09931162C FIMS Hardware Guide

ATOMIC SPECTROMETRY
FIMS
FLOW INJECTION MERCURY SYSTEM
Hardware Guide
FIMS
Hardware Guide
2 . FIMS Hardware Guide
Release History
Part Number Release Publication Date
09931162 C October 2015
Any comments about the documentation for this product should be addressed to:
User Assistance
PerkinElmer
710 Bridgeport Avenue
Shelton, CT 06484-4794
U.S.A.
Or emailed to: info@perkinelmer.com
Notices
The information contained in this document is subject to change without notice.
Except as specifically set forth in its terms and conditions of sale, PerkinElmer makes no
warranty of any kind with regard to this document, including, but not limited to, the
implied warranties of merchantability and fitness for a particular purpose.
PerkinElmer shall not be liable for errors contained herein for incidental consequential damages in
connection with furnishing, performance or use of this material.
Copyright Information
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translated into any language without the prior, written permission of PerkinElmer, Inc.
Copyright © 2015 PerkinElmer, Inc.
Trademarks
Registered names, trademarks, etc. used in this document, even when not specifically marked as such,
are protected by law.
PerkinElmer is a registered trademark of PerkinElmer, Inc.

.3
Table of Contents
Introduction ...................................................................................... 7
About This Manual ................................................................................... 9
About This Handbook......................................................................... 9
Using this Handbook .......................................................................... 9
Before You Start .................................................................................... 10
Other Useful Handbooks for the FIMS Analysis System ............................. 11
Conventions Used in this Manual ............................................................. 12
Notes, cautions and warnings ........................................................... 12
Translation of Warnings .......................................................................... 15
Safety Practices .............................................................................. 31

Overview ............................................................................................... 33
Precautions for Instrument ..................................................................... 34
Precautions for Customers ...................................................................... 36
General Operating Conditions.................................................................. 37
Electrical Safety ..................................................................................... 38
UV Radiation .......................................................................................... 40
Waste Disposal ...................................................................................... 41
Sodium Tetrahydroborate ....................................................................... 42
Chemicals .............................................................................................. 43
Compressed Gases ................................................................................. 44
Toxic Fumes .......................................................................................... 45
EMC Compliance .................................................................................... 46
EMC Directive .................................................................................. 46
FCC Rules and Regulations ............................................................... 46
Pollution Degree .............................................................................. 46
WEEE Instructions for PerkinElmer Products ............................................ 47
Decontamination and Cleaning ................................................................ 48
Decontamination ............................................................................. 48
Cleaning the Instrument .................................................................. 48
Warning Signs on the Instrument ............................................................ 49
Warning Labels ...................................................................................... 50
References for Laboratory Safety Practice ................................................ 51
System Description ......................................................................... 53

Introduction ........................................................................................... 55
The FIMS Spectrometer .......................................................................... 56
The FIMS Control System ................................................................. 56
Components on the Front Panel of the FIMS ..................................... 56
Components on the Rear Panel of the FIMS ...................................... 57
Flow System Components ................................................................ 59
Technical Data ....................................................................................... 64
The Flow Injection / Mercury Cold Vapor Technique ................................. 66
The Principle of the Flow Injection Technique.................................... 66
Principle of the Mercury Cold Vapor Technique .................................. 67
Amalgam Technique ........................................................................ 68
Installing the FIMS Analysis System ............................................. 69

Unpacking and Checking the Spectrometer .............................................. 71
When the spectrometer arrives......................................................... 71
Before you or the service engineer installs the spectrometer .............. 71
If the service engineer installs the instrument ................................... 71
Sitting the Spectrometer and the Accessories ........................................... 72

Sitting Accessories ........................................................................... 72
Sitting the Computer and Printer ....................................................... 72
Carrier Gas Connections .......................................................................... 73
Electrical Connections ............................................................................. 74
Communication Cable Connections .......................................................... 75
Line Power Connections .......................................................................... 77
Installing Tubing System Components ..................................................... 79
Tubing Configurations ...................................................................... 79
Tube-Connector Key ......................................................................... 79
Changing Fluid System Components When Changing Reductants ........ 79
Fitting the Pump Tube to the Magazine ............................................. 81
Fitting the Pump Magazine onto the Pump ......................................... 82
Adjusting the Flow ........................................................................... 83
FIAS–Valve Connections ................................................................... 84
Assembling the Manifold ................................................................... 85
FIMS-Cell Connections ............................................................................ 86
Starting Up the System..................................................................... 86
Setting Pump Parameters: ................................................................ 87
Laboratory Requirements ........................................................................ 89
Summary of Requirements ............................................................... 89
Environmental Conditions ................................................................. 89
Operating ........................................................................................ 89
Space Requirements for a FIMS Analysis System ................................ 90
Carrier Gas ...................................................................................... 91
Maintenance .................................................................................... 93
PerkinElmer Service ................................................................................ 95
Checklists for Regular Maintenance Tasks ................................................ 96
General Preventative Maintenance .................................................... 96
Spectrometer Maintenance ...................................................................... 97
Fluid System Maintenance ....................................................................... 98
FIMS-Cell Maintenance ............................................................................ 99
Measuring the Absorbance of the FIMS-Cell Windows ......................... 99
Removing the FIMS-Cell from the Spectrometer ................................. 99
Installing the FIMS-Cell in the Spectrometer .................................... 100
Removing the Windows from the FIMS-Cell ..................................... 100
Fitting the Windows from the FIMS-Cell ........................................... 100
Cleaning the Windows .................................................................... 100
Cleaning the FIMS-Cell ................................................................... 101
Gas/Liquid Separator and Manifold Maintenance ..................................... 102
Cleaning Gas/Liquid Separator and Manifold .................................... 102
Changing the Separator Filter ......................................................... 102
FIAS-Valve Maintenance........................................................................ 103
Cleaning the FIAS-Valve ................................................................. 103
Removing the FIAS-Valve from the Pump Unit ................................. 103
Fitting the FIAS-Valve to the Pump Unit........................................... 103
Dismantling the FIAS-Valve............................................................. 104
Reassembling the FIAS-Valve .......................................................... 105
Carrier Gas System Maintenance ........................................................... 106
Nonreturn Valve ............................................................................. 106
Changing the Mercury Filter .................................................................. 107
Changing the Air Filter .......................................................................... 109
Changing the Source Lamp ................................................................... 110
Changing the Fuse ................................................................................ 112
.5
Parts .............................................................................................. 115

Equipment Provided ............................................................................. 117
Replacement Parts ............................................................................... 119
Spectrometer Parts ........................................................................ 119
Carrier Gas System Parts................................................................ 119
FIAS-Valve Parts ............................................................................ 120
Index .................................................................................................. 127
I ntroduction
Introduction . 9
About This M anual

About This Handbook
This handbook FIMS: Installation, Maintenance, System Description, is an integral part of the
mercury analyzer system. It describes installation and maintenance procedures that you can
perform yourself. Other sections include a description of the laboratory requirements for
correct installation and use of the instrument and a description of the FIMS system and how
it works. Appendices contain lists of the equipment that is provided and lists of replacement
parts.
If you find an error in this handbook or have any comments or suggestions, please tell us so
that we can correct the mistake or otherwise improve the handbook. Our address is on the
inside of the front cover.
Using this Handbook

Use the tables of contents at the beginning of this user guide and the index at the rear of the
handbook to find the sections you require quickly.
This handbook contains detailed descriptions of procedures. Many sections start with a
summary of the procedures described in that section. Once you are thoroughly familiar with
the instrument, you may only need to refer to the summaries for the correct order of more
frequent procedures, and detailed instructions for less frequent procedures. Until you are
familiar with the system, read the relevant section completely, from the beginning.
This hardware guide is divided into following chapters:

Chapter 1 Introduction
This chapter contains a brief introduction on the instrument, the conventions and warnings
used in the manual.
Chapter 2 Safety Practices
Important safety information is provided in this chapter.
Chapter 3 System Description
This chapter contains information on the components of the instrument, how it works and
instrument specifications.
Chapter 4 Installing the FIM S Analysis System
This chapter contains installation information.
Chapter 5 M aintenance
Maintenance and cleaning procedures for the various components of your instrument are
provided.
Chapter 6 Parts
This chapter contains spare parts information.
Before You Start

Before you install or use your spectrometer, and in order to get the best results, you should
be familiar with all of the system components and how to use them. You should also be
aware of the safety procedures in force in your laboratory especially those concerning atomic
spectroscopy instruments. Read the handbooks supplied with the instruments before you
start.
Introduction . 11
Other Useful Handbook s for the FI M S Analysis

System
• FIMS Software Guide
It describes the procedures you need to execute to set up and perform mercury
determinations using the FIMS analysis system.
• S10 Autosampler User Documentation (if applicable).

Describes installation and maintenance procedures for the S10 Autosampler.
• Flow Injection Mercury / Hydride Analyses: Recommended Analytical Conditions and

General Information.
This gives advice on instrument settings, analytical procedures and techniques for flow
injection analyses in general.
See also the FIMS Recommended Conditions window in the software.

Conventions Used in this M anual

Normal text is used to provide information and instructions.
Bold text refers to text that is displayed on the screen.
UPPERCASE text, for example ENTER or ALT, refers to keys on the PC keyboard. '+' is used
to show that you have to press two keys at the same time, for example, ALT+F.
All eight digit numbers are PerkinElmer part numbers unless stated otherwise.
Notes, cautions and w arnings

Three terms, in the following standard formats, are also used to highlight special
circumstances and warnings.
NOTE: A note indicates additional, significant information that is provided with some procedures.
Introduction . 13
CAUTION We use the term CAUTION to inform you about situations that could
result in serious damage to the instrument or other equipment. Details
about these circumstances are in a box like this one.
D Caution (Achtung)
Bedeutet, daß die genannte Anleitung genau befolgt werden muß, um
einen Geräteschaden zu vermeiden.
DK Caution (Bemærk)
Dette betyder, at den nævnte vejledning skal overholdes nøje for at
undgå en beskadigelse af apparatet.
E Caution (Advertencia)
Utilizamos el término CAUTION (ADVERTENCIA) para advertir sobre
situaciones que pueden provocar averías graves en este equipo o en
otros. En recuadros éste se proporciona información sobre este tipo de
circunstancias.
F Caution (Attention)
Nous utilisons le terme CAUTION (ATTENTION) pour signaler les
situations susceptibles de provoquer de graves détériorations de
l'instrument ou d'autre matériel. Les détails sur ces circonstances
figurent dans un encadré semblable à celui-ci.
I Caution (Attenzione)
Con il termine CAUTION (ATTENZIONE) vengono segnalate situazioni
che potrebbero arrecare gravi danni allo strumento o ad altra
apparecchiatura. Troverete informazioni su tali circostanze in un
riquadro come questo.
NL Caution (Opgelet)
Betekent dat de genoemde handleiding nauwkeurig moet worden
opgevolgd, om beschadiging van het instrument te voorkomen.
P Caution (Atenção)
Significa que a instrução referida tem de ser respeitada para evitar a
danificação do aparelho.
We use the term WARNING to inform you about situations that could
result in personal injury to yourself or other persons. Details about
these circumstances are in a box like this one.
WARNING
D Warning (Warnung)
Bedeutet, daß es bei Nichtbeachten der genannten Anweisung zu einer
Verletzung des Benutzers kommen kann.
DK Warning (Advarsel)
Betyder, at brugeren kan blive kvæstet, hvis anvisningen ikke
overholdes.
E Warning (Peligro)
Utilizamos el término WARNING (PELIGRO) para informarle sobre
situaciones que pueden provocar daños personales a usted o a otras
personas. En los recuadros como éste se proporciona información
sobre este tipo de circunstancias.
F Warning (Danger)
Nous utilisons la formule WARNING (DANGER) pour avertir des
situations pouvant occasionner des dommages corporels à l'utilisateur
ou à d'autres personnes. Les détails sur ces circonstances sont
données dans un encadré semblable à celui-ci.
I Warning (Pericolo)
Con il termine WARNING (PERICOLO) vengono segnalate situazioni
che potrebbero provocare incidenti alle persone. Troverete
informazioni su tali circostanze in un riquadro come questo.
NL Warning (Waarschuwing)
Betekent dat, wanneer de genoemde aanwijzing niet in acht wordt
genomen, dit kan leiden tot verwondingen van de gebruiker.
P Warning (Aviso)
Significa que a não observância da instrução referida poderá causar
um ferimento ao usuário.
Introduction . 15
Translation of W arnings
Introduction . 17
Introduction . 19
Introduction . 21
Introduction . 23
Introduction . 25
Introduction . 27
Introduction . 29
Safety P ractices
Safety Practices . 33
Overview
This chapter describes the general safety practices and precautions that must be observed
when operating the FIMS.
This advice is intended to supplement, not supersede, the normal safety codes in the user's
country. It is also a supplement to the PerkinElmer standard Safety and Health Policy. The
information provided does not cover every safety procedure that should be practiced.
Ultimately, maintenance of a safe laboratory environment is the responsibility of the analyst
and the analyst's organization.
Please consult all manuals supplied with the FIMS and accessories before you start working
with the instrument. Carefully read the safety information in this chapter and in the other
manuals supplied. When setting up the instrument or performing analyses or maintenance
procedures, strictly follow the instructions provided.
This equipment requires no specified inspection or preventive maintenance to ensure the

continuous functioning of its safety features.
34 FIMS Hardware Guide
Precautions for I nstrum ent
Be sure that all instrum ent operators read and understand

the precautions listed below . I t is advisable to post a copy of
the precautions near or on the instrum ent shelf.
WARNING
Veillez à ce que tous les opérateurs d'instrum ents aient lu et

com pris les précautions qui suivent. I l est conseillé de placer
une copie des précautions à prox im ité de l'instrum ent ou
AVERTISSEMENT
directem ent sur celui-ci.
Do not operate the instrum ent w ith any covers or parts

rem oved. Disconnect the power cord from the AC line power wherever
the cover is removed.
WARNING
Ne faites pas fonctionner l'instrum ent lorsque les capots ou
certaines pièces ont été retirés.
Déconnectez le cordon d'alimentation de l'alimentation CA dès que le
capot est retiré.
AVERTISSEMENT
Do not attem pt to m ak e adjustm ents, replacem ents or

repairs to this instrum ent ex cept as described in the
accom panying user docum entation.
WARNING
Ne pas essayer de faire des ajustements, remplacements ou
réparations à cet instrument, sauf tel que décrit dans la
documentation d'accompagnement de l'utilisateur.
AVERTISSEMENT
Dispose of w aste in accordance w ith the regulations

applicable to your locality, state and/ or country.
WARNING
Conform ém ent aux pratiques de sécurité des laboratoires,

les substances répandues doivent être nettoyées dès que le
déversem ent se produit et être élim inées.
AVERTISSEMENT
The protection provided by this equipm ent m ay be im paired if

the equipm ent is used in a m anner not specified by
WARNING P erkinElm er.
La protection fournie par cet équipement risque d'être moins

efficace si l'équipement fait l'objet d'une utilisation différente
de celle mentionnée par PerkinElmer.
AVERTISSEMENT
The following precautions must be observed when using the FIMS:
• Be sure that the voltage of the FIMS corresponds to the voltage used in your
laboratory. There is a 110/220 voltage selector switch behind the instrument. Ensure
proper voltage selection is set before the power cord is installed.
• Never remove the side panels of the FIMS without shutting down the instrument and
disconnecting the instrument power cord from line power.
• Before the instrument is installed, the area around, under and behind the instrument’s
planned location is to be cleared of any dirt and dust to prevent their entry into the
instrument’s interior which could cause a negative effect on performance.
Precautions for Custom ers
The laboratory manager is responsible for warning operators of this

instrument about biohazardous materials that are processed in this
instrument and about wastes that result from the operation of this
instrument.
WARNING
Le responsable du laboratoire est chargé d'avertir les opérateurs de cet
instrument concernant les substances présentant un danger biologique
qui sont traitées dans l'instrument, ainsi que concernant les déchets
issus du fonctionnement de cet instrument.
AVERTISSEMENT
The laboratory manager is responsible for disposing of any

biohazardous materials and minimizing any biohazards before the
equipment is removed from use, transported or processed for disposal.
WARNING Le responsable du laboratoire est responsable de l'élimination de toutes

les matières infectieuses et en minimisant les risques biologiques avant
que l'équipement est retiré de l'utilisation, du transport ou de
traitement pour l'élimination.
AVERTISSEMENT
• Appropriate venting, sample and waste collection needs to be provided.
• The waste bottle must be connected.

General Operating Conditions
If the equipment is used in a manner not specified herein, the

protection provided by the equipment may be impaired.
WARNING
Si l'équipement est utilisé d'une manière non spécifiée ici, la
protection fournie par l'équipement peut être altérée.
AVERTISSEMENT
The FIMS has been designed and tested in accordance with PerkinElmer specifications and in
accordance with industry safety requirements.
This equipment requires no specified inspection or preventive maintenance to ensure the

The FIMS is only for indoor use under the following conditions:
• Indoor use
• The location must be free of smoke, dust, corrosive fumes, direct sunlight and excessive
vibration.
• Temperature: +5 to +40 °C (40 °F to 104 °F)
• Relative humidity: 20% to 80%, without condensation
• Altitude: in the range -400 m to 2,000 m (1,312 feet to 6,562 feet)
Storage conditions:
• Ambient temperature: –20°C to +60°C (–4°F to +140°F)
• Relative humidity: 20% to 80%, without condensation
• Altitude: in the range -400 m to 12,000 m (1,312 feet to 39,370 feet)
If possible, avoid any adjustment, maintenance and repair of the opened, operating
instrument. If any adjustment, maintenance and repair of the opened instrument is
necessary, this must be done by a skilled person, trained by PerkinElmer, and who is aware
of the hazard involved..
Whenever it is likely that the FIMS is unsafe, make it inoperative. The FIMS may be unsafe if
it:
• shows visible damage
• fails to perform the intended measurement
• has been subjected to prolonged storage in unfavorable conditions
• has been subjected to severe transport stresses.
Electrical Safety
The instrument has been designed to protect the operator from potential electrical hazards.
This section describes some recommended electrical safety practices.
Lethal voltages are present at certain areas w ithin the

instrum ent. I nternal m aintenance of the instrum ent should
only be perform ed by a P erkinElm er service engineer or
sim ilarly authorized and trained person. When the instrument is
connected to line power, opening the instrument covers is likely to
WARNING expose live parts. Even when the power switch is off, high voltages can
still be present. Capacitors inside the instrument may still be charged
even if the instrument has been disconnected from all voltage sources.
Des tensions m ortelles sont présentes dans certaines zones de

l'instrum ent. La m aintenance interne de l'instrum ent ne doit
être confiée qu'à un responsable technique P erkinElm er ou à
une personne disposant des m êm es autorisations et
AVERTISSEMENT qualifications. Lorsque l'instrument est raccordé à la ligne électrique,
l'ouverture de ses capots risque d'exposer des pièces sous tension.
Même lorsque l'interrupteur d'alimentation est en position off, de hautes
tensions peuvent toujours être présentes. Les condensateurs présents à
l'intérieur de l'instrument peuvent continuer d'être sous charge même si
l'instrument a été déconnecté de toutes les sources de tension.
The instrument must be correctly connected to a suitable electrical supply. The supply must
have a correctly installed protective conductor (earth ground) and must be installed or
checked by a qualified electrician before connecting the instrument.
Any interruption of the protective conductor (earth ground) inside or

outside the instrument or disconnection of the protective conductor
terminal is likely to make the instrument dangerous. Intentional
interruption is prohibited.
WARNING
Toute interruption du conducteur de protection (mise à la terre) à
l'intérieur ou à l'extérieur de l'instrument ou toute déconnexion de la
borne du conducteur de protection risque de rendre l'instrument
dangereux. Il est interdit de procéder à une interruption intentionnelle.
AVERTISSEMENT
To ensure satisfactory and safe operation of the instrument, it is essential that the
green/yellow lead of the line power cord is connected to true electrical earth (ground).
If any part of the instrument is not installed by a PerkinElmer service representative, ensure
that the line power plug is wired correctly:
Terminal Cord Lead Colors
International USA
Live Brown Black
Neutral Blue White
Protective Conductor Green/Yellow Green

(earth/ground)
When working with the instrument:
• Connect the instrument to a correctly installed line power outlet that has a protective
conductor connection (earth ground).
• Do not operate the instrument with any covers or internal parts removed.
• Do not attempt to make internal adjustments or replacements except as directed in the

manuals.
• Disconnect the instrument from all voltage sources before opening it for any
adjustment, replacement, maintenance, or repair. If afterwards, the opened instrument
must be operated for further adjustment, maintenance, or repair, this must only be
done by a PerkinElmer Service engineer.
• Whenever it is possible that the instrument is no longer electrically safe for use, make
the instrument inoperative and secure it against any unauthorized or unintentional
operation. The electrical safety of the instrument is likely to be impaired if, for example,
the instrument shows visible damage; has been subjected to prolonged storage under
unfavorable conditions; or has been subjected to severe stress during transportation.
• Use only fuses with the required current rating and of the specified type for
replacement. Do not use makeshift fuses or short circuit the fuse holders.
• Whenever it is likely that the instrument is no longer electrically safe for use, make the
instrument inoperative and secure it against any unauthorized or unintentional
operation.
The instrument is likely to be electrically unsafe when it:
• Shows visible damage;
• Has been subjected to prolonged storage under unfavorable conditions;
• Has been subjected to severe transport stresses.

UV R adiation
UV Radiation-Risk of Eye Damage
The lamp emits intense UV radiation which can damage your eyes.
Do not gaze into a lighted lamp.
WARNING
Rayonnem ent UV
La lampe émet un rayonnement UV intense susceptible de provoquer

AVERTISSEMENT des lesions oculaires. Ne pas regarder fixament une lampe allumée..
You should be aware of the health hazard presented by UV radiation. The source lamp
generates UV radiation. Always wear UV-absorbing eye protection when viewing the radiation
from the source lamp. When the spectrometer is on, do not remove any covers unless
specifically instructed to do so in the instruction manual.
W aste Disposal
Waste vessels may contain acidic or organic solutions and small amount of elements that
were analyzed. If these materials are toxic, you may have to treat the collected effluent as
hazardous waste. Refer to your local safety regulations for proper disposal procedures.
Mercury lamps contain small quantities of the lamp element in a very pure form. When you
dispose of lamps containing toxic elements you must treat them as hazardous waste.
Mercury lamps are maintained under reduced pressure. Handle and dispose correctly to
minimize the implosion risk.
Treat the used mercury filters as hazardous waste and dispose of them according to local
safety regulations.
Sodium Tetrahydroborate
Sodium tetrahydroborate solutions are unstable and decompose, releasing hydrogen. They
also release hydrogen when they come into contact with acids.
• Ensure that the work area has an adequate ventilation system to prevent the buildup
of explosive hydrogen/air mixtures.
• Use and store sodium tetrahydroborate according to manufacturer’s

recommendations.
• Keep sodium tetrahydroborate solutions
 Out of direct sunlight
 Away from open flames
 In an area with an efficient ventilation system
 Protect sodium tetrahydroborate solutions from temperature variations.
• Handle sodium tetrahydroborate solutions with care as they are corrosive.
• Do not allow smoking in the area where sodium tetrahydroborate is used.
• When you are using sodium tetrahydroborate as the reductant with the flow-injection
system, hydrogen is formed when it comes into contact with the acidic carrier
solution.
 To prevent air entering the system make sure that the tubing connections
are correctly assembled and tight.
 Do not loosen or remove connections while the system is running.
 The maximum concentration of sodium tetrahydroborate that you should use

with a PerkinElmer flow injection systems is 0.5%.
 At the end of the work session, pump deionized water through the sodium
tetrahydroborate tubing system to remove all traces of the reductant.
Chem icals
Dispose of waste in accordance with the regulations applicable to

your locality, state and/or country.
WARNING
Éliminez les déchets conformément à la réglementation en vigueur.
AVERTISSEMENT
Use, store and dispose of chemicals that you require for your analyses in accordance with the
manufacturer’s recommendations and local safety regulations.
Com pressed Gases

Handle cylinders of compressed gas with care, in accordance with local regulations.
We recommend that gas cylinders should be located outside of the laboratory and the gases
led to the laboratory through approved piping. Use only approved tubing, connectors and
regulators for gas supply lines.
Tox ic Fum es
Tox ic Gases – Fum e Ventilation System
Without adequate ventilation, potentially toxic vapors can build up in

the laboratory. Your laboratory must have a reliable fume ventilation
WARNING system before you use this instrument.
N'ouvrez pas la porte. Risque chim ique
Avant que vous puissiez utiliser cet instrument, votre laboratoire doit
AVERTISSEMENT
s'être doté d'un système de ventilation efficace pour les fumées.
Use, store and dispose of chemicals that you require for your analyses in accordance with the
manufacturer’s recommendations and local safety regulations.
A charcoal filter is used to absorb the mercury vapor emitted from the FIMS-cell.
CAUTION
Do not restrict air intake or exhaust.
N'entravez pas l'admission ou l'évacuation de l'air.

ATTENTION
EM C Com pliance
EM C Directive
This product has been designed and manufactured, having regard to the state of the art, to
ensure that:
a) the electromagnetic disturbance generated does not exceed the level above which
radio and telecommunications equipment or other equipment cannot operate as
intended;
b) it has a level of immunity to the electromagnetic disturbance to be expected in its
intended use which allows it to operate without unacceptable degradation of its
intended use.
Europe
All information concerning EMC standards is in the Declaration of Conformity, and these
standards may change as the European Union adds new requirements.
FCC R ules and Regulations

This device complies with part 15 of the FCC Rules.
Operation is subject to the following two conditions:
1) This device may not cause harmful interference, and
2) this device must accept any interference received, including interference that may
cause undesired operation.
P ollution Degree
This product will operate safely in environments that contain nonconductive foreign matter
up to Pollution Degree 2 in EN/IEC 61010-1.
W EEE I nstructions for Perk inElm er Products
or
A label with a crossed-out wheeled bin symbol and a rectangular bar indicates that the
product is covered by the Waste Electrical and Electronic Equipment (WEEE) Directive and is
not to be disposed of as unsorted municipal waste. Any products marked with this symbol
must be collected separately, according to the regulatory guidelines in your area.
The objectives of this program are to preserve, protect and improve the quality of the
environment, protect human health, and utilize natural resources prudently and rationally.
Specific treatment of WEEE is indispensable in order to avoid the dispersion of pollutants into
the recycled material or waste stream. Such treatment is the most effective means of
protecting the customer’s environment.
Requirements for waste collection reuse, recycling, and recovery programs vary by regulatory
authority at your location. Contact your local responsible body (e.g., your laboratory
manager) or authorized representative for information regarding applicable disposal
regulations. Contact PerkinElmer at the web site listed below for information specific to
PerkinElmer products.
Web address:
http://www.perkinelmer.com/pages/010/onesource/environmental-health-and-
safety/environmental-directives-compliance.xhtml
For Customer Care telephone numbers select “Contact us” on the web page.
Products from other manufacturers may also form a part of your PerkinElmer system. These
other producers are directly responsible for the collection and processing of their own waste
products under the terms of the WEEE Directive. Please contact these producers directly
before discarding any of their products.
Consult the PerkinElmer web site (above) for producer names and web addresses.
Decontam ination and Cleaning

Before using any cleaning or decontamination methods except those specified by
PerkinElmer, users should check with PerkinElmer that the proposed method will not damage
the equipment.
Decontam ination
Customers wishing to return instrumentation and/or associated materials to
PerkinElmer for repair, maintenance, warranty or trade-in purposes are advised
that all returned goods must be certified as clean and free from contamination.
The customer's responsible body is required to follow the “Equipment Decontamination

Procedure” and complete the “Certificate of Decontamination”. These documents are
available on the PerkinElmer public website:
Procedure:
http://www.perkinelmer.com/Content/technicalinfo/dts_instrumentdeconprocedure.pdf
Certificate form:
http://www.perkinelmer.com/Content/technicalinfo/dts_perkinelmercertificationofdecontaminat
ionform.pdf
If you do not have access to the internet and are located in the U.S., call toll free at 1-800-
762-4000 or (+1) 203-925-4602, 8:30 a.m. - 7 p.m. EST and speak to Customer Support.
In Canada, call toll free 800-561-4646 and speak to Customer Support.
If you are located outside of the United States or Canada, please call your local PerkinElmer
sales office for more information.
Cleaning the I nstrum ent

Exterior surfaces may be cleaned with a soft cloth, dampened with a mild detergent and
water solution. Do not use abrasive cleaners or solvents.
W arning Signs on the I nstrum ent
Caution, hot surface.
Attention: surface chaude
Caution, risk of electric shock.
Attention: Risque de choc électrique.
Indicates alternating current

Indique la présence d'un courant alternatif
Indicates the off position of the main power switch

Indique la position Off de l'interrupteur d'alimentation
principal
Indicates the on position of the main power switch

Indique la position On de l'interrupteur d'alimentation
Indicates the protective conductor terminal

Indique la borne du conducteur de protection
W arning Labels
When this label is attached to an instrument it means refer to the

manual.
WARNING
Lorsque cette étiquette est apposée sur un instrument, cela signifie que
vous devez vous reporter au manuel.
AVERTISSEMENT
The instrument interface is a set of five potential-free relays that are used for controlling
accessories such as the Amalgam System. The voltages and currents that you apply to these
relays must not exceed the values shown in the table below.
I max V max
DC 1.0 A 42.4 V
AC 0.5 A 30 V
R eferences for Laboratory Safety Practice

• Bretherik, L., Bretherik's Handbook of Reactive Chemical Hazards, 7th ed., Butterworth &
Co. Ltd., London, UK, 2006.
• Safe Practices in Chemical Laboratories, Royal Society of Chemistry, London, UK, 1989.
• Hazards in the Chemical Laboratory, 5th edition, Luxon, S.G., ed., Royal Society of
Chemistry, London, UK, 1993.
• CRC Handbook of Laboratory Safety, 5th edition, Furr, K., ed., The Chemical Rubber Co.
Press, Florida, USA, 2000.
• Prudent Practices for Handling Hazardous Chemicals in Laboratories and Prudent

Practices for Disposal of Chemicals from Laboratories, 2nd edition, National Research
Council, National Academic Press, Washington D.C., USA, 2010.
• Sax's Dangerous Properties of Industrial Materials, 11th edition, Sax, N.I. and Lewis, R.J.,
eds., Wiley, New York, USA, 2004.
• Pohanish, R.P., HazMat Data, 2nd edition, Barnes & Noble, New York, USA, 2004.
• Compressed Gas Association, Inc., Arlington, VA 22202, USA, various publications.
• Data Sheets provided by chemical manufacturers, e.g.:
 USA, Safety Data Sheet (SDS),
 FRG, DIN-Sicherheitsblätter,
 UK, Safety Data Sheet (SDS).

. 53
System Description
System Description . 55
I ntroduction
FIMS is an acronym for Flow Injection Mercury System
The FIMS is a compact, software-driven, analysis system for mercury determinations. The
basic system consists of the FIMS spectrometer and a computer. Other instruments are
available as options, such as an autosampler (S10), the Amalgam System, and a printer.
The FIMS spectrometer consists of an atomic absorption spectrometer specifically designed

to measure the absorption of mercury and a flow injection system to prepare the samples for
the spectrometer. The FIMS spectrometer is not intended for use in diagnostic procedures.
With the FIMS analysis system, sample and reagent consumption is much lower than with
traditional manual sample preparation and delivery. This results in lower costs, less waste -
benefits the environment, and more sample being available for other analyses. Another
important advantage of using FIMS is the speed of analysis (up to 144 samples per hour).
The FI M S Spectrom eter

The FI M S Control System
The software application controls your analyses.
The software uses a graphic interface running under Microsoft Windows.
Com ponents on the Front Panel of the FI M S

Com ponents on the R ear P anel of the FI M S
9
1
2 3 4 10 5 6 7
1 Gas Inlet (Argon, Nitrogen)
2 RS-232-C Interface
3 System Interface
4 Dip Switches are for diagnostics only.
5 Instrument Interface (relay contacts to control

accessories)
Imax= 1 A (DC); Umax= 42.4 V (DC)
Imax= 0.5 A (AC); Umax= 30 V (AC)
6 Voltage Selector
7 Power Input Socket
8 Fuse Holder
9 Power Connector for Heated Cell
10 Thermocouple for Heated Cell

The Optical Unit
The Optical Unit is in the upper part of the FIMS. It contains the radiation source (Hg lamp),
the FIMS-cell compartment and the photocell detector.
R adiation Source
The radiation source (line source) is a low pressure mercury lamp.
Detector
The detector is a photocell with maximum sensitivity at 254 nm.
FIMS-Cell
The mercury vapor flows into the FIMS-cell where the absorption of the mercury is
measured. The FIMS-cell has an inner diameter of 4 mm and an optical path length of 260
mm. The cell is heated to about 50 °C to prevent the formation of condensation.
The FIMS-cell is a sensitive optical component. Please protect it from damage or

contamination.
Flow System Components

Pumps
FIMS uses peristaltic pumps to transport the various liquids through the system. The speed
of the pumps is under software control: 20-120 rpm or off.
Magazines
Each pump accepts up to four magazines which hold the pump tubing. There are different
magazines for the different sizes of pump tubing. The pressure adjustment lever regulates
the pressure applied to the pump tubing. A list of the magazines that are available is given in
the Parts chapter.
Pump Tubing
A variety of pump tubes with differing diameters is available. The different sizes have
differently colored collars. The pump tubing is available in acid-resistant and solvent resistant
materials.
Pump tubing with three collars is needed.
A list of the sizes and types that are available is given in the Parts chapter.
Flow -Injection Valve (FIAS-Valve)
The FIMS is normally shipped with a 5-port valve. The valve has two positions, Fill and
Inject.
In the Fill position the sample is drawn into the sample loop. The carrier stream flows
continuously to the manifold. In the Inject position the sample loop is switched into the
carrier stream and the sample is transported to the manifold. The sample pump stops while
the valve is in the Inject position.
For normal flow-injection analyses, port 1 is closed with a screw plug.
Sample Loops
The sample loops are made from PTFE tubing and have screw connectors. The sample loops
are available in different lengths with volumes between 50 µL and 1000 µL. A list of the sizes
that are available is given in the Parts chapter.
Carrier Gas System
An inert carrier gas is required for mercury determinations with the FIMS system. The carrier
gas carries the mercury vapor from the manifold to the FIMS-cell in the spectrometer unit.
The requirements for the carrier gas are described in Laboratory Requirements.
The inlet for the carrier gas is on the rear of FIMS (the GAS IN connection). The FIMS has a
gas economy function: when FIMS is not used for more than 10 minutes the gas flow is
automatically turned off.
The gas outlet, flow regulator and flow gauge are on the front panel of the FIMS unit. The
gauge is calibrated for argon. Useable flows are between 40 mL/min and 250 mL/min at a
recommended gas inlet pressure between 320 kPa (46 psi and 3.2 bar) and 400 kPa (58 psi
and 4 bar). The gas flow is off (0 mL/min) when the control knob is turned fully clockwise.
Nonreturn Valve
The nonreturn valve at the gas outlet prevents liquid from the manifold entering the gas
control system.
Manifold
In the manifold two fluid streams are mixed. This can be to initiate a reaction or to dilute one
of the streams.
The manifold blocks have three channels that are interconnected blocks as shown below. The
inlets of the channels have a 1/4"- 28 UNF internal screw thread. The locks are made of an
inert, translucent plastic. Each block has two additional holes for connector pegs to join
adjacent blocks.
Gas/Liquid Separator
The gas/liquid separator is used in the mercury cold vapor technique to separate the gaseous
product and liquid waste in the mixture that leaves the manifold.
The gas/liquid separator block is joined to a manifold block with a plug connector.
Plug Connector
(B050-7960)
Connection and Reaction Tubes
The connection tubing is made from PTFE tubing and have screw connectors. The screw
connectors are color coded to identify the internal diameter of the tubing. A list of the sizes
that are available is given in the Parts chapter.
Adapters and Connectors
A selection of adapters and connectors is available to connect the different types and sizes of
connector and pump tubing. Lists of the adapters and connectors that are available are given
in the Parts chapter.
Examples of Connectors and Adapters

Technical Data
Principle Single-beam atomic-absorption spectrometer with integral flow injection
sample-delivery system.
Detector Photocell with maximum sensitivity at 254 nm.
Radiation Low pressure mercury lamp.

Source
Computer Lenovo M83 Computer; Intel Core i5-4670 Processor (3.4GHz, 6M Cache);
1TB 7200RPM HDD; Intel HD Integrated Graphics;
4GB X 2 DIMM 1600MHz; UDIMM DDR3; Optical DVD Recordable; Wireless
WiFi 6235, 2 serial ports and one network port and Win 7 Ultimate 64-bit
Operating system; optional 19” or 24” monitor XVGA, mouse and printer.
Control System
Special application program with graphics user interface, mouse and
keyboard control. Online help function. Hard disk or floppy storage of
measurement data, signals and complete analytical methods
Graphics
High resolution graphics and numerical display of the signals. Calibration
curve display; newest + previous if a reslope or recalibration is done.
Storage and recall of transient absorbance signals. Hard copy printout of
screen graphics on an associated printer. In continuous mode, printout of
real time signals on an associated printer.
Flow Injection Five-port flow-injection valve with various sizes of sample loop. Valve
Valve setting (fill or inject) is controlled by the application program.
Carrier Gas Inert carrier gas system with flow gauge and flow regulator. Flow is
System automatically stopped when FIMS has been idle for 10 minutes.
Inlet pressure: 320 kPa (46 psi and 3.2 bar) to 400 kPa (58 psi and 4 bar).
Flows: 40-250 mL/minute, or off
Pumps One (FIMS-100) or two (FIMS-400) peristaltic pumps.

The pump speed is variable between 20 rpm and 120 rpm or off, and is
controlled by the application program. Up to four pump tube magazines for
each pump.
Interfaces
RS-232-C interface.
Instrument interface (for Amalgam System) with five potential free relays:
Imax = 1 A (DC); Umax = 42.4 V (DC)
Imax = 0.5 A (AC); Umax = 30 V (AC).
Power 115 V or 230 V ± 10%, 50 or 60 Hz ± 1%.

Requirements Maximum power consumption is 450 VA.
Environmental
+10 °C to +35 °C
Requirements
20-80% relative humidity, non-condensing.
(operating)
Dimensions Width: 415 mm (16.3 in.) Height: 255 mm (10.0 in.) Depth: 410 mm (16.1
in.)
Mass 12 kg (26.5 Ibs)

The Flow I njection / M ercury Cold Vapor

Technique
The P rinciple of the Flow I njection Technique
The central component of the flow injection system is the flow injection valve (FIAS-valve).
The FIAS-valve injects a defined and reproducible sample volume into a carrier or reagent
stream. The pump transports the carrier (and sample) and reagent streams to the manifold.
In the manifold the various reagents mix and possibly react. The outflow from the manifold
usually goes to some form of detection system.
P rinciple of the M ercury Cold Vapor Technique

If a reagent solution is introduced at a suitable point in the flow injection system, the sample
undergoes a chemical reaction as it is transported through the system. This procedure is
used in FIMS applications.
The mercury must be in an ionic form in the sample solution. When the reducing agent (e.g.
NaBH4) mixes with the sample, the ionic mercury is converted to metallic mercury. An inert
carrier gas (e.g. argon) transports the mercury to the spectrometer. A major advantage of
the technique is the inherent separation of the analyte element from the matrix. Nonspecific
background absorption and matrix interference are almost unknown with this technique.
Some important advantages of using FIMS for mercury determinations are the reduction in
sample and reagent consumption and increase in speed of analysis. With FIMS, up to 144
samples per hour can be analyzed.
R educing Agents
For mercury determination, either sodium tetrahydroborate or tin (II) chloride are suitable
reducing agents. It is important to have separate fluid system components reserved for
sodium tetra-hydroborate and tin(II) chloride applications. If you use a system that has had
tin(II) chloride in it for determinations with sodium tetrahydroborate, there is a severe
reduction in sensitivity .
A special Reductant Change kit is available for this purpose; part number B0508594. This
contains all fluid system parts that come into contact with the reducing agent.
The first channel of pump 2 feeds a stream of carrier fluid (HCl) continuously through the
FIAS-valve to the manifold. With the FIAS-valve in the Fill position, pump 1 fills the sample
loop. In the inject position (shown in the illustration) the contents of the sample loop enter
the carrier stream and are carried to the manifold, which acts as the reaction cell.
The second channel of pump 2 carries the reducing agent NaBH4 or SnCl2 directly to the
manifold. The sample (in the acidic carrier stream) and reductant mix in the manifold and a
spontaneous reaction takes place, reducing the ironic mercury to metallic mercury.
The hydrogen that is released from the reductant, along with the stream of carrier gas
(argon or nitrogen), carry the mercury vapor to the gas/liquid separator where the liquid is
separated from the gaseous components.
Am algam Technique
The automatic Amalgam System can greatly improve the detection limit of your mercury
determinations.
In this system the atomic mercury is carried to a gold-platinum gauze with which it forms an
amalgam. This is done for a defined time for each of a number of aliquots of sample and
results in the gauze becoming enriched with mercury. At the end of the enrichment
procedure the gauze is quickly heated to release the mercury, which is then transported to
the measurement cell.
Using this technique the detection limit for mercury can be improved by more than an order
of magnitude. FIMS functions fully automatically with the Amalgam System.
Further details about the Amalgam System are contained in the Amalgam System Operator's
Manual.
I nstalling the FI M S
Analysis System
Installing the FIMS
Analysis System . 71
Unpack ing and Check ing the Spectrom eter

W hen the spectrom eter arrives
• Unpack the spectrometer carefully. Check it and any other equipment for any visible
signs of damage. If you find that something is damaged, file a claim with the
authorized carrier immediately and inform your nearest PerkinElmer office.
• Check that nothing is missing; a list of the equipment delivered is given in the Parts
chapter. If you think that something is missing, inform your nearest PerkinElmer
office.
• The instrument will typically be installed by a PerkinElmer service engineer, contact

your local PerkinElmer office to arrange for the installation.
Before you or the service engineer installs the

spectrom eter
• You need to prepare a suitable site for the spectrometer and any accessories. See
the section on Laboratory Requirements on page 89 and the accessories' own
handbooks.
• We recommend that you read the installation instructions in order to become familiar
with the spectrometer and its requirements before you install it or start using it.
• These instructions are also provided in case you need to alter any of the connections
or move the instrument.
I f the service engineer installs the instrum ent

• The service engineer will perform pre-installation checks, install the spectrometer
and ensure that everything functions correctly.
Sitting the Spectrom eter and the Accessories

For maximum stability and minimum maintenance, the site for FIMS and any accessories
must:
• Be free of dust, smoke, and corrosive fumes.
• Be smooth, level, and free from vibration.
• Be out of direct sunlight.
• Be away from radiators and heaters.
• Have a relative humidity in the range 20% to 80 %, non condensing.
• Be near to the required electric, gas and water supply points.
• A mercury filter needs to be installed.
• Have sufficient room to work comfortably with the instruments, and allow
you to reach connections at the rear of the instruments.
For more details about these requirements see Laboratory Requirements. For the
requirements of the computer and any other accessories, see the handbooks provided with
the relevant instrument.
Sitting Accessories
If the autosampler fits securely on the top of the FIMS, we recommend that you place the
autosampler there. Place accessories such as the Amalgam System very close to the FIMS.
This will minimize the length of the sample transfer tubes between the instruments.
Sitting the Com puter and P rinter

Place the computer near the spectrometer in a convenient position for working with the FIMS
and any additional accessories if applicable. A movable table specially designed for a
computer and printer may be most convenient.
Installing the FIMS
Carrier Gas Connections

The FIMS requires a supply of carrier gas. The specification of the gas supply is described on,
Laboratory Requirements on page 89. The connector provided for the gas tubing is suitable
for connection to most commercially available pressure regulators.
If you require an adapter for your regulator, contact the gas supplier, the regulator
manufacturer, or your local PerkinElmer office.
1. While the gas supply is off, set the pressure regulator to zero.
2. Remove the knurled nut from the GAS IN nipple on the rear of FIMS and slide it onto
the free end of the gas supply tube.
3. Push this end of the tube onto the GAS IN nipple on the rear of FIMS.
Push the tube over the bulge on the nipple, then slide the knurled nut up the tube to
the screw fitting of the nipple and tighten it securely.
NOTE: The regulator connectors/fittings do not come installed on the gas tube assembly. See the
following figure for the location of these fittings.
4. Connect the other end of the gas supply tube securely to the outlet of the gas supply
pressure regulator.
FIMS Carrier Gas Connections

Electrical Connections
Electrical Hazard
To prevent potential injury to yourself and damage to the

instrument, switch off all instruments in the system and
disconnect them from the line power supply before you alter, or
WARNING make any new, electrical connections.
Danger Électrique
Pour éviter les risques de blessures à vous-même et les

dommages à l'instrument, éteignez tous les instruments dans le
système et débranchez-les de l'alimentation de la ligne avant de
AVERTISSEMENT modifier, ou de faire des nouvelles, des connexions électriques.
1. Switch off the instrument and accessories and disconnect their line cords from the
line power supply.
2. Connect the communication cables, see page 75.
3. Set the DIP switches to select the interface and set the relevant parameter values,
see page 75.
4. Set the voltage selector correctly, see page 75.
5. Connect the mouse and printer to the computer as described in the handbooks
supplied with these instruments.
Use the proper cable to connect the printer to the computer. If you use a different
cable the printer may not function correctly.
6. Connect the line cords, see page 77.

Installing the FIMS
Com m unication Cable Connections
Risk of damaging internal electrical components.

CAUTION
ATTENTION Risque de composants électriques internes dommageables.
FIMS Voltage Selection

1. Switch off the spectrometer (FIMS).
2. Slide the switch of the voltage selector, on the rear of FIMS, to show the value
that corresponds to the voltage of the electrical supply, either 115 V or 230 V.
To Select the R S-232-C-Interface and Set the Baud Rate
NOTE: With the serial connection, all the dip switches should be turned off.
1. Switch off the spectrometer (FIMS) [1-10].
2. Select the RS-232-C-interface: set DIP-switch [8] to off.
3. Set the baud rate with DIP-switches [1] and [2].
4. Set DIP-switches [3-5] and [6], and [7] to off.

Voltage Selector
DIP Switches – RS-232-C Operation

Set RS-232-C interface active:[8] off.
Set [6] [7] off,
Set [3], [4], [5] off.
Set the baud rate: switches [1-2]:
Baud Switch
Rate [1] [2]
9600 off off
19200 on off
38400 off on
Example: RS-232-C, baud rate 9600 (all the

DIP switches are in the OFF position – down
position)
Installing the FIMS
Line Pow er Connections
Electrical Hazard

instrument, switch off all instruments in the system and
disconnect them from the line power supply before you alter, or
Danger Électrique
Pour éviter les risques de blessures à vous-même et les

dommages à l'instrument, éteignez tous les instruments dans le
système et débranchez-les de l'alimentation de la ligne avant de
AVERTISSEMENT modifier, ou de faire des nouvelles, des connexions électriques.
To avoid problems of interference caused by earth loops, always connect the FIMS, the
computer and the printer to the same phase of the line power supply. The most convenient
method is to use a multi-socket distributor.
See Laboratory Requirements for details of the line power supply. See the computer and
printer manuals for details of their power requirements.
1. Before you alter or make any new electrical connections, switch off all the
instruments in the system and disconnect their line cords from the line power supply.
Connect the communication cables correctly, see page 75.
Set the DIP switches to select the interface and set the relevant parameter values,
see the previous page.
Set the voltage selector correctly, see page 75.
Make sure that the two fuses in the power input socket on the rear of FIMS are of
the correct type, 6.3 AT, slow- blow, see page 112.
2. Connect the line cords of the FIMS, the computer and the printer to the multi-socket
distributor.
3. Connect the multi-socket distributor to a correctly installed line power supply that
has a protective conductor connection (earth/ground)
NOTE: When you switch on the instruments, follow the correct procedure described in the
handbooks supplied with each instrument installation.
Auto-
sampler
Line Power Connections

Installing the FIMS
I nstalling Tubing System Com ponents

Tubing Configurations
The illustrations on the following pages show recommended tubing configurations. We
recommend that you start with the suggestions given here and experiment with other setups
when the system is working.
For a description of specific applications, see the booklet Recommended Analytical Conditions
and General Information for Flow Injection Mercury/Hydride Analyses.
Constricted Tubing
Make sure that the tubing is not kinked or otherwise constricted,

since this could lead to an increase in pressure in the tubing.
WARNING
Organic Solvents
The normal pump tubing supplied with the FIAS are not resistant
to organic solvents. Use solvent resistant pump tubing if you are
pumping organic solvents.
Constricted Tubing
Assurez-vous que le tuyau ne soit pas plié ou autrement

resserrée, car cela pourrait conduire à une augmentation de la
pression dans le tube.
AVERTISSEMENT
Les solvants organiques
Le tuyau de la pompe normale fournie avec la FIAS ne sont pas

résistants aux solvants organiques. Utiliser un solvant tuyau de la
pompe résistante si vous êtes de pompage des solvants
organiques
Tube-Connector Key
Tighten the screw fittings on the PTFE tubing by hand or with the tube connector key (Part
No. B0501315). Do not use any other tool. Do not over tighten the connector; the connection
will be distorted and may leak.
Changing Fluid System Com ponents W hen Changing

R eductants
You can use either tin (II) chloride or sodium tetrahydroborate as reductants for mercury
determinations. When you change reductants you must change all fluid system components
that come in contact with the reductant. A special Reductant Charge kit is available for this
purpose (Part No. B0508594). The cell should also be dedicated to a reductant.
Recommended Tubing Configurations for FIMS-100

Installing the FIMS
Recommended Tubing Configurations for FIMS-400
Fitting the Pum p Tube to the M agazine

You tension the tube in the pump magazine between two of the collars on the pump tube.
The pump tubing is placed in the magazine using the middle collar and one of the remaining
collars. The other side of the pump tubing can be used after the first side becomes worn.
When the system is not being used, one of the collars should be removed from the
magazine, or it will wear prematurely.
Since each pump tube has three collars, each tube has two sections that you can use to
tension the tube in the magazine. If the section of tube in the magazine becomes deformed,
but there is no other damage, you can tension the other section of tube in the magazine.
Fitting the Pum p M agazine onto the P um p

1. Slide the pump magazine into the pivot above or below the pump.
The flow is from the left to right for pump magazines placed above the pump
rotor and right to left for pump magazines placed below the pump rotor.
Installing the FIMS
2. Rotate the pressure adjustment lever until the end of the screw locates in the notch
on the back of the pump magazine.
Adjusting the Flow

• The flow depends on the speed of the pump, the diameter of the pump
tubing, the pressure applied to the tubing and the viscosity of the liquid.
• Start the pumps and adjust the flows as described in the FIMS Software
Guide.
 To increase the flow, rotate the pressure adjustment screw clockwise to
press the magazine against the pump rotor and increase the pressure on
the pump tubing.
 To decrease the flow, rotate the pressure adjustment screw counter
clockwise to decrease the pressure on the pump tubing. Adjust the
pressure to obtain a steady flow without bubbles.
Do not over tighten the pressure adjustment screw since this shortens the working life of the
tubing, and may slow or stop the pump.
FI AS–Valve Connections
Part numbers for PTFE tubes, sample loops and other fluid system components are given in
the Parts chapter.
Installing the FIMS
Assem bling the M anifold

FIMS-Cell Connections
Toxic Gases
The fumes emitted from the FIMS-cell may be toxic.
WARNING The FIMS uses a charcoal filter which has been attached during
installation, removes the toxic fumes.
Constricted Tubing
Make sure that the tubing is not kinked or otherwise constricted,

since this could lead to an increase in pressure in the tubing
system.
Gaz Toxiques
AVERTISSEMENT Les fumées provenant de la FIMS cellules peuvent être toxiques.
Le FIMS utilise un filtre de charbon de bois qui a été fixé lors de

l'installation, supprime les fumées toxiques.
Constricted Tubing
Assurez-vous que le tuyau ne soit pas plié ou autrement resserrée,

car cela pourrait conduire à une augmentation de la pression dans
le tube.
1. Connect the sample transfer tube from the gas/liquid separator to the FIMS-cell
inlet nipple.
2. Connect the silicone exhaust tube to the FIMS-cell outlet nipple.
To install (or remove) the FIMS-cell from the cell compartment of FIMS, use the procedure
described on page 99.
Starting Up the System

Switching On
• Read the safety information at the front of this handbook and in the
handbooks for the other instruments before you start up the system.
• Make sure that the system is correctly installed and that the electrical
connections are correct. See the previous sections of this chapter and the
handbooks for the other instruments.
• Switch on the computer and printer as described in the manuals supplied
with these instruments.
• Switch on the FIMS and any accessories as described in the FIMS Software
Guide.
• The power switch for the FIMS is at the left-hand side of the front panel.
Installing the FIMS
Setting Pump Parameters:

• Start the pumps and adjust the liquid flows as described in the FIMS
Software Guide.
The flow depends on the speed of the pump, the diameter of the pump tube, the pressure
applied to the tubes and the viscosity of the liquid.
The gas supply should be turned on before the pumps. If the pumps are turned on first, it is
possible for the solution being pumped back into the flow meter.
Setting the Carrier Gas Flow

• Start and adjust the carrier gas flow as described in the FIMS Software
Guide.
• Set the flow of the carrier gas with the flow regulator on the front of the
instrument.
• The gauge is calibrated for argon. Useable flows are between 40 mL/min and
250 mL/min at a recommended gas inlet pressure between 320 kPa (46 psi
and 3.2 bar) and 400 kPa (58 psi and 4 bar). The gas flow is off (0 mL/ min)
when the control knob is turned fully clockwise. For most analyses a flow of
about 50 mL/min is recommended.
The Power Switch

When you press the power switch to the ON position, the green light under the switch
illuminates. The instrument is ready for use and the FIMS-cell heating and the source lamp
are switched on.
When you press the power switch to the off position, the green control light under the switch
goes out and O is shown on the upper edge of the switch. All instrument functions are
interrupted.
Installing the FIMS
Laboratory R equirem ents

Sum m ary of R equirem ents
Before you can operate the FIMS correctly you must ensure that the laboratory or work area
provides the necessary facilities. This section details these requirements.
The booklets: Preparing Your Laboratory for PerkinElmer Atomic Spectroscopy Instruments,
and Preparing Your Laboratory for PerkinElmer Flow Injection Atomic Spectroscopy, available
from PerkinElmer, also contain useful information.
Summary of things to consider:

• Environmental conditions.
• The space required by the FIMS and ancillary equipment.
• Fume ventilation.
• The electricity supply.
• The carrier gas supply.
Environm ental Conditions

Operating
Ex plosive Atm osphere
This instrument is not designed for operation in an explosive

atmosphere.
WARNING
Atm osphère Ex plosive
Cet instrument n'est pas conçu pour fonctionner dans une

atmosphère explosive.
AVERTISSEMENT
Recommended operating conditions:

• Indoors.
• The location must be free of smoke, dust, corrosive fumes, direct sunlight and
excessive vibration.
• Ambient temperature +10 °C to +35 °C (+50 °F to +95 °F), with a maximum
change not exceeding 2.8 °C (5 °F) per hour. For optimum instrument performance,
the room temperature should be controlled at 20° ± 2 °C.
• Relative humidity 20% to 80%, without condensation.
• Altitude in the range -400 m to 2,000 m (-1,312 ft. to 6,562 ft).
Safe operating conditions:
• Indoors
• Temperature +5 °C to +40 °C (+41 °F to +104 °F).
• Altitude in the range -400 m to 2,000 m (-1,312 ft. to 6,562 ft).
Storage conditions:
• Ambient temperature –20 °C to +60 °C (–4 °F to +140 °F).
• Altitude in the range -400 m to 12,000 m (-1,312 to 39,370 feet).
Space R equirem ents for a FI M S Analysis System

The illustration on the following page shows a recommended arrangement for a FIMS
analysis system.
You should have sufficient room around the instruments to reach all the connections on the
rear, and reach the gas and electric supply points.
Line Pow er Supply
FIMS requires a stable single phase, 115 V or 230 V ± 10%, 50 Hz or 60 Hz ± 1%, line
power supply that has a correctly wired protective conductor terminal (earth/ground). The
instrument uses 450 VA maximum power.
The line power supply must conform with your local safety regulations and be checked by a
qualified electrician before you connect the instrument.
Installing the FIMS
Autosampler
Autosampler
Carrier Gas
The FIMS requires a supply of inert carrier gas. Argon is recommended but purified nitrogen
can be used.
The carrier gas must meet the following specification:
Gas Purity Outlet Gauge Pressure (± 10%)
kPa Bar (psig)
Argon 99.996% 360 3.6 (52)
Nitrogen 99.999% 360 3.6 (52)

• The gas supply system must conform with your local safety regulations. PerkinElmer
recommends that cylinders or tanks be stored outside the laboratory and the gas piped
to the instrument in approved gas lines.
• The gas supply line must contain a suitable pressure reducing valve and an on/off valve
between the gas supply and the FIMS spectrometer. Either the gas manufacturer or
PerkinElmer can supply suitable two-stage pressure reducing valves.
• You must be able to reach the on/off valve and pressure regulator and see the pressure
gauge while you are working with FIMS.
Maintenance . 93
M aintenance
Maintenance . 95
PerkinElm er Service
You should only perform the maintenance procedures described in this handbook.
For maintenance procedures that are not described in this manual, contact your local Perkin-
Elmer office to arrange for a service engineer to visit.
In particular you must only allow a PerkinElmer service engineer to perform any work on the
electrical components inside the instrument.
Unauthorized Adjustm ents and Servicing
Do not attempt to make adjustments, replacements or repairs to this

instrument except as described in the accompanying User
WARNING Documentation.
Ajustem ents et entretien non autorisés
Seul un responsable technique PerkinElmer ou une personne

possédant des qualifications et autorisations similaires est autorisé à
AVERTISSEMENT effectuer l'entretien de l'instrument.
Checklists for R egular M aintenance Tasks

General P reventative M aintenance
NOTE: This equipment requires no specified inspection or preventive maintenance to ensure the
Component Maintenance Required/Frequency
Complete analysis system For safety reasons, and to avoid contaminating new
and work area samples, make sure that the instrument and the work area
are kept absolutely clean. This is especially important
when working with toxic substances and when measuring
trace amounts of any elements.
Wipe up spills immediately before they can cause further

contamination or damage.
Mercury Filter PerkinElmer guarantees that the filter will safely adsorb all
the mercury leaving the FIMS-cell for a period of 6 months
or up to a total mercury load of 5.5 mg, whichever occurs
sooner.
This total mercury load would be produced by 110,000

injections of a 100 µg/L mercury solution using a 500 µL
sample loop and the recommended conditions for
mercury. The filter cannot be cleaned and must be
replaced (Part No. B3000274).
Treat the used mercury filter as hazardous waste and

dispose of them according to local safety regulations.
Environmental conditions If the environmental conditions are as described in

Laboratory Requirements, and you use an efficient fume
ventilation system, the instrument will require very little
regular maintenance.
Instrument outer surfaces Exterior surfaces may be cleaned with a soft cloth,
dampened with a mild detergent and water solution. Do
not use abrasive cleaners or solvents.
Wipe up spills immediately before they can cause further

contamination or damage.
Maintenance . 97
Spectrom eter M aintenance
FIMS-cell windows Measure the absorbance of the cell windows regularly,

see Page 99.
Clean windows have an absorbance of about 0.75. If

the windows show an absorbance greater than this,
they are probably dirty.
You do not normally need to clean these windows

regularly, but if the windows become marked, e.g. with
fingerprints, you can clean them as described on page
100.
The cell windows form an important part of the optical

system. Dirt, scratches and finger marks on the
windows reduce the amount of radiation transmitted
through the cell.
FIMS-cell, inner surface Clean the inner surface of the cell only if there is a
decrease in sensitivity which is not attributable to other
factors, such as unsuitable analytical parameters or
instrument settings, or incorrectly prepared or
contaminated solutions.
Under normal working conditions, clean the inner

surface of the cell only if the sensitivity is significantly
reduced, or if the cell becomes seriously contaminated
(e.g., when the reaction mixture from the gas/liquid
separator has overflowed into the cell).
Air filter Install a new filter yearly, or more often in a dusty

environment. See page 107.
Fluid System M aintenance
Complete fluid system When you have finished an analysis, rinse the fluid system. See
the FIMS Software Guide (Part No. 09931164) for the correct
procedure to use.
Pump tubes Acidic Solutions
The standard pump tubing is acid-resistant, but not resistant to

organic solvents.
Organic Solutions
If you wish to use organic solvents, install solvent-resistant pump

tubing.
To reduce wear on the pump tubing, place one drop of silicone

oil on the part of the tubing in contact with the pump rollers.
Leave only one pump tubing clip attached to the magazine when
the system is not being used.
Pump rollers Wipe the rollers with a dry lint free cloth.
All tubes On a daily basis, make sure that all tubing is clean and free of
kinks. Replace any tubing that may be damaged, worn, or
contaminated.
Waste bottle Empty the waste bottle regularly; never allow it to overflow or
allow the liquid to reach the end of the drain tubing.
If the drain bottle contains hazardous, toxic, or flammable

substances, dispose of the waste properly, according to local
safety regulations.
Solutions that are left over at the end of the day must be
combined in a waste container that is in a fume hood.
FIAS-valve The FIAS valve is easily clogged. You can remove the FIAS-valve
to clean it or replace parts; see page 103.
Maintenance . 99
FI M S-Cell M aintenance
M easuring the Absorbance of the FI M S-Cell W indow s
1. Switch on the FIMS analysis system as described in the FIMS Software Guide (Part
No. 09931164).
2. Start the software.
3. In the Instrument tab, click on the Continuous Graphics icon.
4. Remove the FIMS-cell from the cell compartment of FIMS; see page 99.
5. In the Continuous Graphics window, click on Auto zero graph button.
6. Install the FIMS-cell in the cell compartment; see page 100.
7. The absorbance reading in the Continuous Graphics window is the absorbance of

the FIMS-cell windows.
If the absorbance is greater than 0.75, remove the windows from the FIMS-cell and clean
them.
R em oving the FI M S-Cell from the Spectrom eter

1. Make sure that there is no analysis in progress.
2. Carefully disconnect the exhaust tube and sample transfer tube from the FIMS-cell.
3. Grip the two nipples on the cell window assemblies and pull the cell out of the cell
compartment.
I nstalling the FI M S-Cell in the Spectrom eter

To install the FIMS-cell in the spectrometer, grip the two nipples on the window assemblies
and carefully push the FIMS-cell into the cell compartment.
R em oving the W indow s from the FI M S-Cell

1. Pull and simultaneously twist the cell window assemblies off the ends of the FIMS-cell.
2. Carefully insert the tip of a small screwdriver in the notch of the window assembly and
remove the outer O-ring.
Remove the window from the cell window assembly.
Fitting the W indow s from the FI M S-Cell

1. Carefully place the clean windows in the cell window assembly.
Insert the outer O-ring in the cell window assembly to secure the window.
2. Push and simultaneously twist the cell window assemblies onto the ends of the FIMS-cell.
NOTE: Install the cell in the spectrometer and measure the absorption of the windows; see page 99.
If the absorbance is still too great, either clean the windows more thoroughly, or install new
windows. See the Parts chapter for part numbers.
Cleaning the W indow s
Take care not to scratch or touch the surface of the quartz windows. You
CAUTION
must replace scratched windows. The more you rub the surface of the
windows, the more chance there is of scratching them. Wearing gloves
are recommended.
Prenez soin de ne pas rayer ou de toucher la surface des fenêtres de

ATTENTION
quartz. Vous devez remplacer les fenêtres rayé. Le plus vous frottez la
surface des fenêtres, plus il ya de chances de les rayer. Le port de gants
est recommandé.
Keep cleaning solutions and water away from other parts of the instrument.
1. Remove the FIMS-cell from the cell compartment of the spectrometer; see page 99.
2. Remove the windows from the FIMS-cell; see page 100.
3. Wash the windows with mild laboratory-grade detergent, and rinse with plentiful of
deionized water and allow them to dry.
4. Clean the windows with a soft, lint-free cloth moistened with a spectroscopic-grade
alcohol or absolute alcohol.
Do not use too m uch alcohol since this m ay produce drying m arks.
Maintenance . 101
NOTE: Install the cell in the spectrometer and measure the absorption of the windows; see page 99.
If the absorbance is still too great, either clean the windows more thoroughly, or install new
windows. See the Parts chapter for part numbers.
Cleaning the FI M S-Cell

1. Remove the FIMS-cell from the cell compartment of the spectrometer; see page 99.
2. Remove the windows from the FIMS-cell; see page 100.
Wash the FIMS-cell with deionized water and allow it to dry.

Gas/ Liquid Separator and M anifold M aintenance

Cleaning Gas/ Liquid Separator and M anifold
Norm al Procedure
When you have finished an analysis, rinse the fluid system. See the FIMS Software Guide
(Part No. 09931164) for the correct procedure to use.
To clean the manifold and separator more thoroughly:
Hydrochloric Acid
Hydrochloric acid (HCL) is corrosive and can cause severe burns.

When using hydrochloric acid, always wear suitable protective
WARNING clothing including a face mask, work in a fume hood, and observe
the manufacturer's instructions and your local safety regulations.
Acide Chlorhydrique
Acide chlorhydrique (HCl) est corrosif et peut provoquer des

brûlures graves. Lors de l'utilisation de l'acide chlorhydrique,
AVERTISSEMENT toujours porter des vêtements de protection appropriés, y compris
un masque, le travail dans une hotte, et observer les instructions
du fabricant et vos règles de sécurité locales.
• Separate the manifold and separator blocks.
• Disconnect the tubing from the manifold and separator blocks.
• Unscrew the separator cover and remove the PTFE filter.
• Pump deionized water through each channel of the blocks.
• If necessary, use a nylon filament and compressed air to unblock the fluid channels
of the blocks.
• Rinse the manifold and separator blocks with 1:1 hydrochloric acid (v/v, one part
concentrated hydrochloric acid diluted with one part water -about six molar).
• Rinse the manifold and separator components thoroughly with deionized water.
Changing the Separator Filter

For successful analyses, the filter must be clean and dry.
• Unscrew the separator cover and remove the old filter.
• Insert a new filter with the smooth side down.
• Replace the cover.

Maintenance . 103
FI AS-Valve M aintenance
Cleaning the FI AS-Valve
Norm al Procedure
• When you have finished an analysis, rinse the fluid system. See the FIMS Software Guide
(Part No. 09931164) for the correct procedure to use.
To clean the channels of the valve individually:
1. Disconnect all the tubing from the valve.
2. Pump deionized water through each channel of the valve.
If the procedure described above is not sufficient to clean the valve, you can dismantle the
valve and clean the component parts as described below.
1. Disconnect all tubings from the valve.
2. Remove the valve from the pump unit, see page 103.
3. Dismantle the valve, see page 104.
4. Clean the individual parts of the valve with deionized water. Pump deionized water
through each channel of the valve components. If necessary, use a nylon filament and
compressed air to unblock the channels of the valve. A squirt bottle can be used to direct
water into a valve opening with a short piece of pump tubing connected to a fitting.
5. Reassemble the valve, see page 105.
6. Attach the valve to the pump unit, see page 103.
R em oving the FI AS-Valve from the P um p Unit

1. Make sure that there is no analysis in progress.
2. Disconnect all the tubing from the FIAS-valve.
3. Using a 3 mm hexagonal key unscrew the two screws that secure the valve to the pump
unit.
4. Gently pull the FIAS-valve away from the motor mount.
Fitting the FI AS-Valve to the Pum p Unit

1. Align the coupling on the spindle of the valve over the motor mount on the pump unit,
then push the valve onto the motor mount.
2. Tighten the two screws that hold the FIAS-valve onto the pump unit.
Dism antling the FI AS-Valve
CAUTION Damage to the Valve

The FIAS-valve is a precision component. To avoid damage to the valve,
read the following directions carefully before you dismantle the valve.
ATTENTION Les dommages à la Valve

La FIAS soupapes est un composant de précision. Pour éviter
d'endommager la vanne, lisez attentivement les instructions suivantes
avant de démonter la soupape.
1. Remove the FIAS-valve from the pump unit as described on page 103.
2. Place the dismantling tool on the rear of the FIAS-valve. Make sure that the lug on the
dismantling tool engages the notch in the spindle.
3. Hold the valve and dismantling tool securely and, with a 7 mm wrench, unscrew and
remove the securing bolt.
4. Carefully separate the valve components.
5. Carefully clean the valve components.
NOTE: Do not use metal or abrasive tools to clean the valve.
• Use deionized water or use a soft lint free cloth moistened with ethanol, or isopropanol
(IPA).
Maintenance . 105
• If necessary, use a nylon filament and compressed air to unblock the channels in the
valve.
• Rinse the components thoroughly with deionized water.
• Pump deionized water through each channel of the valve components.
R eassem bling the FI AS-Valve

1. Check the components. Inspect the o-ring and replace if needed.
NOTE: The valve rotor and the valve body are matched components. If either is damaged you must
replace both with a matched pair of components.
2. Reassemble the valve components as shown below. Make sure that the groove in the
valve rotor locates correctly over the pin on the valve body.
3. Screw the securing bolt into the spindle, first by hand, then use the 7 mm wrench. Do
not over tighten the securing bolt.
4. Pump deionized water through the channels of the valve to make sure that the channels
are open.
5. Install the valve on the pump unit, see page 103.

Carrier Gas System M aintenance

Nonreturn Valve
If liquid enters the nonreturn valve, you must dismantle the valve and clean it.
Periodically check the nonreturn valve. If the rubber sleeve shows signs of deterioration,
replace it.
Maintenance . 107
Changing the M ercury Filter

The mercury filters (Part No. B3000274) for the flow-injection mercury system, FIMS, safely
adsorbs the entire mercury vapor that is flushed out of the FIMS-cell.
The FIMS that is fitted with this filter can be used anywhere in the laboratory; it is not
necessary to have a special fume ventilation system for the instrument.
When replacing the filter you will require a piece of the silicone exhaust tube (Part No.
B0046948) from the equipment provided with the instrument.
The mercury filter consists of an open ended polyethylene tube filled with granular active
charcoal, specially treated for adsorbing mercury. Polyethylene mesh at each end of the tube
holds the active charcoal on place.
1. Connect the silicone exhaust tube (Part No. B0046948) to the left-hand nipple on the
FIMS-cell.
2. With instruments that have the filter holder on the rear panel, cut the silicone tube so
that it reaches the filter holder.
Push one end of the mercury filter onto the silicone tube.
3. Push the mercury filter into the filter holder on the rear panel of the instrument. If there
is no filter holder, let the filter lie on the bench.
Note: Make sure that the silicone tube is not kinked or restricted and that the outlet of the filter is
not blocked.
Maintenance . 109
Changing the Air Filter

To ensure that the components inside the spectrometer are properly cooled, the air filter
must allow sufficient air intake into the spectrometer.
Check the filter regularly. If it is dirty, install a new one.
1. Switch off FIMS.
2. Open up and remove the filter cover.
3. If the old filter is dirty, remove it and insert a new filter (Part No. B0502706).
4. Press the filter cover firmly back into place.

Changing the Source Lam p
Electrical Hazard

instrument, switch off all instruments in the system and disconnect
them from the line power supply before you alter, or make any
WARNING new, electrical connections.
UV Radiation
The lamp emits intense UV radiation which can damage your eyes.
Do not gaze into a lighted lamp.
Always wear UV absorbing safety glasses when looking at the

radiation from the lamps.
Danger Électrique
Pour éviter les risques de blessures à vous-même et les dommages

à l'instrument, éteignez tous les instruments dans le système et
débranchez-les de l'alimentation de la ligne avant de modifier, ou
AVERTISSEMENT de faire des nouvelles, des connexions électriques.
Le rayonnem ent UV
La lampe émet intense rayonnement UV qui peuvent endommager

vos yeux. Ne pas regarder dans une lampe allumée.
Toujours porter des lunettes de sécurité absorbant les UV quand

on regarde le rayonnement des lampes.
Change the source lamp if the lamp fails or the intensity falls to an unacceptable level.
1. Switch off the instrument and disconnect the line cord from the line power supply.
2. Using a 2.5 mm hexagonal key remove the two screws securing the lamp cover and
pull off the cover.
3. Hook the Hg lamp removal tool (Part No. B8300243) under the lamp and carefully
pull the lamp out of the socket.
4. Hold the new lamp with a lint free cloth and carefully push it into the lamp socket
until it locks into place.
5. Replace the lamp cover and secure it with the two screws.
Maintenance . 111
Changing the Fuse
Electrical Hazard

instrument, switch OFF all instruments in the system and
disconnect them from the line power supply before you alter or
Danger Électrique
Pour éviter les risques de blessures à vous-même et les dommages

à l'instrument, éteignez tous les instruments dans le système et
AVERTISSEMENT débranchez-les de la puissance de la ligne d'alimentation avant de
modifier ou de procéder à de nouvelles connexions électriques.
The fuses are located in the fuse holder of the line power socket (receptacle) at the rear of
the instrument.
1. Switch off the instrument and disconnect the line power cord from the electrical
supply.
2. Remove the line power plug from the socket on the rear of the instrument.
3. Squeeze the two lugs at each side of the fuse holder and gently pull the fuse holder
out of the socket.
4. Remove both fuses and check them. If they have blown, discard them.
5. Insert one or two new fuses of the correct rating.
The instrument needs two, 6.3 AT, slow blow fuses (Part No. B0155576 for a pack of
10 fuses).
6. Align the lug at the top of the fuse holder with the slot in the socket. Push the fuse
holder into the socket until the lugs snap into place.
NOTE: If the new fuses blow, and the cause cannot be readily determined, then a service call is
needed.
Maintenance . 113
. 115
P arts
Parts . 117
Equipm ent Provided

PerkinElmer reserves the right to alter the schedule of equipment provided without prior
notice.
Quantity Description Part Number

1 Line cord 230 V (Europe) B0019800
1 Line cord 115 V (USA) B0073775
2 Fuses, 6.3 AT, slow blow B0155576
1 Gas tube assembly with connectors B0079873
1 FIMS-Cell Cuvette Complete B0510334
1 Silicone sleeve for FIMS-cell sample inlet B0018283
1 Silicone tubing, 3 m, for FIMS-cell exhaust outlet B0046948
1 PVC tubing, waste B0048139
1 Waste container, 4L B0156271
2 Wide neck bottle, 1000 mL B0196856
4 Adapter A B0193342
2 Adapter B B0506716
1 Adapter E B0196857
2 Adapter K B0507918
2 Adapter L B0507920
1 Adapter M B0507919
2 Connector; type I, for tubes with i.d. 1.7-3.2 mm B0199233
2 Connector; type I, for tubes with i.d. 2.4-3.2 mm B0196882
2 Connector; type II, with ¼” – 28 UNF internal thread B0196704
2 Connector; type III, T-connector for tubes with i.d. 1.5-2.5 mm B0199035
1 Sample loop 200 µL B0194048
1 Pump tube, red/red, set of 12 B0193160
1 Pump tube, yellow/blue, set of 12 B0193161
1 Pump tube, black/white, set of 12 B0508310
1 PTFE tube i.d. 1.0 mm, length 110 mm B0191058
1 Tubing Per Pump 3.18 MM BL/WH B0508310
1 Manifold assembly (gas/liquid separator with PTFE membrane,
2 manifold blocks, adapters with PTFE tubes, 5 spare B0507957
membranes).
1 FIAS-valve dismantling tool B0509590
1 Hexagonal Socket Wrench, 7mm B0853181
1 Hexagonal Key, 3 mm B0853099
1 Hexagonal Key, 2.5 mm B0853098
1 Lamp Extractor B3000243
1 Fitting Push in Metric Y 09920179
2 Rear Clamping Ring 6MM 09923472
2 Front Clamping Ring 6MM 09923473
2 Insert for Plastic Tube B0147498
2 Small Hose Adapter B0193342
1 Cable Holder with Catch B0510925
2 Union Nut 6MM 09920583
1 Nut B0018079
Quantity Description Part Number

1 LOC Nut B0048138
1 Connectors B0166485
1 1000MM PTFE Tube B0191060
1 HGA-600MS Carrier Gas Tubing x 5M B0508264
1 Mercury Filter B3000274
1 Documentation:
FIMS Hardware Guide 09931162
1 FIMS Software Guide

09931164
Parts . 119
R eplacem ent P arts

Every day you count on PerkinElmer to provide you with solutions that deliver reliable
performance, control operating costs and maximize operational time. Our complete portfolio
of consumables, parts, supplies, training and service helps you meet both routine and
demanding measurement challenges. We invest heavily in testing and validating our products
to ensure you receive guaranteed compatibility and performance-on-time, every time, for
every instrument in your laboratory.
Supplies, replacement parts, and accessories can be ordered directly from PerkinElmer, using
the part numbers quoted in the guides provided with the instrument.
See our website:
http://perkinelmer.com
PerkinElmer's catalog service offers a full selection of high-quality supplies.
To place an order for supplies and many replacement parts, request a free catalog, or ask for
information:
If you are located within the U.S., call toll free 1-800-762-4002, 8 a.m. to 8 p.m. EST. Your
order will be shipped promptly, usually within 24 hours.
If you are located outside of the U.S., call your local PerkinElmer sales or service office.
Spectrom eter P arts

Description Part Number
Fuses, 6.3 AT, slow blow, pack of 10 B0155576
Mercury Lamp B0510487
Lamp Removing Tool B3000243
Tube-Connector Key to tighten the screw fittings B0501315
Hexagonal Key, 3mm B0853099
Carrier Gas System P arts

Nonreturn Valve B0198111
Rubber Sleeve for Nonreturn Valve B0135123
Supply Gas (argon or nitrogen) tubing assembly B0079873

Cell holder B300-0227
Tubing connection B300-0228
The sizes of the different O-rings:

B0146408 (12.2 x 1.78)
B0500748 (15.6 x 1.78)
B0507230 (6.07 x 1.78)
FI AS-Valve P arts

Five-port Valve, complete B0507914
Valve Spindle Assembly B3000002
O-Ring 18. 77 x 178 mm B0501250
Pressure Plate B0507908
Washer B0509589
Securing Bolt B0508808
FIAS-Valve Dismantling tool B0509590
Parts . 121
Complete Manifold Assembly (B0507957)
Manifold
B050-7957
Separator Cover O-rings in Separator Cover:

B050-8507 Large B050-8312
Small B050-1250
Base Plate
B314-0661
Pump Tubes
Solvent Resistant Pump Tubing
If you require solvent resistant pump tubing, see the current PerkinElmer price lists.
Acid Resistant Pump Tubes
i.d. (mm) Color of Collars Material Part number

0.38 orange/green Tygon® B0506736
0.51 orange/yellow Tygon® B0506737
0.64 orange/white Tygon® B0506738
0.76 black/black Tygon® B0506058
0.89 orange/orange Tygon® B0506740
0.95 white/black Tygon® B0506741
1.02 white/white Tygon® B0506742
1.14 red/red Tygon® B0193160
1.52 yellow/blue Tygon® B0193161
2.06 violet/violet Tygon® B0199034
3.18 black/white Tygon® B0508310
Parts . 123
Parts . 125
PTFE tubing Assemblies

NOTE: The color of the screw fitting denotes the tubing i.d.
i.d. (mm) Color of Screw Length Part number
Fittings (mm)
0.5 red 100 B0506706
0.5 red 180 B0506707
0.5 red 170 B0506708
0.5 red 220 B0506709
1.0 blue 110 B0191058
1.0 blue 300 B0198097
1.0 blue 700 B0191059
1.0 blue 1000 B0191060
1.75 black 250 B0198099
1.75 black 450 B0198100
Sample Loops
Size (µL) Part number
50 B0506714
100 B0506715
200 B0194048
500 B0194049
1000 B0501000
Reaction Loops
Size /Type Part number
300 mm, 0.5 mm i.d B0506712
600 mm, 0.5 mm i.d B0506713
3-D – Reactor, Knotted PTFE Tube B0501595
Parts . 127
I ndex
reducing agent ............................................ 67
Flow Injection Valve ............................................ 59
A Flow System ........................................................ 59
About This Manual ................................................. 9 Fluid System Components ................................... 79
Adaptors and Connectors...................................... 63 Fuse
Air Filter changing ........................................................ 112
changing ........................................................ 109
Amalgam G
technique.......................................................... 68
Gas/Liquid separator ............................................ 61
Gas/Liquid Separator
C cleaning ......................................................... 102
Carrier Gas ......................................................... 60
Carrier Gas System L
maintenance ................................................... 106
Chemical Warnings .............................................. 43 Labels
Cleaning the Instrument........................................ 48 Warning Signs ................................................. 49
Connections Laboratory Requirements
carrier gas ........................................................ 73 environmental conditions ................................ 89
electrical .......................................................... 74 summary .......................................................... 89
FIMS cell ......................................................... 86 Locating
line power ........................................................ 77 accessories....................................................... 72
Conventions computer ......................................................... 72
Notes, cautions and warnings .......................... 12 instrument ....................................................... 72
text ................................................................... 12 printer .............................................................. 72
Customer Precautions ........................................... 36
M
D Maintenance Checklists ....................................... 96
Detector ................................................................ 58 Manifold............................................................... 61
cleaning ......................................................... 102
Mercury Filter
E changing ........................................................ 107
Electrical Safety.................................................... 38
EMC Compliance ................................................. 46 N
Nonreturn Valve................................................. 61
F
FCC Rules ............................................................ 46 O
FIAS Valve
cleaning.......................................................... 103 Optical.................................................................. 58
dismantling .................................................... 104
fitting ............................................................. 103
reassembling .................................................. 105
P
removing ........................................................ 103 Parts
FIMS carrier gas system .......................................... 119
-100 equipment ...................................................... 117
rear panel .................................................... 57 FIAS-valve .................................................... 120
-400 pump tubes .................................................... 122
control ......................................................... 56 spectrometer .................................................. 119
front panel ................................................... 56 Pollution Degree .................................................. 46
spectrometer Precautions.......................................................... 34
FIMS Cell Pump Tubing........................................................ 81
cleaning.......................................................... 101
FIMS-cell
checklist: .......................................................... 97 R
window Radiation Source
checklist ...................................................... 97 References ............................................................ 68
FIMS-Cell............................................................. 58 Replacement Parts .............................................. 119
Flow Injection
mercury cold trap ............................................. 66
S changing ........................................................ 110

Space Requirements ............................................. 90
Safety
EMC Compliance ............................................ 46
FCC Rules ....................................................... 46
T
general operating conditions ........................... 37 Technical Data ...................................................... 64
overview .......................................................... 33 Tubing System Installation ................................... 79
Pollution Degree.............................................. 46
Precautions ..................................................... 34
Safety Information U
electrical safety ............................................... 38 Unpacking ............................................................ 71
gases ................................................................ 44 UV Radiation........................................................ 40
toxic fumes .................................................... 45
waste disposal ................................................. 41
WEEE instructions .......................................... 47 W
Sample Loop ....................................................... 60
Warning Translations ........................................... 15
Separator Filter
Warnings .............................................................. 50
changing ........................................................ 102
WEEE Instructions ............................................... 47
Sodium Tetrahydroborate
Windows
warnings .......................................................... 42
cleaning ......................................................... 100
Source Lamp
PerkinElmer, Inc.
710 Bridgeport Avenue
Shelton, CT 06484-4794, U.S.A.
Internet: http://www.perkinelmer.com
email: info@perkinelmer.com
PerkinElmer is a registered trademark of PerkinElmer, Inc.

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09931162C FIMS Hardware Guide

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ATOMIC SPECTROMETRY

Part Number Release Publication Date

09931162 C October 2015

Or emailed to: info@perkinelmer.com

Copyright © 2015 PerkinElmer, Inc.

PerkinElmer is a registered trademark of PerkinElmer, Inc.

Safety Practices .............................................................................. 31

System Description ......................................................................... 53

Installing the FIMS Analysis System ............................................. 69

Sitting the Spectrometer and the Accessories ........................................... 72

Parts .............................................................................................. 115

About This M anual

Using this Handbook

This hardware guide is divided into following chapters:

Before You Start

Other Useful Handbook s for the FI M S Analysis

• S10 Autosampler User Documentation (if applicable).

• Flow Injection Mercury / Hydride Analyses: Recommended Analytical Conditions and

See also the FIMS Recommended Conditions window in the software.

Conventions Used in this M anual

Bold text refers to text that is displayed on the screen.

Notes, cautions and w arnings

This equipment requires no specified inspection or preventive maintenance to ensure the

Precautions for I nstrum ent

Be sure that all instrum ent operators read and understand

Veillez à ce que tous les opérateurs d'instrum ents aient lu et

Do not operate the instrum ent w ith any covers or parts

Do not attem pt to m ak e adjustm ents, replacem ents or

Dispose of w aste in accordance w ith the regulations

Conform ém ent aux pratiques de sécurité des laboratoires,

The protection provided by this equipm ent m ay be im paired if

La protection fournie par cet équipement risque d'être moins

The following precautions must be observed when using the FIMS:

Precautions for Custom ers

The laboratory manager is responsible for warning operators of this

The laboratory manager is responsible for disposing of any

WARNING Le responsable du laboratoire est responsable de l'élimination de toutes

• Appropriate venting, sample and waste collection needs to be provided.

• The waste bottle must be connected.

General Operating Conditions

If the equipment is used in a manner not specified herein, the

This equipment requires no specified inspection or preventive maintenance to ensure the

Lethal voltages are present at certain areas w ithin the

Des tensions m ortelles sont présentes dans certaines zones de

Any interruption of the protective conductor (earth ground) inside or

Terminal Cord Lead Colors

Live Brown Black

Neutral Blue White

Protective Conductor Green/Yellow Green

When working with the instrument:

• Do not attempt to make internal adjustments or replacements except as directed in the

The instrument is likely to be electrically unsafe when it:

• Shows visible damage;

• Has been subjected to prolonged storage under unfavorable conditions;

• Has been subjected to severe transport stresses.

UV Radiation-Risk of Eye Damage

La lampe émet un rayonnement UV intense susceptible de provoquer

• Use and store sodium tetrahydroborate according to manufacturer’s

• Keep sodium tetrahydroborate solutions

 Out of direct sunlight

 Away from open flames

 In an area with an efficient ventilation system

 Protect sodium tetrahydroborate solutions from temperature variations.

• Handle sodium tetrahydroborate solutions with care as they are corrosive.