Professional Documents
Culture Documents
Metal Parts
Leather
Rubber
1. AZO
1.1 Aryl amines that are not allowed to be BGVO § 3 ≤ 10 mg/kg
DIN EN 14362-1 Textile, DIN EN 14362-3 for
split off (Annex 1,7) (pass)
p- Aminoazobenzene (pAAB); DIN EN ISO 17234-1, x x x x 3
from dyes under reductive conditions EC 1907/2006 ≤ 20 mg/kg
DIN EN ISO 17234-2 for p- Aminoazobenzene (pAAB)
(AZO) Annex XVII (need)
≤ 10 mg/kg
Extraction with Ethylacetate, 30 min., (pass)
1.2 Technical MDA LFGB § 30; SVHC x x x x 3
40°C ultrasonic, detection with GC/MS ≤ 20 mg/kg
(need)
EC 2019/1021
for PCP
3.1 Pentachlorophenol (PCP) 1 mg/kg
chemicals prohibition LFGB § 64 B 82.02-8; DIN EN ISO 17070
Tetrachlorophenol (TeCP) 2 mg/kg x x x 3
ordinance Solvent extraction with KOH
Trichlorophenol (TriCP) 2 mg/kg
EC 1907/2006
Annex XVII
Metal Parts
Leather
Rubber
Extraction with Acetonitrile: 1h/70 °C,
11. 2-Mercaptobenzothiazol (2-MBT) LFGB § 30 100 mg/kg x x 1
HPLC/DAD/MS
Sb 30 mg/kg;
As 0,2 mg/kg;
Cd 0,1 mg/kg;
Cr. total 1,0 mg/kg -
EC 1907/2006 DIN EN 16711-2 Textile; only Textile;
14. Soluble heavy metals x x 1
Annex XVII DIN EN 17072-1 Leather Co 4,0 mg/kg;
Cu 50,0 mg/kg;
Pb 0,8 mg/kg;
Hg 0,02 mg/kg;
Ni 4,0 mg/kg
Benzene 1mg/kg
Benzaldehyde 100 mg/kg
Bis(2-methoxyethyl)ether 1000 mg/kg
Metal Parts
Leather
Rubber
17.2 Fumigation
Methylbromid 1 ppm
1,2-Epoxyethan German workplace 0,1 ppm
VOC-Detector x 1
Hydrogencyanide exposure limit 1,9 ppm
Phosphine 0,1 ppm
Sulfurylfluoride 1 ppm
French Arrete
17.3 Formamide Extraction with Methanol, GC/MS analysis 100 mg/kg x 3
1st August 2012
500 mg/kg
Extraction DMFa: CEN ISO/TS 16189,
17.4 Dimethyl Formamide (DMFa) LFGB § 30 if waterbased x x x 3
DIN SPEC 52411
PU < 50 mg/kg
19.1 Short-chain chlorinated paraffins EC 2019/1021 E DIN EN ISO 18219* 500 mg/kg x x x 3
EC 1907/2006
20. Chlorinated Organic Carriers EN 17137:2018 1 mg/kg x 3
EC 2019/1021
21. Biocide
EC 1907/2006
21.1 Dimethylfumarate (DMFu) Annex XVII
ISO/TS 16186 0,1 mg/kg x x x 3
50 mg/kg
Children
22. Soluble mineral tanning agents LFGB § 30/BFR DIN EN ISO 17072-1 x 1
200 mg/kg
Adults
x
(not
23.1 Total Chromium EN ISO 17072-2 1000 mg/kg Chrome
3
tanned)
x
< 1500 mg/kg (full ve-
23.2 Total sum: Aluminium, Titanium, Iron EN ISO 17072-2 3
(pass) getable
tanned)
24. N-Nitrosamines LFGB § 30 Extraction with solvent, GC-TEA or APCI-LC QQQ 1,0 µg/dm² x 1
* (Modification: Internal Standard PCB 209, SPE or sulphuric acid clean up, extended temperature program to determine SCCP/MCCP in parallel,
determination of SCCP by evaluation of 21 masses for SCCP and 21 masses for MCCP, comparison of retention time and peak shape)
Natural Fibres/Natural Material
Synthetics/Plastic Components
Metal Parts
Leather
Rubber
26. Flame retardants
Verification of odour
Articles with an atypi-
cal odour suggesting
28.1 Odour SNV 195 651 an improper produc- x x x x 1
tion, storekeeping
will not be accepted
(grade 3).
1. List of the aryl amines that are not allowed to be split off from dyes under reductive conditions/Technical MDA
Name CAS-No. Name CAS-No.
4-Aminodiphenyl 92-67-1 p-Cresidine 120-71-8
Benzidine 92-87-5 4,4‘-Methylen-till-(2-chloraniline) 101-14-4
4-Chloro-o-toluidine 95-69-2 4,4‘-Oxydianiline 101-80-4
2-Naphthylamine 91-59-8 4,4‘-Thiodianiline 139-65-1
o-Aminoazotoluene 97-56-3 o-Toluidine 95-53-4
2-Amino-4-nitrotoluene 99-55-8 2,4-Toluylendiamine 95-80-7
p-Chloraniline 106-47-8 2,4,5-Trimethylaniline 137-17-7
2,4-Diaminoanisole 615-05-4 o-Anisidine 90-04-0
4,4‘-Diaminodiphenylmethane 101-77-9 2,4-Xylidine 95-68-1
3,3‘-Dichlorobenzidine 91-94-1 2,6-Xylidine 87-62-7
3,3‘-Dimethoxybenzidine 119-90-4 p-Aminoazoben-zene (pAAB) 60-09-3
3,3‘-Dimethylbenzidine 119-93-7 Technical MDA 25214-70-4
3,3‘-Dimethyl-4,4‘-diaminodiphenylmethane 838-88-0 p-Phenylendiamine (pPDA) 106-50-3
2. Navy Blue
Name CAS-No. Name CAS-No.
Navy Blue 118685-33-9
3. Chlorinated Phenols
Name CAS-No. Name CAS-No.
o-Phenylphenol (OPP) 90-43-7 3,4,5-Trichlorophenol 609-19-8
Pentachlorophenol 87-86-5 2-Chlorophenol 95-57-8
2,3,4,5-Tetrachlorophenol 4901-51-3 3-Chlorophenol 108-43-0
2,3,4,6-Tetrachlorophenol 58-90-2 4-Chlorophenol 106-48-9
2,3,5,6-Tetrachlorophenol 935-95-5 2,3-Dichlorophenol 576-24-9
2,3,4-Trichlorophenol 159-50-66-0 2,4-Dichlorophenol 120-86-2
2,3,5-Trichlorophenol 933-78-8 2,5-Dichlorophenol 586-78-8
2,3,6-Trichlorophenol 933-75-5 2,6-Dichlorophenol 87-65-0
2,4,5-Trichlorophenol 95-95-4 3,4-Dichlorophenol 95-77-2
2,4,6-Trichlorophenol 88-06-2 3,5-Dichlorophenol 591-35-5
4. Nickel
Name CAS-No. Name CAS-No.
Nickel 7440-02-0
5. Cadmium
Name CAS-No. Name CAS-No.
Cadmium 7440-43-9
6. Lead
Name CAS-No. Name CAS-No.
Lead 439-92-1
9. Softeners / Phthalates
Name CAS-No. Name CAS-No.
Benzylbutylphthalate (BBP) 85-68-7 Dicyclohexyl phtalate (DCHP) 84-61-7
1,2-Benzenedicarboxylic acid dipentylester,
84777-06-0 Diisopentylphtalate (DIPP) 605-50-5
branced and linear (DPP)
1,2-Benzenedicarboxylic acid,
68515-42-4 Di(2-ethylhexyl)phthalate (DEHP) 117-81-7
di-C7-11-branched and linear alkyl esters (DHNUP)
1,2-Benzenedicarboxylic acid,
71888-89-6 Diisodecylphthalate (DIDP) 26761-40-0, 68515-49-1
di-C6-8-branched alkyl esters. C7-rich (DIHP)
1,2-benzenedicarboxylic acid, di-C6-10-alkyl esters;
1,2-benzenedicarboxylic acid, mixed decyl and hexyl 68515-51-5
Di-n-octylphthalate (DNOP) 117-84-0
and octyl diesters with ≥ 0.3% of dihexyl phtalate 68648-93-1
(EC 201-559-5) (DC6-10P)
1,2-Benzenedicarboxylic acid, dihexylester,
68515-50-4 Diisononylphthalate (DINP) 28553-12-0, 68515-48-0
branched and linear (DHP)
Bis(2-methoxyethyl)phtalate (DMEP) 117-82-8 Di-n-hexylphtalate (DnHP) 84-75-3
Diisobutylphthalate (DIBP) 84-69-5 n-Pentyl-isopentylphtalate (PIPP) 776297-69-9
Dibutylphthalate (DBP) 84-74-2 Dipentylphthalate (DPP) 131-18-0
10. PFOS / PFOA
Name CAS-No. Name CAS-No.
Ammonium pentadecafluoroctanoate (APFO) 3825-26-1 Perfluorooctanoic Acid 335-67-1
Perfluoroctanesulfonate 2795-39-3
11. 2-Mercaptobenzothiazol
Name CAS-No. Name CAS-No.
2- Mercaptobenzothiazol 149-30-4
12. Formaldehyde
Name CAS-No. Name CAS-No.
Formaldehyde 50-00-0
15. PAH
Name CAS-No. Name CAS-No.
Acenaphthylene 208-96-8 Benzo(e)pyrene* 192-97-2
Acenaphtene 83-32-9 Crysene* 218-01-9
Anthracene* 120-12-7 Dibenzo(a,h)anthracene* 53-70-3
Benzo(a)pyrene* 50-32-8 Fluoroanthene 206-44-0
Benzo(a)anthracene* 56-55-3 Fluorene 86-73-7
Benzo(b)fluoroanthene* 205-99-2 Indeno(123-cd)pyrene 193-39-5
Benzo(g,h,i)perylene 191-24-2 Naphthalene 91-20-3
Benzo(k)fluoroanthene* 207-08-9 Phenanthrene 85-01-8
Benzo(j)fluoroanthene* 205-82-3 Pyrene 129-00-0
* REACh
21. Biocide
Name CAS-No. Name CAS-No.
CMK 59-50-7 OPP 90-43-7
Dimethylfumarate (DMFu) 624-49-7 TCMTB 21564-17-0/64441-45-8
OIT 26530-20-1 Triclosan 3380-34-5
24. N-Nitrosamine
Name CAS-No. Name CAS-No.
N-Nitrosamine 930-55-2
25. pH-value
Name CAS-No. Name CAS-No.
pH-value -
Growing knowledge of the effect of harmful substances has encouraged the legislature and the trade to acknowledge this situation
in the form of new legislation and voluntary commitments from the trade. Sophisticated research methods and the level of knowledge
of the effect of aggressive substances will result in more exacting standards appearing in the future. It is self-evident to us that all those
partners participating in production should guarantee compliance with the maximum values.
We guarantee that all materials processed by us do not contain any substances harmful to health. We undertake in particular not to use
the substances listed in the appendix or to use them only within the specified limits.
The declaration is binding in Law and applies to all future orders and deliveries without special reference having to be made to us each
time.
_______________________ _____________________________________________
Place/Date Supplier‘s legally binding signature