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h> I loplial (lc< Idlin',
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100, ATI* Ik formed Inside niltocliondtiii at
'*• Ii, Oxysomc
M'OHx d, inner membrane
Answer of 2015
1 .U 2,d 3.a 4,a 5,0
6 ,a 7,c 0.c 9.a 10,a
11,(1 12,a 13.1) 14,b 15.d
16.1) 17,c IB.b 19.b 20.1)
2 1 , 1) 22,a 23.1) 24,d 25.3
26-c 27.6 20.c 29.a 30.b
31.c 32.1) 33.b 34.1) 35.a
36.1) 37.c 30, a 39.a 40.1)
41.a 4 2 ,h 43.b 44.b 4 5 .C
46,c 47,c 48,d 49,b 50.b
51.1) 5 2 .C 53. b 54.b 55.c
56.a 57.a 50.c 59,b 60.a
61.a 62,c 63.(1 64.b 65. c
66.c 67.1) 60.a 69.c 70,c
7 .1 .C 72.c 73.1) 74.c 75.d
76.1) 77.C 70.a 79,a OO.b
81.1) 02.d 83,a 04.b 05.d
B6.(J 07.a 00,a 09.d 90,c
91.a 92.d 93.d 94.a 95.b
96,b 97.a 90.a 99.a lOO.b
1. Ans: (;»)<§>
• If the valency of element 'M' is x, then its
chloride Is MCI*.
We have,
Molecular wt. of MCI* = 2 * vapour density of
MCI*
or, Atomic wl of M + x x Atomic wt, of Cl
= 2 x 60
or, Valency x Eq.wt of M = x x 35,5 = 120
Atomic wt.,
ce Solved Questions 11 93 11
Mnl.Wt. of MClx
Atomic vvt. of element 'M'
. Eq.wt fo M 35.5
01’ Eq.wt of M
2 * v.D of MClx
“ Valency x cq.wt of M
[v Eq. \vt of MClx =Eq.wt of M + Eq.wt of Cl]
4 + 35.5 2 x 60
or' 4 = 4 xx
or, x = 3.03*3
A t a glance,
.... Mol.wt
'■ k q - w t o t a c l d T ^
(Basicity= No. of replaceable H+or replaced
H+ in chemical rxn)
For eg: Basicity of H 3 P O 4 = 3
But Basicity of H 3 PO3 =2
0
T
... H -O -P -O -H
I
0
H
0
t Replaceable H+
H -0 - P -< © * ^
li
Molecular wt.
ii. Eq.wt base = Acidity
Eq.wt o f H2SO4 = 1 - 98
KzCr207+4H2S0.i—>K2S04+Ci‘2(S04j3+H20+3[oj
Here,
Change in O.N. of single Cr=(+6)-(-t-3) = 3
Since .1 molecule of K2CV2O7 has 2 Cr atoms,
So,
Total change in O.N. per molecule = 2x3 = 6
296
Eq. wt ofKzCr207 = = 49
v. Eq. wt by H2 displacement/oxide
form ation/ chloride formation method:
Eq. wt of metal
_ w t of metal x fEq.wt of respective element)
~w t of respective element combined or displaced
= wt. of metal x (volume occupied by eq.wt of
H2 or 0 2 or Clz at STP) + (Vol. of lh
displaced by metal or O2 or CI2 combined In
ml at STP)
Here,
■ Volume occupied by 2gm of Hz/32 gm of
Oz/71 gm of Cl2 fat STP) =22.4 L
Volume occupied by 1.008 gm of H2
11200ml
- Volume occupied by Sgm (eq.wt) of O2 -
22400
~ J — = 5600 mb
For this,
= Pascal sec.
Since, l poiseulle = 1 decapoise = 1 Pascal
second so, option a is the answer and others
are excluded.
At a glance,
* Dimensions of q = [MLr1T*1]
• Viscosity is friction existing in fluid
• CC.S u n it of viscosity is poise
* Viscosity for liquid arises from intermolecular
force of attraction.
A n s:fa )© >
# jn the reaction, water mSlecule is removed
from intramolecular dehydration. In the
reaction, there is no change in oxidation state
j e neither species is oxidised or reduced. So,
options b, c & d is not suitable, as bleaching is
At a glance,
O r d e r o f p m (n) R ate law
Zero K -~
K " dt
2.303 , <
r ~ K= , * lo g (
t
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also oxidation (permanent type) or reduction
(temporary type). So. HsSO* acts as dehydrating
agent.
At a glance,
• Cone. H2SO4 act as both intermolecuiar and
intramolecular dehydrating agent as well as
oxidizing agent.
• Other dehydrating agents are: P2O5, anhydrous
COCh, etc
« Oxidising agent oxidizes other but itself gets
reduced.
• Generally, compounds with atom in higher O.S,
+6
are oxidising agent Eg: H 2 S O 4
• Reducing agent reduces other but itself gets
oxidized generally, compounds with atom in
lower O.S. eg: H2S-2
• Bleaching agent:
- Permanent: O3, H 2O 2, CI2 water, CaOCte
- Temporary:S02
Dry: O3 [Others are wet i.e. bleach when
contact with water)
0 Na202 + dil water —> Soda bleach/ oxone-> used
______ to bleach delicate fibers.
7. Ans: fc] ©
• Half life i.e. time for the no of molecules left
unreacted be half is reduced to 20 yrs from 40
yrs, for the same am ount o f substance, That
means rate of reaction is quadrupled on
doubling the concentration which ultimately
implies it's a 2nd order reaction. Alternatively,
1
we have. ti/2oc^7p
V Unit o f K
Rate eqn H alf life __ ^
a molL-^S-J
R = k[A]° ___J
0.693 S'1
2V-*
II
Ti/z- K
/R ? C\ (Ctb)»CH0H - S hZ S Z S L h c h ,) ! - c = 0 h. h zT
a- l°/2°/3° = Red Blue colourless (Acetone)
ii. Action with heated Cu/Dehydrogenation (CHaJjCOH —£H/5Z3K_^ ciia-Caaij
(Removal of H:) * © dehydration
s
C113
(Isobutene] (not dehydrogenation)
CH3CH2OH —Cu /573-^ ->CH3 - CHO + Hz t iii. O xidation:
(Ethanol) (Ethanal)
P ”) R - CHi0H - (HYKM nO.) | R _ C0QH
0 0
CHi
A t a g la n c e , or, N = 2 x 18 = 36 N
• Normality * Eq.wt = Molarity x Molecular wt. So, No. of gm equivalent = Nx V [V -» in L]
0 Actually,
C2H5OH CHsCHO + HC1
Cl ^ (Acetaldehyde)
(0=180°)
CH3CHO ^lz(ey °lve<y CChCHO(Chloral)
NaOH remaiped ril/,,
j jAnsrfbl® 1 = 5 (Chloroform)
According to law of equivalence. Note: Electrolysis of aq. NaCl results in
evolution of CI2 and \h as Na remains to the left
N:Vt = N:V» of H and Cl to the right of OH in electrochemical
or, 0,5 x 100=02 * (100 + x) series. Hence, in solution Na+ and OH- are
remaining (From ID, OH*, Na+& C1-).
or, SO = 20 + 02x
18. Ans: (b) ©
^___orat = lS0ml
Concept:
Ans: (d) <8
♦ Vulcanization is the process of heating natural
* Dehydration of alcohol has ^^ku^'snecific ruher with sulphur or sulphur compound so
carbocation as intermediate that sulphur linkage (cross links) is established.
Hence, polymer becomes more elastic.
At a glance,
. For dissolution of salt, Hydration energy >
lattice energy
. Some ionic salts like CaFz, BaSO-i , PbS04,etc
have lattice energy> Hydration enet gy.
• Lattice energy is energy released during the
formation of one mole of ionic compound in
crystal lattice.
• Na+& Cl- ions in lattice are bonded by
electrostatic force of attraction, So, solid NaCl
do not conduct electricity.
20. Ans: (b) ©
Concept:
• If the solubility of constituents of mixture differ
less, then process of crystallization is repeated
& is successive, which is called fractional
crystallization.
Eg: For Glucose [less soluble in water] &
fructose (more soluble]
At a glance,
• Constituents having diff. boiling point: by
distillation
• Mixture having volatile constituents by
sublimation
• Mixture having diff. density by gravimetric
separation.
21. Ans: (b] ©
Concept:
• (C2H.5]4Pb or TEL is used to increase the octane
number of fuel and hence act as fuel additive
(as anti-knocking agent]. It increases the no,
of branched chain isomer in a mixture of
straight chain and branched chain isomer.
• Straight chain paraffin' s>Branched chain
paraffin > oleffin>Aromatic hydrocarbon is the
order of knocking property.
• TEL prevents the knocking of fuel.
.!_____ Knocking of fuel causes i in octane no.
22. Ans: (a) ©
0
HCN + 2H20 — gontplete___ ^ R _ J! _ QH
hydrolysis (formic acid]
complete v r _ c - Oil
R - CN + 2HaO-
hydrolysis Carboxylic acid
of same no.
A t a glance
0
R - C =N + H2O - NH2(Amide)
fv_N + rHl____RCH2NH2
R - C=
Na/C^HsOH (Amine]
X NaCN >XCN2Hz0/rH>CH3 - C - OH
Since hydrolysis of alkyl cyanide gives
carboxyllic acid with a carbon no. greater than
alkyl group. So, the alkyl group must be methyl.
Hence, the compound x is methyl chloride is
CH3 COOH
(Acetic acid]
24, Ans:(d) ©
Concept:
• Oxides of metals like Na & Mg are basic
whereas their chlorides are neutral salts.
Oxides of Na & Mg forms hydroxides of metal,
which are basic whereas chloride of Na & Mg in
water is neutral. So, they do not have same
effect on litmus.
• A I2 O 3 in water gives Al(OH]3 which is
amphoteric whereas A IG 3 in water undergoes
cationic hydrolysis to give an acidic solution.
M m i II
Note that:
m*
or, T - mgcos90 = * lake Radioactivity means rate of radioactive
process, similarly thermal activity mean5
rate o f thermal conductance.
or. T = 3mg
• In the question, temperature difference (dm
is doubled from 10 to 20r'C and other
Self-inductance (L) = —
iio(2N)-A ( uoN-A\
•■L:= 21 =V I j =2U
Hence, inductance becomes doubled acc. to
question.
At a glance,
Self - inductance of a thin wire is 0
6
Self - inductance (L) = y
Magnetic flux linked in coil • Case of mirror & lens are different
current in coil • Concave mirror form image like convex lens
(except side)
vl
6i • Convex mirror form image like concave (except
Mutual inductance (M) = y
side)________
Magnetic flux linked in one coil 30. Ans: (a) ©
current flowing in next coil
Concept: Dimension of q = Nm Js
36. Ans: (b) © K
• As, Nnv- = Pascal p\s P » y so, It Is equivalent
Concept:
• If torque 1 = 0, angular momentum is constant to Pascal second.
or conserved, so, At a glance
hw i = I2W2 • 1 Pasec = 1 Polseullo = 10 poise => l decopnise
• Lowering of outstretched arm causes less 39. Ans:(a) ©
distribution of mass which decreases moment • According to l.nv of conservation of momentum,
of inertia [1) 3mxV + mx(-2v) « (m + 3m)Vc
• As I I s , angular velocity (w) 1s
• Angularm om entum (L) remains constant.
At a glance,
• In translational motion, it is analogous to
—>
3m m
conservation of linear momentum ( P ) or. Mv = dmVc
force applied (F) = 0 V
or, Vc = y Here Vc is common velocity after
• In planetary motion, angular moment,
collision)
constant
Note: Total Initial momentum** Final total
7. Ans: (c] © momentum and momeimim is a vector
quantity, So, the term (-2V) is written with
“ " ' a convex mirror always forms virtu al.erect
dim inished image on other side of tmrro, w.r.i respect to direction of V ,
At a glance,
real object • Conservation of linear momentum applies only
when external force during collision (l:| « 0 ,
A a glance, virtua, erect and
A concave mirror for , n • Above question is the case of inelastic collision.
enlarged image on same side 0 mu In, elastic collision—►momentum Akinetic
energy both conserved.
i 1 4 ftir I 4 ■
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• Fe, Co, Ni, and their alloys arc* paramagnetic
Concept'- substances.
, Bismuth (Bi), Antimony [Sb], H20, H2, He, Ne, • Electronic configuration of Cr-*[Ar] As'i3d'j,
Hg. Diamond, etc. are diamagnetic substance. which has 5 unpaired electrons in d-orbital. So,
it is paramagnetic in nature.
At a glance,
Diamagnetic Paramagnetic Ferromagnetic j
s, Relative permeability ur<l [p<po] • |Ur>l(p>po) p r » > l[ p » > p o ]
Magnetic susceptibility xm= pr-i * Xm —|Jr-l • Xm = p-r- 2
i ■l
Xm = - ve Xm = small + ve varies inversely with temp Xm = large, +ve
1 1
• Xm=oC[: [Curie law] * Xzn y J
mv2 T)2
' = 40 kw For a body with energy E, ^ = E
Ptotal 40 Kw P = y/2mE
r average— £ =20 Kw.
c 1 ll
^ a glance, yj2mE
dw At a glance,
Power (p) = — [W -» workdone)
• Short - cuts: de - Broglie w avelength for,
= d [£ xS I ds
dt f 'dt r a. Electron, a* = £
yjv
[Only if F is constant]
* If an object accelerates steadily (i.e. With b. cc-particle (2H e ^ ) = ^ i A
constant acceleration ] from rest then
Distance covered In successive equa c. Deutron [iFP]
interval of time [t] = l*3-5:7:-........~-:C2n -1]
12-1 ° ° .
• M k modulus o rd astld ly (K )- g g
= X oV' A
Here, X must bo in A. anil energy Is In electron • Shear modulus of elasticity /modulus of rigidity
volt. tangential stress
'•nJ “ shearing strain
47. A n s:(c)©
a. Electron gun: Electrical component In some • All modulus of elasticity have the dimension of
vacuum tubes that produces electron beam In a pressure i.e [ML-'T*2] is, all strain are
precise kinetic energy and used in cathode ray dim ensionless.
tube oscilloscope. 50. Ans:(b) ©
b. P ho toelectric effect: Process In which According to Newton's laws of cooling,
electrons are ejected by the Introduction of
photons (or light) d()
dt ccO - 0s
c. Cathode tube oscilloscope: Process is used
where the highly energetic beam of collimated [0s: Temperature of surrounding]
electrons strik e the tube w all to produce out From 80°C to 60°C
fluorescence at very low pressure of gas in
tube. »0 - 00 „ rrBOHO + 60 „ “x
' • 60 =
" i<[——
,v ^ 2 - 30J ..... (I)
d. T h erm ion ic effect: Effect in which heat
produces electrons donot have appropriate [•■■0must be average]
energy enough to produce fluorescence.
From 60 to 50°C.
48. Ans:(d) ©
60 - 50 .. r o6 o0 + 50
B -(li)
In parallel plate capacitor, t " KM[ — 2 2 ” -30j
coA
Cair —‘ u -to Dividing (i) by (ii)
20 _t_ 7 0 -3 0
KciiA 60 x 10 = 55 - 30
Cnird = j -0 0
t 40
„ Cmed .. or' 30 = 25
S°' Cair = K
or, t = 40s * 50s.
or, K = = 2.20 Time taken to cool down from 60°C to 50° is
50 s.
A t a glan ce,
Dielectric constant (K) or (<=r)
Botany
- For vacuum, K = 1 51. Ans: (b) ©
For air, K ^l Pancreatic Juice is an alkaline fluid (pH 7.5
0,5) secreted by the exocrine part of
For metal, K = w
pancreas(acJnl) which consist of enzymes: @
- For perfect insulator, K = 0
Eetcr's Ja il Cat Cats Corn AndLoves
Fair . . . „ qi.02 r
Dinner fancrcatlc juice:
* Fm c/ K- A s' Falr=4 n c u r ^
i _____________
Circumvalabe
papillae
Fib Form
t— Ventri cul ar
Sj’sieCa.Is} )
E izSSfe (0.7 s Syrrois f03s) Diastofe (0.5s)
Table
I Ammonotelic Ureotelic Uricotelic Aminotelic
Excrete urea Excrete uric acid Excrete amino
Excrete ammonia
acids
Not as toxic as Not as toxic as Eg: Asteria,
Mosttoxic product ammonia ammonia & urea unio
Animals subjected to excess adequate Moderate Very less
water supply
Eg. Sponges, bony fishes, ovarians, Eg. Cartilaginous
Eg. Insects, Birds
Platvheiminth, annelid, roundworm etc fishes, mammals
73, Ans:(b) © • Tranquilizers are anxiolytic (killing anxiety)
• Barbiturates and benzodiazepams are examples and sedative produce drowsiness without
of tranquilizer and sedatives inducing sleep.
• Examples of stimulants: Caffeine, theln, • Stimulant stimulates the CNS, thus increases
Amphetamine (supermandrug), cocaine. confidence and conccntrntio
• Examples of narcotics are morphine, heroine, 74. Ans:(c) ©
codeine, pethidine, etc. • Progesterone is secreted by corpus luteum,
• Examples of Hallucinogens are L.S.D,marijuana, which is further maintained by HCG hormone
ghanza, charas, bang, hashish etc: produce from implanted placenta.
sense of reaction without stimulus in actual. At a glance,
• Primordial follicle-* Primary follicle-*
Secondary follicle-* Graffian follicle with
Integuments
Body of ovule
(Nuceltost Embryosac Embryo sac
Nucellust
Nucellus
Micropyle (formed by inner integument)
unicle