Energy Balance across Pump

Inlet Pressure=
Outlet Pressure=
∆P=
Intel Temp T₁
Outlet Temp T₂

Pump Efficiency=

Density of Diesel=
Specific Volume=

Specific Heat

H₂-H₁=
Actual Work=

T₂

Energy Balance Around Mixer2:

Components
Butyl Sulphide
Diethyl sulphide
Diethyl disulphide
Pyridine
Pyrole
Chlorooctane
Benxene
Phenol
Pentene
Thiophene
Hydrogen
Ethane
Butane
Hydrogen sulphide
Heat Exchanger Energy Balance:
For Cold Stream

∑[m(in)*Cp]=
T₁=
T₂=
T₂-T₁=

Q=

For Hot Stream

[m(hot)*Cp]=
T₃(reactor outlet)=
T₄=
Calculations:
Capacity50,000 bbl/day of diesel oil feed.

Specific Gravity 15 oC
Density (kg/m3) at 15 oC
Pour point (oC)
Boiling range (ASTM) (oC)

Parrafins
Aromatics
Olefins
Nitrogen Compounds
Halides
Total Sulfur (wt %)

Sulfur Compounds (wt %)

Properties and composition of diesel oil

Data for Diesel Oil

Specific Gravity of Diesel Oil
Density of water (ρH2O)
Density of Diesel Oil (ρOil)

Quantity of Oil (Feed rate) F1 =

Material balance around reactor

Energy Balance Around Reactor:
Material Balance around seperators:
Balance Around Coolers:
Balance Around Absorber:

Material balance around Splitter:

Energy Balance Around Mixer3:

Energy Balance Around Mixer1:
Mass Balance Around Distillation Column:

170

78
18
72
 58
84
114
17
30
34
2

Energy Balance Around Distillation Column:

 101.325
6067.39
5966.065
60 333

0.75

914
0.00109409190372

7.3837

V∆P 6.52742341356674
V∆P/Ꞃ 8.70323121808899

334.178708671545
61.1787086715453

Molar Mass Diesel Stream (kg/hr)

90 1074.6
90 1074.6
122 1074.6
79 3783.81
67 3783.81
148.5 7567.63
78 39351.7
94 39351.7
70 12108.22
84 1074.6
2 0
30 0
58 0
72 0
 Heat (in)= Q(H₂) + Q(diesel)

∆T of H₂ stream=
∑nCp=
Q(H₂)=

∆T for diesel stream=

∑nCp=
Q(dieseel)=

Heat(in)=

Flow rate of Mixed Stream=

Temp of mixed stream=

Q=∑[m(cold)*Cp]*(T₂-T₁)

414.212736670939 KJ/K
54.34 ⁰C
120 ⁰C
65.66 ⁰C

27197.2082898138 KJ

Q=∑[m(hot)*Cp]*(T₃-T₄) 27197.2082898138
361.448541003533 KJ/K
368.99 ⁰C
293.744964526062 ⁰C
 Composition

Mercaptans
Sulfides
Disulfides
Thiophenes

0.9158
997 kg/mᵌ
913.0526 kg/mᵌ

50,000 bbl/day
Component Name Molar mass
Butyl Mercaptan 90
Diethyl sulphide 90
Diethyl disulphide 122
Pyridine 79
Pyrole 67
Chlorooctane 148.5
Benxene 78
Phenol 94
Pentene 70
Thiophene 84
Hydrogen 2
Ethane 30
Butane 58
Pentane 72
Ammonia 17
Hydrsulphide 34
water 18
Octane 114
cycloHexane 84
ammonium chloride 53.5
Paraffins 170

Conditions:

Adiabatic
100% Conversion
No Shaft work

1
2
3
4
5
6
7
 8
9

Heat of Reaction at 25⁰C=

Flash Eq: yi=ziki/1+v(ki+1)
COMPONENTS
H2
H2S
NH3
H2O
C6H12
C2
C4
C5
C8
Benzene
Paraffins
NH4Cl

V=

Hot High Pressure Separator

FEED STREAM

Components
H2
H2S
NH3
H2O
C6H12
C2
C4
C5
C8
Benzene
Paraffins
NH4Cl

Cold High Pressure Seperator

FEED STREAM

Components
H2
H2S
NH3
H2O
C6H12
C2
C4
C5
C8
Benzene
Paraffins
NH4Cl

V=
For Top Products:

Components
H2
H2S
NH3
H2O
C6H12
C2
C4
C5
C8
Benzene

For 1st Cooler:

Q=
Q=NcCpc(∆T) [Coolant is water at 20⁰C]
∆T
Cpc=
Nc=
Mass flow rate of Cooling Water=
Components
H2
H2S
NH3
H2O
C2
C4
C5
Diglycolamine

1.7
2.56435944429145
0.246507439076016
0.006947953978883
0.820366732176846
0.096104905765231

0.221836328356267
5.65612280364469

Components
H2
C2
C4
C5

Componets
 Hydrogen
Hydrogen sulphide
Ethane
Butane
pentane

Components Molar Mass

H2 2
H2S 34
NH3 17
H2O 18
C6H12 84
C2 30
C4 58
C5 72
C8 114
Benzene 78
Paraffins 170
NH4Cl 53.5

Temperature of HHPS Bottom Stream=

Temperature of CHPS Bottom Stream=

Mixed Stream Temperature=

Mixed Stream Flow Rate=

Components
HK C12
NH4CL
LK C6H6
H20
C5
C4
C6H12
C8
NH3
C2
H2S
H2
kPa
kPa
kPa

kg/mᵌ

KJ/K

KJ
KJ

K
⁰C

H2 Stream(kg/hr)
0
0
0
0
0
0
0
0
0
0
6952.4
 27.57
99.41932
2740.9906524

65.2
245.539615382978
16009.1829229701

18750.1735753701

4773.13128264849
54.3547989402086
inlet (Kg/hr)
756.76
756.76
756.76
3783.81
3783.81
13621.743
40865.23
40865.23
12108.22
756.76
6716.004

184650.294
309421.381

General Energy Balance Equation:

∆Hr T(R )(J/kmol)

-5.862
-10.471
-26.186
-100200019.3
-86261433.45
-20.618
-6.257
 -12.514
15.058
-186461519.6
-186.4615196

-186.4615196
K- Values (at 294⁰ C)
1.52E+052
45
21.26
1.9382
1.137
79.87
5.74
1.7846
2.88
1.206
0.1241
0

0.4
Kg/Hr

Kg/Hr

0.45
zi
0.3825
0.036290322580645
0.03502855887522
0.163480309464255
0.015091012514221
0.026993056408996
0.045587016574586
0.082856816659563
0.023013698630137
0.130360310421286
0.060365125300166
0

V=1432.7kmol/hr
Mol fraction
0.3825
0.036290322580645
0.03502855887522
0.163480309464255
0.015091012514221
0.026993056408996
0.045587016574586
0.082856816659563
0.023013698630137
0.130360310421286

1758.45417302017

10
0.036
4.88
87.92
Molar Mass
2
34
17
18
30
18
72
105.14

Temp=
Qin=
Qout=

Heat Of Absorption=

Purge Ratio=0.2=
Mass of H₂ in makeup gas=

Molar Mass
2
30
18
72
∑

Molar Mass
 2
24
30
58
72

HHPS Bottom stream (mole fraction)

2.51644736842105E-53
0.000806451612903
0.00164762741652
0.084346460357164
0.013272658323853
0.000337962394003
0.007941988950276
0.046428788893625
0.007990867579909
 0.108093126385809
0.486423249799889
0.242710818286049
1

523.005133676039
2150.04152174015

1
2
3
4
5
 6
7
8
9
10
11
12
∑
H2 Stream(kmol/hr)
0
0
0
0
0
0
0
0
0
0
3476.2
0
0
0

3476.2
⁰C
KJ/K
KJ/hr

K
KJ/K
KJ/hr

KJ/hr

kmol/hr
⁰C
 0.84
914
-10
232-350

0.61
0.27
0.04
0.025
0.045
0.01
0.25
0.25
0.25
0.25

F1=
Conversion = 100%
H₂ was taken in 20% excess. Excess of H₂ suppress coke formation (Ref: Fundaments of Petroleum and Petrochemical Enginee
mass fraction of diesel at inlet
0.002499988437603
0.002499988437603
0.002499988437603
0.012499975223435
0.012499975223435
0.045
0.135000003303542
0.135000003303542
0.040000013214168
0.002499988437603
0
0
0
0
0
0
0
0
0
0
0.61
0.999999924018534

Q-W-FAo∑Ɵ[T-To] Cpi - ∆Hrx (T) FaoX

H₁ - H₂ = ∆Hrx
H₁ = Inlet of Reactor
H₂ = Outlet of Reactor

Temperature(T)
345
350
360
370
365
366
367
 368
369
368.1
368.2
368.5
368.6
368.7
368.8
368.9
368.95
368.97
368.98
368.99
368.993
KJ/mol

Outlet Temperature of Reactor=

K values at 40⁰C
2.62234482468802E+015
17.65
0.2798
0.0013
0.0014
1.024
0.068
0.0208
0.000745
0.00437
2.7707311091824E-155
0

Components
H2
H2S
NH3
H2O
C6H12
C2
C4
C5
C8
Benzene
Paraffins
NH4Cl
Components
H2
H2S
NH3
H2O
C6H12
C2
C4
C5
C8
Benzene
Paraffins
NH4Cl

ki
2.62234482468802E+015
17.65
0.2798
0.0013
0.0014
1.024
0.068
0.0208
0.000745
0.00437
2.7707311091824E-155
0

Moles
548.00775
51.9931451612903
50.1854163005272
234.218239369437
21.620893629124
38.6729519171685
65.3125186464088
118.708961228156
32.9717260273973
186.767216740577

KJ/hr

K
KJ/mol.K
kmol
kg/hr

DGA Flowrate=
Molecular Weight=
Molar Flowrate=

Feed(mole fraction)
0.85
0.075422336596808
0.014500437592707
0.000385997443271
0.027345557739228
0.005339161431402
0.003081060116059

40
686.994061844904
5953.85904130475

5266.86497945984

Mass of H₂ in purged gas/Mass of H₂ in make up gas (ref:/[Mohamed_A._Fahim,_Taher_A._Al-Sahhaf,_Amal_Elkila(z-lib.org).p

1098.73-1095.05=3.64Kg/hr

Absorber top product(kg/hr)

1095.09444
528.458263
61.90820468
142.9010175
1095.09444

Make Up stream(kg/hr)
 5669.46
0
0
0

Q(make up H₂)
∆T=
∑nCp=
Q(make up H₂)

Q(recycle stream)
∆T=
∑nCp=
Q(recycle stream)
Heat (in)=

Mixed Stream
Flow rate of mixed stream=
temp of mixed stream=

CHPS Bottom stream

3.24137387271761E-16
0.004273220203785
0.051824294470003
0.296921110208695
0.027406811314714
0.026704646229715
0.078517079873554
0.148127890195157
0.041817598691229
 0.236174315689967
0.10975477327303

1.02152174014985

293.7
40

K
kmol/hr

km0l/hr
2953.9607
F
0.38
0.18
0.14
0.14
0.073
 0.028
0.017
0.017
0.015
0.007
0.0017
8.64E-17
0.9987
diesel stream(kmol/hr) Cp for H2 stream
11.94
11.94
8.80819672131148
47.896329113924
56.474776119403
50.9604713804714
504.508974358974
418.635106382979
172.974571428571
12.7928571428571
0 0.0286
0
0
0

1296.93128264849
 0.01

302705.4 kg/hr
daments of Petroleum and Petrochemical Engineering by Uttam Ray chapter 3)
moles at inlet(moles/hr) mole fraction at inlet
8.40844444444445 0.001242120925255
8.40844444444445 0.001242120925255
6.20295081967213 0.000916318715352
47.896329113924 0.007075391058166
56.474776119403 0.008342625277539
91.7289090909091 0.013550472764069
523.913205128205 0.077394048257896
434.736489361702 0.064220593235275
172.974571428571 0.025552328510704
9.00904761904762 0.001330843848488
3358.002 0.496054243898115
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
2051.66993333333 0.303078907489681
6769.42510090366 1.00000001490579

∆Hr(T) = ∆Hr (Tr) + ∆Cp(T-Tr)

H1 = mCpT-T( R ) 404197.238682951
∆Cp= -985.875587939636

∆Cp x T - T ( R ) Hr(TR) + ∆Cp T - T ( R )

-302731.55904 -302918.0205596
-307461.73965 -307648.2011696
-316922.10087 -317108.5623896
-326382.46209 -326568.9236096
-321652.28148 -321838.7429996
-322598.317602 -322784.7791216
-323544.353724 -323730.8152436
 -324490.389846 -324676.8513656
-325436.425968 -325622.8874876
-324584.9934582 -324771.4549778
-324679.5970704 -324866.05859
-324963.407907 -325149.8694266
-325058.0115192 -325244.4730388
-325152.6151314 -325339.076651
-325247.2187436 -325433.6802632
-325341.8223558 -325528.2838754
-325389.1241619 -325575.5856815
-325408.04488434 -325594.50640394
-325417.50524556 -325603.96676516
-325426.96560678 -325613.42712638
-325429.803715146 -325616.265234746

368.99⁰C
Σyi=1 1=ziki/1+v(ki+1)

zi
0.153
0.015
0.015
0.116
0.014
0.011
0.023
0.061
0.014
0.117
0.316
0.014
PRODUCT STREAM

TOP (Kg/hr)
0.3825
0.036290322580645
0.03502855887522
0.163480309464255
0.015091012514221
0.026993056408996
0.045587016574586
0.082856816659563
0.023013698630137
0.130360310421286
0.060365125300166
0

PRODUCT STREAM

TOP (Kg/Hr)
0.6375
0.058282456191846
0.017258911694877
0.000530276965676
5.27078572994436E-05
0.02724851120151
0.007032479870853
0.004178194788884
4.2815167748671E-05
0.001414911645516
4.18138826447161E-156
0

zi
0.3825
0.036290322580645
0.03502855887522
0.163480309464255
0.015091012514221
0.026993056408996
0.045587016574586
0.082856816659563
 0.023013698630137
0.130360310421286
0.060365125300166
0

v ziki
0.6 1.00304689544317E+015
0.6 0.640524193548387
0.6 0.009800990773286
0.6 0.000212524402304
0.6 2.1127417519909E-05
0.6 0.027640889762812
0.6 0.003099917127072
0.6 0.001723421786519
0.6 1.71452054794521E-05
0.6 0.000569674556541
0.6 1.67255530578864E-156
0.6 0

Cp( 294 n 210) Cp (210 n 40)

0.0295 0.029
-0.6711 -0.66
0.037 0.037
0.034 0.034252102111009
0.152 0.149659660492787
0.065 0.064884160156363
0.12 0.123918068446528
-0.164 -0.1558
0.31 0.306
0.113 0.111

For 2nd Cooler:

Q= 2820.16235295688
Q=NcCpc(∆T) [Coolant is water at 20⁰C]
∆T 10
Cpc= 0.036
Nc 7.83
Mass flow rate of Cooling W 141.01

5000 kg/hr
 105.14 kg/kgmol
47.5556400989157 kmol/hr

Feed Moles Feed(kmol/hr)

547.54722 547.54722
48.5850479170425 133.321047917043
9.34079328549425 9.34079328549425
0.248649208223894 0.248649208223894
17.6152754346634 17.6152754346634
3.43934470458261 3.43934470458261
1.98473635435426 1.98473635435426
847.36
∑

K
KJ/K
KJ/K

KJ/K

him,_Taher_A._Al-Sahhaf,_Amal_Elkila(z-lib.org).pdf)
Mass of H₂ in purge stream= 0.2*3.64=0.728kg/hr
Purge Stream= 0.728/0.598948393=1.3056kg/hr
Mass Fraction Purge Stream(kg/hr)
0.598948393111642 0.781987022046559
0.289033727036747 0.377362434019177
0.03385992875054 0.044207522976705
0.078157948464832 0.102043017515684

recycle stream mole fraction Recycle Stream(kg/hr)

 0.962939419849294 1094.31245297795
0 0
0.030978959415152 528.080900565981
0.001877144060822 61.8639971570233
0.003490440282822 142.798974482484

Heat of mixing Qm= Heat (in) - Heat (out)

Heat (in)= Q(make up H₂) + Q(recycle stream)

25 ⁰C
81.073278 KJ/K
2026.83195 KJ/hr

40 ⁰C
16.7934520547372 KJ/K
671.738082189488 KJ/hr
2698.57003218949 KJ/hr

3402.53886290518 Kmol/hr
27.5739266110165 ⁰C

moles for HHPS Bottom(kmol/hr) Moles CHPS Bottom(kmol/hr)

5.40789572368421E-50 2.55414426697177E-13
1.73308064516129 3.36722060261901
3.54078427065026 40.8366112050619
181.262230236752 233.968490264468
28.5232081911263 21.5960739933906
0.72628794395969 21.0427805453833
17.0674930939227 61.8700456329231
99.7763959081776 116.72211117176
17.1725342465753 32.9515150519117
 232.294290465632 186.101109626011
1045.33329228496 86.4847857532284
521.590402713085 0
2149.02 804.940743846758

566.85 K
313.15 K

250.005133676039 ⁰C

kmol/hr kmol/hr
1435.96 1518.0007
D W
0.0023 0.65
0 0.1
0.45 0.08
0.23 0
0.1 0.0034
 0.09 0.0056
0.06 0.05
0.05 0.1
0.01 0
0.003 0.002
0.0015 0.008
0.00019 0
0.99699 0.999

Overall Energy Balance eq:

Qc=
Qc=
Cpc=
∆T=
Nc=
Mc(liq propane)=
Cp for Diesel Stream(54.34 ⁰C) nCp for Diesel stream
1.7437 20.819778
1.7437 20.819778
1.957 17.2376409836066
0.1578 7.55804073417721
0.1387 7.83305144776119
1.23 62.6813797979798
0.0858 43.28687
0.106 44.3753212765957
0.113 19.5461265714286
0.108 1.38162857142857

245.539615382978
0.0611 KJ/Kmol.K
outlet of reactor(kg/hr) mass fraction at outlet
0
0
0
0
0
0
33909.4461702128 0.109506205076898
0
0
0
1119.334 0.003614745517761
876.657 0.002831051287073
4285.472 0.013839381903428
15901.92 0.051353210072953
214.727 0.00069343329229
1299.866 0.004197750445524
7825.25680851064 0.025270662710053
10457.0956363636 0.033769848481639
44008.7092307692 0.142120479172778
4870.5015 0.01572865960149
184650.294 0.596304429767883
309419.279345856 0.99922985732977

T-Tr=
KJ/Hr

H2 (Reactor Outlet) H2-H1

46271.285124 -333273.244876
47866.84668 -331677.68332
51057.969792 -328486.560208
54249.092904 -325295.437096
52653.531348 -326890.998652
52972.6436592 -326571.8863408
53291.7559704 -326252.7740296
 53610.8682816 -325933.6617184
53929.9805928 -325614.5494072
53642.77951272 -325901.75048728
53674.69074384 -325869.83925616
53770.4244372 -325774.1055628
53802.33566832 -325742.19433168
53834.24689944 -325710.28310056
53866.15813056 -325678.37186944
53898.06936168 -325646.46063832
53914.02497724 -325630.50502276
53920.407223464 -325624.122776536
53923.598346576 -325620.931653424
53926.789469688 -325617.740530312
53927.7468066216 -325616.783193378
ki ZiKi
1.52E+052 2.3256E+051
45 0.675
21.26 0.3189
1.9382 0.2248312
1.137 0.015918
79.87 0.87857
5.74 0.13202
1.7846 0.1088606
2.88 0.04032
1.206 0.141102
0.1241 0.0392156
0 0
Bottom (Kg/hr)
2.51644736842105E-53
0.000806451612903
0.00164762741652
0.084346460357164
0.013272658323853
0.000337962394003
0.007941988950276
0.046428788893625
0.007990867579909
0.108093126385809
0.486423249799889
0.242710818286049

Bottom (Kg/Hr)
2.43103040453821E-16
0.003302122163844
0.061683029645735
0.407905358212123
0.037648469499603
0.026609874220225
0.103418821630185
0.200874749465581
0.05747002382372
0.323778408584941
0.150912813250416
0

ki ZiKi
2.62234482468802E+015 1.00304689544317E+015
17.65 0.640524193548387
0.2798 0.009800990773286
0.0013 0.000212524402304
0.0014 2.1127417519909E-05
1.024 0.027640889762812
0.068 0.003099917127072
0.0208 0.001723421786519
 0.000745 1.71452054794521E-05
0.00437 0.000569674556541
2.7707311091824E-155 1.67255530578864E-156
0 0

v(Ki+1) 1+V(Ki+1)
1.57340689481281E+015 1573406894812815
9.99 10.99
-0.43212 0.56788
-0.59922 0.40078
-0.59916 0.40084
0.0144 1.0144
-0.5592 0.4408
-0.58752 0.41248
-0.599553 0.400447
-0.597378 0.402622
-0.6 0.4
-0.6 0.4

nCp (294 to 210) nCp(210 to 40)

16.166228625 15.89222475
-34.8925997177419 -34.3154758064516
1.85686040311951 1.85686040311951
7.96342013856088 8.02246705114259
3.28637583162685 3.23577560008536
2.51374187461595 2.50926200591289
7.83750223756906 8.09340115604083
-19.4682696414175 -18.4948561593467
10.2212350684932 10.0893481643836
21.1046954916851 20.731161058204
16.5891903115111 17.6201682230905

KJ/hr

K
KJ/mol.K
Kmol
KJ/hr
 3900.47KPa Joural of Chem and engineering data vol 23 no 2 978
solubility of H2S IN liq DGA (MOLE ratio of H2S in liq DGA) =1.09

moles of H2S which can absorb in 47.

Feed(kg/hr) Top Product Stream(kg/hr)

1095.09444 1095.09444
4532.91562917945 0
158.793485853402 0
4.4756857480301 0
528.458263039902 528.458263
61.908204682487 61.90820468
142.901017513507 142.9010175
89091.4304 0
95615.9771260168 1828.36192518

713.497066904361

Recycle Stream(kg/hr)
1094.31245297795
528.080900565981
61.8639971570233
142.798974482484

make up stream (kmol/hr) recycle stream(kmol/hr)

 2834.73 547.156226488977
0 0
0 17.6026966855327
0 1.06662064063833
1.9833190900345
2834.73 567.808862905182

Cp for HHPS Stream Cp for CHPS Stream

0.02976113 0.028733928
0.036 -0.512730620011608
0.04291085 0.0345339
0.03615138 0.0336735
0.22293651 0.1129649
0.0880311 0.054607
0.16772 1.009009
-0.469421139354185 -0.065470045034758
0.461121403848 0.260580128424
 0.15592782 0.0861174
0.475364695085044 0.291548544623092
0.084 0.184

Hf(KJ/mol) Hd(KJ/mol)
77.88 81.82

5.6379 59.11
25.646 55.39
26.339 69.74
 38.0529 74.87
60.702 68.94
23.833 84.09
29.33 39.88
20.9481 39.41
22.01 31.58
8.3531 17.12

∑Qfi+Qr= Qc+∑Qdi+∑Qwi
nƛ 10.8358157063226
NcCpc(∆T)
0.064 KJ/mol.k
10 K
16.930962041129 kmol
744.962329809677 kg/hr
ncp for H2 stream
0
0
0
0
0
0
0
0
0
0
99.41932
0
0
0

99.41932
moles at outlet(moles/hr) mole fraction at outlet
cp 25 n 54.34
0 0 1.7437
0 0 1.7437
0 0 1.957
0 0 0.1578
0 0 0.1387
0 0 1.23
434.736489361702 0.121375532676102 0.0858
0 0 0.106
0 0 0.113
0 0 0.108
559.667 0.156255299264097 0.0286
29.2219 0.008158559875007
73.8874482758621 0.020628883500734
220.86 0.061662641169604
12.631 0.003526491083099
38.2313529411765 0.010673939137192
434.736489361702 0.121375532676102
91.7289090909091 0.025610100544019
523.913205128205 0.14627307784043
91.0374112149533 0.025417038942123
1086.1782 0.30325371997123
3596.82940537451 1.00421081667974

300
v(Ki-1) 1+V(Ki-1) Yi
6.08E+051 6.08E+051 0.3825
17.6 18.6 0.036290322581
8.104 9.104 0.035028558875
0.37528 1.37528 0.163480309464
0.0548 1.0548 0.015091012514
31.548 32.548 0.026993056409
1.896 2.896 0.045587016575
0.31384 1.31384 0.08285681666
0.752 1.752 0.02301369863
0.0824 1.0824 0.130360310421
-0.35036 0.64964 0.0603651253
-0.4 0.6 0
Σyi= 1.001566227429
 For Top Streams: zi
0.153
0.015
0.015
0.116
0.014
0.011
0.023
0.061
0.014
0.117
0.316
0.014

v(Ki-1) 1+V(Ki-1) Yi
1.18005517110961E+015 1.18005517110961E+15 0.85
7.4925 8.4925 0.075422336597
-0.32409 0.67591 0.014500437593
-0.449415 0.550585 0.000385997443
-0.44937 0.55063 3.83695358E-05
0.0108 1.0108 0.027345557739
-0.4194 0.5806 0.005339161431
-0.44064 0.55936 0.003081060116
-0.44966475 0.55033525 3.1154111E-05
-0.4480335 0.5519665 0.00103208176
-0.45 0.55 3.0410096E-156
-0.45 0.55 0
Σyi= 0.976144074566
m and engineering data vol 23 no 2 978
A (MOLE ratio of H2S in liq DGA) =1.09

51.8356477078182 kmol/hr

Bottom Product(kg/hr) Cp at 40 deg C moles top

0 0.028739 547.54722
4532.915629 -0.5127306 0
158.793485853402 0.034533 0
4.4756857480301 0.03367357 0
0 0.05460704 17.61527543333
0 0.10090098 3.439344704444
0 0.06547 1.984736354167
89091.4304 0.25594 0
93787.6152006014
95615.9771257814

Cp makeup (25⁰C) Cp recycle nCp for make up

 0.0286 0.028739 81.073278
0
0.0546 0
0.1009 0
0.06547
81.073278

nCp for CHPS Bottom nCp for HHPS Bottom Mixed Stream mo
7.33905974687795E-15 1.6094508765901E-51 2.55414427E-13
-1.7264771072967 0.062390903225807 5.10030124778
1.41024744769449 0.151938062720233 44.37739547571
7.87853795692057 6.5528797649363 415.2307205012
2.43959833905597 6.35886448813311 50.11928218452
1.14908311724175 0.06393592662351 21.76906848934
62.4274328740301 2.86255994171271 78.93753872685
-7.64180187496711 -46.8371494478709 216.4985070799
8.58651002399253 7.91862309940868 50.12404929849
 16.0265436981071 36.2211423107528 418.3954000916
25.2145134183937 496.914541749285 1131.818078038
0 43.8135938278992 521.5904027131
115.764187893172 554.083320626826 2953.960743847

Hw(KJ/mol) Moles in F Moles in D

94.28 1122.5048 3.302708
531.7128 0
63.29 413.5544 646.182
56.45 413.5544 330.2708
75.04 215.63908 143.596
 76.5 82.71088 129.2364
74.59 50.21732 86.1576
92.45 50.21732 71.798
41.09 44.3094 14.3596
41.66 20.67772 4.30788
32.65 5.021732 2.15394
19.45 2.55222144E-13 0.2728324

KJ/hr Qr=
cp =
cp 54.34 n 120
1.898
1.89
1.998
0.164
0.223
1.344
0.1
0.122
0.127
0.1244
0.0291

Fired Heater Energy Balance:

T(ref)=25 deg celcius

ki
1.52E+052
45
21.26
1.9382
1.137
79.87
5.74
1.7846
2.88
1.206
0.1241
0
moles bottom
0
133.321047911765
9.34079328549425
0.248649208223894
0
0
0
847.36

nCp for recycle

 15.7247227930667
0
0.961107239030085
0.107622022640408

16.7934520547372

Mixed mole fraction

8.64650714184225E-17
0.001726597504093
0.015023014630729
0.140567447060569
0.016966807120344
0.007369450841065
0.026722609258495
0.073290922203243
0.016968420924448
 0.141638781402724
0.38315271465171
0.176573234350702
0.999999999948123

Moles in W
986.7
151.8
121.44
0
5.1612
 8.5008
75.9
151.8
0
3.036
12.144
0

95947.3364032703
0.1 KJ/Kg.K
cp 25 n 325
1.757
1.757
2.0032
0.793
0.4572
1.6766
0.1227
2.048
0.193
0.1135
0.0294

10.9506

Qin

∆T=t2-T(ref)
∑NiCpi=

t2-T(ref)=

Qin=
Qout

∑NiCpi =

∆T=325-T(ref)

325-T(ref)=

Qout=

Heat duty of fired heater=

v
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.4
nCp for top
15.73595955558
0
0
0
0.961918050199051
0.347033251236255
0.129940689107292
0
17.1748515461226
Qfi(KJ)
87420.673824
0
2331.57835176
10606.0161424
5679.71772812
 3147.388845552
3048.29175864
1196.82938756
1299.594702
433.158946332
110.52832132
2.1318960910464E-12
115273.778007684

KJ/hr
cp 25 to 360

0.1266

0.0294
0.0817
0.139
0.205
0.04
0.036
0.035
0.0788
0.2381
0.9112
0.09988
2.02068

Qout=Qin+Qfuel
Qfuel =heater duty

Qin=∑NiCpi *∆T

414.212736670939

120

49705.5284005127
Qout=∑NiCpi *∆T (FOR OUTLET)

1347.32412894317

300

404197.238682951

354491.710282438
ziki
2.3256E+051
0.675
0.3189
0.2248312
0.015918
0.87857
0.13202
0.1088606
0.04032
0.141102
0.0392156
0
nCp for bottom
0
-68.3577808884279
0.322565614527973
0.008372906518572
0
0
0
216.8733184
148.846476032619

Compressor Balance:
Innlet Pressure=
Outlet Pressure=
Inlet temp=
Effficiency=
Density=
flow rate=

Vol flowrate=qa=

Isentropic Work=W=[(0.371*Ta*qa* Ꚕ)((Pb/Pa)^(1-1/Ꚕ)-1)](Ꚕ-1)Ꞃ

Qdi(KJ)
270.22756856
0
38195.81802
18293.699612
10014.38504
 9675.929268
5939.704944
6037.49382
572.660848
169.7735508
68.0214252
4.670890688
89242.384987248
nCp(inlet)(KJ/K) nCp(outlet))(KJ/K)
14.7736368888889 0
14.7736368888889 0
12.4257510819672 0
37.9817889873418 0
25.820267641791 0
153.792688981818 0
64.2841502692308 55.0376395531915
890.340330212766 0
33.3840922857143 0
1.0225269047619 0
98.7252588 16.4542098
0 2.38742923
0 10.2703553103448
0 45.2763
0 0.50524
0 1.37632870588235
0 15.2157771276596
0 7.22823803636364
0 124.743734141026
0 82.9532890990654
0 0
1347.32412894317 361.448541003533

KJ/K.hr

KJ/hr
KJ/K.hr

KJ/hr

KJ/hr
v(Ki-1) 1+V(Ki-1)
6.08E+051 6.08E+051
17.6 18.6
8.104 9.104
0.37528 1.37528
0.0548 1.0548
31.548 32.548
1.896 2.896
0.31384 1.31384
0.752 1.752
0.0824 1.0824
-0.35036 0.64964
-0.4 0.6
Pa 25
Pb 60.67
Ta 300.57
Ꞃ 0.75
PM/RT 3.22452684200219
qa 1827.05632518344

566.61222396554 mᵌ/hr
0.157392284434872
105.5162798769 KW
Qwi(KJ) ƛ(KJ/mol)
93026.076 3.2809
0
7685.9376 -6.813E-08
0 2.605E-07
387.296448 -2.13E-07
 650.3112 -2.233E-07
5661.381 -2.59E-07
14033.91 6.722E-08
0 -1.952E-07
126.47976 -1.889E-07
396.5016 -2.007E-07
0
121967.893608
ncp cold stream of HE ncp hot stream for HE ncp fired heater in
15.9592275555556 0 15.9592275555556
15.89196 0 15.89196
12.3934957377049 0 12.3934957377049
7.85499797468354 0 7.85499797468354
12.5938750746269 0 12.5938750746269
123.283653818182 0 123.283653818182
52.3913205128205 55.0376395531915 52.3913205128205
53.0378517021277 0 53.0378517021277
21.9677705714286 0 21.9677705714286
1.12072552380952 0 1.12072552380952
97.7178582 16.4542098 97.7178582
0 2.38742923 0
0 10.2703553103448 0
0 45.2763 0
0 0.50524 0
0 1.37632870588235 0
0 15.2157771276596 0
0 7.22823803636364 0
0 124.743734141026 0
0 82.9532890990654 0
0 108.487478616 0
414.212736670939 361.448541003533 414.212736670939
0
bar
bar
K Components Molar Mass
Hydrogen 2
kg/mᵌ Hydrogen sulphide 24
kg/hr Ethane 30
Butane 58
pentane 72
nƛ(KJ)
10.8358546772

-4.402437966E-05
8.60355434E-05
-3.0585948E-05
 -2.885848812E-05
-2.23148184E-05
4.82626156E-06
-2.80299392E-06
-8.13758532E-07
-4.32295758E-07
0
10.8358157063226
ncp fired heater out
14.7736368888889
14.7736368888889
12.4257510819672
37.9817889873418
25.820267641791
153.792688981818
64.2841502692308
890.340330212766
33.3840922857143
1.0225269047619
98.7252588
0
0
0
0
0
0
0
0
0
0
1347.32412894317
mole fraction mi*ni
0.963627493543158 1.92725498708632
0 0
0.031001093038696 0.930032791160888
0.001878479242497 0.108951796064832
0.003492934096083 0.251491254917952
0
Molar Mass 3.21773082922999
DGA-H2S Solubility Operating Line
Xo Yo
0.01 0.00981
0.06 0.00231
0.11 0.00519 Operating Line (DGA-H2S)
0.16 0.01269 0.12
0.21 0.02019
0.26 0.02769 0.1
0.31 0.03519
0.08
0.36 0.04269
0.41 0.05019
0.06

Yo
0.46 0.05769
0.51 0.06519 0.04
0.56 0.07269
0.61 0.08019 0.02
0.66 0.08769
0
0.71 0.09519 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
0.76 0.10269 Xo
0.81 0.11019
(DGA-H2S)

0.5 0.6 0.7 0.8 0.9

o
Heat Exchanger Property Data
Component Name Molar mass inlet (Kg/hr) mass fraction of dies
Butyl Mercaptan 90 756.76 0.0024999884376
Diethyl sulphide 90 756.76 0.0024999884376
Diethyl disulphide 122 756.76 0.0024999884376
Pyridine 79 3783.81 0.01249997522344
Pyrole 67 3783.81 0.01249997522344
Chlorooctane 148.5 13621.743 0.045
Benxene 78 40865.23 0.13500000330354
Phenol 94 40865.23 0.13500000330354
Pentene 70 12108.22 0.04000001321417
Thiophene 84 756.76 0.0024999884376
Hydrogen 2 6716.004 0
Ethane 30 0
Butane 58 0
Pentane 72 0
Ammonia 17 0
Hydrsulphide 34 0
water 18 0
Octane 114 0
cycloHexane 84 0
ammonium chloride 53.5 0
Paraffins 170 184650.294 0.61
309421.381 0.99999992401854

mole fraction at inlet Avg. Molar Weight mol.frac (Out) Avg. Molar weight
0.001242120925255 0.111790883272952 0 0
0.001242120925255 0.111790883272952 0 0
0.000916318715352 0.111790883272952 0 0
0.007075391058166 0.558955893595099 0 0
0.008342625277539 0.558955893595098 0 0
0.013550472764069 2.01224520546427 0 0
0.077394048257896 6.03673576411586 0.1213755326761 9.46729154873594
0.064220593235275 6.03673576411586 0 0
0.025552328510704 1.78866299574927 0 0
0.001330843848488 0.111790883272952 0 0
0.496054243898115 0.992108487796231 0.1562552992641 0.3125105985282
0 0 0.008158559875 0.24475679625021
0 0 0.0206288835007 1.19647524304258
0 0 0.0616626411696 4.43971016421146
0 0 0.0035264910831 0.05995034841268
0 0 0.0106739391372 0.36291393066453
0 0 0.1213755326761 2.18475958816983
 0 0 0.025610100544 2.91955146201811
0 0 0.1462730778404 12.2869385385962
0 0 0.0254170389421 1.35981158340359
0.303078907489681 51.5234142732458 0.3032537199712 51.5531323951092
1.00000001490579 69.9549778107693 1.0042108166797 86.3878021971425
outlet of reactor( mass fraction at outlet
Cp (Cold) Viscosity density
0 1.03 BTU/lbm. oF 7.08 lbf/hr.ft 0.123 lb/ft3
0
0
0 Cp (Hot) Viscosity (Hot) density (Hot)
0 2.08 BTU/lbm.oF 0.486 lbf/hr.ft 0.114 lb/ft3
0
33909.44617021 0.109506205076898
0
0
0
1119.334 0.003614745517761
876.657 0.002831051287073
4285.472 0.013839381903428
15901.92 0.051353210072953
214.727 0.00069343329229
1299.866 0.004197750445524
7825.256808511 0.025270662710053
10457.09563636 0.033769848481639
44008.70923077 0.142120479172778
4870.5015 0.01572865960149
184650.294 0.596304429767883
309419.2793459 0.99922985732977
Thermal Conductivity
0.13 lb/ft2.hr. oF

Thermal Conductivity (hot)

0.11 lb/ft2.hr.oF