Stream 31 and 37

T31= 64.7 °C

Component Heavy key/Light Key xi(Feed)

CH3OH Light key 0.887
H2O Heavy key 0.123

Vapor Pressure (Antoine) Equation Constants

log p = A - [B/(T+C)]

Component A B
CH3OH 8.07247 1574.99
H2O 7.94917 1657.462

Bubble point calculation

Component Heavy key/Light Key xi(Bottom) pisat(bar) Kc = pisat/ptotal
CH3OH Light key 0.003 3.54358736 3.543587361319
H2O Heavy key 0.997 1.01314054 1.013140544954
Total

Dew Point Calculation

Component Heavy key/Light Key yi(Top) pisat(bar)
CH3OH Light key 0.997 1.02082936 1.020829363325
H2O Heavy key 0.003 0.24681009 0.246810092399
Total
 T37= 100 °C p= 1 bar

xiF(kmol/hr) yi(Top) yiD(kmol/hr) xi(Bottom) xiB(kmol/hr)

6155.07 0.997 6151.72 0.003 20.08
864.36 0.003 16.43 0.997 6173.98

T=100°C T=64.7°C
C log px px (mmHg)
sat
log px pxsat(mmHg)
238.86 3.4246 2658.0449 2.8841 765.7241
227.02 2.8808 759.9567 2.2675 185.1323

αi=pisat/pjsat αixi Kc=1/∑αixi yi=Kcαixi

3.49762664 0.0105 0.0104
1 0.9970 0.9926 0.9896
Total 1.0075 Total 1.0000

αi=pisat/pjsat yi/αi Kc=∑yi/αi xi=(yi/αi)/Kc

4.1361 0.2410 0.9877
1.0000 0.0030 0.2440 0.0123
Total 0.2440 Total 1.0000