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May 1, 2017
John Tomczyk
Hydrofluorocarbon (HFC) R-404A has been used for many years as a long-term
refrigerant replacement blend for chlorofluorocarbon (CFC) R-502. R-502 was a binary,
azeotropic refrigerant blend of hydrochlorofluorocarbon (HCFC) R-22 and CFC-115 with
an ASHRAE safety classification of A1.
Because R-502 was a 500-series blend, it had negligible temperature glide and
fractionation potential. R-502 was a popular medium- and low-temperature refrigerant
because it could operate in positive pressures at very low evaporator temperatures. Even
in applications with evaporator temperatures of minus 40°F, R-502 could operate out of
a vacuum on the low side of the system.
Low compression ratios were also seen in systems using R-502, giving it much better
volumetric efficiencies and improved capacities than its competitor R-12 in those days.
R-502 was first manufactured in 1961; however, in 1996, there was a production ban on
R-502 and all other CFC refrigerants because of the environmental concerns of ozone
depletion and global warming.
R-404A systems use a polyolester lubricant. R-404A is being used by OEMs in new
equipment and also on retrofitted equipment. However, because of its high global-
warming potential (GWP), the U.S. Environmental Protection Agency (EPA), under its
Significant New Alternatives Policy (SNAP) program, has listed R-404A as an
“unacceptable” refrigerant in a number of retail food refrigeration categories and in the
vending machines end-uses listed here:
Although R-404A consists of a mixture of three HFC refrigerants and has an ozone
depletion potential (ODP) of zero, it does have a GWP of 3,922, according to the
Intergovernmental Panel on Climate Change (IPCC) Fourth Assessment Report, 2007. A
GWP of 3,922 means R-404A traps 3,922 times as much heat per kilogram as carbon
dioxide does over a 100-year period of time.
HFC refrigerants are rapidly accumulating in the atmosphere, and as they accumulate,
they change the balance between the energy entering the earth’s climate from the sun
and the energy escaping the earth back into space. HFC-134a, which makes up a small
part (4 percent) of the blend R-404A, has had an atmospheric concentration increase of
about 10 percent per year from 2006 to 2012. Also, the concentrations of HFC-143a and
HFC-125, which are components of R-404A and many other commonly used refrigerant
blends presently in use today in HVACR equipment, had annual atmospheric
concentration rises of 13-16 percent, respectively, from 2007 to 2011. Even though HFCs
represent a small fraction of the current greenhouse gas emissions by weight, their
warming impact per kilogram is very strong.
The majority of HFC use in the U.S. and globally is in the refrigeration and air
conditioning sector, and their emissions are projected to increase substantially and at an
increasing rate over the next several decades if their production is left uncontrolled.
Globally, HFC emissions are increasing 10-15 percent annually. In fact, emissions are
projected to double by 2020 and triple by 2030. Without action, annual global emissions
of HFCs are projected to rise from 6,400 to 9,900 million metric tons of carbon dioxide
equivalent (MMTCO2eq) in 2050.
Testing has shown that R-449B (R-404A replacement and retrofit) can offer up to an 11
percent efficiency increase over R-404A while cutting the GWP by two-thirds.
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All You Need to Know About HVAC Capillary John Tomczyk is HVACR professor emeritus, Ferris
Tubes, Part 2 State University, Big Rapids, Michigan, and
coauthor of Refrigeration & Air Conditioning
All You Need To Know About HVAC Capillary Technology, published by Cengage Learning.
Tubes, Part 1 Contact him at tomczykjohn@gmail.com.