Kinetic Data Generation CM1:

450 For 2nd order:

400
350
300
Time250
(hr) XA XA/(1- XA)
Xa/(1-Xa)

200
150
100
0 50 0 0
0
0 5 10 15 20 25
8 0.87 Time 6.69

22 0.9976 415.667

Plot is not fitted to 2nd order

7 For 1st order:

6
5
-ln(1-Xa)

4 Time (hr) XA -ln(1- XA)

3
2
1 0 0 0
0
0 5 10 15 20 25
8 Time0.87 2.04

22 0.9976 6.03

Concentration time graph is fitted for first order.

Slope = (6.03-0) / (22-0) = 0.2741 hr-1

K = 0.2741 hr -1

Reactor Design Equation

1 1
t= ln ⁡( )
K 1−X A
 Kinetic Data Generation X9:

For 2nd order:

40
Time (hr) XA XA/(1- XA) 35
30
25
0 0 0
20
15
14 0.79 3.79 10
5
0
24 0.97 35.49 0 5 10 15 20 25 30

Plot is not fitted to 2nd order

For 1st order:

Time (hr) XA -ln(1- XA) Xa

4
3.5
0 0 0 3
2.5
2
14 0.79 1.56 1.5
1
0.5
0
24 0.97 3.59 0 5 10 15 20 25 30

Concentration time graph is fitted for first order.

Slope = (3.59-0) / (24-0) = 0.149 hr-1

K = 0.149 hr -1

1 1
Reactor Design Equation t= ln ⁡( )
K 1−X A
 Kinetic Data Generation X4:

For 2nd order:

700
Time (hr) XA XA/(1- XA) 600
500
0 0 0 400
300

3 0.985 65.66 200

100

6 0.9983 415.667 0
0 1 2 3 4 5 6 7

Plot is not fitted to 2nd order

For 1st order:

7
Time (hr) XA -ln(1- XA) 6
5
0 0 0 4
3

3 0.985 5.02 2
1
0
6 0.9983 6.37 0 1 2 3 4 5 6 7

Concentration time graph is better fitted for 1st order.

Slope = (6.37-0) / (6-0) = 1.06 hr-1

K = 1.06 hr -1

Reactor Design Equation

1 1
t= ⁡ln ( )
K 1−X A
 Kinetic Data Generation CM6:

For 2nd order:

Time (hr) XA XA/(1- XA) Xa

20

0 0 0 15

10
3 0.933 13.94
5

19 0.945 17.18 0
0 2 4 6 8 10 12 14 16 18 20

Plot is not fitted to 2nd order

For 1st order:

Time (hr) XA -ln(1- XA) Xa

3.5
3
0 0 0 2.5
2
1.5
3 0.933 2.07
1
0.5
19 0.945 2.9 0
0 2 4 6 8 10 12 14 16 18 20

Plot is not fitted to 1st order