Technological Institute of the

Compressor 3

∆ H 103
∆ H 101
T =560 ℃
T =550 ℃
P=1 atm

Equipment Type Compressor

Equipment Number C-102 A/B
Operating Temperature 550 ℃
Operating Pressure 1 atm

Energy Balance for Compressor 2

❑ ❑
∆ H = ∑ ni (∆ H t )−∑ ni (∆ H t )
outlet inlet

Substances Inlet Outlet

n H ¿(kJ/hr) n H out (kJ/hr)
(kmol/hr) (kmol/hr)
BUTANE 3.1587 262,063.439 H10 3.1582 6,522.9226 H10
0 1a
3a

BUTENE 12.2891 884,874.814 H10 12.2891 21,950.1953 H10

0 1b
3b

BUTADIEN 0.5120 34,021.0671 H10 0.5120 831.8936 H10

1c
E 3c

H2O 5.2198 98,651.3363 H10 5.2198 2,040.1533 H10

 Technological Institute of the

1d 3d

CO2 0.1662 3,960.4598 H10 0.1662 85.1070 H10

1e
3e

H2 8.2954 127,630.434 H10 8.2954 2,460.3041 H10

8 1f
3f

O2 0.4222 7,012.0634 H10 0.4222 143.1493 H10

1g
3g

N2 12.0392 188,775.036 H10 12.0391 3,731.4487 H10

1 1h
3h

Inlet

kJ
∆ H S−101 =1,606,988.6505
hr

Outlet

∆ H S−103 =n H S−103 a+ n H S−103 b+ n H S−103 c + n H S−103d + n H S +n H S −103f + n H S−103 g +n H S −103 h

103e

833.15
H S −103a=n ∫ C p dT + ∆ H f =3.1582 ¿ ¿
823.15

833.15
H S −103b=n ∫ C p dT + ∆ H f =12.2891 ¿ ¿
823.15

833.15
H S −103c =n ∫ C p dT +∆ H f =0.5120 ¿ ¿
823.15
 Technological Institute of the

833.15
H S −103d =n ∫ C p dT + ∆ H f =5.2198 ¿ ¿
823.15

833.15
H S −103e =n ∫ C p dT +∆ H f =0.1662 ¿ ¿
823.15

833.15
H S −103f =n ∫ C p dT + ∆ H f =127,630.4348 ¿¿
823.15

833.15
H S −103g =n ∫ C p dT + ∆ H f =0.4222 ¿¿
823.15

833.15
H S −103h=n ∫ C p dT + ∆ H f =12.0391 ¿ ¿
823.15

∆ H S−103 =n H S−103 a+ n H S−103 b+ n H S−103 c + n H S−103d + n H S−103 e +n H S−103f + n H S−103 g +n H S −103 h

kJ kJ kJ kJ kJ
¿−390,747.0596 + 153 ,144.1578 +56,762.7015 +−124,279.0116 +−65,316.1044 +3
hr hr hr hr hr
kJ
¿ 37,735,320.87
hr

∆ H =( ∆ H S −103 ) −( ∆ H S −101 )

kJ kJ
¿ 37,735,320.87
hr
−1,067,220.3366
hr ( )
kJ hr
¿ 36,668,100.53 ×
hr 3600 s
 Technological Institute of the

¿ 10,185.5835 kW ( power of compressor 3)

Dehumidifier

Dehumidifier

Equipment Type Heat Exchanger

Equipment Number DH-101
Operating Temperature 34 ℃
Operating Pressure 1 atm

Energy Balance for Dehumidifier

 Technological Institute of the

❑ ❑
∆ H = ∑ ni (∆ H t )−∑ ni (∆ H t )
outlet inlet

Substances Inlet Outlet

n H ¿(kJ/hr) n H out (kJ/hr)
(kmol/hr) (kmol/hr)
O2 10.4457 0.0000 H1a 10.4457 -27.7740 H104a
N2 39.2957 0.0000 H1b 39.2957 103.6667 H104b
Inlet

kJ
∆ H 1=0
hr

Outlet

∆ H S−104 =nH S −104a + nH S−104 b

307.06
H 104 a=n ∫ C p dT +∆ H f =10.4457 ¿ ¿
307.15

307.06
H 104 b=n ∫ C p dT +∆ H f =39.2957 ¿ ¿
307.15

kJ kJ kJ
∆ H 104 =−27.7741 +−103.6660 =−131.4401
hr hr hr

∆ H =( ∆ H 104 )−( ∆ H 1 )

kJ kJ
¿−131.4401
hr
−0( )
hr
 Technological Institute of the

kJ hr
¿−131.4401 ×
hr 3600 s

¿−0.0365 kW ( power of dehumidifier )

Compressor 4

∆ H 105
∆ H 104
T =33.91 ℃
T =33.91 ℃
P=1 atm

Equipment Type Compressor

Equipment Number C-103A/B
Operating Temperature 33.91 ℃
Operating Pressure 1 atm

Energy Balance for Compressor 4

❑ ❑
∆ H = ∑ ni (∆ H t )−∑ ni (∆ H t )
outlet inlet

Substances Inlet Outlet

 Technological Institute of the

n H ¿(kJ/hr) n H out (kJ/hr)

(kmol/hr) (kmol/hr
)
O2 10.4457 0.0000 H104a 10.3025 10.4457 H105a
N2 39.2957 0.0000 H104b 38.7569 39.2957 H105b

Inlet

kJ
∆ H S−104 =0
hr

Outlet

kJ
∆ H S−105 =0
hr

∆ H =( ∆ H S −105 ) −( ∆ H S −104 )

kJ kJ
¿0
hr ( )
− 0
hr

kJ hr
¿0 ×
hr 3600 s

¿ 0 kW (power of compressor 3)
 Technological Institute of the

Reactor 2 – Oxidative Dehydrogenation

T =33.91 ℃ P=1atm

Fixed Bed
Reactor
T =560 ℃ P=1 atm

Equipment Type Reactor

Equipment Number R-102
Operating Temperature 450 ℃
Operating Pressure 1 atm
Heat of Reaction -10.924 kJ / mole
Type of Reaction Exothermic

Energy Balance for Rea ctor 1- Oxidative Dehydrogenation

 Technological Institute of the

❑ ❑
∆ H = ∑ ni (∆ H t )−∑ ni ( ∆ H t ) + ¿ ∆ H rxn ¿
outlet inlet

Substances Inlet Outlet

n H ¿(kJ/hr) n H out (kJ/hr)
(kmol/hr) (kmol/hr)
BUTANE 3.1587 6,522.9226 H7a 3.1587 - H8a
69,151.3062

BUTENE 12.2891 21,950.1953 H7b 4.0771 - H8b

77,236.7092

BUTADIEN 0.5120 831.8936 H7c 7.8117 - H8c

E 135,234.448
3

H2O 5.2198 2,040.1533 H7d 16.1694 - H8d

68,384.3142

CO2 0.1662 85.1070 H7e 3.8161 - H8e

21,108.4203

H2 8.2954 2,460.3041 H7f 8.2954 - H8f

26,984.8296

O2 10.8679 180,517.766 H7g 1.7432 -6,429.3701 H8g

7

N2 12.4137 194,648.077 H7h 51.3349 - H8h

 Technological Institute of the

4 173,659.511
4

Inlet

kJ
∆ H S−103+S−105 =1,019,345.0969
hr

Outlet
∆ H S−106 =n H S−106 a +n H S−106 b +n H S −106 c + n H S−106 d +n H S −106e + n H S−106 f +n H S−106 g+ n H S−106 h

723.15
H S −106a=n ∫ C p dT + ∆ H f =¿ ¿
823.15

723.15
H S −106b=n ∫ C p dT + ∆ H f =4.0771 [(−18,943.96329+−540 ) ]=−79,438.0667 kJ / hr
823.15

723.15
H S −106c =n ∫ C p dT +∆ H f =7.8117 ¿¿
823.15

723.15
H S −106d =n ∫ C p dT + ∆ H f =1 6.1694 ¿ ¿
823.15

723.15
H S −106e =n ∫ C p dT +∆ H f =3.8161 ¿ ¿
823.15

723.15
H S −106f =n ∫ C p dT +∆ H f =8 .2954 ¿ ¿
823.15
 Technological Institute of the

723.15
H S −106g =n ∫ C p dT + ∆ H f =1.7432¿ ¿
823.15

723.15
H S −106h=n ∫ C p dT + ∆ H f =51.3349 ¿ ¿
823.15

∆ H S−106 =n H S−106 a +n H S−106 b +n H S −106 c + n H S−106 d +n H S −106e + n H S−106 f +n H S−106 g+ n H S−106 h

kJ
¿−461,149.0616
hr

∆ H =( ∆ H S −106 ) −( ∆ H S−103 + ∆ H S−105 )

kJ kJ
¿−461,149.0616
hr (
− 1 , 019 ,345.097
hr )
kJ hr
¿−1,480,494.159 ×
hr 3600 s
¿−411.2484 kW ( power of reactor 2)