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Journal of King Saud University – Science (2012) 24, 123–129

King Saud University


Journal of King Saud University –
Science
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ORIGINAL ARTICLE

Simultaneous heat and mass transfer in natural convection


about an isothermal vertical plate
a,*
F. Khani , Abdul Aziz b, S. Hamedi-Nezhad a

a
Department of Mathematics, Bakhtar Institute of Higher Education, Ilam, Iran
b
Department of Mechanical Engineering, School of Engineering and Applied Science, Gonzaga University, Spokane,
WA 99258, USA

Received 23 July 2010; accepted 5 September 2010


Available online 24 November 2010

KEYWORDS Abstract The homotopy analysis method has been used to derive a highly accurate analytic solu-
Vertical plate; tion for simultaneous natural convection and mass transfer from an isothermal vertical plate. Veloc-
Natural convection; ity, temperature, and concentration profiles are presented for a fixed Prandtl number of 0.71 and for
Simultaneous heat and mass Schmidt numbers of 0.5, 5, and 10 and for the buoyancy ratio of 0 (pure mass transfer), 0.5 (simul-
transfer; taneous heat and mass transfer), and 1 (pure heat transfer). The present results corroborate well
Homotopy analysis method; with the numerical results reported in other research literature on the problem. The auxiliary
Optimal convergence-control parameter in the homotopy analysis method is derived by using the averaged residual error concept
parameter which significantly reduces the computational time. The use of optimal auxiliary parameter pro-
vides a superior control on the convergence and accuracy of the analytic solution.
ª 2010 King Saud University. Production and hosting by Elsevier B.V. All rights reserved.

1. Introduction to the problem were made by Gebhart and Pera (1971),


Mollendorf and Gebhart (1974), Taunton et al. (1970), and
The problem of simultaneous heat and mass transfer from an Bottemanne (1972a,b). Because of simultaneous heat and mass
isothermal vertical flat plate is of fundamental importance to transfer, the transport process is driven by the interaction of
the thermal science community. The pioneering contributions velocity, concentration and thermal boundary layers. The veloc-
ity, concentration, and temperature profiles depend on whether
* Corresponding author. Tel./fax: +98 841 2238527. the buoyancy forces due to temperature difference and concen-
E-mail address: farzad_khani59@yahoo.com (F. Khani). tration difference aid (aiding flow) or oppose each other (oppos-
ing flow). Bottemanne (1972a,b) considered mass transfer due to
1018-3647 ª 2010 King Saud University. Production and hosting by the injection of water vapor from the plate into the surrounding
Elsevier B.V. All rights reserved.
fluid. He found that for the aiding flow, the heat and mass trans-
fer processes can be treated independent of each other and the
Peer review under responsibility of King Saud University.
doi:10.1016/j.jksus.2010.09.002 results combined to predict the case when the two processes oc-
cur simultaneously. This work was examined by Schenk et al.
(1976) who noted that Bottemanne’s conclusion was valid be-
Production and hosting by Elsevier cause the Prandtl number Pr = 0.71 and Schmidt number
Sc = 0.94 used by him were nearly the same. The numerical
124 F. Khani et al.

computations of Schenk et al. (1976) led to the conclusion that directions of the velocity components u and v are also indi-
for Pr = 0.7 and 0.6 < Sc < 0.9, the mutual interaction of heat cated. The boundary layer equations for this model can be
and mass transfer processes was indeed minimal and the two written as (Bottemanne, 1972a; Schenk et al., 1976)
processes can be treated separately and the two results added. @u @v
This approach gives results that are in error by about 2%, when þ ¼ 0; ð1Þ
@x @y
compared with the result from the simultaneous analysis. The 2
numerical method used by Schenk et al. (1976) involved an iter- @u @u q q @ u
u þv ¼g 1 þv 2; ð2Þ
ative procedure to solve the coupled similarity equations for the @x @y q @y
stream function, temperature, and concentration. @h @h @2h
In the present work, we revisit the problem considered by u þv ¼a 2; ð3Þ
@x @y @y
Bottemanne (1972b) and provide a highly accurate analytical
@X @X @2X
solution of the problem using the homotopy analysis method u þv ¼D 2: ð4Þ
@x @y @y
(HAM). In recent years, the homotopy analysis method
(HAM) (Liao, 1999, 2003, 2009; Liao and Tan, 2007), has been where q is the local density, q1 is the density of the fluid out-
successfully applied to many nonlinear problems in science and side the boundary layers, h is the local temperature difference,
engineering (Molabahrami and Khani, 2009; Khani et al., a is the thermal diffusivity of the fluid, X is the local mass frac-
2009a,b,c; Khani and Aziz, 2009; Darvishi and Khani, 2009; tion difference, and D is the mass diffusivity. The proper
Aziz and Khani, 2009). Unlike the perturbation techniques, boundary conditions are:
HAM is independent of any small physical parameters. More 8
importantly, unlike the perturbation and non-perturbation <x > 0 y ¼ 0
> u ¼ v ¼ 0 h ¼ h 0 X ¼ X0 ;
methods, HAM provides a simple way to ensure the conver- x>0 y¼1 u¼0 h ¼ 0 X ¼ 0; ð5Þ
>
:
gence of series solution so that one can always get accurate en- x¼0 y>0 u¼0 h ¼ 0 X ¼ 0:
ough approximations even for the strongly nonlinear
The classical method of solving the system of Eqs. (1)–(5) may
problems. Furthermore, HAM provides the freedom to choose
be found in most heat and mass transfer textbooks. The same
the so- called auxiliary linear operator so that one can approx-
set of equations were considered by Bottemanne (1972a,b). To
imate a nonlinear problem more effectively by means of better
start the procedure, we have to introduce an expression for the
base functions, as demonstrated by Liao and Tan (2007). The
density q as a function of the temperature h and the concentra-
degree of freedom is so large that even the second-order non-
tion X. This expression is taken from Bottemanne (1972b),
linear two-dimensional Gelfand equation can be solved by
who derived it from the assumption that the ideal gas law
means of a 4th-order auxiliary linear operator within the
applies to the air vapour mixture about the vertical wall. If
framework of the HAM as shown in Liao and Tan (2007).
we also introduce the well known stream function substitutions
Especially, by means of the HAM, a few new solutions of some
of von Mises and thereupon the similarity transformation of
nonlinear problems (Liao, 2005, 2006) have been achieved
Pohlhausen, we finally obtain (Bottemanne, 1972b):
which otherwise were not solvable by other analytic methods.
 2
d3 f df d2 f
 2 þ 3f þ dt þ ð1  dÞx ¼ 0; ð6Þ
2. Formulation of the problem dg3 dg dg2
d2 t dt
The physical model and the coordinate system are shown in þ 3Prf ¼ 0; ð7Þ
dg2 dg
Fig. 1 where heat and water vapour are transferred simulta-
neously from the vertical flat plate to the environment. The d2 x dx
þ 3Scf ¼ 0; ð8Þ
dg2 dg
with boundary conditions

g fð0Þ ¼ 0 f0 ð0Þ ¼ 0 tð0Þ ¼ 1 xð0Þ ¼ 1; ð9Þ


f0 ðþ1Þ ¼ 0 tðþ1Þ ¼ 0 xðþ1Þ ¼ 0: ð10Þ
In this formulation f, t, and x represent the reduced stream
u function, temperature and concentration respectively; the inde-
pendent variable g = cyx1/4, where the constant c depends on
v
the buoyancy forces. The Prandtl and Schmidt numbers have
their usual definitions: Pr = t/a and Sc = t/D. The parameter
T d represents essentially the ratio of the thermal buoyancy to
T0 C the total body force; so is (1  d) the ratio of concentration
C0 buoyancy to the total effect. For aiding (upward) buoyancy
forces d is necessarily 0 < d < 1. In the next section, we solve
the system of non-linear ordinary differential Eqs. (6)–(10)
x analytically using HAM.

3. HAM solution
y
In view of the boundary conditions (9) and (10), f(g), t(g), and
Figure 1 Physical model and coordinate system. x(g) can be expressed by the set of base functions of the form
Simultaneous heat and mass transfer in natural convection about an isothermal vertical plate 125

fgj expðngÞjj P 0; n P 0g ð11Þ @ 2 xðg;


^ qÞ ^
^ qÞ @ xðg; qÞ
N3 ¼ þ 3Scfðg; :
in the form of the following series @g2 @g
1 X
X 1 Clearly, when q = 0 the zero-order deformation Eqs. (24)–(26)
fðgÞ ¼ a00;0 þ akn;k gk expðngÞ; ð12Þ give rise to
n¼0 k¼0
^ 0Þ ¼ f0 ðgÞ;
fðg; ^tðg; 0Þ ¼ t0 ðgÞ; ^
xðg; 0Þ ¼ x0 ðgÞ:
X1 X 1
tðgÞ ¼ bkn;k gk expðngÞ; ð13Þ When q = 1, they become
n¼0 k¼0
X 1 X 1 ^ 1Þ ¼ fðgÞ;
fðg; ^tðg; 1Þ ¼ tðgÞ; ^
xðg; 1Þ ¼ xðgÞ:
xðgÞ ¼ ckn;k gk expðngÞ ð14Þ
n¼0 k¼0 ^ qÞ; ^tðg; qÞ and xðg;
Expanding fðg; ^ qÞ in the Maclaurin series
in which akn;k , bkn;k , and ckn;k are the coefficients. Invoking the so- with respect to the embedding parameter q, we obtain
called rule of solution expressions for f(g), t(g), x(g) and Eqs. X
1
^ qÞ ¼ f0 ðgÞ þ
fðg; fk ðgÞqk ; ð29Þ
(9), (10) the initial guesses f0(g), t0(g), x0(g) and linear opera-
k¼1
tors L1 , L2 , and L3 are X1

f0 ðgÞ ¼ ð1 þ gÞ expðgÞ  1; ð15Þ ^tðg; qÞ ¼ t0 ðgÞ þ tk ðgÞqk ; ð30Þ


k¼1
t0 ðgÞ ¼ expðgÞ; ð16Þ X1

x0 ðgÞ ¼ expðgÞ; ð17Þ ^


xðg; qÞ ¼ x0 ðgÞ þ xk ðgÞqk ; ð31Þ
k¼1
3
@ f @f
L1 ðfÞ ¼  ; ð18Þ where
@g3 @g
@2t 1 @k ^ 1 @k
L2 ðtÞ ¼ 2  t; ð19Þ fk ðgÞ ¼ fðg; 0Þ; tk ðgÞ ¼ ^tðg; 0Þ;
@g k! @qk k! @qk
@2x 1 @k
L3 ðxÞ ¼  x: ð20Þ xk ðgÞ ¼ ^
xðg; 0Þ: ð32Þ
@g2 k! @qk

The operators L1 , L2 , and L3 have the following properties: Assuming that above series converges at q = 1, we have
X
1
L1 ðc1 þ c2 expðgÞ þ c3 expðgÞÞ ¼ 0; ð21Þ fðgÞ ¼ f0 ðgÞ þ fk ðgÞ; ð33Þ
L2 ðc4 expðgÞ þ c5 expðgÞÞ ¼ 0; ð22Þ k¼1
X1
L3 ðc6 expðgÞ þ c7 expðgÞÞ ¼ 0: ð23Þ tðgÞ ¼ t0 ðgÞ þ tk ðgÞ; ð34Þ
k¼1
in which ci, i = 1, 2, . . . , 7 are arbitrary constants.
X1
Let q 2 [0, 1] denotes an embedding parameter and  h1, 
h2, xðgÞ ¼ x0 ðgÞ þ xk ðgÞ: ð35Þ
and h3 are non-zero auxiliary parameters. Then we construct k¼1
the following zeroth-order deformation equations
Differentiating the zero-order deformation Eqs. (24)–(28) m
^ qÞ  f0 ðgÞ ¼ qh1 N 1 ½fðg;
ð1  qÞL1 ½fðg; ^ qÞ; ^tðg; qÞ; xðg;
^ qÞ; times with respect to q, then setting q = 0, and finally dividing
ð24Þ by m!, we have the high-order deformation equations (m P 1)
L1 ½fm  vm fm1  ¼ 
h1 Rm ; ð36Þ
^ qÞ; ^tðg; qÞ; xðg;
ð1  qÞL2 ½^tðg; qÞ  t0 ðgÞ ¼ qh2 N 2 ½fðg; ^ qÞ; L2 ½tm  vm tm1  ¼ 
h2 S m ; ð37Þ
ð25Þ L3 ½xm  vm xm1  ¼  h3 Km ; ð38Þ

ð1  qÞL3 ½xðg;
^ ^ qÞ; ^tðg; qÞ; xðg;
qÞ  x0 ðgÞ ¼ qh3 N 3 ½fðg; ^ qÞ; with the boundary conditions:

ð26Þ fm ð0Þ ¼ f0m ð0Þ ¼ f0m ðþ1Þ ¼ 0; ð39Þ


subject to the conditions tm ð0Þ ¼ tm ðþ1Þ ¼ 0; ð40Þ
xm ð0Þ ¼ xm ðþ1Þ ¼ 0; ð41Þ
^ qÞ ¼ 0;
fð0; f^0 ð0; qÞ ¼ 0; f^0 ðþ1; qÞ ¼ 0; ð27Þ
where

^tð0; qÞ ¼ 1; ^tðþ1; qÞ ¼ 0; ^
xð0; qÞ ¼ 1; ^
xðþ1; qÞ ¼ 0 0; m ¼ 1;
vm ¼
ð28Þ 1; m > 1;
where the non-linear operators are defined as: and
!2 X
m1 X
m1
^ qÞ
@ 3 fðg; ^ qÞ
@ fðg; 2^
N1 ¼  2 þ 3 ^ qÞ @ fðg; qÞ þ d^tðg; qÞ
fðg; Rm ¼ f000
m1  2 f0i f0m1i þ 3 fi f00m1i þ dtm1 þ ð1  dÞxm1 ;
@g3 @g @g2 i¼0 i¼0
X
m1
þ ð1  dÞxðg;
^ qÞ; S m ¼ t00m1 þ 3Pr fi t0m1i ;
i¼0
X
m1
@ 2^tðg; qÞ ^ qÞ @^tðg; qÞ ; Km ¼ x00m1 þ 3Sc fi x0m1i :
N2 ¼ 2
þ 3Prfðg;
@g @g i¼0
126 F. Khani et al.

Then the solutions for Eqs. (36)–(38) can be expressed by 0.999998

fm ðgÞ ¼ vm fm1 þ h1 L1


1 ½Rm  þ d1 þ d2 expðgÞ þ d3 expðgÞ;
tm ðgÞ ¼ vm tm1 þ h2 L1
2 ½S m  þ d4 expðgÞ þ d5 expðgÞ; 0.999998
xm ðgÞ ¼ vm xm1 þ h3 L1
3 ½Km  þ d6 expðgÞ þ d7 expðgÞ;

where di are constants to be determined by boundary condi- 0.999999


tions (39)–(41), L1 1 ; L2
1
and L1
3 denote the inverse linear
operators of L1 ; L2 , and L3 so that the problem is closed.
For example, solving the 1st-order deformation equation, we 0.999999
have
   
35h1 h1 31h1 11h1 g h1 g2
f1 ðgÞ ¼ þ eg   h1 g2 þ e2g    ; 1.000000
108 27 108 18 6
   
7h2 Pr h2 g 3h2 Prg 7h2 Pr
t1 ðgÞ ¼ eg   þ e2g   h2 Prg ;
3 2 2 3
    1.000000
7h3 Sc h3 g 3h3 Scg 7h3 Sc
x1 ðgÞ ¼ eg   þ e2g   h3 Scg :
3 2 2 3
1.000000
With the aid of mathematical software, such as MATHEM- 1.3 1.2 1.1 1.0 0.9 0.8 0.7
ATICA or MAPLE, it is easy to derive the higher order
solutions.
Figure 2 The curve of the f000 ð0Þ versus 
h at Pr = 0.71, Sc = 0.1,
4. Results and discussion and d = 0.5 for the 13th-order approximation when
h1 = 
 h2 = 
h3 = 
h.
At the mth-order approximation, we have the analytic solu-
tions of (6)–(8), namely
X
m1 X
m1 X
m1
0.0001
fðgÞ  fk ðgÞ; tðgÞ  tk ðgÞ; xðgÞ  xk ðgÞ:
k¼0 k¼0 k¼0

As pointed out by Liao (2009), the convergence and the rate of 0.00008
approximation for the HAM solution strongly depends upon
h. In order to obtain the admissible value of h for the present
 0.00006
problem, we set h1 = h2 = h3 = h and the h-curves are plotted
for 13th-order of approximations. This helps us to determine
0.00004
the valid region of 
h, which corresponds to the line segment al-
most parallel to the horizontal axis. Figs. 2–4 show the valid
region of h for f000 ð0Þ; t00 ð0Þ, and x00 ð0Þ, respectively. The 0.00002
parameters chosen for establishing the region of convergence
were Pr = 0.71, Sc = 0.1, and d = 0.5. In fact, the interval
0.0000
for the admissible values of h shrinks as the parameters in-
crease. In theory, at the mth-order of approximation, one
can define the exact square residual errors 0.00002
Z þ1 " #!2
Xm X
m X
m
Di;m ¼ Ni fj ; tj ; xj dg; i ¼ 1; 2; 3: 0.00004
0 j¼0 j¼0 j¼0

ð42Þ 1.4 1.2 1.0 0.8 0.6

Note that Di,m contains at most three unknown convergence-


control parameters h1, h2, and h3, even at very high order of Figure 3 The curve of the t00 ð0Þ versus 
h at Pr = 0.71, Sc = 0.1,
approximation. Obviously, the more quickly Di,m decreases and d = 0.5 for the 13th-order approximation when
to zero, the faster the corresponding homotopy-series solution h1 = 
 h2 = 
h3 = 
h.
converges. So, at the given order of approximation m, the cor-
responding optimal values of the convergence-control param- in practice. To overcome this disadvantage, Liao (2010) intro-
eters h1, h2, and h3 are given by the minimum of Di,m, duced a more efficient definition of the residual error to replace
corresponding to a set of three nonlinear algebraic equations (42). Thus, to greatly decrease the CPU time, we use here the
@Di;m @Di;m @Di;m so-called averaged residual error defined by
¼ 0; ¼ 0; ¼ 0: ð43Þ
@h1 @h2 @h3 " #!2
1 XK Xm Xm Xm

Unfortunately, the exact square residual error Di,m defined by Ei;m ¼ Ni fj ðsDgÞ; tj ðsDgÞ; xj ðsDgÞ ;
K s¼0 j¼0 j¼0 j¼0
(42) consumes too much CPU time to calculate even if the or-
der of approximation is not very high, and thus is often useless i ¼ 1; 2; 3: ð44Þ
Simultaneous heat and mass transfer in natural convection about an isothermal vertical plate 127

10
2. 10

10
1. 10

10
1. 10

1.2 1.1 1.0 0.9 0.8

Figure 4 The curve of the x00 ð0Þ versus 


h at Pr = 0.71, Sc = 0.1, and d = 0.5 for the 13th-order approximation when 
h1 = 
h2 = 
h3 = 
h.

where Dg = 10/K and K = 20 for this problem. The averaged


residual error Ei,m defined by (44) can give good enough Sc 0.5
approximation of the optimal convergence-control parame- Sc 5
ters. However, the CPU time to get the averaged residual error 0.25
Sc 10
Ei,m is much less than that to calculate the exact residual error
Di,m in case of m > 6. We reports the optimal values of  h1, 
h2,
and h3 for different values of Sc and d at 13th-order approxi- 0.20
mation in Tables 1 and 2.
Fig. 5 shows the distribution of the vertical component of
the velocity as a function of the similarity variable for Schmidt 0.15
number Sc = 0.5, 5, and 10 with Pr = 0.71 and d = 0.5. In
each case, the peak velocity occurs at g = 1. However, the
magnitude of the peak velocity decreases as the Schmidt num-
0.10
ber Sc increases. This behavior is consistent with the velocity
profiles presented in Fig. 1 of Schenk et al. (1976). The temper-
ature profiles corresponding to the velocity profiles in Fig. 5
0.05

Table 1 Optimal values of 


h1, 
h2, and 
h3 for different values of
Sc at 13th-order approximation. 0.00
Pr = 0.71 d = 0.5 0 1 2 3 4 5 6 7
Sc h1
 h2 h3
0.5 1.23 1.21 1.22 Figure 5 Influence of Sc on f0 ðgÞ at Pr = 0.71 and d = 0.5 at the
5 0.95 1.10 1.13 h1, 
optimal values of  h2, and 
h3.
10 0.72 0.92 0.93

are illustrated in Fig. 6. These profiles show that as the


Schmidt number Sc increases, the local temperature in the
thermal boundary layer increases. The same pattern can be
Table 2 Optimal values of h1, 
h2, and 
h3 for different values of
gleaned from the temperature distributions in Fig. 1 of Schenk
d at 13th-order approximation.
et al. (1976). The concentration profiles corresponding to the
Pr = 0.71 Sc = 0.1 velocity profiles of Fig. 5 and temperature profiles of Fig. 6
d h1
 h2 h3 are provided in Fig. 7. Both the thickness of the concentration
0 1.12 1.02 1.05 boundary layer and the local concentration decrease sharply as
0.5 0.84 1.10 0.87 the Schmidt number increases. The thinning of the concentra-
1 0.83 0.81 0.84 tion boundary layer with the increase in Sc can also be ob-
served distinctly in the results presented in Schenk et al. (1976).
128 F. Khani et al.

1.0 process. The lowest peak velocity occurs for d = 1, i.e., for
Sc 0.5
the pure heat transfer process. The hydrodynamic boundary
Sc 5
is thickest for pure mass transfer and thinnest for pure heat
Sc 10
transfer with the thickness for simultaneous heat and mass
0.8 transfer falling in the middle. The pattern exhibited by the
present results matches with the results reported in Schenk
et al. (1976). The temperature profiles corresponding to the
velocity profiles of Fig. 8 are given in Fig. 9. The highest tem-
0.6
peratures occur in the pure heat transfer case (d = 1). The low-
est temperature are predicted for the pure mass transfer

0.4
0.4
0
0.5
0.2 1

0.3

0.0
0 1 2 3 4 5 6 7

0.2
Figure 6 Influence of Sc on t(g) at Pr = 0.71 and d = 0.5 at the
optimal values of h1, 
h2, and 
h3.

1.0 0.1

Sc 0.5
Sc 5
Sc 10
0.8
0.0
0 1 2 3 4 5 6 7
η

0.6 Figure 8 Influence of d on f0 ðgÞ at Pr = 0.71 and Sc = 0.1 at the


optimal values of 
h1, 
h2, and 
h3.

0.4
1.0
0
0.5
0.2 1
0.8

0.0
0 1 2 3 4 5 6 0.6

Figure 7 Influence of Sc on x(g) at Pr = 0.71 and d = 0.5 at the


optimal values of h1, 
h2, and 
h3. 0.4

We now turn to the results which demonstrate the effect of


varying the parameter d. The parameter d represents the ratio 0.2
of thermal buoyancy force and the total body force (algebraic
sum of gravity, thermal and concentration buoyancy forces).
Thus d = 0 corresponds to zero thermal buoyancy force which
means the process is pure mass transfer driven. Similarly, 0.0
d = 1 implies a pure heat transfer process. The effect of d on 0 1 2 3 4 5 6 7
the velocity distribution in the hydrodynamic boundary is
shown in Fig. 8 for Pr = 0.71 and Sc = 0.1. The highest peak Figure 9 Influence of d on t(g) at Pr = 0.71 and Sc = 0.1 at the
velocity occurs for d = 0, i.e., for the pure mass transfer h1, 
optimal values of  h2, and 
h3.
Simultaneous heat and mass transfer in natural convection about an isothermal vertical plate 129

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The homotopy analysis method has been successfully imple- nonlinear differential equations. Commun. Nonlinear Sci. Numer.
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This work is partly supported by Bakhtar Institute of Higher free convection heat and mass transfer in laminar boundary layers.
Chem. Eng. Sci. 25 (12), 1927–1937.
Education of Iran.

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