Subject Topic Practice Paper - 3 Date

Chemistry Complete Syllabus PU – 12 – C 2017

Max. Marks: 70 Duration: 3hrs 15 mins

Instructions:
1. The question paper has four parts: A, B, C and D. All parts are compulsory.
2. Write balanced chemical equations and draw labeled diagrams wherever required.
3. Use log tables and the simple calculator if necessary.
(Use of scientific calculators is not allowed)

PART – A
I. Answer ALL of the following. (Each question carries 1 mark) 10 x 1 = 10
1. Mention the SI unit of boiling point elevation constant
2. Given an example for a solution liquid in solid?
3. How many number of coulombs of charge required for the oxidation of one mole of water to
oxygen?
4. Give an example for a second order reaction
5. Give an example for oil in water emulsion
6. Give the method used for the concentration of tin stone or casseterite
7. Give reason majority of noble gas compounds are those xenon
8. In the following pair of compounds which will reach faster in SN 2 reaction with

OH ,  CH3 3 Br & CH3 Br

9. Draw the structure of the following compound 3- methyl butanal

10. Name the vitamin responsible for coagulation of blood

PART – B
II. Answer any FIVE of the following. (Each question carries 2 marks) 5 x 2 = 10
11. Explain the germ ferrimagnetism. Give an example
12. Mention any two methods to prevent corrosion of metal
13. From the graph given below, what does the slope and intercept indicates?

ln k

14. Give reasons “transition elements are known to form

1/ t
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 Subject Topic Practice Paper - 3 Date

Chemistry Complete Syllabus PU – 12 – C 2017

complex compounds
15. Give one example each of the following:
(i) Dihydric alcohol (ii) Trihydric alcohol
16. What happens when sodium acetate alone is heated strongly, give the reaction
17. What is (a) Drug target (b) Receptor
18. Mention a sue of (a) an ionic detergents (b) cationic detergents

PART – C
III. Answer any FIVE of the following. (Each question carries 3 marks) 5 x 3 = 15
19. Draw the Ellingham diagram for the formation of FeO from Fe, Co from C and CO2 from Co,

suggest a suitable reducing agent for the reduction of Fe2O3 below 1073K and above 1073K

temperature. (3)

20. (a) How is ammonia used to detect Cu 2 ion? Give the equation (2+1)
(b) Write the structure of orthophosphorus acid
21. (a) Complete the following equation (2+1)

(i) 2SO2  g   O2  g  

VO
2 5  ........

(ii) 2I   aq   H 2O 1  O2  g  
 ......  ........  ........

(b) Give reason ozone is thermodynamically unstable with respect to oxygen

22. (a) Complete the following equation (1+1+1)

2KMnO4  16HCl 
 ........  ........  ........  ........

(b) Arrange the following oxocids of halogens in the increasing order of acidic strength;
HClO4 , HClO2 , HClO3 , HClO

(c) Write structure of perchloric acid

23. Give reason: (1+1+1)
(a) Transition metal exhibits higher enthalpies of automisation

(b) Cr 2 is a stronger reducing agent than Fe2

(c) The highest oxidation state is exhibited by oxoanions of the metal
24. (a) Name an important alloy which contains some of the lanthanoid metal and mention it use
(2+1)
(b) Name the common oxidation state of Actinoids

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 Subject Topic Practice Paper - 3 Date

Chemistry Complete Syllabus PU – 12 – C 2017

25. (a) Draw the Facial and Meridional isomers for Co  NH3 3  NO2 3  (2+1)

(b) What is spectrochemical series?

26. (a) Write the IUPAC name for the following coordination compounds

(i) K3  Al  C2O4 3  (ii) CoCl2  en 2  (2+1)

(b) Mention a difference between a double salt and complex compound

PART – D (i)
IV. Answer any THREE of the following. (Each question carries 5 marks) 3 x 5 = 15

27. (a) In corundum, oxide ions are arranged in hcp arrangement and Al  ions occupy 2/3rd of the
octahedral voids. What is the formula of the compound
(b) Mention any two applications of the semiconductors
(c) Which stoicheometric defect increases the density of the solid (2+2+1)

28. (a) The mole fraction of helium in a saturated solution at is 1.2 106 . Find the pressure of
helium above the solution. Given Henry’s constant at 20c  144.97k bar . (2)

(b) Give reason:

(i) NaCl dissolves in water but not in benzene
(ii) Solution of chloroform and acetone shows negative deviation from Raoult’s law
(iii) Raisen Swell in size when kept in water (1+1+1)
29. (a) Calculate the equilibrium constant of the reaction at 298 K (3+2)

cu  s   2 Ag   aq  
 Cu 2  aq   2 Ag  s  , Given E cell  0.46V

(b) Write the reaction occurring at anode and cathode in mercury cell
30. (a) Derive an integrated rate equation for the velocity constant for a first order gas phase reaction
(b) Write the rate constant equation by combining energy factor and orientation factor
(c) What is an activated complex (3+1+1)
31. (a) Mention any two differences between adsorption and absorption
(b) Define the terms:
(i) Critical micelle concentration
(ii) Electro Kinetic potential or Zeta potential
(c) What is a promoter? (2+2+1)

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 Subject Topic Practice Paper - 3 Date

Chemistry Complete Syllabus PU – 12 – C 2017

PART – D (ii)
V. Answer any FOUR of the following. (Each question carries 5 marks) 4 x 5 = 20
32. (a) Name the type of isomerism shown by lactic acid. Write its isomers
(b) Identify A and B in the following reaction
Cl

NaOH H2 O
A B
623 K, (Pressure) 
300 atm

(c) How do polar solvents help in the first step of SN 1 mechanism (2+2+1)
33. (a) Explain hydration of propene in the presence of concentrated H 2 SO4

(b) Give the structure of A and B

OH

(i) CHCl 3 + NaOH (i) NaOH / CO2

340K 410K
A + B
(ii) H
O CH3
(c) Give the IUPAC name for (2+2+1)

34. (a) Arrange the following carbonyl compounds in the increasing order of their reactivity with
nuclepluttic addition reactions and give reason; Ethanal, Proponal, Propanone, Butanone
(b) Give two test to distinguish between propanal and propanone
(c) Complete the following reaction
COOH
Fe Br3
+ Br2 + HBr (2+2+1)


35. (a) write the IUPAC name for;

N(CH 3)2
(i)

CH3

(ii) C2H5 N CH2CH3

(b) What are coupling reaction? Give an example
(c) Given reason: Primary amines have higher boiling point than tertiary amines. (2+2+1)
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 Subject Topic Practice Paper - 3 Date

Chemistry Complete Syllabus PU – 12 – C 2017

36. (a) Write the Haworth’s structure of   D  ribose

(b) Mention any two structural differences between starch and cellulose
(c) Give the name of one male hormone (3+2)
37. (a) Give one example each for the following polymers:
(i) Linear polymer (ii) Branched chain polymer
(iii) Cross linked or Network polymer
(b) Which type of polymers are called chain growth polymers and step growth polymers
(3+2)