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h i g h l i g h t s
SCC mixture incorporating pumice powder possesses better slump flow retention.
Pumice replacement of 30% gives the best performance hardened and fresh test results.
Pumice and silica fume blended cement satisfies all the criteria of EFNARC limit.
A strong relationship between superplasticizer demand and slump loss of the mixtures.
a r t i c l e i n f o a b s t r a c t
Article history: This paper presents the results of an experimental study carried out to investigate the performance of
Received 19 July 2016 self-compacting concrete (SCC) mixes, which produced using blended binders containing pumice powder
Received in revised form 8 November 2016 in various proportions. As a volcanic material, pumice possesses pozzolanic properties and can effectively
Accepted 18 December 2016
be added to the concrete mixture. The influence of pumice powder on the self-compactibility properties
such as slump flow, V-funnel flow, U-box and J-ring flow and compressive strength was investigated.
Also, in order to clearly understand the effect of pumice powder on the workability retention of concrete,
Keywords:
the slumps were measured with elapsed time. The comparison has been made between SCC with pumice
Self-compacting concrete
Pumice
powder to other mixtures with fly ash and slag through tests on fresh and hardened concrete. In all of the
Silica fume mixtures the portland cement was partially replaced from 10% to 50% by pumice, fly ash and slag. The
Fly ash incorporation of more than 30% of pozzolanic materials in the binary blended portland cement mixtures
Slag results in a significant decline in the fresh and hardened test results. In addition, to improve the proper-
Fresh properties ties of SCC containing pumice, the ternary blended cement replacement with pumice and silica fume (SF)
SP demand was developed. The results revealed that incorporation of SF substantially enhanced the properties of the
Slump loss mixtures.
Compressive strength
Ó 2016 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.conbuildmat.2016.12.090
0950-0618/Ó 2016 Elsevier Ltd. All rights reserved.
R. Bani Ardalan et al. / Construction and Building Materials 134 (2017) 116–122 117
and slag, substantially increase the workability, durability and 20,000 m2/kg. The fly ash class F and slag used have a specific grav-
long-term properties of concrete [11–14]. Recently, pumice pow- ity of 2.2 and 2.85 and fineness of 260 and 445 m2/kg, respectively.
der, which is a sub product of extraction and manufacturing of The chemical compositions of the cementitious materials are
pumice was added to the SCC mixture as a supplementary cement- shown in Table 1.
ing material and its incorporation effect on the fresh properties of The coarse aggregates have a maximum size of 19 mm, a speci-
SCC was investigated. Volcanic materials like pumice have poz- fic gravity of 2.78 and water absorption of 1.9%. The natural river
zolanic properties so that it is possible to use in SCC manufacturing fine aggregate in this study with fineness modulus of 3.2, the speci-
with a double effect: on one hand as filler and on another hand as a fic gravity of 2.6 and water absorption of 2.3% was used. The par-
pozzolanic element in the mixture [3]. It was proved that pumice ticle size gradation obtained through the sieve analysis of the
use is applicable in SCC production as no segregation and bleeding fine and coarse aggregates are given in Table 2. Superplasticizer
were observed [15]. Pumice is a natural material of volcanic origin (SP) which is a high-range water-reducing, plays a vital role in
which is produced during the solidification of lava through the SCC mixture and help SCC flow under its own weight [23]. A
release of gases. As volcanic activities are common phenomena in polycarboxylic-ether type SP with a specific gravity of 1.08 was
various parts of the world, volcanic debris like pumice is found employed to achieve the desired workability in all concrete
abundantly [16]. Since pumice has lower weight compared other mixtures.
aggregates, it has been used extensively as a coarse or fine aggre-
gate in lightweight concrete mixtures [17]. In a recent study, Gran-
2.2. Mix design
ata [3] investigated the applicability of pumice powder as filler in
SCC and hardened states, and its pozzolanicity was confirmed. SCC
In this study several SCC mixtures were made having a constant
containing pumice presented good workability properties and
water to cementitious materials ratio (w/cm) of 0.38 and fixed
achieved reasonable compressive strength after 28 days of curing.
cementitious materials content of 500 kg/m3, incorporating differ-
It is well understood that when SCC is used as a ready-mixed
ent replacement levels of pumice, fly ash and slag (0–50% weight of
concrete, the fresh property requirements need to be met at the
cement) in binary mixes, in order to evaluate and compare the
time of placement. Thus the effect of production and transport
effect of these mineral admixtures on properties of SCC. Also, tern-
on the workability properties of SCC must be considered in the ini-
ary cementitious blends of pumice and silica fume were designed
tial and time dependent workability testing of SCC [18–20]. Slump
to clarify the influence of these mineral admixtures on properties
loss is known to be one of the main reasons of concrete strength
of SCC. Superplasticizer was adjusted to attain a slump flow of
and durability [21]. Since the conditions for the transport process
650 ± 25 mm. Details of the mix proportions are shown in Table 3.
involved in concrete’s degradation mechanism strongly depend
on its pore structure [22], still more investigation is required to
account for a clear understanding of required quantity of super- 2.3. Specimen preparation and testing methods
plasticizers (SP) to achieve superior workability and placeability.
Workability properties of SCC containing pumice powder espe- All the materials were mixed using a rotary drum mixer with a
cially with respect to other mineral admixtures performance which maximum capacity of 80 L. SCC production requires careful consid-
is still lacking in the literature. To do so, the effect of using pumice, eration in terms of mixing sequence and duration as to supply sim-
fly ash and slag as supplementary cementitious materials in binary ilar homogeneity and uniformity in all mixtures [24]. First, the dry
(two-component) blends at different levels of replacements was ingredients were combined. Next, the wet ingredients (water and
taken into account on fresh and hardened properties. For each mix- SP) were added, and the ingredients were mixed until a homoge-
ture, the SP dosage for obtaining initial slump flow value of neous mixture was achieved. The concrete was designed to give
650 ± 25 mm and also slump flow loss over time up to 50 min after a slump flow of 650 ± 25 mm according to EFNARC committee
casting was measured. The aforementioned properties were mea- [25] recommendation which was obtainable by using SP in varying
sured for ternary (three-component) systems of pumice and silica dosage. When the initial slump flow of the SCC was deemed satis-
fume as well. The fresh properties of SCC, including the slump flow, factory, the SCC was placed into five slump cones and the slump
U-box, V-funnel flow and J-ring flow were investigated. Also, the flow test was conducted at intervals of 10 min, i.e. ten-minutes
effectiveness of the mineral admixtures on the compressive after the initial slump flow test, one slump cone was lifted, after
strength of SCCs was assessed at 7, 28 and 90 days. Finally, the another 10 min another cone was lifted and so on. The slump flow
optimum percentage of cement replacement by pumice was pro- value was recorded for five cones for each mixture.
posed for binary and ternary mixtures considering the results of Besides, upon achieving target slump flow, the V-funnel, J-ring
the experiments. and U-box self-compactibility tests were conducted on the fresh
properties for each mixture in accordance with EFNARC standards,
in the following order:
2. Experimental study
(a) J-ring flow test (flow diameter and difference in concrete
2.1. Materials height inside and outside J-ring (h2–h1)). The J-Ring is a cage
of rebar that is set up around the slump cone. The slump
A commercially available ASTM type II portland cement with flow test is run both with and without the J-Ring in place
specific gravity of 3.16 and fineness of 290 m2/kg has been used and the passing ability is the difference in slump flow;
for the production of all SCC mixtures. The volcanic pumice used (b) V-funnel flow test (time taken by concrete to flow through
in this experimental program, which has a specific gravity of 2.85 V-funnel after 10 s (T10 s), time taken by concrete to flow
and a fineness of 3200 m2/kg was collected from the resources in through V-funnel after 5 min (T5 min)). The described
Khash area, Iran. As presented in Table 1, the total content of V-funnel test is used to determine the filling ability (flow
SiO2, Al2O3, and Fe2O3 in the pumice was approximately 73% which ability) of the concrete with a maximum aggregate size of
is more than the minimum requirement (70%) specified in ASTM C 20 mm. The funnel is filled with about 12 L of concrete and
618 for natural pozzolans. the time taken for it to flow through the apparatus mea-
Silica fume was obtained from Azna ferro-silicon alloy manufac- sured. If the concrete shows segregation, then the flow time
turer with a specific gravity of 2.35 and a specific surface area of will increase significantly.
118 R. Bani Ardalan et al. / Construction and Building Materials 134 (2017) 116–122
Table 1
Chemical composition of binders.
Chemical properties
Cement Slag Fly ash Pumice Silica Fume
SiO2 20.03 34.9 61.3 51.2 86.2
Al2O3 5.53 13.9 28.8 20.7 1.44
Fe2O3 3.63 0.52 4.98 1.24 0.2
CaO 62.25 36.8 1.05 6.0 3.06
MgO 3.42 10.6 0.63 1.6 1.32
SO3 2.23 0.58 0.13 0.44 0.34
Na2O 0.3 – 0.24 – –
K2O 0.73 – 1.40 – –
L.O.I CO2 + H2O – – – – –
Polymer Coated – – – – –
Physical properties
Specific gravity (kg/m3) 3150 2850 2200 2700 2350
Blaine (m2/kg) 290 445 342 480 20,000
Table 2 covered with plastic sheets and water saturated burlap and left
Sieve analysis of the fine and coarse aggregates. at room temperature for 24 h. the specimens were demoulded
Sieve number (inch) Sieve size(mm) Percentage passing (%) 24 h after casting and were cured in lime-saturated water at
Coarse aggregate Fine aggregate
20 ± 2 °C until the testing day.
Compressive strength tests were performed with a loading rate
1 25 100 100
3/4 19 83.25 100
of 0.5 N/mm2/s at the age of 7, 28 and 90 days with a testing
3/8 9.5 10.65 100 machine having a capacity of 2000 kN. The average compressive
#4 4.75 0.1 97.8 strength of three specimens was considered for each age.
#8 2.36 0 85.6
#16 1.18 0 55.3
#30 0.6 0 24 3. Test results and discussion
#50 0.3 0 4.6
#100 0.15 0 0.3 3.1. Fresh state properties
3.1.1. SP demand
(c) U-box test (difference in height of concrete in two chambers The required SP dosage to achieve the target slump flow of
(H2–H1)). The apparatus consists of a vessel that is divided 650 ± 25 mm of all binary mixes is shown in Fig. 1. The SP dosage
by a middle wall into two compartments; an opening with of the pumice blends was significantly higher than that of other
a sliding gate is fitted between the two sections. The left- mixtures and the control concrete. The higher the replacement of
hand section is filled with about 20 L of concrete then the cement by pumice, the more SP was required to achieve the target
gate is lifted and the concrete flows upwards into the other slump flow, which probably stemmed from the large amount of
section. The height of the concrete in both sections is pores in the frame structure and high surface area of pumice and
measured. in turn leads to increased water demand. A binder having greater
surface area requires more water to obtain a given slump flow,
Then the fresh concrete was placed without any vibration into so more SP is required to keep the content of water constant [26].
the steel cube moulds of 150 mm dimension for compressive On the other hand, the use of fly ash and slag in the mixes
strength measurements. After casting, all the specimens were decreased the required SP to gain desired slump flow as depicted
Table 3
Mix proportions of concrete (kg/m3).
Mix description Mix ID Water Coarse aggregate Fine aggregate Cement Fly ash Slag Silica fume Pumice
Control M1 191 580 1070 500 0 – – –
10FA M2 191 590 1063 450 50 – – –
20FA M3 191 584 1052 400 100 – – –
30FA M4 191 578 1040 350 150 – – –
40FA M5 191 571 1029 300 200 – – –
50FA M6 191 565 1017 250 250 – – –
10GGBFS M7 191 595 1072 450 – 50 – –
20 GGBFS M8 191 594 1069 400 – 100 – –
30 GGBFS M9 191 592 1066 350 – 150 – –
40 GGBFS M10 191 590 1063 300 – 200 – –
50 GGBFS M11 191 580 1069 250 – 250 – –
10PU M12 191 595 1072 450 – – – 50
20 PU M13 191 594 1069 400 – – – 100
30 PU M14 191 592 1066 350 – – – 150
40 PU M15 191 590 1063 300 – – – 200
50 PU M16 191 589 1060 250 – – – 250
25PU5SF M17 191 590 1063 350 – – 25 125
45PU5SF M18 191 587 1057 250 – – 25 225
40PU10SF M19 191 584 1051 200 – – 50 200
R. Bani Ardalan et al. / Construction and Building Materials 134 (2017) 116–122 119
0.6 200
175
0.3 100
75
0.2
50
0.1 25
0 0
ctrl 10 20 30 40 50 ctrl 10 20 30 40 50
replacement level (%)
replacement level (%)
Fig. 3. Relative slump flow loss of binary mixtures after 50 min.
Fig. 1. SP dosage of binary concrete mixes to obtain target fluidity.
14
slump loss (cm)
0.7
12
0.6
10
0.5
8
0.4
6
0.3
4
0.2
2
0.1
0
0
25PU5SF
45PU5SF
40PU10SF
ctrl
25PU5SF
45PU5SF
40PU10SF
Ctrl
Fig. 2. SP dosage of ternary concrete mixes to obtain target fluidity. Fig. 4. Slump flow loss of ternary mixtures after 50 min.
120 R. Bani Ardalan et al. / Construction and Building Materials 134 (2017) 116–122
0.6 measurements of some mixtures (M1, M2, M3, M12, M13, and
SP demand(% by binder weight)
M17) did not hit the lower limit which shows that the concrete
0.5 with FA and PU at low level of replacement, up to 20%, has low vis-
cosity and increase in the dosage value of the minerals led to
0.4
increasing in the viscosity.
0.3 In general, the authors observed that all of the moulds were
filled without the need for vibration and no bleeding or segregation
0.2 was observed for any of mixtures during the slump flow test.
Although most of the mixtures did not satisfy the EFNARC recom-
0.1 mended criteria for the J-ring test, they were found to usually pos-
sess enough passing ability. Also, the U-box results for the EFNARC
0
limitations might be too strict to account for passing ability by the
0 5 10 15
J-ring test.
Slump loss (cm)
Table 4
Fresh properties of SCC mixtures.
Mix description Mix ID Slump flow mm J-ring mm U-box mm V-funnel flow time (s)
Control M1 650 10 5 5
10FA M2 650 10 10 5
20FA M3 650 10 10 5
30FA M4 650 20 15 7
40FA M5 650 30 20 7
50FA M6 650 30 20 8
10GGBFS M7 650 15 15 8
20 GGBFS M8 650 15 10 8
30 GGBFS M9 650 20 10 9
40 GGBFS M10 650 20 5 7
50 GGBFS M11 650 30 5 7
10PU M12 650 10 10 5
20 PU M13 650 20 10 5
30 PU M14 650 20 15 7
40 PU M15 650 30 20 8
50 PU M16 640 30 25 9
25PU5SF M17 650 10 20 5
45PU5SF M18 650 10 10 6
40PU10SF M19 650 10 10 6
Acceptance criteria for SCC [25]
Min 650 0 0 6
Max 800 10 30 12
R. Bani Ardalan et al. / Construction and Building Materials 134 (2017) 116–122 121
60.0
50.0
50.0
40.0 40.0
30.0 30.0
20.0
20.0
10.0
10.0 0.0
45PU5SF
25PU5SF
40PU10SF
Ctrl
0.0
20FA
30FA
ctrl
10FA
40FA
50FA
Fig. 6. Variation of compressive strength with concrete mixtures incorporating Fig. 9. Variation of compressive strength with concrete mixtures incorporating
various amount of fly ash. various amount of pumice and silica fume.
4. Conclusions
7 days 28 days 90 days
60.0 An experimental program is carried out to investigate the pos-
Compressive Strength (MPa)
20PU
30PU
40PU
50PU
10Pu
60.0
containing pumice need higher SP dosage than fly ash to reach
50.0 the desired value.
40.0 5. The relation between the amounts of superplasticizer used for
obtaining the initial slump of concrete different in the composi-
30.0 tion is linear with a correlation coefficient of 0.83.
20.0 6. All the binary mixtures satisfied the limits for the U-box and V-
funnel tests while most of them did not fulfill the EFNARC rec-
10.0 ommendation for the J-ring test. On the other hand, the ternary
0.0 blends of cement, pumice and silica fume yielded satisfactory
performance in all the tests.
ctrl
10GGBFS
20GGBFS
30GGBFS
40GGBFS
50GGBFS
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