Appendix A

Pu re Com ponent Para m eters

G e n e ra l data for selected compo u n d s .

Substance Form ula T, P, v, M w Tb Tm L1 h m L1hJ L1g J

(K) (bar) (cm 3 fmol) (gfmol) (K ) (K) (Jig) (Jjmol) (Jfmol)

Water HzO 647 096 220. 640 5 5 . 94 7 18.01 5 0 . 3 443 3 7 3 . 1 3" 273 . 1 5 3 3 3 . 1 - 2 4 1 820 - 2 28590
Ammonia NH3 405 . 500 1 1 3.592 7 5 . 768 17.031 0 . 2 5 60 239.82 195.45 132.2 - 4 5 773 . 16150
Hydrogen H CI 324.650 8 3 . 100 81.016 36.461 0. 1 3 1 4 188.08 1 58 . 9 5 54.9 -92310 - 9 5 300

Cl z
chloride
Chl orine 4 1 6 . 958 79. 9 1 1 1 22 . 92 7 70. 906 0 . 0874 239. 1 7 172. 1 5 90.3 0 0
0

Oz
N itrogen Nz 1 26 . 1 92 33.958 89 . 4 1 6 28.014 0.0372 77.36 63.15 25.7 0
Oxygen 1 5 4 . 5 99 50. 464 74.948 3 1 .999 0 . 022 1 90. 1 9 54.35 13.9 0 0
H ydrogen Hz 3 3 . 1 90 1 3 . 150 66.938 2.016 -0.2187 20. 3 8 1 3 .95 58. 1 0 0
Sul fur SOz 430.643 78.757 1 2 2 .087 64.062 0.2552 263. 1 3 200.00 1 1 5 . 5 - 296850 - 3 001 50
dioxide
Carbon co 1 3 2 . 860 3 4 . 98 2 9 2 . 088 28.010 0.0503 8 1 .64 68. 1 5 30.0 - 1 10540 - 1 3 7270

COz
monoxide
Carbon 304. 1 28 73.773 94. 1 1 7 44. 009 0.2236 216.55 204 . 9 - 39 3 500 - 394380

CH4
dioxide
M ethane 1 90. 564 45.992 98.629 1 6 . 04 3 0.01 1 4 1 1 1 . 67 90.65 58.7 - 74850 - 508 3 5

C 1 Hs
Ethane C2 H6 3 05 . 3 2 2 48.722 1 4 5 . 843 30. 070 0. 0995 1 84 . 5 7 90. 3 5 95 . 1 - 84680 - 32930

C4 H 10
Propane 369.825 4 2 . 47 7 200.004 44.097 0 . 1 524 2 3 1 .03 85.45 7 9 . 9 - 1 03840 - 2 3470
11-B utane 42 5 . 1 2 5 1 7 . 960 254.930 58.124 0. 2008 2 7 2 . 66 1 34 . 8 5 80.2 - 1 2 6 1 5 0 - 1 7 1 54
l sobutane C 4 H 10 407 . 8 1 0 36. 290 257.756 58. 1 2 4 0.1835 2 6 1 . 40 1 1 3.55 78 . 1 - 1 34 5 1 0 - 20878

C 6 H 14
n-Pentane C5 H 1 2 469 . 6 5 9 3 3 . 689 306. 766 72. 1 5 1 0.25 1 7 3 09 . 2 1 1 43 .40 1 1 6 . 4 - 1 46760 - 88 1 3
n- H exane 507.795 30.41 6 3 86 . 7 5 3 86. 1 7 8 0 . 3 002 3 4 1 .87 1 77 . 8 5 1 5 1 . 8 - 1 67190 - 25 0
Cyclohexane C 6 H 1 2 5 5 3 . 600 40.750 308 . 2 6 3 84. 1 62 0. 2092 3 5 3 .86 279.65 3 2 . 6 - 1 2 3 3 00 31910

C g H 1s
n-Heptane C7 H 1 6 5 4 1 . 226 27.738 445 . 5 5 1 100. 205 0 . 3460 371.53 182.55 1 4 0 . 2 - 1 87650 8165

CHz =CHz
n-Octane 569. 570 2 5 . 067 501 . 8 3 5 1 1 4. 2 3 1 0.3943 398.78 216.35 1 8 1 . 6 - 208750 1 6000
Ethylene 282 . 3 50 50.418 1 30 . 947 28.054 0.0866 169.38 104.05 1 19 . 4 5 2 300 68 1 1 0
P ropylene C3 H6 365.570 46.646 1 88 . 376 42.08 1 0 . 1 408 2 2 5 . 46 87.85 7 1 .4 20420 62720

Chemical Thermodynamics: for Process Simulation, First Edition.

© 2 0 1 2 Wiley-VCH Verlag G m b H & Co. KGaA. Published 2 0 1 2 by Wiley-V C H Verlag G m b H &

filrgen G m ehling, Ba rbel Kolbe, M ichael Kleiber. and f ilrgen Rarey.
Co. KGaA.
 620 1 Appendix A Pure Component Parameters

v, w Tb Tm .d hm .d h .f
Substance Formula T, P, M .f .dg
(K) (bar) (cm 3 fmol) (gfmol) (K ) (K) (J/g) (Jfmol) (Jfmol)

! - Butene C4 Hg 4 1 9 . 290 40.057 2 3 5 . 802 5 6 . 108 0. 1 9 1 9 266.114 87.85 68.6 - 540 70270
M ethanol CH30H 5 1 3 . 380 82 . 1 5 9 1 1 3.828 3 2 . 042 0.5625 3 3 7 .63 175.50 1 00 . 3 - 20 1 1 60 - 1 62 5 00
Ethanol Cz H s O H 5 1 3 . 900 6 1 . 480 1 66 . 9 1 7 4 6 . 069 0.6441 351 .41 1 59 . 0 5 107.0 - 2 3 4800 - 1 68280
n-Propanol C3 H70H 5 36 . 750 5 1 . 750 2 1 8 . 990 60.096 0 . 62 1 1 370. 3 1 1 46 . 9 5 89.4 - 2 5 5 200 - 1 59900
n - B utanol C4 H 9 0 H ') 6 3 .050 44.230 274. 996 74 . 1 2 3 0 . 5 905 390.90 1 8 3.85 126.4 - 2 74600 - 1 50300
Ethylene CzH4 (0H)2 719.150 82. 000 190.983 6 2 . 068 0 . 5 1 29 470 . 2 2 260. 1 5 1 60.4 - 3 92 200 - 30 1 800
glycol
I s opro panol C 3 H70H 508 . 2 50 47.620 220. 0 1 1 60.096 0 . 66 3 1 3 5 5 . 36 185.25 90.0 - 2 7 2 700 - 1 7 3470
Acetic acid C H 3 CO O H 591 .950 5 7 . 1160 1 79 . 676 60.052 0.4630 3 9 1 .04 289.85 195.3 - 4 34830 - 376680
M ethyl CH3- 506 . 5 5 0 47 . 500 228.0 1 5 74 . 079 0 . 3 306 3 30.08 1 75 . 1 5 107.6 - 4 1 1 900 - 3 24200
acetate COO-C H 3
Ethyl CH3- 5 2 3 . 200 38.301 285.992 88. 106 0. 3 606 3 5 0 . 27 1 89 . 6 5 1 18.9 - 4 4 2 9 1 0 - 3 27390
acetate COO-C 2 H 1
Vinyl C4 H 6 0 2 5 1 9 . 1 50 1 9 . 580 269. 978 86 090 0 . 3 5 26 345.86 1 80 . 3 5 62.4 - 3 1 4900 - 2 2 7900
acetate
MTBE C5H 120 497 . 1 5 0 3 4 . 3 00 3 2 8 .976 88. 1 50 0.2662 328.29 164.S5 86.2 - 28 3 5 00 - 1 1 7 100
Acetone C 3 H6 0 ')08. 1 00 46.924 2 1 2 . 299 5 8 . 080 0 . 3 064 329.23 1 78 . 4 5 99.4 - 2 1 5700 - 1 5 1 3 00
Benzene C r, H 6 562 . 0 1 4 49.010 2 5 5 . 044 78. 1 1 4 0 . 2 10 3 3 5 3 . 24 278.65 1 26 . 3 82930 1 29660
Toluene C 6 H 5 -C H 3 5 9 1 . 749 4 1 . 26 3 3 1 5 . 422 92. 1 4 1 0.2657 383.75 1 78. 1 5 72.0 5 0 1 70 1 2 2200
p-Xylene Cg H w 6 1 6 . 250 3 5 . 1 10 377.958 106. 1 68 0.3218 411.51 286.45 161.2 1 8030 1 2 1 400
R23 CHF3 2 9 9 . 747 48. 690 133.115 70.0 1 3 0.2584 1 9 1 . 09 1 1 7 .95 58.0 - 697050 -662610
R32 C H 2 F2 351.255 57.826 1 2 2 . 696 '> 2 .0 2 3 0.2770 2 2 1 . 50 1 37 . 05 99.2 - 4 5 27 1 0 - 42 5 1 60
R12 CCl z F 2 3 85 . 1 20 4 1 . 36 1 2 1 4.006 1 2 0. 9 1 3 0. 1 79 5 243.39 1 1 5. 1 5 34.2 -481 1 60 - 4 4 2 2 5 0
R22 CHCIF2 369. 180 49.885 1 66 . 282 86. 468 0 . 2207 232.35 1 1 5 . 75 47.7 - 4 8 1 600 - 4 50500
R l 34a C F rCH 2 F 374. 2 1 2 40. 5 9 3 1 99 . 299 102.030 0 . 3268 247.08 1 72 . 1 5 63.5 -895 790 - 826900
R125 C F 3 -C H F z 340.229 37.039 2 1 2. 1 3 1 1 20.020 0.3017 2 2 5 04 1 70. 1 5 47.0 - 1 105000- 1 0 3 0000

a According to ITS-90.
Vapor pressure correlations for selected com pou nds.

ps 1
Equation : ln - = - [A ( l - T,) + B ( l - TJ 5 + C ( l - T,) 2 5 + D ( l - T, ) 5 )
P, T,

Substance A B c D Range of Verification

validation point
Tmin (K) Tmax T (K) p• (bar)

Wa ter - 7 . 870154 1 . 906774 - 2 . 3 1 0330 -2 .06 3 390 274 T, 39 3 . 1 5 1 . 9859

Ammonia - 7 . 303825 1 .64995 3 - 2 . 02 1 6 1 5 - 1 . 960295 196 T, 275 . 1 5 4.6237
Hydrogen chloride - 6 . 634574 1 . 068097 0.043272 - 4 . 4436 38 159 T, 243 . 1 5 1 0. 7 1 3 7
Chlorine - 6 . 442452 1 . 492841 - 1 .2 25096 - 2 . 0 1 5 398 174 Tc 27 3 . 1 5 3 . 6877
Nitrogen - 6 . 1 2 3 680 1 . 26061 0 - 0.760446 - 1 . 794726 65 T, 1 03 . 1 5 9 . 6 1 98
Oxygen - 6 . 0 5 1 46 5 1 . 2 3482 3 - 0 . 628 1 1 8 - 1 . 6 14 1 80 64 Tc 123.15 12.2153
Hydrogen - 4 . 8 3 68 3 9 0 . 9439 1 5 0.76 3880 -0.467794 15 T, 1 8.05 0.4651

�
Sulfur dioxide - 7 . 2780 1 6 1 . 72687 1 - 2 . 3 7 1926 - 2 . 708750 203 T, 3 03 . 1 5 4.6239
Carbon monoxide - 6 . 1 94 1 7 5 1 . 3 1 9639 -0.94 3 2 1 2 - 2 . 00 1 5 4 5 68 Tc 1 01 . 1 5 5 . 92 1 5 ""'
T,
"'

T, ;;;; ·
Carbon dioxide - 7 . 026565 1 . 5 27245 - 2 . 2463 1 1 - 2 . 630030 218 253. 1 5 1 9 .6972 "
"'-

)>
M ethane - 6 . 024057 1 . 2 68690 - 0 . 5 70278 - 1 . 3 7 5 3 60 93 173.15 26.0390
Tc

Ol
�
Ethane - 6 . 46 1 277 1 .353559 - 1 .04 3 3 60 - 2 . 044654 123 243. 1 5 1 0 . 64 1 7
Propane -6.71 5816 1 . 387038 - 1 . 3 1 1 343 - 2 . 5 6 3 166 1 60 T, 260. 1 5 3 . 1 220
T,
6'
3
n-Buta ne - 7 . 084375 1 . 789499 - 1 . 994745 -2. 3257 1 1 180 280. 1 5 1 . 3 35 6
1 sobutane - 6 . 90 7 1 84 1 . 578704 - 1 . 803286 - 2 . 4 2 7 1 86 1 80 T, 300. 1 5 3.7173
T, 0
""'

n-Hexa ne �
n-Pentane - 7 . 363978 1 .943238 - 2 .47 1007 - 2 . 3491 44 213 343 . 1 5 2.8355 "
Tc
"'
- 7 . 6 1 1 39 3 2 . 007192 - 2 . 744096 - 2 .82 5408 233 303 . 1 5 0. 2498
T,

tl
Cyclohexane - 7 . 009954 1 . 5 7 5 242 - 1 .968888 - 3 .260142 2R3 373. 1 5 1 . 7462 "
T,
3
"'
n-Heptane - 7 . 7 5446 1 1 . 847289 - 2 . 8024% - 3 . 625021 263 373.15 1 . 0619

�
(continued overleajj �
"'

�
--
"'
 �
...
(continued) . --

:to
""
Substance A B c D Range of Verification ""
"'
validation point "
;;: ·
"'-

Tmin (K } Tmax T (K ) P' (bar) :to

Ol
;p
r,
0
3
>t-O c ta ne -8.010138 1 . 984728 - 3 . 25 9 1 3 8 - 4 . 00 3 5 80 283 343 . 1 5 0 . 1 58 3 (")

Ethylene r,
0
- 6 . 4 1 2447 1 .452364 - 1 . 2 39075 - 1 .9968 1 4 1 10 260. 1 5 30. 1 3 1 0
r,
""

�
Propylene - 6 . 6666 1 0 1 .436075 - 1 . 39 5 3 8 1 - 2 .466962 140 280. 1 5 7 1796 "
T,
"'
! - Bute n e - 7 . 078279 1 . 876 1 5 7 - 2 . 0 1 9940 - 2 . 65 1 1 69 183 293 . 1 5 2 . 5462
r,
cl'
Cl
M et h a nol - 8 . 726980 1 .450050 - 2 . 77 1 770 -0. 723874 233 343 . 1 5 1 . 2545

3
Ethanol - 8 . 3 380 1 5 0.087 185 - 3 . 305779 - 0 . 2 59857 253 r, 353.15 1 . 0845
>t- P rop a nol - 8 . 606755 2 . 1 73634 - 8 . 046856 3 . 69 1 766 290 r, 3 64. 1 8 0. 7990 "'
r,
VI
;;
n-Butanol - 8 . 3 30857 2.054 1 3 4 - 8 . 1 75663 0 . 1 90068 275 418.85 2 .4959
Eth yle n e glycol - 7 . 807002 0 . 9 1 5488 -4. 927491 - 1 . 926 1 3 5 333 r, 45 3 . 7 5 0.6057
I s op ro p anol - 8 .439864 1 . 149220 - 6 .938392 0.61 5959 276 r, 3 7 3 .70 2.0101
Acetic acid -9. 345421 3 . 784980 - 3 .602383 - 1 . 5 5 3062 290 r, 364.64 0.4227
Methyl acetate - 8 . 5 74704 4 . 224264 - 5 . 3 68 1 1 4 -0.827557 227 r, 332.15 1 .0881
Ethyl acetate - 7 .897 1 9 1 2. 167535 - 3 . 5 2 3305 - 3 . 107122 242 r, 330. 1 5 0.4977
Vinyl acetate - 7 . 5 54439 1 . 364168 - 2 . 6 5 68 1 3 - 2 .993477 252 r, 352.25 1 . 24 7 1
M e thyl-tert-butyl ether - 7 . 565 3 01 2 . 5 77840 - 3 .917256 - 0.671 678 217 r, 374.55 3 . 74 3 5
Acetone - 7 .670734 1 .9 6 5 9 1 7 - 2 .4454 3 7 - 2 . 899873 213 r, 353.15 2 . 1 544
Benzene - 7 . 1 1 4987 1 .841 409 - 2 . 25 4 1 5 6 - 3 . 1 47450 283 r, 373. 1 5 1 . 8014
Toluene - 7 .498890 2 . 084280 - 2 . 5 56275 - 2 . 8601 3 5 273 T, 333. 1 5 0.1853
p-Xylene - 7 . 6 7 1 695 1 .8 1 2883 - 2 . 387960 - 3 . 45 6690 286 T, 37 3 . 1 5 0 . 3 206
R23 - 7 . 285947 1 . 636279 -2.1 35618 - 2 . 48 1 506 158 T, 263 . 1 5 1 8 .8963
R32 - 7 .470600 1 . 7 5 6960 - 2 . 0 1 5692 - 2. 6 1 9790 158 T, 263 . 1 5 5 .8274
R12 - 6 . 9 1 9773 1 . 62 2 7 1 6 - 1 . 7 34359 - 2 . 589279 1 68 T, 263 . 1 5 2 . 1879
R22 - 7 .092406 1 . 619996 - 2 .01 3 5 1 6 - 2. 729725 1 58 r, 2 63 . 1 5 3 . 5500
R 1 34a - 7 . 649281 1 . 79 8 1 90 - 2 . 660067 - 3 . 3209 2 1 173 r, 263 . 1 5 2 . 006 3
R125 - 7 . 5 3 7003 1 .8 3 7 3 3 9 -2.675330 - 2 . 787620 173 r, 28 3 . 1 5 9 . 0868

The required critical data Tc an d Pc are given in the Table "General data for selected compounds " .
Liquid dens ity corre l ations fo r selected compo u n d s .

L
__!.'f._3 +
[( L
)035 ( 1 t3 ( 1 ) L + L +
( L) ]
4j 3
Equation : __
P 3 A 1 - + B - - D 1 -
T, T, T, T,
= C
kgjm kgjm

Substance Pc ( kgfm 3 ) A B c D Ran ge of Verification

validation point

Tmin ( K) Tmax T (K) P L (kgfm 3 )

Water 3 2 2 . 00 see Eq. 3.52 274 T, 3 73 . 1 5 958.20

Ammonia 224.78 5 3 3 .0864 - 3 9 . 1 990 2 7 1 . 4070 - 7 2 . 5 1 96 1 96 T, 3 1 0. 1 5 584 . 3 3
Hydrogen chloride 450.05 640.0083 462 .2040 - 1 80.0889 2 7 3 . 3080 159 T, 246 . 1 5 101 6 . 46
Chlorine 576.81 908.9017 948 . 048 3 - 1 3 5 3 . 2687 1 09 3 . 5 2 5 2 173 T, 273 . 1 5 1467.02
N itrogen 3 1 3 . 30 47 1 . 2 1 6 9 492.8646 - 5 6 1 . 5971 391 . 1454 68 Tc 123.15 47 1 . 5 4
Oxygen 426.95 748 . 3728 3 96 . 2 3 76 - 4 1 6 . 2 389 3 7 2 . 6904 58 T, 123.15 952.52
T,
Sulfur dioxide
Hydrogen 30. 1 2 5 2 . 8201 2 . 7 1 20 6 . 2764 -4.0288 15.0 18 . 05 73.30
T,
T, .,
)>
5 24.72 1 02 6 . 4 1 47 287.94 1 5 -59.1833 242 . 7 1 78 203 27 3 . 1 5 1 4 3 5 . 62

.,
"'
Carbon monoxide 304 . 1 7 571.93 1 2 - 6 7.0962 387 . 1 504 - 1 2 1 . 7320 68 113.15 626 . 5 3
T,
:s
T, )( '
�
Carbon dioxide 467.60 897 .8433 1 70.0655 169. 2649 37.6341 218 253 . 1 5 1 0 3 1 .67

T,
Methane 1 62 . 66 267.8594 1 29. 3958 - 7 3 . 6070 69 . 9 7 1 4 93 133.15 388 . 78
)>
"
Ethane 206 . 1 8 339.3617 278. 2759 - 326. 5676 246. 4990 93 213.15 5 0 5 . 90
T, s::
til
Propane 220.48 372 . 1 807 3 2 9 . 3 106 -439.7196 3 3 1 .6824 90 280. 1 5 5 1 8. 7 3
n-Butane 228.00 4 1 8 . 6984 246 .8435 - 3 1 7 . 6268 274.8872 T, 280. 1 5
Q
140 5 9 2 . 99

3
T,
.,
!sobutane 2 25 . 50 38 3 . 5 780 3 6 3 . 7638 -483 . 8 1 4 3 3 5 3 . 4964 1 20 280. 1 5 572.34
T,
c
"'
:s
n- Pentane 2 3 5 . 20 3 3 1 . 1 728 680.8988 - 96 5 . 2 0 1 9 602 . 3 687 153 293 . 1 5 62 5 . 5 5
T,.
:s
n-Hexane 222.82 5 3 7 . 4 1 49 87.8736 - 2 8 3 . 5449 344.6594 183 293 . 1 5 659.38
-
"
T,
T, "'
Cyclohexane 273 .02 370.9435 865 . 3421 - 1 29 1 . 8 1 4 1 834. 1977 283 353.15 720. 1 1

i3
3
n-Heptane 224.90 308 .6265 1070.9890 - 1 6 6 3 . 6827 989 . 8 3 2 6 183 293 . 1 5 68 3 . 7 2
T,.
�
"'
n-Octane 227.63 3 14.9330 1030. 8629 - 1 576.0010 9 3 9 . 7454 223 293. 1 5 702 . 3 3

Ol
--
"'
"'
....
(continued overleajj
 "'
...
....
(continued).
):.
"""'
"""'
"
Substance Pc ( k gfm 3 ) A B c D Range of Verification
"
validation point "'-
;;: ·
):.
Tmin (K) Tmax T (K) P L ( kg f m 3 ) "
<::
�
Q
�
"""'
Ethylene 2 1 4.24 364.8832 208.8422 - 1 98. 1 499 1 8 5 . 2 595 1 20 Tc 280 . 1 5 287.91
0
T,
"
Propylene
"
223.39 369. 7 1 24 440 . 5 7 1 3 - 608. 9 5 7 3 4 3 8 . 0698 90 T, 280 . 1 5 533.55

�
! · Butene 237.95 3 74.9006 5 3 2 . 73 7 5 -823 .2356 5 8 5 . 6584 93 283 . 1 5 605.90
Tc
�
i3
Methanol 281 .49 1 64 . 7427 2257.8517 - 3545.8257 1929.8087 183 173. 1 5 810.52

�
Ethanol 276.00 748.6190 - 4 1 2 . 3645 776.4385 - 4 3 6 . 6754 253 T, 343 . 1 5 744.74

�
"
n·Propanol 274.42 816.2710 - 549. 2099 696.9837 - 2 3 2 .0819 147 T, 290 . 5 5 806. 7 6

�
n·Butanol 269 . 5 4 777.2536 -446.84 1 1 578.8807 - 1 72 . 9 5 5 2 185 T, 284 . 1 5 816.58
Ethylene glycol 3 2 4 . 99 1 305.6439 - 1 374 . 3 2 1 8 1 690.8786 -664. 8 1 68 261 T, 381 . 1 5 1048.42
Isopropanol 27 3 . 1 5 865 . 9 1 79 - 744.0946 9 7 5 . 9034 - 3 8 1 . 1 2 80 186 T, 304 . 2 5 776.23
Acetic acid 334.22 92 5 . 3877 - 3 1 2 . 7976 340.0648 29.7201 290 T, 337.55 1000.46
Methyl acetate 324.89 7 3 5 .4603 - 1 3 1 .4940 3 7 1 .8328 - 5 3 .9224 176 T, 297 . 2 5 928. 7 5
Ethyl acetate 308.07 660 . 3 749 8.85 1 3 207 . 1 687 1 . 5101 207 T, 277.45 918.19
Vinyl acetate 3 1 8.88 7 5 2 . 0380 - 204 . 4664 468.8042 - 1 07 . 5 5 5 0 181 T, 287 . 3 5 939. 1 7
Methyl·tert·butyl ether 267.95 6 1 5 . 1 648 - 3 32 . 9 1 7 9 7 1 6. 5664 - 284.87 5 1 165 T, 304 . 5 5 729.60
Acetone 273.58 548 . 0439 205 . 2643 - 197. 7406 250.6303 183 T, 313.15 767.89
Benzene 306 . 28 502 . 4 3 4 1 5 3 1 . 5958 - 66 3 . 9 8 5 3 469.5977 283 T, 343 . 1 5 825.92
Toluene 292 . 1 2 439 . 5 8 3 5 8 39 . 1 5 5 8 - 1 234.8445 797.8741 183 T, 313.15 848 . 5 3
p·Xylene 280.90 660. 6 6 1 2 - 2 7 9 . 7990 602.9859 - 1 9 2 .8244 287 T, 321.15 8 3 6 . 72
R23 5 2 5 . 96 640.0829 2 1 66.2973 - 3 069. 2 6 5 5 1827 . 1 404 158 T, 283 . 1 5 941 . 76
R32 424.00 895 2 7 5 7 224 . 1921 - 50.9230 229. 6594 138 Tc 27 3 . 1 5 1054.86
R12 5 6 5 . 00 914.8334 994.9288 - 1 324.2838 961. 0109 123 T, 27 3 . 1 5 1 395 .42
R22 520.01 904 . 0763 874. 3000 - 1 1 76 . 1 5 5 6 880.9367 123 T, 28 3 . 1 5 1246 . 6 1
R l 3 4a 5 1 1 .94 1 04 3 .9503 239.7177 - 1 02 . 7 6 3 3 287.7073 173 T, 283 . 1 5 1 260. 67
R125 5 6 5 . 78 800. 1 882 1 9 1 7 . 3007 -2752.5653 1 696. 7682 173 Tc 283 . 1 5 1272.60

fhe required critical temperature Tc is given in the Table ""General data for selected compounds".
Enthalpy of vaporization correlations for selected compo u n d s .

Equation : tl.hv = RTc (Ar113 + Br 2 1 3 + Cr + Dr 2 + £r 6 ) , T = 1 - Tj T,

Substance A B c D E Range of Verification

validation point
Tmin {K) Tmax {K) T (K) .d hv (Jf g)

Water 6 . 8 5 3 064 7 . 437940 - 2 . 9 3 7 398 - 3 .282 1 84 8 . 3968 3 3 273 r, 323.15 2380.25

Ammonia 5 . 744770 7 . 282878 - 2 . 428749 - 2 . 26 1 92 3 2 . 909393 1 96 r, 300 . 1 5 1 1 57 . 7 0
Hydrogen chloride 7 . 669223 0.21 1221 0 . 9 1 7 107 - 1 . 245487 4 . 5 26673 159 r, 246. 1 5 370.87
Chlorine 5 . 1 1 3960 5 . 494794 - 1 . 6 39730 -2. 193617 4 . 3 5 64 5 5 173 r, 273 . 1 5 267.42
N itrogen 5.063172 5 . 5 1 8 1 54 - 2. 6459 1 3 - 1 .981 109 5 . 3 3 3 3 68 65 r, 93.15 1 74.93
Oxygen 4 . 9696 1 7 5 . 305 3 1 9 - 2 . 426090 - 2 . 1 5 1263 3 . 466285 58 r, 123. 1 5 167.73
Hydrogen 4. 1 1 52 5 6 2 . 5 1 1 597 - 1 .539154 - 2 . 5 78672 2 . 1 65454 15 T, 20.05 46 1 . 39
Sulfur dioxide 6 . 4 3 1 380 6.405860 - 2 . 656015 - 0 . 900937 6. 5022 1 1 203 Tc 323.15 328 . 1 6

):.
Carbon monoxide 5 . 3 6 5 1 60 4 . 6 1 5630 - 1 . 502620 - 2 . 360346 7 . 2 14583 68 T, 101 . 1 5 1 8 1 .89
Carbon dioxide 6. 285 898 5 . 640077 - 1 . 240625 - 2 . 040365 26. 542058 218 r, 253. 1 5 282.44
�"'
::s
Methane 4 . 9905 5 5 5.035 1 5 1 - 2 . 28 3 393 - 2 .4609 3 3 4 . 3 78278 93 T, \83. 15 2 1 4.96

"-
;;: ·
):.
Ethane 5 . 240570 7 . 1 9 5872 - 4 . 6 3 5 360 - 0 . 641 593 2.271410 93 T, 243 . 1 5 388 . 6 2
Propane 5 . 532218 7 . 865983 - 5 .298339 0.075567 2 . 1 54822 90 T,- 280 . 1 5 364 . 5 9

�
n·Butane 5 . 894590 7.877690 - 5 .041876 - 0 . 1 5 1 283 3 . 790784 140 T, 280. 1 5 379.00
�
!sobutane 5.985358 6 . 8701 70 - 3 . 95 7940 - 0 . 3 5 6806 2 . 9 57430 1 20 r, 280 . 1 5 347.69
T, Q
3
.,
n· Pentane 5 . 7 5 2 590 9.973145 - 6 . 896600 0 . 5 3483 1 4.463225 153 273. 1 5 3 8 5 . 00
Tc
0
n·Hexane 5 . 8 2 3448 1 1 .201235 - 8 . 0 7 1 440 1 . 348380 3.456936 183 343 . 1 5 3 3 3 .92

::s

�
Cyclohexane 3.437910 1 4 . 06 1 5 1 0 - 8 . 7 30995 0.671730 0.025579 283 T, 294 . 1 5 394 . 3 4
n-Heptane 3 3 1 6640 2 1 . 992820 - 1 8.808 160 5 . 5 34334 2 . 9 3 1 020 183 T, 303 . 1 5 362 02
"'
�
tl
n·Octane 4.4642 30 1 9 . 78 3260 - 1 6 .839 300 5 . 360490 3 . 956600 223 T, 3 03 . 1 5 3 6 1 .66

3
;;
"'
Vl
-
(continued overleajj

�
"'
 "'
....
"'
(continued). --

""
-S"
"'
"
Substance A B c D E Range of Verification
validation point "'-
;:;: ·
Tmin (K) Tmax (K) T (K) .<i h v (J fg) ):.

�
�
('\
0
3
""
Ethylen� 5 . 1 43747 6 . 9 3 4 1 86 - 4 . 2688 3 1 -0. 584890 3.213931 110 T, 250. 1 5 303.81
r,
!-Bu te n e "
0
Propylene 4.8630 1 4 9 . 287801 - 6 . 283872 0. 380303 1 . 3 2 5 099 88 280 . 1 5 366.30

"'
T,
M etha n o l �
5 . 495498 9. 245589 - 6 . 920092 1 .448008 2 . 307289 93 303 . 1 5 354.54
5 . 46 5 5 79 1 5 . 6 1 6850 - 7 . 6764 1 6 - 4 . 926600 6 . 3 34842 183 T, 373 . 1 5 1 020.27
r,
�
i3
Ethanol 1 4 . 687649 - 1 5 . 27 1 1 94 26.062303 - 2 0 . 04966 1 1 5 .8 1 6495 253 293. 1 5 925.91

3
�
n-Propanol 5 . 890074 1 6 . 292544 - 5 . 7 7 79 1 3 -2.767181 -8.575518 293 T, 343.65 740.74
r,
Tc "'
n-Butanol 3 . 92 5 2 2 6 18.801993 - 5 . 348588 - 2 . 9 3 7749 -0. 1 8 1 003 224 343.85 654.47
Ethylene glycol ;;j
7 . 07 9 1 69 8 . 7 2 1 527 1 .0 1 3498 - 5 . 214016 4 . 44 1 808 333 333.15 1 027.05
Isopropanol 1 3 .846539 - 1 6 . 693668 3 2 . 098404 - 19.9002 1 5 - 9 . 894509 253 r, 304. 2 5 7 5 7 . 07
Acetic acid 6 . 686640 1 5 . 0 1 448 3 - 22 . 08661 8 3 . 077698 1 7 . 354972 290 T, 369 . 3 5 3 9 5 . 64
Methyl acetate 6. 3988 3 3 1 3 . 1 2 5 464 - 1 2 . 779956 5 . 864096 - 9. 1 68706 227 T, 297 . 2 5 439.04

Ethyl acetate 8 . 5 68302 3 . 6 9 1 585 - 0 . 6 1 4594 - 0 . 6 3 5779 0.817636 1 90 T, 330.15 3 8 1 .82

Vinyl acetate 7 . 959075 5.923838 - 2 . 473449 - 1 .445 393 4.01 3 308 273 r, 336.35 377.62
Methyl-tert- 7 . 677 1 2 5 3 . 10 1 996 0. 388899 - 1 . 672830 0. 763 1 38 217 T, 339.55 3 1 1 . 02

butyl ether
r,
B enzen e
Acetone 5.731751 9. 1 74230 - 4. 934225 0.048998 3 . 7 3 5669 183 37 3 . 1 5 448 . 7 3
T,
Tolue n e
5 . 007470 1 0 . 6908 1 0 -7.3 16719 1 . 1 407 1 4 6.786710 283 333. 1 5 408 . 3 1
4. 607790 1 3 .962 1 60 - 1 0. 5 79 1 48 2 . 1 1 2462 4 . 2 84860 183 r, 323.15 398.25
p-Xylene 8. 707394 1 . 08 1 8 3 6 2 . 5 7 1 094 - 3 .4 3 5 0 2 1 9.405508 287 r, 373.15 361 . 1 3
R23 5 . 3460 1 6 10.065090 - 6.445266 0.855815 0 . 1 00753 158 r, 253.15 1 70.98
R32 6. 302860 6 . 634830 - 2 . 5 30184 - 1 . 546727 4 . 892836 138 r, 253.15 344 . 1 2
R12 5 . 672474 8.015016 - 5 . 1 35777 -0. 1 86 5 1 8 4 . 6 1 6427 123 r, 253.15 162.o7
r,

R 1 34 a
R22 5 .94 1 889 7 . 847445 - 4 . 7 36810 0 . 1 1 8054 4 .060834 123 253.15 220.00
7 . 2 58 1 60 4.942 1 0 5 - 0 . 1 5 5 284 - 2 . 7 6 1 780 1 2 . 4 5 5860 173 r, 27 3 . 1 5 1 98.76
R125 5 . 543650 1 1 . 76 1 440 -8. 102561 0.932260 5 . 1 773 1 9 173 Tc 27 3 . 1 5 133.16

The required critical temperature T, and the molar mass M are given i n the Table "General da ta for selected com p ound s " .
Liquid heat capacity correlations for selected compou nds.

Equation : c� = R (� + B + C r + Dr 2+ Er 3 + Fr4) , T =
T
1--
Tc

Substance A 8 c D E F Range of Verification

validation point
Tmin (K) Tmax (K) T (K) c� (J /(g K))

- -
Water 0 . 2 5 5 980 1 2 . 545950 - 3 1 .408960 97.766500 - 145 .423600 87.01 8500 273 586 343 . 1 5 4 . 1 87 5
Ammonia 0 . 5 1 8380 8 . 1 1 1677 - 3.922537 1 6 . 080840 - 1 8.078723 -4. 265 080 205 355 265 . 1 5 4.5730
Hydrogen chloride 9.205 1 42 - 3 . 5 ! 8062 1 59 185 1 82 . 8 5 1 . 7487
Chlorine 0. 348448 9 . 5 8 1 768 - 3 5 . 8 2 3 396 1 98.970547 - 4 5 6 . 44023 4 365 . 47 7 1 24 173 383 273 . 1 5 0.9791
Nitrogen 0.468003 5 .8 5 9 1 2 5 - 3 . 29447 1 10.949390 - 1 0 . 9 3 1 129 3 . 5 2 1 050 68 113 1 03 . 1 5 2 . 4109
Oxygen 0 . 49 1 044 4.97 1 1 89 3 . 1 65818 - 1 5 .7 30230 3 5 . 1 29 3 5 8 - 24.450400 58 1 38 1 03 . 1 5 1 . 7546
Hydrogen 0.412752 1 . 939203 -0. 676502 2 . 1 6 1 263 - 9 . 684044 1 4 . 4 1 0 1 97 16 28 18.75 1 1 .2238

)>
Sulfur dioxide 4.251653 203 413 303 . 1 5
""'
0 . 492030 9 .882450 - 5 .736710 1 2 .991 290 - 7 . 898405 1 .403 3

""'
"'
Carbon monoxide 0.434226 6 . 8 52270 - 7 .8 26240 2 5 . 69 3 5 70 - 3 9 . 2 1 9 300 3 1 . 506260 68 125 10 1 . 1 5 2 . 3261
"'
"'-
Carbon dioxide 0 . 5 00361 8 . 830377 - 3 . 8688 3 7 1 0 . 3 24592 0.675891 1 . 845 1 8 3 218 283 253. 15 2. 1654
5<'
)>
Methane 0.407 1 1 2 7.061 3 6 5 - 1 1 . 142546 37.881423 -60.945893 38.024820 93 168 123.15 3 . 5803

"
�
<::
Ethane 0.428053 1 0 .459037 - 1 8 . 182884 5 1 . 7 1 1 500 - 7 5 . 884470 44 . 5 00540 93 283 213.15 2 . 5942
Propane 0 . 5 5 8680 1 2 . 802352 - 5 . 738203 -9. 5 5 1 125 26. 702477 - 1 5 . 77 5 1 34 81 330 280. 1 5 2.5415

�
�
n-Butane 0 . 4942 2 1 19.195325 - 1 1 . 64623 3 - 1 3 .063580 3 7 . 5 5 26 3 7 - 18 . 508970 140 400 280. 1 5 2 . 3449

""'
1sobutane 0.497 3 3 0 1 8 . 773678 - 1 4 . 5 5 2 1 60 - 0 . 2 54646 1 9 . 3 5 9040 - 1 5 . 8 8 1 925 120 380 280. 1 5 2 . 3207
0
"'
n-Pentane
"'
0.493 1 5 7 2 5 . 403260 -18.571 150 -8.45 5922 2 7 . 383 1 10 - 5 . 186790 !53 443 273 . 1 5 2 . 2 1 00

�
n-Hexane 0 . 503827 30.695832 - 16 . 437834 - 28 . 1 45485 50. 3 1 2 7 1 0 - 18 . 044650 183 463 333.15 2.4093

�
a
Cyclohexane 0.452602 29.040500 - 1 7 . 260650 - 6 9 . 5 08970 2 5 4 . 3 8 1 420 - 307.047 1 20 283 523 298.65 1 . 8 1 45

�
n-Heptane 0 .2741 3 1 3 9 .690828 - 38. 327579 48 . 5 35630 - 1 1 6 . 903726 1 1 5 .685562 183 523 393 . 1 5 2 . 6629

1;i
"'

(continued overleajj
--
�

0\
"'
....,
 "'
....
..
(continued) .

�
"'
""'
:::.
Substance A B c D E F Range of Verification
validation point "'­
;;: ·
Tmin (K) Tm•x ( K) T (K) c� (J/(g K)) )>

(;\
�
bl
3
n-Octane 0. 6 1 5 2 1 5 4 2 . 7 5 3 600 - 2 7 . 390185 8 . 2 285 1 0 - 5 8 . 65 2690 79. 1 1 6 1 70 223 533 293 . 1 5 2 . 2091

""'
:::.
Ethylene 0 . 475969 7 . 5 65091 - 3 . 36 1 502 - 1 . 6020 1 4 2 4 . 5 4 1 1 97 - 2 2 . 072075 1 10 260 250. 1 5 3 . 3689
0
"'
Propylene 0.4988 1 7 1 2 . 3 24942 - 1 0 . 1 68 1 20 1 1 .351221 - 9 . 765026 1 0 . 9 1 4720 93 350 280 . 1 5 2 . 49 1 8

;;
1 -Butene 0.474628 1 7 . 444100 - 16 . 144424 1 8 . 5 6 3 3 60 -20.820925 1 6 . 6 54776 93 383 243 . 1 5 2 .0809

;s>
<:;
Methanol 0. 6 1 2632 1 3 . 1 9 5540 - 5 . 208870 - 4 5 . 76 2 1 2 0 9 1 . 190270 -44.456 180 183 463 32 3 . 1 5 2 . 7082

3
"'
Ethanol 0 . 5 0 3 568 2 2 . 442022 - 36.783235 1 60 . 3 7 3 246 -466.432673 396 027992 253 473 343 . 1 5 3 . 0966

"
n-Propanol 0. 3 1 3992 4 2 . 5 98 ] ! 7 - 78.401 260 3 0 . 6 1 2206 40 . 10 2 1 6 6 - 1 6 . 5 8849 1 147 400 293.45 2. 3626

;;:
n-Butanol 1 . 203976 50.595 3 1 4 - 9 1 . 3 3 1 488 3 7 .897784 28.22 5069 - 2 . 3 5 1 873 185 391 303.95 2 . 45 1 3

Ethylene glycol - 0 . 1 06462 3 2 . 547745 -27 .000190 2 2 . 1 66665 -43.223418 2 1 .074 1 3 6 261 493 284.65 2 . 3 342

Isopropanol - 0.0280 1 1 37 .27272 1 - 60. 2 1 2901 145.141653 - 4 1 5 . 6 1 2074 383.532 1 17 185 480 293.85 2 . 5706

Acetic acid 0 . 1 29079 2 3 . 227878 - 19 . 0 3 5099 1 1 . 1 72422 - 32 . 209650 3 2 . 222624 290 413 332.23 2 . 1 868

Methyl acetate - 3 . 2 701 5 3 54.948876 - 1 1 0 . 920230 7 3 . 069065 86. 1 5 2790 - 9 1 . 367990 177 373 329. 1 5 2 . 0263

Ethyl acetate 1 . 5 5 8660 24. 189499 - 26 . 4 5 1 00 3 27.6445 5 3 - 2 5 . 493 382 29.857034 190 350 316.35 1 .9958

Vinyl acetate 0 . 5 32294 28.92 0 1 2 1 - 2 6 . 3 29666 18.066 3 7 1 - 4 1 . 7789 18 48 .998543 260 389 266. 3 5 1 . 8743

Methyl-tert-butyl ether 0.681223 28.641641 - 26 . 2 76 1 3 2 26.982673 - 34. 1 7 7 1 3 3 2 2 . 9 1 2098 165 328 29 3 .85 2 . 1 107

Acetone 0.4401 8 3 1 7 .664600 - 8 . 86 6 3 5 6 - 1 1 . 726743 34. 192440 - 1 7 .4240 5 6 183 503 333.15 2 . 2404

Benzene 0. 497842 2 2 . 393654 - 1 5 . 407940 3 . 3 9 1 770 - 2 5 . 948450 39 . 5 1 0594 283 523 343 . 1 5 1 .8693
Toluene 0.472576 28.776500 - 29. 760240 48 .79 3090 - 1 1 3 . 292550 94. 204740 183 563 313.15 1 . 7496
p-Xylene - 0 . 298962 48.97 1447 - 144 . 5 3 9 1 20 4 5 1 . 2 79840 - 8 1 1 . 386690 5 5 1 . 296903 287 5 67 3 3 5 .95 1.8151
R23 0 . 583673 8.825460 3 . 660254 - 28 . 7 1 5 384 7 1 . 3 3 6899 - 5 7 . 63 1 705 158 288 263 . 1 5 1 . 63 1 9
R32 0 . 48278 1 9 . 7 3 6 5 60 - 7 . 746770 1 8 .994675 - 2 2 . 694329 1 6 . 2 3 2080 138 343 29 3 . 1 5 1 .8863
Rl2 0.4699 1 7 1 4 . 390100 - 1 7 .0069 1 0 5 3 .677 1 90 - 1 04. 5 1 1075 78 . 2 1 5 790 123 373 29 3 . 1 5 0.9757
R22 0 . 5 09972 1 1 . 1 54020 - 3 . 7 30 1 3 1 - 1 . 359015 1 1 . 3 25878 - 5 . 456086 123 353 29 3 . 1 5 1 . 2 395
R 1 34a 0.509 6 1 4 1 7 .066100 - 1 5 .8 34770 3 9 . 3 90760 -69. 727496 5 3 . 4 5 5900 173 368 29 3 . 1 5 1 .405 3
R125 0 . 6 1 9806 1 5 . 4 7 3 500 2 . 397560 - 32 . 903800 3 3 . 244360 2 2 . 7 29920 173 333 293. 1 5 1 . 3682

The required critical temperature T, and the molar mass M are given in the Table "General data for selected compounds".
 Appendix A Pure Component Parameters 1 629
Ideal gas heat capacity correlati o n s for selected compou nds.

Equations :

__r_
dd
R
B B) l [1
+ (C - + (y - l)(D + Ey + Fl + G/ + Hl)] , y= A+ (A. l )
T

=A+B( r+D( r
=

T
cid
p

J / (kmol K)
Cj T
sinh ( C/ T)
Ef T
cosh(E/ T)
(A . 2 )
Substance Number of A B c D
equation

Water A. 2 3 3484. 7 5 927 5 . 3 0 1 2 18.48 2024 1 . 42

Ammonia A.2 3408 3 . 1 8 26087.00 990.77 3 3 100.02
Hydrogen chloride A.2 2 9 1 4 1 . 68 8602 . 70 2038.41 995 56.02
Chlorine A.2 29197.65 8502.80 405.49 - 3 2 5 3 . 99
Nitrogen A. 2 2 9 1 08 . 79 8526.28 1678.41 66784.83
Oxygen A.2 29 1 1 6.90 1 04 3 7 . 46 2565 .44 93 38.84
Hydrogen A.2 2046 3 . 6 1 9591 . 1 9 2 1 6.79 16524.83
Sulfur dioxide A. 1 904 . 5 3 3 5 1 3 . 981 1 8 5 .66358 3 . 2 1 967
Carbon monoxide A.2 29104.60 866 5 . 8 1 3043 . 79 8336.18
Carbon dioxide A. I 1 8 8 . 2 7392 3 . 50426 8. 29771 4 . 7 1 883
Methane A.2 33356.35 45763.85 1025.42 48699. 0 1
Ethane A.l 903 . 4 1 1 3 5 4.48148 1 1 . 69046 8 . 47923
Propane A. 1 1 2 2 2 . 85277 4.63428 6 . 1 7777 - 3 1 . 84476
n-Butane A. l 668 .649 1 8 8.908 1 0 1 4 . 24670 4 1 . 04664
Isobutane A.l 2084.48 3 3 4 5 .07542 7.06 1 98 - 264 . 30 2 1 8
n- Pentane A. I 1074. 74180 8. 97762 1 1 .92509 3 1 . 16797
n.- Hexane A. l 918.01459 1 1 . 29386 1 8 . 05869 29. 3 3969
Cyclohexane A.l 6 7 1 .99039 4 . 04945 5 . 43698 67. 1 7766
n- Heptane A.l 7 5 1 . 2 1 484 1 4. 78843 1 7 .8 2902 1 2 1 . 15456
n-Octane A. 1 580. 69298 2 2 . 78850 3 2 . 5 0664 7 3 . 77 5 3 7
Ethylene A.1 1 00 . 67955 3 .46632 1 8 . 86798 - 1 . 5 8496
Propylene A.l 2039 . 5 7 2 3 8 4 . 2 7246 6 . 58039 -84.96 3 3 2
! -Butene A. I 444.42742 4.002 1 5 4 . 77657 - 1 0 3 . 78383
M ethanol A. I 7 2 . 3 2 1 65 -43 .80600 1 8 . 04246 - 8 . 74148
Ethanol A.l 1 1 65 .86482 4 . 70209 9 .77865 - 1 . 1 7688
n-Propanol A. 2 6 1 7 2 3 .88 203342.08 757.27 -967 2 7 . 69
n-Butanol A.2 74802.09 1 67505.02 -711 .59 1 30880 . 3 7
Ethylene glycol A. 1 3 1 6 . 790 1 9 3 . 05 2 4 1 3 . 58464 - 1 52 . 76283
Isopropanol A.1 3 1 3 . 1 0693 8 . 962 18 9 . 4 1 683 702.94470
Acetic acid A.l 589.884 1 7 5 . 10642 5 . 5 2776 2 1 1 .48957
Methyl acetate A.2 54664.40 1 79099 . 9 5 595.63 - 1 065 1 4 . 5 2
Ethyl acetate A. 2 99847 . 1 6 2 1 0798 . 7 3 -947 . 3 9 - 5 2228.85
Vinyl acetate A.1 3 3 9 .004 5 3 10.85084 1 1 . 20264 1 1 1 6 .09686
Methyl-ten-butyl ether A.2 100524.03 2068 5 3 .45 -807.44 1 3764 1 . 68
Acetone A.2 5808 3 . 2 5 1 0 1 389. 1 5 - 761 .09 84650.28
Benzene A.1 560.93643 4.00088 6 . 208 1 1 2 2 . 1 93 0 1
Toluene A.1 1 250.94941 3 .99957 1 0 . 7 3 3 66 - 1 9 . 78047
p-Xylene A.1 1 2 99.9 1 280 4.4309 1 6.06047 - 22 9 . 7 3 9 1 0
R23 A.1 766.08865 4 . 000 5 5 4 . 56857 5 7 . 65285
R32 A. 1 889 . 2 3 598 4 . 39579 9 .60005 1 5 . 90687
R12 A. 1 7 2 2 . 38297 3 . 1 38 2 1 3.33217 - 8 1 8 . 7265 1
R22 A.1 1036.65937 3 . 60012 4. 64243 -89.43873
R l 34 a A.1 1 1 08 . 3 9974 4 . 00203 6.01963 - 1 38.01236
R125 A. l 863.9005 3 6.1 1410 6 . 4 1 788 - 3 0 1 .848 5 5

(continued overlea.fl
63
0 I Appendix A Pure Component Parameters

(continued) .

E F G H Range of Verification
validation point

Tmin (K) Tmax (K) T (K) 4 UJ (g K) )

1919.59 278 1173 373.15 1 . 8909

2905 .60 196 1 500 394.75 2. 2598
8581 . 3 3 so 1 77 3 355.25 0.7996
3892.43 173 1 1 23 273. 1 5 0.472 1
1 0672.63 73 1773 313.15 1 .0399
1 1 49.97 63 1773 1 200 1 . 1 1 50
39 5 5 . 44 24 2173 513.15 1 4.6353
-88.88 1 44 186.92401 - 1 2 1 . 5 5 5 29 0.0 203 1773 343 . 1 5 0.6483
1 5 3 1 .93 73 1773 313.15 1 .0407
- 1 1 . 7 5 1 09 1 3 .94035 - 6 . 7 3 001 0.0 223 1273 373. 1 5 0.9158
2664 .97 93 1823 29 3 . 1 5 2 . 2073
- 7 7 . 02 1 5 1 1 2 1 . 97656 -74.05999 0.0 123 1 500 273. 1 5 1.6518
-487 . 5 8 9 1 8 1 2 1 6 . 90986 - 9 7 2 . 09252 0.0 123 1 500 373 . 1 5 2 . 0080
- 2 58. 18297 4 1 1 .82384 -258 .68803 0.0 163 1 500 373. 1 5 2 . 03 1 4
-47. 27861 2 3 09.95 342 - 3 5 24.85868 0.0 143 1223 373. 1 5 2.0137
- 59 2 . 5 0 3 5 1 1 2 0 1 . 6499 1 -830. 32720 0.0 183 1673 323 . 1 5 1 . 7761
- 307.72814 5 5 6 . 38463 - 3 5 6 . 72 1 60 0.0 193 1773 313.15 1 . 7239
- 79 5 . 7 5 587 1 090.93493 - 7 0 1 .78714 0.0 283 1273 373. 15 1 .6512
-843.82591 1 3 60. 0 1 383 - 814.87301 0.0 183 1773 303 . 1 5 1 . 6734
- 348 . 56358 493. 58782 - 170.191 4 1 0.0 233 1773 303 . 1 5 1 . 6663
6 . 3 7008 0. 00005 - 0 . 00003 0.0 1 43 1273 473 . 1 5 2 . 1 337
- 389. 76058 2 1 8 1 .03718 - 1 78 6 . 7 1808 0 0 1 00 1210 280. 1 5 1 . 4656
269 . 0 1 469 - 5 4 5 . 1 5 186 27. 1 5 3 1 1 0.0 93 1273 293 . 1 5 1 . 499 1
1 0 . 37780 -0.33156 - 1 .05 900 0.0 183 1023 303 . 1 5 1 . 3840
- 1 35 . 76765 3 2 2 . 7 5959 - 247.7 3488 0.0 100 1 500 373 . 1 5 1 . 66 3 5
880 . 1 3 200 1 77 3 473.65 1 . 0484
2 2 1 3 . 47 200 1 77 3 473.65 2 . 1 41 3
2 1 2 . 94465 84.60646 - 662 . 8 1 1 3 4 0.0 1 00 1000 373. 1 5 1 . 5 5 68
- 32 9 5 . 08 1 98 5 34 5 . 62488 - 3 4 3 5 . 86066 0.0 100 1 500 573. 1 5 2 . 3965
- 1 404. 1 09 1 2 2057.41 805 - 1 3 1 7.64721 0.0 50 1 195 373. 1 5 1 . 2 540
660.06 298 1773 424. 5 5 1 .4729
1 2 03 . 3 5 268 1273 473.65 1 .7668
- 5 1 1 7. 97374 8086 .03265 - 5 0 2 2 . 3 7492 0.0 1 00 1 500 394 . 7 5 1 .4167
2358. 1 6 268 1 500 336.85 1 . 5946
2 186 . 5 9 183 1773 313.15 1 . 3247
- 1 59.24845 -48.97058 1 5 5 . 54 1 3 2 0.0 2 00 1023 37 3 . 1 5 1 . 3487
- 2 1 8 . 247 1 3 677.57410 - 5 9 5 . 4 1 549 0.0 183 1 27 3 313.15 1 . 1 85 8
- 186.84354 1 1 5 6 . 78 3 5 0 - 1 1 6 4 . 5 3 180 0.0 200 1 500 3 36 . 8 5 1 . 3 369
-767.99 1 8 1 1 4 3 1 . 42397 - 9 2 3 .07484 0.0 163 1773 363 . 1 5 0.8213
- 1 1 1 . 3 1 449 190 . 1 1 067 - 1 1 2 . 69276 0.0 143 1773 3 73 . 1 5 0. 9440
1463. 34239 -979.86258 - 1 88.05965 0.0 123 1773 3 73 . 1 5 0.6677
2 2 . 60799 204 . 5 8845 - 2 4 1 .99955 0.0 123 1 773 373.15 0.7332
3 3 4 . 5 1 996 - 4 1 7 . 38 3 1 3 - 4 . 62768 0.0 173 1773 373 . 1 5 0.9632
- 4 2 3 . 46781 1 665 . 3 1 1 09 - 2 6 1 2 . 24748 0.0 173 1773 373.15 0.8932

The required molar mass M is given in the Table "General data for selected compounds ' ' .
Liquid visco sity correlations for selected compou nds.

ry L
Equation : - = E exp A -- --
Pa s
·
[ (c- r y/3 (c- ry/ 3 ]
T-D
+B
T-D

Substance A B c D 108 E Range of Verification

validation point
Tmin (K) Tmax (K) T (K) 'It (mPa s)

Water 1 . 02 3 096 0 .669483 640 . 884 1 24 . 8677 4694 . 8 3 2 274 638 333.15 0.4645
Ammonia 2 .081 580 0 . 6 3 7466 409 . 229 2 9 . 3 262 2290 . 3 30 196 400 278.65 0. 1 605
Hydrogen chloride 5 . 97 3 708 - 0 . 6923 1 3 446. 3 3 2 99.6543 55.655 233 313 233. 15 0 . 1 647
Chlorine 0.485 630 1 . 344777 439.888 - 1 09 . 3 797 1 7 1 3 5 . 830 173 416 2 23 . 1 5 0 . 5 582
Nitrogen 2 .238583 0 . 0 1 8882 127.141 36. 1 39 1 1 34 3 .698 68 1 23 113.15 0 . 0478
Oxygen 2 . 1 48 5 5 0 0. 000 5 3 2 1 5 7 . 422 3 6 . 1 14 1 1839. 3 1 5 73 148 113.15 0. 1 098

)>
Hydrogen 1 . 5 2 5476 0.000001 3 3 .246 7.4900 285 . 1 92 14 33 18.2 0.0157

�"'
"'
Sulfur dioxide 1 2 . 38 3 6 1 0 1 0 . 060090 598 . 1 54 - 1 5 2 5 . 6990 1 2 . 008 225 4 00 280 . 2 5 0 . 3 347

"-
Carbon monoxide 1 .0 3 7 4 1 0 1 . 39 1 890 1 69.937 - 4 3 .9656 289 3 . 372 68 131 88. 1 5 0 . 1 460

i< '
)>
Carbon dioxide 2. 7 0 1 205 4 . 82 1 786 304.972 - 2 1 9.7839 296 5 . 800 218 298 221 . 1 5 0.2374
M ethane 2 . 3 1 3648 0. 668030 200. 2 1 1 - 1 9 . 1 784 1 039. 192 93 178 123.15 0. 0920

"
Ethane 2.435910 0.097 102 309 . 7 3 4 3 3 .4667 1 5 54. 1 80 103 293 213.15 0 . 1 175 �
�
�
Propane 2 . 5 63440 0 . 1 6 1 368 372.533 3 8 . 03 3 1 1 7 5 1 . 1 40 90 350 280. 1 5 0 . 1 1 75

-,.
n-Butane 2 . 629043 0 . 2 3 7 3 24 428.065 3 7 . 0486 1801 .085 1 40 420 272.65 0.2035

"'
0
"'
lsobutane 2 . 794999 0.373353 419.617 28. 0546 1 5 67. 570 1 30 390 250. 1 5 0.2615

�
n-Pentane 2 . 803 3 1 2 0.2 50738 474 . 4 5 5 3 2 . 8562 1 6 5 2 . 600 163 463 27 3 . 1 5 0.2830

�
tl
n-Hexane 0.65 4 1 92 0 . 3 6 44 1 2 902 . 902 18.83 1 2 4603 . 1 84 175 343 256. 1 5 0. 4596

�
Cyclohexane

"'
2 . 889560 0. 0008 5 3 4884 . 2 30 1 1 5 . 5 702 1 7 .677 280 553 303 . 1 5 0.82 1 4

I;
n-He ptane 2 .960020 0 . 2 47 1 5 3 5 5 3 . 942 62 . 17 1 9 1 424. 064 203 513 263 . 1 5 0 . 6070

�
--
"'
!:::
(continued overleaf)
 "'
...
"'
--

.,
)>
.,
(continued) .
"'
l oB E "'-
::s
)( "
Substance A B c D Range of Verification
validation point )>

"
"1J
�
Tmin (K) Tmax (K) T (K) .,l (mPa s)

[;'
�
.,
0
"'
n-Octane 2.870880 0 . 3 54830 5 7 7 . 5 34 48.9830 1 72 1 .664 223 553 283 . 1 5 0.6176
::s

�
Ethylene 2 . 098284 0.091 540 281 .46 1 47.5527 2107.291 110 270 250. 1 5 0.0655
Propylene 1.41 3955 0. 360563 7 1 2 . 79 1 - 1 6. 7 1 2 9 1 1 80. 602 88 320 283 . 3 5 0 . 1 03 9

;?
<l
1-Butene 1 . 1 22814 1 . 464498 4 3 1 . 564 - 78.5456 4506.029 120 413 259. 1 5 0. 2009

�
�
Methanol 3 . 7487 1 0 0.2 1 3 107 546. 888 8 2 . 9003 8 1 8 . 340 176 483 303.65 0.5010

"'
Ethanol 6 . 1 68237 - 0 . 00 1 200 740 . 289 90.7653 38. 1 2 5 1 69 516 326.35 0 . 6496
n- Propanol 6 . 1 407 1 6 0.001 4 1 1 5 7 1 .434 1 3 3 .6983 1 3 5 . 184 217 370 276.25 3 .402 1 Vl
n- Butanol 4 . 3 64 7 1 6 1 .0057 5 2 743 . 4 1 8 27.0658 2 1 1 . 208 190 562 327.35 1 . 2962
Ethylene glycol - 0 . 44 3 5 6 1 1 . 3 1 8848 89 5 . 794 79 . 3 6 1 6 203 1 7 . 7 6 1 261 450 320. 1 5 7 . 60 7 1
Isopropanol 0 . 5 3 6067 1 . 881026 1 14 3 . 342 -77.3655 386.920 188 363 293.45 2 . 3078
Acetic acid 2 . 230867 0 . 7 1 5487 5 2 7 . 102 77.23 1 3 5 5 6 7 .007 288 393 327. 1 5 0.7514
Methyl acetate 2.0725 1 7 2 . 2 39494 489 . 7 5 6 - 1 76.43 1 5 3968.760 250 425 277.65 0.4462
Ethyl acetate 2 . 2 3 3 189 5 . 92 1 434 608.986 - 574.6203 1 98 1 . 9 1 3 220 473 286 .65 0 . 489 3
Vinyl acetate -0.0761 34 1 . 103327 668 . 1 29 - 1 3 .9030 1 0998 . 540 225 346 275.75 0 . 5 284
Methyl-tert-butyl ether 1 . 4 1 6944 0.905146 712.916 - 4 2 . 5 044 2260.808 180 450 29 3 . 65 0. 3503
Acetone 1 . 895877 0 . 3 3 7 1 09 766.008 2 1 .4982 1613.371 190 333 298 . 1 5 0 . 3046

To luene
Benzene 2 . 486500 2. 199610 787 . 2 5 3 - 2 5 5 . 5922 8 5 5 . 5 45 279 545 3 03 . 1 5 0.5633
2.954350 - 0 . 000010 1 047 . 1 7 9 1 37.2255 397. 694 221 588 275.55 0 . 7 500
p-Xylene 0 .809643 1 . 3 7 1 902 6 3 8 . 5 09 -40.40 1 8 6772. 298 282 613 3 1 9. 7 5 0.4728
R23 1 . 720363 0.385773 288.676 44 . 72 1 1 5 5 70 . 3 7 7 118 285 276.25 0 . 1 074
R32 2 . 5 75043 - 0 . 0 3 5 320 3 5 8 . 978 1 1 7 .8077 2372.017 137 287 279 . 3 5 0 . 1 789
R12 2.886860 - 0 . 0002 1 6 380 . 3 60 5 3 . 1 287 2 5 5 3 .078 183 373 253.15 0 . 3056
R22 2 . 506270 0 . 00 1 628 369 . 1 99 5 5 .9 6 3 5 2948 .260 178 363 27 3 . 1 5 0 . 1 99 1
R 1 3 4a 2 . 589 1 29 0.0000 3 3 374.968 1 2 7 .0868 2718.736 173 373 243 . 1 5 0.405 1
R125 2 . 9 1 3 370 0 . 2 1 1906 3895 . 0 1 2 - 209 . 8 7 3 9 3 . 090 216 298 293 . 1 3 0 . 1 581
Vapor vi scos ity corre l ations fo r selected co m po u n d s at low �

7J i d
Equation : -- =
ATB
Pa s 1 + CT- l + D T-2

Substance 1 06 A B c D Range of Verification

validation point
Tmin (K) Tmax (K) T (K) llid (JL Pa s)

Water 0.501 246 0. 709247 869.465599 - 90063 .891 278 1173 353.15 1 1 . 7 342
Ammonia 1 . 1 1 3854 0.573628 695 . 1 64458 - 39937.499 196 1 000 280. 1 5 9.4972
Hydrogen chloride 2 . 001 380 0 . 4948 1 4 414.835 270 -853 8.403 200 1 000 284.25 1 3 .9219
Chlorine 0 . 1 64926 0.801 668 42.635 734 3 2 2 3 . 277 200 1 000 2 73 . 1 5 1 2 . 3467
Nitrogen 0.847662 0 . 5 74033 75.437536 56.771 73 1 7 73 313.15 1 8 .4896
Oxygen 1 . 1 02259 0.563255 96.450180 -3.515 54 1 500 358.65 2 3 .8665

""
Hydrogen 0. 1 69 1 04 0. 692485 - 7 . 6 34394 467 . 1 20 78 3000 328.25 9 . 5 254
)>.
""
"'
Sulfur dioxide 4.465290 0.379352 600 . 546520 -469.440 198 1 000 493 . 2 5 2 1 . 1826

"'-
::s
Carbon monoxide 0 . 734306 0 . 5 88574 5 2 . 3 1 8660 1018.822 68 1 47 3 3 79 . 1 5 2 1 . 1 283
Carbon dioxide 4 . 7 1 9875 0 . 3 73279 5 1 2 .686300 - 6 1 1 9 .961 223 1473 233. 1 5 1 1 . 7023 ;:; ·
M ethane 1 . 1 1 9 1 78 0.49 3 2 3 4 2 1 4 . 627200 - 39 5 2 . 087 93 1 000 233.15 8. 9 1 3 1 )>.

�
Ethane 0 . 6 1 2 1 79 0 . 5 67691 1 99 . 802 1 3 9 799.607 1 03 973 233.15 7.2233 ;,?
bl
3
Propane 0 . 1 73 966 0 . 734798 1 4 3 . 207060 - 7 1 47.859 85 1 000 313.15 8.5718

""
n-Butane 0 . 075828 0.837082 67 . 6 1 8677 - 2 14 1 . 762 143 963 313.15 7 . 7972
c

n- P en tan e "'
::s
l sobutane 0 . 1 2 1 656 0. 767652 92 . 1 47580 -2356.256 131 1 000 284.25 7.1853
�
0.208 1 09 0.692504 209. 3 5 5 3 1 0 -9032.643 153 1 1 73 323 . 1 5 7 . 2872
�
<3
n-Hexane 0.8296 1 7 0 . 5 24075 548 . 5 3 7420 - 1 9506. 1 00 183 1 22 3 28 3 . 1 5 5 . 9364

3
Cyclohexane 1 . 707204 0 . 444162 797. 904850 - 5 5 646. 900 280 900 377.65 8. 7486

�
n-H eptane 0.893462 0 . 5 23 746 800 . 5 5 4090 - 500 1 4 . 7 5 0 213 973
�
303 . 1 5 5 . 75 3 8

-
n-Octane 0. 647995 0 . 5 5 8004 678.981 600 - 3 5 3 97 . 490 223 1 273 30 3 . 1 5 5 . 5056

....
...
(continued overleaf) ...
 "'
...
..
-

..,
)>
..,
(continued) .
"'
"-
3
Range of Verification
;;: ·
Substance 1 06 A B c D
)>
"
validation point
'lid (JL Pa s) "
;;;
Tm in (K) Tmax (K) T ( K)
()
0
�
..,
0
"'
Ethylene 1 . 503552 0.456140 288. 342422 73. 362 170 1000 300.55 10.3537
3

�
Propylene 0.921 458 0. 5 1 4534 301 .722 140 - 1 79.984 88 1 000 375.95 10.81 1 5
"
1 - Butene 1 . 5 90010 0.43 5591 427.677300 1432.659 1 75 1000 348.65 9.0969
0
i3
�
M ethanol 0.47791 5 0.641076 284.838034 - 3 2 30.7 1 3 240 1000 400.05 13 . 1 568

�
"'
Ethanol 0.106484 0.806176 5 3 . 1 33947 - 1 9.624 200 1000 284.25 8.5323

n- B u ta n ol
0.446996 622. 575600 1735.926 200 1000 284.25 7 . 1 686
�
n-Propanol 1 . 842 372
1.261930 0.4739 1 9 5 1 0.297350 - 1 43.068 185 1000 3 1 3 . 25 7 . 3 169
Ethylene glycol 0 . 1 49939 0.770025 161 .702296 -7162 . 270 260 1 000 376.95 10.4782
I sopropanol 0. 1 97482 0.724489 176.81 1793 1 3 .775 1 85 1000 3 1 3 .95 8 . 1 363
Acetic acid 2 . 1 81432 0.479850 1 1 26.897790 -76689.777 290 800 343 . 5 5 9.90 1 1
Methyl acetate 2 . 5 1 5403 0.453254 12 31.787070 -82656.705 250 800 336.85 8.9530
Ethyl acetate 1 . 845324 0.424328 522.471640 -23 16.919 1 90 1 000 360.25 9.2229
Vinyl acetate 1 .698675 0.447738 583.23 3050 - 17183.346 1 80 1 000 352.95 9. 3404
Methyl-tert-butyl ether 0.168450 0.724727 1 19. 588355 - 5 38. 542 165 1 000 340.45 8 . 5 561
Acetone 0.060442 0.894053 1 37. 302579 - 10508.844 178 1 000 308. 1 5 7.6028
Benzene 3 3 . 944850 0. 179320 3840.605800 - 1 1 4442 .650 279 1 000 353 8. 8669
Toluene 26. 356700 0.089851 1 41 1 .952400 4923 5 . 071 1 78 1 000 351.15 8.2336
p-Xylene 1 .2971 41 0.436899 446. 549129 - 1 248.050 286 1000 3 2 3 . 95 6.8501
R23 0.588485 0. 620799 76. 1 03710 1 0940.869 191 1 000 3 1 8.75 1 5 .6563
R32 2 . 505 242 0.445997 489.840880 - 1 0877.245 1 73 513 303 . 1 5 1 2.8280
R12 2.043 170 0.483 200 63 3 . 356640 -4945 5 . 2 39 250 575 284.25 1 1 .975 1
R22 2.496580 0.445 339 480. 1 72300 - 10278.585 173 513 293 . 1 5 12.4428
Rl 34a 2 . 5 3 5768 0.434922 5 1 9 . 1 95800 - 1 1741 . 298 173 493 293.15 1 1 . 3870
R125 2 . 322973 0.450581 419.744700 -7324.273 173 45 3 293 . 1 5 1 2 . 8005
Liquid thermal con d u ctivity correlations for selected co mpot

).. L
Equations :
W/ (Km)
=
T
A(l + Br 1 1 3 + C r 2 1 3 + D r ) ' r = 1- -
Tc
(A. 3)

)._ L T ( TY (T Y (Tr
- + D (A. 4 )
K K K K
= A + B- + C - +E -
W/(Km)

Substance N u mber of A B c D E Range of validation Verification point

equation
-
l_L
Tmin Tma• T
(K) (K) ( K) (W/ (Km))

'1 . 949 2 1 5 . w - •
II
Water A.4 - 2 .41 488460 0.024 5 1 6 -7.31 2129 . w-1 - 5 . 37 3 0 1 9 · 10· 27 5 623 403 . 1 5 0 . 6843

-
Ammonia A.3 0 . 4 5 8 1 2600 - 3 .407603 7 . 363882 - 3 . 1 1 0926 203 383 30 3 . 1 5 0.4592

- "')>.
Hydrogen chloride A.3 0 . 1 2208099 5 . 589949 173 323 275.75 0. 2249
Chlorine A.3 0.08364446 - 2 . 244378 6 . 000759 - 1 . 768471 173 410 273. I S 0 . 1 478
N i trogen A.3 0.03723700 0.819379 1 . 5468 3 0 2 . 9 5 6 1 70 73 123 1 1 3. 1 5 0 . 0756 "'
"'::s
"'-
;;: ·
Oxygen A.3 0. 04849099 0.662250 - 0 . 1 5 7473 4 . 1 80248 73 148 1 33 . 1 5 0.09 1 2

)>.
Hydrogen A.3 0 . 3 1 2 5 7 1 02 - 4 . 480248 8.852520 - 5 .476372 14 31 22.05 0. 1 0 1 2

0:
t:
Sulfur dioxide A.3 0. 1 1 1 79000 0.049672 - 0 . 08 3 1 44 2.454405 19H 400 304. 1 5 0 . 1 920
"
Carbon monoxide A.3 0.04654000 0. 258036 -0.495 5 00 5 . 394290 68 125 83. 1 5 0 . 1 372

b'
�
-
Carbon dioxide A.3 0 . 1 1 094000 - 2 . 38 1 6 3 6 4 . 902 1 3 0 0. 1845 1 6 218 293 273 . 1 5 0 . 1 08 2
Methane A.3 0 . 09222700 - 1 .466680 2.951 520 1 . 069580 93 1 8R 143. 1 5 0 . 1 394
"'0
"'::s
Ethane A.3 0.03263560 5 .689980 - 1 1 . 845846 1 5 .965704 103 303 24 3 . 1 5 0. 1 1 4 2

- �
Propane A.3 0.0482 1 980 1 . 8 1 5 034 - 4 . 456460 7 . 1 38 1 20 85 360 290. 1 5 0.0976

-
n-Butane A.3 0.03328196 6 . 4 1 7034 - 1 4.997547 1 5 . 44 3 1 5 0 135 420 358. 1 5 0. 0840

J'
- <l
l sobutane A.3 0 . 0 1 668096 1 5 . 5 27922 - 3 6.06 1 7 2 1 3 5 . 162423 203 373 293. 1 5 0.09 3 1

�
�
-
n-Pentane A.3 0 . 0 1 128 5 1 5 2 6 . 8 1 7246 - 5 5 . 05 3 3 99 47. 844687 1 93 443 29 3 . 1 5 0 . 1 090
n- H exane A.3 0 . 045 5 1 5 3 4 3 . 9 4 1 700 178 370 3 09 . 3 5 0. 1 1 56
"'
<A

(continued overleajj
--
....
...
"'
 "'
...
"'
(continued) . --

)>.
A B c D E �
�
"'
"
Substance N u mber of Range of validation Verification point

"'-
i<"
equation

Tmin T�, T l.'

(K) (K) (K) (Wf(Km)) )>.
"
<:
�
()
0
�
Cyclohexane A.3 - 0 . 0 1 629480 - 36 . 9 3 3 160 7 3 .652630 - 5 2 . 004 1 30 280 354 287.45 0. 1 260

�
"
0
n-Heptane A.3 0.005546 1 3 3 0 . 5 28260 - 38 . 792760 4 5 . 698080 190 370 260 0 . 1 343

"'
�
n-Octane A.3 0.00609920 28. 1 37870 - 38.82 3 1 60 4 5 . 582000 216 399 273.95 0 . 1 354
Ethylene A.3 0.0055 3668 76.084404 - 1 5 3 . 166503 1 50.029799 Ill 270 2 30. 1 5 0.1239

- �
i3
Propylene A.3 0.00393223 8 3 . 5 3895 3 - 1 42.76 3856 128. 3 5 5 0 1 5 253 330 313.15 0.0944
88
- �
! -Butene

"'
A.3 0.0667 3 00 1 2 . 200248 267 248.05 0. 1 267

-
r;
Methanol A.3 0 . 1 3 9 5 1 266 1 .0 3 3 3 1 7 176 338 298 . 1 5 0. 2000

-
Ethanol A.3 0. 1 1 1 24054 1 . 2 1 7548 1 60 353 312.25
�
0 . 1 644

-
n-Propanol A.3 0 . 1 0464898 1 . 1 049 1 3 20 1 535 372. 1 5 0 . 1 40 1
n-Butanol A.3 0 . 09905 1 70 1 . 1 5 6703 185 553 303.95 0.1518

- 1 86
Ethylene glycol A.3 0 . 00 1 3 5 1 74 - 1 1 70. 50402 3868 .88659 - 2 6 3 2 . 07239 260 593 326. 5 5 0.2592

-
I sopropanol A.3 0.065 9 1 520 5 . 1041 1 6 - 1 2 . 1 20860 9 . 6 34 1 9 0 507 403 . 1 5 0. 1 1 68

-
Acetic acid A.3 0. 1 0546986 1 . 028583 292 573 300.45 0 . 1 589
Methyl acetate A.3 0.06649329 3 . 1 7 5936 176 493 186 . 2 5 0. 1 58 3
Ethyl acetate
1 81
A.3 0 . 00008 141 44 1 4 . 597964 - 7291 . 8 3987 6016. 90670 1 90 493 281 . 5 5 0. 1 4 9 1

-
Vinyl acetate A.3 0.072 3 2 3 3 3 2.541833 513 313.35 0 . 1 45 1
Methyl-tert-butyl A.3 0.036205 3 0 2 . 747481 - 3 .446100 5 . 9 3 9223 165 328 311.15 0.1235

- -
ether
Acetone A.3 0. 07089878 3 . 058789 1 79 343 299.85 0 . 1 598
Benzene A.3 0 . 06389367 2.610350 279 413 363.55 0. 1 2 28
Toluene A.3 - 0 . 0 1 200600 - 3 2 .702200 5 5 .625500 - 4 2 . 1 1 1000 1 78 475 287.45 0 . 1 3 39

-
p-Xylene A.3 0. 065 3 1 592 2 . 1 09022 -6.476927 6. 7046 1 9 287 413 3 3 3.05 0 . 1 209

-
R13 A. 3 0 . 066268 34 2.521 323 118 243 216.75 0. 1 1 2 5
R32 A.3 0.099 1 1 900 0.0764 1 7 3 . 7 1 2613 - 1 .4608 3 1 163 348 263. 1 5 0 . 2 1 39

-
R12 A.3 0.03202120 0.066322 - 0. 1 1 7768 5 . 3 20465 ! 50 363 273.45 0 . 08 1 2
R22 A.3 0.06064400 - 1 .049875 2. 1 1 5769 1 . 0768 5 7 163 363 26 3 . 1 5 0.0933
R 1 34a A.3 0.07364600 - 1 . 7 56262 2.633737 1 . 096548 1 73 373 293 . 1 5 0 . 0834
R l 25 A.3 0.06652 500 - 2 . 3 16396 5 . 0 1 69 1 0 - 1 .260304 173 333 298 . 1 5 0. 0622

The required critical temperature T.: is given in the Table "General data for
Vapor thermal conductivity correlations for selected com p o u n

. A id .jT,.
= ---;;--
- ,.--;::-
+ 12..
EquatiOn :
W/ ( Km ) A + .§..
Tr + .£
Tl Tl

Substance A B C D Range of Verification

validation point
Tmin (K) Tmax (K) T (K) A_id (W/(Km))

Water 2 . 000796 1 4 . 1 69449 5 . 237322 - 2 . 0 1 3030 278 1073 353. 15 0.0223

Ammonia 1 7 7 1 596 2 5 .648577 - 2 .263 1 80 1 . 1 20586 203 1000 279. 7 5 0.0221
Hydrogen chloride 2 1 . 1 2 7674 5 9 . 5608 1 5 - 2 1 349900 3 . 6 1 1 350 159 1 000 291.75 0 . 0 1 44
Chlorine 3 5 . 1 64546 3 7 . 2 5 46 1 0 6 .665 306 - 1 .775010 200 1 000 373 . 1 5 0.01 1 4
N itrogen 3 0. 5 1 6440 1 00 . 7 6 1 278 -84.097324 3 5 . 70 5 2 2 1 93 1223 323 . 1 5 0 . 0270
Oxygen 2 5 . 097426 69. 2 5 1 077 - 3 5 . 326230 1 0 . 740 1 8 3 80 1 495 284.4 0 . 02 5 1
Hydrogen 9 . 3 5 5729 86.604301 - 1 6 3 . 42 1 0 1 2 8 1 . 498903 22 1 600 27 1 . 1 5 0. 1619
Sulfur dioxide 27.058610 - 3 . 3 1 5050 54. 097200 - 1 5 . 764240 250 900 386.85 0.0138 �
Carbon monoxide 3 2 . 987680 7 3 . 9 1 9420 - 2 8 . 849020 4. 398 1 2 0 70 1 5 00 97 3 . 1 5 0.0636 ]
Carbon dioxide 1 8 .890387 1 1 .895399 40.89 7 1 8 3 - 1 3 . 035 620 223 973 373 . 1 5 0 . 0227 ff
Methane 0. 826598 7 1 . 3741 30 - 29 . 034600 6 . 1 07060 93 1 000 27 3 . 1 5 0.0310 )>

Ethane 3.233358 1 9 . 029493 27.805380 - 4 . 7 1 7205 113 1000 31 3.35 0.0231 ;p

Propane 1.35 1410 1 9 . 983850 20.026000 - 3 . 5 5 3 930 203 1 000 352.55 0.0243
�
n-Butane 3 . 2 1 5 5 04 1 0 . 07 3 6 3 3 2 1 .826 3 1 2 - 3 . 6 2 1 102 203 1000 387.45 0.0267
3
]
�
lsobutane 9.038150 - 1 . 39 5 5 2 0 3 2 . 309630 - 5 . 5 77840 203 1 000 2 73 . 1 5 0.0135

a
n-Pentane - 1 . 1 7 5 174 2 2 . 5 6061 0 1 0 . 1 2 5 880 - 1 . 6 5 3 540 273 1000 273. 1 5 0.0129
n-Hexane - 1 . 52 1446 2 1 . 5 20796 9.432466 - 1 . 141610 339 1 000 478 . 2 5 0.03 1 7
Cyclohexane - 1 .927981 1 6 . 082202 6.83 3899 2 . 2098 3 3 323 1 000 467 . 1 5 0.0302 !?
n-Heptane 0. 059077 1 5 .9 34620 1 1 .446140 - 1 . 1 20901 273 1 000 373.95 0 . 0 1 90 �
�
n-Octane - 1 . 585 376 1 8 . 8 5 7260 9 . 328904 - 1 . 062463 339 1 000 443 . 3 5 0 .0247 �

(continued overleaj}
�
 "'
...
..
--

)>
.,
(contin1-1ed) .
.,
"
"
Range of Verification <L.
i< '
Substance A B c D
)>
l.id (W/(Km))
validation point
"tl
Tmin (K) Tmax ( K) T (K) s::
�
(;\
3
.,
0
Ethylene 0.284146 3 3 . 66 1 0 5 0 29. 2 3 5 2 1 7 - 10 . 5 1 085 1 1 69 900 323.25 0 . 0238
1000 "
"
�
Propylene 3 . 226603 20. 1 93072 1 9 . 1 4 3 5 30 - 2 . 027584 225 306.95 0.0180
1 - B utene - 1 . 734943 2 8 . 5 08830 1 0 . 986 1 20 - 1 . 5 3 6220 225 800 376. 3 5 0.0228

;,p
tl
M ethanol 1 000 324.38 0.0179

3
- 2 . 097847 1 7 . 979169 1 2 . 828005 - 3 . 546304 273

�
Ethanol - 2 . 2 5 9996 2 1 .881454 5 .488168 - 0 . 304888 293 1 000 293 . 1 5 0.0147

"
n-Propanol - 1 . 6 58 3 5 1 1 9 . 595786 6 .903 1 38 - 0 . 7 5 5881 372 720 372 . 1 5 0.02 1 5
n-Butanol - 2 2 . 982020 69 . 1 28385 - 2 8 . 209030 5.678522 370 800 573.65 0.0438 Vl
Ethylene glycol - 2 . 98 6 5 3 5 1 8. 296988 3 . 5 89649 - 0 . 3 2 1 265 470 1 000 470.45 0.02 5 1
I s opropanol 0 .670345 9.782420 20.438520 - 5 .081 3 3 0 304 1 000 473 . 1 5 0.0339
Acetic acid 0 . 704 1 4 3 7 . 249838 22.437444 - 4 . 7 5 1 947 295 687 294 . 7 5 0 . 0 1 05
Methyl acetate - 3 . 5 26070 2 4 . 686506 1 1 . 8 1 4704 - 1 . 4 5 0865 273 1000 3 30.05 0 . 0 1 42
Ethyl acetate - 1 . 48 1 7 1 0 1 5 . 774236 2 4 . 3 2 2 5 00 - 5 . 59 7 1 74 273 1000 3 1 1 . 45 0.01 1 5
Vinyl acetate - 2 . 302838 1 8 . 466591 1 6 . 708090 - 2 . 78 5 1 9 5 346 1000 345 . 6 5 0.01 5 2
Methyl-tert-butyl ether 5 . 1 2 1987 1 7 . 7745 1 4 6 . 2 1 3344 0. 976908 273 1 000 349 . 5 5 0.0183
Acetone - 1 . 729843 20. 390480 1 5 . 370780 - 1 .97 1064 293 1 000 364.75 0 . 0 1 66
Benzene 1 . 0 1 4925 1 7 . 7 8 1 470 9.661990 - 0 .4090 1 6 339 1 000 478 . 2 5 0.0267
Toluene 0.631015 1 7 . 1 86500 6 . 1 39255 0 . 1 7 7 1 87 384 1 000 383 . 7 5 0 . 0 1 90
p-Xylene - 1 .261201 3 6 . 2 0 1 340 - 2 6 . 4 3 1 40 1 14.075927 320 1 000 39 1 . 5 5 0.0177
R23 2 1 . 1 79034 1 5 .9 1 5 7 5 8 49 . 0 1 6 1 1 2 - 1 3 . 3 36 3 7 1 191 1000 3 18 . 7 5 0.01 5 1
R32 - 7 . 0 18654 7 7 . 642855 - 5 . 0848 6 1 - 1 . 5 50638 1 63 473 28 3 . 1 5 0.01 14
R12 1 . 049970 67 . 1 65 700 3 . 1 5 7079 -0.843364 243 700 363 . 5 5 0.0130
R22 3 . 086424 39.018330 32.276130 -8.032932 173 473 313.15 0.01 14
R1 3 4a - 1 . 3466 3 1 67.782530 - 34 . 25 1 5 30 1 9 . 287077 193 1 000 313.15 0 . 0 1 44
R125 1 5 .887050 - 7 . 776550 75 .408970 - 2 5 .482380 225 1 000 333.15 0.0166

The required critical temperature T, is given in the Table " G eneral data for selected compounds . "
S u rface te nsion correlations for selected compou nds.

Equation :
N;m = A(l - Tr) B+CT, + DT� +ETl

Substance A B c D E Range of Verification

validation point
Tmin ( K) Tmu ( K) T (K ) a (m Nfm)

Water 0 . 1 5 8990 1 .800 1 3 2 - 1 . 1 78740 - 0 . 4 10700 0. 964067 273 608 292 . 8 5 7 3 . 8843
Ammonia 0 . 1 03 2 5 8 1 . 320142 - 0 . 300843 0 . 3 50729 - 0 . 1 5 4 1 49 1 96 395 239.65 34. 2903

Hydrogen chlorid� 0.085 1 66 1 . 296700 - 159 316 246 . 1 5 1 3 . 5 1 42

Chlorine 0. 069660 1 . 2907 1 1 - 0 . 5 9 5 300 0.689530 - 0 . 297926 173 404 273.15 2 1 . 3050
Nitrogen 0 . 0295 1 2 1 . 278290 0.044647 - 0. 1 5 7 9 3 3 0. 089708 63 123 1 1 2.95 1 . 7387
Oxygen 0.0 37848 1 . 200264 - 0 . 0 1 9 308 0 .080429 - 0 . 050479 54 1 49 73.15 1 7 . 4984
Hydrogen 0.005 6 3 1 1 . 201 1 8 7 0.024380 -0.439855 0. 3036 1 0 14 32 1 8 .05 2 . 3 1 36

""'
Sulfur dioxide -0.475261 - 0 . 258743 198 406 295.85 2 2 . 1 365
-6'
0.088735 1 . 329490 0. 585 308

"'
"
Carbon monoxide 0. 040422 2 . 7 1 6037 - 3 . 1 85805 2 . 5 37085 -0.839567 68 123 85 . 1 5 8. 7400

;:;:·
.,_
Carbon dioxide 0 . 08 1 5 6 3 1 . 5 27091 - 0 . 8 36249 0.924520 - 0 . 348 1 9 5 216 299 239.65 1 1 . 3432

)>
"
Methane 0.033795 0 . 8 37809 0 . 5 24994 -0.287428 0.048288 91 185 153.75 5 . 5421

1:::
�
Ethane 0 . 048339 1 . 18 1 1 7 2 - 0 . 0 1 2966 0.082275 - 0 . 0 5 5848 90 294 282.65 2 . 1 598

Propane 0.050936 1 . 225863 - 0 . 03 1 5 5 1 0.052927 - 0 . 0277 1 3 85 355 280.05 9.0520

(;'
3
»·Butane 0.05 1 62 5 1 . 2 1 4678 - 0.063855 0. 1205 1 1 - 0.05 3450 1 35 355 273.30 14.8635

""'
Isobutane 0.05843 1 2 . 186481 - 2 . 69 1 774 3 . 097050 - 1 . 32 3847 1 14 377 283 .95 1 1 .4621

"
0
"'
n-Pentane 0.05 2049 1 . 208440 - 0 . 0 1 48 7 1 0 . 0 1 9269 -0.00894 1 143 435 280.85 1 7 . 3662

�
n-Hexane 0.054 5 2 1 1 . 260288 175 456 299 . 3 5 1 7 . 7 507
- -
cl'
"
Cyclohexane 0.065637 1 . 266746 273 524 332. 1 5 20.5630
- -
3
"'
n-Heptane 0.054835 1 . 269376 183 521 314.35 1 8 . 1866
-
�
n-Octane 0.05 3060 1 . 241 3 5 7 216 532 290 . 5 5 2 1 . 8806

<;:
--
(continued overleajj "'
""
"'