LILAVATIBAI PODAR SENIOR SECONDARY SCHOOL (ISC)

First Terminal Examination: 2017-18 Subject: Chemistry/ Answer Key

Question1:
a. One mark each
a. sp3d, T shaped c. 8,6
b. Glucose and fructose d. methyl iodide, ethanol

b. One mark each

a. 0.01M Na2SO4 c. AB6C2
b. HI d. 0.093F

c. One mark each

A B
1 Ethylene diammine a Chelate
2 Ethanol + water b Azeotropic mixture
3 Vanadium pentoxide c Contact process
4 Sodium phenoxide + CO2 d Kolbe's Schmidt
d.
1. Assuming conc is constant
Thus R1/R2 = k1/k2
R2 = 3 R1 thus k1/k2 = 3 T1 = 293K T2 = 323K
Log (k2/k1) = Ea/2.303T (1/T1 – 1/T2) = 28819.18 Jmol-1 2 marks
2. (CH3)2 – C = CHCH3 and CH2 = C(CH3) – CH2CH3. ½ mark each
2-methyl but-2-ene is major product according to saytzeff rule. ½ mark each
3. Mg, Fe, Cis-paltin, Ca/Mg EDTA complex ½ mark each
4. Acetic acid there shows intermolecular hydrogen bonding 1 mark
Acetaldehyde does not show. 1 mark
Question 2:
a. (i) Tetraamminesulphatocobalt(III)nitrate ½ mark each
(ii) Mercury tetrathiocyanato-S cobaltate (III)
b. (i) K2[Zn(OH)4] (ii) Ni(CO)4 ½ mark each

OR
a. (i) potassium trioxalatoaluminate (III) ½ mark each
(ii) bromo bis(ethylenediammine)nitrito-Ncobalt(III)ion
b. (i) [Fe(H2O)6]SO4 (ii) Na3[Co(NO2)6] ½ mark each

Question 3:
a. HCHO + CH3CHO dil. NaOH HO- CH2- CH2 – CHO 1 mark
b. C6H3CHO + (CH3CO)2O C6H5CH = CH – COOH + CH3COOH 1mark
Question 4
W = At wt. x I x t / valency x 96500
1.45= 108 x 1.5 x t / 1 x 96500 t= 863.74s 1mark
Wcu/Wag = Ecu/Eag
Wcu/1.45 = (63.5/2)/ (108/1) WCu = 0.426g ½ mark
WZn/Wag = EZn/Eag
WZn/1.45 = (65.3/2)/ (108/1) WCu = 0.438g ½ mark

Question 5
a. PbS + 4O3 PbSO4 + 4O2 ½ mark reaction + ½ mark balancing
b. MnO2 + 2NaCl + 3H2SO4 MnSO4 + 2NaHSO4 + H2O + Cl2

Question 6 1 mark each

CHO HC = N-NHPh HC = N-NHPh
| NH2NHC6H5 | 2NH2NHC6H5 |
(CHOH)4 -H2O (CHOH)4 HC = N-NHPh
| | |
CH2OH CH2OH (CHOH)3
|
CH2OH

CHO CHO
| 5(CH3CO)2O |
(CHOH)4 (CHOCOCH3)4 + 5CH3COOH
| |
CH2OH CH2OCOCH3

Question 7
a. p=1, q=1, r=2
Rate law is R = k [A]1[B]1[C]2 1 mark
k = 2.08 x 10-4 / ([0.02][0.02][0.02]2) = 1300 mol-3L2s-1 1 mark
OR
a. k = 0.693/t1/2 = 5.77 x 10-3 per min 1 mark
For 90%
t = 2.303 / k log (100/10) = 399 min 1mark

Question 8
a.

1 mark
 b.
1 mark

Question 9
Po –P = weight of solute x molecular weight of solvent
Po molecular weight of solute x weight of solvent
4.579 – 4.559 = 8.45 x 18 = 348.25g 1 marks
4.579 m2 x 100

b. ∆Tf = X ∆Tb = 100.128

Kf = 1.86 K m -1
Kb = 0.512K m-1

∆Tb = Kb
∆Tf Kf

0.128 = 0.512 = 0.465 1 mark

∆Tf 1.86
Tf = 273 - 0.465 = 272.535K 1 mark

OR

a. ∏urea/ ∏ potassium sulphate = Curea/3Cpotassium sulphate

∏ potassium sulphate = 3.8 x 3 x 0.25/0.25 = 11.4 atm 1mark

b. 3.5 = 2 x 0.53 x 1000 x w2

74.5 X 700
W2 = 172.193 g 1 mark

c. π = i x C x R x T
4.6 = i x 0.1 x 0.0821 x 30 thus i = 1.86
α = i-1/ n-1
α = 1.86-1/2-1 = 0.867 or 86.7% 1 mark
Question 10
a. CHCl3 + 3KOH -3KCl CH(OH)3 HCOOK + H2O 1 mark
 b. CH3CH2Br + KNO2 CH3ONO + KBr 1mark
c. CH3CH2Cl + CH3COOAg CHCOOCH2CH3 + AgCl 1 mark

Question 11
a. dsp2, square planar, diamagnetic ½ mark each
b. Ionisation isomerism ½ mark
Add AgNO3 ½ mark
[PtCl2(NH3)4]Br2 : gives a pale yellow ppt ½ mark
[PtBr2(NH3)4Cl2 : gives a white ppt

Question 12
a. 3.5 = 2 x 98/6.023 x 1023 x a3
a3 = 2x98/3.5x6.023x1023 = 453pm 1mark
r = √3/4a = 0.433x 453= 196.14 pm 1marks
b. F-center defect. Anions are missing from the lattice points and their position is taken by
electrons. These electrons give colour to the compound due to excitation
1 mark
Question 13
a. CH3COCH3 + CH3MgCl H+/H2O (CH3)3COH + MgClOH ½ mark
tert-butyl alcohol ½ mark
b. C6H5OH PCl5 C6H5Cl CH3Cl/AnhyAlCl3 C6H5CH3 CrO2Cl2 C6H5COOH
2 marks
OR

a. C2H5OH + CH3COCl pyridine CH3COOC2H5 + HCl ½ mark

Ethylacetate ½ mark
b. C6H5OCH3 + conc. HNO3 Conc. H2SO4 o and p nitro anisole ½ + ½ mark

c. Lucas reagent test: ZnCl2 + conc HCl ½ mark

Propan-2ol turbidity after 5 min. Tert-butyl alcohol immediate turbidity. ½ mark

Question 14
a. K1 = 0.693/t1/2 = 1.925 x 10-3 min-1 1 mark
Log(k2/k1) = Ea/2.303R (1/T1 – 1/T2) thus k2 = 0.0681 min-1 1 mark
At 4500C
t = 2.303/k2 log (100/25) = 20.36 min 1mark

Question 15
a. Ammoniacal silver nitrate: Glucose gives silver mirror, sucrose does not. 1mark
b. Vit D and Vit K ½ mark each
c. CHO – (CHOH)4 – CH2OH + NH2OH HON = C – (CHOH)4 – CH2OH
1 mark.
Question 16
 a. (i) 52/6 g of Cr = 96500C
For 24000C; x = 52 x 24000/6 x 96500 = 2.155g 1 mark
(ii) 1.5 = 52 x 12.5 x t/ 6x96500 t= 1336.15s 1 mark
b. Cathode 3Ni2+ + 6e- 3Ni
Anode 2Al 2Al3+ + 6 e- ½ mark each
Ecell = Eocell – 0.059/n log[Al3+]2/ [Ni2+]3
= (-0.25 – (-1.66)) – 0.059/6 log (0.001)2/ (0.50)3
Ecell = 1.46V 1 mark
c. Nature of metal, conc of ions, temperature. Any 2; 1 mark
OR
a. ∧ ∞
∧ ∧
(NH4OH) = (NH4Cl) + (NaOH) - (NaCl) ∧
= 129.8 + 217.4 – 108.9 = 238.3 Scm2mol-1 1 mark
ά = 9.33/238.3 = 0.039 1 mark
b. Ecell = EoCell – 0.059/n log[Zn2+]/[Ag+]2
1.48 = (0.8+0.763) – 0.059/2 log (0.10)/[Ag=]2
[Ag+]2 = 1.536 x 10-4
[Ag+] = 1.247 x 10-2 M 2 marks
c. Connect two half cells, maintain electrical neutrality, minimize junction potential.
Any 2; 1 mark
Question 17
a. (i) sp3d3, pentagonal bi pyramidal 1 ½ mark

(ii) sp3d2, square pyramidal 1 ½ mark

b. (i) 2KI + H2O + O3 2KOH + I 2 + O2 1mark

(ii) 2KMnO4 + 5SO2 + 2H2O K2SO4 + 2MnSO4 + 2H2SO4 1 mark

OR
a. (i) sp3d2, square pyramidal 1 ½ mark

(ii) sp3, pyramidal 1½ mark

b. (i) 3Cl2 + 6NaOH 5NaCl + NaClO3 + 6H2O 1 mark

(ii) Na2SO3 + 2HCl 2NaCl + H2O + SO2 1 mark

Question 18
 a. Fehling solution test: Formaldehyde gives brick red ppt, benzaldehyde does not
Add alk. KMnO4 Benzaldehyde gives white ppt, formaldehyde does not
Any one 1 mark
b. A: Benzaldehyde , B: Benzyl alcohol , C: Benzoic acid , D: Benzylidine dichloride , E: Benzoyl
chloride Name: Cannizaro’s reaction ½ mark each
c. CH3COOH Ca(OH)2 (CH3CO)2Ca dry distillation/heat CH3COCH3 1 mark

OR

a. Fehling solution test or Tollens reagent test: Formic acid gives brick red ppt and silver mirror. Acetic
acid does not. Any one, 1 mark
b. A: Propanamide B :ethanamide C: ethanol D: ethanol E: Cyanohydrin F: Lactic acid
½ mark each
c. C6H5COOH NaOH C6H5COONa NaOH, CaO/heat C6H6 CH3Cl C6H5CH3
Anhy AlCl3
(O)/KMnO4 C6H5CHO 1 mark