Chemistry

FSC. Part-2 (Subjective) 40

Short Questions /24
1. Why size of cation is smaller than its parent atom?
2. Why the second value of electron affinity is usually show with positive sign?
3. Why metallic character increase from top to bottom in group?
4. Why alkali metals give ionic hydrides?
5. What are problems faced in diaphragm cell?
6. What is role of KO2 in the breathing equipments?
7. Differentiate between milk of magnesia and milk of lime?
8. Why lime water turns milky with CO2 but becomes clear with excess CO2?
9. Why there is no free rotation round a double bond and free rotation around single bond?
10. 2- Butene shows cis-trans isomerism but 1-Butene does not. Why?
11. Differentiate between homocyclic and heterocyclic compounds?
12. What is functional group? Name typical functional group containing oxygen?
13. Write down the objections of Kekule’s formula?
14. How will you prepare following compounds from benzene in two steps:
(a) m-chloronitrobenzene
(b) p-chloronitrobenzene
15. How benzene converted into oxalic acids?
Long Questions /16
Q3: (a) How do you justify the position of hydrogen at top of various groups?
(b) What is geometric isomerism? Explain it and give examples?
Q4: (a) Write note on commercial preparation of sodium hydroxide by diaphragm cell? Problems and its solution?
(b) Describe Friedel Crafts reactions of benzene along with mechanism?
Q5: (a) Write a note on cracking of petroleum. Also give its significance?
(b) Modern concepts about structure of benzene (atomic orbital theory)?
 (Objective) /10
Multiple choice questions. Encircle the correct answer.
ⅰ) Mark the correct statement.
a) All lanthanides are present in the same group.
b) All halogens are present in the same period.
c) All the alkali metals are present in the same group.
d) All the noble gases are present in the same period.
ⅱ) Down’s cell is used to prepare:
a) Sodium Carbonate b) Sodium bicarbonate c) Sodium metal d) Sodium hydroxide
ⅲ) Which one of following is not alkali metal?
a) Francium b) Caesium c) Rubidium d) Radium
ⅳ) Mark the correct statement:
a) Metallic character increases down the group
b) Metallic character increases from left to right along a period
c) Metallic character remains the same from left to right along a period
d) Metallic character remains the same down the group
ⅴ) Linear shape is associated with which set of hybrid orbitals
a) sp b) sp2 c) sp3 d) dsp2
ⅵ) A double bond consist of:
a) two sigma bonds b) one sigma and one pi bond
c) one sigma and two pi bonds d) two pi bonds
ⅶ) The chemist who synthesized urea from ammonium cayanate was:
a) Berzelius b) Kekule c) Wholer d) Lavoisier
ⅷ) Benzene cannot undergo
a) Substitution reactions b) addition reactions
c) oxidation reactions d) elimination reactions
ⅸ) The benzene molecule contains
a) Three double bonds b) Two double bonds c) One double bond d) Delocalized π-electron charge
ⅹ) Chile saltpetre has the chemical formula:
a) NaNO3 b) KNO2 c) Na2B4O7