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Write answers in the provided space. MM : 720 (+4R, -1W)
1. Which of the following represents the correct 6. A force of –F k̂ acts on O, the origin of coordinate
dimension of the cofficient of viscosity ? system torque about the point (1, –1) is
(1) ML–1T–2 (2) MLT–1 (1) F(iˆ – ˆj) (2) –F (iˆ ˆj)
(3) ML–1T–1 (4) ML–2T–2
(3) F ( î ĵ) (4) –F(iˆ – ˆj)
2. A particle moves along a circle of radius 20 cm
with a constant tangential acceleration 5 cm/s2. 7. Reading shown in two spring balances, S1 and S2
How much time is needed after motion begins for is 60 kg and 30 kg respectively and lift is
the normal acceleration of the particle to be equal accelerating upward with acceleration 10 m/s2.
to tangential acceleration ? The mass is stationary with respect to lift. Then
(1) 1 sec (2) 2sec the mass of the block will be
(3) 3 sec (4) 4 sec 10 m/s2
3. A thin wire of length 2 and mass is bent in the
form of a semicircle. Its moment of inertia about S1
the line joining the free ends would be :-
(1) 2 (2) 4 (3) 6 (4) None
4. Two solids A and B float in water. It is observed m
that A floats with half its volume immersed and
S2
B floats with 2/3 of its volume immersed.
Compare the densities of A and B:
(1) 4 : 3 (2) 2 : 3 (1) 45 kg (2) 30 kg
(3) 3 : 4 (4) 1 : 3 (3) 60 kg (4) 15 kg
5. A thermodynamic process is shown in the 8. A wheel initially at rest, is rotated with a uniform
following figure. The pressure and volumes angular acceleration. The wheel rotates through
corresponding to some points in the figure are : an angle 1 in first one second and through an
PA = 3 × 104 Pa, VA = 2 × 10–3 m3 additional angle 2 in the next two second. The
PB = 8 × 104 Pa, VD = 5 × 10–3 m3 2
ratio is
1
B C
(1) 4 (2) 2 (3) 8 (4) 3
R 21C 2 R 22C1
(3) R C (4) R C
1 2 1 1 1 2
31. Two buses A and B are at positions 50 m and 35. String A has a length L, radius of cross-section r,
100 m from the origin at time t = 0. They start density of material and is under tension T. String
moving in the same direction simultaneously with B has all these quantities double those of string A.
uniform velocity of 10 m/sec and 5 m/sec. if A and B are the corresponding fundamental
Determine the position from origin at which A frequencies of the vibrating string, then :-
over takes B.
(1) A = 2B
(1) 110m (2) 150 m
(3) 100m (4) 200m (2) A = 4B
46. Arrange these compounds in decreasing order of 52. An organic compound C4H6 on ozonolysis gives
basicity :- formaldehyde and glyoxal. The compound is :-
(a) C6H5–NH2 (b) o-NO2–C6H4–NH2 (1) CH3–CC–CH3
(c) m-NO2–C6H4–NH2 (d) p-NO2–C6H4–NH2
(2) CH2=CH–CH=CH2
(1) a > b > c > d (2) b > a > c > d
(3) Cyclobutene
(3) a > c > d > b (4) a > c > b > d
47. The reagent which is used to distinguish between (4) 2-Methylcyclopropene
propene and propyne is ? 53. Which of the following weak acids will make a
(1) Bromine (2) Alkaline KMnO4 salt with NaOH, that undergoes maximum
(3) Ammoniacal AgNO3 (4) Ozone hydrolysis under similar conditions ?
48. Which of the following on mixing can form a (1) HCN (Ka = 10–6M)
buffer solution ? (2) CH3COOH (Ka=10–5M)
(1) 0.2 mol HCN + 0.1 mol HCl (3) HCOOH (Ka = 10–4M)
(2) 0.5 mol NaCN + 0.2 mol HNO3 (4) HNO2 (Ka = 10–3M)
(3) 0.2 mol KOH + 0.1 mol HCl
54. The kinetic and potential energy (in eV) of
(4) 0.4 mol HCN + 0.2 mol NaCl
electron present in third Bohr's orbit of hydrogen
49. What is mass of N2F4 produced by the reaction
atom are respectively :-
of 2.0 g of NH3 and 8.0 g of F2
(1) –1.51, –3.02 (2) 1.51, –3.02
2NH3 + 5F2 N2F4 + 6HF
(3) –3.02, 1.51 (4) 1.51, –1.51
(1) 6.11 g (2) 4.33 g
55. Which of the following oxides has a three
(3) 7.92 g (4) 10 g
dimensional structure ?
50. Which of the following do not contains dangling
(1) CO (2) CO2 (3) SiO2 (4) SO2
bonds–
56. Arrange these three compounds in decreasing
(1) Diamond (2) Fullerene order of C–Cl bond length.
(3) Graphite (4) All of these (A) CH3–CH2–Cl (B) CH2=CH–Cl
(C) HCC–Cl
51. Which of the following carbanion is most stable?
(1) A > B > C (2) C > B > A
–
CH2 (3) B > C > A (4) A > C > B
–
CH2 57. The IUPAC name of Cl3C.CHO is :-
(1)
NO2
(2) (1) Trichloroacetaldehyde
(2) 1,1,1-Trichloroethanal
NO2
(3) 2,2,2-Trichloroethanal
– (4) Chloral
– CH2
CH2
CN
(3) (4)
CN
58. Based on the following thermochemical equations 63. Consider the following reaction,
H2O(g) + C(s) CO(g) + H2(g); H = 131 kJ 3Br2 + 6CO32– + 3H2O 5Br– + BrO3– + 6HCO3–
CO(g) + 1/2O2(g) CO2(g); H = –282 kJ Which of the following statements is true
H2(g) + 1/2O2(g) H2O(g); H = –242 kJ regarding this reaction :-
C(s) + O2(g) CO2(g); H = X kJ (1) Bromine is oxidized and the carbonate is
The value of X will be :- reduced
(1) –393 kJ (2) –655 kJ (2) Bromine is reduced and the carbonate is
(3) +393 kJ (4) +655 kJ oxidized.
59. Which of the following set of quatum numbers (3) Bromine is neither reduced nor oxidized.
is impossible for an electron ?
(4) Bromine is both reduced and oxidized.
1 64. Select pair of compound in which both have
(1) n = 1, = 0, m = 0, s = +
2 different hybridisation but have same molecular
1 geometry:-
(2) n = 9, = 7, m = –6, s = –
2 (1) BF3, BrF3 (2) ICl2, BeCl2
1 (3) BCl3, PCl3 (4) PCl3, NCl3
(3) n = 2, = 1, m = 0, s = +
2
1 65. Which of the following reaction does not take
(4) n = 3, = 2, m = –3, s = + place:-
2
(1) Na + H2O (2) Mg + H O
Cold
Hot
60. X
Y
Z (Glassy material) 2
(3) Be + H O
2
(4) Li + H O
Steam 2
H ot
Oxidisin g
Z + CoO
Flame
W. (Blue bead)
66. The most stable free radical is :-
Incorrect statements is :-
Me
(1) Aqueous solution of X is basic in nature but
acidic buffer solution (1) (2)
(2) W is Co(BO2)
(3) Z is (NaBO2 + B2O3)
(4) X can be prepared by reaction of colemanite (3) (4)
with Na2CO3
61. Which of the following is a non-aromatic
compound/species ?
67. Total number of 1º isomeric alcohols with the
+ molecular formula C4H10O is :-
(A) (B)
(1) 2 (2) 3 (3) 4 (4) 5
(1) i > iii > iv > ii (2) i > iii > ii > iv (4) Cl2CHCH2CHCl2
(3) iv > i > iii > ii (4) i > iv > iii > ii 87. Kc for A + B C + D is 10 at 25°C. If a
container contains 1,2,3,4 mol/litre of A,B,C and
82. A+B C+D D respectively at 25°C, the reaction will
If initial concentration of A and B are both equal proceed:-
but the equilibrium concentration of D is twice that (1) From left to right (2) From right to left
of A, then equilibrium constant of the reaction is :
(3) in Equilibrium (4) Either of these
4 9 1 88. A sample of PCl3 contains 1.4 moles of the
(1) (2) (3) (4) 4
9 4 9 substance. How many atoms are there in the
83. For the reaction sample ?
(1) 4 (2) 5.6
C3H8(g) + 5O2(g) 3CO2(g) + 4H2O()
(3) 8.431 × 1023 (4) 3.372 × 1024
at constant temperature H – U
89. Which of the following is methanide :
(1) –RT (2) +RT
(1) Be2C (2) Al4C3
(3) –3RT (4) 3RT
(3) Mg2C3 (4) Both (1) & (2)
84. Four diatomic species are listed below in different 90. When temporary hard water containing
sequences. Which of these presents the correct Mg(HCO3)2 is boiled, the precipitate formed is of:-
order of their increasing bond order? (1) MgCO3 (2) MgO
(1) C22– < He2+ < NO < O2– (3) Mg(OH)2 (4) None
91. Select the correct option in respect of given diagrame. 94. Which is not a lipid ?
(1) Lanoline (2) Cholesterol
(3) Glycerol (4) Cerumen
95. Flowering in pinapples is promoted by
(1) Auxins (2) Cytokinin
(3) Gibberellin (4) ABA
96. The inhibitors which react with protein side chain,
can not stop...........
(a) (b) (1) Diffusion (2) Facilitated Diffusion
(3) Active transport (4) Symport
(1) a - Penicillium b - Agaricus
(2) a - Aspergillus b - Agaricus 97. Members of which phylum are commonly known
(3) a - Rhizopus b - Mucor as sea walnut or comb jellies ?
(4) a - Aspergillus b - Penicillium (1) Coelenterata (2) Ctenophora
92. Which of the following option is correct ? (3) Platyhelminthes (4) Aschelminthes
(A) In gymnosperms the sporophyte and the 98. Mesothelium originate from :-
gametophytes do not have an independent (1) Mesoderm (2) Endoderm
free-living existence. (3) Ectoderm (4) Ectomesoderm
(B) The leaves of gymnosperms are not well- 99. Match the following columns-
adapted to with stand extremes of temperature
humidity and wind. Column-I Column-II
(C) Pollination in gymnosperms is mainly carried
Ball and Humerus and
by insects like honey bee. (A) (1)
socket joint Glenoid cavity
(D) The multicellular females gametophyte of
gymnosperm is retained with microsporangium. Between atlas
(B) Gliding joint (2)
(1) A, B, C and D = All incorrect and axis
(2) A, B, C and D = all correct
(3) A, B and C = correct (C) Pivot joint (3) Knee Joint
(4) A, D and C = correct
93. When placenta forms a ridge along the ventral (D) Hinge Joint (4) Between carpals
suture of the ovary and the ovules are borne on the
ridge forming two rows, the type of placentation A B C D
is termed as :- (1) 1 2 3 4
(1) Marginal (2) Axil
(2) 1 3 4 2
(3) Parietal (4) Free central
(3) 1 4 2 3
(4) 1 3 2 4
100. Anterior aorta in cockroach is :- 106. What is the correct sequence of following events ?
(1) Last heart chamber (a) Plasmatic growth (b) Differentiation
(2) 2nd heart chamber
(c) Senescence
(3) 1st heart chamber
(1) (a) – (b) – (c) (2) (b) – (c) – (a)
(4) 10th heart chamber
(3) (c) – (a) – (b) (4) (c) – (b) – (a)
101. How many statements are true about
Chrysophytes? 107. Following animals is ?
(1) They are found in fresh water as well as Marine
habitat
(2) They are microscopic structure and float
passively in water current
(3) This group includes diatoms and desmids
(4) They are mostly Saprophytic
Option : (1) Roundworm (2) Flatworm
(1) Two (2) Four (3) Earthworm (4) Sandworm
(3) Three (4) One 108. Match the following columns and choose the
102. Which of the following statement is correct :- correct answer from the options given below
(1) Capsule of moss and roots of club moss are (a) indigestion (i) ejection of stomach
diploid contents through
(2) Rhizoids of moss and roots of horse tails are mouth
diploid (b) constipation (ii) it reduces the
absorption of food
(3) Fronds of fern and protonema of moss are
haploid (c) diarrhoea (iii) the faeces are
retained in the
(4) Leaves and endosperm of gymnosperm are
rectum as the bowel
diploid movements
103. Which condition is not clear in the floral formula :- becomes irregular
K(5) C1 + 2 + (2) A(9) + 1 G1 (d) vomiting (iv) food is not properly
digested
(1) Number of carpels
a b c d
(2) Aestivation of calyx and corolla
1 iv i ii iii
(3) Gamosepalous and polysepalous condition 2 iv iii i ii
(4) Position of ovary 3 i ii iii iv
104. DNA is made up of :- 4 iv iii ii i
114 Collagen is :- A B C D
(1) Lipid (2) Protein
(1) 1 3 2 4
(3) Carbohydrate (4) Sterol
(2) 2 1 3 4
(3) 3 1 2 4
(4) 3 1 4 2
120. Which of the following option gives the correct
(a) (b) (c)
categorisation of functioning of channels and
pump according to the stage:- (1) Sphagnum Lycopsida Haploid
Strobilus
Node
Internode
Branch
(1) Asymmetry (2) Radial
(3) Biradial (4) Bilateral
Rhizome 127. Body divided into proboscis, collar and trunk in ?
(1) Ascidia (2) Branchiostoma
(3) Petromyzon (4) Balanoglossus