TECHNOLOGICAL INSTITUTE OF THE PHILIPPINES gas that expands isothermally from 0.6 L to 1.

2 L at 0 oC
CHEMICAL ENGINEERING DEPARTMENT according to the following conditions:
PHYSICAL CHEMISTRY I 5. Against a constant external pressure of 0.9 atm.
QUIZ 1 A. - 54.68 J B. - 109.34 J
C. + 55.68 J D. + 109.34 J
INSTRUCTIONS: Select the correct answer by marking
the circle corresponding to the letter of your choice on the 6. Against a variable pressure which varies with the
sheet provided. Solutions (if applicable) are required, box volume according to the equation PV n = k. Below
your final answer. Strictly no erasures. Use pencil no.2 or are the data gathered from experiment:
black ball pen only. WARNING: SHADED ANSWERS Px103(atm) 194 134 100 79
WITHOUT CORRESPONDING SOLUTION WILL INCUR V (L) 0.6 0.8 1 1.2
DEDUCTIVE POINTS.
A. - 4.92 J B. - 11.07 J
C. - 7.38 J D. + 11. 07 J

7. Reversibly assuming gas is ideal.

A. + 157.41 J B. + 236.12 J
C. - 157.41 J D. - 236.12 J

8. Reversibly assuming gas obeys Van Der Waals’

equation of state where a = 0.86 (Pa - m 6)/mol2 and
b = 3.18x10-5m3/mol.
A. 8 in B. 5 in
C. 4 in D. 10 in

9. Calculate the minimum work needed

necessary to compress 20 g of O 2 from 10
to 5 liters at 0oC. How much heat is
evolved in the process.
A. + 984 J B. + 236 J
C. - 984 kJ D. - 236 J

10. Two liters of N2 at 0oC and 5 atm pressure are

expanded isothermally and reversibly until the
confining pressure is 1 atm. Assuming the gas to
LINKED PROBLEMS: be ideal, calculate the work for the expansion.
A reversible non - flow (closed) process occurs from A. + 390 cal B. + 1086 J
which work is 9.4 BTU. If the pressure varies as (P = -V 2 + C. - 390 cal D. - 1086 J
100/V) in psia, where V is in ft3 and P1 = 46 psia.
1. Find V2.
A. 1.18 ft3 B. 1.6 ft3
C. 2.11 ft3 D. 3.08 ft3

2. Find P2.
A. 83.35 psia B. 69.94 psia
C. 42.94 psia D. 4.64 psia

LINKED PROBLEMS 3 - 4:
A group of 50 persons attended a secret meeting in a
room which is 12 meters wide by 10 meters long and a
ceiling of 3 meters. The room is completely sealed off and
insulated. Each person gives off 150 kcal per hour of heat
and occupies a volume of 0.2 cubic meter. The room has
an initial pressure of 101.3 kPa and a temperature of
16oC.
3. Calculate the heat exchanged in the system after
10 minutes.
A. 5230 kJ B. 298.75 kJ
C. 3000 kJ D. 1250 kJ

4. Calculate the temperature in the system after 10

minutes.
A. 87.38oC B. 20.08oC
C. 34.0oC D. 25.79oC

LINKED PROBLEMS 5 – 8:
Calculate the work done by a sample of 0.1 mole of Neon
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