,iii (d) i,ii,iii (e)I only ( f) ii only (g) iii only
om
3 Considerthe statement · ·
(i) when we operate the operator S2 on state a. 1 a.2 then eigenvalue is 0. 1==
(ii) The spin angular 1!10mentum operator i,s generally represented by pauli spin matrix. T
.c
(iii) For being total function antisymmetric if space part is symmetric then spin part.may be
symmetric may be ant symmetric. fr' C• , • ·
B
The true statement above are (a) i,ii (b) i,iii (c) ii,iii (d) i,ii,iii (efonly (f) ii only (g) iii only
4 Consider the statement · S ,· ( ~ 1 S. ~, St'--) ·
A
(i) only the magnitude of the spin angular momentum and~ ofits components can be known
y
simultaneously. f . -
tr
(ii)Pauli exclusion principle requires that each orbital have a maximum occupancy of two
is
electrons may be explained by Slater determinant. 1 , ·

(iii)The two electron with same spin in a state have zero probability. T
m
Correct statements above are (a) i,ii (b) i,iii (c) ii,iii (d) i,ii,iii (e)I only (f) ii only (g) iii only
he
5.fu certain axis of quantization z ·componen;;l[_ sp~ ~gular n10menttim have the following .
representation · . So111 ~OJD--?M4.l ~ <rd':;,. r, 4:- ~ <::i.-2.
t>] s~~s.;:-
.c
Sz= lj ( I o what would be th~fthe matrix S/ is 'd ..,,..

o O CJ · (a)Olj 2 (b)llj2 ( ~ (d)noneoftheabove s.,L- tl
w
. 6 ?>-f
@)A random distribution of error obey the Gaussian fonn as (Alx)°- ?Ja1l~kvJ7
w
5
e•Ax2 , The mean and
standard deviation of this distribution obeys ·
w
(a)<;x>=O , ax 1/ (A)05 (b) )<x>:f:0 , ax= 1/ (A)05 (c) )<x>=O , crx = (A)°-5 (d)
)<x>:;=0 ax= (A)
7. Fill in the blanks
i)The wave function corresponding to helium atom including spin is ..................... .
ii)Normalisation constant corresponding to lithium atom in slater determinant is ........... .
iii) The NxN slater detenninant may be written as . .. . . . . . . . . . . . .. ? , , , ..
iv) percent ionic character may be obtained by parameter 1 as ......... -~~ 2. - lr IOY1! C
v) In MOT the covalent term and ionic corresponding fo two atom two electron system may
~ ~ : : :~;i~-~~~~~tum operator in ~·dk~ti~~in form ofpauli matrix is ..$.t: ::-:&, lif ~ [ h

vii) When we operate Sz operator on a spin then corresponding eign value i ........... .. _1

st~.•-·· Cr,'J:.rJi ,...," ·· . ·
·-1''·•.·f"!iv""Nl!f•·"'S
·~:<
:.,~;?}'~, . l
. . ? ' 'ijjf~~.• "f'
,,,•
.rlr1 ft:~f -#1°, ..(.:
'.~
/i/-~~~,..$T~·.
l_SA (Jf _J.SJj"4., .. ' !.1,ll
·"'. st'';,
.i/•''~)
t~ittfJ~·, ·'>.
-~'I»>~~.
, , t,St:A. DSC~~,., - ~ - ' ,
;~~t¥tl:. /'./~ < . ,. .. t•>
om
.c
C
B
yA
tr
is
m
he
.c
w
w
w
I
(
(
s
(
7
8
rr

DPP 17 Regular Batch

1. Consider the· statements
(i) Overlapping Sab can have value between zero and o~e. In order to have a chemical bond it is
necessary that Sab> 0. -r
(ii) The bonding orbital change sign on inversion in Px and py orbital so it is ungerade, and
antibonding orbital remain same on inversion so it is gerade. T · '
(iii) Bonding orbital show a build up a electron density in an internuclear region while
antibonding orbital show a d~crease of electron density in internuclear region. T
Correct statements above are (a) i Ji (b) ii,iii (c) i,ii ,iii (d) none
(i)In the case of bonding orbital of HF molecule N(C1'1'1 · + C2'1'2) C1<< C2 T
(ii) Photoelectron spectrn generally support the existence of molecular orbital.""t
(iii)For Hetroatomic molecule higher atomic orbital contribute more to antibonding MO and
lower atomic orbital contribute to bonding. T
Correct statement above are (a) i ,ii (b) ii ,iii (c) i,ii ,iii (d) none:
m
3.Consider the statement ·
o
(i) Virial theorem apply to atom and molecule described by either by exact wavefunction or by
approximate wavefunction. 1"' ttJ. ·
. . .· . . · .
.c
(ii) Orbitals are conserved and generally probability amplitude can be positive or negative. T
C
(iii) Size and energy of any atomic orbitalare generally determined by quantum number n, and
B
both play a crucial role in detennining the significant interaction between AO.T
Correct statement above are (a) i,ii (b) ii,iii ('err,ii,iii (d) none
yA

(i) The sign of the wave function does not indicate anything about charge. I
tr
(ii)In a 2p orbital, it is just as probable to find electron density in the negative lobe as it
is
is to find electron density in the positive lobe. T

(iii)A molecular orbital cannot hold more than two electrons. T
m
Correct statements above are (a) i,ii (b) ii,iii (c) i,ii,iii (d) none
he

(i)An antibonding molecular orbita,L(designated with an*) occurs when the electron
.c
density of the orbital is concentrated in regions of space outside the area between the
atomic nuclei "'i. ·
w
(ii)rotating sigma bond does not decrease the overlap of the orbitals involved T . _,
w
(iii)pi bonds cannot rotate around the bond axis. T .,~"'lf»'

The true stat~ment above are (a) i,ii (b) ii,iii (~i,iii (d) none a-10--'-of l
w
6 Consider the statements · . • .j._\'1,/l,,

(~~Forb~nding MO Sav0 'for antibonding Sab<0.. T 'bi
¢tVl\
(n)I3ondmg and antibonding molecular orbital are orthogonal. 1
(iii) !he magnetic quantum number in molecular ;rbital'is denoted by 'A. , if 'A.=0 the orbital
syminetrical with respect to reference axis. -r .
Corft:ct st~tements.above are (a) i,ii (b) ii,iii (c) iJi,iii (d) none · ~
7Nom,ta11;Z~:the molecul~_?rbital 'I'+ in case ofH( molecule ifS=0.~9. ~ .
8 ~13~nd1ng molecular orbital leads to accumulation of electron density between the nuclei to
Jl11~~1P'.~~~9!(!Us nucleus repulsion. (f/F). 1
· ._, (Il}Gom-·aroo to H + c' · · · ·
,1,,,,,'""~ ~.y,,,,_,., - , . 2 the bond energy of H2 is greater. 1
-
-; _.,- ~-~·?--:'"*·•'•"- --~ ...,-:. .>,-._-: '• •. , .
(f)-(i)
Ct2@·G
' . :

(i) In VB theory, a bond forms when an electron in an atomic orbital on one atom pairs its
spin with that of an electron in an atomic orbital on another atom. --r
(ii)In MO theory the covalent and ionic term have equal weight. T
(iii) VBT asserts that electron pairs occupy directed ·orbitals delocalized on a Qarticular atom I
The true statements above are (a) i,ii (b) ii,iii (c) i,iii (d) all (e)none ~l>fn?D~C.
(i) According to u.ie Pauli exclusion principle when electrons a8'f~challjed 'I' must change sign
'P (1,2) = -'I' (2,1). - T ~ _...,( 48.{~l
(ii)For the molecule to be stable Llliio1a1< 0, Lllikinctic<O , ~potentiai<O. f=
(iii) Slater detennmants are used to express wave .functions of many electron systems, and by
many electron we 'mean more than one electron 'f' ·
Correct statements above are (a)I,ii (b) ii,iii (c) I,iii (d) all€ none I
I
.. I 11.Consider the statements '-. I
(i) wave:functiondecibing many electrom system must change sign under the exchange of any
om
two electron --T c_()N,ct{.- l!t(P1~'-?
(ii)The integral H 11 represents the binding energy of the electron in the ls state to nucleus LT
.c
(iii)overlap of the orbitals becomes Owhen the atoms are separated 1:,y an infinite distance. T ·
The true statement above are (a)i,ii (b) ii,iii(c) i,'iii ( ~ l (e).none
1-2 Consider the statement . C
B
(i) H 2 molecule, the two electrons reside in the 1O'g ~olecular orbital and the configuration is
-r , -.
yA
(lug)2
(ti)A purely covalent structure with equal sharing of the bonding electron pair would result in a dipole
moment ofO for the molecule. 'T ·
tr
(iii)for most heteronuclear diatomic molecules and write the wave :function as '!f'molecule=
is
wcovalent+ A'lfionic. T
The correct statements above are (a)i,ii (b) ii,iii (c) i,iii (M-rall ( e) none
m
he
13 For a molecule XY, wmolecule= wcovalent+0.50wionic. Calculate the percent ionic character
oftheX--:-Ybond. t-1-=- £hS'-o ti.!l. 1<.{UO .
r,r;; ·
.c
14 Consider the statement ~

(i) Ionic term dominate in molecular orbital methos so we need correction in theory. 'T
w
(ii)If th~ electron in the HF n,iolecule is described b~ 'If= 0.34 <l>H(lS) + 0.84 <l>F(2pz) then
w
. propabibility of finding the electron on H atom is 21 %.

w
(iii)In thp VB model the molecular wave:function are generated from AO whereas in in MO
model the molecular wave function are generated from MO , which are linear combination of
AO. 1 .
Correct statement 'is (a)i,ii (b) ii,iii (c) i,iii (d)' aU (e) none . ,.
15 Consider the statement .,. l,:,tv1cli'1'
(i) the energy of the MO that has form w=C 1w1+c2w2 in-phase atomic:orbital is lower than that
oflower lying orbital by LIB+.© ' : · .·
(ii)The energy splitting LIB+.+AR. always increase with overlapping integral. -r
(iii)The negative of o; is generally considered the ionization energy -t
Correct statement is (a)i,ii (b) ii,iii (c) i,iii (d)all (e) none
16 Normalization constant for [<l>a(l )<l>b(2) +<l>a(2)<1>bU )] for a homonuclear diatomic molecule
according to valence bond theory if S=0:59. ·
l
258 Download all notes by clicking here- www.chemistryABC.com l

... l ~,~:?~:t
fj): <$.q(l) "1,t2.J. + ~4{2J 'Pb0)
[6~0.5~
I 1
N ::
om
.c
C
B
yA
tr
is
h em
.c
w
w
w

om
download all hand
.c
C
B
i
yA
tr
written notes here
is
m
he
.c
(click)
..
w
w
w

(WWW - chemistryABC.com) QUANTUM - CHEMISTRY - Sahender - Sir PDF

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

(WWW - chemistryABC.com) QUANTUM - CHEMISTRY - Sahender - Sir PDF

Uploaded by

Copyright:

Available Formats

QUANTUM

By Sahendra Sir(In India's top 2 Educator)

1 Download all notes by clicking here- www.chemistryABC.com

PHILOSPHY OF QUANTUM MECHANICS

QUANTUM MECHANJCS CLASSICAL MECHANICS

dynamics of matter at microsco ic scale macroscopic scale

It is invisible world It is visible world.

2 Download all notes by clicking here- www.chemistryABC.com

. (J) ~<I. r\t~atueol f'vi 1.uaKlum ~~

@ opotUoir a,. rcnrn ' . . ·/: 111~' 1

::; :dfn" ~ e,n ~~ t'V1~

· .spiJ1 �q���· momeµlvw1 � o,s-b1-1a-l q1fta'«r 1ll1 om�

�te.�o.l paJnrtc.cr p'dOh�

3 Download all notes by clicking here- www.chemistryABC.com

P<h...fuma:J/O'YI m�- 'U-o"l(oiJ.'¥ fodv�or,

C �ufr at- /)kaG oJ.dl-q f ndtm}

fH,omfc .-6+7S'Ud:u--<� � --&F-�<Df1f-

� tca.1__ Btmd.Lnf r111 d1'a:Jo»,i(_ fYltJ i.J. t..LJ.h

,cm 1 rno "T, (., V 8T

H'u 1�e1 M..0 Th�� tth ctpplL�CM/2 +o

4 Download all notes by clicking here- www.chemistryABC.com

rnab?emllffcs tnvoru� www.chemistryABC.com

cl (i) ��mcdt'1Yl � · ( -ve.)

• .1 SL'hax. a.. Ct>.&ax:.

(f) j x'>lcJ~ ~ [~,]

1 Si\-ix_ d:x. :: - GM.x.

J Ce@<_ c/,c_ =c srn:>t

(D St rt"'8 -:::. I- C&>.5 26

UP>20 :. '_,.. CJ,,,!, U}

.s,ne U>lB .:::. sin2s

6 Download all notes by clicking here- www.chemistryABC.com e

Siw, (_ 1f 1 :i.'Jf, . _r. n,r) -:::..0

(ff) W,c_ll-rB) ::: &.,!ICMB - S'ir1II.Sir1B

(1.) J&in-,.b"-~"" J 1- ~~'-cht "' -H?(J _ ½[ st vi:;,~

7 Download all notes by clicking here- www.chemistryABC.com

C>pe:1£alo'"'( fJ.> QV\ ~\ttli' fLta±- ope..-irctt<:A oYt a if tAd:fan.Qyto/

&1,fc. ChazradesJ1>·ti'cJ-0/s= crp:.,i-g:/or -

@ opt..7f'~ a.M. ciL'"ll't!..of,"r.tn::J. ln v, afvre l. <!:.. ha.A.Jc::.

8 Download all notes by clicking here- www.chemistryABC.com

.~ --vtt"'· ,'fOUJ<!.Jt tnc!t:lH6 · O~

kf\11.e:ktc.. 0te..!'ft cpewa:lo¥ -

10 Download all notes by clicking here- www.chemistryABC.com @

~ f [ ~Pz- z~J _.. ] [ Zfk] ~ 1 [ :,'¾-~P,J

l ~ 1.7-z-- ~ I + J Czp..c - x_h.) + K( :x.Pr ~ P....)

•• S~R (7} ::: S~~ (3+4)

4-o 11,te. orc.1S"crknr M°1 be cl.tt-o.mikld ,.g.tn,uti:-o.~ ~ ' ft Q_tn, l t-

Lj) JV1M\)tC. ca Y\ \+ be.. dJ.l-c.is-mt Vl~.

e ~ ufoUJ.±e ~ keQ.~be"1' UV1~~ pcif>1U~lt.

.., J\ .1, ...

•• 11-13 =- an --rh e,v, n~8 a rG ~ -fo be

••• W McJ-t O {>e"'lf eQ(J1'

~u4- f"'-q ~ vatu'--of a,vv,w,~cf

c,nre . . ,2.1JtJ8 or=17on '>Ir i.}

14 Download all notes by clicking here- www.chemistryABC.com

[A, f3J = - [B,11]

15 Download all notes by clicking here- www.chemistryABC.com

I f;>x -n;,(11-1 ::- - [ p,,

e,- - [-:tj, t>,t.] c. cdi, ax2...

16 Download all notes by clicking here- www.chemistryABC.com

)!IJ, c) -" 13.[11,1:J t- [~ c].$ 1

-=:.. f-t; ¥!~:1- 1

~(_ I i,:!]-= -+ i-~1 n p,2'1-)

17 Download all notes by clicking here- www.chemistryABC.com

· .spiJ1 �q��· momeµlvw1 � o,s-b1-1a-l q1fta'«r 1ll1 om�