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EXP3 Solubility of Solids in Liquids PDF
EXP3 Solubility of Solids in Liquids PDF
THEORY
When a sufficiently large amount of solute is in contact with the limited amount of
solvent, dissolving of the solute starts taking place. After a certain period of time,
the reverse process, precipitation, starts to occur. When dissolving and
precipitation of the solute takes place at equal rates (i.e. equilibrium has been
established), the solution is said to be saturated. After this point the concentration
of the solute in the solution remains unchanged. The concentration of the
saturated solution is defined as the solubility of the solute in the given solvent.
Solubility is generally a function of temperature.
− ΔH f ⎛ 1 1 ⎞
ln X A = ⎜ − ⎟ (7)
R ⎜⎝ T2 T1 ⎟⎠
In determining the solubility of a solute, it is practically more correct to start off
at a high temperature, cool the solution down to the required temperature and
wait for thermal equilibrium to be reached. This approach is known as “reaching
equilibrium from the molecular rather than the crystal side”.
2
The solubility of the solute (benzoic acid in this case) can be determined as a
function of temperature. As shown in equation (7), a plot of lnXA versus 1/T
should give a straight line with the slope being equal to heat of solution (ΔHf).
Experimentally, the heat of solution measured is the heat absorbed when 1 mole of
solid is dissolved in an almost saturated solution. This value is different from the
heat of solution measured at “infinite dilution”, and the difference is equivalent to
the heat of dilution.
PROCEDURE
CALCULATIONS
1. Use titration results to determine the solubility, X, of benzoic acid. Define the
solubility as moles per 1000 g of solvent.
2. Plot lnX versus 1/T.
3. Draw tangents to the curve at least four temperatures, and determine ΔHf from
each slope.
4. Determine the deviations in each value obtained. Why do you think it differs
for each temperature?
DATA SHEET