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To cite this article: Anthony J. Crawford , W. E. Cameron & Reid R. Keays (1984) The association
boninite low‐ti andesite‐tholeiite in the heathcote greenstone belt, Victoria; ensimatic
setting for the early lachlan fold belt, Australian Journal of Earth Sciences, 31:2, 161-175, DOI:
10.1080/08120098408729290
Article views: 90
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Australian Journal of Earth Sciences (1984) 31, 161-175
The Heathcote Greenstone Belt is composed mainly of Lower Cambrian metavolcanic rocks and is
one of three outcropping belts of the apparent basement to the Lachlan Fold Belt in SE Australia.
The greenstones may be assigned to two broad magma series. A younger tholeiitic series with
mid-ocean ridge basalt (MORB) affinities has intruded through, and been erupted upon low-Ti,
intermediate SiO2 lavas. The latter were originally boninites (both clinoenstatite-phyric and more
fractionated orthopyroxene-phyric varieties) and plagioclase-phyric, low-Ti andesites. They have
partially re-equilibrated to the lower greenschist facies and outcrop mainly in the central segment
of the Heathcote Greenstone Belt, where deeper stratigraphic levels are exposed. Tholeiitic lavas
and sills metamorphosed to the prehnite-pumpellyite facies dominate the northern and southern
segments. As the association boninite/low-Ti lavas/MORB is known only from modern West
Pacific-type settings involving island arcs and backarc basins, the early history of the Lachlan
Fold Belt is inferred to have taken place in a similar setting.
Key words: Lachlan Fold Belt, Cambrian greenstones, boninite, low-Ti andesite, tholeiite,
Heathcote Greenstone Belt
161
162 A. J. CRAWFORD ET AL
9^ Cambrian Greenstones
\ \
1 — — — Inferred trends
l! ^ \^>
^y
v
* " ' w . v " "^ ~ Limit of Palaeozoic Outcrop
\ NEW SOUTH
\
MOL0N0 ,
\
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Fig. 1 The distribution of Cambrian greenstones in the Lachlan Fold Belt of SE Australia.
I CornellaEast
10 km
45-h
H 45'
46'
46'
48'
48'
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50'
50'
511
52' 52'
53' 53'
54'h
54'
-L™,
55' j -
55'
561 56'
57'h 57'
Fig. 2 Geological map of the central segment of the Heathcote Greenstone Belt. Sample numbers correspond to last two digits of
University of Melbourne Geology Dept sample numbers, which are listed for each sample in Table 2.
BONINITE ASSOCIATION, HEATHCOTE, VICTORIA 163
Ordovician to Mid-Devonian Melbourne Trough to succession in both segments has been tilted to a
the E (Fig. 1). Based on petrological affinities, the steep westerly dip. Large-scale folding of sedimen-
Heathcote Greenstone Belt is divisible into three tary bands is absent along strike, but small drag
segments: the southern segment (S of the Cobaw folds and oblique transcurrent faults, with offsets
batholith) and the northern segment (N of Mount generally less than 50 m, are present at a number
Camel) are dominated by tholeiitic metabasalts and of locations. Cleavage is uncommon in the
metadolerites with MORB affinities (Crawford & greenstone belt.
Keays 1978), whereas the central segment, map- The stratigraphy within the greenstones is rela-
ped by D. E. Thomas in 1940 and 1941, shows far tively simple. The oldest unit, dominated by
greater petrological diversity and structural com- boninitic rocks, is limited in outcrop to the eastern
plexity. It became apparent after extensive exami- slopes of the Mount Camel Range, from Cornelia
nation of thin sections (including Thomas' original East at the southern end of the northern segment to
thin sections housed at the Victorian Mines De-
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pelagic sediments resemble dark shales and, where 1 :31680 maps as a base, we remapped and
baked by the Cobaw batholith, have hornfelsic resampled much of the central segment, and a new
textures and contain abundant spessartine, suggest- interpretation is presented in Fig. 2.
ing derivation from a manganiferous sediment The stratigraphy mapped in the Cornelia East
(Bradfield 1978). In drillcore from Mount Camel, area of the northern segment, namely tholeiites
pelagic sediments within the greenstones are pyri- separated from underlying boninites by a shale
tic black shales, rarely thicker than 3 m. band, continues into the northern end of the central
Except for the contact metamorphic aureoles segment, to just S of the Crosbie Granite (Fig. 2).
around the Crosbie and Cobaw granitic intrusions, Further S, both the stratigraphy and its interpreta-
the metamorphic grade throughout the greenstone tion are considerably complicated by extensive
pile in both the southern and northern segments is faulting, the occurrence of a third lava suite
prehnite-pumpellyite to lower greenschist facies. (mainly andesites), and very poor outcrop.
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Limited occurrences of amphibolites adjacent to The tholeiitic series in the central segment is
the boundary faults may have been excavated from largely represented by fine-grained amphibolites in
depth during movements along the faults. The the aureole of the Crosbie Granite; these terminate
Upper Devonian Cobaw Batholith has produced a abruptly against shales along the western margin of
thermal aureole to a distance of at least 500 m greenstone outcrop, at a contact thought by us to
from the contact, in which basaltic and, doleritic be a fault (see below). A band of black cherty
rocks have recrystallized to fine- to medium- shale separates the amphibolitized tholeiites from
grained amphibolite. underlying boninites.
Conformably overlying the greenstones in both Boninites occur in two outcrop areas. The more
segments is a sequence of marine sediments northerly is a continuation of the boninites which
around 250 m thick, including a basal unit of outcrop along the eastern flank of the Mount
graded lithic sandstones, overlain by black shales Camel Ridge, and these extend about 3 km S of
containing a rich Middle Cambrian hydroid band the Crosbie Granite, where they terminate abruptly
approximately 65 m from the top (Chapman & at a NE-striking fault. In this northern outcrop
Thomas 1938). These sediments are the lateral area, boninites are generally altered by extensive
equivalents of the fossiliferous Knowsley East shearing, quartz veining and thermal and hyd-
Formation of the central segment of the Heathcote rothermal effects of the adjacent granite. Schistose
Greenstone Belt (Thomas & Singleton 1956). The amphibolites and serpentinites derived mainly
Knowsley East Formation equivalents are overlain from boninitic precursors are common, and small
conformably by 500-1000 m of thinly-bedded, dykes, sills and pods of amphibolitized tholeiitic
bleached shales, the Goldie Shales. These are dolerite and ferrodiorite intrude the boninites here,
always unfossiliferous and commonly silicified in as at Cornelia East.
outcrop; however, by virtue of their position The southern area of boninite outcrop is a
stratigraphically between the underlying Middle fault-bounded block 5 km long by 1.5 km
Cambrian Knowsley East Formation and the con- (maximum width), at the base of the western
formably overlying, graptolite-bearing earliest Or- slopes of Mount Ida. The lavas vary from vesicular
dovician shales and slates of the eastern Ballarat to massive, are generally porphyritic, and show
Trough, the Goldie Shales are considered by us to excellent textural preservation. Pillows 0.5-1 m
be of Upper Cambrian age. across outcrop in She-Oak Gully, in a section in
which sedimentary interbeds are rare. Most boni-
nites are deep blue-green or brown on fresh
surfaces, with black phenocrysts 1-2 mm long in a
GEOLOGY OF THE CENTRAL SEGMENT
structureless, almost glassy matrix. Occasional
This segment of the Heathcote Greenstone Belt lies small outcrops of slightly coarser-grained, almost
between the Cobaw Batholith in the S and Mount doleritic-textured boninites are interpreted by us as
Camel in the N (Fig. 1). Though Thomas' (1940) narrow dykes intruding the lava pile.
outcrop mapping and geological boundaries appear Andesites, with interbedded volcanogenic sedi-
generally to be very accurate, he did not attempt to ments, also outcrop in two areas. The largest and
subdivide the greenstones petrographically, refer- best exposed of these extends several kilometres N
ring to all igneous rocks present in the area as and S of Lady's Pass (Fig. 2). Flows are usually
dolerite or diabase. Using Thomas' (1940) less than 10 m thick and are occasionally separated
BONINITE ASSOCIATION, HEATHCOTE, VICTORIA 165
by units of volcanogenic sandstones composed this area is a massive quartz reef, some 400 m
largely of andesitic detritus. Early Cambrian fos- long, trending parallel to the direction of shearing
sils have been found in these sediments (P. Jell, (Fig. 2). It is likely that the major eastern
pers. comm. 1980). In the vicinity of Lady's Pass, boundary fault of the greenstones between Mount
one sedimentary section at least 50 m thick is Camel and Lady's Pass is not a single fault, but a
composed of 10-30 cm thick, commonly graded scries of steeply-dipping, subparallel shears.
beds. Crook and Powell (1976) considered these to Good evidence is present in the central segment
be of shallow-water origin, on the basis of for the existence of several major cross-strike
medium-scale cross lamination and rare scour and faults. The most significant of these, not recog-
fill structures. Throughout this area, sedimentary nised by Thomas (1940), strikes NE between
interbeds strike around 060° and dip towards the Lady's Pass and the Crosbie Granite. It is respon-
NW, usually at steep angles. The across-strike sible for the abrupt termination of the boninites
thickness of the andesite-volcanogenic sediment
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166
A. J. CRAWFORD ET AL
BONINITE ASSOCIATION, HEATHCOTE, VICTORIA 167
Fig. 3a Unaltered boninite showing larger, skeletal crystals of orthopyroxene (cruciform projections, right of
photograph) and orthopyroxene-pigeonite-augite (centre). Acicular microlites are pigeonite-augite, set in unaltered
glass. Specimen 106, Chichijima, Bonin Islands; Anal., Table 2. Plane-polarized light (PPL). Width of field 1.6 mm.
Fig. 3b Metaboninite with chlorite pseudomorphs after skeletal orthopyroxene (centre) and equant orthopyroxene (lower
left) enclosing chromite. The groundmass consists of relict augite (lower right), actinolite after augite, and albite after
glass. Specimen 26270, PPL. Width of field 1.6 mm. Fig. 3c Metaboninite with chlorite pseudomorphs after what is
interpreted to be clinoenstatite. Groundmass consists of acicular grains of actinolite, with chlorite cores after augite with
low-Ca pyroxene cores. Specimen 26268, crossed polars. Width of field 1.2 mm. Fig. 3d Metaboninite with random
spinifex texture. Actinolite has replaced augite blades, clear matrix is albite, after glass. Specimen 26277, PPL. Width
of field 1.6 mm. Fig. 3e Metaboninite. Orthopyroxene microphenocrysts are replaced by chlorite but augite rims are
relict. Similar morphology may be seen in groundmass grains. The matrix is albite with minor quartz. Specimen 26275,
PPL: Width of field 1.6 mm. Fig. 3f More slowly-cooled metaboninite probably from interior of a dyke or sill.
Orthopyroxene phenocrysts pseudomorphed by chlorite, in an intrafasciculate-textured groundmass composed of
intergrown sheaves of albitized plagioclase and actinolite after calcic pyroxene. Specimen 26282, crossed polars. Width
of field 7 mm. Fig, 3g Originally a two-pyroxene + plagioclase-phyric andesite; augite phenocryst (upper right) is
preserved, while orthopyroxene phenocrysts (below augite) are faithfully pseudomorphed by chlorite. A tabular
plagioclase phenocryst (upper left) has been almost entirely replaced by sericite. Specimen 26263, PPL. Width of field
7 mm. Fig. 3h Typical tholeiitic metabasalt from the Heathcote Greenstone Belt. Fresh augite and albitized plagioclase
define a sub-ophitic to intergranular texture. Fe-Ti oxides are conspicuous compared with other Heathcote lavas.
Specimen 27146, PPL. Width of field 1.0 mm.
168 A. J. CRAWFORD ET Ah
rocks. The pseudomorphs are commonly rimmed The most fractionated Heathcote boninitic lavas
by fresh augite, and since they show no sign of (6-7% MgO, e.g. sample 26278) are almost
resorption or replacement by serpentine minerals, holycrystalline, though notably finer-grained than
were almost certainly orthopyroxene. Confirmation the feeder dykes. These are almost aphyric and
of this comes from observations of the morphology have sparse, chloritized microphenocrysts of or-
of skeletal orthopyroxene in modern boninites; thopyroxene in a groundmass containing elongate
tiny, cruciform projections which grow inwards in (uralitized) calcic pyroxene and nearly acicular
an equant, skeletal microphenocryst (now chlorite, albitized plagioclase laths which define a seriate
Fig. 3b) in a Heathcote boninite have identical intersertal texture.
counterparts in the Bonin rock (Fig. 3a). In
contrast, skeletal olivine has lantern, chain and
blade forms (Donaldson 1976). Andesites
Heathcote boninite 26268 contains chlorite
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pseudomorphs that do not extinguish uniformly Andesites occur only in the central segment of the
under crossed polars, in contrast with those in all Heathcote Greenstone Belt, and are easily recog-
other Heathcote boninites. In these pseudomorphs, nized in the field by their abundance of plagioclase
narrow parallel planes with inclined extinction phenocrysts and their yellow weathering rind.
(Fig. 3c) suggest the former presence of clinoens- They are always non-vesicular, and may be
tatite. Significantly, Sample 26268 is the most divided into two petrographic groups: dark-
magnesian Heathcote boninite sample of the 20 coloured pyroxene + plagioclase-phyric andesites
analysed. and lighter-coloured hornblende + plagioclase-
The formerly glassy groundmass of Heathcote phyric varieties. The former probably constitute
boninites is charged to varying extents with fresh more than 95% of the outcropping andesites.
or pseudomorphed pyroxene microphenocrysts and The pyroxene + plagioclase-phyric andesites are
microlites which have variable growth habits, even usually prophyritic (up to 30 modal %), with
within a single thin section, due to different plagioclase typically as abundant as, or more
cooling rates. Elongate, skeletal pyroxenes in abundant than pyroxene. In more evolved rocks,
26277 define a texture (Fig. 3d) closely resembling the modal abundance of plagioclase increases
the random spinifex texture present in some dramatically; one such sample contains sparse,
flowtops of komatiitic basalts (Arndt et al 1979). primary quartz phenocrysts. Plagioclase pheno-
In 26270, the groundmass is characterized by crysts are large (to 5 mm across) blocky euhedra,
abrupt changes from devitrified glass to fan now albitized. Ghost zoning and twinning is
spherulites of quenched pyroxene, which enclose commonly preserved. Smaller (up to 1.5 mm long)
and have crystallized around both phenocrysts and augite phenocrysts are present in all samples, but
microphenocrysts of pyroxene. The most common are usually pseudomorphed by pale-green actino-
habit of groundmass pyroxene is stubby to elon- lite. Relict augite is colourless and non-pleochroic,
gate, strongly-zoned, sometimes hollow euhedra and contains occasional inclusions of Fe-Ti oxides.
(Fig. 3e). Glass has invariably crystallized to In these samples bearing fresh augite, a second
mosaics of quartz and albite, containing patches of type of pseudomorph, more elongate than augite
chlorite and felted, locally stellate aggregates of and consisting of very pale green chlorite, repre-
green ferrostilpnomelane. In places, the latter has sents original orthopyroxene. Its morphology is not
oxidized to flaky aggregates of red-orange ferri- characteristic of olivine. All the pyroxene +
stilpnomelane. plagioclase-phyric andesites appear to have been
Several coarser-grained boninites (e.g. sample two-pyroxene varieties (e.g. sample 26260;
26282) have textures indicating that they were Fig. 3g).
once holocrystalline. These we interpret as feeder Hornblende + plagioclase-phyric andesites con-
dykes to overlying boninites, but field evidence is tain less than 5 modal % of small (<1 mm long)
lacking. Chloritized orthopyroxene phenocrysts hornblende euhedra with a foxy brown to pale
(up to 1.5 X 3 mm) lack quench overgrowths of brown pleochroic scheme, and 5-10 modal % of
calcic pyroxene so common in the lavas. The blocky euhedra of albitized plagioclase. A few
groundmass is composed of elongate sheaves of hornblende phenocrysts are pseudomorphed by
intergrown actinolite (after calcic pyroxene) and green, strongly pleochroic actinolite. In both
albitized plagioclase (Fig. 3f). petrographic groups, microlitic-textured
BONINITE ASSOCIATION, HEATHCOTE, VICTORIA 169
groundmass consists of aligned laths of albitized andesites to the S (Fig. 2). The outcrops show
plagioclase and acicular to granular uralitized marked textural heterogeneity, with hornblende
clinopyroxene. Originally glassy groundmass in a varying in habit from bladed crystals 2 cm long to
few samples has crystallized to granular albite- equidimensional grains only 2 mm across, set in a
quartz-chlorite mosaics. pale matrix of feldspar and quartz. Hornblende,
In the absence of any diagnostic field relation- pleochoric in shades of brown, constitutes 30-50%
ships, we have been able to identify only two of the rock and is partly replaced by chlorite.
pieces of evidence pertinent to determining the age Tabular plagioclase crystals (up to 5 mm long) are
of the Heathcote andesites relative to the boninites. almost entirely replaced by epidote-clinozoisite
The first is 2 x 1 cm inclusion of boninite (11% except for distinct albitic rims. Large, skeletal
MgO, 0.15% TiO2) in andesite 26258. The second grains of Fe-Ti oxide, which subsequently altered
concerns the compositions of some plagioclase- to leucoxene, have exsolved ilmenite along oc-
free rock fragments containing chromite in an tahedral planes. Interstitial areas originally were
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andesitic agglomerate from Box Knob, and frag- composed of minor alkali feldspar (now largely
mented chromite euhedra in tuffs from S of Lady's clay minerals) and myrmekite. Primary euhedral
Pass [e.g. sample 26287 = KE28 of Thomas' crystals of sphene are common, and were sepa-
(1940) map and Thomas et al (1976)]. These rated in an attempt to date the rock by fission-track
chromites are very similar to those in the boninites method, but were found to contain insufficient
(55-64% Cr2O3). Since the andesites contain only uranium.
Fe-Ti oxides, we suggest that these chromites are Two stocks of microgranodiorite occur in the
derived from an earlier, underlying boninite forma- vicinity of Heathcote township (Fig. 2). The
tion, and that the stratigraphic succession is interiors of the intrusions consist largely of sub-
boninite overlain by andesite. equal proportions (40-45 modal %) of quartz and
plagioclase. Quartz occurs as anhedral crystals
Tholeiites interstitial to larger, subhedral plagioclase, in
which unzoned cores have sharp boundaries
Basaltic and doleritic rocks with tholeiitic affinities
against wide, strongly-zoned rims. Zoning is
dominate the northern and southern segments of
normal, with cores as calcic as An5<>. Small
the Heathcote Greenstone Belt, and are subordi-
interstitial areas of brown, highly-altered alkali
nate to boninites and andesites in the central
feldspar (On 5) make up less than 10 modal % of
segment. Except in the thermal aureoles of the
the microgranodiorite. The sole mafic phase origi-
Cobaw and Crosbie granitic inclusions, the basalts
nally was biotite, now altered to strongly pleo-
display sub-ophitic to intergranular textures, in
chroic, deep green chlorite. Apatite is abundant. A
which augite is invariably fresh and plagioclase is
slightly finer-grained, porphyritic marginal phase
generally albitized, although fresh calcic plagioc-
contains about 20 modal % quartz and 30 modal %
lase is preserved in some thick flows and sills.
of saussuritized plagioclase phenocrysts set in a
Olivine appears to have been absent from these
fine-grained, equigranular groundmass of anhedral
mainly aphyric lavas, and phenocrysts, where
albite and spherulitic quartz. Elongate prisms of
present, are euhedral augite (<1 mm long) rarely
pleochroic, green-khaki hornblende constitute ap-
constituting more than 5 modal % of the rock.
proximately 5 modal % of the rock, and are
Microphenocrysts of plagioclase are rare, but
extensively replaced by chlorite and epidote. The
many basalts contain fairly abundant Fe-Ti oxide
extent of alteration of the mafic minerals in the
microphenocrysts and groundmass granules. The
diorite and microgranodiorite contrasts strongly
dolerites are also augite-plagioclase-Fe-Ti oxide
with their freshness in the Upper Devonian Cobaw
rocks with grainsize usually less than 2 mm.
and Crosbie granitoids. This is consistent with our
assumption that the diorite and microgranodiorite
Diorite and microgranodiorite form an integral part of the Heathcote Greenstone
Rocks of the diorite-granodiorite association, of Belt.
presumed Cambrian age, have intruded the ande-
sites of the central segment. The best outcrops of
METAMORPHISM
hornblende diorite occur on the bank of Mclvor
Creek, close to the fault that separates the boni- Tholeiitic lavas of the Heathcote Greenstone Belt
nites around She-Oak Gully from the larger area of lack penetrative deformation. Except within the
170 A. J. CRAWFORD ET AL
thermal aureoles of the Cobaw and Crosbie green actinolites with 0.6-0.7% Na2O (Table 1)
Batholiths, they display prehnite—pumpellyite typical of most Heathcote metaboninites. The
facies metamorphic assemblages. Plagioclase laths sodic amphibole in the She-Oak Gully metaboni-
are replaced by albite or tiny stout rods of strongly nite is compositionally similar to amphiboles
pleochroic, Fe-rich pumpellyite. The latter and crystallised between 4 and 5 kb (Brown 1977);
green chlorite replace the mesostasis, which is however, the restriction of this amphibole to a
riddled with leucoxene granules after Fe-Ti oxides. single outcrop in the proximity of more abundant
Clear and buff-coloured prehnite occurs in patches metaboninites which contain significantly less
and veins. Augite is fresh and actinolite is absent; sodic actinolite is puzzling, and perhaps reflects a
calcite occurs as veins near major faults. Dolerites localized metasomatic event.
in the lower part of the greenstone pile have the Thomas et al's (1976) record of a partly
assemblage albite-chlorite-actinolite-epidote- serpentinized peridotite with unaltered olivine, also
relict augite, indicative of lower greenschist facies requires comment. We have re-examined this
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metamorphic conditions.
In the aureoles of the Upper Devonian Table 1 Representative electron-probe analyses of
granitoids, basalts and dolerites with burial Heathcote amphiboles.
metamorphic assemblages were overprinted by
Boninites Andesites
albite-epidote hornfels and hornblende hornfels
12 26277 26276 26282 26256 H33
facies contact metamorphic assemblages in the
outer and inner aureoles, respectively. Hornblende SiO2 52.47 55.01 55.36 51.71 52.76 51.73
(6-8% AI2O3) and plagioclase (An4o) composi- T1O2 0.13 0.07 0.10 0.08 0.06 0.13
tions are relatively constant within 50 m of the AI2O3 2.50 2.35 1.05 2.65 3.08 2.59
contact, but with increasing distance from the FeO* 17.22 13.23 14.34 15.30 12.05 15.79
contact become more variable compositionally. MnO 0.23 0.34 0.24 0.31 0.19 0.43
Amphiboles in metabasic rocks of the outer MgO 12.36 14.59 14.06 14.83 15.42 14.40
aureole display a considerable range of AI2O3 CaO 9.90 11.59 11.55 11.99 12.67 11.47
Na2O 1.71 0.61 0.69 0.23 0.35 0.36
contents (2-16%) even in a single thin section,
K2O 0.12 0.04 0.09 0.07 0.11 0.07
indicative of metamorphic disequilibrium. Augite Cr2O3 0.12 0.07 _ 0.16 0.11
0.08
persists in dolerites to much closer to the granite NiO 0.03 0.01 _ — - -
contact than it does in the finer-grained basaltic Total 96.75 97.93 97.55 97.17 96.85 97.08
rocks (Bradfield 1978). Cations calculated to 23 oxygens
Boninites underlying tholeiites at Cornelia East Si 7.785 7.882 8.005 7.598 7.653 7.623
in the northern segment display greenschist facies Al 0.215 0.118 - 0.402 0.347 0.377
assemblages dominated by actinolite, chlorite, Al 0.222 0.279 0.179 0.058 0.180 0.073
albite and quartz. Boninites in the central segment Ti 0.014 0.007 0.011 0.009 0.006 0.014
Fe 2.137 1.585 1.734 1.880 1.462 1.946
have similar assemblages with the addition of
Mn 0.029 0.041 0.029 0.040 0.023 0.053
ferro- and ferristilpnomelane. Epidote is absent.
Mg 2.734 3.116 3.032 3.247 3.335 3.164
Thomas et al (1976) provided a rapid wet Ca 1.573 1.775 1.789 1.887 1.970 1.811
chemical analysis of a metamorphic amphibole Na 0.492 0.170 0.194 0.066 0.102 0.104
(crossite) separated from a She-Oak Gully rock. K 0.023 0.008 0.017 0.013 0.022 0.013
We examined a thin section of this metaboninite Cr 0.009 0.013 0.009 _ 0.020 0.013
lava. Amphibole pseudomorphs after groundmass Ni 0.004 0.001 _ - - _
pyroxene show pale green to bluish-green pleo- £ 15.237 14.995 14.999 15.202 15.124 15.191
chroism; electron probe microanalysis shows that Mg 0 5fi 0.66 0.64 0.63 0.70 0.62
they have a maximum Na2O content of 1.8% Mg+2Fe
(Table 1). The high Na2O contents (5.3%) re-
"Iron calculated as FeO.
corded by Thomas et al (1976) are almost certainly
12 Blue-green actinolite replacing groundmass
attributable to the incorporation in the analysed
acicular augite. She-Oak Gully.
separate of albite, which fills the cores of former
26277 Pseudomorph after spinifex clinopyroxene
hollow pyroxene microlites in the groundmass. 26276 Pseudomorph after groundmass acicular augite
Thus, this amphibole is sodic actinolite, and 26282 Pseudomorph after groundmass augite
differs significantly from the crossitic composi- 26256^ Pseudomorphs after augite phenociysts in
tions reported in Thomas et al (1976) and the H33 ^originally two-pyroxene andesites.
BONINITE ASSOCIATION, HEATHCOTE, VICTORIA 171
sample, which comes from the boninitic unit in the earth element data will be published in a separate
thermal aureole of the Crosbie Granite. Porphyro- paper describing the petrogenesis of the Heathcote
blasts of olivine (F078-80) occur in a groundmass low-Ti lavas.
composed of talc, and minor anthophyllite and Whole rock compositions of the Heathcote
magnetite. We interpret this rock as having formed boninites confirmed our petrographic identification
by the contact metamorphism of an altered pyrox- of this rock type. An analysis of an essentially
enite or serpentinite. aphyric, extremely fresh boninite from the Bonin
The andesites always show greenschist facies Islands (Cameron et al 1983) is given "for
assemblages, characteristically albite-chlorite- comparison in Table 2. The main compositional
epidote-actinolite-quartz + relict augite. The ac- difference between fresh boninites and the Heath-
tinolites are less sodic (<0.5% Na20; Table 1) cote samples lies in the higher Na2O contents of the
than those in the boninites, perhaps implying lower latter, due to albitization of glass. The Heathcote
boninites display the very low TiO2 contents
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Table 2 Representative chemical compositions of rocks from the Heathcote Greenstone Belt, and a typical Bonin Is
boninite.
Boninites Andesites Basalts Diorite Grano-
diorite
Loc. Bonin 26268 26270 26282 26277 26278 26258 26289 27146 27148 26292 26291
SiO2 56.2 57.9 52.1 54.0 56.2 53.9 62.5 60.0 48.3 48.8 50.2 71.4
TiO2 0.13 0.07 0.25 0.14 0.33 0.30 0.27 0.22 1.21 1.14 1.4 0.30
AI2O3 10.6 4.8 10.0 9.5 10.6 12.9 12.1 13.5 13.9 12.8 14.8 13.9
FeaOa 2.0 2.9 1.9 3.7 2.9 n.d. 2.3 n.d. 1.2 1.9 n.d. n.d.
FeO 6.2 7.1 9.2 9.5 6.4 10.1 4.1 6.5 8.5 9.9 10.7 2.8
MnO 0.16 0.24 0.18 0.17 0.15 0.12 0.10 0.13 0.38 0.24 0.14 0.06
MgO 11.2 15.1 12.2 10.2 7.2 7.2 6.9 3.6 7.4 7.4 8.4 0.76
CaO 7.4 6.1 6.5 5.2 5.9 5.3 4.2 2.4 10.9 10.1 8.1 2.2
Na 2 O 1.5 1.2 3.4 2.6 5.1 5.2 3.5 6.8 3.9 3.7 2.4 3.8
K2O 0.40 0.02 0.15 0.59 1.3 1.4 1.2 0.7 0.13 0.17 1.3 2.6
P2O5 0.02 0.02 0.05 0.07 0.08 0.05 0.08 0.11 0.09 0.09 0.14 0.09
H2O+ 3.0 4.6 3.6 3.9 2.3 3.4 2.9 5.4 3.3 3.0' 1.9 1.3
H2O- 0.9 0.8 0.8 0.5 0.6 n.d. 0.1 n.d. 0.2 0.2 n.d. n.d.
CO2 <0.1 <0.1 <0.1 <0.1 <0.1 n.d. <0.1 n.d. <0.1 0.2 n.d. n.d.
Total 99.8 100.8 100.3 100.1 99.0 99.9 100.3 99.3 99.4 99.6 99.5 99.2
Cr 695 2580 1240 684 147 191 275 67 204 192 429 6
Ni 19.4 460 243 156 69 72 83 40 102 85 87 2
Mg 0.71 0.73 0.67 0.59 0.59 0.56 0.64 0.50 0.58 0.53 0.58 0.33
Mg + 2Fe
n.d. = not determined. For these samples, loss on ignition is reported as H2O"1" and total Fe as FeO.
Sample numbers are those of the Melbourne University Geology Department Collection.
172 A. J. CRAWFORD ET AL
Analyses of a two-pyroxene andesite (26258) diorite nor the microgranodiorite (which is the
and a hornblende-phyric andesite (26289) from most evolved rock in the Heathcote Greenstone
Heathcote are given in Table 2. The majority of Belt) have any obvious chemical features in
Heathcote andesites are compositionally similar to common with the andesites, boninites or tholeiites.
Sample 26258, which has a most unusual composi- They appear to represent a later magmatic episode,
tion compared with modern orogenic andesites but in the absence of fresher samples and geo-
(Gill 1981). Ignoring contents of elements likely to chronological data, any interpretation of the
have been significantly mobile during metamor- petrogenesis and significance of these rocks is
phic modification of these lavas (Na, K, Ca and premature.
perhaps Si), characteristic features of the Heath-
cote andesites are their extremely low TiCh con-
tents, their low FeO* and AI2O3 contents, and their TECTONIC IMPLICATIONS
generally high MgO, Cr and Ni contents. Petro-
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erupted onto backarc basin crust. When the sub- consists of boninites and unusual low-Ti andesites;
ducted spreading centre reached approximately indirect evidence suggests that the andesites are
40-50 km depth, diapirs feeding the spreading slightly younger than the boninites. Several stocks
centre ascended into the over riding plate and and dykes of (?) Cambrian diorite-
MORB magmas generated from partial melting of microgranodiorite have intruded the andesites.
these diapirs were erupted upon low-Ti lavas in the Fossiliferous Middle Cambrian sediments overlie
Middle Cambrian, thus explaining the stratigraphic the tholeiitic lavas of the northern and southern
sequence of metavolcanics observed in the Heath- segments, and are faulted against andesites in the
cote Greenstone Belt. central segment. Tholeiitic volcanism is thus
Continued subduction of oceanic crust after presumed to have ceased in the late Lower
subduction of the spreading centre led to consump- Cambrian or early Middle Cambrian.
tion of the remaining oceanic crust. As a result, The association of low-Ti lavas and MORB in
the Heathcote Greenstone Belt is known only from
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CONCLUSIONS
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