Professional Documents
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1007/s10717-018-0071-0
Glass and Ceramics, Vol. 75, Nos. 7 – 8, November, 2018 (Russian Original, Nos. 7 – 8, July – August, 2018)
UDC 691.175.3:67.02
B. B. Bobovich1
The properties of reinforced polymer composite materials based on different types of polymer binders and
glass fiber fillers were studied. The recipe and production technology were developed for articles made from
fiberglass. This technology is based on a spraying assembly from the Glas Craft Company, combined with a
chopper — a high-output cutting machine from the Greco Company. It is shown that the spray technology for
producing from fiberglass, based on polyester resins and glass roving, large-size modules of water slides and
other attractions for pools and water parks is technically sound and economically efficient.
Key words: fiberglass, articles for water attractions, production technology, coating, design.
Reinforced polymer composite materials (RPCM) such ing account of the topography of the site for an open water
as fiberglass are widely used in the building of aircraft, auto- park or architectural designs of an enclosed pool.
mobiles, ships, and aerospace engineering structures. This is The RPCM fabrication technology makes it possible to
associated with the high mechanical properties of these ma- design not only components but also the material itself — its
terials, which surpass in terms of the specific indices the properties and structure [6]. A fiberglass article is formed si-
properties of other materials, including metal alloys. It multaneously with material itself, since the material is fabri-
should also be noted that many RPCM possess excellent re- cated from several components that enter into interaction at
sistance to corrosive media, including water [1 – 4]. the moment the article is formed. In other words, the material
Expensive forming tools are not required to make articles does not exist before the article is formed.
from such materials — articles are produced using compara- During the transformation of the liquid composition into
tively inexpensive matrices. Such materials are of special in- a structural material, the composition solidifies owing to the
terest in different fields for making large-size articles in stretching of the oligomer resin molecules and their conver-
small series: automobile tuning, new hardware development sion into polymers and formation of cross-links between the
in machine engineering, transport equipment fabrication, and polymer macromolecules. The correct choice of the compo-
in construction and other fields.
275
0361-7610/18/0708-0275 © 2018 Springer Science+Business Media, LLC
276 B. B. Bobovich
TABLE 1. Effect of Polymer Binder on the Properties of Glass- The polymerization of resins is an exothermic process.
Filled Composites As a result the material is significantly heated up, which in
Resin the case of an incorrectly built forming technology can result
Index in significant internal stresses in the article and cracking of
phenol-formal-
polyester epoxy the article during operation. The heating temperature of the
dehyde
material during polymerization and the gel-formation time of
Strength, MPa:
the polyester resin were regulated by varying the content of
in tension 65 70 58
the hardening catalyst in the composition.
in bending 140 140 65
Pre-accelerated resins with low styrene emission were
Density, g/cm3 1.58 1.62 1.64
used to fabricate the fiberglass modules of water slides; this
Linear shrinkage, % 0.35 0.25 0.21 made it possible to reduce the emission of styrene in the
Specific impact tough- work zone and improve labor conditions.
ness, kJ/m2 52 48 24
s, MPa
significant shrinkage phenomena, distortion of the channel,
and even cracking of the surface of the matrix.
The deposited layers were carefully compacted with roll-
sb ers in order to eliminate the porosity of the material and other
defects.
The deposition (on the matrix) and hardening of the glass
st
filled oligomer composition were conducted in layers at tem-
a, kJ/m2 perature 18 – 22°C. A thickness gauge was used to check the
thickness of each layer and a TM-8810 thickness gauge with
a microprocessor was used to make the final check of the
thickness of the ready article after the resin hardened.
In a regime with steady deposition of the composition on
the matrix and experienced operators servicing the spring ap-
Fiber content, wt.% paratus the thickness of the material is a derivative of the
spraying time.
Fig. 2. Effect of the glass fiber content on the impact toughness a After the resin has hardened a colored polymer coating
and the rupture strength in tension st and in bending sb of fiberglass. (top-coat) with a prescribed color was deposited on the outer
(non-working) surface of the module. This coating protected
vity, and organize small series production of articles made the main material of the module from external disturbances.
from fiberglass composites. The gel-coat and top-coat were deposited by spraying, which
The glass fiber content has a decisive effect on the prop- increases the quality of the coatings. Industry produces
erties of fiberglass. Figure 2 shows the change in the charac- gel-coats and top-coats with different colors and uses: for
teristics of material as a function of its content of glass fiber. manual deposition with a brush (hand) and spraying.
In the fabrication of water-slide modules the glass fiber con- The fiberglass module was removed from the matrix and
tent was equal to 40% by weight of the composite, since at processed after the top-coat hardened.
higher contents the increase created process difficulties. Articles were removed from the matrix with the aid of
Chopping glass braids into segments of prescribed length compressed air, which was delivered into the gap between
(50 mm) and dosing and mixing of the components in a pre- the article and the matrix. Screw pushers were provided in
scribed ratio were conducted automatically using the 3WPG the matrices in order to remove large and complex articles.
setup (Glas Craft company) [15] in combination with a chop- The final processing of the fiberglass modules for water
per — a high-output cutting machine (Graco Company) [16]. slides consisted in edging them along the perimeter, remov-
The operation of the assembly is based on the principle ing from the module the dust accumulated during edging,
of external mixing of catalyst with resin. At the exit from the and adding a colored top-coat on the end surfaces after edg-
sprayer the mixed components pass into an air tunnel, where ing. A pneumatic tool with a diamond edging wheel was used
aerosol spraying of the components occurs. Comminuted to edge the fiberglass modules.
glass roving, whose length can be regulated from 10 to During assembly of the water-slide the modules were
70 mm, was automatically introduced under air pressure into connected into a single structure, which was placed on a spe-
the mixture of resin with catalyst. The setup was operated cially prepared metal support structure. They were designed
from a compressor with working pressure 0.6 – 0.8 MPa and taking account of the extant static and dynamic loads as well
air flow rate 600 – 800 L/min. as the topography of the location for open water parks or ar-
An important feature of this assembly is that the mixing chitectural designs for enclosed areas.
of the oligomer (resin) with the hardening catalyst and glass The fiberglass modules were connected with one another
fiber in the air flow occurs outside the spray gun, which along their flanges with self-gluing liners made of a neo-
makes it possible to spray continuously without worrying prene-based porous rubber, which sealed the channel of the
about the oligomer transforming into polymer inside the pro- water slide.
cess equipment. In the fabrication of articles by spraying
onto molds with vertical walls the rheological properties of CONCLUSIONS
the resin, specifically, the presence of thixotropy in it, are
very important. The properties of reinforced polymer composite materi-
We formed channels with prescribed wall thickness als based on different types of polymer binders and glass fi-
(8.0 ± 0.5 mm for the water-slide modules) by depositing the ber fillers were studied. A recipe and technology for produc-
composition in layers with temperature control of the lami- ing fiberglass modules for water slides, based on the use of
nate and cooling of each layer prior to deposition of the next high-precision dosing sprayers (Glas Craft Company) in
layer. This eliminated overheating of the material owing to combination with a high-output cutting machine (Graco
the high exothermicity of the process, which can result in Company), were developed.
278 B. B. Bobovich
This technology makes it possible to mechanize the pro- 7. K. E. Perepelkin, Reinforcing Fibers and Fibrous Polymer
cess, increase labor productivity, and organize small serial Composites [in Russian], Scientific foundations and technolo-
production of water slides from fiberglass. The design and gies, St. Petersburg (2009).
fabrication were developed for the forming equipment, mak- 8. A. O. Kurnosov, M. I. Vavilova, and D. A. Mel’nikov, “Techno-
ing it possible to fabricate standard and special modules with logies for the production of glass fillers and study of the effect
a constant cross section of the channel of the water slide. The of the sizing agent on the physico-mechanical characteristics of
use of software made it possible to design from these mod- fiberglass,” Aviats. Mater. Tekhnol., No. 1, 64 – 70 (2018).
9. A. S. Borodulin, “Properties of glass fibers, mats and fabrics
ules slides of any length, height, and geometry.
used for the production of fiberglass,” Vse Materialy, Éntsikl.
Our investigations have shown the technical soundness
Sprav., No. 1, 50 – 56 (2013).
and economic expediency of using a spray technology for
10. M. I. Vavilova and N. S. Kavun, “Properties and features of re-
producing from fiberglass based on glass roving and polyes- inforcing glass fillers used for the manufacture of building fi-
ter resins large size modules for water slides and other attrac- berglass,” Aviats. Mater. Tekhnol., No. 3, 33 – 37 (2014).
tions for pools and water parks. 11. A. Yu. Alent’ev and M. Yu. Yablokova, Binders for Polymeric
Composite Materials [in Russian], Izd-vo MGU, Moscow
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