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2. A hot air balloon is being inflated to its full extent by heating the air inside it. In
the final stages of this process, the volume of the balloon changes from 3.5 x 106
L to 4.50 x 106 L by the addition of 13 MJ of energy as heat. Assuming that the
balloon expands against a constant pressure of 1.2 atm, calculate E for the
process. To convert between L atm and J, use 1 L atm = 101.3 J.
a. How much heat is evolved when 2.5 mol sulfur is burned in excess O2?
4. Answer the following questions on thermochemistry:
CH3OH(l) -730
a. In the empty box in the table above, write a balanced equation for the
complete combustion of one mole of CH3OH(l). Assume products are in their
standard states at 298 K. Coefficients do not need to be whole numbers.
b. On the basis of your answer to part “a” and the other information in the table,
determine the enthalpy change for the reaction
C(s) + 2 H2(g) + ½ O2 (g) CH3OH(l) .
c. Assume that the specific heat capacity of the calorimeter is negligible and that the
specific heat capacity of the solution of urea and water is 4.2 J/ g oC throughout
the experiment.
i. Calculate the heat of dissolution for the solution made of urea AND
water in joules.
ii. Calculate the molar enthalpy of solution, Hosoln, of urea in kJ/ mo1
urea.
6. Reactions: Please write the unbalanced net ionic equation for each of the following: