TECHNOLOGICAL INSTITUTE OF THE PHILIPPINES LINKED PROBLEMS 8 – 10

CHEMICAL ENGINEERING DEPARTMENT Using the data given below for saturated steam, estimate
CHEMISTRY FOR ENGINEERS ∆S for the following process:
PHYSICAL CHEMISTRY II (1.oo kg liquid water, 250OC)  (1.00 kg saturated
steam, 250OC)
FINAL EXAM Temperatur Pvap vliq vgas
e (oC) (kPa) (cm3/g) (cm3/g)
INSTRUCTIONS: Select the correct answer by marking 248 3844.9 1.247 51.81
the circle corresponding to the letter of your choice on the 252 4113.7 1.265 48.33
sheet provided. Solutions (if applicable) are required, box
your final answer. Strictly no erasures. Use pencil no.2 or 8. Using the Clapeyron equation
black ball pen only. WARNING: SHADED ANSWERS A. – 3162.77 J/K B. – 3397.83 J/K
WITHOUT CORRESPONDING SOLUTION WILL INCUR C. 53.84 J/K D. 3280 J/K
DEDUCTIVE POINTS.
9. Using the Clausius-Clapeyron equation.
1. In the reaction; N2 + O2  2NO, increasing the A. 4080 J/K B. 3397.83 J/K
pressure will result in C. 16.78 J/K D. – 254.18 J/k
A. shifting the B. shifting the
equilibrium equilibrium 10. Which value is more accurate, (a) or (b)?
towards right towards left A. Clapeyron B. Both have the
C. no change in D. none of these equation same value
equilibrium C. Clausius D. NOTA
condition Clapeyron
equation
2. Gibbs free energy at constant pressure and
temperature under equilibrium conditions is 11. A 1.00 L sample of ethanol (C 2H5OH) at 0.00°C
A. infinity B. maximum were subjected to a pressure of 100 atm, by how
C. 0 D. minimum much would its Gibbs free energy change? The
densities of ethanol at 25.00°C and 0.00°C are
3. If the vapour pressure at two temperatures of a 0.785 g cm3 and 0.806 g cm3, respectively.
solid phase in equilibrium with its liquid phase are A. 1 kJ B. 100 kJ
known, then the latent heat of fusion can be C. 10 kJ D. 1000 kJ
calculated by the
A. Maxwell's B. Clausius – LINKED PROBLEMS 12 – 13
equation Clapeyron At 630°C and a pressure at equilibrium of 1.00 atm, SO3
equation is 33.1% dissociated into SO2 and O2. Calculate the
C. Van Laar D. Nernst equation equilibrium constant for the following reactions at 630°C:
equation 12. 2SO3  SO2 + 0.5O2
A. 0.0483 B. 1.12x10-3
4. The freezing point of a liquid decreases when the C. 0.188 D. 0.0352
pressure is increased, if the liquid
A. contracts B. does not change 13. SO2 + 0.5O2  2SO3
in volume A. 6.09 B. 5.33
C. expands D. either A, B and C C. 7.14 D. 4.26
5. The degrees of freedom at the triple point is LINKED PROBLEMS 14 – 15
A. 0 B. 1 When the temperature becomes sufficiently high, water
C. 2 D. 3 vapor starts to decompose into hydrogen gas and oxygen
gas according to
6. Pick out the wrong statement pertaining to the 2H2O(g)  2H2(g) + O2(g)
decomposition of PCl5 represented by, PCl5  Using the following data, and assuming that 6CP is
PCl3 + Cl2. Degree of dissociation of PCl5 will constant for this reaction and has an effective value of
A. becrease on B. Increase on ∆CP = 18.88 J/mol – K over the temperature range in
addition of Cl2. addition of an question, calculate:
inert gas at
constant
pressure.
C. decrease on D. none of these 14. The value of the decomposition constant at 1000 K
increasing the
A. 6.23x106 B. 4.40x1019
pressure
C. 7.6x10-21 D. 9.49x10-12
7. Equilibrium constant decreases as the temperature
15. The percent decomposition of water vapor at 1000
A. increases, for an B. increase, for an
K and one bar total pressure.
exothermic endothermic
A. 2.45% B. 0 %
C. decreases, for an D. none of these
C. 3.91% D. 82.7%
exothermic

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LINKED PROBLEMS 16 – 19
At 250°C, K = 1.804 for the reaction
PCl5(g) PCl3(g) + Cl2(g)
16. If 0.10 mole of PCl5 is held at 250°C in a 2-
liter flask, how much Cl2 is formed?
A. 0.0335 mol B. 1.60 mol
C. 0.366 mol D. 0.0586 mol

17. How much PCl5 must be added to a 1-liter

vessel, held at 250°C, in order to obtain 0.10
mole of Cl2?
A. 0.366 mol B. 0.0412 mol
C. 0.0137 mol D. NOTA

18. Under what pressure must an equimolar

mixture of Cl2 and PCl3 be kept so that at
equilibrium
the partial pressure of PCl5 is 1.00 atm?
A. 1.50 bar B. 2.60 bar
C. 0.050 bar D. 3.72 bar

19. The degrees of freedom at the critical point is

A. 0 B. 1
C. 2 D. 3

20. How many subjects will you fail this semester?

A. None B. 3
C. 1 D. All

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