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Diagram 3.1
(i) How are sodium ion and chloride ion formed from their respective atoms? [2 marks]
Sodium ion produced when sodium atom donate/release one electron to chlorine atom.
Chloride ion formed when chlorine atom accept/gain/receive one electron from sodium atom.
(ii) Name the force that exists between these ions in the compound. [1 mark]
Ionic bond // electrovalent bond
(iii) The melting point of sodium chloride, NaCl, is 801ºC and its boiling points is 1413ºC.
What will happen to the ions in this compound at 900ºC? [1 mark]
Ions will moves more faster
(iv) Give one reason for your answer in (b)(iii). [1 mark]
Ions are absorbed heat energy.
(c) Diagram 3.2 shows the proton number and nucleon number for two elements, X and Y.
The letters used do not represent the actual symbols of the elements.
Diagram 3.2
Draw a diagram to show the bonding formed between elements X and Y. [3 marks]
(X : 4 proton number, electron arrangement 2.2; Y : 8 proton number, electron arrangement 2.6; so
ions X2+ and Y2- produced XY compound)
2. (a) Table 1 shows four substances and their respective formulae.
Substances Chemical formula
Iodine I2
Copper Cu
Describe Graph 8 in terms of states of matter, particle arrangements and changes in energy.[10 marks]
4. Formation of ionic compound (metal [Group 1, 2 & 13] and non metal [ Group 14, 15, 16& 17])
Sample answer:
1. Electron arrangement of atoms ( Na , 28.1 ; Cl 2.8.7 ) // valence electrons
2. To achieve stable / octet electron arrangement
3. Atom ( Na) releases one / valence electron to form sodium ion, Na+
4. Half equation ( Na Na+ + e)
5. Atom (Cl) gain / accept electron to form chloride ion, Cl-
6. Half equation ( Cl + e Cl- )
7. Oppositely charged ion, Na+ & Cl- are attracted to one another by strong electrostatic force of
attraction to form ionic compound, NaCl
8. Diagram
Formation of covalent compound (nonmetal)
1. electron arrangement of the atom /valence electrons
2. to achieve duplet /octet electron arrangement
3. Atom (Carbon) contributes 4 electrons while (H) atom contributes 1 electron (for sharing).
4. one ( Carbon ) atom share 4 pairs of electrons with 4 (H) atoms to form covalent compound , CH4 /
ratio
5. diagram
Compare the physical properties of covalent and ionic compound
Properties Covalent compound ( naphthalene) Ionic compound ( sodium chloride)
Melting and - low - high
boiling - consist of molecules - consist of oppositely charged ions
- weak inter molecular forces - ions are held together by strong electrostatic
between molecules forces .
Target SPM (P2&P3) 2013 3
- less energy needed to overcome the - more heat energy needed to overcome the
weak forces strong forces
Electrical - consist of molecules - consist of oppositely charged ions
conductivity - does not conduct electricity in any - conduct electricity in molten or aqueous
state (molten or aqueous). solution.
- in molten or aqueous solution, ions can move
freely.
2. EMPIRICAL FORMULA
a) Unreactive metal – reaction oxide metal with Reactive metal ( Mg, Zn – burn in excess oxygen
hydrogen gas, (CuO, PbO ,SnO ) / air ) – more reactive than H2
b) Diagram Hydrogen
c) Procedure
- Weigh and record the mass of combustion tube - Weigh and record a crucible with its lid
with porcelain dish - Clean Mg ribbon with sand paper then coil the
- Add a spatula of copper (II) oxide on the Mg ribbon and place into the crucible. Weigh and
porcelain dish. Weigh the tube again. record.
- Allow hydrogen gas flow into the tube for 5 – 10 - Heat strongly
minutes. - When Mg ribbon start to burn, cover the crucible
- Burn the excess hydrogen. with lid.
- Heat copper (II) oxide strongly. - Lift / raise the lid at intervals.
- Turn off the flame when black solid turns - When the burning is complete, remove the lid
brown completely. and heat strongly.
- Continue the flow of hydrogen until the set of -Allow the crucible to cool down.
apparatus cool down to room temperature. -Weigh and record the crucible with content and
- Weigh the combustion tube with its content. lid.
- -Repeat the process heating, cooling and -Repeat the process heating, cooling and
weighing until a constant mass is obtained and weighing until a constant mass is obtained and
record. record.
- Observation : White fume / solid formed
Result :
- combustion tube with porcelain dish = a g - mass of crucible + lid = a g
- combustion tube with porcelain dish + copper - mass of crucible + lid + Mg = b g
(II) oxide = b g - mass of crucible + lid + magnesium oxide = c g
-combustion tube with porcelain dish + copper = c - mass of Mg = ( b – a ) g
g - mass of oxygen = ( c – b) g
- mass of copper = ( c- a) g , Mass of oxygen = (
b- c ) g
Heat
Element M O
Mass 0.64 0.16
Number of mole 0.64 0.16
0.01 0.01
64 16
Simplest ratio 1 1
Empirical formula is MO
(ii) Write the chemical equation for the reaction between M oxide and hydrogen gas
Tulis persamaan kimia bagi tindak balas antara oksida M dengan gas hidrogen.
MO + H2 M + H2O
(d) (i) The empirical formula of magnesium oxide cannot be determined by the above
method. Explain why.
Diagram 2
(a) Based on Diagram 2, answer the following questions. What is the element represented by the symbol Fe? [1
mark]
Ferum // Iron // Besi
(b)In Diagram 2, mark ‘X’ in the boxes for all the transition elements. [1 mark]
Cross all boxes between group 2 and 13 include Fe
(c) State one specific characteristic of transition elements. [1 mark]
Form coloured compounds //Have more than one oxidation number//Act as catalyst //Form complex ions /
compounds.
(e) Write the chemical equation for the reaction between aluminium and oxygen gas. [1 mark]
4Al + 3O2 → 2Al2O3
(f) Briefly state the electron transfer in the bond formation between aluminium and oxygen. [ 2 mark]
Target SPM (P2&P3) 2013 8
Aluminium atom donate 3 electron to oxygen atom to achieved stable octet electron arrangement.
Oxygen atom will accepted 2 electron to achieved stable octet electron arrangement also.
(g)State one gas is more suitable to be used in meteorological balloons? Give a reason. [1 mark]
Helium because it is not flammable gas.
2. Diagram below shows part of the Periodic Table of the Elements. Q,R,T,X and Y do not represent the
actual symbol of the elements.
(a) Using the letters in the Periodic Table of the Elements in Diagram above, answer the following questions.
You may use the Periodic Table of the Elements at the back.
(i) Choose an element that is a halogen. [1 mark]
Y
(ii) Which element is monoatomic? [1 mark]
R
(iii) Which element forms an amphoteric oxide? [1 mark]
X
(b) Arrange Q,R,T,X and Y according to the increase in size of the atoms. [1 mark]
R, Q, Y, X, T
(c ) Write the electron arrangement for an atom of element Q. [1 mark]
2.4 (Group 14 Period 2)
(d) Write the formula for the ion formed from an atom of element Y. [1 mark]
Y-
(e) Why are elements Q and R placed in the same period? [1 mark]
Have same number of shells occupied/filled with electrons
(f) When a small piece of element T is put into water, TOH solution is formed and hydrogen gas is released.
State one observation when red litmus paper is put into the solution. [1 mark]
Red litmus paper turns blue
(g) State the common name of the elements between group 2 and group 13. [1 mark]
Transition elements
(ii) sodium oxide reacts with water to produced a solution. In table below, mark (√) in the box which
shows the value of pH of the solution. [1 mark]
pH value
4 7 11
√
(iii) State which is more electronegative, sodium or chlorine. Explain your answer. [2 marks]
Chlorine because has stronger nuclei attraction to attract electrons towards its nucleus.
4. ELECTROCHEMISTRY
1 Diagram 6 shows two types of cell.
Diagram 6
(a) Compare and contrast cell P and cell Q. Include in your answer the observation
and half equations for the reactions of the electrodes in both cells. [8 marks]
2. Figure 1 shows an experiment to construct an electrochemical series by measuring the voltage of a pair of
metals in a simple voltaic cell. Rajah 1 menunjukkan
e satu eksperimen untuk membentuk satu siri
elektrokimia dengan cara mengukur nilai voltan pasangan logam dalam satu sel kimia.
Logam lain
Kuprum
Figure 2/ Rajah 2
(b) Show the direction of electron flow on figure 1. Tunjukkan arah pergerakan elektron pada gambarajah 1.
(c) What is the function of voltmeter in voltaic cell. Apakah fungsi voltmeter di dalam sel kimia.
To measure the reading of voltage
(d) Arrange the metals in (a) in the electrochemical series in ascending order.
Susun logam dalam soalan (a) dalam siri elektrokimia mengikut tertib menaik.
Mg, Zn, Fe, Pb, Cu
(d) Explain why copper be a positive terminal compare to it’s metal pair base on the arrangement of metal in
electrochemical series. Jelaskan mengapa kuprum bertindak sebagai terminal positif berbanding
pasangan logamnya berpandukan kepada aspek susunan logam di dalam siri elektrokimia.
Because Copper is place lower than other metals in electrochemical series/Copper is less
electropositive metal than its pair of metal
(e) Another voltaic cell is formed by using magnesium and iron as electrodes. Which electrode will be the
positive terminal? Satu sel kimia yang lain dibina dengan menggunakan magnesium dan ferum sebagai
elektrod.Elektrod yang manakah akan bertindak sebagai terminal positif?
Iron
3. Electroplating
Zinc
Zinc
Zink
Zink
Apparatus set-up
Susunan radas
4 (a) (i) P 1
(ii) Concentration of H+ ion in P highest 1
(iii) Acid : P & Q 1
Alkali : R 1
(b) (i) Water 1
(ii) H+ 1
(iii) Test tube I : HCl exist as molecule / No H+ ion 1
Test tube II : HCl ionise to produces H+ ion 1
(c) Add magnesium // calcium carbonate //[suitable metal//metal
carbonate] 1
Bubble gas release 1
TOTAL 10
6. SALTS
1. Diagram 7.1 shows a series of reaction for salt S which is a green colour compound. Salt S is heated
strongly to produce black residue of compound T and gas U. Compound T reacts with sulphuric acid to
form blue solution of compound W.
Rajah 7.1 menunjukkan satu siri tindak balas bagi garam S yang merupakan sebatian berwarna hijau.
Garam S dipanaskan dengan kuat untuk menghasilkan baki hitam sebatian T dan gas U. Sebatian T
bertindak balas dengan asid sulfurik membentuk larutan biru sebatian W.
Diagram 7.2
Based on Diagram 7.2: Berdasarkan Rajah 7.2:
(i) State the name of salt X and salt Y. Nyatakan nama bagi garam X dan garam Y. [2 marks]
(ii) State one observation and name the type of reaction occurred.
Nyatakan satu pemerhatian dan namakan jenis tindak balas yang berlaku. [2 marks]
(iii) Compound W reacts with 50 cm3 of 0.1 mol dm-3 barium nitrate solution. Write the ionic equation for
the reaction and calculate the mass of salt X produced. [Relative molecular mass of salt X: 233]
Sebatian W bertindak balas dengan 50 cm3 larutan barium nitrat 0.1 mol dm-3. Tuliskan persamaan
ion bagi tindak balas itu dan hitung jisim garam X yang dihasilkan. [Jisim molekul relatif garam X:
233] [4 marks]
Sub
No. Answer Mark
Mark
1(a)(i) Carbonate ion // CO32- 1 1
(ii) Salt S : Copper(II) carbonate // CuCO3 1
Compound T: Copper(II) oxide // CuO 1
Gas U: Carbon dioxide // CO2 1
Compound W: Copper(II) sulphate // CuSO4 1 4
1. Correct formulae of reactants and products 1
2. Balanced equation 2
(b) 1
CuO + H2SO4 → CuSO4 + H2O
1. Add sodium hydroxide solution 1
2. Blue precipitate formed indicate the presence of Cu+ ion 1
(c) 3. Add hydrochloric acid 1
4. Add barium chloride solution 1
5. White precipitate formed indicate the presence of SO42- ion 1 5
2. Preparation of lead(II)sulphate.
Procedure:
1. pour ( 25 – 50cm3) of soluble salt Pb(NO3)2 into a beaker
2. add ( 25 – 50cm3) of soluble salt (Na2SO4)
3. stir
4. filter the mixture
5. rinse residue / solid / precipitate
6. dry between sheets of filter paper
Observation
Chemical equation
Ionic equation
(a) Test for anion (Cl-)
1. pour 2 cm3 the solution into a test tube
2. add 1 cm3 of dilute nitric acid and silver nitrate solution.
3. white precipitate formed
4. confirm the presence of chloride ions
10. Experiments I and II are carried out to investigate the effect of different sizes of solid X on the rate of
reaction. Table 10 shows the reactants and time taken to collect 30 cm3 of colourless gas.
Eksperimen I dan II telah dijalankan untuk mengkaji kesan perbezaan saiz pepejal X ke atas kadar
tindak balas. Jadual 10 menunjukkan bahan tindak balas dan masa yang diambil untuk mengumpul
30cm3 gas yang tidak berwarna.
II
I
5
Time /s
10 -functional diagram for the reaction between solid X and HCl 1
(a)(iv) -label (solid X/substance given eg. Zn/Mg/CaCO3, hydrochloric acid, 1
water) 1
-functional diagram to collect the gas
HCl
water
Zn
10. Diagram 10.1 shows the time taken for meat to cook using different size of beef.
Rajah 10.1 menunjukkan masa yang diambil untuk memasak daging menggunakan saiz daging lembu
yang berbeza.
Experiment
Isipadu gas (cm3 ) II : Acid and magnesium
20 powder
1. Your are required to prepare one namely ester by using ethanoic acid is one of the reactants. By using a
namely alcohol, describe one experiment to prepare the ester. In your description include the chemical
equation and observation involved.
Ester: ethylethanoate
Material: ethanol, etahanoic acid, water, concentrated sulphuric acid
Apparatus: Boiling tube / test tube, Bunsen burner, test tube holder, beaker
Procedure: 1. Pour 2 cm3 of ethanol into a boiling tube / test tube
2. Add 1 cm3 of ethanoic acid
3. Add 2 to 4 drops of concentrated sulphuric acid
4. Heat the mixture gently for about two minutes
5. Pour the mixture into a beaker containing water.
Observation: Sweet/ pleasant / fruity smell // insoluble in water
Chemical equation: CH3COOH + C2H5OH CH3COO C2H5 + H2O
2. Dehydration of alcohol
Diagram of set up of apparatus
1. Complete and functional
2. Labels of set up of apparatus correct
Ester Z
Ester Z
Diagram / Rajah 9
(a)(i) Name one alkene that has less than five carbon atoms.Write its molecular formula
Namakan satu alkena yang mempunyai kurang daripada lima atom karbon.Tulis formula molekulnya.
[2 marks]
(ii) Based on the answer in 9 (a) (i), state the name of alcohol X and compound Y.
Berdasarkan jawapan di 9 (a) (i), nyatakan nama bagi alkohol X dan sebatian Y. [2 marks]
(iii) Write the chemical equation and state the observation for the reaction between alcohol X and
potassium dichromate, K2Cr2O7 to produce compound Y that you named in (a) (ii).
Tuliskan persamaan kimia dan nyatakan pemerhatian bagi tindak balas antara alkohol X dan kalium
dikromat, K2Cr2O7 untuk menghasilkan sebatian Y yang anda namakan di (a) (ii). [3 marks]
(b) (i) By using alcohol X and compound Y that you named in (a) (ii), describe the preparation of ester Z in
the laboratory. In your description, include the chemical equation for the reaction.
Dengan menggunakan alkohol X dan sebatian Y yang anda namakan di (a) (ii), huraikan penyediaan
ester Z di dalam makmal. Dalam huraian anda, sertakan persamaan kimia bagi tindak balas itu.
[5 marks]
(ii) Alkene W can be prepared from alcohol X. Draw the set –up of apparatus for the preparation of the
alkene W. Alkena W boleh disediakan daripada alkohol X. Lukiskan susunan radas bagi penyediaan
alkena W itu. [2 marks]
(c) Table 9 shows the results of latex coagulation. Jadual 9 menunjukkan keputusan pengumpalan getah.
Functional diagram 1
Label 1……2
(c) Compound Y contains a lot of hydrogen ions 1
H+ ions neutralize the negative charge on the protein membranes 1
The particles collide and the protein membranes break 1
4. Alkane and alkene are two homologous series for hydrocarbon compounds.
(a) Explain the meaning of hydrocarbon compounds.
Hydrocarbon compounds are made up of carbon and hydrogen elements only.
(b) Butane and butene are member of alkane and alkene series respectively. Write down the
equation which represents complete combustion in air of
i) butane : 2C4H10 + 13O2 → 8CO2 + 10H2O
ii)butene : C4H8 + 6O2 → 4CO2 + 4H2O
(c) Draw the structural formula for all butene isomers and name the isomers you have drawn.
H H H H H H H H
│ │ │ │ │ │ │ │
H─ C ─ C ─ C ═ C ─ H H─C─ C ═ C─C─H
│ │ │ │
H H H H
But-1-ene But-2-ene
(d) Methane is the simplest member in the alkane series but ethene is the simplest member in
the alkene series. Explain why.
General formula of alkane is CnH2n+2 .
In methane, carbon atom forms four single covalent bond with hydrogen atoms which is stable.
General formula of alkene is CnH2n.
Ethene is the first member in alkene because they must have at least one double covalent bond between
carbon atoms in the molecules.
(e) Ethane and ethene can be differentiated by using aqueous bromine. State how this can take place.
Ethene reacts with aqueous bromine through addition reaction which decolourises aqueous bromine.
There is no reaction between ethane and aqueous bromine.
H H
Propan-2-ol
d. Table 1 shows the results of a test to differentiate between alkene Y and propane.
Procedure Observations
Bromine water is added to alkene Y Brown solution is decolourised
Bromine water is added to propane Brown colour remains
Explain why there is difference in these observations.
Because alkene Y is unsaturated hydrocarbon which undergo addition reaction with bromine. Propane is
saturated hydrocarbon which does not undergo addition reaction but substitution reaction.
6. Figure below shows the set-up of apparatus for the preparation of ethyl ethanoate from the reaction of
ethanol with ethanoic acid.
Liebig condenser
X
a On the Liebig condenser in figure above, mark ‘X’ to indicate the place where water flows in and Y’
where water flows out.
b Why is the mixture heated using a water bath ?
To give a uniform supply of heat to prevent the mixture from burning.
c (i) Name the reaction for the preparation of ethyl ethanoate.
Esterification
S
S
S S
S S
9. REDOXS
B. Describe an experiment to investigate oxidation and reduction in the change of iron(II) ions to iron(III)
ions and vice versa.
(i) Changing of Fe2+ ions to Fe3+ ions
Procedure:
1. Pour 2 cm3 of freshly prepared iron(II)sulphate solution into a test tube.
2. Using dropper, add bromine water drop by drop until no further changes are observed.
3. Heat slowly / gently
4. Add 3 drops of potassium hexacyanoferrate (II) solution / sodium hydroxide solution.
5. Dark blue precipitate // brown precipitate formed.
(ii) Changing of Fe3+ ions to Fe2+ ions
Procedure:
1. Pour 2 cm3 of iron(III)sulphate solution into a test tube.
2. Add half spatula of zinc / Mg powder to the solution.
3. Shake the mixture until no further changes are observed.
4. Filter the mixture.
5. Add 3 drops of potassium hexacyanoferrate (III) solution / sodium hydroxide solution into the filtrate.
6. Dark blue precipitate // green precipitate formed.
C Diagram 6 shows an apparatus set up to investigate the effect of three different metals A,B and C on the
rusting of iron. Rajah 6 menunjukkan susunan radas untuk mengkaji kesan tiga logam berbeza A,B, C
yang berlainan ke atas pengaratan besi.
1 2 3
Diagram 6
Target SPM (P2&P3) 2013 28
Table 6 shows the results of the experiment after three days
Jadual 6 menunjukkan keputusan eksperimen itu 6 selepas tiga hari
Test tube
1 2 3
Tabung uji
High intensity of blue Low intensity of pink Low intensity of
Observation colour colour. blue colour
Pemerhatian Keamatan warna biru Keamatan warna Keamatan warna
yang tinggi merah jambu yang biru yang rendah
rendah
Table 6
(a) (i) Rusting is a redoxs reaction. What is meant by redoxs reaction? [1 mark]
Pengaratan adalah satu tindak balas redoks. Apakah yang dimaksudkan dengan tindak balas redoks?
(ii) Write the half equation for the oxidation reaction in Test tube 1. [2 marks]
Tuliskan setengah persamaan bagi tindak balas pengoksidaan dalam Tabung uji 1.
(b) Based on the observation in Table 6: Berdasarkan pemerhatian dalam Jadual 6:
(i) Identify metals A, B and C. Kenal pasti logam A, B dan C. [3 marks]
(ii) Compare why there is different in the observation in Test tubes 2 and 3. [1 mark]
Bandingkan mengapa terdapat perbezaan pemerhatian dalam Tabung uji 2 dan 3.
(c) (i) Describe your answer in (b)(ii). Huraikan jawapan anda di (b)(ii). [3 marks]
(c) (ii)What is the change of oxidation number of iron in Test tube 3. [1 mark]
Apakah perubahan nombor pengoksidaan besi dalam Tabung uji 3.
Explanation Mark
No mark
C (a)(i) Oxidation reaction and reduction reaction that occur 1
simultaneously // at same time 1
(a)(ii) 1. Correct formulae of reactant and products 1
2. Balanced equation 1 2
Fe → Fe2+ + 2e
(b) (i) metal A= Siver / Ag // Copper / Cu 1
metal B = Zinc / Zn 1
metal C= Lead / Pb // Tin / Sn 1 3
(b) ii) Iron in test tube does 2 not rust but iron in test tube 3 rust 1 1
(c) (i) 1. Metal B / Zn is more electropositive than iron 1
2. Metal C / Pb / Sn is less electropositive than iron 1
3. Iron in test tube 3 is oxidized // Fe2+ formed 1 3
(c) (ii) 0 → +2 1 1
Total 11
Carbon X Carbon Y
Karbon X Karbon Y
Iron (II) sulphate solution Acidified potassium manganate(VII)
solution
Larutan ferum(II) sulfat
Larutan kalium manganat (VII) berasid
Dilute sulphuric acid
(i) State the name of the oxidizing agent in this Asid sulfurikNyatakan
reaction. cair nama agen pengoksidaan dalam
tindak balas ini. Acidified potassium manganate(VII) solution
(ii) Referring to the reaction that takes place at carbon X : Merujuk pada tindak balas yang berlaku di
karbon X : Write the half equation for the reaction. Tuliskan persamaan setengah untuk tindak
balas itu.
Fe2+ ------------- Fe3+ + e-
(iii) State one observation that occurred. Nyatakan satu pemerhatian yang berlaku.
Green solution turns to brown solution (purple to colourless)
(iv) Show the direction of the electron flow in Diagram. Tunjukkan arah pengaliran elektron dalam
Rajah From electrod carbon X to Y
(v) Referring to the reaction that takes place at carbon Y, calculate the oxidation number of manganese
in MnO4-. Merujuk pada tindak balas yang berlaku pada karbon Y, hitungkan nombor
pengoksidaan bagi mangan dalam MnO4-
X + 4 (-2) = -1
X + (-8) = -1
X = +7
(b) Diagram 6.2 shows the apparatus set-up to investigate the displacement of halogen
from its halide solution. Chlorine water was added to a test tube containing a
potassium iodide solution and organic solvent, 1,1,1-trichloroethane.
Rajah 6.2 menunjukkan susunan radas untuk mengkaji penyesaran halogen daripada larutan
halidanya. Air klorin ditambah ke dalam tabung uji yang mengandungi larutan kalium iodida dan
pelarut organik 1,1,1-trikloroetana.
Chlorine water
Air klorin
Purple
organic layer
1,1,1-trichloroethane Lapisan organik
Target SPM (P2&P3) 2013
1,1,1-trikloroetana 30
berwarna ungu
(i) Write the ionic equation for the reaction. Tuliskan persamaan ion bagi tindak balas itu.
Cl2 + 2I- ----------- I2 + 2Cl-
(ii) What is the function of chlorine water? Apakah fungsi air klorin? An oxidizing agent
(iii) State the change of oxidation number for iodine. Nyatakan perubahan nombor pengoksidaan bagi
iodin. -1 to 0
(iv) State the name of another reagent that can replace chlorine water. Nyatakan nama satu bahan uji lain
yang boleh menggantikan air klorin.
Bromine water
10. THERMOCHEMISTRY
10. A student carried out an experiment to determine the heat of displacement of copper for the reaction
between zinc and copper(ll) sulphate solution. In this experiment, excess zinc powder is added to 25cm 3
of 0.2mol/dm3 copper(ll) sulphate solution in a plastic cup. The temperatures of copper(ll) sulphate
solution before and after the addition of zinc powder are recorded
Initial temperature of copper sulphate solution = 28oC
The highest temperature of the solution after the addition of zinc = 37.5oC
(specific heat capacity of the solution, 4.2 Jg-1oC; the density of the solution, 1 gcm-3)
Seorang pelajar menjalankan satu eksperimen untuk menentukan haba penyesaran kuprum bagi
tindakbalas di antara zinc dan larutan kuprum sulfat. Dalam eksperimen ini serbuk zink berlebihan
ditambahkan kepada 25cm3 of 0.2mol/dm3 larutan kuprum sulfat dalam cawan plastik. Suhu larutan
kuprum sulfat sebelum dan selepas penambahan serbuk zink dicatatkan;
Suhu awal larutan kuprum sulfat = 28oC
Suhu tertinggi larutan selepas penambahan zinc = 37.5oC
( Muatan haba tentu bagi larutan, 4.2 Jg-1oC; ketumpatan larutan, 1 gcm-3 )
(a) What is meant by heat of displacement ? [1M]
Apakah yang dimaksudkan dengan haba penyesaran?
Heat of displacement is the heat change when one mole of a metal is displaced from its salt solution
by a more electropositive metal.
(b) What is the colour change of the copper(ll) sulphate solution in this reaction?
Apakah perubahan warna larutan kuprum sulfat dalam tindakbalas ini? [1M]
The intensity of blue solution ( copper(ll) sulphate solution ) in this reaction decreases until they
become colourless.
(c) Write an ionic equation for the reaction. Tuliskan persamaan ion untuk tindakbalas ini [1M]
Zn + Cu 2+ Zn 2+ + Cu
(d) Based on the results of this experiment, calculate Berdasarkan keputusan eksperimen ini, kirakan
(i) The number of mole of copper(ll) ions displaced. Bilangan ion kuprum yang dinyahcaskan.
Number of mole of copper(ll) ions
= MV
1000
= 2(25)
1000
= 0.005 mole. [2 marks]
Zn + Cu 2+
∆H = -199. 5 kJ/mol
Zn 2+ + Cu
2. (a) Table 5.1 shows the results obtained when cleaning agent L and cleaning agent M
are used to wash cloth in hard water and soft water.
Jadual 5.1 menunjukkan keputusan yang diperolehi apabila agen pencuci L dan agen pencuci M
digunakan untuk mencuci kain dalam air liat dan air lembut.
ICE CREAM
Ingredients:
Non-dairy milk, sugar, ethyl butanoate, ascorbic acid, cellulose gum and
tartrazine.
Product by:
Shukrov Company, Exp. Date : 02/09/13
Bangkong City. Net weight : 450g
KM 23, Rompin Muadzam Road
Diagram 5.2
(i) State one food additive used as thickening agent in the ice cream.
Nyatakan satu bahan tambah makanan yang digunakan sebagai agen pemekat dalam ais krim itu.
(ii) Determine the food aditive that cause hyper activities among children.
Tentukan bahan tambah makanan yang menyebabkan hiper aktif di kalangan kanak-kanak
(iii)What is the function of ethyl butanoate in the ice cream?
Apakah fungsi etil butanoat dalam ais krim itu?
(iv)Draw the structural formula of ethyl butanoate.
Lukiskan formula struktur bagi etil butanoat.
4
Total 11
3. (a) A patients suffered from tuberculosis that caused by a certain bacteria. What type of medicine that can
be used to treat the patient ? Seorang pesakit menghidap batuk kering yang disebabkan oleh
bakteria tertentu. Apakah jenis ubat yang boleh digunakan untuk merawat pesakit itu?
Explain why the patient must complete the whole course of the medicine that his doctor prescribes
to him even if he feels better. Terangkan mengapa pesakit tersebut mesti menghabiskan semua ubat
yang dipreskripsikan oleh doktor walaupun jika dia berasa sihat. [5 marks]
1. antibiotic
2. This is to make sure that all the bacteria are killed.
3. Otherwise, patient B may become ill again
4. bacteria may become more resistant to the antibiotic.
5. As a result, the antibiotic is no longer effective.
(b) Diagram 2 shows the structure of anion parts of a soap and a detergent. These anions consist of part A
and part B as shown in the diagram 2. Diagram 2 menunjukan struktur bagi bahagian anion bagi satu
sabun dan satu detergen. Anion-anion ini terdiri daripada bahagian A dan bahagian B seperti
ditunjukan dalam Rajah 2
Anion of a soap
Anion of a
detergent
Part A Part B
Diagram 2
You are given a piece of cloth stained with grease. Anda diberi sehelai kain yang terkena gris.
(i) Describe briefly the experimental procedure, observation and conclusion to prove the above statement.
Huraikan dengan ringkas prosedur experiment, pemerhatian dan kesimpulan untuk membuktikan
pernyataan di atas. [5 marks]
Procedure:
1. Two basins/beakers are filled with hard water.
2. Soap is added to one beaker and detergent is added to another beaker.
3. A piece of dirty cloth is placed into each beaker and agitated.
4. Observations:
Soap in hard water Detergent in hard water
1. cloth not clean 1. cloth clean
2. scum forms 2. no scum
3 water less dirty 3. water turns dirty
(any one pair)
5. Conclusion: detergent cleans stains more effectively than soap.
(ii) Explain how soap works in removing grease from a piece of cloth.
Terangkan bagaimana sabun bertindak dalam menanggalkan gris daripada sehelai kain. [6 marks]
1. soap particles dissolve in water and (reduce the surface tension of water)
/(water wet the cloth thoroughly)
2. the hydrophilic part dissolve in water while the hydrophobic part dissolves in
grease//diagram
3. During cleaning/rubbing/heating/scrubbing, grease is lifted off the surface
4. Hydrophobic part / soap anion surrounded the grease//diagram
5. Grease is broken up into small droplets/forming an emulsion//diagram
6. When rinsed, the grease droplet will be removed
4. (a) Ammonia which is used to produce ammonium fertilizer can be obtained through the Haber
process in industry. Ammonia yang digunakan dalam penghasilan baja ammonium boleh
diperolehi melalui proses Haber dalam industri.