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Characteristics of Air-blown Gasification for Woods in a Fixed-bed Downdraft Gasifier 163

Characteristics of Air-blown Gasification for Woods


in a Fixed-bed Downdraft Gasifier
Chih-Lun Hsi, Tzong-Yuan Wang, Chiu-Hao Liu, and Jing-T Kuo*
* Department of Mechanical Engineering, National Taiwan University, Taipei, Taiwan 10617
(E-mail: jtkme@ntu.edu.tw)

Abstract: An experimental investigation of a fixed-bed, downdraft air-blown gasifier has been carried out using wooden cubes 15
mm3 made of Lauan wood. The reactor is a cylinder with an internal diameter of 200 mm and a height of 1000 mm. The effect of
airflow rate, air preheating temperature, and moisture content of wood cubes on producer gas composition and heating value were
presented. The conversion rate of wooden cubes increases linearly with the cold airflow rate within the range from 6 to 18 Nm3g h-1.
The producer gas heating value and efficiency of gasifier increase with increasing rate of cold air up to 15 Nm3 gh-1 then drop down
due to the dilution effect of cold air. Preheated air temperature up to 573 K was found to have marginal effect on producer gas
heating value. Moisture content of wood can significantly lower the wood cubes conversion rate and producer gas heating value. The
optimum mean higher heating value of producer gas obtained in this work, using woods with 18% of moisture content and cold air, is
~ 5.2 MJgNm-3. A one-dimensional steady model was developed for biomass gasification to predict the axial profiles of temperature
and gas composition in a downdraft reactor. Agreement between experimental and predicted producer gas heating value is acceptable.

Keywords: Gasifier, Gasification, Producer gas


the calorific value of the producer gas were observed to
increase with the increasing equivalence ratio up to some peak
1 INTRODUCTION value and then start decreasing. Dogru et al. [10] carried out
Biomass has been widely recognized to be a major source gasification of hazelnut shells in a 5 kWe downdraft gasifier
of renewable energy. Gasification is a process for converting ranging from 1.7 to 5.5 kggh-1. Optimum operation was
biomass to combustible gas composed of H2, CO, and CH4. achieved between 1.44-1.47 Nm3gkg-1 of air/fuel ratio and
There are some excellent reviews of biomass gasification produced gas with a calorimetric value of ~5 MJgm-3.
technologies [1, 2]. The producer gas composition is In this work, experimental investigation of a
influenced by factors such as properties of feedstock, laboratory-scale air-blown downdraft wood gasifier has been
manipulation of the air, reaction temperature, etc. Downdraft performed to study the effects of air manipulation such as the
gasification is a simple and reliable technology that can flow rate and the preheating temperature of the air streams, as
generate a producer gas with very low tar content. Therefore, well as the moisture content of fuels, on performance of the
the downdraft gasifier is generally favored for coupling to a wood gasifier. A one-dimensional steady model was developed
small-scale electricity generation with a heat engine [2]. for biomass gasification to predict the axial profiles of
The characteristics of fixed-bed downdraft biomass temperature and gas composition in a downdraft reactor.
gasifiers have been investigated theoretically [3-6] and
experimentally [7-10]. Walawender et al. [7] carried out
2 EXPERIMENTAL
experiments using a commercialized downdraft gasifier, which
The wood gasification system is represented as Fig.1 and
has a diameter of 0.6 m and is completely open at the top. The
Fig.2. It mainly consists of a reactor, a fuel feeding system, an
gasifier was operated by feeding mixed hardwood chips of 14
air blower connected with an electric heater, an igniter, a
mm with 6 to 17% moisture content and 43.1-202.1 kggh-1 of producer-gas-cooling heat exchanger, a condensate water
dry air. The chip feed rate ranging from 27-126 kggh-1 with a collector, and an ash collector. The reactor is a cylinder with
reported producer gas mean heating value of 5.51 MJgm-3. A an internal diameter of 200 mm and a height of 1000 mm. The
small-scale stratified downdraft gasifier (100 mm i.d. and 500 thickness of the wall is 140 mm consisting of refractory
mm height) was operated under steady conditions by Barrio et cement (50 mm), steel cylinder (10 mm), rock wool (30 mm),
al. [8]. Wood pellets (6 mm diameter and 6-15 mm of length) steel cylinder (10 mm), and blanketed on the outside with
with 7.5% moisture content were used to produce the gas with fabric of fiberglass (40 mm). A total of ten K-type
a LHV of 5.3~5.7 MJgNm-3. An experimental study of a thermocouple temperatures sensors were installed at various
downdraft gasifier was carried out by Zainal et al. [9] to locations above the grate. Thermocouple CH01 is located at
investigate the effect of equivalence ratio on the gas the height of 930 mm above the grate. The other nine
composition calorific value and the gas production rate. It was thermocouples are spaced 100 mm apart and the lowest one
found that the percentage of H2 increases linearly with the (CH10) is located at a distance of 30 mm above the grate.
equivalence ratio. The percentages of CO and CH4, as well as
164 International Conference on Power Engineering-2007, October 23-27, 2007, Hangzhou, China

Nine runs of gasification tests have been performed in this


work. Experiments no. 1 to no. 5 were executed with the same
moisture content of 18% of wood cubes under the same
temperature of the air streams. Experiments no. 6 and 7 were
carried out with the air preheated to 473 and 573K,
respectively. The fuels used in No. 8 were oven dried at 378K
for 96 hours. Those used in No. 9 were oven dried in the same
procedure as No. 8 at first, bathed in water for seven days and
then dried by natural convection to the moisture content of ~
33% (wet basis). Before tests, woods were preserved in plastic
bags to control the moisture content.
Wooden cubes were fed into the reactor by a screw feeder
from the top of the gasifier. Air was separated to six streams
and introduced to the reactor at the height of 530 mm above
the grate. The wood bed was ignited by an igniter located at a
distance of 130 mm above the grate. The bed level was
controlled above the height of the air inlet and kept constant
Fig.1 Gasification system: (1) silo; (2) screw feeder; (3) safety
by a photoelectric sensor. Gas samples were taken at the
valve; (4) reactor; (5) air distributor; (6) air blower; (7)
positions at the same heights but different meridian angles to
igniter; (8) heat exchanger; (9) condensate water
those of the thermocouples, as well as at the exit of the reactor.
collector; (10) ash collector
Gas was sampled by using sampling bottles and suction pump,
tar content and the particulates were filtered by glass wool.
Gas composition on a dry basis was analyzed by gas
chromatography.

3 MODELING

3.1 Chemical reactions and the kinetics


The reactions involving in a downdraft gasifier include
drying, pyrolysis, flaming combustion of volatile material,
heterogeneous char combustion and char gasification. Since
the feeding air is under the stoichiometric air demand, oxygen
is consumed rapidly in the flaming pyrolysis region and
reduced to ~ 1%. Glowing combustion may occur if there was
unburned oxygen penetrates to the char surface. Based on the
Fig.2 Photograph of downdraft gasifier consideration that the burning rate of solid fuel bed is related
to the consumption rate of oxygen as the air is flowing through
Wooden cubes made of Lauan of 15mm×15mm×15mm the fuel bed, Kuo [11] developed a model to estimate the
were used as fuel of the air-blown gasifier in the present work. burning rate of refuse bed in a combustion furnace. The gross
The ultimate analysis on a dry basis is: C, 45.85%; H, 5.98%; reaction of solid fuel in the pyrolysis and flaming combustion
O, 48.05; and N, 0.12%. The average of wood density with region can be described as:
18% moisture content (wet basis) is 790 kg g m-3. Test CaHbOcgf(H2O)+ r̂ ofO2 o
conditions and some characteristics of the gasifier (1)
a (1  rCO )CO 2  arCO CO  ( f  b / 2)H 2 O
performance are listed in Table 1.
Table 1 Test conditions and characteristics of the gasifier where r̂of is the oxygen-to-fuel mole ratio, rco is fraction of
carbon converted to carbon monoxide.
Oxygen distribution in the fuel bed can be represented as:

dX O2
 KX on2 (1  ar X O2 ) (2)
dy

where K ( Rd / ar ) ln(1  ar X O2 ) ; Rd is the coefficient of reaction,


which is likely to be on the order of 10; n is the order of
reaction, and ar is the ratio of change in gaseous moles to the
Characteristics of Air-blown Gasification for Woods in a Fixed-bed Downdraft Gasifier 165

change in oxygen moles. The corresponding fuel combustion


rate is: 3.2 Conservation equations
In this study, conservation of mass and energy for solid and
1 dX Mˆ (3)
rFP  U g u g O2 R gas phases based on a macro-scale, described in one
rˆof dy Mˆ a dimensional form and along the axial direction of the reactor,
was used for modeling the steady state processes of the
The flaming pyrolysis region is followed by a gasification
downdraft gasifier.
region, in which the char is converted to the producer gas
Continuity equations of solid phase, gas phase, and the
mainly by the following endothermic reactions [12]:
gaseous species are given as:
C  CO 2 o 2CO 'hG ,CO2 14372kJ/kg (4)
d( U s us ) (14)
(rFP  rG ,CO2  rG ,H2O  rG ,H2 )
dy
C  H 2 O o CO  H 2 'hG ,H2O 14609kJ / kg (5)
d( U g u g ) (15)
rFP  rG ,CO2  rG ,H 2O  rG ,H2
Reaction rates of Eqs. (4) and (5) are taken from ref. [12]: dy
rG ,CO 2 = UCO2 a p ( Mˆ C / Mˆ CO ) hD kG ,CO /( hD  kG ,CO ) d( U g ,i u g ,iYg ,i ) (16)
¦b
2 2 2
r
i, j j
(6) dy j

rG ,H2O U H O a p ( Mˆ C / Mˆ H
2 2O
) hD kG ,H
2O
/( hD  kG ,H
2O
) where Y is the mass fraction of gas species i; bi,j is the yield of
species i from reaction j; i = CO, CO2, CH4, H2O, O2.
(7)
Energy balances of solid and gas phases within the fuel bed
where a 6(1  H ) / d is the fuel bed solid surface area per unit are formulated as:
p p

volume, the parameter H is the void fraction of fuel bed; d( U s u s hs ) (17)


dy
¦ r 'h j j  hsg a p (Ts  Tg )  4 hws (Ts  Tw ) / D
hD 0.8Dg (2.0  1.1Re Sc ) / d p is the mass transfer coefficient;
0.6 1/ 3 j

M̂ is molecular weight; the reaction rate constant of Eqs. (6) d( U g u g hg ) (18)


and (7) described in Arrhenius form is dy
¦ r 'h j
j j  hsg a p (Ts  Tg )  4hwg (Tg  Tw ) / D

kG ,CO 3.42TS exp(1.56 u104 / TS ) and kG ,H2O 1.67kG ,CO2 , where hsg
2
2.06(1/ H )C pg U g u g Re 0.575 Sc 2 / 3 is the heat transfer
respectively. coefficient between solid and gas phases [14] ; the wall heat
An exothermic reaction of char with hydrogen producing transfer coefficients hws and hwg are also taken from ref. [14].
methane is considered in this model,

C  2H 2 o CH 4 'hG ,H2 74.93kJ / mol (8) 4 RESULTS AND DISCUSSION


The reaction rate of Eq. (8) is
4.1 General characteristics of the fuel bed gasification
rG ,H 2 a p CH 2 hD kG ,H2 /(hD  kG ,H2 ) (9) Nine runs experiments have been carried out in this work,
the operational parameters and the corresponding characteristics
where CH is the hydrogen molar concentration; hD is the mass of the gasifier are listed in Table 1. Fig.3 shows the
2
temperature record of the exp. No. 3. Fuel bed was ignited by
transfer coefficient, hD 2.06(1/ H )ug Re0.575 Sc 2/ 3 ;
an igniter located at a distance of 130 mm above the grate (CH
and kG ,H 104 exp(26095 / TS ) [13]. 09), thus the temperature at CH10 rose to the peak values after
2

The water gas shift reaction is included in this work and ~ 20 minutes. It is evident that the flame front propagated
was considered to be reversible as [13]: upwards from the bottom of the fuel bed (CH10) to the
location of the air inlet (CH 06). Fig.3 also indicates that it
CO  H2O U CO2  H2 'hWGS 41.2kJ / mol (10) took~120 minutes for the whole packed fuel bed to achieve
the steady condition.
The kinetic rate of water gas shift reaction rWGS is taken
from [13]: 4.2 Effect of airflow rate
Table 1 indicates that fuel conversion rate increases with
rWGS H kWGS (CCOCH O  CCO CH / K E ) (11)
2 2 2 increasing rate of airflow. Fig.4 confirms the proportionality
between the fuel conversion rate and airflow rate. However,
kWGS 2.78exp(1513 / Tg ) (12) the heating value of producer gas and the cold gas efficiency
increase with the increasing rate of cold air up to 15 Nm3 gh-1
KE 0.0265 exp(3966 / Tg ) (13) then drop down, as shown in Table 1. The axial temperature
profiles of exp. no.1 to No. 5 are demonstrated in Fig. 5. Fig.5
166 International Conference on Power Engineering-2007, October 23-27, 2007, Hangzhou, China

shows that temperature of the gasification zone of exp. No.5 is


lower that those of No. 2 to No. 4, owing to the dilution effect 4.3 Effect of air preheating temperature
resulting from the larger amount of cold air. As a result, the In order to investigate the effect of air preheating
rates of gasification reactions were decelerated. Flame temperature on the performance of wood gasifier, exp. No. 6
spreading speed increased with the airflow rate up to 15 and No. 7 were conducted with preheated air of 473 and 573K,
Nm3 g h-1 then decreased dramatically. This finding is respectively. Table 1 reveals the fact that, as compared with
consistent with the result of Saastamoinen et al. [15]. the result of exp. No. 3, preheating the air to 473 and 573 K
can accelerate the flame spreading velocity significantly.
Experimental observations showed that the time to reach the
steady condition of a gasifier operated with preheating air at
473 and 573 K is ~ 100 and 90 minutes, respectively, which
was shorter than the time required to steady situation of exp.
No. 3 (120 min, as shown in Fig. 3). The higher temperature
of air can accelerate both the preheating of the reactor and the
moisture evaporation of the woods in the start-up period.
On the other hand, as to exp. No. 7, even the air was
preheated up to 573 K, it seems to have marginal effect on the
heating value of producer gas and cold gas efficiency, as given
in Table 1. Although the mean HHV of producer gas increases
from 4.91 to 4.96 MJgNm-3 when the air was preheated from
Fig.3 Temperature histories at various locations inside the room temperature to 573 K, the cold gas efficiency slightly
the fuel bed of exp. No. 3 decreases from 71% to 68%. The elevation of sensible heat of
gas by preheating the air streams seems to have a relatively
marginal effect on heating value of the producer gas as
compared with the airflow rate. Jayah et al. [6] simulated a
wood downdraft gasifier and found that the conversion
efficiency slightly increases from 56.0% to 57% when the
inlet air temperature increases from 300 K to 600 K.

4.4 Effect of moisture content of woods


Moisture content of feedstock can affect the temperature in
the fuel bed and consequently influences the heating value of
the producer gas of a gasifier. The wooden cubes used in exp.
No. 8 were oven dried at 378 K for four days to eliminate the
moisture. The conversion rate of oven-dried woods is
significantly higher than those of the other experiments (Table
1). It was also found that the time to reach the steady condition
of gasifier supplied with dry woods is ~ 50 minutes. Welker
Fig.4 Fuel conversion rate as a function of airflow rate [16] reported that the cellulosic materials almost completely
decompose to carbon-hydrogen rich gases at a very high
heating rate. The higher heat-up rate accelerates the thermal
decomposition of an oven-dried wooden particle, consequently
more combustible gas is released. On the contrary, results of
exp. No. 9 indicates that the gasifier performance such as the
conversion rate of woods, the flame spreading rate, and the
heating value of producer gas, were significantly interfered by
the relatively higher moisture content of woods, owing to the
much more energy consumed in moisture evaporation.

4.5 Modeling results


Fig.6 and 7 illustrate the measured and calculated profiles
of producer gas compositions and temperatures of exp. no. 3
under steady state condition. The order of reaction in Eq. (2)
was chosen as n = 0 to fit the oxygen depletion speed. A
Fig.5 Temperature profiles of fuel bed of exp. No. 1 to 5
constant value 0.8 for rco was assumed to achieve the best
Characteristics of Air-blown Gasification for Woods in a Fixed-bed Downdraft Gasifier 167

agreement between predicted and experimental CCO and CCO2. constants of kinetics and the grate heat loss estimation.
Fig.6 indicates that oxygen was rapidly depleted within a thin Nevertheless, the trend of calculated temperature is
flaming combustion region nearing the height of fair inlet. The qualitatively acceptable, and the calculated producer gas HHV
carbon monoxide and carbon dioxide concentrations increased at the outlet of grate is 5145 kJgNm-3, which is close to the
mainly due to the pyrolysis and flaming combustion reactions measured HHV of 4911 kJgNm-3.
in this thin flaming combustion region. In the gasification
region, hydrogen continuously increased form both the 5 CONCLUSION
Char-H2O gasification and water gas shift reactions, whereas
CO slightly decreased owing to the forward water gas shift An experimental investigation of a small-scale fixed-bed
reaction. downdraft gasifier was performed in the present work. It was
observed that the gross conversion rate of woods increases
linearly with the increasing rate of air supply. The variations
of the heating value of producer gas and the cold gas
efficiency with air flow rate shows that the optimum rate of
cold air stream is ~ 15 Nm3 gh-1 for the best performance of
the downdraft gasifier built in this study. The optimum mean
HHV of producer gas obtained in this work, using woods with
18% of moisture content and cold air feeding, was ~ 5.2 MJ
Nm-3, which is comparable to the results of Walawender et al.
[7] and Barrio et al. [8]. It was observed that the flame
spreading speed significantly rose when the air was preheated
to 573 K. However, the preheating of air streams seems to
have marginal effect on quality of the produce gas. The
heating value of producer gas decreased with the increasing
Fig. 6 Measured and predicted profiles of producer gas moisture content of woods. A one-dimensional, steady state
compositions of exp. No. 3 model has been developed for calculating the axial profiles of
temperature and gas compositions of downdraft gasifier. The
model is adequate for predicting the producer gas heating
value.

ACKNOWLEDGMENTS
This work was supported by National Science Council of
ROC (NSC 94-2218-E-002-070) and Dai-East Incinerators
Inc., Taiwan.

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