Professional Documents
Culture Documents
Index
Preamble 5
1 Introduction 7
3 Full-scale experience with the SHARON process through the eyes of the operators 13
4 Reference list 23
Contact 51
SHARON | 5
Preamble
Hubert Habib
Director Infrastructure & Environment
SHARON | 7
1 Introduction
Stable High rate Ammonia Removal Over Nitrite. Full treatment capacity can be maintained even when a
limited feed load is available, which allows for sudden
SHARON is a cost-effective treatment system for the total increases in load without adverse effects on effluent
removal of nitrogen from wastewater. The system is used quality. The system can be shut down for days without
for treatment of high strength ammonia liquors. A loss of treatment capacity.
typical application is the treatment of liquors from
dewatered digested primary sludge and waste activated The process has moved beyond the development stage.
biosolids at municipal wastewater treatment plants. It Six full-scale SHARON systems have been constructed at
may also be used to treat wastewater flows from sludge large wastewater treatment plants in the Netherlands
dryers and incinerators. (located in Rotterdam, Utrecht, Zwolle, Beverwijk,
Groningen and The Hague). The SHARON plants at
SHARON is a biological nitrification/denitrification Rotterdam and Utrecht have provided more than ten
process operating with minimal sludge retention time. years of operational experience each. Operator
Due to differences in growth rates of the bacterial experiences with these systems are discussed in the next
species at the process design temperature (30-40°C) a chapter.
selection can be made wherein the nitrite oxidizing
bacteria are washed out of the system while ammonia A SHARON for New York City (USA) is operational since
oxidizing bacteria are retained along with denitrifying May 2009. SHARON systems are in preparation for
bacteria. This effectively stops the nitrification process at Geneva (CH), Paris (F), Shell Green (Manchester, UK) and
nitrite and prevents the formation of nitrate. Using this Whitlingham (Norwich, UK).
metabolic mode of operation allows for a 25% reduction
in aeration energy required for nitrification and a 40% The SHARON process has also been successfully tested
reduction in the amount of BOD required for on wastewater from the dewatering and drying of
denitrification. The separate treatment of high strength digestate from a combined manure and organic slurry
ammonia liquors significantly reduces the load on the digestion plant (MAV, Ghent, Belgium). This 50 m3/h
main treatment plant, thus increasing plant capacity wastewater flow contains high levels of ammonia and
without the need for the construction of additional basin suspended solids. It was determined that the SHARON
volume. process was preferable to conventional aerobic
treatment processes or treatment in a membrane
The SHARON process is characterized by extreme bioreactor, or to non-biological treatment methods like
process stability, due to the high growth rate of bacteria ammonia stripping.
and the absence of sludge retention. The sludge
retention time is equal to the hydraulic retention time, Compared to these other processes, the SHARON
which means that no external control of the mixed liquor process configuration was found to be technologically
suspended solids concentration is required. Basically the less complex and more flexible, and the investment and
system controls itself. The process will adjust even to operational costs were considerably lower.
strong variations in feed conditions without operator
intervention and will recover from process disturbances
in hours, rather than days.
*Cost estimate base on STOWA (1996) for WWTP capacity of 500,000 p.e.
1 The STOWA (Dutch acronym for the Foundation for Applied Water Research) coordinates and commissions research on behalf of a large number of local water administrations.
Among the 61 bodies which contribute to the STOWA, there are water boards, provinces and the Ministry of Transport, Public Works and Water Management
SHARON | 9
2 SHARON Nitrogen Removal over Nitrite
Compact systems for treatment of concentrated wastewater flows are increasingly more important, particularly
where space is lacking. A new development is the SHARON (Single reactor system for High activity Ammonia
Removal Over Nitrite). SHARON is a joint development of Grontmij, TU Delft and the Waterboard ZHEW. SHARON
is especially fit for treatment of nitrogen rejection waters from sludge digestion, the treatment of landfill
Background Advantages
Bacterial activity increases at high temperatures. At Compared to other techniques for treatment of
temperatures of 30 - 40 °C nitrifying sludge needs only a nitrogen-rich wastewaters like steam stripping, the
short residence time. At these high temperatures MAP-process or the air lift reactor, SHARON has several
nitrogen-rich wastewaters can be treated in a single advantages:
reactor. No sludge retention is required to maintain the • low investment costs
nitrifying sludge in the system as long as the hydraulic • low operational costs
retention time is equal or higher than the minimum • no chemical by-products
sludge retention time. SHARON (pat.) is specially fit for • simple operation and maintenance
treatment of nitrogen-rich wastewaters, for example • easy start-up
rejection water from the dewatering of digested sludge • insensitive to high influent SS levels
at a WWTP. Furthermore SHARON is also fit for pre- • negligible odour emission
treatment of various highly concentrated industrial
wastewaters.
NO2 N2
(Alkalinity) 30 - 40 ˚C
C-source
Mixing
Aeration
SHARON | 11
2 SHARON Nitrogen Removal over nitrite
SHARON | 12 SHARON | 13
3 Full-scale experience with the SHARON process...
...through the eyes of the operators
J.W. Mulder, J.O.J. Duin, J. Goverde, W.G. Poiesz,
H.M. van Veldhuizen, R. van Kempen, P. Roeleveld
Abstract Introduction
This paper summarizes different operating aspects and The SHARON process was developed in the 90’s of the last
experiences of several SHARON plants. The SHARON process century at the Delft University of Technology (Hellinga et al.,
is suitable for treatment of high strength ammonia 1998; Hellinga et al., 1999; STOWA, 1996). SHARON refers to
wastewaters such as reject water from dewatering of digested Stable and High activity Ammonia Removal Over Nitrite. The
sewage sludge and wastewater from sludge drying or process is especially suitable for high strength ammonia
incineration plants. The aerated retention time and nitrite wastewaters. Typical applications are treatment of reject
concentration are the two most important process water from dewatering of digested sewage sludge (Mulder et
parameters to control the ammonia outlet concentration. al., 2001; Kempen et al., 2001) and wastewater from sludge
Ammonia removal efficiencies can be over 95%, are variable drying or incineration plants. By treating reject water which is
and can be targeted according to the required needs of the only 1% of the hydraulic load of a WWTP, the nitrogen load to
main WWTP and/or to minimize overall nitrogen removal a WWTP is reduced by 10 to 30%. With side stream treatment
costs. The process is compact and simple to operate. the overall nitrogen removal efficiency of the WWTP can be
Depending on site specific circumstances there are different significantly improved. Other applications are treatment of
system configurations possible. Nine years of operating landfill leachate and wastewater from digestion of organic
experience prove that the SHARON process is sustainable and waste and manure (Notenboom et al., 2002).
highly competitive. Compared to conventional techniques
there are significant savings of energy and consumables. The SHARON process makes advantage of the difference in
Application of fine bubble aeration has further decreased growth rate of ammonia oxidizers and nitrite oxidizers which
aeration costs. Recently the use of by-products of the biofuel is illustrated in Figure 1. At higher temperatures, the ammonia
industry as COD source for denitrification has further oxidizers have a significant higher growth rate. By controlling
increased the cost effectiveness. SHARON is successfully the aerated retention time to approximately 1 day, the nitrite
applied to significantly improve the main WWTP nitrogen oxidizers will be washed out of the tank, and nitrification will
effluent quality. It proves to be a cost effective alternative for be limited to nitrite formation. The SHARON process is
conventional extension of the WWTP. operated in completely mixed reactors without sludge
retention. Therefore the hydraulic retention time (HRT) is
Keywords equal to the sludge retention time (SRT). A system without
SHARON, Nitrogen removal, nitrification, denitrification, sludge retention behaves like a chemostat. Typically the
nitrite, rejection water, side stream outlet concentration of a chemostat is independent of the
inlet concentration. A chemostat is therefore especially suited
for treatment of high strength wastewaters. Furthermore the
absence of sludge retention makes the SHARON process
insensitive to suspended solids levels that may vary in reject
water of sludge dewatering.
Figure 1 – Different growth rate of ammonia and nitrite oxidizers Figure 2 – The nitrite route
O2 (75%) O2 (25%)
SHARON | 15
3 Full-scale experience with the SHARON process
As a result of N-removal by nitrite instead of nitrate energy Therefore a 25% reduction of the aeration energy is a The advantage of a high conversion rate and the savings on System configuration
and COD are saved. Nitrification limited to nitrite saves 25% of significant decrease of the overall energy consumption. In consumables demand makes the SHARON process a compact The basic configuration of SHARON process consists of a
aeration energy. Denitrification of nitrite saves 40% of COD, as addition 30% less surplus sludge is produced and overall 20% and sustainable method for nitrogen removal. single, completely mixed tank. The tank is aerated
is indicated in Figure 2 (page 11). More than 80% of the less CO2 is emitted. intermittently to accommodate nitrification and
energy demand related to the treatment of high strength This paper presents from an operational perspective an denitrification (Figure 4). An alternative configuration consists
ammonia wastewaters is contributed to aeration energy. overview of the different SHARON plants. of two separate tanks, one for nitrification and one for
denitrification. Water is recirculated between the two
Figure 3 – From left to right and from top to bottom: SHARON plant: Rotterdam-Sluisjesdijk, Utrecht, Zwolle, Beverwijk, The Haque-Houtrust and Groningen-Garmerwolde Overview of sharon plants compartments. An advantage of this configuration is a lower
The first full scale SHARON plant came in 1997 in operation. installed aeration capacity because the aeration system can
At present six systems are implemented. In Table 1 an operate continuously at design treatment capacity. A
overview of the SHARON systems in the Netherlands is disadvantage however is the need for a recirculation flow
presented and Figure 3 contains a photograph of each plant. which restricts the maximum denitrification efficiency and
requires an extra pump. Depending on the site specific
Most plants are applied for treatment of reject water from circumstances such as space restrictions, wastewater
sludge dewatering. The first large scale SHARON system characteristics, existing available tank volume and minimum
outside the Netherlands will be built at the WWTP New York overall costs an optimum system configuration is selected.
Wards Island (Carrio, 2003). This plant will have a capacity of Table 2 presents the configuration and volume of the
5.000 kg nitrogen per day and will be operational in 2007. different full scale plants.
(Alkalinity) 30 - 40 ˚C Jet aerators or fine bubble diffusers are used for aeration. The
first SHARON plants were equipped with jet aerators. For
more recent SHARONs, material developments made
application of fine bubble diffusers in warm media possible,
C-source achieving higher oxygen transfer efficiencies. The
Mixing denitrification process requires mixing.
Aeration
SHARON | 16 SHARON | 17
3 Full-scale experience with the SHARON process
Aerated retention time control The SHARON Rotterdam-Sluisjesdijk plant was run with nitrite PH control In practice dosage of caustic can be needed in situations
The nitrification is limited to nitrite formation. A key feature to concentrations as high as 200-300 mg NO2-N/l. During a Nitrification results in a pH decrease. Because of the high inlet where due to addition of specific chemicals such as iron
obtain stable nitrite production is control of the Aerated period with complete denitrification low outlet ammonia concentrations the pH effect will be strong, and without pH chloride for dewatering, the CO2 content of the wastewater is
Retention Time (ART). At a temperature of around 35°C an concentrations (< 20 mg/l) were achieved. High nitrite levels correction nitrification will be inhibited. Three mechanisms decreased. In these cases the CO2 stripping effect will be less
ART of 1-2 day is required to predominately (>98%) produce do significantly reduce the activity of ammonia oxidizers. can be responsible for pH adjustment. than 50% and depending on targeted nitrification efficiencies
nitrite. The aeration is operated discontinuously and Besides the ART and nitrite outlet concentration the process addition of caustic may be needed. Two of the six full scale
according to the inlet flow the length of an aeration period is parameters pH, temperature and oxygen concentration do The first mechanism is stripping of CO2. Wastewater SHARON plants in operation do require additional caustic
adjusted accurately. A typical trend of the ART control is influence the actual outlet ammonia concentration. Increased originating from sludge digestion will contain high dosage due to the use of ferric chloride at the dewatering.
illustrated in Figure 5. temperatures, pH values and oxygen levels do in general concentrations of CO2. In these wastewaters the stripping Other SHARON plants have caustic dosing systems as a
increase the ammonia removal efficiency. The ammonia effect will be responsible for neutralizing about 50% of the pH backup provision. The SHARON The Haque-Houtrust plant has
Ammonia removal efficiency outlet concentration is thus variable and depends on the decrease. The process of CO2 stripping cannot be controlled. no caustic dosing system at all.
An advantage of the process is a high conversion rate at actual settings of the process operating parameters. Based on
temperatures above 30° C and therefore a short ART (1-2 full scale experience the ammonia outlet concentration can The second mechanism is denitrification. A maximum of 50% In all situations pH measurement and control is very
days) is sufficient for the nitrification process. On the other be targeted according to a required ammonia removal of the pH effect can be neutralized by denitrification. For important for process stability. In case of a single tank system
hand the Ks value (Monod kinetics) for ammonia increases demand and/or to minimize overall nitrogen removal costs. denitrification both external and internal COD sources are the aeration is discontinuous and the pH will vary during a
with increasing growth rates. As a consequence the ammonia applied. Dependant on the requirements of the main WWTP cycle. The difference between the maximum and minimum
outlet concentration increases with shorter ARTs. As rule of Figure 6 presents the nitrogen removal efficiency of SHARON full or partial denitrification can be targeted. For pH control pH value during a cycle can be 0.5 pH unit. A typical pH trend
thumb the ammonia outlet concentration increases from less Beverwijk. The average ammonia removal efficiency is 94%. only partial denitrification is often sufficient. In addition any of single tank system is illustrated in Figure 7.
than 5 NH4-N/l at an ART of 2 days to approximately 100 mg Incidentally there is a shortage of COD source (sludge dryer outlet nitrite will be denitrified in the part(s) (head of works,
NH4-N/l at an ART of 1 day. At an ART of 1.5 days an ammonia condensate) that lowers the denitrification efficiency. Even so primary sedimentation, first aeration etc.) of the main WWTP.
outlet concentration of approximately 20 mg NH4-N/l can be the average total nitrogen removal efficiency is 88%.
achieved. In addition the ammonia outlet concentration The third mechanism is dosage of caustic which is the most
depends on the nitrite outlet concentration. Originally In Table 3 the average ammonia removal results of several direct way of pH control. However dosage of caustic is more
denitrification was applied for pH control only. SHARON plants are presented. expensive in comparison with denitrification with external
C-sources.
Figure 5 – Typical trend ART control SHARON Zwolle Figure 6 – Removal efficiencies SHARON Beverwijk Figure 7 – Typical pH trend SHARON The Haque-Houtrust
Location ART (day) Inlet concentration (mg NH4-N/l) NH4-N removal efficiency (%)
Utrecht1 3–6 600 – 900 90 – 95
Rotterdam 1.3 – 1.8 1.000 – 1.500 85 – 98
Zwolle 1.3 – 1.8 400 – 600 85 – 95
Beverwijk 1.3 – 1.8 700 – 900 85 – 95
Houtrust 1.5 – 1.8 900 – 1.200 85 – 98
Garmerwolde2 1.4 – 1.5 700 – 800 ≥ 95
1
Due to the ART above 2 days nitrogen is removed partly by nitrate
2
Expected results after start pre-thickening surplus sludge
SHARON | 18 SHARON | 19
3 Full-scale experience with the SHARON process
COD sources for deninitrification Alternative COD sources such as industrial waste products Temperature control Sludge dewatering
The BOD concentration of most ammonia rich wastewaters is can be used as well. Issues for use of industrial waste products Biological processes produce heat. As a consequence the heat Sludge dewatering operation can have a significant effect on
very limited, e.g. wastewater from dewatering of digested are residuals such as heavy metals, continuity of delivery and production of the high strength wastewaters is significant. As both inlet temperatures and inlet concentrations. For
sludge. In this situation an external COD source has to be COD concentration. A high COD concentration is important in rule of thumb nitrogen removal (nitrification/denitrification) example in case of a belt filter press the belt press water
dosed. The ratio of COD:N for denitrification has a order to avoid significant decrease of the hydraulic retention by nitrite produces 10° C temperature increase per 1 gram (filtrate) should preferably be collected separately from the
stoichometric value of 2.86 in case of denitrification of nitrate time due to dilution. The application of industrial waste ammonia per liter. A temperature of 35° Celsius (95 F) is used belt pres rinse water as is illustrated in Figure 9. The filtrate
and 1.71 in case of nitrite. Including sludge production the products is not very common yet. as design temperature. In practice the process functions well can be reused as belt rinse water. Additionally the used belt
COD consumption is expected to be about 4 g COD/g NO3-N Recently byproducts from the rapid growing biofuel within a range of 30° to 40° Celsius (86 - 104 F). In full scale press rinse water can be added to the sludge input to remove
and 2.4 g COD/g NO2-N. The actual COD consumption is the production industry have become widely available as external practice even maximum temperatures of 42° Celsius (108 F) suspended solids. In case fresh water is used as belt pres rinse
best indicator for nitrification/denitrification by the nitrite COD source. These products can be 2-4 times more cost were reached. Temperature control is therefore not a very water the filtrate is unnecessarily cooled and diluted. Also
route. Nitrate and nitrite effluent concentrations are of little effective than high grade methanol and may require less critical factor. For each plant a detailed heat balance is made. filtrate can be used to dilute the Poly Electrolyte (PE) base
importance because the actual ratio between production and stringent storage measures. Usually existing storage and Most dominant factors are wastewater temperature, inlet solution and can be subject of optimization. Optimum sludge
conversion of nitrate and nitrite are unknown. dosing facilities for methanol can be used. ammonia concentration and tank insulation. thickening prior to digestion is another factor of importance
Figure 8 illustrates a heat balance of the SHARON to reach high inlet concentrations and does improve the
Different types of COD sources are used for denitrification as Some SHARON plants treat a mixture of wastewater from Rotterdam-Sluisjesdijk plant. effectiveness of digestion and side stream treatment in
is presented in Table 4. dewatering of digested sludge and wastewater (condensate) general. Large uncovered digested sludge storage tanks
from sludge drying. Wastewater from sludge drying is COD A system without cooling/heating equipment is preferable should be avoided to prevent unnecessary cooling. Finally the
Traditionally methanol is applied as a cost effective external rich and therefore no or less external COD source is needed. because of its simplicity. The SHARON plant The Haque- use of specific anti-foam agents prior to the SHARON process
COD source. Methanol is not part of the natural citric acid Houtrust has no heating or cooling system. Here the system can have a negative effect on oxygen transfer efficiency of the
cycle breakdown pathway and therefore denitrifying bacteria In practice the SHARON plants have a COD:N ratio below 2.4 temperature varies over season between 34° and 42° Celsius aeration. In case an anti-foam agent is needed, a suitable
need some adaptation time. In full scale practice the gram COD per gram nitrite removed. SHARON Utrecht has a (93 – 108 F). product should be carefully selected depending on site
observed adaptation time is short and amounts to less than COD:N ratio of 3.0. The ART of this plant is above 2 days and On other locations depending on site specific circumstances specific wastewater characteristics and circumstances. In
several days. The use of methanol requires safety measures therefore partially nitrate besides nitrite is produced by cooling or heating can be required. At sites with sludge general the SHARON processes are operated without the
for storage and dosing, due to fire and explosive risks. Plants nitrification drying, the condensate can have temperatures up to 70° additional use of anti-foam agents.
that use methanol do investigate the feasibility of using Celsius (158 F) and thus cooling is necessary. Locations with
alternative COD sources. relatively low wastewater temperatures (below ≈ 25° Celsius
(77 F)) and low inlet concentrations (below ≈ 700 mg NH4-N/l)
may require additional heating. In many occasions excess
heat and/or biogas are available for additional heating.
Table 4 – Different COD sources used for denitrification Figure 8 – Heat balance SHARON Rotterdam-Sluisjesdijk Figure 9 – Reuse of belt press water (filtrate) as belt rinse water
SHARON | 20 SHARON | 21
3 Full-scale experience with the SHARON process
Process stability and control Operational costs By implementation of SHARON the effluent ammonia load Mixing and Mass transfer Technologies INC, Lotepro
The definition of process stability depends on the required The main operational costs are for energy and COD source. was decreased by approximately 50%. At WWTP Utrecht the Environmental Systems and Services is the licensee from
ammonia outlet concentration. For example the ammonia Costs for the COD source are strongly influenced by the type denitrification capacity was the limiting factor. After Grontmij of the SHARON process in North America. Please
outlet concentration of SHARON Rotterdam-Sluisjesdijk may of COD source used. COD from condensate from sludge implementation of SHARON the overall TN removal efficiency address all communications regarding SHARON to Alphonse
amount to about 100 mg/l. Here this outlet concentration is drying is available for free. Application of industrial waste increased from 65% to over 75%. Warakomski by e-mail at: awarakomski@m2ttech.com
sufficiently low for the main WWTP. Other SHARON plants do streams as COD source can even be a source of income. The In both situations the improved overall nitrogen removal
reach lower ammonia outlet concentrations, even as low as use of byproducts from the production of biofuel can be up results were achieved even with a 6% increase of the WWWP References
20 mg/l. To continuously achieve low ammonia outlet to four times more cost effective than the use of a high grade influent nitrogen load. At both locations SHARON did Abma, W, (2006), J.W. Mulder, W. v .d. Star, M. Strous, (2006),
concentrations advanced process control is needed. These methanol. Expressed per kg nitrogen removed the SHARON improve the WWTP effluent quality and made compliance Anammox in Rotterdam overtreft verwachtingen (in Dutch),
systems are therefore not only equipped with an oxygen, pH process is highly competitive with other techniques for with nitrogen removal requirements possible. SHARON H2O, 10, pp 47 - 49.
and temperature sensor but also with an online ammonia removal of high strength wastewaters. proved to be a cost effective alternative for conventional
sensor and online nitrite sensor to enable a more advanced extension of the WWTP. Carrio, L, J. Sexton, A. Lopez, K. Gopalakrishnam, V. Sapienza,
process control program. Improved WWTP effluent quality (2003), Ammonia-Nitrogen Removal from Centrate, 10 years
The effect of SHARON on the main WWTP nitrogen effluent Conclusions of testing and operating experience in New York City, WEFTEC
In full scale practice the supply of reject water can be quality was previously described (Kempen et al., 2005). For Nine years of operating experience prove that SHARON is an 2003 - Session 42: Municipal Wastewater Treatment Processes,
interrupted due to a discontinuous operation of the two large WWTPs (Utrecht and Rotterdam-Dokhaven) the economic and sustainable process for nitrogen removal of Water Environment Federation, 2003.
dewatering facility during for example weekends or nitrogen balance was studied. The balances show the external high strength wastewaters. Compared to conventional
maintenance periods. During these periods, that may last and internal nitrogen loads before and after side stream techniques there is a significant saving of energy and Dongen, U. van, Jetten, M.S.M. & van Loosdrecht, M.C.M.
several days or longer, the actual ammonia removal capacity treatment implementation. In both cases, implementation of consumables. The process is compact and simple to operate. (2001). The SHARON – Anammox process for treatment
is preserved. This is achieved by restriction of the aeration. SHARON significantly improved the overall WWTP nitrogen Depending on site specific circumstances, different system of ammonium rich wastewater. Wat. Sci. Tech. 44 (1),
Without the availability of oxygen the activity of the nitrite removal efficiency and nitrogen effluent quality. configurations are possible. pp 153 - 160.
oxidizers is preserved and full capacity remains standby. The Three situations can be distinguished where SHARON is
high process temperature and thus the high growth rate of effective; (i) a limited aeration capacity, (ii) a limited The process can be operated very stable. The aerated Hellinga, C., M.C.M. van Loosdrecht, J.J. Heijnen, (1999). Model
the ammonia oxidizers, contributes to the high process denitrification capacity and (iii) a limited aerobic sludge age. retention time and nitrite concentration are the two most based design of a novel process for nitrogen removal from
stability of the SHARON process. In addition the high process It was shown that SHARON is successfully applied in the first important process parameters to control the ammonia outlet concentrated flows. Math. Comp. Modell. Dyn. Sys. 5, pp 1-13.
temperature enables during start-up a capacity increase of up and second situation. Based on model study and supported concentration. The process temperature is less critical and
to 50% per day. by full scale practice it was shown that in case SHARON is may vary between 30° and 40°C. Ammonia removal Hellinga, C., A.A.J.C. Schellen, J.W. Mulder, M.C.M. van
combined with enhanced suspended solids removal, the efficiencies can be over 95%, are variable and can be targeted Loosdrecht and J.J. Heijnen, (1998). The SHARON process; An
All SHARON plants operate automatically. In full scale aerobic sludge age can be extended to maintain nitrification according to the required needs of the main WWTP and/or to innovative method for nitrogen removal from ammonium
practices normal operation activities are restricted to less at lower temperatures. In the example the critical minimize overall nitrogen removal costs. rich waste water. Wat. Sci. Tech. 37, pp. 135-142.
than 1 hour per day. temperature for nitrification could be lowered with several
degrees Celsius. In Table 5 an overview of the model results of The SHARON process is highly competitive with other Kempen, R. van, J.W. Mulder, C.A. Uijterlinde and M.C.M.
the effect of SHARON on the WWTP nitrogen effluent quality techniques for removal of high strength wastewaters. Loosdrecht, (2001). Overview: full scale experience of the
is presented. In full scale practice the following improvements Application of fine bubble aeration has further decreased SHARON process for treatment of rejection water of digested
were achieved. At WWTP Rotterdam-Dokhaven, aeration aeration costs. Recently the use of by-products of the biofuel sludge dewatering. Wat. Sci. Tech., 44 (1), pp 145-152, IWA
capacity of the activated sludge system was limiting. production industry as COD source for denitrification, has Publishing 2001.
further increased the cost effectiveness.
Kempen, R. van, C.C.R. ten Have, S.C.F. Meijer, J.W. Mulder, J.O.J.
Table 5 – Model results effect of SHARON on WWTP nitrogen removal efficiency SHARON is successfully applied to improve the main WWTP Duin, C.A. Uijterlinde and M.C.M. van Loosdrecht, (2005).
nitrogen effluent quality. It proves to be a cost effective SHARON process evaluated for improved wastewater
Nitrogen balance Activated sludge process (AS) without SHARON AS with SHARON alternative for conventional extension of the WWTP. treatment plant effluent quality. Wat. Sci. Tech., 52 (4),
Limited aeration capacity Limited denitrification capacity Limited aerobic sludge age pp 55-62, IWA Publishing 2005.
Acknowledgments
TN load
The authors of this paper like to thank the Delft University of Mulder, J.W., M.C.M. van Loosdrecht, C. Hellinga and R. van
Raw influent 100 100 100 100 Technology and the STOWA (the Dutch foundation of Applied Kempen, (2001). Full-scale application of the SHARON process
Rejection water 20 20 20 1 Water Research) for their support and contribution to the for treatment of rejection water of digested sludge
development of the SHARON process. dewatering. Wat. Sci. Tech., 43 (11), pp 127-134, IWA
N removal AS
Publishing 2001.
Nitri/Deni 72 72 0 72 End notes
Surplus sludge 4 4 4 4 J.W. Mulder is employee of the ‘Hollandse Delta’ Water Board, Notenboom, G. J., J.C. Jacobs, R. van Kempen, M.C.M. van
SHARON - - - 19 J.O.J. Duin is employee of the ‘De Stichtse Rijnlanden’ Water Loosdrecht, (2002) High rate treatment with SHARON process
Board, J. Goverde is employee of the ‘Hollands of waste water from solid waste digestion , IWA, 3rd
Total 76 76 4 95 Noorderkwartier’ Water Board, W.G. Poiesz is employee of the International Symposium Anaerobic Digestion of Solid
Effluent load ‘Noorderzijlvest’ Water Board, H.M. van Veldhuizen is Wastes, 18 to 20 September 2002 Munich / Garching,
TKN 21 2 96 2 employee of the ‘Groot Salland’ Water Board, and R. van Germany.
Kempen and P. Roeleveld are employees of the ‘Grontmij
NO3-N 3 22 0 3
Nederland’ Consulting Engineering Company. STOWA (1996). Treatment of nitrogen-rich return flows of
TN 24 24 96 5 sewage treatment plants. Single reactor system for removal of
ammonium over nitrite (in Dutch). STOWA report 96-01.
SHARON | 22 SHARON | 23
4 Reference list
SHARON | 25
4 Reference list
Project SHARON WPCP Wards Island, New York City, USA Project SHARON WWTP Rotterdam-Dokhaven, The Netherlands
Client Metcalf & Eddy of New York, Inc. / New York City Department of Client Waterboard Hollandse Eilanden en Waarden
Environmental Protection Capacity 600 m3/day, Ammonium removal 850 kg per day.
Capacity 7000 m3/day, Ammonium removal 5000 kg per day. Year 1997-1998 (Operational)
Year 2008 – 2009 (Under construction) Description A system for the treatment of nitrogen rich wastewater (centrate)
Description A system for the treatment of nitrogen rich wastewater (centrate) produced during dewatering of digested sludge. The capacity of WWTP
produced during dewatering of digested sludge. The capacity of WPCP Rotterdam-Dokhaven is 470,000 p.e.
Wards Island is 285 MGD. The SHARON system is currently under Contracting method used Grontmij was responsible for design, preparation of tender documents,
construction. construction supervision and commissioning.
Contracting method used SHARON Systems LLC, a joint Grontmij/M2T company, is responsible for
design, supply and installation of mechanical and electrical equipment, Project SHARON WWTP Utrecht, The Netherlands
commissioning and one year operation assistance. Client Water Authority De Stichtse Rijnlanden
Capacity Ammonium removal 900 kg per day.
Project SHARON WWTP Garmerwolde, The Netherlands Year 1997 (Operational)
Client Waterboard Noorderzijlvest Description A system for the treatment of nitrogen rich wastewater (centrate)
Capacity 3200 m3/day, Ammonium removal 2500 kg per day. produced during dewatering of digested sludge. The capacity of
Year 2005 (operational) WWTP is 400,000 p.e.
Description A system for the treatment of nitrogen rich wastewater (centrate and Contracting method used Grontmij was responsible for Turnkey realisation.
condensate) produced during dewatering of digested sludge and sludge
drying. The capacity of WWTP Garmerwolde is 300,000 p.e.
Contracting method used Grontmij was responsible for Turnkey realisation.
SHARON | 26 SHARON | 27
SHARON Linköping (SE)
At the wastewater treatment plant in Linköping an existing sequencing batch reactor for treatment
Location Characteristics
Sweden SHARON: 490m3/day
610 kg/day NH4
Clients Influent: Centrate
Tekniska Verken N-removal: >96%
Operational: 2009
Period
2009 - 2009
SHARON | 29
SHARON Seine Grésillons (F)
OTV, in a joint venture with Bouygues Traveaux Publics, has been selected by SIAAP (Syndicat Interdépartmental
pour l’Assainissement de l’Agglomeration Parisienne) for the extension of the wastewater treatment plant Seine
Grésillons. The project will triple the capacity of the plant to 300,000 m3/day and will add sludge digestion,
Location Characteristics
France, Paris region SHARON: 3200m3/day
3500 kg/day NH4
Clients Influent: Centrate
OTV on behalf of SIAAP N-removal: >96%
Operational: 2012
Period
2008 - 2010
SHARON | 31
SHARON Geneva (CH)
Geneva (Switzerland) has selected the SHARON process for nitrogen removal for the extension of the
In a joint project team with the client, Grontmij is responsible for process design, preliminary design,
process control and automation systems, and assistance with start-up and operation.
The wastewater treatment plant Aïre 2 at Geneva is one SIG has selected the SHARON process in an extensive
of the three largest wastewater treatment plants in system selection procedure, including a technological
Switzerland. The capacity amounts to 600,000 evaluation and additional site visits in the Netherlands
population equivalents at a maximum hydraulic capacity and Austria. SHARON is selected for reasons of proven
of 18.000 m3/h. The plant discharges the treated process stability, flexibility, robustness of operation and
wastewater of the city of Geneva into the river Rhône. the competitive investment and operational costs.
© SIG
Location Characteristics
Switzerland Geneva WWTP: 600,000 p.e.
SHARON: 1600m3/day
Clients 1700 kg/day NH4
Services Industriels de Genève (SIG©) Influent: Centrate
N-removal: >95%
Period Operational: 2010
2007 - 2010
SHARON | 33
SHARON Whitlingham STC (UK)
The SHARON Liquor Treatment Plant forms part of Anglian Water’s Bio-solids capital programme with
particular regard to their Whitlingham STC (Sludge Treatment Centre) upgrade scheme.
The overall bio-solids project at Whitlingham comprises Following a detailed appraisal of available process
the upgrading of the existing sludge treatment plant to options, including the undertaking of Risk & Value
provide increased capacity. The processed sludge is to be Intervention (R&VI) analysis; the Grontmij SHARON
treated to ADAS Enhanced Treatment Standards. (Stable High Ammonia Removal Over Nitrite) process is
A consequence of increasing the sludge treatment the preferred selection for the Whitlingham STC site.
capacity and the degree of treatment is that the SHARON will achieve a removal efficiency of 96%
associated liquor flow and loads will also increase to the
detriment of the works discharge consent standards. Grontmij, as a subcontractor to Black &Veatch Ltd, is
There is a need therefore, to install a new Liquor responsible for process design and commissioning.
Treatment Plant (LTP), to reduce the aqueous ammonia The SHARON process will come into operation in 2010.
concentrations contained in the liquors.
Location Characteristics
United Kingdom Norwich SHARON: 900m3/day
1500 kg/day NH4
Clients Influent: Centrate
Black & Veatch Ltd on behalf of Anglian Water N-removal: >96%
Operational: 2010
Period
2008 - 2010
SHARON | 35
SHARON MVPC Shell Green (UK)
United Utilities has selected the SHARON process for removal of nitrogen from centrate at the MVPC (Shell
Green) centre for sludge processing. Grontmij, as a subconractor to S3JV, is responsible for process design and
commissioning.
The MVPC (Shell Green) is United Utilities regional SHARON is a high active process for N-removal operating
dewatering and incineration centre, located in the without sludge retention. Due to differences in growth
Mersey Valley near Widnes. The existing works comprises rate nitrite oxidisers are washed out of the system while
of sludge dewatering and two streams of incineration. As ammonia oxidisers can be maintained, resulting in
part of a major extension project, the Veolia Water / N-removal over nitrite instead of nitrate. N-removal with
Costain; Stream Three Joint Venture (S3JV) have been SHARON via nitrite has the following advantages:
appointed by United Utilities to design and construct a • oxidation to nitrite saves 25% of the aeration energy
third incineration stream, along with the replacement of • denitrification of nitrite saves 40% on BOD addition
the existing dewatering process and various ancillary • denitrification of nitrite at high temperatures reduces
plant and equipment necessary for the operation of the sludge production by 50%
new stream. The increase in dewatering capacity will • simple process with high process stability.
lead to an increase in the load of ammonia discharged
with centrate. United Utilities have been informed by the Grontmij, as a subcontractor to S3JV, is responsible for
Environmental Agency that a proportion of the centrate process design and commissioning. The SHARON
will have to be treated to remove ammonia. After pilot process will come into operation in 2010.
trials on site, United Utilities have selected the SHARON
process as the prefered method of centrate treatment.
Location Characteristics
United Kingdom Widnes SHARON: 1400m3/day
1600 kg/day NH4
Clients Influent: Centrate
Stream Three Joint Venture (Veolia, Costain) N-removal: >96%
on behalf of United Utilities Operational: 2010
Period
2008 - 2010
Partner(s)
Grontmij Ltd. (UK)
SHARON | 37
SHARON New York (USA)
New York City has developed a Comprehensive Nitrogen Management Plan to reduce the aggregate effluent
nitrogen loading from Water Pollution Control Plants (WPCPs) to the Upper East River and Jamaica Bay. Separate
centrate treatment has been identified as an integral part of this plan, since up to 40% of nitrogen loading at
Pilot research by the New York City Department of Under the Management Plan, New York City has built a
Environmental Protection related to nitrogen removal demonstration plant for the SHARON system at Wards
and other related operational issues, showed SHARON to Island WPCP. This SHARON will treat centrate produced at
demonstrate significant potential as a highly efficient, the plant in the sludge dewatering facility. This facility
cost effective and environmentally sound process for the dewaters anaerobically digested sludge produced at
removal of high levels of nitrogen from centrate. Wards Island and at two other WPCPs.
SHARON is a high active process for N-removal operating Grontmij, who is the owner of the proprietary SHARON
without sludge retention. Due to differences in growth technology, is responsible for design, commissioning
rate nitrite oxidisers are washed out of the system while and process start-up. The SHARON for Wards Island
ammonia oxidisers can be maintained, resulting in WPCP, with a capacity of 5000 kg NH4-N per day, will
N-removal over nitrite instead of nitrate. be operational in 2009.
N-removal with SHARON via nitrite has several
advantages:
• oxidation to nitrite saves 25% on aeration energy;
• denitrification of nitrite saves 40% on BOD addition;
• denitrification of nitrite at high temperatures reduces
sludge production by 50%;
• simple process with high process stability.
Location Characteristics
United States New York WPCP: 250 MGD
SHARON: 1.85 MGD
Clients 5000 kg NH4/day
NYCDEP Influent: Centrate
N-removal: >95%
Period Operational: 2009
2003 - 2009
SHARON | 39
SHARON Garmerwolde (NL)
The wastewater treatment plant (WWTP) at Garmerwolde (Groningen, The Netherlands) is refurbished to meet
future effluent standards. Part of the refurbishment is the construction of a SHARON system for treatment of
flows produced at the sludge dewatering and sludge drying facilities at Garmerwolde. At WWTP Garmerwolde
locally produced sludge is anaerobically digested and, together with sludge imported from other facilities,
dewatered and dried. The filtrate produced in the sludge dewatering process together with the condensate
produced in the sludge drying process contribute approximately 34% of the total nitrogen load to WWTP
Garmerwolde.
The Waterboard Noorderzijlvest, who owns WWTP N-removal with SHARON via nitrite has several
Garmerwolde, has selected the SHARON process as advantages:
preferred method for filtrate and condensate treatment • oxidation to nitrite saves 25% on aeration energy;
on the basis of overall treatment cost, high guaranteed • denitrification of nitrite saves 40% on BOD addition;
ammonia removal efficiency, stable operations and • denitrification of nitrite at high temperatures reduces
proven track record. sludge production by 50%;
• simple process with high process stability.
SHARON is a high active process for N-removal operating
without sludge retention. Due to differences in growth Grontmij, as main contractor and owner of the
rate nitrite oxidisers are washed out of the system while proprietary SHARON technology, was responsible for the
ammonia oxidisers can be maintained, resulting in design and construction of the SHARON system and
N-removal over nitrite instead of nitrate. operated the SHARON for one year.
Location Characteristics
Netherlands Groningen WWTP: 300,000 p.e.
SHARON: 2500 kg NH4/day
Clients Influent: Filtrate and condensate
Waterschap Noorderzijlvest N-removal: >95%
Operational: 2005
Period
2004 - 2006
SHARON | 41
SHARON The Hague (NL)
Under European regulation, The Netherlands is required to achieve an overall nitrogen removal efficiency of 75%
in 2006 for urban wastewater. The wastewater treatment plant Houtrust at The Hague, with a capacity of 930,000
population equivalents, is a significant contributor to nitrogen discharge in The Netherlands. WWTP Houtrust
Location Characteristics
Netherlands The Hague WWTP: 930,000 p.e.
SHARON: 1200 kg NH4/day
Clients Influent: Centrate
Delfluent Services bv N-removal: >95%
Operational: 2005
Period
2004 - 2006
SHARON | 43
SHARON Beverwijk (NL)
New legislation for N-removal required optimisation of the Beverwijk WWTP. The Hoogheemraadschap Hollands
Noorderkwartier (HHNK) is responsible for the treatment of wastewater in the region north of Amsterdam.
Wastewater sludge produced at the WWTP’s in the region of the Hoogheemraadschap Hollands Noorderkwartier
is dried at a central location situated next to Beverwijk WWTP. The condensate produced during the drying
process is nitrogen rich and discharged to the Beverwijk WWTP. A study of the N-balance of the WWTP showed
that a significant fraction of the nitrogen is recirculated from the sludge digestion (so-called rejection water)
towards the activated sludge tanks. Together with the condensate of the drying process this amounts to 30% of
the total N-load of the WWTP. Removing this load will directly result in a significant decrease of the total N-load
in the effluent.
Several techniques for treatment of the rejection water After successful laboratory tests it was decided to design
were evaluated, including lab test and pilot tests at large and construct a full scale process without performing an
wwtp’s. This research was initiated by STOWA (the Dutch intermediate pilot test. Grontmij designed the system,
foundation for Applied Water Research). The SHARON assisted the Water Authority with the selection of a
(pat.) process pointed out to be the most cost-effective general contractor and with construction supervision
technique. and is responsible for process commissioning.
SHARON has been originally developed at the Technical The SHARON system of Beverwijk WWTP is operational
University of Delft (TUD). It concerns a high active since 2003. The implementation of SHARON resulted in
process for N-removal operating without sludge an overall 2% nitrogen discharge reduction of the total
retention. Due to differences in growth rate nitrite area serviced by the Hoogheemraadschap Hollands
oxidisers are washed out of the system while ammonia Noorderkwartier.
oxidisers can be maintained, resulting in N-removal over
nitrite instead of nitrate. N-removal with SHARON via
nitrite has the following advantages:
• oxidation to nitrite saves 25% of the aeration energy;
• denitrification of nitrite saves 40% on BOD addition;
• denitrification of nitrite at high temperatures reduces
sludge production by 50%;
• simple process with high process stability.
Location Characteristics
Netherlands Beverwijk WWTP: 320,000 p.e.
SHARON: 1200 kg NH4/day
Clients Influent: rejection water and condensate
Water Authority HHNK (NL) N-removal: >95%
Operational: 2003
Period
2002 - 2003
Partner(s)
TUD
SHARON | 45
SHARON Zwolle (NL)
The Groot Salland Water Board has constructed a SHARON (pat.) reactor for the purpose of sidestream
treatment at the sludge treatment site of the WWTP Zwolle. Grontmij was responsible of the system
Location Characteristics
Netherlands Zwolle WWTP: 200,000 p.e.
SHARON: 600m3/day
Clients 410 kg/day NH4
Waterboard Groot Salland Influent: Centrate
N-removal: >93%
Period Operational: 2003
2002 - 2003
SHARON | 47
SHARON Rotterdam (NL)
New legislation for N-removal required optimisation of the Dokhaven WWTP of Rotterdam. This WWTP was
designed as a two-stage process. The two-stage process is well suitable for BOD (Biological Oxygen Demand)
removal as well as nitrification. However denitrification in the second stage is poor due to BOD shortage and a
A study of the nitrogen balance of the WWTP showed SHARON has been developed at the Delft University.
that a significant fraction of the nitrogen is recirculated After successful laboratory tests it was decided to design
from the sludge digestion (so-called rejection water) and construct a full scale process without performing an
towards the activated sludge tanks. This amounts to 15% intermediate pilot test. Grontmij in co-operation with the
of the total N-load of the WWTP. Therefore removing this Water Authority ZHEW did the detailed full-scale process
load will directly result in, at least, an equivalent design.
decrease of the total nitrogen load in the effluent.
Because there was no area available for extension a
Several techniques for treatment of the rejection water post-thickener had to be taken out of operation and was
were evaluated, including lab tests and pilot tests at converted into a SHARON reactor. The SHARON system
large wwtp’s. This research was initiated by STOWA (the has been successfully in operation since 1999. Since the
Dutch foundation for Applied Water Research). The implementation of SHARON the total nitrogen effluent
SHARON (pat.) process pointed out to be the most load of the Dokhaven WWTP dropped by over 30%. As a
cost-effective technique. It is a high active process for result ZHEW was able to meet the required N-removal
N-removal operating without sludge retention. Due to demands.
differences in growth rate nitrite oxidisers are washed
out of the system while ammonia oxidisers can be
maintained, resulting in N-removal over nitrite.
N-removal with SHARON via nitrite has the following
advantages:
• oxidation to nitrite saves 25% of the aeration energy;
• denitrification of nitrite saves 40% on BOD addition;
• nitrogen removal at high temperature reduces
biological sludge production by 50%.
• compact and simple process.
Location Characteristics
Netherlands Rotterdam Capacity: 470,000 pe
Influent: rejection water
Clients N-load: 830 kg/day
Water Authority ZHEW N-removal: >95%
Operational: since 1999
Period
1995 - 1999
Partner(s)
TU Delft and STOWA
SHARON | 49
SHARON Utrecht (NL)
New legislation for N-removal required optimisation of the Utrecht WWTP which is operated by the Water
Authority HDSR. This WWTP was designed as a two-stage process. This two-stage process is suitable for BOD
(Biological Oxygen Demand) removal, nitrification and denitrification. However denitrification in the second
stage is poor due to BOD shortage and a high sludge loading rate.
A study of the N-balance of the WWTP showed that a After successful laboratory tests it was decided to design
significant fraction of the nitrogen is recirculated from and construct a full scale process without performing an
the sludge digestion (so-called rejection water) towards intermediate pilot test. Grontmij designed, built and
the activated sludge tanks. This amounts to 15% of the commissioned the SHARON plant of WWTP Utrecht.
total N-load of the WWTP. Removing this load will
directly result in a significant decrease of the total N-load The SHARON system has been successfully in operation
in the effluent. since 1999. Since the implementation of SHARON the
total nitrogen discharge load of the Utrecht WWTP
Several techniques for treatment of the rejection water dropped by 30%. As a result the Water Authority HDSR
were evaluated, including lab test and pilot tests at large can meet the strict nitrogen discharge standards.
wwtp’s. This research was initiated by STOWA (the Dutch
foundation for Applied Water Research). The SHARON
process pointed out to be the most cost-effective
technique. SHARON has been originally developed at the
Technical University of Delft (TUD). It concerns a high
active process for N-removal operating without sludge
retention. Due to differences in growth rate nitrite
oxidisers are washed out of the system while ammonia
oxidisers can be maintained, resulting in N-removal over
nitrite instead of nitrate. N-removal with SHARON via
nitrite has the following advantages:
• oxidation to nitrite saves 25% of the aeration energy
• denitrification of nitrite saves 40% on BOD addition
• denitrification of nitrite at high temperatures reduces
sludge production by 50%
• simple process with high process stability
Location Characteristics
Netherlands Utrecht WWTP: 400,000 p.e.
SHARON: 900 kg/day NH4
Clients Influent: Filtrate
Water Authority HDSR (NL) N-removal: >95%
Operational: 1997
Period
1996 - 1997
Partner(s)
TUD and STOWA
SHARON | 51
Contact
E henkwim.demooij@grontmij.nl
T +31 30 220 78 75
When Grontmij N.V. was founded in 1915, its vision was sustainable land consolidation and reclamation for the agricultural
sector and the development of the rural areas. Almost a century later, the company has developed and grown, but it is
essentially the same: Grontmij creates value for its customers and shareholders by designing and realising sustainable
living and working environments.
Grontmij’s mission is to be the best local service provider for design, consultancy, management, engineering and
contracting in the environmental, water, energy, building, industry and transportation sectors. We aim to achieve this
through the design and realisation of plans for the future together with the people and parties in our regions.
Grontmij creates value for its customers and shareholders by designing and realising sustainable living and working
environments.
SHARON | 53
www.grontmij.com